JPH10204477A - Detergent composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain the subject composition capable of developing good foaming property, creamy feeling of foam and good performance in rinsing and useful for facial cleansing cream, (body) shampoo, etc. by including specific heterogeneous anionic surfactants and a higher fatty acid alkanol amide. SOLUTION: This detergent composition comprises (A) two-chain and dipolar group-containing anionic surfactant having a long-chain hydrophobic group (R1 ) with a carbon number of 18, 16, 14, 12, 10 or 8, a polar group (R2 ) which is carboxyl, sulfuric acid group, sulfonic acid group or phosphoric acid group and a pair ion (R3 ) which is a monovalent or divalent alkali metal ion or an (organic) ammonium ion, (B) a mono-chain and monopolar group-containing anion surfactant having R2 and R3 and (C) a higher fatty acid alkanol amide so that weight ratio of components (A+B)/C becomes (30/1) to (3/1).

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a cleaning composition having good lathering, excellent lathering feeling, and good rinsing performance.

[0002]

2. Description of the Related Art Conventionally, a cleaning composition which is used for cleaning the body and hair has been studied which is excellent in foaming and creaminess of foam and has a good rinsing feeling. For example, in order to improve the feeling of rinsing during hair washing, an attempt has been made to blend a cationic polymer such as cationic cellulose with a normal (single-chain, one-polar-group-containing) anionic surfactant which is a main ingredient of a hair cleaning agent. It has been recognized that this formulation improves the rinsing feel. This is because an anionic surfactant for hair washing, such as polyoxyethylene lauryl ether sulfate or alkyl sulfate, forms a complex salt with a cationic polymer upon rinsing and is adsorbed on hair. On the other hand, the blending of the cationic polymer has disadvantages such as hardening of the hair at the time of rinsing or finishing. Therefore, recently, a hair cleaning agent containing an amphoteric surfactant and a specific amphoteric polymer has been studied. When this is used, defects such as hardening of hair at the time of rinsing or finishing can be solved, but it cannot be said that foaming and creaminess of foam are sufficiently satisfied. As described above, a cleaning composition having good foaming, excellent foam creaminess, and good rinsing performance has not yet been developed, and improvement thereof has been desired.

[0003]

The present inventor has made intensive studies to improve such disadvantages of the prior art, and as a result,
Specific two-chain anionic surfactant containing a dipolar group and one-chain one
The present inventors have found that a detergent composition containing a polar group-containing anionic surfactant and a higher fatty acid alkanolamide remarkably improves the above disadvantages, and have completed the present invention. That is, an object of the present invention is to provide a detergent composition which has good foaming, is excellent in creamy feeling of foam, and has good performance at the time of rinsing.

[0004]

The invention of claim 1 of the present invention relates to (a) a method wherein (a) the long-chain hydrophobic group has 18, 16, 14, 1 or more carbon atoms;
2, 10 or 8, wherein the polar group is a carboxyl group, a sulfate group, a sulfonic acid group, or a phosphate group, and the counter ion is a monovalent or divalent alkali metal ion, ammonium ion or organic ammonium ion. One or more of the chain dipolar group-containing anionic surfactants, and (b) the polar group is a carboxyl group, a sulfate group, a sulfonic acid group, or a phosphate group, and the counter ion is monovalent or divalent. And (c) a higher fatty acid alkanolamide, which contains one or more anionic surfactants containing one chain and one polar group, which are alkali metal ions, ammonium ions or organic ammonium ions. ) + (B)] / (c) in a mixing weight ratio of 30: 1 to 3: 1.

[0005]

Next, an embodiment of the present invention will be described. The two-chain dipolar group-containing anionic surfactant in the present invention has a long-chain hydrophobic group having 18, 16, 14, 12, or 12 carbon atoms.
10 or 8 as long as it has this type of molecular structure. As an example, N, N'-bis [2-lauramidoethyl) ethylenediamine-N, N'-di (sodium acetate) can be mentioned. A mixture with a homologue having a different hydrophobic group in the molecular structure of the compound is also blended within the scope of the present invention. As the counter ion used here, a monovalent or divalent alkali metal ion, ammonium ion or organic ammonium ion is applied. However, basic amino acids such as lysine and arginine also correspond to the organic ammonium ion. In addition to N, N'-bis [2-lauramidoethyl) ethylenediamine-N, N'-di (sodium acetate), more specifically,
N'-bis [2-myristoylamidoethyl) ethylenediamine-N, N'-di (sodium acetate), N, N'-
Bis [2-palmitoiramidoethyl) ethylenediamine-N, N'-di (sodium acetate), N, N'-bis [2-lauramidoethyl) ethylenediamine-N, N '
-Di (sodium propionate), N, N'-bis [2
-Myristoylamidoethyl) ethylenediamine-N,
N'-di (sodium propionate), N, N'-bis [2-palmitoiramidoethyl) ethylenediamine-
N, N'-di (sodium propionate), N, N'-
Bis (lauroylamide) ethane-N, N'-di (sodium acetate), N, N'-bis (myristoylamide)
Ethane-N, N'-di (sodium acetate), N, N'-
Bis (palmitoylamide) ethane-N, N'-di (sodium acetate), N, N'-bis (lauroylamide)
Ethane-N, N'-di (sodium propionate),
N, N'-bis (myristoylamide) ethane-N,
N′-di (sodium propionate), N, N′-bis (palmitoylamide) ethane-N, N′-di (sodium propionate), N, N′-bis (lauroylamido) butane-N, N ′ -Di (potassium acetate), N, N '
-Bis (myristoylamide) butane-N, N'-di (potassium acetate), N, N'-bis (palmitoylamide) butane-N, N'-di (potassium acetate), N, N '
-Bis (lauroylamide) ethane-N, N'-di (potassium ethanesulfonate), N, N'-bis (myristoylamide) butane-N, N'-di (potassium ethanesulfonate), N, N ' -Bis (palmitoylamide) ethane-N, N'-di (sodium ethanesulfonate). Also, 4,7-dioctanoyl-4,7-
Diazadecane-1,10-disulfonate disodium,
3,6-dioctanoyl-3,6-diazadecane-1,
8-disulfate is also included. The two-chain, two-polar group-containing anionic surfactant applied to the present invention is not limited to the compounds or homologs shown here, and mixtures thereof. No printed matter (for example, JP-A-8-103646)
Also known are those known as.

Among the one-chain and one-polar group-containing anionic surfactants according to the present invention, those containing a carboxyl group mean firstly those generally called soaps having 10 to 10 carbon atoms.
It refers to up to 20 and is usually used as a mixed fatty acid regardless of animal origin, plant origin, or synthetic product. The counter ion is arbitrarily selected from monovalent or divalent alkali metal ions, ammonium ions and organic ammonium ions. Further, among the anionic surfactants containing one long chain and one polar group in the present invention, those containing a carboxyl group are those having N
-Means an acyl amino acid-based anionic surfactant collectively, having an acyl group of 10 to 20 carbon atoms,
The constituent amino acids include glutamic acid, glycine, alanine, valine, taurine and the like. Further, the anionic surfactant containing one long-chain and one polar group in the present invention means a surfactant containing a polar group other than the above-mentioned carboxyl group, that is, a sulfonic acid group, a sulfate group, and a phosphate group. That is, alkane sulfonates, α-olefin sulfonates, sulfonates of higher fatty acid esters, sulfonates of higher fatty acid amides, sulfonates such as sulfosuccinates, alkyl sulfates, alkyl ether sulfates, higher fatty acid esters Sulfates, such as sulfates of higher fatty acid alkylolamide, and phosphates such as alkyl phosphates and alkyl ether phosphates. The counter ion of the anionic surfactant containing one long-chain and one polar group is arbitrarily selected from monovalent or divalent alkali metal ions, ammonium ions and organic ammonium ions. Here, it goes without saying that basic amino acids such as lysine and arginine also correspond to the organic ammonium ion. One or more of these one long-chain and one polar group-containing anionic surfactants are blended in the cleaning composition of the present invention.

[0007] The higher fatty acid alkanolamide in the present invention means a condensation product of a higher fatty acid having 8 to 20 carbon atoms with an alkanolamine such as diethanolamine, monoethanolamine and isopropanolamine. It does not matter what is called the 2: 1 type or the 1: 1 type. As a higher fatty acid constituting this, a mixed system of coconut oil fatty acid and the like is also applied. The blending amount of the higher fatty acid alkanolamide is 10 to 0.5% by weight.

The total amount (% by weight) of the two-chain, two-polar group-containing anionic surfactant and the one long-chain, one-polar group-containing anionic surfactant ((a) + (b)) according to the present invention and the higher fatty acid The ratio of the amount of alkanolamide (% by weight) (c)
30: 1 to 3: 1 is essential. The effect can be expected even if the total amount of the two-chain, two-polar group-containing anionic surfactant and one long-chain, one-polar group-containing anionic surfactant exceeds 30 with respect to 1 of the higher fatty acid alkanolamide. Not as high. On the other hand, the amount of the higher fatty acid alkanolamide was 1 and the amount of the anionic surfactant containing a two-chain bipolar group was 1
The total amount of the long chain monopolar group-containing anionic surfactant is 3
If it is less than the above, the effect on the foam is reduced. The total amount of the two-chain, two-polar group-containing anionic surfactant and the one long-chain, one-polar group-containing anionic surfactant in the detergent composition of the present invention is 35 to 50%.
3% by weight.

The detergent composition of the present invention comprises the above-mentioned composition. If necessary, other detergents, emulsifying auxiliaries,
Flavors, colorants, preservatives, pigments, and the like can be appropriately blended within a range that achieves the object of the present invention. The cleaning composition of the present invention is applied to ordinary cosmetic cleaning compositions mainly for the purpose of cleaning face-wash creams, liquid facial cleansers, body shampoos, shampoos and the like.

[0010]

EXAMPLES The present invention will be described below with reference to examples, but the present invention is not limited to these examples. In addition, the compounding amount is weight%. The performance evaluation of the cleaning compositions of the examples and the comparative examples was performed by sensory evaluation when ten test subjects washed hair using the cleaning compositions. That is, the subject's head is divided into two parts, one of which is washed with 3 g of the standard sample A and the other with 3 g of the test sample, and i. Foaming, ii. Foamy creaminess; iii. The three items, whether or not there was creaking during rinsing, were scored by the report of the subjects. The scoring criteria are +3 points when B is better than A, +2 points when B is better than A, +1 point when B is slightly better than A, 0 point when A and B are equal, and-when B is worse than A. 2 points, and -3 points when B was much worse than A. And the total obtained from 10 subjects is 30 to 2
0 points are ◎, 19 to 10 points are ○, 9 to -10 points are Δ, -1
1 to -30 points are shown as x in the table. The standard sample A
Is a washing method in which 15% of sodium polyoxyethylene lauryl ether sulfate (additional mole number: 3), 5% of N-lauroylglutamic acid triethanolamine and 5% of coconut oil fatty acid diethanolamide are added to water, and the pH is adjusted to 7 with citric acid. Agent composition.

Examples 1 to 5 and Comparative Examples 1 to 3 Table 1 shows the compositions of the cleaning compositions (test samples) of the present invention. The formulations shown here show the following: (1) Anionic surfactant containing a two-chain dipolar group to be blended A1: N, N'-bis (lauroylamide) ethane-
N, N'-di (sodium acetate) A2: N, N'-bis (lauroylamide) ethane-
N, N'-di (sodium propionate) (2) Single-chain / single-polar-group-containing anionic surfactant incorporated B1: Sodium laurate B2: Triethanolamine N-lauroylglutamate (3) Non-ionic incorporated Surfactant C1: Lauric acid diethanolamide C2: POE (10) dodecyl ether

[0012]

[Table 1]

From Table 1, it can be seen that when the hair was washed using the cleaning compositions of the examples, all of the above evaluation items were better than when the standard samples were used. Since the standard sample is a known representative model, it can be seen that the cleaning composition of the present invention is superior to the conventional product. On the other hand, it can be seen that the performance of the cleaning composition of the comparative example lacking any one of the components of the cleaning composition of the present invention is much worse than that of the cleaning composition of the present invention.

[0014]

As described above, it is apparent that the present invention provides a detergent composition which has good lathering, is excellent in foamy creaminess, and has good rinsing performance.

Claims (1)

[Claims] (1) a long-chain hydrophobic group having 18 or 1 carbon atoms;
6, 14, 12, 10 or 8, the polar group is a carboxyl group, a sulfate group, a sulfonic acid group, or a phosphate group, and the counter ion is a monovalent or divalent alkali metal ion, ammonium ion or organic ammonium Ion 2
One or more of the chain dipolar group-containing anionic surfactants, and (b) the polar group is a carboxyl group, a sulfate group, a sulfonic acid group, or a phosphate group, and the counter ion is monovalent or divalent. And (c) a higher fatty acid alkanolamide, which contains one or more anionic surfactants containing one chain and one polar group, which are alkali metal ions, ammonium ions or organic ammonium ions. ) + (B)] /
The cleaning composition according to (c), wherein the mixing weight ratio is 30: 1 to 3: 1.