JPH10168499A - Pasty nonionic detergent composition held in container - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a detergent compsn. held in a container which is excellent in solubility, can be applied only to esp. dirty parts of clothes, is compact requiring little space, and is a stable paste in a container, facilitating handling in the use, such as taking out of the container. SOLUTION: A pasty nonionic detergent compsn. contg. at least 10wt.% nonionic surfactant, if necessary water, at least 20wt.% cleaning builder, and 0.1-10wt.% viscosity modifier comprising a layer-structured clay minerale and polyethylene glycol or carboxymethylcellulose is held in a tubular or pump-type container. In the compsn., the sum of the surfactant and water is 30-80wt.%. and the wt. ratio of the surfactant to water is (100/0)-(80/20) or (40/60)-(15/85).

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a detergent composition in a container, and more particularly, it has excellent solubility, can be partially applied to particularly dirty portions of clothing, is compact in a small space, and The present invention relates to a container-containing detergent composition which forms a stable paste in a filled state and is easy to use such as taking out a detergent.

[0002]

2. Description of the Related Art Nonionic surfactants generally have a low foaming property, their detergency is hardly affected by the hardness of water, and they are particularly excellent in mud dirt and dispersibility at low temperatures. Furthermore, nonionic surfactants are excellent surfactants such as good biodegradability, low environmental load, low toxicity, and no problem in safety. In addition, when a clay mineral is blended with a detergent mainly composed of a nonionic surfactant, the exudation of the nonionic surfactant from a nonionic granular detergent product to a detergent container is prevented, and the fluidity under high temperature and high humidity is improved. Preferred for Therefore, detergents for clothing utilizing the characteristics of such nonionic surfactants are already known. By the way,
Clothes detergents are manufactured and sold as bead-shaped hollow particles having an average particle size of 200 to 800 µm by spray drying for the purpose of improving solubility. In other words, the bulk density is about 0.3 g / cc, and the volume per unit weight is large, so a large space is taken for transportation. As a result, the transportation cost increases, and the space for storage and display is increased. In addition, if a large amount is to be stored even at home, an undesired case arises, such as requiring a separate storage location.

[0003] For this reason, a paste-like detergent has been proposed as a detergent which requires less space, requires only a small space, and can be washed with a small amount of detergent (for example, JP-A-63-8496). Unlike the granular detergent, the detergent in the paste state does not require a drying step, which simplifies the process and contributes to energy saving. However, although the use of a paste improves the convenience, the solubility as a detergent cannot be said to be sufficient, and further improvement is required. In addition, when the paste-like nonionic detergent is used by filling it into, for example, an extruded tube-shaped container or a pump-extruded or suction-type container, the paste state can be stably maintained in the container. However, when used, a predetermined amount of the nonionic detergent paste cannot be weighed, and liquid dripping occurs from the mouth of the container.

[0004] Recently, granular detergents having a high bulk density have also become available on the market. This high bulk density granular agent is useful for saving space because the density is higher than conventional ones, but also because it is solid,
The solubility in water is greatly reduced as compared with the pasty nonionic detergent. For use in partial washing or the like, a liquid such as a paste-like nonionic detergent is suitable.

[0005]

SUMMARY OF THE INVENTION Accordingly, an object of the present invention is to provide a detergent composition in a container which is excellent in solubility and can form a stable paste when filled.

[0006]

Means for Solving the Problems The present inventors have conducted intensive studies in order to solve the above-mentioned problems, and as a result, when filled in an extruded tubular container or a pump extruded container, the nonionic surfactant is gelled. In a region not to be converted, by blending a specific viscosity modifier in a predetermined amount, it has been found that a detergent that is excellent in solubility and can be stably held in a paste state can be obtained, and has reached the present invention. is there.
That is, the present invention relates to (a) a nonionic surfactant, 10% by weight or more, (b) as required, water, (c) a washing builder, 20% by weight or more, and (d) a clay mineral having a layered structure. , A paste-like nonionic detergent composition containing 0.1 to 10% by weight of a viscosity modifier comprising polyethylene glycol or carboxymethyl cellulose, wherein the paste-like nonionic detergent composition is filled in a tubular container or a pump-type container. The total amount of the nonionic surfactant (a) and the water (b) is 30 to 80% by weight, and the weight ratio of the nonionic surfactant (a) / water (b) is 100/0.
To 80/20 or 40/60 to 15/85.

[0007]

BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in detail. As the nonionic surfactant used in the present invention, various nonionic surfactants can be used. Preferred nonionic surfactants include, for example, the following. (1) For example, an aliphatic alcohol having 6 to 22 carbon atoms, preferably 8 to 18 carbon atoms, and an alkylene oxide having 2 to 4 carbon atoms, for example, an average of 3 to 30 mol, preferably 7 to
20 moles of a polyoxyalkylene alkyl (or alkenyl) ether. Among them, polyoxyethylene alkyl (or alkenyl) ether and polyoxyethylene polyoxypropylene alkyl (or alkenyl) ether are preferable. As the aliphatic alcohol used here, a primary alcohol or a secondary alcohol is used. Further, the alkyl group may have a branched chain. As preferred aliphatic alcohols, primary alcohols are used. (2) polyoxyethylene alkyl (or alkenyl)
Phenyl ether. (3) A fatty acid alkyl ester alkoxylate represented by the following formula, in which an alkylene oxide is added between ester bonds of a long-chain fatty acid alkyl ester.

R ¹ CO (OA) _n OR ² (R ¹ CO represents a fatty acid residue having 6 to 22 carbon atoms, preferably 8 to 18 carbon atoms. OA represents 2 to 4 carbon atoms such as ethylene oxide and propylene oxide. Represents an addition unit of alkylene oxide, preferably 2 to 3. n represents an average number of added moles of alkylene oxide, and generally represents 3 to 3
0, preferably a number from 7 to 20. R ² has 1 carbon atom
Represents a lower alkyl group which may have 1 to 3 substituents. (4) Polyoxyethylene sorbitan fatty acid esters. (5) Polyoxyethylene sorbite fatty acid ester. (6) Polyoxyethylene fatty acid esters. (7) Polyoxyethylene hydrogenated castor oil. (8) Glycerin fatty acid ester. (9) fatty acid alkanolamides.

Among the above-mentioned nonionic surfactants, the melting point is 40 ° C. or less, preferably 5 to 35 ° C., and the HLB is 9 to 9 ° C.
16, preferably 10 to 15 polyoxyethylene alkyl (or alkenyl) ethers, polyoxyethylene polyoxypropylene alkyl (or alkenyl) ethers, and fatty acid methyl ester ethoxylates obtained by adding ethylene oxide to fatty acid methyl esters are particularly preferably used. . Further, these nonionic surfactants may be used as a mixture. The nonionic surfactant is at least 10% by weight, preferably at least 15% by weight, based on the weight of the pasty nonionic detergent. The upper limit is preferably 80% by weight, more preferably 60% by weight. When the amount of the nonionic surfactant is less than 10% by weight, the detergency decreases, which is not preferable.

Water is used in a range where the nonionic surfactant does not gel. Thus, water may or may not be used. For example, gelation tends to occur when the amount of the nonionic surfactant is in the range of 40 to 80% by weight based on the total amount of the nonionic surfactant and water. The total amount of the nonionic surfactant (a) and water (b) is based on the weight of the pasty nonionic detergent composition.
30 to 80% by weight, preferably 35 to 75% by weight, particularly preferably 40 to 70% by weight is suitable. If the total amount is less than 30% by weight, the viscosity becomes too high, and the dischargeability from the container is greatly reduced. On the other hand, when the total amount exceeds 80% by weight, liquid dripping from the mouth of the container occurs. The weight ratio of the nonionic surfactant (a) / water (b) is 100/0 to 80/20 or 40/60 to 15
/ 85, preferably 100/0 to 85/15 or 3
5 / 65-20 / 80, more preferably 100 / 0-9
0/10 or 30/70 to 20/80 is preferred. This ratio is less than 80/20 and 40/60
If it is larger than this, the viscosity becomes excessive and the dischargeability from the container decreases. On the other hand, when this ratio is smaller than 14/86, the cleaning power is significantly reduced.

The washing builder used in the present invention is not particularly limited as long as it has been conventionally used in the field of detergents, and various washing builders such as an alkali builder and a chelate builder can be used. Can be used. As the washing builder, an alkali builder is preferable. Specifically, for example, an alkali metal oxide, an alkali metal hydroxide, an alkali metal carbonate (for example, heavy sodium carbonate such as soda ash), an alkali Examples thereof include metal silicates, alkali metal sulfites (for example, sulfites, etc.), and mixtures thereof. Examples of the alkali metal include sodium and potassium. As the chelate builder, for example, alkali metal aluminosilicates such as zeolite, condensed phosphates such as sodium tripolyphosphate and sodium pyrophosphate, NTA, EDTA and the like are used.

[0012] The cleaning builder is 20 to 60% by weight, preferably 25% by weight, based on the weight of the pasty nonionic detergent.
It is used in an amount of .about.55% by weight, particularly preferably 30-50% by weight. If this amount is less than 20% by weight, the detergency is significantly reduced. On the other hand, if this amount exceeds 60% by weight, the viscosity becomes excessively high, and the dischargeability from the container is greatly reduced. The viscosity modifier used in the present invention comprises a clay mineral having a layered structure, polyethylene glycol or carboxymethyl cellulose. One important feature of the present invention is that by mixing such a specific viscosity modifier with the paste-like nonionic detergent composition, the paste-like nonionic detergent composition can be stably held in the container. It is. When such a viscosity modifier is not used, liquid dripping occurs or the paste state changes, so that phase separation easily occurs.

As the clay mineral having a layered structure, a clay mineral belonging to the smectite group and having a three-layered dioctahedral or trioctahedral crystal structure can be preferably used. Such a clay mineral has a cleavage property and has a layered structure. The clay mineral which can be preferably used in the present invention preferably has an oil absorption of less than 80 ml / 100 g, more preferably 30 to 7 g.
It is 0 ml / 100 g. Specific examples of such clay minerals include, for example, montmorillonite (oil absorption: 50 ml / 1) as a clay mineral having a dioctahedral type three-layer structure.
00g), nontronite (oil absorption: 40 ml / 100)
g), beidellite (oil absorption: 62 ml / 100 g),
Pyrophyllite (oil absorption: 70 ml / 100 g) and the like. As a clay mineral having a trioctahedral type three-layer structure, saponite (oil absorption: 73 ml / 100
g), hectorite (oil absorption: 72 ml / 100 g),
Stephensite (oil absorption: 30 ml / 100 g), talc (oil absorption: 70 ml / 100 g), and the like. These clay minerals generally include those naturally produced and those artificially hydrothermally synthesized, but are not particularly limited. Such clay minerals are 10-
As long as a peak derived from the spread of the clay layer detected at 20 ° and a peak derived from the three-layered structure of clay detected at 4 to 5 ° are developed, they can be used without particular limitation. In addition, clay minerals, particularly in the case of natural products, may contain many impurities such as quartz, cristobalite, calcite, opal, and feldspar, and those having many impurities are not suitable for the present invention and have at least a purity of at least. It is preferable to use 60%, more preferably 70% or more, and most preferably 100%. Particularly preferably used clay minerals include Na-type montmorillonite, Ca-type montmorillonite, activated bentonite (Na / Ca-type montmorillonite), Na-type hectorite, and Ca-type hectorite.

The polyethylene glycol (PEG) preferably has a molecular weight of 5,000 to 500,000, particularly preferably 10,000 to 200,000. Carboxymethyl cellulose (CMC) has a molecular weight of 10,0
Those having a molecular weight of from 00 to 500,000, particularly preferably from 100,000 to 300,000, are suitable. The viscosity modifier is used in an amount of 0.1 to 10% by weight, preferably 0.1% by weight, based on the weight of the pasty nonionic detergent.
Suitably, it is used in an amount of 3 to 8% by weight, particularly preferably 0.5 to 5% by weight. When this amount is less than 0.1% by weight, dripping of the liquid is liable to occur remarkably. On the other hand, if this amount is 10
If the amount exceeds 100% by weight, the viscosity becomes excessively high, so that the dischargeability from the container is significantly reduced. In the paste-like nonionic detergent composition of the present invention, as long as it does not particularly affect the paste properties of the detergent, any component usually blended in the detergent raw material can be used in combination without any particular limitation. .

[0015] Such components include, for example, the following components. (1) As anionic surfactants, linear alkylbenzene sulfonates, α-olefin sulfonates, alkyl sulfates, alkyl ether sulfates and the like. (2) As a fluorescent agent, for example, a bis (triazinylamino) stilbene disulfonic acid derivative, a bis (sulfostyryl) biphenyl salt [Tinopearl CBS-X], and the like. (3) Examples of enzymes include lipase, protease, cellulase, amylase and the like. (4) As a bleaching agent, for example, percarbonate, perborate and the like. (5) Examples of the bleaching activator include sodium dodecanoyloxybenzenesulfonate, decanoyloxybenzenecarboxylic acid, and the like. (6) As a bulking agent, for example, sodium sulfate, potassium sulfate, sodium chloride, potassium chloride and the like. (7) As a foam inhibitor, for example, silicone oil, silicone compound and the like. (8) Fragrances (9) Dyes The paste-like nonionic detergent composition used in the present invention comprises:
For example, it can be easily produced by mixing a nonionic surfactant, water (when used), a washing builder, a viscosity modifier and optional components, for example, in a vertical kneader. Mixing is usually performed at 20 to 80 ° C., preferably 3
It is suitable to carry out at 0 to 70 ° C, particularly preferably at 40 to 60 ° C.

The paste-like nonionic detergent composition used in the present invention is usually 5,000 to 20 ° C at 10 to 30 ° C.
It is appropriate to set the viscosity to 0,000 cps, preferably 7,000 to 150,000 cps, particularly preferably 10,000 to 100,000 cps. The paste-like nonionic detergent composition of the present invention is filled or accommodated in a tubular container or a pump-type container. The material of the tubular container may be made of plastic or metal. In addition, a single layer or a laminate type including a plurality of layers may be used. For example, a material made of polyolefin such as polyethylene or polypropylene can be formed. Further, a paper or metal layer may be laminated so that the components of the paste-like nonionic detergent composition do not permeate.

The shape of the tubular container is not particularly limited, and may be, for example, a cylindrical shape, and its cross section changes from cylindrical to flat continuously or stepwise from one end to the other end. You may do it. Further, the cross section may gradually increase or decrease from one end to the other end. The cap of the container may be a screw cap or a one-touch cap. An example of a preferred tubular container is shown in plan views in FIGS. As a pump type container, for example, Japanese Utility Model Application Laid-Open No. 54-34641,
Japanese Utility Model Application Laid-Open No. 56-37883, 56-46572
No., Shokai Sho 56-100378, Shokai Sho 56-121
677, 59-28078, JP-A-2-10590
No. 0, etc. can be used. A preferred example is shown in FIG. 3 as a cross-sectional view.

[0018]

The present invention will be described below in more detail with reference to Examples and Comparative Examples. However, in Examples and Comparative Examples, the obtained paste-like nonionic detergent compositions were evaluated by the following test methods. The extruded tubular container used in the test has the structure shown in FIG. 1 (material: composite material composed of low-density polyethylene / PET / ethylene-methacrylic acid copolymer / aluminum foil).

[Liquid dripping test] The tip of an extruded tubular container filled with the obtained paste-like nonionic detergent composition was brought into contact with a cloth to be cleaned, and the container was grasped to apply the contents to the cloth to be cleaned. Thereafter, the container was placed on a flat desk, and the state of liquid dripping of the contents from the mouth of the container was visually observed and evaluated according to the following evaluation criteria. ：: No content Δ: Little content (3 mm or less) ×: A large amount of content (5 mm or more) [Squeezing test] A cloth to be washed with the tip of a container filled with a paste-like nonionic detergent composition. , And the degree of squeezing of the tube when applying 15 g of the content to the cloth to be cleaned by grasping the tube was evaluated according to the following criteria. ○: The contents are released by squeezing lightly. △: The contents are released if a little force is applied. ×: The contents are not released unless a considerable amount of force is applied. [Detergency test] In a dirty bath of the artificial soil composition shown below. Clean cotton cloth (Cotton No.60, 5 × 5cm specified by Japan Oil Chemical Association)
After immersion, the water was squeezed with two rubber rolls to make the amount of adhered dirt uniform. After drying this soiled cloth at 105 ° C. for 30 minutes, the surface of the cloth was rubbed left and right 25 times. Of these, those with a reflectance of 42 ± 2% were used as dirty cloth. 60 pieces of the soiled cloth and 15 g of the sample detergent were put into a two-tub washing machine (CW-225 type, manufactured by Mitsubishi Electric Corp.), and the temperature of 30 ° C. and 30 ° C.
After washing with 10 liters of water (3 ° DH) for 10 minutes,
Dehydrated for 1 minute. Then, rinsing for 3 minutes with 30 liters of water at 15 ° C. and dehydration for 1 minute were repeated twice.
Then, after the cloth to be washed was air-dried indoors for 48 hours, the reflectance of this cloth to be washed was measured, and the cleaning rate was calculated by the following equation. Cleaning rate (%) = (K / S of dirty cloth−K / S of cleaning cloth) /
(K / S of soiled cloth-K / S of unsoiled cloth) × 100 K / S = (1−R / 100) ² / (2R / 100) (Formula of Kubelka-Munk) Soil composition (% ) Ratio (%) Oleic acid 28.3 Triolein 15.6 Cholesterol oleate 12.2 Liquid paraffin 2.5 Squalene 2.5 Cholesterol 2.5 Gelatin 7.0 Inorganic dirt 29.85 Carbon black (Nippon Oil Chemical Association) 0.5 [Solubility test] Tap water cooled to 5 ° C is gently stirred with a stirrer, 5 g of detergent is added thereto, and the mixture is stirred for 8 minutes. After drying the particles left over at 105 ° C. for 2 hours,
The weight of the undissolved particles was weighed, and the dissolution residue was calculated by the following equation. Dissolved residue (%) = ｛weight of undissolved particles (g) / 5
(G)｝ × 100 [Production Example of Nonionic Detergent Composition in Paste] In the table, nonionic surfactant, water, washing builder, viscosity modifier and optional components (enzyme, fragrance, fluorescent agent) are mixed with a vertical kneader. did.

[Raw Materials] The nonionic surfactants, cleaning builders and viscosity modifiers used in Examples and Comparative Examples are as follows. Nonionic surfactant (A) (1) A- 1 C 12-13 H 25-27 O (CH 2 CH 2 O) 7 H ( Shin Nippon Rika Co., Ltd. Konoru 20P (primary alcohols, carbon atoms 1
2, branching degree 0%) and Diadoll 13 manufactured by Mitsubishi Chemical Corporation
(Primary alcohol, 13 carbon atoms, degree of branching 50%) and an alcohol mixed at a weight ratio of 1: 4, polyoxyethylene alkyl ether obtained by adding 7 mol of ethylene oxide on average, manufactured by Lion Chemical Co., Ltd., trade name : NALG-8
3) (2) A-2 C 13 H 27 O (CH 2 CH 2 O) 7 (CH 3 CHCH 2) 3 H
(Polyoxyethylene polyoxypropylene alkyl ether obtained by adding an average of 7 mol of ethylene oxide and an average of 3 mol of propylene oxide to Diadol 13 (primary alcohol, carbon number 13, branching degree 50%) manufactured by Mitsubishi Chemical Corporation) Water (B) washing builder (C) (1) C-1 zeolite: crystalline sodium aluminosilicate (manufactured by Mizusawa Chemical Co., Ltd.) (2) C-2 sulfite: sodium sulfite (manufactured by Shinshu Chemical Co., Ltd.) (Anhydrous sodium sulfite) (3) C-3 soda ash: heavy sodium carbonate (produced by Asahi Glass Co., Ltd., granulated ash) viscosity modifier (D) (1) D-1 Ca montmorillonite (produced by Meiwa Sangyo Co., Ltd., BPW00)
9) (2) D-2 PEG: polyethylene glycol (manufactured by Junsei Chemical Co., Ltd.
(3) D-3 sodium carboxymethyl cellulose (Daicel Chemical Industries, Ltd., CMC 1380, molecular weight 250,000)

[0021]

Table 1 Example composition (% by weight) 1 2 3 4 5 6 7 8 Nonionic surfactant (A) A-1 55 46.8 22 22 19.3 16.5 13.8 A-2 49.5 22 Water (B) 5.5 8.2 11 33 35.7 38.5 41.2 A + B 55 55 55 55 55 55 55 55 A / B * 100 90 85 80 40 35 30 25 Cleaning builder (C) C-1 18 18 18 18 18 18 18 18 C-2 11 1 1 1 1 1 2 2 C-3 18 18 18 18 18 18 16 16 Viscosity modifier (D) D-13 21 D- 23 21 D-3 33 33 Fluorescent agent 0.2 0.2 0.2 0.2 0.2 0.3 0.4 0.4 Enzyme 1 1 1 1 1 1 2 2 Fragrance 0.5 0.4 0.3 0.3 0.2 0.2 0.1 0.1 Other minor ingredients Bla * Bla Bla Bla Bla Bla Bla Bla evaluation result Detergency (%) 88 88 88 88 86 85 83 82 Residual residue (%) 0 0 0 2 2 0 0 1 Liquid dripping ○ ○ ○ ○ ○ ○ ○ ○ Squeeze out ○ ○ ○ △ △ ○ ○ ○ Note) A / B * is the total of nonionic surfactant (A) and water (B) Percentage of nonionic surfactant based on volume. Bla * means the remaining amount.

[0022]

[Table 2] Table 1 (Continued) Example Comparative Example Composition (% by weight) 9 10 11 12 13 14 15 1 Nonionic surfactant (A) A-1 11 11.4 28.8 45 45 45 45 22.5 Water (B) 44 64.6 3.2 5 5 5 5 2.5 A + B 55 76 32 50 50 50 50 25 A / B * 20 15 90 90 90 90 90 90 Wash Builder (C) C-1 18 10 28 22 22 19 19 30 C-2 21 1 1 1 1 1 3 C-3 16 10 28 22 22 19 16 30 Viscosity modifier (D) D-1 0.2 0.46 9 D-25 5 D-3 31 Fluorescent agent 0.4 0.2 0.2 0.2 0.2 0.2 0.2 0.2 Enzyme 2 1 1 1 1 1 1 2 Fragrance 0.1 0.1 0.2 0.2 0.2 0.2 0.2 0.2 Other minor components Bla * Bla Bla Bla Bla Bla Bla Bla evaluation result Detergency (%) 81 80 86 88 88 88 87 85 Dissolution residue (%) 0 0 0 0 0 0 0 0 Liquid dripping ○ ○ ○ ○ ○ ○ ○ ○ Squeeze out ○ ○ △ ○ ○ ○ △ × Note) A / B * is the total of nonionic surfactant (A) and water (B) Percentage of nonionic surfactant based on volume. Bla * means the remaining amount.

[0023]

Table 3 (Continued) Comparative Example Composition (% by weight) 2 3 4 5 6 7 Nonionic surfactant (A) A-1 73.8 37.5 22.5 8 45 45 Water (B) 8.2 12.5 27.5 72 5 5 A + B 82 50 50 80 50 50 A / B * 90 75 45 10 90 90 Cleaning builder (C) C-18 22 22 8 17 22 C-2 11 1 11 C-3 8 20 20 8 17 22 Viscosity modifier ( D) D-1 3 3 D-2 0.612 D-3 1 Fluorescent agent 0.2 0.2 0.2 0.2 0.2 0.2 Enzyme 1 1 1 1 1 1 1 Fragrance 0.2 0.2 0.2 0.2 0.2 0.2 Other minor components Bla * Bla Bla Bla Bla Bla Evaluation results Detergency (%) 75 88 84 72 88 88 Dissolution residue (%) 0 20 22 0 0 0 Liquid dripping × ○ ○ △ ○ × Squeezing ○ ○ × × ○ × ○ Note) A / B * indicates nonionic surface activity Percentage of nonionic surfactant based on the total amount of agent (A) and water (B). Bla * means the remaining amount.

The following were used as optional components. Fluorescent agent: 2: 4,4'-bis (2-sulfostyryl) biphenyl disodium (Ciba Geigy, Tinopearl C
BS-X) Enzyme: A mixture of alkali protease granules and alkali lipase granules in a ratio of 7/2 (weight ratio) (manufactured by Novo Nordisk, a mixture of Savinase 12T / Lipolase EX = 7/2) The fragrance has the following composition. ing. Perfume composition parts by weight 3,7-dimethyl-1,6-octadien-3-ol 80 3,7-dimethyl-1,6-octadien-3-yl-acetate 60 3,7-dimethyl-6-octene-1- All 40 β-phenylethyl alcohol 50 p-tert-butyl-α-methylhydrocinnamic aldehyde 70 α-methyl-p-isopropylphenylpropionaldehyde 60 α-n-amylcinnamic aldehyde 20 α-n-hexyl cinnamic aldehyde 60 7-acetyl-1,1,3,4,4,6-80 hexamethyltetrahydronaphthalene 3- (5,5,6-trimethyl-norbarnan-20 2-yl) cyclohexane-1-ol Beltfix 30 2-ethyl -4- (2,2,3-trimethyl-3-10cyclo Ante-1-yl) -2-butan-1-ol 10% α, α-dimethyl-p-ethylhydrocinnamic aldehyde 40 2,4-dimethyl-3-cyclohexene-1- 10 carboxaldehyde cis-3-hexenol 10 2-trans-3,7-dimethyl-2,6-30 octadien-1-ol n-decylaldehyde 5 10-undecene-1-al 5 methylnonylacetaldehyde 5 4- (4-hydroxy-4-methylpentyl) -3- 30 cyclohexene-1-carboxaldehyde naphthalene-2-acetyl-1,2,3,4,6,7,830-octahydro2,3,8,8-tetramethyl 5- (2-methylene-6 , 6-Dimethyl-cyclohexyl) 50-4-penten-3-one 2-methoxy-4-prope Lephenol 20 Allylcyclohexanepropionate 10 6,7-dihydro-1,1,2,3,3-pentamethyl-54 (5H) -indanone p-propenylphenyl methyl ether 5 Methyl-2-aminobenzoate 5 Lemon oil Reference Signs List 30 orange oil 20 lavandin oil 20 patchouli oil 10 3,7-dimethyl-2,6-octadienal 30 methyldihydrojasmonate 50 Percentage of fragrance components having a boiling point of 230 ° C. (1 atm) in the total fragrances (66) wt%)

[0025]

According to the present invention, it has excellent solubility and can be partially applied to particularly dirty portions of clothing.
A nonionic detergent composition in a container can be obtained which is compact without taking up space, and forms a stable paste when filled, so that it is easy to use such as taking out a detergent.

[Brief description of the drawings]

FIG. 1 is a plan view showing one embodiment of a tubular container that can be used in the present invention.

FIG. 2 is a plan view showing another embodiment of the tubular container that can be used in the present invention.

FIG. 3 is a cross-sectional view showing one embodiment of a pump-type container that can be used in the present invention.

──────────────────────────────────────────────────の Continued on the front page (51) Int.Cl. ⁶ Identification code FI C11D 3/04 C11D 3/04 3/10 3/10 3/12 3/12 3/14 3/14 3/37 3/37 17/04 17/04 (72) Inventor Seiji Abe 1-3-7, Honjo, Sumida-ku, Tokyo Inside Lion Corporation

Claims (1)

[Claims] 1. A nonionic surfactant (10% by weight)
(B) water as required, (c) a washing builder, 20% by weight or more, and (d) a viscosity modifier comprising a clay mineral having a layered structure, polyethylene glycol or carboxymethyl cellulose, 0.1 to 10% by weight. % Of the nonionic surfactant (a) and the water (b), wherein the nonionic surfactant (a) and the water (b) are contained in a tube-like container or a pump-type container. The quantity is 30-8
0% by weight, and the weight ratio of the nonionic surfactant (a) / water (b) is 100/0 to 80/20 or 40/6.
A detergent composition in a container, which is from 0 to 15/85.