JPH10139981A - Epoxy resin composition for reinforcing car body, car body reinforcement structure, and method for reinforcing car body - Google Patents

Epoxy resin composition for reinforcing car body, car body reinforcement structure, and method for reinforcing car body

Info

Publication number
JPH10139981A
JPH10139981A JP31256696A JP31256696A JPH10139981A JP H10139981 A JPH10139981 A JP H10139981A JP 31256696 A JP31256696 A JP 31256696A JP 31256696 A JP31256696 A JP 31256696A JP H10139981 A JPH10139981 A JP H10139981A
Authority
JP
Japan
Prior art keywords
epoxy resin
reinforcing
weight
vehicle body
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP31256696A
Other languages
Japanese (ja)
Inventor
Takayuki Fukui
孝之 福井
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nissan Motor Co Ltd
Original Assignee
Nissan Motor Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nissan Motor Co Ltd filed Critical Nissan Motor Co Ltd
Priority to JP31256696A priority Critical patent/JPH10139981A/en
Publication of JPH10139981A publication Critical patent/JPH10139981A/en
Pending legal-status Critical Current

Links

Landscapes

  • Body Structure For Vehicles (AREA)
  • Laminated Bodies (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Epoxy Resins (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide an epoxy resin compsn. for reinforcing car bodies which can be foamed easily and uniformly in a box-shaped member to fill it and can surely increase the stiffness of a car body, and to provide a car body reinforcement structure, and a method for reinforcing car bodies using the same. SOLUTION: This compsn. comprises 100 pts.wt. epoxy resin derived from bisphenol A and/or bisphenol F, 1-40 pts.wt. arom. polyether, 3-30 pts.wt. thermally activated curative for epoxy resins, 0.5-20 pts.wt. thermally decomposable org. blowing agent, and 3-200 pts.wt. inorg. filler. This method for reinforcing a car body comprises arranging a sheet comprising the compsn. in the inside of a box-shaped member and foaming the sheet at the step of baking in the electrodeposition coating of a car body. This car body reinforcement structure is a box-shaped member filled with a foam of the compsn.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、新規な車体補強用
エポキシ樹脂系組成物に係り、更に詳しくは、芳香族ポ
リエーテルを強靱性と耐熱性を付加するための改質剤と
して配合して成り、予め成形された鋼板に装着し、該鋼
板を用いて箱型部材を組み上げた後、車体電着塗装時の
焼き付け工程で、発泡・充填して車体剛性を向上させる
ことができる車体補強用エポキシ樹脂組成物、車体補強
構造及び車体の補強方法に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a novel epoxy resin composition for reinforcing a vehicle body, and more particularly, to a method in which an aromatic polyether is blended as a modifier for imparting toughness and heat resistance. After mounting on a preformed steel plate, assembling a box-shaped member using the steel plate, baking and filling in the body electrodeposition coating, foaming and filling to improve body rigidity The present invention relates to an epoxy resin composition, a vehicle body reinforcing structure, and a vehicle body reinforcing method.

【0002】[0002]

【従来の技術】一般に、自動車の車体構造は、走行安定
性や乗り心地、騒音・振動性能の面から車体各部の骨格
が強固に作り上げられている。従来の車体構造は、箱型
の閉断面構造を多く採用しており、種々の断面形状に作
成されているが、化石燃料の枯渇や大気汚染を防止する
観点からの燃費向上という社会的要請により、車体重量
を軽減するために、いずれも板厚が薄い構造となってお
り、その分の剛性低下を補うため金属製の補強剤を用い
るのが一般的である。
2. Description of the Related Art In general, in a vehicle body structure, a skeleton of each part of the vehicle body is firmly formed in terms of running stability, riding comfort, noise and vibration performance. Conventional body structures often employ a box-shaped closed cross-section structure, and have various cross-sectional shapes.However, due to social demands to improve fuel efficiency from the viewpoint of preventing fossil fuel depletion and air pollution. In order to reduce the weight of the vehicle body, each of them has a thin plate structure, and a metal reinforcing agent is generally used to compensate for a decrease in rigidity.

【0003】また、一方では、該閉断面構造の内部に硬
質ウレタン発泡体を充填することにより、車体骨格を補
強する自動車の車体構造が特開昭48−2631号公報
に提案されている。発泡体の充填は、壁面座屈の抑制効
果が高く、箱型部材の剛性を著しく向上させるため、金
属製補強材による車体の補強方法と比較して、車体重量
を大幅には増大させることなく、剛性の向上が図れる。
On the other hand, Japanese Unexamined Patent Publication (Kokai) No. 48-2631 proposes a vehicle body structure in which a rigid urethane foam is filled in the closed section structure to reinforce the vehicle body skeleton. Filling the foam has a high effect of suppressing wall buckling and significantly improves the rigidity of the box-shaped member. And the rigidity can be improved.

【0004】なお、樹脂発泡タイプの充填材としては、
上記ウレタン系の他に、オレフィン系樹脂発泡充填材
(日本シーカ社製、シーカラストマー240)やエポキ
シ樹脂系発泡充填剤(イイダ産業製、OROTEX81
5)等があり、これらは車体塗装において発泡・充填し
て使用されるタイプである。
[0004] As the resin foam type filler,
In addition to the urethane-based resin, an olefin-based resin foam filler (Seakalastomer 240, manufactured by Nippon Sika Co., Ltd.) and an epoxy resin-based foam filler (ORIDEX81, manufactured by Iida Sangyo)
5) and the like, which are foamed and filled in vehicle body painting.

【0005】[0005]

【発明が解決しようとする課題】しかしながら、上述の
ウレタン樹脂による補強方法では、施工の際の箱型閉断
面部材へのウレタン原液注入・発泡時に、箱型部材の小
穴及び閉断面箱型部材の合わせ目からのウレタン材の漏
洩が少なからず発生するため、これを防止する手段を講
じなければならず、自動車の生産ラインへの適用は難し
いと考えられる。また、作業環境改善の観点から、近年
では、フロンを用いた発泡方法から水を用いた発泡方法
へと置き換わっているが、水発泡法では、フロン発泡法
に比べて発泡の均一性が達成しにくいという課題があ
る。
However, according to the above-mentioned reinforcing method using urethane resin, when the urethane stock solution is injected and foamed into the box-shaped closed-section member during construction, the small holes of the box-shaped member and the closed-section box-shaped member are removed. Since the leakage of the urethane material from the joints occurs to a considerable extent, it is necessary to take measures to prevent this, and it is considered that application to a production line of an automobile is difficult. In recent years, from the viewpoint of improving the working environment, in recent years, the foaming method using CFCs has been replaced with a foaming method using water.However, the water foaming method achieves more uniform foaming than the CFC foaming method. There is a problem that it is difficult.

【0006】一方、オレフィン系樹脂発泡材では、ベー
スとなるオレフィン樹脂に低分子量のポリエチレンワッ
クス等が用いられるため、材料の剛性が十分でなく、箱
型部材に充填した場合でも、箱型部材の剛性向上効果は
十分ではないという課題がある。
On the other hand, in the case of an olefin-based resin foam material, since low-molecular-weight polyethylene wax or the like is used as an olefin resin serving as a base, the rigidity of the material is not sufficient. There is a problem that the effect of improving the rigidity is not sufficient.

【0007】また、エポキシ樹脂系発泡材では、まず、
エポキシ樹脂の耐衝撃性が不十分であるという欠点を補
わなければならない。更に、車体への荷重の入力は静的
とは限らず、走行中に路面の凹凸により衝撃荷重が車体
に作用する場合もあり、車体補強材においても、このよ
うな衝撃荷重に耐え得るだけの耐衝撃性や靱性が要求さ
れる。
[0007] In the case of epoxy resin foam,
The disadvantage of the poor impact resistance of epoxy resins must be compensated for. Further, the load input to the vehicle body is not always static, and an impact load may be applied to the vehicle body due to uneven road surface during traveling. Impact resistance and toughness are required.

【0008】この耐衝撃性を改良する方法は、エポキシ
樹脂の化学構造自体を改良する方法と、別途調製した耐
衝撃性改良剤をエポキシ樹脂に添加する方法とに大別さ
れるが、前者の方法だけでは耐衝撃性を十分に満足させ
得るエポキシ樹脂は得られない。一方、後者の方法で
は、未硬化エポキシ樹脂に、(1)可溶性エラストマー
単量体を添加し、両者を同時に重合する方法、(2)相
溶性のあるエラストマー重合体を添加する方法、(3)
微粒子状の耐衝撃性改良用重合体を分散させる方法など
が知られている。
The method of improving the impact resistance is roughly classified into a method of improving the chemical structure itself of the epoxy resin and a method of adding a separately prepared impact modifier to the epoxy resin. An epoxy resin capable of sufficiently satisfying impact resistance cannot be obtained by the method alone. On the other hand, in the latter method, (1) a method of adding a soluble elastomer monomer to an uncured epoxy resin and simultaneously polymerizing the two, (2) a method of adding a compatible elastomer polymer, and (3)
A method of dispersing a fine particle-like polymer for improving impact resistance and the like are known.

【0009】上記(1)の方法は、相互貫通網目構造:
IPN(Inter−Penetorating Ne
twork)として知られているが、この方法では一般
に生成物の軟化点が低下するとともに機械的強度がばら
つく等の欠点を有している。
[0009] The method of the above (1) is characterized in that the interpenetrating network structure:
IPN (Inter-Penorating Ne)
However, this method generally has disadvantages such as a decrease in softening point of the product and a variation in mechanical strength.

【0010】また、(2)の方法については、カルボキ
シル基やアミノ基を末端に有するブタジエン−アクリロ
ニトリル(CTBN又はATBN)などのエラストマー
成分を添加してゴム変性する例が種々提案され、その一
部は実用化されているが、この方法で得られたものは、
車体剛性の補強に用いるには耐衝撃性や靱性の点で十分
に満足し得るものとはいえない。
Regarding the method (2), various examples have been proposed in which rubber is modified by adding an elastomer component such as butadiene-acrylonitrile (CTBN or ATBN) having a carboxyl group or an amino group at the terminal. Has been put into practical use, but the result obtained by this method is
It cannot be said that it is sufficiently satisfactory in terms of impact resistance and toughness for use in reinforcing vehicle body rigidity.

【0011】更に、(3)の方法では、ポリアミド系樹
脂をはじめとして多くの耐衝撃性改良剤が提案されてい
るが、これらはいずれも機械的に混練するものため、粒
子の分散に少なからず不均一性が残存し、機械的性能が
安定しにくいという欠点がある。
Furthermore, in the method (3), many impact modifiers such as polyamide resins have been proposed, but all of them are mechanically kneaded, so that not only a small amount of particles are dispersed in the particles. There is a disadvantage that non-uniformity remains and mechanical performance is hardly stabilized.

【0012】一般に、プラスチックの耐衝撃性改良剤と
してガラス転移温度が−30℃以下のゴム成分を添加す
ると、外部からの応力を緩和する働きをして耐衝撃性が
大幅に改良されることが知られているが、このようなゴ
ム成分の多くは、液状エポキシを母材とした場合、その
分散性が混合条件に影響され易く、且つ得られた組成物
は貯蔵性が不安定であり、長期の安定性が要求される自
動車生産用途には実用的でない。
In general, when a rubber component having a glass transition temperature of -30 ° C. or less is added as an impact resistance improving agent for plastics, the effect of relieving external stress is exerted and the impact resistance is greatly improved. Although it is known, many of such rubber components, when a liquid epoxy is used as a base material, the dispersibility thereof is easily affected by mixing conditions, and the obtained composition has an unstable storage property, It is not practical for automotive production applications where long-term stability is required.

【0013】また、発泡温度域で樹脂の粘度が急激に低
下すると、発泡剤から発生したガスを樹脂中に保持する
ことが困難となり、発泡して発泡体を形成することが困
難となる。発泡体中に発泡セルが安定して存在するため
には、発泡温度域における樹脂粘度の温度依存性を制御
しなければならない。このためには、エポキシ樹脂と相
溶性の高いエラストマー等を添加して、粘度の温度依存
性を制御するか、又は物理的架橋により粘度の温度依存
性を制御する必要がある。
Further, when the viscosity of the resin sharply decreases in the foaming temperature range, it becomes difficult to retain the gas generated from the foaming agent in the resin, and it becomes difficult to foam to form a foam. In order for foam cells to be stably present in the foam, the temperature dependence of the resin viscosity in the foaming temperature range must be controlled. To this end, it is necessary to control the temperature dependence of the viscosity by adding an elastomer or the like having high compatibility with the epoxy resin, or to control the temperature dependence of the viscosity by physical crosslinking.

【0014】しかし、エラストマーの添加による粘度の
制御方法では、エポキシ組成物が本来有する剛性が低下
してしまうという欠点があり、また、化学反応を伴う架
橋により粘度の制御を行う場合、架橋密度が反応条件に
左右され、厳密に制御ができないため、粘度が高すぎて
発泡が不十分となり、上述の箱型部材中に十分には充填
されない可能性がある。
However, the method of controlling the viscosity by adding the elastomer has the disadvantage that the rigidity inherent in the epoxy composition is reduced, and when the viscosity is controlled by crosslinking involving a chemical reaction, the crosslinking density is reduced. Since it cannot be strictly controlled depending on the reaction conditions, the viscosity is too high and the foaming becomes insufficient, so that the above-mentioned box-shaped member may not be sufficiently filled.

【0015】本発明は、このような従来技術の有する課
題に鑑みてなされたものであり、その目的とするところ
は、箱型部材中に簡易且つ均一に発泡・充填することが
でき、自動車車体の剛性を確実に向上させることのでき
る車体補強用エポキシ樹脂系組成物、車体補強構造及び
車体の補強方法を提供することにある。
The present invention has been made in view of the above-mentioned problems of the prior art, and an object of the present invention is to easily and uniformly foam and fill a box-shaped member. It is an object of the present invention to provide an epoxy resin composition for reinforcing a vehicle body, a vehicle body reinforcing structure, and a vehicle body reinforcing method capable of reliably improving the rigidity of the vehicle body.

【0016】[0016]

【課題を解決するための手段】本発明者は、上記課題を
解決すべく鋭意検討を行った結果、ある種の芳香族ポリ
エーテルをエポキシ樹脂と混合することにより、耐衝撃
性を備えたエポキシ樹脂系組成物が得られ、また、これ
をシート化した後、予め形成された鋼板に装着、該鋼板
を用いて箱型部材を組み上げた後、車体電着塗装時の焼
き付け工程で発泡・充填することにより、軽量化を図り
つつ車体骨格を補強し得ることを見出し、本発明を完成
するに至った。
The present inventors have made intensive studies to solve the above-mentioned problems, and as a result, by mixing a certain aromatic polyether with an epoxy resin, an epoxy resin having impact resistance has been obtained. A resin-based composition is obtained, and after forming this into a sheet, it is mounted on a pre-formed steel sheet, and after assembling a box-shaped member using the steel sheet, foaming and filling in a baking step at the time of body electrodeposition coating. As a result, the inventors have found that the vehicle body skeleton can be reinforced while reducing the weight, and the present invention has been completed.

【0017】即ち、本発明の車体補強用エポキシ樹脂系
組成物は、(A)ビスフェノールA及び/又はビスフェ
ノールFから誘導されたエポキシ樹脂100重量部に対
して、(B)芳香族ポリエーテル1〜40重量部、
(C)エポキシ樹脂用熱活性型硬化剤3〜30重量部、
(D)熱分解型有機系発泡剤0.5〜20重量部、及び
(E)無機系充填剤3〜200重量部を含有して成るこ
とを特徴とする。
That is, the epoxy resin composition for reinforcing a vehicle body according to the present invention comprises: (A) 100 parts by weight of an epoxy resin derived from bisphenol A and / or bisphenol F; 40 parts by weight,
(C) 3 to 30 parts by weight of a thermally activated curing agent for epoxy resin,
(D) 0.5 to 20 parts by weight of a thermal decomposition type organic foaming agent and (E) 3 to 200 parts by weight of an inorganic filler.

【0018】また、本発明の車体補強構造は、箱型部材
の内部に、上記エポキシ樹脂系組成物から得られる発泡
体を充填して成ることを特徴とする。
The vehicle body reinforcing structure of the present invention is characterized in that a box-shaped member is filled with a foam obtained from the epoxy resin composition.

【0019】更に、本発明の車体の補強方法は、鋼板か
ら構成された箱型部材を備える車体を補強するに当た
り、上記箱型部材の内部に相当する上記鋼板の部分に、
上記車体補強用エポキシ樹脂系組成物から成るシートを
配置し、次いで、上記鋼板を組み付けて上記箱型部材を
組み上げ、しかる後、組み上げた箱型部材を電着塗装処
理に供し、この処理の焼き付け工程で上記シートを発泡
させることを特徴とする。
Further, according to the method for reinforcing a vehicle body of the present invention, when reinforcing a vehicle body provided with a box-shaped member made of a steel plate, a portion of the steel plate corresponding to the inside of the box-shaped member is
A sheet made of the epoxy resin composition for reinforcing the vehicle body is arranged, and then the steel plate is assembled to assemble the box-shaped member. Thereafter, the assembled box-shaped member is subjected to an electrodeposition coating process, and baking of this process is performed. The method is characterized in that the sheet is foamed in the step.

【0020】[0020]

【発明の実施の形態】以下、本発明を詳細に説明する。
上述の如く、本発明のエポキシ樹脂系組成物は、(A)
ビスフェノールA及び/又はビスフェノールFから誘導
されたエポキシ樹脂と、(B)芳香族ポリエーテルと、
(C)エポキシ樹脂用熱活性型硬化剤と、(D)熱分解
型有機系発泡剤と、(E)無機系充填剤とを含有する。
BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in detail.
As described above, the epoxy resin composition of the present invention comprises (A)
An epoxy resin derived from bisphenol A and / or bisphenol F, (B) an aromatic polyether,
It contains (C) a thermally activated curing agent for epoxy resin, (D) a thermally decomposable organic foaming agent, and (E) an inorganic filler.

【0021】ここで、上記(A)成分として用いられる
ビスフェノールAから誘導されるエポキシ樹脂の例とし
ては、次の一般式[1]
Here, as an example of the epoxy resin derived from bisphenol A used as the component (A), the following general formula [1]

【0022】[0022]

【化1】 Embedded image

【0023】(式中のnは、0以上の数を示す。)で表
されるものを挙げることができる。また、ビスフェノー
ルFから誘導されるエポキシ樹脂の例としては、次の一
般式[2]
(Wherein n is a number equal to or greater than 0). Examples of the epoxy resin derived from bisphenol F include the following general formula [2]

【0024】[0024]

【化2】 Embedded image

【0025】(式中のnは、0以上の数を示す。)で表
されるものを挙げることができる。なお、上記一般式
[1]及び[2]におけるnが平均値として1未満で表
されるエポキシ樹脂は、常温で液状であり好適に使用す
ることができる。
(In the formula, n represents a number of 0 or more.) The epoxy resin represented by the general formulas [1] and [2] in which n is less than 1 as an average value is liquid at room temperature and can be suitably used.

【0026】本発明においては、上記一般式[1]及び
[2]で表されるエポキシ樹脂を混合して用いることが
でき、これ以外にも、一般式[1]又は[2]における
ビスフェノール連鎖部分としてビスフェノールA単位と
ビスフェノールF単位とが混合した連鎖のものも好適に
使用することができる。
In the present invention, the epoxy resins represented by the above general formulas [1] and [2] can be used as a mixture. In addition, the bisphenol chain represented by the general formula [1] or [2] can be used. As a part, a chain in which a bisphenol A unit and a bisphenol F unit are mixed can also be suitably used.

【0027】次に、上記(B)成分として用いられる芳
香族ポリエーテルとしては、特にポリエーテルスルフォ
ン、ポリエーテルイミドが望ましい。これらは、上記
(A)成分で記載したビスフェノールA及びF型のエポ
キシ樹脂に対して相溶性が良好であり、例えば塩化メチ
レン等の極性溶媒により均一な組成物を得ることが可能
である。また、かかるポリエーテルは、その主鎖骨格に
ベンゼン環を有するため極めて耐熱性が高く、これによ
り、得られる組成物の耐熱性能を著しく向上させること
が可能である。
Next, as the aromatic polyether used as the component (B), polyether sulfone and polyetherimide are particularly desirable. These have good compatibility with the bisphenol A and F type epoxy resins described in the above-mentioned component (A), and can obtain a uniform composition with a polar solvent such as methylene chloride. Further, such a polyether has a benzene ring in its main chain skeleton, and thus has extremely high heat resistance, whereby the heat resistance of the obtained composition can be significantly improved.

【0028】この(B)成分として用いられる芳香族ポ
リエーテルの配合量は、特に限定されるものではない
が、通常(A)成分のエポキシ樹脂100重量部に対し
て1〜40重量部である。1重量部未満では、十分な耐
衝撃性や耐熱性能が得られず、40重量部を超えると、
未硬化物の粘度が著しく増加して鋼板部材への接着が困
難になるとともに、発泡倍率を高くすることが困難とな
る。
The amount of the aromatic polyether used as the component (B) is not particularly limited, but is usually 1 to 40 parts by weight based on 100 parts by weight of the epoxy resin (A). . If it is less than 1 part by weight, sufficient impact resistance and heat resistance cannot be obtained, and if it exceeds 40 parts by weight,
The viscosity of the uncured product increases remarkably, making it difficult to adhere to the steel plate member and making it difficult to increase the expansion ratio.

【0029】また、上記(C)成分として用いられるエ
ポキシ樹脂用熱活性型硬化剤としては、例えば、ジシア
ンジアミド、4,4’−ジアミノジフェニルスルホン、
2−n−ヘプタデシルイミダゾールのようなイミダゾー
ル誘導体、イソフタル酸ジヒドラジド、N,N’−ジア
ルキル尿素誘導体、N,N’−ジアルキルチオ尿素誘導
体、テトラヒドロ無水フタル酸のような酸無水物、イソ
ホロンジアミン、m−フェニレンジアミン、N−アミノ
エチルピペラジン、メラミン、グアナミン、三フッ化ホ
ウ素錯化合物、トリスジメチルアミノメチルフェノール
等が挙げられ、これらは1種単独で又は2種以上を任意
に組み合わせて用いることができる。
Examples of the heat-active curing agent for epoxy resin used as the component (C) include dicyandiamide, 4,4'-diaminodiphenylsulfone,
Imidazole derivatives such as 2-n-heptadecyl imidazole, isophthalic dihydrazide, N, N′-dialkyl urea derivatives, N, N′-dialkyl thiourea derivatives, acid anhydrides such as tetrahydrophthalic anhydride, isophorone diamine; m-phenylenediamine, N-aminoethylpiperazine, melamine, guanamine, boron trifluoride complex compound, trisdimethylaminomethylphenol, etc., and these may be used alone or in any combination of two or more. it can.

【0030】なお、これら硬化材の中では、ジシアンジ
アミドを特に好適に用いることができる。この場合、十
分な発泡を行うには、電着塗装の焼き付け温度を140
〜210℃の範囲とすることが望ましく、焼き付け時間
は10〜30分の範囲とするのが好適である。
Among these curing materials, dicyandiamide can be particularly preferably used. In this case, in order to perform sufficient foaming, the baking temperature of the electrodeposition coating is set to 140.
The baking time is preferably in the range of 10 to 30 minutes.

【0031】この(C)成分の熱活性型硬化剤の配合量
は、特に限定されるものではないが、通常(A)成分の
エポキシ樹脂100重量部に対して3〜30重量部であ
る。3重量部未満では、十分に硬化せず剛性が著しく低
下する原因となり、また、30重量部を超えると、硬化
時に過剰な発熱反応を伴い部分的な分解や熱劣化を引き
起こし、組成物の機械的強度を著しく損なう原因とな
る。
The amount of the heat-active type curing agent (C) is not particularly limited, but is usually 3 to 30 parts by weight based on 100 parts by weight of the epoxy resin (A). If the amount is less than 3 parts by weight, the composition is not sufficiently cured and the rigidity is remarkably reduced. If the amount is more than 30 parts by weight, an excessive exothermic reaction occurs during the curing, causing partial decomposition and thermal deterioration. It may cause significant deterioration of the target strength.

【0032】次に、上記(D)成分として用いられる有
機系発泡剤としては、例えばアゾジカルボンアミド、ア
ゾビスイソブチロニトリルのようなアゾ化合物、ジニト
ロソペンタメチレンテトラミンのようなニトロソ化合
物、p−トルエンスルホニルヒドラジド、4,4’−オ
キシベンゼンスルホニルヒドラジドのようなスルホヒド
ラジド化合物が挙げられ、これらは1種単独で又は2種
以上を任意に組み合わせて用いることができる。また、
これらの中では、アゾジカルボンアミドを特に好ましく
使用することができる。
Next, examples of the organic blowing agent used as the component (D) include azo compounds such as azodicarbonamide and azobisisobutyronitrile; nitroso compounds such as dinitrosopentamethylenetetramine; -Sulfohydrazide compounds such as -toluenesulfonylhydrazide and 4,4'-oxybenzenesulfonylhydrazide, and these can be used alone or in any combination of two or more. Also,
Among them, azodicarbonamide can be particularly preferably used.

【0033】なお、有機系熱分解型発泡剤を用いる場合
には、通常、発泡適正温度制御するために、発泡助剤と
して、亜鉛華、硝酸亜鉛、フタル酸鉛、炭酸鉛、三塩基
性リン酸鉛、三塩基性硫酸鉛等の無機塩、亜鉛脂肪酸石
鹸、鉛脂肪酸石鹸、カドミウム脂肪酸石鹸等の金属石
鹸、ホウ酸、シュウ酸、コハク酸、アジピン酸等の酸
類、尿素、ビウレア、エタノールアミン、グリコール、
グリセリン等のうちから1種以上のものを混合して使用
することができる。
When an organic pyrolysis type foaming agent is used, zinc white, zinc nitrate, lead phthalate, lead carbonate, and tribasic phosphorus are usually used as foaming aids in order to control an appropriate foaming temperature. Inorganic salts such as lead acid, tribasic lead sulfate, etc., metal soaps such as zinc fatty acid soap, lead fatty acid soap, cadmium fatty acid soap, acids such as boric acid, oxalic acid, succinic acid, adipic acid, urea, biurea, ethanolamine , Glycol,
One or more of glycerin and the like can be mixed and used.

【0034】この(D)成分の有機系発泡剤の配合量
は、特に限定されるものではないが、通常(A)成分の
エポキシ樹脂100重量部に対して0.5〜20重量部
の範囲が好適である。この量が0.5重量部未満では、
発泡が不十分となり、20重量部を超えると、発泡の制
御が十分ではなくなり、安定した機械特性が得られな
い。
The amount of the organic foaming agent (D) is not particularly limited, but is usually in the range of 0.5 to 20 parts by weight per 100 parts by weight of the epoxy resin (A). Is preferred. If this amount is less than 0.5 parts by weight,
If the foaming becomes insufficient, and if it exceeds 20 parts by weight, the control of the foaming becomes insufficient, and stable mechanical properties cannot be obtained.

【0035】また、上記(E)成分として用いられる無
機系充填剤としては、例えば炭酸カルシウム、タルク、
クレー、マイカ、水酸化アルミニウム、ガラスビーズ、
シラスバルーンなどが挙げられ、これらは1種単独で又
は2種以上を任意に組み合わせて用いることができる。
また、これらの中では、炭酸カルシウムを特に好適に用
いることができる。
The inorganic filler used as the component (E) includes, for example, calcium carbonate, talc,
Clay, mica, aluminum hydroxide, glass beads,
Shirasu balloons and the like can be mentioned, and these can be used alone or in any combination of two or more.
Among them, calcium carbonate can be particularly preferably used.

【0036】この(E)成分として用いられる無機系充
填剤の配合量は、特に限定されるものではないが、通常
(A)成分のエポキシ樹脂100重量部に対して3〜3
00重量部である。3重量部未満では、十分に補強効果
が得られず、200重量部を超えると、粘度が著しく増
加して塗布や接着が困難になるとともに、組成物が脆く
なり機械的強度を著しく損なう原因となる。
The amount of the inorganic filler used as the component (E) is not particularly limited, but is usually 3 to 3 based on 100 parts by weight of the epoxy resin (A).
00 parts by weight. If the amount is less than 3 parts by weight, a sufficient reinforcing effect cannot be obtained. If the amount exceeds 200 parts by weight, the viscosity is remarkably increased to make application and adhesion difficult, and the composition becomes brittle and the mechanical strength is significantly impaired. Become.

【0037】次に、本発明のエポキシ樹脂系組成物の製
造方法について説明する。このエポキシ樹脂組成物は、
(A)成分のエポキシ樹脂に、(B)成分の芳香族ポリ
エーテル、(C)成分の熱活性型硬化剤、(D)成分の
有機系発泡剤、(E)成分の無機系充填剤、及び所要に
応じて用いられる添加成分を配合し、均一に混合するこ
とにより、調製することができる。
Next, a method for producing the epoxy resin composition of the present invention will be described. This epoxy resin composition,
Component (A) is an epoxy resin, component (B) is an aromatic polyether, component (C) is a thermally activated curing agent, component (D) is an organic foaming agent, component (E) is an inorganic filler, It can be prepared by blending the additive components used as required and mixing them uniformly.

【0038】上記添加成分としては、例えば可塑剤、希
釈剤、安定剤、乳化剤、強化剤、着色剤、酸化防止剤、
紫外線吸収剤、滑剤、チクソ性付与剤、硬化促進剤なと
が挙げられる。
The above-mentioned additional components include, for example, plasticizers, diluents, stabilizers, emulsifiers, reinforcing agents, coloring agents, antioxidants,
UV absorbers, lubricants, thixotropic agents, and curing accelerators.

【0039】次に、本発明の車体の補強方法について説
明する。この補強方法は、上述した本発明のエポキシ樹
脂系組成物を箱型部材の内部で発泡・充填することを骨
子とするものであり、代表的には、以下のような工程か
ら成る。
Next, a method of reinforcing a vehicle body according to the present invention will be described. This reinforcing method is based on the fact that the above-described epoxy resin composition of the present invention is foamed and filled inside a box-shaped member, and typically includes the following steps.

【0040】即ち、上記エポキシ樹脂系組成物をシート
化し、得られた組成物シートを、箱型部材を構成する予
め形成された鋼板に貼着する。この際、組成物シート
は、鋼板の部分のうち、箱型部材の内部に相当する箇所
に貼着することを要する。次に、組成物シートを貼着し
た鋼板を用いて箱型部材を組み上げ、自動車車体を形成
する。そして、このような箱型部材を備えた自動車車体
を電着塗装処理するが、貼着された組成物シートは、こ
の処理における焼き付け工程で加熱されて発泡し、形成
される発泡体が箱型部材内部に均一に充填され、車体の
補強が完了する。
That is, the above-mentioned epoxy resin composition is formed into a sheet, and the obtained composition sheet is adhered to a pre-formed steel sheet constituting a box-shaped member. In this case, the composition sheet needs to be adhered to a portion corresponding to the inside of the box-shaped member in the portion of the steel plate. Next, a box-shaped member is assembled using the steel sheet to which the composition sheet is adhered to form an automobile body. Then, an automobile body provided with such a box-shaped member is subjected to an electrodeposition coating process, and the adhered composition sheet is heated and foamed in the baking step in this process, and the formed foam is a box-shaped body. The inside of the member is uniformly filled, and the reinforcement of the vehicle body is completed.

【0041】上述のように、本発明の補強方法では、組
成物シートが固体状であるため、ウレタン樹脂系の発泡
とは異なり、原液が漏洩することがなく、ハンドリング
性が極めて良好である。また、上述の工程において、所
要に応じて、箱型部材を組み上げた後に、その内部に組
成物シートを貼着してもよいのは勿論のことである。な
お、上述の焼き付け工程は、組成物シートの発泡を十分
に行うためには、140〜210℃で10〜30分間加
熱することにより行うのが好ましい。
As described above, in the reinforcing method of the present invention, since the composition sheet is solid, unlike the urethane resin foaming, the stock solution does not leak and the handling property is extremely good. In addition, in the above-described steps, it is a matter of course that, after assembling the box-shaped member, the composition sheet may be adhered inside the box-shaped member. The above-mentioned baking step is preferably performed by heating at 140 to 210 ° C. for 10 to 30 minutes in order to sufficiently foam the composition sheet.

【0042】[0042]

【実施例】以下、本発明を実施例及び比較例により更に
詳細に説明するが、本発明はこれら実施例に限定される
ものではない。なお、各例で得られたエポキシ樹脂組成
物の物性については、次に示す方法により評価した。
EXAMPLES Hereinafter, the present invention will be described in more detail with reference to Examples and Comparative Examples, but the present invention is not limited to these Examples. The physical properties of the epoxy resin compositions obtained in each example were evaluated by the following methods.

【0043】(1)静的試験 図1に示すような50×60×400mmの断面を持つ
箱型断面部材20の中央部100mmに対し、各例のエ
ポキシ樹脂組成物を発泡させて得られる発泡材10を充
填して曲げ試験を行い、該エポキシ樹脂組成物を未充填
の場合の箱型断面部材と比較し、曲げ剛性を次の判定基
準に従って評価した。なお、発泡材の充填条件は、17
0℃で20分間の焼き付けとした。
(1) Static test A foam obtained by foaming the epoxy resin composition of each example with respect to a central portion 100 mm of a box-shaped section member 20 having a cross section of 50 × 60 × 400 mm as shown in FIG. The material 10 was filled and subjected to a bending test. The epoxy resin composition was compared with a box-shaped cross-section member when not filled, and the bending rigidity was evaluated according to the following criteria. The filling condition of the foam material is 17
Baking was performed at 0 ° C. for 20 minutes.

【0044】 ○:同重量の未充填部材に比べて剛性が上回るもの △:同重量の未充填部材に比べて剛性が同等のもの ×:同重量の未充填部材に比べて剛性が下回るもの○: Rigidity higher than unfilled member of the same weight Δ: Rigidity equivalent to unfilled member of the same weight ×: Rigidity lower than unfilled member of the same weight

【0045】(2)衝撃試験 図1に示した箱型断面部材20を用いて、重量7kgの
重りを25km/時の速度で落下させて曲げ衝撃試験を
行い、各例のエポキシ樹脂組成物を充填・未充填の場合
で比較し、エネルギ吸収量を次の判定基準に従って評価
した。なお、発泡材の充填条件は上記静的試験と同じで
ある。
(2) Impact Test Using the box-shaped section member 20 shown in FIG. 1, a 7 kg weight was dropped at a speed of 25 km / h to conduct a bending impact test, and the epoxy resin composition of each example was used. The comparison was made between the filled and unfilled cases, and the energy absorption was evaluated according to the following criteria. The filling condition of the foam material is the same as the static test.

【0046】 ○:同重量の未充填部材に比べて剛性が上回るもの △:同重量の未充填部材に比べて剛性が同等のもの ×:同重量の未充填部材に比べて剛性が下回るもの:: Rigidity higher than unfilled member of the same weight △: Rigidity equivalent to unfilled member of the same weight ×: Rigidity lower than unfilled member of the same weight

【0047】(実施例1)液状ビスフェノールA型エポ
キシ樹脂100重量部とポリエーテルスルフォン2重量
部を塩化メチレン200mlに溶解し、攪拌しながら真
空乾燥を行い、ペースト状物を得た。次いで、このペー
スト状物に、硬化剤ジシアンジアミド6重量部と、有機
系発泡剤アゾジカルボンアミド5重量部と、無機充填剤
炭酸カルシウム100重量部とを、プラネタリーミキサ
ーを用いて室温で混合し、エポキシ樹脂組成物を調製し
た。評価結果を表1に示す。
Example 1 100 parts by weight of a liquid bisphenol A type epoxy resin and 2 parts by weight of polyethersulfone were dissolved in 200 ml of methylene chloride and vacuum-dried with stirring to obtain a paste. Next, 6 parts by weight of a curing agent dicyandiamide, 5 parts by weight of an organic blowing agent azodicarbonamide, and 100 parts by weight of an inorganic filler calcium carbonate were mixed with the paste at room temperature using a planetary mixer. An epoxy resin composition was prepared. Table 1 shows the evaluation results.

【0048】(実施例2)ポリエーテルスルフォンの配
合量を30重量部とした以外は、実施例1と同様の操作
を繰り返し、エポキシ樹脂組成物を得た。評価結果を表
1に示す。
Example 2 An epoxy resin composition was obtained by repeating the same operation as in Example 1 except that the blending amount of polyethersulfone was changed to 30 parts by weight. Table 1 shows the evaluation results.

【0049】(比較例1)ポリエーテルスルフォンの配
合量を0.5重量部とした以外は、実施例1と同様の操
作を繰り返し、エポキシ樹脂組成物を得た。評価結果を
表1に示す。
Comparative Example 1 An epoxy resin composition was obtained by repeating the same operation as in Example 1 except that the amount of the polyether sulfone was changed to 0.5 part by weight. Table 1 shows the evaluation results.

【0050】(比較例2)ポリエーテルスルフォンの配
合量を50重量部とした以外は、実施例1と同様の操作
を繰り返し、エポキシ樹脂組成物を調製した。しかし、
得られた組成物の粘度が高すぎて十分に発泡させること
ができなかった。
Comparative Example 2 An epoxy resin composition was prepared by repeating the same operation as in Example 1 except that the blending amount of polyethersulfone was changed to 50 parts by weight. But,
The viscosity of the obtained composition was too high to foam sufficiently.

【0051】(実施例3)ポリエーテルスルフォンの配
合量を10重量部とし、硬化剤ジシアンジアミドの配合
量を3重量部とした以外は、実施例1と同様の操作を繰
り返し、エポキシ樹脂組成物を得た。評価結果を表1に
示す。
Example 3 The same operation as in Example 1 was repeated except that the blending amount of the polyether sulfone was changed to 10 parts by weight and the blending amount of the curing agent dicyandiamide was changed to 3 parts by weight. Obtained. Table 1 shows the evaluation results.

【0052】(実施例4)ポリエーテルスルフォンの配
合量を10重量部とし、硬化剤ジシアンジアミドの配合
量を30重量部とした以外は、実施例1と同様の操作を
繰り返し、エポキシ樹脂組成物を得た。評価結果を表1
に示す。
Example 4 The same operation as in Example 1 was repeated except that the blending amount of polyether sulfone was changed to 10 parts by weight and the blending amount of the curing agent dicyandiamide was changed to 30 parts by weight. Obtained. Table 1 shows the evaluation results.
Shown in

【0053】(比較例3)ポリエーテルスルフォンの配
合量を10重量部とし、硬化剤ジシアンジアミドの配合
量を1重量部とした以外は、実施例1と同様の操作を繰
り返し、エポキシ樹脂組成物を得た。評価結果を表1に
示す。
Comparative Example 3 The same procedure as in Example 1 was repeated except that the blending amount of polyethersulfone was changed to 10 parts by weight and the blending amount of the curing agent dicyandiamide was changed to 1 part by weight. Obtained. Table 1 shows the evaluation results.

【0054】(比較例4)ポリエーテルスルフォンの配
合量を10重量部とし、硬化剤ジシアンジアミドの配合
量を40重量部とした以外は、実施例1と同様の操作を
繰り返し、エポキシ樹脂組成物を得た。評価結果を表1
に示す。
Comparative Example 4 The same operation as in Example 1 was repeated except that the blending amount of polyether sulfone was changed to 10 parts by weight, and the blending amount of the curing agent dicyandiamide was changed to 40 parts by weight. Obtained. Table 1 shows the evaluation results.
Shown in

【0055】(実施例5)有機系発泡剤アゾジカルボン
アミドの配合量を1重量部とした以外は、実施例1と同
様の操作を繰り返し、エポキシ樹脂組成物を得た。評価
結果を表1に示す。
Example 5 An epoxy resin composition was obtained by repeating the same operation as in Example 1 except that the amount of the organic blowing agent azodicarbonamide was changed to 1 part by weight. Table 1 shows the evaluation results.

【0056】(比較例5)ポリエーテルスルフォンの配
合量を10重量部とし、有機系発泡剤アゾジカルボンア
ミドの配合量を0.1重量部とした以外は、実施例1と
同様の操作を繰り返し、エポキシ樹脂組成物を得た。評
価結果を表1に示す。
Comparative Example 5 The same operation as in Example 1 was repeated except that the blending amount of the polyether sulfone was changed to 10 parts by weight and the blending amount of the organic blowing agent azodicarbonamide was changed to 0.1 parts by weight. Thus, an epoxy resin composition was obtained. Table 1 shows the evaluation results.

【0057】(比較例6)ポリエーテルスルフォンの配
合量を10重量部とし、有機系発泡剤アゾジカルボンア
ミドの配合量を25重量部とした以外は、実施例1と同
様の操作を繰り返し、エポキシ樹脂組成物を得た。評価
結果を表1に示す。
Comparative Example 6 The same operation as in Example 1 was repeated except that the blending amount of the polyether sulfone was changed to 10 parts by weight and the blending amount of the organic blowing agent azodicarbonamide was changed to 25 parts by weight. A resin composition was obtained. Table 1 shows the evaluation results.

【0058】(実施例7)ポリエーテルスルフォンの配
合量を10重量部とし、無機系充填剤炭酸カルシウムの
配合量を5重量部とした以外は、実施例1と同様の操作
を繰り返し、エポキシ樹脂組成物を得た。評価結果を表
1に示す。
Example 7 The same operation as in Example 1 was repeated except that the amount of the polyether sulfone was changed to 10 parts by weight and the amount of the inorganic filler calcium carbonate was changed to 5 parts by weight. A composition was obtained. Table 1 shows the evaluation results.

【0059】(実施例8)ポリエーテルスルフォンの配
合量を10重量部とし、無機系充填剤炭酸カルシウムの
配合量を200重量部とした以外は、実施例1と同様の
操作を繰り返し、エポキシ樹脂組成物を得た。評価結果
を表1に示す。
Example 8 The same operation as in Example 1 was repeated except that the blending amount of the polyether sulfone was changed to 10 parts by weight and the blending amount of the inorganic filler calcium carbonate was changed to 200 parts by weight. A composition was obtained. Table 1 shows the evaluation results.

【0060】(比較例7)ポリエーテルスルフォンの配
合量を10重量部とし、無機系充填剤炭酸カルシウムの
配合量を1重量部とした以外は、実施例1と同様の操作
を繰り返し、エポキシ樹脂組成物を得た。評価結果を表
1に示す。
Comparative Example 7 The same operation as in Example 1 was repeated except that the amount of the polyether sulfone was changed to 10 parts by weight and the amount of the inorganic filler calcium carbonate was changed to 1 part by weight. A composition was obtained. Table 1 shows the evaluation results.

【0061】(比較例8)ポリエーテルスルフォンの配
合量を10重量部とし、無機系充填剤炭酸カルシウムの
配合量を250重量部とした以外は、実施例1と同様の
操作を繰り返し、エポキシ樹脂組成物を得た。評価結果
を表1に示す。
Comparative Example 8 The same operation as in Example 1 was repeated except that the blending amount of the polyether sulfone was changed to 10 parts by weight and the blending amount of the inorganic filler calcium carbonate was changed to 250 parts by weight. A composition was obtained. Table 1 shows the evaluation results.

【0062】(実施例9)液状ビスフェノールA型エポ
キシ樹脂の代わりに液状ビスフェノールF型エポキシ樹
脂100重量部を用い、ポリエーテルスルフォンの配合
量を10重量部とした以外は、実施例1と同様の操作を
繰り返し、エポキシ樹脂組成物を得た。評価結果を表1
に示す。
Example 9 The same procedure as in Example 1 was carried out except that 100 parts by weight of a liquid bisphenol F type epoxy resin was used instead of the liquid bisphenol A type epoxy resin, and the blending amount of polyether sulfone was changed to 10 parts by weight. The operation was repeated to obtain an epoxy resin composition. Table 1 shows the evaluation results.
Shown in

【0063】(実施例10)ポリエーテルスルフォンの
代わりにポリエーテルイミド10重量部を用いた以外
は、実施例1と同様の操作を繰り返し、エポキシ樹脂組
成物を得た。評価結果を表1に示す。
Example 10 An epoxy resin composition was obtained by repeating the same operation as in Example 1 except that 10 parts by weight of polyetherimide was used instead of polyethersulfone. Table 1 shows the evaluation results.

【0064】[0064]

【表1】 [Table 1]

【0065】(実施例11)車体のセンタピラー・ウエ
スト部及びルーフレール/センタピラー結合部を構成す
るように予め成形された鋼板2に、図2に示すように、
本発明のエポキシ樹脂組成物シート1を貼着した。次い
で、この鋼板2を溶接し、更に車体3を組み上げた後、
車体3の塗膜密着性を向上するために苛性処理液で洗浄
した。更に、車体3を電着液槽4に浸漬して防錆処理を
施した後、車体3を焼き付け炉5に収容し、170℃×
20分の条件で電着塗膜を焼き付けたところ、上記組成
物シート1は十分に発泡・硬化し、均一な発泡材1’を
形成した。このように、本発明のエポキシ樹脂組成物
は、実際の自動車生産ラインにおいても良好に使用で
き、車体の箱型構造部材の剛性を確実に向上させること
ができる。
(Embodiment 11) As shown in FIG. 2, a steel plate 2 formed in advance so as to constitute a center pillar waist portion and a roof rail / center pillar joint portion of a vehicle body is formed as shown in FIG.
The epoxy resin composition sheet 1 of the present invention was adhered. Next, after welding the steel plate 2 and further assembling the vehicle body 3,
The body 3 was washed with a caustic treatment solution in order to improve the adhesion of the coating film. Further, after the vehicle body 3 is immersed in the electrodeposition liquid tank 4 and subjected to rust prevention treatment, the vehicle body 3 is placed in a baking furnace 5 and heated at 170 ° C.
When the electrodeposition coating film was baked under the conditions of 20 minutes, the composition sheet 1 was sufficiently foamed and cured to form a uniform foamed material 1 '. As described above, the epoxy resin composition of the present invention can be favorably used in an actual automobile production line, and the rigidity of the box-shaped structural member of the vehicle body can be reliably improved.

【0066】[0066]

【発明の効果】以上説明したように、本発明によれば、
ある種の芳香族ポリエーテルをエポキシ樹脂と混合する
ことにより、耐衝撃性を備えたエポキシ樹脂系組成物を
得、また、これをシート化した後、予め形成された鋼板
に装着、該鋼板を用いて箱型部材を組み上げた後、車体
電着塗装時の焼き付け工程で発泡・充填させることとし
たため、箱型部材中に簡易且つ均一に発泡・充填するこ
とができ、自動車車体の剛性を確実に向上させることの
できる車体補強用エポキシ樹脂系組成物、車体補強構造
及び車体の補強方法を提供することができる。
As described above, according to the present invention,
By mixing a certain kind of aromatic polyether with an epoxy resin, an epoxy resin composition having impact resistance is obtained, and after forming this into a sheet, it is mounted on a preformed steel sheet, and the steel sheet is attached. After assembling the box-shaped member, it is foamed and filled in the baking process at the time of electrodeposition coating of the car body, so it can be easily and uniformly foamed and filled in the box-shaped member, ensuring the rigidity of the car body The present invention can provide an epoxy resin composition for reinforcing a vehicle body, a vehicle body reinforcing structure, and a method of reinforcing a vehicle body, which can be improved.

【0067】即ち、本発明によれば、軽量化を図りつつ
車体骨格を確実に補強することが可能となる。また、こ
れにより、車両の乗り心地の改善、騒音・振動の低減が
期待され、更に、箱型閉断面部材中に高剛性の発泡体が
充填されることにより、車両衝突時のエネルギ吸収効果
も期待することができる。
That is, according to the present invention, it is possible to reliably reinforce the body frame while reducing the weight. In addition, this is expected to improve the riding comfort of the vehicle and reduce noise and vibration, and furthermore, since the highly rigid foam is filled in the box-shaped closed section member, the energy absorbing effect at the time of vehicle collision is also improved. You can expect.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の車体補強構造の剛性を評価する試験装
置を示す斜視図である。
FIG. 1 is a perspective view showing a test device for evaluating the rigidity of a vehicle body reinforcement structure according to the present invention.

【図2】本発明の車体補強方法の適用例を示す工程図で
ある。
FIG. 2 is a process chart showing an application example of the vehicle body reinforcing method of the present invention.

【符号の説明】[Explanation of symbols]

1 エポキシ樹脂組成物シート 1’ 発泡材 2 鋼板 3 車体 4 電着液槽 5 焼き付け炉 10 発泡材 20 箱型断面部材 DESCRIPTION OF SYMBOLS 1 Epoxy resin composition sheet 1 'Foaming material 2 Steel plate 3 Car body 4 Electrodeposition bath 5 Baking furnace 10 Foaming material 20 Box-shaped section member

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 FI C08L 81/06 C08L 81/06 // C08G 59/24 C08G 59/24 59/40 59/40 ──────────────────────────────────────────────────の Continued on the front page (51) Int.Cl. 6 Identification code FI C08L 81/06 C08L 81/06 // C08G 59/24 C08G 59/24 59/40 59/40

Claims (7)

【特許請求の範囲】[Claims] 【請求項1】 (A)ビスフェノールA及び/又はビス
フェノールFから誘導されたエポキシ樹脂100重量部
に対して、(B)芳香族ポリエーテル1〜40重量部、
(C)エポキシ樹脂用熱活性型硬化剤3〜30重量部、
(D)熱分解型有機系発泡剤0.5〜20重量部、及び
(E)無機系充填剤3〜200重量部を含有して成るこ
とを特徴とする車体補強用エポキシ樹脂系組成物。
1. An epoxy resin derived from bisphenol A and / or bisphenol F (A) (100 parts by weight), (B) 1 to 40 parts by weight of an aromatic polyether,
(C) 3 to 30 parts by weight of a thermally activated curing agent for epoxy resin,
An epoxy resin composition for reinforcing a vehicle body, comprising (D) 0.5 to 20 parts by weight of a thermally decomposable organic foaming agent and (E) 3 to 200 parts by weight of an inorganic filler.
【請求項2】 上記芳香族ポリエーテル(B)が、ポリ
エーテルスルフォンであることを特徴とする請求項1記
載の車体補強用エポキシ樹脂系組成物。
2. The epoxy resin composition for reinforcing a vehicle body according to claim 1, wherein the aromatic polyether (B) is a polyether sulfone.
【請求項3】 上記芳香族ポリエーテル(B)が、ポリ
エーテルイミドであることを特徴とする請求項1記載の
車体補強用エポキシ樹脂系組成物。
3. The epoxy resin composition for reinforcing a vehicle body according to claim 1, wherein the aromatic polyether (B) is a polyetherimide.
【請求項4】 常温で固体状をなし、加熱処理により発
泡して発泡体を形成することを特徴とする請求項1〜3
のいずれか1つの項に記載の車体補強用エポキシ樹脂系
組成物。
4. A foamed body formed in a solid state at normal temperature and foamed by a heat treatment.
The epoxy resin composition for reinforcing a vehicle body according to any one of the above items.
【請求項5】 箱型部材の内部に、請求項4記載の発泡
体を充填して成ることを特徴とする車体補強構造。
5. A vehicle body reinforcing structure characterized by filling the inside of a box-shaped member with the foam according to claim 4.
【請求項6】 鋼板から構成された箱型部材を備える車
体を補強するに当たり、 上記箱型部材の内部に相当する上記鋼板の部分に、請求
項1〜4のいずれか1つの項に記載の車体補強用エポキ
シ樹脂系組成物から成るシートを配置し、 次いで、上記鋼板を組み付けて上記箱型部材を組み上
げ、 しかる後、組み上げた箱型部材を電着塗装処理に供し、
この処理の焼き付け工程で上記シートを発泡させること
を特徴とする車体の補強方法。
6. The reinforcing member according to claim 1, wherein a portion of the steel plate corresponding to the inside of the box-shaped member is provided for reinforcing a vehicle body having a box-shaped member formed of a steel plate. A sheet made of an epoxy resin composition for reinforcing the vehicle body is arranged, and then the steel plate is assembled to assemble the box-shaped member. Thereafter, the assembled box-shaped member is subjected to an electrodeposition coating process.
A reinforcing method for a vehicle body, wherein the sheet is foamed in a baking step of this processing.
【請求項7】 上記焼き付け工程を、140〜210℃
で10〜30分間加熱することにより行うことを特徴と
する請求項6記載の車体の補強方法。
7. The baking step is performed at 140 to 210 ° C.
7. The method according to claim 6, wherein the heating is performed for 10 to 30 minutes.
JP31256696A 1996-11-11 1996-11-11 Epoxy resin composition for reinforcing car body, car body reinforcement structure, and method for reinforcing car body Pending JPH10139981A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP31256696A JPH10139981A (en) 1996-11-11 1996-11-11 Epoxy resin composition for reinforcing car body, car body reinforcement structure, and method for reinforcing car body

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP31256696A JPH10139981A (en) 1996-11-11 1996-11-11 Epoxy resin composition for reinforcing car body, car body reinforcement structure, and method for reinforcing car body

Publications (1)

Publication Number Publication Date
JPH10139981A true JPH10139981A (en) 1998-05-26

Family

ID=18030766

Family Applications (1)

Application Number Title Priority Date Filing Date
JP31256696A Pending JPH10139981A (en) 1996-11-11 1996-11-11 Epoxy resin composition for reinforcing car body, car body reinforcement structure, and method for reinforcing car body

Country Status (1)

Country Link
JP (1) JPH10139981A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2342356A (en) * 1998-10-07 2000-04-12 Sumitomo Chemical Co Thermosetting resin compositions; printed circuit boards
JP2003500509A (en) * 1999-05-21 2003-01-07 アルバート カポテ ミグエル High performance cyanate-bismaleimide-epoxy resin compositions for printed circuits and encapsulants
WO2004101349A3 (en) * 2003-05-07 2005-01-20 L & L Products Inc Activatable material for sealing, baffling or reinforcing and method of forming same
JP2010195852A (en) * 2009-02-23 2010-09-09 Hitachi Chem Co Ltd Resin composition, prepreg using the same, laminated sheet, and wiring board
US7892396B2 (en) 2006-06-07 2011-02-22 Zephyros, Inc. Toughened activatable material for sealing, baffling or reinforcing and method of forming same
US8105460B2 (en) 2006-09-08 2012-01-31 Zephyros, Inc. Handling layer and adhesive parts formed therewith
US9394468B2 (en) 2011-02-15 2016-07-19 Zephyros, Inc. Structural adhesives

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2342356A (en) * 1998-10-07 2000-04-12 Sumitomo Chemical Co Thermosetting resin compositions; printed circuit boards
GB2342356B (en) * 1998-10-07 2002-01-23 Sumitomo Chemical Co Thermosetting resin compositions for build-up method
JP2003500509A (en) * 1999-05-21 2003-01-07 アルバート カポテ ミグエル High performance cyanate-bismaleimide-epoxy resin compositions for printed circuits and encapsulants
WO2004101349A3 (en) * 2003-05-07 2005-01-20 L & L Products Inc Activatable material for sealing, baffling or reinforcing and method of forming same
US7125461B2 (en) * 2003-05-07 2006-10-24 L & L Products, Inc. Activatable material for sealing, baffling or reinforcing and method of forming same
US7892396B2 (en) 2006-06-07 2011-02-22 Zephyros, Inc. Toughened activatable material for sealing, baffling or reinforcing and method of forming same
US8105460B2 (en) 2006-09-08 2012-01-31 Zephyros, Inc. Handling layer and adhesive parts formed therewith
US8741094B2 (en) 2006-09-08 2014-06-03 Zephyros, Inc. Handling layer and adhesive parts formed therewith
JP2010195852A (en) * 2009-02-23 2010-09-09 Hitachi Chem Co Ltd Resin composition, prepreg using the same, laminated sheet, and wiring board
US9394468B2 (en) 2011-02-15 2016-07-19 Zephyros, Inc. Structural adhesives

Similar Documents

Publication Publication Date Title
JPH1160900A (en) Car body-reinforcing epoxy resin composition and method for reinforcing car body
JP3954119B2 (en) Heated foam filling reinforcement and closed cross-section structural member reinforcement structure using the same heated foam filling reinforcement
US7736743B2 (en) Heat curable, thermally expandable composition with high degree of expansion
US9045161B2 (en) Paste form heat-blowing injection composition and method for injecting and soundproofing closed section of automobile body member
US8741094B2 (en) Handling layer and adhesive parts formed therewith
JP4491236B2 (en) Expandable epoxy resin system modified with thermoplastic polymer
US5151327A (en) Adhesive sheet for reinforcing thin rigid plates
US7084210B2 (en) Heat activated epoxy adhesive and use in a structural foam insert
US20070117874A1 (en) Expandable material
DE102006048739A1 (en) Foamable composition useful for reinforcing and/or stiffening structural members e.g. stiffening thin-walled building components, comprises epoxy resins; curatives; blowing agents; and polyesters
JPH0669739B2 (en) Sheet material for panel reinforcement and vehicle outer panel structure using the same
GB2463858A (en) Foamed insulation
JPH10139981A (en) Epoxy resin composition for reinforcing car body, car body reinforcement structure, and method for reinforcing car body
JP2006281741A (en) Steel plate reinforcing sheet
JPH09316169A (en) Epoxy resin composition for reinforcing automotive body and method for reinforcing automotive body using the same
JPH11263865A (en) Expandable reinforcement composition and reinforcement of car body
JPH11129368A (en) Box type structural member, manufacture thereof and reinforcing structure of car body
JPH05111973A (en) Panel reinforcing sheet material and vehicle outer panel structure using the same
JP2000239431A (en) Expandable filler composition and reinforcing method of car body
JP2000063555A (en) Foamable reinforcing material composition and reinforcement of car body
JP2000085618A (en) Rigidity improving method for foam filler and box-type member
JPH1095869A (en) Crosslinked foam for reinforcing car body and method for reinforcing car body therewith
WO1996005240A1 (en) Structural strengthening
JPH10101902A (en) Epoxy resin composition for reinforcing car body and method for reinforcing car body
JP2006176668A (en) Expandable filler composition