JPH10139402A - Plate-type reactor - Google Patents

Plate-type reactor

Info

Publication number
JPH10139402A
JPH10139402A JP8296393A JP29639396A JPH10139402A JP H10139402 A JPH10139402 A JP H10139402A JP 8296393 A JP8296393 A JP 8296393A JP 29639396 A JP29639396 A JP 29639396A JP H10139402 A JPH10139402 A JP H10139402A
Authority
JP
Japan
Prior art keywords
plate
temperature gas
flow path
filler
gas flow
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP8296393A
Other languages
Japanese (ja)
Other versions
JP3843509B2 (en
Inventor
Minoru Koga
実 古賀
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IHI Corp
Original Assignee
IHI Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IHI Corp filed Critical IHI Corp
Priority to JP29639396A priority Critical patent/JP3843509B2/en
Publication of JPH10139402A publication Critical patent/JPH10139402A/en
Application granted granted Critical
Publication of JP3843509B2 publication Critical patent/JP3843509B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/06Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • H01M8/0625Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material in a modular combined reactor/fuel cell structure
    • H01M8/0631Reactor construction specially adapted for combination reactor/fuel cell
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Fuel Cell (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide a plate-type reactor having plural partition walls for two kinds of fluid, designed to efficiently conduct heat exchange between the two kinds of fluid and enabling a specified reaction to be promoted or controlled, and also efficiently affordable in high accuracy and at low cost without any machining work. SOLUTION: This plate-type reactor has press-molded separator plates 12 each bearing many projections 11 both on the surface and reverse face and flat plates 13 each firmly attached to both the surface and reverse face of each of the projections; these separator plates and flat plates are alternately laminated with each other, affording high-temperature gas flow channels 14 and low-temperature gas flow channels 15 therebetween. Each of the projections is of waveform design and composed of a projected emboss and recessed emboss adjacent to each other which are alternately repeated on the plane of the separator plate.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、二種の流体が隔壁
により仕切られ、その間の熱交換により反応を促進又は
制御するプレート式反応器に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a plate reactor in which two kinds of fluids are separated by a partition wall, and the reaction is promoted or controlled by heat exchange therebetween.

【0002】[0002]

【従来の技術】二種の流体間の熱交換により反応を促進
或いは制御する反応器として、燃料電池用の改質器(リ
フォーマ)、シフトコンバータ、等が知られている。更
に、かかる改質器やシフトコンバータの反応室を平板状
の隔壁で仕切りこれを複数積層した反応器が一部で提案
され、既に実施されている。以下、かかかる反応器を
「プレート式反応器」と呼ぶ。
2. Description of the Related Art As a reactor for promoting or controlling a reaction by heat exchange between two kinds of fluids, a reformer for fuel cells, a shift converter, and the like are known. Further, a reactor in which a reaction chamber of such a reformer or a shift converter is partitioned by a flat partition wall and a plurality of the reactors are stacked has been proposed and has already been implemented. Hereinafter, such a reactor is referred to as a “plate reactor”.

【0003】図7〜図9は、リン酸型(PAFC)燃料
電池発電システム(図7)、溶融炭酸塩型(MCFC)
燃料電池発電システム(図8)及び固体高分子型(SO
FC)燃料電池システム(図9)を示している。これら
の発電システムには、従来から、プレート式反応器が適
用されている。例えば、PAFC発電システムでは、改
質器、高温及び低温シフトコンバータ、MCFC発電シ
ステムでは改質器、SOFC発電システムでは改質器及
び低温シフトコンバータが対象となる。
FIGS. 7 to 9 show a phosphoric acid type (PAFC) fuel cell power generation system (FIG. 7) and a molten carbonate type (MCFC)
Fuel cell power generation system (Fig. 8) and solid polymer type (SO
FC) shows a fuel cell system (FIG. 9). Conventionally, a plate reactor has been applied to these power generation systems. For example, the reformer and the high-temperature and low-temperature shift converter are targeted in the PAFC power generation system, the reformer and the low-temperature shift converter are targeted in the MCFC power generation system, and the reformer is the target in the SOFC power generation system.

【0004】[0004]

【発明が解決しようとする課題】図10は、従来のプレ
ート式反応器であるプレートリフォーマ(改質器)の構
造図である。この図において、高温段と低温段は平板状
の隔壁1で仕切られており、この隔壁1に多数のパイプ
2が点付溶接され、この隔壁1とパイプ2とによって形
成される空間に充填材3が充填されている。なお、この
図で5は、穴開板(パンチ板)等で構成された仕切り部
材であり、内部に充填された触媒等の流出を防止しかつ
内部とのガスの流通を可能にしている。
FIG. 10 is a structural diagram of a plate reformer (reformer) which is a conventional plate type reactor. In this figure, a high-temperature stage and a low-temperature stage are separated by a flat partition 1, and a large number of pipes 2 are spot-welded to the partition 1, and a filler formed in the space formed by the partition 1 and the pipe 2. 3 are filled. In this figure, reference numeral 5 denotes a partition member constituted by a perforated plate (punched plate) or the like, which prevents a catalyst or the like filled therein from flowing out and allows gas to flow therethrough.

【0005】しかし、この構造のプレートリフォーマ
は、サイドバー4とパイプ2の高さを高精度に製作す
る必要があるため、多数のパイプ2を機械加工する必要
があり、かつ隔壁1と多数のパイプ2の位置決め及び
溶接に多大の時間を要する、等の問題点があり、このた
め製作費が高く、大幅なコストダウンが要望されてい
た。
However, in the plate reformer having this structure, since the heights of the side bars 4 and the pipes 2 need to be manufactured with high precision, a large number of pipes 2 need to be machined, and the partition wall 1 and the large number of pipes 2 must be machined. It takes a lot of time for positioning and welding of the pipe 2, and therefore, the production cost is high, and a great cost reduction has been demanded.

【0006】本発明はかかる問題点を解決するために創
案されたものである。すなわち、本発明の目的は、二種
の流体間を仕切る複数の隔壁を有し、その間の熱交換を
効率よく行い、所定の反応を促進或いは制御することが
でき、かつ機械加工なしで高精度かつ低コストで効率よ
く製造できるプレート式反応器を提供することにある。
The present invention has been made to solve such a problem. That is, an object of the present invention is to have a plurality of partitions for partitioning between two kinds of fluids, efficiently perform heat exchange therebetween, promote or control a predetermined reaction, and have high precision without machining. Another object of the present invention is to provide a plate reactor that can be efficiently manufactured at low cost.

【0007】[0007]

【課題を解決するための手段】本発明によれば、表裏に
多数の突起部を有するプレス成形によるセパレータ板
と、該突起部の表裏に密着する平板と、を有し、該セパ
レータ板と平板とが交互に積層され、その間に高温ガス
流路及び低温ガス流路を形成することを特徴とするプレ
ート式反応器が提供される。
According to the present invention, there is provided a press-formed separator plate having a large number of projections on the front and back, and a flat plate closely contacting the front and back of the projections. Are alternately stacked, and a high-temperature gas flow path and a low-temperature gas flow path are formed therebetween, thereby providing a plate reactor.

【0008】この構成により、プレス成形によるセパレ
ータ板と平板とを交互に積層することにより、従来のよ
うに多数のパイプの機械加工や溶接が不要であり、機械
加工なしで高精度かつ低コストで効率よくプレート式反
応器を製造することができ、かつ反応器の軽量化、及び
組立工数の低減を図ることができる。なお、プレート式
反応器を改質器として使用する場合に、低温ガス流路に
改質触媒を充填し、この流路に炭化水素と水蒸気の混合
ガスを流し、高温ガス流路に伝熱促進材(すなわち、ア
ルミナボール)を充填し、燃焼ガス等を流すことによ
り、低温ガス流路の炭化水素を高温ガス流路からの伝熱
により水素とCOに改質することができる。プレート式
反応器をシフトコンバータとして使用する場合も同様で
ある。
[0008] With this configuration, by alternately laminating the separator plate and the flat plate by press molding, machining and welding of a large number of pipes are unnecessary as in the prior art, and high precision and low cost can be achieved without machining. A plate reactor can be manufactured efficiently, and the weight of the reactor can be reduced and the number of assembly steps can be reduced. When a plate reactor is used as a reformer, a low-temperature gas flow path is filled with a reforming catalyst, a mixed gas of hydrocarbon and steam flows through this flow path, and heat transfer is promoted through a high-temperature gas flow path. By filling a material (that is, alumina balls) and flowing a combustion gas or the like, hydrocarbons in the low-temperature gas channel can be reformed into hydrogen and CO by heat transfer from the high-temperature gas channel. The same applies when a plate reactor is used as a shift converter.

【0009】本発明の好ましい実施形態によれば、前記
セパレータ板は、高温ガス流路及び低温ガス流路に反応
触媒、反応触媒+伝熱促進材、伝熱促進材のいずれかの
充填材をブリッジ形成なしで充填できる波型形状を有す
る。ブリッジ形成なしで充填できる波型形状とは、例え
ば、円型エンボス、楕円型エンボス等である。ま
た、反応触媒及び伝熱促進材は、ガス通路内でブリッジ
を形成しない粒径及び形状であるのがよい。この構成に
より、プレート式反応器を分解することなく、反応触媒
及び伝熱促進材を交換することができる。
According to a preferred embodiment of the present invention, the separator plate is provided with a filler selected from the group consisting of a reaction catalyst, a reaction catalyst and a heat transfer promoting material, and a heat transfer promoting material in the high temperature gas flow path and the low temperature gas flow path. It has a corrugated shape that can be filled without bridge formation. The corrugated shape that can be filled without forming a bridge is, for example, a circular emboss, an elliptical emboss, or the like. Further, the reaction catalyst and the heat transfer promoting material preferably have a particle size and a shape that do not form a bridge in the gas passage. With this configuration, the reaction catalyst and the heat transfer promoting material can be exchanged without disassembling the plate reactor.

【0010】また、前記波型形状は、互いに隣接した凸
型エンボスと凹型エンボスからなり、セパレータ板の平
面内で交互に繰り返されている。この構成により、プレ
ス成形により1枚の平板から容易にセパレータ板を高精
度に量産することができる。
[0010] The corrugated shape includes a convex emboss and a concave emboss adjacent to each other, and is alternately repeated in the plane of the separator plate. With this configuration, it is possible to easily mass-produce separator plates from one flat plate with high precision by press molding.

【0011】更に、前記エンボスと接触することなく高
温ガス流路又は低温ガス流路を仕切る充填材止と、該仕
切られた流路に充填材を充填する充填材投入孔とを有
し、該充填材止は、ガスを該流路内のガスの流通を可能
にする貫通穴を有し、かつ前記仕切られた各流路に異な
る充填材が充填される。この構成により、各ガス通路内
に複数の充填材を区分けして充填することができ、プレ
ート式反応器における伝熱を制御し、プレート式反応器
における反応を促進或いは制御することができる。
[0011] Further, there is provided a filler stop for partitioning the high-temperature gas flow path or the low-temperature gas flow path without contacting the emboss, and a filler charging hole for filling the divided flow path with the filler. The filler stopper has a through-hole for allowing gas to flow through the flow path, and each of the partitioned flow paths is filled with a different filler. With this configuration, it is possible to separately fill a plurality of fillers in each gas passage, control the heat transfer in the plate reactor, and promote or control the reaction in the plate reactor.

【0012】[0012]

【発明の実施の形態】以下、本発明の好ましい実施形態
を図面を参照して説明する。なお、各図において共通す
る部分には同一の符号を付して使用する。図1は、本発
明によるプレート式反応器の全体構成図である。この図
において、(A)は部分縦断面図、(B)は(A)のB
−B線における断面図、(C)は(A)のC−C線にお
ける断面図、(D)は(B)のD矢視である。すなわ
ち、(B)は低温段(低温ガス流路)の平面図、(C)
は高温段(高温ガス流路)の平面図である。
DESCRIPTION OF THE PREFERRED EMBODIMENTS Preferred embodiments of the present invention will be described below with reference to the drawings. In the drawings, common parts are denoted by the same reference numerals. FIG. 1 is an overall configuration diagram of a plate reactor according to the present invention. In this figure, (A) is a partial longitudinal sectional view, and (B) is B of (A).
FIG. 3C is a cross-sectional view taken along line B, FIG. 3C is a cross-sectional view taken along line CC in FIG. 3A, and FIG. That is, (B) is a plan view of the low-temperature stage (low-temperature gas flow path), and (C)
FIG. 3 is a plan view of a high-temperature stage (high-temperature gas channel).

【0013】この図に示すように、本発明のプレート式
反応器10は、表裏に多数の突起部11を有するプレス
成形によるセパレータ板12と、突起部11の表裏に密
着する平板13と、を有し、セパレータ板12と平板1
3とが交互に積層され、その間に高温ガス流路14及び
低温ガス流路15を形成するようになっている。なお、
この図で4は、サイドバーであり、セパレータ板12と
平板13の周囲を溶接等により気密に連結するようにな
っている。
As shown in FIG. 1, a plate reactor 10 of the present invention comprises a separator plate 12 formed by press molding having a large number of protrusions 11 on the front and back, and a flat plate 13 closely contacting the front and back of the protrusions 11. Having a separator plate 12 and a flat plate 1
3 are alternately stacked, and a high-temperature gas channel 14 and a low-temperature gas channel 15 are formed therebetween. In addition,
In this figure, reference numeral 4 denotes a side bar, which is connected airtightly by welding or the like around the separator plate 12 and the flat plate 13.

【0014】また、(B)(C)に示すように、高温ガ
ス流路14及び低温ガス流路15のガス流入部及びガス
流出部には、穴開板(パンチ板)等で構成された仕切り
部材5が取り付けられ、内部に充填された触媒等の流出
を防止しかつ内部とのガスの流通を可能にしている。
As shown in (B) and (C), the gas inlet and the gas outlet of the high-temperature gas flow path 14 and the low-temperature gas flow path 15 are provided with a partition formed by a perforated plate (punch plate) or the like. A member 5 is attached to prevent outflow of the catalyst and the like filled in the inside, and allows gas to flow through the inside.

【0015】更に、プレート式反応器(プレート型改質
器及びシフトコンバータ)の充填層内に生ずる温度分布
を改善するため、高温ガス及び低温ガスの流れが対称と
なるようにヘッダ17を左右対称になるように設置して
いる。隔壁(セパレータ板12)は一体プレス成形され
ているので、反応器の軽量化、組立及び仮付溶接工数の
低減を図ることができる。
Furthermore, in order to improve the temperature distribution generated in the packed bed of the plate reactor (plate reformer and shift converter), the header 17 is symmetrical so that the flow of the high-temperature gas and the low-temperature gas is symmetric. It is installed so that it becomes. Since the partition wall (separator plate 12) is formed by integral press molding, it is possible to reduce the weight of the reactor, assemble and reduce the number of man-hours for temporary welding.

【0016】なお、この図は、プレート式反応器を改質
器として使用する場合を示しており、低温ガス流路15
に改質触媒を充填し、この流路に炭化水素と水蒸気の混
合ガスを流し、高温ガス流路14に伝熱促進材(すなわ
ち、アルミナボール)を充填し、高温ガス等を流すこと
により、低温ガス流路の炭化水素を高温ガス流路からの
伝熱により水素とCOに改質することができる。また、
この図のプレート式反応器をシフトコンバータとしてそ
のまま使用することもできる。
FIG. 1 shows a case where a plate-type reactor is used as a reformer.
Is filled with a reforming catalyst, a mixed gas of hydrocarbon and steam flows through this flow path, and a high-temperature gas flow path 14 is filled with a heat transfer promoting material (that is, alumina balls), and a high-temperature gas or the like is flown. Hydrocarbons in the low temperature gas channel can be reformed into hydrogen and CO by heat transfer from the high temperature gas channel. Also,
The plate reactor shown in this figure can be used as it is as a shift converter.

【0017】図2はプレス成形によるセパレータ板12
を示す。図1に示したように、セパレータ板12の表裏
にプレス成形により形成された多数の突起部11は波型
形状をしており、この波型形状は、互いに隣接した凸型
エンボスと凹型エンボスからなる。図2において、凸形
エンボスは○印で示し、●印は凹形エンボスを示してい
る。凸形エンボスの隣接エンボスは必ず凹形であり、セ
パレータ板の平面内で交互に繰り返されている。この構
成により、プレス成形により1枚の平板から容易にセパ
レータ板を高精度に量産することができる。
FIG. 2 shows a separator plate 12 formed by press molding.
Is shown. As shown in FIG. 1, a large number of protrusions 11 formed on the front and back of the separator plate 12 by press molding have a corrugated shape, and this corrugated shape is formed by a convex emboss and a concave emboss adjacent to each other. Become. In FIG. 2, a convex emboss is shown by a mark, and a black mark is a concave emboss. The adjacent embossments of the convex embossments are always concave and are alternately repeated in the plane of the separator plate. With this configuration, it is possible to easily mass-produce separator plates from one flat plate with high precision by press molding.

【0018】図3は低温シフトコンバータの実施例を示
す。低温シフト反応触媒は、Cu−Zn系である。図4
は高温シフトコンバータの実施例を示す。高温板の上流
側は高温ガスが流れるため、高温シフト反応触媒がシン
タリングし活性が低下する可能性があり、この部分には
アルミナボールを充填できるようにしている。高温シフ
ト反応触媒はFe−Cr系である。
FIG. 3 shows an embodiment of a low-temperature shift converter. The low-temperature shift reaction catalyst is based on Cu-Zn. FIG.
Shows an embodiment of a high-temperature shift converter. Since the high-temperature gas flows on the upstream side of the high-temperature plate, there is a possibility that the high-temperature shift reaction catalyst may sinter and its activity may be reduced. This portion is filled with alumina balls. The high-temperature shift reaction catalyst is based on Fe-Cr.

【0019】図4(B)において、エンボス11と接触
することなく高温ガス流路を仕切る充填材止18と、こ
の仕切られた流路に充填材を充填する充填材投入孔19
とを有する。また充填材止18は、流路内のガスの流通
を可能にする貫通穴を有している。この構成により、仕
切られた各流路に異なる充填材(例えば、反応触媒と伝
熱促進材)を充填することにより、プレート式反応器に
おける反応を制御することができる。
In FIG. 4B, a filler stopper 18 for partitioning the high-temperature gas flow path without contacting the emboss 11 and a filler charging hole 19 for filling the partitioned flow path with the filler.
And Further, the filler stopper 18 has a through hole that allows gas to flow in the flow path. With this configuration, the reaction in the plate-type reactor can be controlled by filling each of the partitioned flow paths with a different filler (for example, a reaction catalyst and a heat transfer promoting material).

【0020】図5は上下段の熱的対称性を確保するた
め、上下端に断熱層を設けた実施例であり、構造強度の
安定性確保及びヘッダ取り付けスペースの確保を目的と
している。図6は、断熱段の平面図である。
FIG. 5 shows an embodiment in which heat insulating layers are provided at the upper and lower ends in order to ensure thermal symmetry of the upper and lower stages, and aims at securing stability of structural strength and securing a space for mounting a header. FIG. 6 is a plan view of the heat insulating stage.

【0021】なお、本発明は上述した実施形態に限定さ
れず、本発明の要旨を逸脱しない範囲で種々変更できる
ことは勿論である。
It should be noted that the present invention is not limited to the above-described embodiment, but can be variously modified without departing from the gist of the present invention.

【0022】[0022]

【発明の効果】上述したように、本発明のプレート式反
応器は、従来のように多数のパイプの機械加工や溶接が
不要であり、機械加工なしで高精度かつ低コストで効率
よくプレート式反応器を製造することができ、かつ反応
器の軽量化、及び組立工数の低減を図ることができる、
等の優れた効果を有する。
As described above, the plate-type reactor of the present invention does not require machining or welding of a large number of pipes as in the prior art, and is highly efficient at low cost and efficiently without the need for machining. A reactor can be manufactured, and the weight of the reactor can be reduced, and the number of assembly steps can be reduced.
And so on.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明によるプレート式反応器の全体構成図で
ある。
FIG. 1 is an overall configuration diagram of a plate reactor according to the present invention.

【図2】プレス成形によるセパレータ板の平面図であ
る。
FIG. 2 is a plan view of a separator plate formed by press molding.

【図3】低温シフトコンバータの実施例を示す図であ
る。
FIG. 3 is a diagram showing an embodiment of a low-temperature shift converter.

【図4】高温シフトコンバータの実施例を示す図であ
る。
FIG. 4 is a diagram showing an embodiment of a high-temperature shift converter.

【図5】上下端に断熱層を設けた実施例である。FIG. 5 is an embodiment in which heat insulating layers are provided at upper and lower ends.

【図6】断熱段の平面図である。FIG. 6 is a plan view of a heat insulating stage.

【図7】リン酸型燃料電池発電システムの構成図であ
る。
FIG. 7 is a configuration diagram of a phosphoric acid fuel cell power generation system.

【図8】溶融炭酸塩型燃料電池発電システムの構成図で
ある。
FIG. 8 is a configuration diagram of a molten carbonate fuel cell power generation system.

【図9】固体高分子型燃料電池システムの構成図であ
る。
FIG. 9 is a configuration diagram of a polymer electrolyte fuel cell system.

【図10】従来のプレート式反応器の構造図である。FIG. 10 is a structural diagram of a conventional plate reactor.

【符号の説明】[Explanation of symbols]

1 隔壁 2 パイプ 3 充填材 4 サイドバー 10 プレート式反応器 11 突起部 12 セパレータ板 13 平板 14 高温ガス流路 15 低温ガス流路 17 ヘッダ 18 充填材止 19 充填材投入孔 DESCRIPTION OF SYMBOLS 1 Partition wall 2 Pipe 3 Filler 4 Sidebar 10 Plate type reactor 11 Projection part 12 Separator plate 13 Flat plate 14 High temperature gas flow path 15 Low temperature gas flow path 17 Header 18 Filler stop 19 Filler insertion hole

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 FI H01M 8/06 H01M 8/06 G ──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. 6 Identification code FI H01M 8/06 H01M 8/06 G

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 表裏に多数の突起部を有するプレス成形
によるセパレータ板と、該突起部の表裏に密着する平板
と、を有し、該セパレータ板と平板とが交互に積層さ
れ、その間に高温ガス流路及び低温ガス流路を形成する
ことを特徴とするプレート式反応器。
1. A press-formed separator plate having a large number of protrusions on the front and back sides, and a flat plate closely contacting the front and back surfaces of the protrusions, wherein the separator plate and the flat plate are alternately laminated, and a high temperature A plate reactor comprising a gas flow path and a low-temperature gas flow path.
【請求項2】 前記セパレータ板は、高温ガス流路及び
低温ガス流路に反応触媒、反応触媒+伝熱促進材、伝熱
促進材のいずれかの充填材をブリッジ形成なしで充填で
きる波型形状を有する、ことを特徴とする請求項1に記
載のプレート式反応器。
2. A corrugated type in which the separator plate is capable of filling a high-temperature gas flow path and a low-temperature gas flow path with any one of a reaction catalyst, a reaction catalyst + a heat transfer promoting material, and a heat transfer promoting material without forming a bridge. The plate reactor according to claim 1, wherein the plate reactor has a shape.
【請求項3】 前記波型形状は、互いに隣接した凸型エ
ンボスと凹型エンボスからなり、セパレータ板の平面内
で交互に繰り返されている、ことを特徴とする請求項1
又は2に記載のプレート式反応器。
3. The corrugated shape includes a convex emboss and a concave emboss adjacent to each other, and is alternately repeated in a plane of the separator plate.
Or the plate reactor according to 2.
【請求項4】 前記エンボスと接触することなく高温ガ
ス流路又は低温ガス流路を仕切る充填材止と、該仕切ら
れた流路に充填材を充填する充填材投入孔とを有し、該
充填材止は、ガスを該流路内のガスの流通を可能にする
貫通穴を有し、かつ前記仕切られた各流路に異なる充填
材が充填される、ことを特徴とする請求項2乃至3に記
載のプレート式反応器。
4. A filler stopper for partitioning a high-temperature gas channel or a low-temperature gas channel without contacting the emboss, and a filler charging hole for filling the partitioned channel with a filler. 3. The filler stopper according to claim 2, wherein the filler has a through hole for allowing a gas to flow in the flow path, and each of the divided flow paths is filled with a different filler. 4. The plate reactor according to any one of items 1 to 3.
JP29639396A 1996-11-08 1996-11-08 Plate reactor Expired - Fee Related JP3843509B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP29639396A JP3843509B2 (en) 1996-11-08 1996-11-08 Plate reactor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP29639396A JP3843509B2 (en) 1996-11-08 1996-11-08 Plate reactor

Publications (2)

Publication Number Publication Date
JPH10139402A true JPH10139402A (en) 1998-05-26
JP3843509B2 JP3843509B2 (en) 2006-11-08

Family

ID=17832972

Family Applications (1)

Application Number Title Priority Date Filing Date
JP29639396A Expired - Fee Related JP3843509B2 (en) 1996-11-08 1996-11-08 Plate reactor

Country Status (1)

Country Link
JP (1) JP3843509B2 (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000061283A1 (en) * 1999-04-09 2000-10-19 Mitsubishi Heavy Industries, Ltd. Device for decomposing organic halogen compound and fluid heating device
JP2002211901A (en) * 2001-01-05 2002-07-31 Nissan Motor Co Ltd Reactor
US6733552B1 (en) 1999-03-15 2004-05-11 Matsushita Electric Industrial Co., Ltd. Hydrogen generating apparatus
KR100711893B1 (en) 2005-06-24 2007-04-25 삼성에스디아이 주식회사 Reformer for Fuel Cell
JP2008247683A (en) * 2007-03-30 2008-10-16 Tdk Corp Reaction apparatus
WO2011083534A1 (en) * 2010-01-05 2011-07-14 パナソニック株式会社 Fuel treatment device
JP2014098527A (en) * 2012-11-15 2014-05-29 Kawasaki Heavy Ind Ltd Heat exchanger and producing method of the same

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6733552B1 (en) 1999-03-15 2004-05-11 Matsushita Electric Industrial Co., Ltd. Hydrogen generating apparatus
WO2000061283A1 (en) * 1999-04-09 2000-10-19 Mitsubishi Heavy Industries, Ltd. Device for decomposing organic halogen compound and fluid heating device
JP2002211901A (en) * 2001-01-05 2002-07-31 Nissan Motor Co Ltd Reactor
JP4639472B2 (en) * 2001-01-05 2011-02-23 日産自動車株式会社 Reactor
KR100711893B1 (en) 2005-06-24 2007-04-25 삼성에스디아이 주식회사 Reformer for Fuel Cell
JP2008247683A (en) * 2007-03-30 2008-10-16 Tdk Corp Reaction apparatus
WO2011083534A1 (en) * 2010-01-05 2011-07-14 パナソニック株式会社 Fuel treatment device
JP2014098527A (en) * 2012-11-15 2014-05-29 Kawasaki Heavy Ind Ltd Heat exchanger and producing method of the same

Also Published As

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