JPH10120933A - Carotenoid-based pigment solubilized liquid preparation for food, its production and aqueous food using the same preparation - Google Patents
Carotenoid-based pigment solubilized liquid preparation for food, its production and aqueous food using the same preparationInfo
- Publication number
- JPH10120933A JPH10120933A JP8298191A JP29819196A JPH10120933A JP H10120933 A JPH10120933 A JP H10120933A JP 8298191 A JP8298191 A JP 8298191A JP 29819196 A JP29819196 A JP 29819196A JP H10120933 A JPH10120933 A JP H10120933A
- Authority
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- Japan
- Prior art keywords
- food
- carotenoid
- fatty acid
- acid ester
- pigment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- Coloring Foods And Improving Nutritive Qualities (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、食品用カロチノイ
ド系色素可溶化液製剤及びその製造法並びにその製剤を
使用した水性食品に関する。詳しくは、水性食品を透明
かつ安定に着色する食品用カロチノイド系色素可溶化液
製剤及びその製造法並びにその製剤を使用した水性食品
に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a carotenoid pigment solubilized liquid preparation for food, a method for producing the same, and an aqueous food using the preparation. More specifically, the present invention relates to a carotenoid-based dye-solubilized liquid preparation for food that transparently and stably colors an aqueous food, a method for producing the same, and an aqueous food using the preparation.
【0002】[0002]
【従来の技術】今日、食品の製造において食品の着色は
不可欠である。種々の食品の中でも特に、水性食品の着
色に利用されている黄〜赤橙色の天然色素としてはベニ
バナ黄、クチナシ黄、アナトー、β−カロチン、コチニ
ールなどが挙げられる。しかしながら、飲料、ゼリー、
かき氷用シロップなど酸性域で、しかも透明性を有する
着色が可能な色素は、これらのなかでベニバナ黄、コチ
ニールの2種類しかない。2. Description of the Related Art In today's food production, coloring of food is indispensable. Among various foods, as the yellow to red-orange natural pigments used for coloring aqueous foods, safflower yellow, gardenia yellow, annatto, β-carotene, cochineal and the like can be mentioned. However, beverages, jellies,
Among these, there are only two types of pigments that can be colored in the acidic region such as syrup for shaved ice and have transparency, namely safflower yellow and cochineal.
【0003】本発明の食品用カロチノイド系色素可溶化
液製剤は、このような水性食品を透明かつ安定に着色す
るために利用される。[0003] The carotenoid dye solubilized liquid preparation for food of the present invention is used for coloring such aqueous foods transparently and stably.
【0004】[0004]
【発明が解決しようとする課題】油溶性カロチノイド系
色素は、その物性のため食品における用途が限られてい
た。ところが最近では、乳化技術の進歩と相まって水分
散性の製品が多く市販されるようになってきた。例え
ば、粉末(特開昭57−205453)、乳化液(特公
昭60−43107、特公昭62−61076)などの
製剤が挙げられる。しかしながら、いずれも水に溶解し
たとき均一に分散はするが、透明には溶解しない。ま
た、これらは水溶液中では球状ミセル(通常直径0.3
μm以上)として存在しているために、例えば飲料など
を着色する場合、SAIB(シュークローズドアセテー
トイソブチレート)などの比重調整剤を必要としてき
た。すなわち、現在市販されている水分散性の色素製剤
は飲料を始めとする水性の食品を透明かつ安定に着色で
きない。The use of oil-soluble carotenoid pigments in foods has been limited due to their physical properties. Recently, however, many water-dispersible products have come to be marketed in conjunction with the progress of emulsification technology. For example, preparations such as powder (JP-A-57-205453), emulsion (JP-B-60-43107, JP-B-62-61076) and the like can be mentioned. However, they all disperse uniformly when dissolved in water, but do not dissolve transparently. These are spherical micelles (usually having a diameter of 0.3) in an aqueous solution.
(μm or more), for example, when coloring beverages and the like, a specific gravity adjuster such as SAIB (shoe closed acetate isobutyrate) has been required. That is, currently available water-dispersible pigment preparations cannot color transparent and stable aqueous foods such as beverages.
【0005】本発明は、飲料を始めとする水性食品の透
明かつ安定な着色を可能にする食品用カロチノイド系色
素可溶化液製剤及びその製造法並びにその製剤を使用し
た水性食品を明らかにすることを目的とする。An object of the present invention is to clarify a carotenoid-based dye-solubilized liquid preparation for food which enables transparent and stable coloring of aqueous foods such as beverages, a method for producing the same, and an aqueous food using the preparation. With the goal.
【0006】[0006]
【課題を解決するための手段】本発明の上記課題は、
(1)食品用カロチノイド系色素とポリグリセリン脂肪
酸エステルの組成物が微粒子化され、その可視部の極大
吸収波長での吸光度が1のとき、660nmにおける透
過率が99%以上であることを特徴とする食品用カロチ
ノイド系色素可溶化液製剤、(2)ポリグリセリン脂肪
酸エステルがデカグリセリン脂肪酸エステルを5重量%
以上含有する請求項1記載の食品用カロチノイド系色素
可溶化液製剤、(3)食品用カロチノイド系色素とポリ
グリセリン脂肪酸エステルの組成物に高圧ホモジナイザ
ーを作用させることを特徴とする食品用カロチノイド系
色素可溶化液製剤の製造法、(4)ポリグリセリン脂肪
酸エステルがデカグリセリン脂肪酸エステルを5重量%
以上含有する請求項3記載の食品用カロチノイド系色素
可溶化液製剤の製造法、(5)食品用カロチノイド系色
素とポリグリセリン脂肪酸エステルの組成物が微粒子化
され、その可視部の極大吸収波長での吸光度が1のと
き、660nmにおける透過率が99%以上である食品
用カロチノイド系色素可溶化液製剤を含有することを特
徴とする水性食品、によって解決される。Means for Solving the Problems The object of the present invention is to provide:
(1) The composition of a carotenoid pigment for food and a polyglycerin fatty acid ester is finely divided, and when the absorbance at the maximum absorption wavelength in the visible region is 1, the transmittance at 660 nm is 99% or more. Food carotenoid dye solubilized liquid preparation, (2) polyglycerin fatty acid ester is 5% by weight of decaglycerin fatty acid ester
The food carotenoid-based dye-solubilized liquid preparation according to claim 1, which comprises: (3) a food carotenoid-based dye and a polyglycerin fatty acid ester composition, wherein a high-pressure homogenizer is allowed to act on the composition. Method for producing solubilized liquid preparation, (4) polyglycerin fatty acid ester is 5% by weight of decaglycerin fatty acid ester
The method for producing a food carotenoid-based dye-solubilized liquid preparation according to claim 3, wherein the composition comprises a food carotenoid-based colorant and a polyglycerin fatty acid ester, and the composition has a maximum absorption wavelength in the visible region. Wherein the aqueous food is characterized by containing a carotenoid-based dye-solubilized liquid preparation for food having a transmittance at 660 nm of 99% or more when the absorbance is 1.
【0007】[0007]
【発明の実施の形態】本発明に用いられる食品用カロチ
ノイド系色素としては、トウガラシ色素、マリーゴール
ド色素、β−カロチン色素等の公知のいずれのものであ
ってもよい。BEST MODE FOR CARRYING OUT THE INVENTION The carotenoid pigments for foods used in the present invention may be any of known pigments such as pepper pigments, marigold pigments and β-carotene pigments.
【0008】本発明者は、まず、飲料を始めとする水性
食品を透明に着色するために必要な色素可溶化液製剤の
品質を、その色素製剤水溶液の可視部における極大吸収
波長での吸光度が1のとき、660nmにおける透過率
を95%以上と設定し、これを指標に市販の乳化剤をス
クリーニングした。その結果、ポリグリセリン脂肪酸エ
ステルが可溶化能が優れていることが判明した。ここで
いうポリグリセリン脂肪酸エステルとは、グルセリンの
重合度が2以上の、好ましくは重合度が10のポリオー
ルに脂肪酸が一個以上付加し、さらに脂肪酸の鎖長がC
16以上、好ましくはC18以上のものを意味する。ま
た付加する脂肪酸は不飽和でも飽和でもよい。The inventor of the present invention firstly determined the quality of a dye-solubilized liquid preparation required for transparently coloring aqueous foods such as beverages by measuring the absorbance at the maximum absorption wavelength in the visible part of the aqueous solution of the dye preparation. At 1, the transmittance at 660 nm was set to 95% or more, and a commercially available emulsifier was screened using this as an index. As a result, it was found that the polyglycerin fatty acid ester had excellent solubilizing ability. The polyglycerin fatty acid ester referred to herein means that at least one fatty acid is added to a polyol having a polymerization degree of glycerin of 2 or more, preferably 10 and a chain length of the fatty acid is C
16 or more, preferably C18 or more. The fatty acid to be added may be unsaturated or saturated.
【0009】次いでエステルを用いて最適な添加量並び
に可溶化条件を検討した。その結果、ポリグリセリン脂
肪酸エステルの最適な添加量は2〜30重量%、好まし
くは5〜20重量%であること、可溶化条件は、800
kgf/cm2以上の加圧下において1パス以上、好ま
しくは1000kgf/cm2〜2000kgf/cm
2の加圧下において1パス以上の処理がよいことが判明
した。Next, the optimum amount of addition and the solubilization conditions were examined using an ester. As a result, the optimal addition amount of the polyglycerin fatty acid ester is 2 to 30% by weight, preferably 5 to 20% by weight, and the solubilization condition is 800
One or more passes under a pressure of at least kgf / cm 2 , preferably 1000 kgf / cm 2 to 2,000 kgf / cm
It was found that one or more passes of the treatment under pressure of 2 were good.
【0010】本発明において、食品用カロチノイド系色
素とポリグリセリン脂肪酸エステルの組成物を微粒子化
処理するのに最も好ましい手段は、高圧ホモジナイザー
を用いることである。ここで使用される高圧ホモジナイ
ザーとは、試料を高圧に、具体的には少なくとも800
kgf/cm2以上加圧可能で、この高圧状態の試料を
狭い間隙より高速に射出、あるいは2方向より対向衝突
させることにより微粒子化可能なものを指す。またここ
で言う1パスとは、ホモジナイザーのインタラクション
チャンバー内を試料が1回通過することを意味する。In the present invention, the most preferable means for subjecting the composition of the carotenoid pigment for food and the polyglycerin fatty acid ester to a fine particle treatment is to use a high-pressure homogenizer. As used herein, a high-pressure homogenizer refers to a high-pressure sample, specifically at least 800
It refers to a material that can be pressurized by kgf / cm 2 or more and that can be made into fine particles by injecting a sample in this high pressure state at a high speed from a narrow gap or by colliding in two directions. The term "one pass" as used herein means that the sample passes once through the interaction chamber of the homogenizer.
【0011】このようにして製造した本発明に係る食品
用カロチノイド系色素可溶化液製剤の水溶液は、その極
大吸収波長での吸光度が1のとき、660nmにおける
透過率が99%以上となる。The aqueous solution of the carotenoid-based dye-solubilizing solution for food according to the present invention thus produced has a transmittance at 660 nm of 99% or more when the absorbance at the maximum absorption wavelength is 1.
【0012】[0012]
【実施例】以下実施例を用いて本発明を詳細に説明す
る。尚、「部」とは特に断りのない限り「重量部」を表
わす。また「%」は特に断りのない限り「重量%」を表
わす。The present invention will be described below in detail with reference to examples. Incidentally, “parts” means “parts by weight” unless otherwise specified. “%” Represents “% by weight” unless otherwise specified.
【0013】比較例1 まず、ポリグリセリン脂肪酸モノエステル(理研ビタミ
ン社製、ポエムJ、n=10モノエステル含量8%)1
0部、D−ソルビトール(サンエイ糖化社製、ソルビッ
トS)70部、トコフェロール(理研ビタミン社製、E
オイル800)1部及び水9部からなる混合物を攪拌式
乳化機(エム・テクニック社製)で攪拌して均一に混合
した。次いで、カロチノイド系の油溶性色素(トウガラ
シ色素あるいはマリーゴールド色素)10部をこれに加
え、さらに10000r.p.m.で1分間攪拌し、可
溶化に用いる可溶化試料とした。Comparative Example 1 First, polyglycerin fatty acid monoester (Poem J, manufactured by Riken Vitamin Co., n = 10, monoester content 8%) 1
0 parts, D-sorbitol (manufactured by Sanei Saccharification Co., 70%), tocopherol (manufactured by Riken Vitamin Co., E
A mixture consisting of 1 part of oil 800) and 9 parts of water was uniformly mixed by stirring with a stirring emulsifier (manufactured by M Technique Co., Ltd.). Next, 10 parts of a carotenoid oil-soluble pigment (capsicum pigment or marigold pigment) was added thereto, and 10,000 r.p. p. m. For 1 minute to obtain a solubilized sample used for solubilization.
【0014】β−カロチンについては、攪拌混合前に加
温溶解する以外はすべて、他の色素と同様の処理をした
ものを試料とした。All samples of β-carotene were treated in the same manner as other dyes except that they were heated and dissolved before stirring and mixing.
【0015】実施例1 比較例1で調製したそれぞれの試料を、高圧ホモジナイ
ザー(APVラニー社製)で1000kgf/cm2の
加圧下で5パス処理し、この結果生成した試料をそれぞ
れA1(トウガラシ色素)、B1(マリーゴールド色
素)及びC1(β−カロチン色素)とした。Example 1 Each sample prepared in Comparative Example 1 was subjected to 5 passes with a high-pressure homogenizer (manufactured by APV Lanney) under a pressure of 1000 kgf / cm 2 , and the resulting samples were each subjected to A1 (capsicum dye). ), B1 (marigold dye) and C1 (β-carotene dye).
【0016】比較例2 比較例1の攪拌時間1分間を30分間に変更する以外は
すべて同じ条件で処理し、生成した試料をそれぞれA2
(トウガラシ色素)、B2(マリーゴールド色素)及び
C2(β−カロチン色素)とした。Comparative Example 2 Except that the stirring time of Comparative Example 1 was changed from 1 minute to 30 minutes, all treatments were carried out under the same conditions.
(Capsicum pigment), B2 (marigold pigment) and C2 (β-carotene pigment).
【0017】比較例3 水系の組成を、D−ソルビトール80部、トコフェロー
ル1部及び水9部とする以外はすべて比較例1と同じ方
法で可溶化試料を調製した。さらにこれを実施例1と同
条件で高圧ホモジナイザー処理し、この結果生成した試
料をそれぞれA3(トウガラシ色素)、B3(マリーゴ
ールド色素)及びC3(β−カロチン色素)とした。Comparative Example 3 A solubilized sample was prepared in the same manner as in Comparative Example 1 except that the composition of the aqueous system was changed to 80 parts of D-sorbitol, 1 part of tocopherol and 9 parts of water. This was further subjected to a high-pressure homogenizer treatment under the same conditions as in Example 1, and the resulting samples were designated as A3 (capsicum pigment), B3 (marigold pigment) and C3 (β-carotene pigment), respectively.
【0018】比較例4 比較例1でポリグリセリン脂肪酸モノエステルの代わり
にキラヤサポニン(丸善製薬社製、キラヤニンC−10
0)を用いる以外はすべて同条件で試料を調製した。さ
らに、これを実施例1と同条件で高圧ホモジナイザー処
理し、この結果生成した試料をそれぞれA4(トウガラ
シ色素)、B4(マリーゴールド色素)及びC4(β−
カロチン色素)とした。Comparative Example 4 In Comparative Example 1, instead of the polyglycerin fatty acid monoester, kirayasaponin (Kirayanin C-10, manufactured by Maruzen Pharmaceutical Co., Ltd.) was used.
Samples were prepared under the same conditions except that 0) was used. Further, this was subjected to a high-pressure homogenizer treatment under the same conditions as in Example 1, and the resulting samples were A4 (capsicum dye), B4 (marigold dye) and C4 (β-β-
Carotene pigment).
【0019】試料A1〜A4、B1〜B4及びC1〜C
4について、それぞれ可視部の極大吸収波長における吸
光度を1の水溶液とした後、660nmにおける透過率
を測定した。結果を表1に示す。Samples A1 to A4, B1 to B4 and C1 to C
For each of Sample No. 4, the absorbance at the maximum absorption wavelength in the visible region was set to an aqueous solution, and then the transmittance at 660 nm was measured. Table 1 shows the results.
【0020】[0020]
【表1】 [Table 1]
【0021】この結果から、高圧ホモジナイザー処理の
みでは透過率は上がらず、透過率を上げるためにはポリ
グリセリン脂肪酸エステル存在下、高圧ホモジナイザー
処理が必要であることが明らかになった。一方、ポリグ
リセリン脂肪酸エステルをキラヤサポニンに代えても透
過率は低かった。From these results, it was clarified that the transmittance was not increased only by the high-pressure homogenizer treatment, and it was necessary to perform the high-pressure homogenizer treatment in the presence of the polyglycerol fatty acid ester in order to increase the transmittance. On the other hand, even if the polyglycerin fatty acid ester was replaced with Kirayasaponin, the transmittance was low.
【0022】透過率の値は、具体的にはA1とA2、B
1とB2あるいはC1とC2とでは、それぞれ10倍前
後の透明度の差があることを意味する。The values of the transmittance are specifically A1, A2, B
1 and B2 or C1 and C2 mean that there is a transparency difference of about 10 times.
【0023】実施例3 飲料の着色について実験した。下記処方で模擬飲料を調
製した後、それぞれ300ml容量の飲料用ガラス瓶に
300mlずつ分注し、80℃で30分間加熱した。冷
却後、室温中に放置し、経時的に透明性およびリング発
生を観察した。その結果を表3に示す。リング発生は可
溶化状態が壊れたことを意味する。Example 3 An experiment was conducted on the coloring of a beverage. After preparing a simulated beverage according to the following formulation, 300 ml was dispensed into a 300 ml glass bottle for beverage, and heated at 80 ° C. for 30 minutes. After cooling, it was allowed to stand at room temperature, and the transparency and generation of rings were observed over time. Table 3 shows the results. Ring formation means that the solubilized state has been broken.
【0024】使用した色素試料は、A1、A2、B1、
B2及びC1、C2である。The dye samples used were A1, A2, B1,
B2 and C1 and C2.
【0025】処方 異性化糖(Brix75.5%):16.00% クエン酸 : 0.30% アスコルビン酸 : 0.10% 色素試料 : 0.02% 水 :83.58% pH2.5 計 100.00%Formulation Isomerized sugar (Brix 75.5%): 16.00% Citric acid: 0.30% Ascorbic acid: 0.10% Pigment sample: 0.02% Water: 83.58% pH 2.5 Total 100 0.00%
【0026】[0026]
【表3】 [Table 3]
【0027】この結果より、本発明の可溶化液製剤はS
AIBの酸性飲料中においても非常に安定なことが明ら
かである。From these results, it can be seen that the solubilized liquid preparation of the present invention
It is clear that AIB is very stable even in acidic beverages.
【0028】実施例4 ゼリーの着色について実験した。下記処方にてゼリーを
調製した後、目視で透明性を評価した。結果を表4に示
す。Example 4 An experiment was conducted on the coloring of jelly. After preparing a jelly according to the following formulation, the transparency was visually evaluated. Table 4 shows the results.
【0029】使用した色素試料は、A1、A2、B1、
B2及びC1、C2である。The dye samples used were A1, A2, B1,
B2 and C1 and C2.
【0030】処方 ゲルメイト(大日本製薬株式会社): 0.90% 液糖 :13.00% 砂糖 : 3.00% クエン酸 : 0.12% クエン酸ナトリウム : 0.09% 色素製剤 : 0.02% 水 :82.87% pH4.0 計 100.00%Formulation Gelmate (Dainippon Pharmaceutical Co., Ltd.): 0.90% Liquid sugar: 13.00% Sugar: 3.00% Citric acid: 0.12% Sodium citrate: 0.09% Pigment preparation: 02% water: 82.87% pH 4.0 Total 100.00%
【0031】[0031]
【表4】 [Table 4]
【0032】この結果より、本発明の可溶化液製剤はゼ
リーを透明に着色可能なことが判明した。From these results, it was found that the solubilized liquid preparation of the present invention can color jelly transparently.
【0033】[0033]
1.本発明の食品用カロチノイド系色素可溶化液製剤
は、極めて透明度が高く、水溶液中において安定であ
る。1. The carotenoid dye solubilized liquid preparation for food of the present invention has extremely high transparency and is stable in an aqueous solution.
【0034】2.本発明の食品用カロチノイド系色素可
溶化液製剤を用いれば、飲料、ゼリー、冷菓など水性食
品を比重調整剤なしで透明かつ安定に着色できる。2. By using the carotenoid-based dye-solubilized liquid preparation of the present invention, aqueous foods such as beverages, jellies, and frozen desserts can be transparently and stably colored without a specific gravity adjusting agent.
【0035】3.比重調整剤を用いるまでもなく、透明
かつ安定に着色された飲料、ゼリー、冷菓など水性食品
を提供できる。3. It is possible to provide transparent and stably colored aqueous foods such as beverages, jellies, and frozen desserts without using a specific gravity adjuster.
Claims (5)
ン脂肪酸エステルの組成物が微粒子化され、その可視部
の極大吸収波長での吸光度が1のとき、660nmにお
ける透過率が99%以上であることを特徴とする食品用
カロチノイド系色素可溶化液製剤。1. A composition comprising a food-grade carotenoid pigment and a polyglycerol fatty acid ester, wherein the composition is finely divided and the transmittance at 660 nm is 99% or more when the absorbance at the maximum absorption wavelength in the visible region is 1. Characterized food carotenoid dye solubilized liquid preparation.
セリン脂肪酸エステルを5重量%以上含有する請求項1
記載の食品用カロチノイド系色素可溶化液製剤。2. The polyglycerin fatty acid ester contains at least 5% by weight of decaglycerin fatty acid ester.
A food carotenoid pigment solubilized liquid preparation as described in the above.
ン脂肪酸エステルの組成物に高圧ホモジナイザーを作用
させることを特徴とする食品用カロチノイド系色素可溶
化液製剤の製造法。3. A method for producing a carotenoid dye solubilized liquid preparation for food, which comprises applying a high-pressure homogenizer to a composition of a carotenoid dye for food and a polyglycerin fatty acid ester.
セリン脂肪酸エステルを5重量%以上含有する請求項3
記載の食品用カロチノイド系色素可溶化液製剤の製造
法。4. The polyglycerin fatty acid ester contains at least 5% by weight of decaglycerin fatty acid ester.
A method for producing a food carotenoid-based dye-solubilized liquid preparation according to the above.
ン脂肪酸エステルの組成物が微粒子化され、その可視部
の極大吸収波長での吸光度が1のとき、660nmにお
ける透過率が99%以上である食品用カロチノイド系色
素可溶化液製剤を含有することを特徴とする水性食品。5. A composition comprising a carotenoid pigment for food and a polyglycerol fatty acid ester in the form of fine particles, wherein the transmittance at 660 nm is 99% or more when the absorbance at the maximum absorption wavelength in the visible region is 1. An aqueous food product comprising a carotenoid dye solubilized liquid preparation.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP8298191A JPH10120933A (en) | 1996-10-22 | 1996-10-22 | Carotenoid-based pigment solubilized liquid preparation for food, its production and aqueous food using the same preparation |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP8298191A JPH10120933A (en) | 1996-10-22 | 1996-10-22 | Carotenoid-based pigment solubilized liquid preparation for food, its production and aqueous food using the same preparation |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH10120933A true JPH10120933A (en) | 1998-05-12 |
Family
ID=17856402
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP8298191A Withdrawn JPH10120933A (en) | 1996-10-22 | 1996-10-22 | Carotenoid-based pigment solubilized liquid preparation for food, its production and aqueous food using the same preparation |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH10120933A (en) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0848913A2 (en) * | 1996-12-20 | 1998-06-24 | Basf Aktiengesellschaft | Use of carotenoid solubisate for colouring foodstuffs and pharmaceutical preparations |
JP2007277471A (en) * | 2006-04-11 | 2007-10-25 | Taisho Technos Co Ltd | Annatto pigment preparation |
JP2008143841A (en) * | 2006-12-11 | 2008-06-26 | Taiyo Kagaku Co Ltd | Composition containing highly crystalline substance |
JP2009189335A (en) * | 2008-02-18 | 2009-08-27 | Sanei Gen Ffi Inc | Carotenoid-containing emulsion composition and method for producing the same |
WO2010084789A1 (en) | 2009-01-20 | 2010-07-29 | 富士フイルム株式会社 | Emulsion composition, and food and cosmetic each containing the emulsion composition |
WO2011145659A1 (en) | 2010-05-18 | 2011-11-24 | 富士フイルム株式会社 | Carotenoid-containing composition and production method therefor |
WO2013073620A1 (en) | 2011-11-18 | 2013-05-23 | 富士フイルム株式会社 | Carotenoid-containing composition and method for producing same |
WO2014051115A1 (en) | 2012-09-28 | 2014-04-03 | 富士フイルム株式会社 | Carotenoid-containing oil-in-water emulsion composition |
US9345250B2 (en) | 2006-09-20 | 2016-05-24 | Tsuji Oil Mill Co., Ltd. | Method for preparing solubilized composition containing oil-soluble substance |
WO2021230353A1 (en) * | 2020-05-15 | 2021-11-18 | 三栄源エフ・エフ・アイ株式会社 | Paprika emulsified dye preparation and method for producing same |
-
1996
- 1996-10-22 JP JP8298191A patent/JPH10120933A/en not_active Withdrawn
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0848913A3 (en) * | 1996-12-20 | 1999-01-13 | Basf Aktiengesellschaft | Use of carotenoid solubisate for colouring foodstuffs and pharmaceutical preparations |
US6287615B1 (en) | 1996-12-20 | 2001-09-11 | Basf Aktiengesellschaft | Use of solubilized carotenoid preparations for coloring food preparations |
EP0848913A2 (en) * | 1996-12-20 | 1998-06-24 | Basf Aktiengesellschaft | Use of carotenoid solubisate for colouring foodstuffs and pharmaceutical preparations |
JP2007277471A (en) * | 2006-04-11 | 2007-10-25 | Taisho Technos Co Ltd | Annatto pigment preparation |
US9345250B2 (en) | 2006-09-20 | 2016-05-24 | Tsuji Oil Mill Co., Ltd. | Method for preparing solubilized composition containing oil-soluble substance |
JP2008143841A (en) * | 2006-12-11 | 2008-06-26 | Taiyo Kagaku Co Ltd | Composition containing highly crystalline substance |
JP2009189335A (en) * | 2008-02-18 | 2009-08-27 | Sanei Gen Ffi Inc | Carotenoid-containing emulsion composition and method for producing the same |
WO2010084789A1 (en) | 2009-01-20 | 2010-07-29 | 富士フイルム株式会社 | Emulsion composition, and food and cosmetic each containing the emulsion composition |
WO2011145659A1 (en) | 2010-05-18 | 2011-11-24 | 富士フイルム株式会社 | Carotenoid-containing composition and production method therefor |
WO2013073620A1 (en) | 2011-11-18 | 2013-05-23 | 富士フイルム株式会社 | Carotenoid-containing composition and method for producing same |
US9993010B2 (en) | 2011-11-18 | 2018-06-12 | Fujifilm Corporation | Carotenoid-containing composition and method for producing same |
WO2014051115A1 (en) | 2012-09-28 | 2014-04-03 | 富士フイルム株式会社 | Carotenoid-containing oil-in-water emulsion composition |
WO2021230353A1 (en) * | 2020-05-15 | 2021-11-18 | 三栄源エフ・エフ・アイ株式会社 | Paprika emulsified dye preparation and method for producing same |
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