JPH0947215A - Insect pest attraction-inhibiting material - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain an injurious insect attraction-inhibiting material having a light transmittance for a specific wave length by allowing to contain a specific finely pulverized pigment in a base material. SOLUTION: This injurious insect attraction-inhibiting material contains synthetic resin color chips, which contain yellow, orange, blue and black pigments finely ground to be optically transparent, and a UV absorber in a base material and has <=10% light transmittance at 200-420nm wave length, <=30% light transmittance at 420-480nm wave length and 20-50% light transmittance at <=480nm wave length. As the base material, a pipe-like film made of a heat absorbing synthetic resin and a synthetic resin adhesive are cited.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a pest attracting and blocking material for blocking pests from actively flying due to light, by blocking the transmission of light having a wavelength to which pests are sensitive to the outside. The present invention relates to molded products such as sheets and films having a blocking function.

[0002]

2. Description of the Related Art It is already known that insects have a phototaxis that comes into contact with light stimuli, and the wavelength characteristic of the phototaxis of insects is 200 to 600 nm centered at 360 to 380 nm. There are many things that are sensitive to. Therefore, a sheet or the like has been proposed that suppresses the light transmittance of the wavelength at which insects have a functional property. As such a seat, it is special fair 4
A sheet described in "-65651" Insect repellent method using synthetic resin sheet and synthetic resin sheet as partition material "is known. This type of sheet substantially blocks light having a wavelength of 380 nm or less, and has a light transmittance of 400% to 480 nm or more and 30% or less, and a light transmittance of 520 nm or more to 50%.
% Or more, it is a sheet characterized by not substantially blocking the transmission of light having a wavelength of 580 nm or more. In order to ensure human visibility while having an insect repellent effect, a sheet of 400- It was thought that it was necessary to set the light transmittance of the wavelength of 480 nm to 30% or less and further set the light transmittance of the wavelength of 520 nm or more to 50% or more. As a similar blocking material, a blocking material described in Japanese Patent Laid-Open No. 63-133933 "Pest Induction Blocking Material" is known. This type of blocking material contains at least yellow and black dyes and has a wavelength of 200-50.
A dye was selected as a light-shielding material that is a synthetic resin and exhibits an insect-repellent effect, which is characterized by selectively absorbing 0 nm light and shielding it so that the transmittance becomes 50% or less.

[0003]

As can be seen from the above-mentioned prior art, since it is advantageous to provide a transparent film, it is advantageous to use a dye that dissolves in a molecular state in order to develop optical properties. The reality is that we had to use dyes, even though we understood that they did not have good light resistance. It is a fact that even though it was understood that the use of a microcrystalline pigment had better light resistance, it was difficult to finely disperse it in the same manner as a dye, so that it was not adopted.
Also, even if something that is macroscopically transparent is obtained from the pigment, there is a concern that microscopically there will be gaps between the crystal particles and the insects may be sensitive to the light coming from the gaps. It was also true that they were avoiding hiring. Accordingly, there has been a demand for a pigment system having high light resistance, which is finely dispersed until it is optically transparent, and which has an efficient insect pest-inhibiting function. The present inventors paid attention to this point and found that even an opaque pigment system can be transparent if finely dispersed, and if transparent, a considerable effect can be exhibited even if the pigment is not dispersed in a molecular state. The wavelength range is also 480
Many insects are sensitive to around 600 nm, and a sheet with a light transmittance of 520 nm or more of 50% or more also has some insect repellent effect, but a light transmittance of 480 nm or more does not hinder human vision (light transmission). It has been found that the insect repellent effect is further enhanced by adjusting the ratio (20 to 50%).

[0004]

SUMMARY OF THE INVENTION That is, the present invention provides a finely dispersed yellow, orange, and blue, optically transparent,
In a synthetic resin-pigment-ultraviolet absorbent composition composed of a synthetic resin chip (color chip) containing a black pigment alone or in combination, and an ultraviolet absorber, and a base material, it is an optical property of the composition. Light transmittance of 200 to 4
20 nm is set to 10% or less, 420 to 480 nm is set to 30% or less, and light having a wavelength of 480 nm or more is adjusted to be about 20 to 50% so as not to impair human visibility. The present invention provides a pest attracting and blocking material containing the composition as a main component.

[0005]

BEST MODE FOR CARRYING OUT THE INVENTION More specifically, 400-
Yellow and orange pigments are mainly used as pigments that absorb light with a wavelength of 500 nm. It is preferable in terms of dispersibility, transparency and light resistance. Pigments that absorb light with a wavelength of 500 nm or more are mainly blue and black pigments such as phthalocyanine cyanine blue 4940N (manufactured by Dainichiseika Co., Ltd.) and carbon black F.
W-2 (manufactured by Degussa) is used. 200-400 nm
Hydroquinone, which absorbs light of the wavelength
Known ultraviolet absorbers such as salicylic acid type, benzophenone type, and benzotriazole type are used. In order to make the spectrum of transmitted light that is the object of the present invention into a spectrum for being a light that does not look like a pest, a fine test is performed as described above so that the transmission spectrum of the structures involved meets the corresponding requirements. It is necessary to determine the actual pigment content. The amount of transmitted light varies depending on the thickness even with the same content, and the spectra of pigments also differ, so it will be decided by blending these while conducting a transmitted light test.

Thermoplastic resins such as vinyl chloride, vinyl acetate, polyester, polyethylene, acryl, and nitrified cotton are used as the constituent resin in the synthetic resin chip.
A flushing method or a kneading method using a dry pigment and a two-roll kneading method is used for producing an optically finely dispersed synthetic resin chip. In particular, a color chip obtained by the two-roll method has high transparency and dispersibility. preferable. The flushing method is a method of substituting the oil phase pigment generated in the form of fine particles with an oil phase pigment without drying, and the two-roll kneading method is a method of mixing powder pigment with resin and a small amount of solvent or plasticizer. The added product is kneaded into a sheet while heating the rolls with a powerful two-roll mill capable of adjusting the gap (Nip) between the rolls, and the pigment elementary particles that have aggregated due to the shear stress due to the difference in the rotation speed of the rolls are added. It is a method of dispersing in fine particles.

There is no limitation on the composition for obtaining the color chip, but in general, the range of 10 to 90% is preferable in terms of the pigment content (PWC) in the finished chip. For an inorganic pigment, it is preferably close to 90%, and for an organic pigment, it is preferably 60% or less. For the purpose of the present application, it is preferable to select an organic pigment in terms of optical transparency. In order to finely disperse with the above PWC, it is necessary to wet the surface of the pigment and to plasticize the resin component to be used. For this purpose, an organic solvent and a plasticizer are used. For example, any organic solvent may be used as long as it dissolves the resin component. Esters such as ethyl acetate and butyl acetate, alcohols such as isopropyl alcohol, and aromatic solvents such as toluene and xylene are 20% or less in the external ratio. used. These solvents are hardly contained in the chips after fine dispersion. As the plasticizer used for the same purpose, a phthalic acid ester, a monofunctional epoxy compound (for example, an epoxidized product of unsaturated fatty acid), an amine acid or the like is used. The amount used of these is still about 20% or less in the external ratio, but they remain in the chip. A pigment dispersant can also be used. The pigment dispersant should be selected by trial and error depending on the pigment and the resin, and typical examples thereof include metal salts of fatty acids such as copper oleate, amine acid derivatives such as lecithin and amphoteric compounds, or para compounds. Examples thereof include amino derivatives such as phenylenediamine, and polymer compounds having the above-mentioned functional groups as pendants.

As the synthetic resin in the composition, vinyl chloride, vinyl acetate, an acrylic resin, a synthetic resin capable of exhibiting a shrink function after molding, that is, a polyethylene terephthalate resin giving a heat-shrinkable film, etc. are used. The pest attracting and blocking material may be produced by any method such as a usual melt extrusion method, coater method, calender method and the like. The invention product of the present invention whose wavelength is adjusted by the above materials and means has high optical transparency, excellent light resistance, and high insect repellent effect.

[0009]

EXAMPLES The present invention will be described in more detail below with reference to examples, including comparative examples. Example-1 Synthetic resin chip Shinkasha Gold YT-823D (orange pigment) 40% by weight Cyanine Blue 494ON (blue pigment) 5% 〃 Byron 200 (saturated copolyester) 55% 〃 organic solvent 10% 〃 or above composition The sheet was made into a sheet with two rolls heated at 1 and the sheet was repeated 100 times on the roll, and this was crushed to obtain a synthetic resin chip. Next, a synthetic resin chip (1.0 part by weight) and an ultraviolet absorber (0.4 parts by weight) were added to 100 parts by weight of the heat-shrinkable polyethylene resin, and a 0.1 mm thick yellow-green shrink function was obtained by a normal melt extrusion method. A polyethylene terephthalate heat shrink tube was produced. The tube was covered with a fluorescent lamp and heated at 120 ° C. for 1 minute to cover it. This is used as a fluorescent lamp having a scattering prevention and insect repellent function by being installed inside, outside, entrances, etc. of buildings such as factories and restaurants.

Example-2 Synthetic resin chip Shinkasha Gold YT-823D (orange pigment) 22.5% by weight Carbon black FW-2 (black pigment) 7.5% 〃 Nitrified cotton RS1 / 2 (resin) 55. 0% 〃 dibutyl phthalate (plasticizer) 15.0% 〃 organic solvent 20.0% 〃 Using the above composition, make a sheet with two rolls, repeat the sheet 100 times, and crush it to make synthetic resin chips. . The synthetic resin chip was dissolved with stirring with the mixture of 2), a polyester film was coated with a bar coater to a thickness of 20 μm, and a release film was attached to this to prepare a brown-colored film having an adhesive function. This is used by peeling off a release film as a film having an insect repellent function and sticking it to a transparent window glass, an acrylic plate or the like of a building such as a factory or a restaurant.

Example-3 Synthetic resin chip Shinkasha Gold YT-823D (orange pigment) 40% by weight Cyanine blue 494ON (blue pigment) 5% VYHH (vinyl chloride vinyl acetate copolymer resin) 55% 〃 organic solvent 10 % It was made into a sheet with two rolls heated with the composition above, the sheet was repeated 100 times on the roll, and this was crushed to obtain a synthetic resin chip. Next, polyvinyl chloride resin 100
50 parts by weight of plasticizer, 0.0 parts by weight of synthetic resin chip
8 parts by weight and 0.03 parts by weight of an ultraviolet absorber were contained, and a yellow-green sheet having a pressure of 2.0 mm was prepared by a usual extrusion method or calendering method. This is used as a sheet having an insect repellent function for partitioning buildings such as factories, or cut into strips to be used as a curtain.

Example 4 To 100 parts by weight of polyvinyl chloride resin, 50 parts by weight of a plasticizer, 0.5 parts by weight of the synthetic resin chip in Example 3 and 0.2 parts by weight of an ultraviolet absorber were added. A 0.3 mm thick yellow-green sheet having an insect repellent function was prepared by an extrusion method or a calendar method. This sheet was heat-fused from both sides of a polyester fiber woven fabric having a density of 3 × 3 fibers / cm, and a 0.6 mm-thick base fabric was processed into a strong sheet. This sheet is attached to a shutter of a building such as a factory and is used as a sheet shutter sheet having a visual insect repellent function.

Example-5 Synthetic resin chip Shinkasha Gold YT-823D (orange pigment) 40% by weight Cyanine blue 494ON (blue pigment) 5% VAGH (vinyl chloride vinyl acetate copolymer resin) 55% 〃 organic solvent 10 The sheet was made into a sheet by using two rolls heated with a composition of not less than%, and the sheet was repeated 100 times and crushed to obtain a synthetic resin chip. The synthetic resin chip was dissolved with stirring with the mixture of 1), and the polyester film was coated with a bar coater to a thickness of 15 μm and dried. After drying, an acrylic pressure-sensitive adhesive was further coated thereon, and a release film was attached to this to form a film having a green color adhesive function. This is used by peeling off a release film as a film having an insect repellent function and sticking it to a transparent window glass, an acrylic plate or the like of a building such as a factory or a restaurant.

Comparative Example-1 Synthetic resin chip Shinkasha First Gold YT-915D (yellow pigment) 40% by weight Byron 200 (saturated copolyester) 60% 〃 organic solvent 10% 〃 Two heated with the above composition The sheet was made into a roll and the sheet was repeated 100 times and crushed to obtain a synthetic resin chip. Next, with respect to 100 parts by weight of the heat-shrinkable polyethylene terephthalate resin, the synthetic resin chip 1.
A yellow-colored tube having a thickness of 0.1 mm was prepared by the usual melt extrusion method with 2 parts by weight and 0.4 parts by weight of an ultraviolet absorber being contained. This was covered with a fluorescent lamp and heated at 120 ° C. for 1 minute to cover it.

Comparative Example-2 Zapon Yellow 073 (yellow dye) 0.32% by weight Valiosol Black 3808T (black dye) 0.48% 〃 Acrylic resin 23.8% 〃 UV absorber 0.5% 〃 Organic solvent 74.9% 〃 The above composition was coated on a polyester film with a bar coater to a thickness of 20 µm to form a yellow-green film. When the light transmittances of the compositions shown in Examples 1 to 5 and Comparative Examples 1 and 2 were measured, the results were as shown in FIGS. 1 to 7,
The wavelengths of 200 to 420 nm are 10% in the examples 1 to 5
Below, 420-480nm is 30% or less, further 48
It can be seen that the wavelength of 0 nm or more is about 20 to 50%. It is also highly transparent and sufficient for ensuring human visibility. Next, these compositions were irradiated with a mercury lamp type discoloration tester for 100 hours, and the light transmittances before and after irradiation were measured. In addition, a test was performed for the insect repellent effect. Example 1
The results of No. 5 and Comparative Examples 1 and 2 are shown in Table 1.

[0016]

[Table 1]

Insect repellent test method The test pieces of Examples 1 to 5 and Comparative Examples 1 and 2 in which the periphery of a 10 W white fluorescent lamp was fixed and 15 kinds of 10 W white fluorescent lamps as blanks were linearly spaced at 5 m intervals. Flying insects attracted to the fluorescent lamps were arranged and captured by the adhesive sheets attached to the left and right sides of the fluorescent lamps during 30 minutes of lighting at night, and the attraction inhibition rate was determined to compare the insecticidal performance. The test is the result of the sum total repeated three times while changing the position of the illuminator. The experimental lighting device is shown in FIG. Each of the present inventions shows an excellent attraction blocking rate.

[0018]

INDUSTRIAL APPLICABILITY As described above, the present invention contributes to the living environment by effectively suppressing the attractiveness of pests for a long period of time without substantially damaging the living environment, without the secondary harmful effects of drugs and the like. It is extremely useful because it can.

[Brief description of drawings]

1 shows the light transmittance of the tube of Example 1. FIG.

FIG. 2 shows the light transmittance of the film of Example 2.

FIG. 3 shows the light transmittance of the sheet of Example 3.

FIG. 4 shows the light transmittance of the sheet of Example 4.

FIG. 5 shows the light transmittance of the film of Example 5.

FIG. 6 shows the light transmittance of the tube of Comparative Example 1.

FIG. 7 shows the light transmittance of the film of Comparative Example 2.

FIG. 8 shows an outline of an insect repellent experimental device.

Claims (5)

[Claims] 1. A yellow, which is finely ground to be optically transparent,
A synthetic resin color chip whose main component is one or more pigments selected from the group consisting of orange, blue and black pigments, and an ultraviolet absorber in the base material.
An insect pest blocking material having a light transmittance of 0% or less, 30% or less at a wavelength of 420 to 480 nm and 20 to 50% at a wavelength of 480 nm or more. 2. The pest attraction inhibiting material according to claim 1, wherein the synthetic resin color chip is obtained from a flushing method or a dry pigment by kneading and a two-roll kneading method. 3. The pest attracting and blocking material according to claim 1, wherein the base material is a tubular film of heat-shrinkable synthetic resin for coating phosphors. 4. The pest attracting and blocking material according to claim 3, wherein the film is made of polyethylene terephthalate resin. 5. The base material is a synthetic resin adhesive.
The pest attraction prevention material described.