JPH09327881A - High brightness reflective transfer foil which can be used as stamping foil, etc. - Google Patents

High brightness reflective transfer foil which can be used as stamping foil, etc.

Info

Publication number
JPH09327881A
JPH09327881A JP16819096A JP16819096A JPH09327881A JP H09327881 A JPH09327881 A JP H09327881A JP 16819096 A JP16819096 A JP 16819096A JP 16819096 A JP16819096 A JP 16819096A JP H09327881 A JPH09327881 A JP H09327881A
Authority
JP
Japan
Prior art keywords
layer
glass beads
film
laminate
foil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP16819096A
Other languages
Japanese (ja)
Inventor
Isao Yanagisawa
柳沢勇雄
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DAIRIKI KK
ROBIYUU KK
Original Assignee
DAIRIKI KK
ROBIYUU KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DAIRIKI KK, ROBIYUU KK filed Critical DAIRIKI KK
Priority to JP16819096A priority Critical patent/JPH09327881A/en
Publication of JPH09327881A publication Critical patent/JPH09327881A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00Glass compositions
    • C03C3/04Glass compositions containing silica
    • C03C3/062Glass compositions containing silica with less than 40% silica by weight
    • C03C3/064Glass compositions containing silica with less than 40% silica by weight containing boron

Abstract

PROBLEM TO BE SOLVED: To provide transfer foil which uses glass beads, can be used as stamping foil, and has a good high brightness reflection function. SOLUTION: A transfer foil is composed of a laminate of 70-200μm in total thickness in which a single layer of glass beads 3 is embedded in a thin resin film 2 on a thin metal film 1, and a thermoplastic resin layer 4, an adhesive layer 5, and a film having a mold release surface 7 on the surface are laminated in sequence on the glass beads 3. By bonding the thin metal film layer of the laminate to a material to be transferred, a transfer pattern having a high brightness reflection function with the glass beads 3 exposed on the surface can be obtained. The laminate of a thin layer can be produced stably by arranging the mold release surface 7 to be positioned on a thick backing film 9 through the adhesive layer 8.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は、衣料や靴、袋物等
に所望に応じて、容易に、高輝性反射機能を有する模様
を転写可能な転写箔に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a transfer foil capable of easily transferring a pattern having a high-brightness reflecting function to clothes, shoes, bags and the like as desired.

【0002】[0002]

【従来の技術】交通標識や衣服等に透明なガラスビーズ
を使用した塗料を用いて、再帰反射性塗膜を形成するこ
とは、古くから実施されている。しかし、かかる塗料で
は、ガラスビーズが塗料と一体化された状態で使用され
るため、性能のよい再帰反射性塗膜を得ることは困難で
あり、また、繊細な模様状に塗膜を形成することも困難
であった。
2. Description of the Related Art It has long been practiced to form a retroreflective coating film on a traffic sign, clothes, etc. using a coating material using transparent glass beads. However, in such a paint, it is difficult to obtain a retroreflective coating film with good performance because the glass beads are used in a state of being integrated with the paint, and the coating film is formed into a delicate pattern. It was also difficult.

【0003】そこで、ガラスビーズを使用した高輝性反
射機能を有する層をシート上に設け、該積層シートを裁
断して、布帛等に貼着又は縫製して使用することが、実
施されているが、かかる方法では、該積層シートが厚く
なるため、表現できる図柄に限度があり、また、風合の
よい製品を得ることはできなかった。
Therefore, it has been practiced to provide a layer having a highly bright reflecting function using glass beads on a sheet, cut the laminated sheet, and stick or sew it on a cloth or the like for use. In this method, since the laminated sheet becomes thick, there are limits to the designs that can be expressed, and a product with a good texture could not be obtained.

【0004】[0004]

【発明が解決しようとする課題】そこで、ガラスビーズ
を使用した転写箔を形成し、スタンピング法等で、高輝
性反射機能を有する模様を転写可能な転写箔を提供する
ことが考えられるが、ガラスビーズの層を安定して形成
するためには、比較的厚い基材を使用する必要があり、
また、良好な反射を得るためには、ガラスビーズの輪郭
に沿って金属薄層を均一に形成する必要があるため、従
来の転写箔の製造方法では、実用性あるものを得ること
はできなかった。
Therefore, it is conceivable to form a transfer foil using glass beads and provide a transfer foil capable of transferring a pattern having a highly bright reflection function by a stamping method or the like. In order to form a bead layer stably, it is necessary to use a relatively thick substrate,
Further, in order to obtain good reflection, it is necessary to uniformly form a thin metal layer along the contour of the glass beads, so that a conventional transfer foil manufacturing method cannot obtain a practical one. It was

【0005】本発明は、このような従来技術の問題点を
解決し、ガラスビーズを使用して、スタンピングホイル
としても使用できる、薄層で、しかも高輝性反射機能に
優れる、扱い易い転写箔を提供することを課題とする。
The present invention solves the above problems of the prior art, and uses glass beads to provide a transfer foil having a thin layer and excellent in high-brightness reflecting function, which can be used also as a stamping foil. The challenge is to provide.

【0006】[0006]

【課題を解決するための手段】本発明では、基材フィル
ム上に剥離可能な状態で、高輝性反射ある転写箔を形成
することにより、上記課題を解決した。
SUMMARY OF THE INVENTION In the present invention, the above-mentioned problems are solved by forming a transfer foil having high-glossy reflection on a base film in a peelable state.

【0007】即ち、本発明の転写箔は、金属薄膜層上に
樹脂薄膜を介してガラスビーズが単層状に埋め込まれて
おり、該ガラスビーズ上に熱可塑性樹脂層、接着剤層及
び表面に離型面を有するフィルムが順次積層されてい
る、全体の厚さが70〜200μmである積層物からな
るものである。
That is, in the transfer foil of the present invention, glass beads are embedded in a single layer on the metal thin film layer via the resin thin film, and the thermoplastic resin layer, the adhesive layer and the surface are separated on the glass beads. It is composed of a laminate in which films having mold surfaces are sequentially laminated and the total thickness is 70 to 200 μm.

【0008】かかる積層物を、直接製造することは、困
難であるが、本発明では、該積層物を、粘着剤層を介し
て、厚手の基材フィルム上に積層することにより、容易
に安定して製造可能としたのである。
Although it is difficult to directly produce such a laminate, in the present invention, by laminating the laminate on a thick base material film via an adhesive layer, it is possible to easily stabilize the laminate. It was possible to manufacture.

【0009】このように、本発明の転写箔は、厚さ70
〜200μmという積層物を転写可能とするものである
が、ガラスビーズを使用して、かかる薄層で、高輝性反
射機能に優れる転写模様を形成できるとは従来全く予想
できなかったことである。本発明では、上記積層物を、
前述の如く、剥離可能な状態で基材フィルム上に形成す
ることにより、繊維製品、金属、木材、紙、樹脂成形品
等の上に、安定して、効率よく、ガラスビーズを使用し
た品質のよい転写模様の形成を可能としたのである。
As described above, the transfer foil of the present invention has a thickness of 70.
Although it is possible to transfer a laminate having a thickness of up to 200 μm, it has hitherto been impossible to predict that a transfer pattern excellent in a high-brightness reflection function can be formed with such a thin layer by using glass beads. In the present invention, the above laminate,
As described above, by forming it on the base material film in a peelable state, it is possible to stably and efficiently use glass beads on textiles, metal, wood, paper, resin molded products, etc. This made it possible to form a good transfer pattern.

【0010】本発明の製品は、基材フィルム上に粘着剤
層を形成し、別に、離型性ある表面を有するフィルムに
接着剤層を介して熱可塑性樹脂層を設けた積層フィルム
を準備し、該積層フィルムの離型面を上記粘着剤層上に
積層し、その後に、表面に露出した熱可塑性樹脂層上に
ガラスビーズを熱圧して埋め込み、次いで、単層状に露
出したガラスビーズ表面(曲面)に樹脂薄膜を形成し、
ガラスビーズの脱落を防止し、その上に、アルミニウム
等の金属を蒸着することにより、容易に得ることができ
る。
The product of the present invention is prepared by preparing a laminated film in which a pressure-sensitive adhesive layer is formed on a base film and a thermoplastic resin layer is provided on a film having a releasable surface via an adhesive layer. , The release surface of the laminated film is laminated on the pressure-sensitive adhesive layer, and then glass beads are embedded by thermocompression on the thermoplastic resin layer exposed on the surface, and then the glass bead surface exposed as a single layer ( Form a resin thin film on the curved surface,
It can be easily obtained by preventing the glass beads from falling off and depositing a metal such as aluminum on the glass beads.

【0011】かかる製品は、被転写物表面に所望の模様
状に熱可塑性樹脂からなる接着剤を印捺し、その上に
(上記粘着剤層から剥離した)積層物の金属薄膜層の面
を置き、加熱加圧することによって、上記接着剤の存在
する部分のみ、上記積層物の金属薄膜層\樹脂薄膜\ガ
ラスビーズからなる高輝性反射機能を有する箔状物を転
写し、残りの部分は、ガラスビーズ上の熱可塑性樹脂層
\接着剤層\フィルムと共に除去できるものである。従
って、本発明では、どのような模様であっても、非常に
効率よく、精度よく、高輝性反射機能ある転写柄として
再現できるのである。
In such a product, an adhesive made of a thermoplastic resin is printed in a desired pattern on the surface of an object to be transferred, and the surface of the metal thin film layer of the laminate (peeled from the adhesive layer) is placed thereon. By applying heat and pressure, a foil-like material having a high-brightness reflecting function, which is composed of the metal thin film layer / resin thin film / glass beads of the laminate, is transferred only to the part where the adhesive is present, and the remaining part is made of glass. It can be removed together with the thermoplastic resin layer \ adhesive layer \ film on the beads. Therefore, in the present invention, any pattern can be reproduced very efficiently and accurately as a transfer pattern having a high-brightness reflection function.

【0012】なお、転写用の接着剤は、本発明の転写箔
すなわち上記積層物の金属薄膜層上に印捺されてもよ
い。
The transfer adhesive may be printed on the transfer foil of the present invention, that is, on the metal thin film layer of the laminate.

【0013】基材フィルム及び粘着剤の種類及び厚さ
は、特に限定されないが、離型面を有するフィルムとし
ては、表面にシリコン層等の離型剤を施した薄層フィル
ム(厚さ16〜38μm)を使用するのが好ましく、こ
れに接着剤層を介して積層される熱可塑性樹脂層は、ガ
ラスビーズを加熱加圧により埋め込んで貼着できるもの
であればよく、一般的な熱可塑性樹脂がいずれも使用可
能であるが、その厚さは、ガラスビーズを一部曲面を露
出した状態で埋め込んで貼着できるように、ガラスビー
ズの径の1/3〜2/3程度であるのが好ましい。通
常、25〜40μm程度に形成されるのがよい。
The type and thickness of the base film and the pressure-sensitive adhesive are not particularly limited, but as a film having a release surface, a thin film (thickness 16 to 16) having a release agent such as a silicon layer on the surface is used. 38 μm) is preferably used, and the thermoplastic resin layer laminated via an adhesive layer may be any that can be embedded by adhering glass beads by heating and pressurization, and is a general thermoplastic resin. Can be used, but the thickness thereof is about 1/3 to 2/3 of the diameter of the glass beads so that the glass beads can be embedded and attached with the curved surface partially exposed. preferable. Usually, it is preferable that the thickness is about 25 to 40 μm.

【0014】なお、上記薄層フィルムに熱可塑性樹脂層
を貼着する接着剤層は、熱可塑性樹脂層の種類に応じて
選ばれればよい。
The adhesive layer for sticking the thermoplastic resin layer to the thin film may be selected according to the type of the thermoplastic resin layer.

【0015】ガラスビーズは通常40〜100μmの径
のものを使用するのが好ましく、その表面に、樹脂薄膜
を介して形成される金属薄膜層は600〜800Å程度
の厚さでよく、通常アルミニウムの蒸着等によって形成
されればよい。
It is preferable to use glass beads having a diameter of 40 to 100 μm, and the metal thin film layer formed on the surface of the glass beads through a resin thin film may have a thickness of about 600 to 800 Å. It may be formed by vapor deposition or the like.

【0016】また、上記樹脂薄膜は、リバースコーター
やコンマコーター等で、数μmの厚さに形成されればよ
い。使用される樹脂は、アクリル系、ポリエステル系、
ポリオレフィン系等のいずれであってもよい。
The resin thin film may be formed by a reverse coater, a comma coater or the like to have a thickness of several μm. The resins used are acrylic, polyester,
It may be of a polyolefin type or the like.

【0017】本発明の転写箔は、全体に70〜200μ
mの厚さ、好ましくは80〜150μmの厚さに形成さ
れればよいが、通常、基材フィルムとして50〜100
μm程度のフィルムを使用するので、基材フィルム及び
粘着剤層を保持した状態の厚さとしては、150〜25
0μm程度に形成される。
The transfer foil of the present invention has a total thickness of 70 to 200 μm.
m, preferably 80 to 150 μm, but usually 50 to 100 as a substrate film.
Since a film having a thickness of about μm is used, the thickness with the base film and the pressure-sensitive adhesive layer held is 150 to 25
The thickness is about 0 μm.

【0018】[0018]

【発明の実施の形態】次に、図面に示す一例に従って、
本発明を更に詳しく説明する。図1Aの転写箔は、厚さ
75μmのポリエステルフィルムからなる基材フィルム
9上に、粘着剤層8を介して、転写用積層物Xが形成さ
れたものである。表面にシリコン系の離型面7を有する
25μmのポリエステル樹脂フィルム6の裏面にポリイ
ミン系接着剤層5を介してポリエチレンからなる厚さ3
0μmの熱可塑性樹脂層4を積層した積層フィルムの、
離型面7側を上記粘着剤層8に貼着、積層し、その後、
露出した熱可塑性樹脂層4の表面に直径40〜100μ
mのガラスビーズ3を、熱圧して、単層状に埋め込み、
その後、ガラスビーズ3の露出面に、全面にアクリル系
樹脂をリバースコータで塗布し、樹脂薄膜2を形成し、
その上にアルミニウムを蒸着して、厚さ約650Åの金
属薄膜層1を形成した。
BEST MODE FOR CARRYING OUT THE INVENTION Next, according to an example shown in the drawings,
The present invention will be described in more detail. The transfer foil of FIG. 1A has a transfer laminate X formed on a base film 9 made of a polyester film having a thickness of 75 μm via a pressure-sensitive adhesive layer 8. A 25 μm-thick polyester resin film 6 having a silicon-based releasing surface 7 on the front surface, and a thickness 3 made of polyethylene with a polyimine-based adhesive layer 5 interposed therebetween.
Of a laminated film in which a thermoplastic resin layer 4 of 0 μm is laminated,
The release surface 7 side is adhered to and laminated on the pressure-sensitive adhesive layer 8, and then,
The exposed surface of the thermoplastic resin layer 4 has a diameter of 40 to 100 μm.
m glass beads 3 are hot pressed to be embedded in a single layer,
Then, an acrylic resin is applied to the entire exposed surface of the glass beads 3 with a reverse coater to form a resin thin film 2.
Aluminum was vapor-deposited thereon to form a metal thin film layer 1 having a thickness of about 650Å.

【0019】このようにして形成した転写箔は、図1B
〜Dの如く、前記粘着剤層8から積層物Xを剥離し、布
帛等の被転写材10の表面に転写される。例えば、被転
写材10の表面に、熱可塑性のポリアミド系接着剤11
を格子模様の柄状にスクリーン印捺し、その上に、転写
用積層物Xの金属薄膜層1の面を置き、加熱加圧し、冷
却後、転写箔を剥離することにより、樹脂薄膜2を介し
て下面を金属蒸着層1で覆ったガラスビーズ3が厚さ約
100μmの薄い高輝性反射機能ある転写柄として精度
よく格子模様に再現できた。
The transfer foil thus formed is shown in FIG. 1B.
As shown by D, the laminate X is peeled off from the pressure-sensitive adhesive layer 8 and transferred onto the surface of the transfer material 10 such as cloth. For example, on the surface of the transfer material 10, a thermoplastic polyamide adhesive 11
Is screen-printed in a lattice pattern, and the surface of the metal thin film layer 1 of the transfer laminate X is placed thereon, heated and pressed, and after cooling, the transfer foil is peeled off so that the resin thin film 2 is interposed. As a result, the glass beads 3 whose lower surface was covered with the metal vapor deposition layer 1 could be accurately reproduced in a lattice pattern as a thin transfer pattern having a high-brightness reflective function with a thickness of about 100 μm.

【0020】[0020]

【発明の効果】本発明の転写箔は、スタンピング法等
で、容易に、種々の基材に高輝性反射機能ある転写柄を
精度よく再現できるものであり、しかも、転写柄は非常
に薄膜に形成できるので、衣料や靴、袋物等にも、風合
よく、高輝性反射機能ある模様を形成できる。
INDUSTRIAL APPLICABILITY The transfer foil of the present invention can easily and accurately reproduce a transfer pattern having a high brilliant reflection function on various base materials by a stamping method or the like, and the transfer pattern is a very thin film. Since it can be formed, it is possible to form a pattern having a high brilliant and reflective function on clothes, shoes, bags and the like.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の製品の一例の使用状態を示す説明図で
ある。
FIG. 1 is an explanatory diagram showing a usage state of an example of a product of the present invention.

【符号の説明】[Explanation of symbols]

1 金属薄膜層 2 樹脂薄膜 3 ガラスビーズ 4 熱可塑性樹脂層 5 接着剤層 6 フィルム 7 離型面 8 粘着剤層 9 基材フィルム 10 被転写材 11 接着剤 DESCRIPTION OF SYMBOLS 1 Metal thin film layer 2 Resin thin film 3 Glass beads 4 Thermoplastic resin layer 5 Adhesive layer 6 Film 7 Release surface 8 Adhesive layer 9 Base film 10 Transfer material 11 Adhesive

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 FI 技術表示箇所 B32B 27/00 B32B 27/00 N B44C 1/165 B44C 1/165 H ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification code Internal reference number FI Technical display location B32B 27/00 B32B 27/00 N B44C 1/165 B44C 1/165 H

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 金属薄膜層1上に樹脂薄膜2を介してガ
ラスビーズ3が単層状に埋め込まれており、該ガラスビ
ーズ3上に熱可塑性樹脂層4、接着剤層5及び表面に離
型面7を有するフィルム6が順次積層されている、全体
の厚さが70〜200μmの積層物からなることを特徴
とするスタンピングホイル等として使用できる高輝性反
射転写箔。
1. Glass beads 3 are embedded in a single layer on a metal thin film layer 1 with a resin thin film 2 interposed therebetween, and a thermoplastic resin layer 4, an adhesive layer 5 and a mold release on the surface of the glass beads 3. A high-brightness reflective transfer foil that can be used as a stamping foil or the like, comprising a laminate having a total thickness of 70 to 200 μm in which films 6 having a surface 7 are sequentially laminated.
【請求項2】 上記積層物の離型面7が、粘着剤層8を
介して基材フィルム9に貼着されていることを特徴とす
る請求項1の高輝性反射転写箔。
2. The high-brightness reflective transfer foil according to claim 1, wherein the release surface 7 of the laminate is adhered to a base film 9 via an adhesive layer 8.
JP16819096A 1996-06-07 1996-06-07 High brightness reflective transfer foil which can be used as stamping foil, etc. Pending JPH09327881A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP16819096A JPH09327881A (en) 1996-06-07 1996-06-07 High brightness reflective transfer foil which can be used as stamping foil, etc.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP16819096A JPH09327881A (en) 1996-06-07 1996-06-07 High brightness reflective transfer foil which can be used as stamping foil, etc.

Publications (1)

Publication Number Publication Date
JPH09327881A true JPH09327881A (en) 1997-12-22

Family

ID=15863460

Family Applications (1)

Application Number Title Priority Date Filing Date
JP16819096A Pending JPH09327881A (en) 1996-06-07 1996-06-07 High brightness reflective transfer foil which can be used as stamping foil, etc.

Country Status (1)

Country Link
JP (1) JPH09327881A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
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KR100915337B1 (en) * 2007-10-25 2009-09-03 재단법인서울대학교산학협력재단 Method of fabricating substrate where patterns are formed
KR100944946B1 (en) * 2009-02-10 2010-03-02 재단법인서울대학교산학협력재단 Method of fabricating substrate where patterns are formed
US8936828B2 (en) 2009-04-29 2015-01-20 Snu R&Db Foundation Method of fabricating substrate where patterns are formed

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008154623A (en) * 2006-12-20 2008-07-10 Bridgestone Sports Co Ltd Golf club head with decorated hosel and golf club using the same
KR100915337B1 (en) * 2007-10-25 2009-09-03 재단법인서울대학교산학협력재단 Method of fabricating substrate where patterns are formed
KR100944946B1 (en) * 2009-02-10 2010-03-02 재단법인서울대학교산학협력재단 Method of fabricating substrate where patterns are formed
US8936828B2 (en) 2009-04-29 2015-01-20 Snu R&Db Foundation Method of fabricating substrate where patterns are formed

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