JPH09276002A - Antistatic shoes and manufacture thereof - Google Patents

Antistatic shoes and manufacture thereof

Info

Publication number
JPH09276002A
JPH09276002A JP8125209A JP12520996A JPH09276002A JP H09276002 A JPH09276002 A JP H09276002A JP 8125209 A JP8125209 A JP 8125209A JP 12520996 A JP12520996 A JP 12520996A JP H09276002 A JPH09276002 A JP H09276002A
Authority
JP
Japan
Prior art keywords
insole
outsole
antistatic
shoes
shin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP8125209A
Other languages
Japanese (ja)
Inventor
Mutsuji Fujii
陸司 藤井
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NOGUCHI GOMME KOGYO KK
Original Assignee
NOGUCHI GOMME KOGYO KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NOGUCHI GOMME KOGYO KK filed Critical NOGUCHI GOMME KOGYO KK
Priority to JP8125209A priority Critical patent/JPH09276002A/en
Publication of JPH09276002A publication Critical patent/JPH09276002A/en
Pending legal-status Critical Current

Links

Abstract

PROBLEM TO BE SOLVED: To obtain a stable conducting effect in the soles and bottoms of shoes by a method wherein conductive pieces using carbon fibers or the like having an electric resistance below a specified value are mounted at one point or more in each layer of insole, inner sole and core and successively arranged to partly or wholly overlap in position between layers for reducing changes in electric resistance. SOLUTION: Insoles 6, inner soles 5 and cores 4 are produced from a regenerated leather, a pulp material, an unwoven cloth or the like mixed with metallic fibers, metallic powder, carbon fibers or the like and conductive pieces 8 made up of carbon fibers, aluminum foils, copper plated fabrics or the like with the resistance thereof of below 0.1MΩ are stuck, sewn and welded being folded back on upper and lower sides of the insoles 6, the inner soles and the cores 4 at one point or more in respective same positions where the conductive pieces overlap. This can reduce changes in the electric resistance to yield a stable conducting effect in the soles and the bottoms of the shoes thereby easing impact on the soles with improved wearing touch during walking.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、電気抵抗を少なく、か
つ、安定化し、身体に帯電した静電気を、安全、確実に
大地に漏洩させ、かつ、履き心地を良好にし、歩行中の
足底への衝撃を緩和する、帯電防止用靴の製造方法に関
するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention has a low electric resistance and is stable, allows static electricity charged on the body to be safely and surely leaked to the ground, and is comfortable to wear. TECHNICAL FIELD The present invention relates to a method for manufacturing an antistatic shoe, which reduces the impact on shoes.

【0002】[0002]

【従来の技術】石油プラント、塗料製造工場、ガソリン
スタンド等では、人体に静電気が帯電し、身体からの火
花で着火、爆発を防止するために、種々の帯電防止具や
帯電防止用靴が用いられている。従来から、帯電防止用
靴は、各種構造を有するものが履用されているが、通常
は、中底やインソールに金属鋲を装着して、導電性アウ
トソールに接触させ、人体に帯電した静電気を大地に漏
洩させたり、不織布板、繊維板に帯電防止剤、帯電防止
塗料を合浸、塗布、混合したインソール、または、中底
を導電性アウトソールに接触させて、帯電した静電気を
漏洩させている。
2. Description of the Related Art In petroleum plants, paint manufacturing plants, gas stations, etc., various antistatic devices and antistatic shoes are used to prevent human bodies from being charged with static electricity and sparks from the body to prevent ignition and explosion. Has been. Conventionally, antistatic shoes with various structures have been worn, but normally, metal studs are attached to the insole or insole to contact the conductive outsole, and the static electricity charged to the human body is charged. To the ground, or by contacting the non-woven fabric or fiberboard with an insole mixed with, coated with, or mixed with an antistatic agent or antistatic paint, or by contacting the insole with a conductive outsole to leak charged static electricity. ing.

【0003】[0003]

【発明が解決しようとする課題】中底やインソールに金
属鋲を装着した場合は、履用中、歩行の屈曲により金属
鋲が脱落して帯電防止性能が不能になったり、また、不
織布板、繊維板のインソールや中底に帯電防止塗料を含
浸した場合は、温度変化や水分の影響で導電効果の低下
する場合がある。不織布板、繊維板にカーボン繊維細片
や、銅メッキ繊維を混合した場合も、混合が均一になら
ないため、導電効果が低下する場合がある。これら、従
来からの方法の帯電防止用靴においては、いずれも足
底、インソール、中底、アウトソールの接触不良による
不安定要素が多く、これらの防止や、歩行中の履き心地
の向上、足底の衝撃緩和などが望まれていた。
When metal studs are attached to the insole or the insole, the metal studs may fall off due to the bending of the walking during wearing, and the antistatic performance may be impaired. When the insole or the insole of the fiberboard is impregnated with the antistatic paint, the conductive effect may be reduced due to the influence of temperature change and moisture. Even when a carbon fiber strip or a copper-plated fiber is mixed with a nonwoven fabric plate or a fiber plate, the mixing may not be uniform, so that the conductive effect may be reduced. In these conventional antistatic shoes, there are many instability factors due to poor contact of the soles, insoles, midsoles, and outsoles, and prevention of these, improvement of comfort during walking, foot It was desired to reduce the impact on the bottom.

【0004】[0004]

【課題を解決するための手段】本発明は金属繊維、金属
粉、カーボン繊維等を、再生革、パルプ材、不織布等に
混合した靴のインソール(6)、中底(5)、中しん
(4)に0.1MΩ以下のカーボン繊維布、アルミ箔、
銅メッキした布地等を用いた導電片(8)を、インソー
ル(6)、中底(5)、中しん(4)の各層毎に1ケ所
以上取り付け、各導電片の位置が全体、または、一部が
重なるように連設され、表底は導電性を有してなる帯電
防止用靴であり、また、表底(9)にはウレタン樹脂に
発泡剤、帯電防止剤、架橋剤、触媒、着色剤、イソシア
ネートを混合した表底材を、通常の製法で製造した甲被
(7)に射出成形方法、または、接着式成形方法で靴底
を接合した帯電防止用靴の製造方法である。また、表底
(9)はミッドソール(3)、内側アウトソール
(1)、外側アウトソール(2)、または、ミッドソー
ル(3)、外側アウトソール(2)にも構成される。さ
らに、導電片(8)をインソール(6)、中底(5)、
中しん(4)のそれぞれの内甲の土踏まず部の上下面に
折り返して貼り付けた帯電防止用靴でもある。
According to the present invention, a shoe insole (6), an insole (5), and an insole (in which a metal fiber, a metal powder, a carbon fiber, etc. are mixed with recycled leather, pulp material, non-woven fabric, etc. 4) Carbon fiber cloth of 0.1 MΩ or less, aluminum foil,
A conductive piece (8) made of copper-plated cloth or the like is attached at one or more places for each layer of the insole (6), insole (5), and middle shin (4), and the position of each conductive piece is the whole or The outer soles are antistatic shoes which are continuously arranged so that they overlap each other, and the outer soles have conductivity, and the outer soles (9) are made of urethane resin with a foaming agent, an antistatic agent, a crosslinking agent, and a catalyst. A method for producing an antistatic shoe in which an outsole material mixed with a colorant and an isocyanate is injection-molded on an instep cover (7) produced by a usual production method or a shoe sole is joined by an adhesive molding method. . The outsole (9) is also configured as a midsole (3), an inner outsole (1), an outer outsole (2), or a midsole (3) and an outer outsole (2). Furthermore, the conductive piece (8) is attached to the insole (6), the insole (5),
It is also an antistatic shoe that is folded back and attached to the upper and lower surfaces of the arch of each instep of the middle shin (4).

【0005】[0005]

【作用】本発明の帯電防止用靴はインソール(6)、中
底(5)、中しん(4)に、金属繊維、金属粉、カーボ
ン繊維等を再生革、パルプ材、不織布等に混合し、かつ
0.1MΩ以下のカーボン繊維、アルミ箔、銅メッキし
た布地等を用いた導電片(8)をインソール(6)、中
底(5)、中しん(4)の重なりあう同位置に1ケ所以
上、上下面に折り返して、貼り付け、縫い付け、溶着し
て、それぞれの接触を確実にし、電気抵抗変化を小さ
く、かつ、安定化させる。一般的にウレタン樹脂表底
は、帯電防止剤の量を増加させると電気抵抗値は小さく
なるが、引っ張りに対する強さや耐摩耗性が低下し、も
ろく、割れやすくなるため、履物の表底には適さない。
また、内側アウトソール(1)は、特に早く摩耗するの
で、帯電防止剤を多く用いることができず、電気抵抗値
を小さくすることが困難である。本発明の帯電防止靴
は、ミッドソール(3)、外側アウトソール(2)に
は、発泡剤、帯電防止剤、架橋剤、触媒、着色剤、イソ
シアネートを混合したウレタン樹脂と、0.1〜100
MΩに調整した表底材を用いて導電性を良好にし、内側
アウトソール(1)にはクッション性、耐摩耗性を考慮
し、ウレタン樹脂に発泡剤、帯電防止剤、架橋剤、触
媒、着色剤、イソシアネートを混合して、0.1〜10
0MΩになる表底剤を、通常の製法で製造した甲被
(7)に射出成形方法、または、接着式方法で製造して
おり、歩行中の履き心地や足底の衝撃の緩和、表底の耐
摩耗性を向上させることができる。
In the antistatic shoe of the present invention, the insole (6), the insole (5) and the shin (4) are mixed with regenerated leather, pulp material, non-woven fabric, etc. And a conductive piece (8) made of carbon fiber of 0.1 MΩ or less, aluminum foil, copper-plated cloth, etc., at the same position where the insole (6), the insole (5), and the middle shin (4) overlap. By folding back to the upper and lower surfaces and attaching, sewn, and welding at each place or more to ensure contact with each other, change in electrical resistance is small and stabilized. Generally, the urethane resin outsole has a smaller electric resistance value when the amount of the antistatic agent is increased, but the strength against abrasion and the abrasion resistance are reduced, and it becomes brittle and easily cracked. Not suitable.
Further, since the inner outsole (1) wears particularly quickly, it is difficult to use a large amount of antistatic agent, and it is difficult to reduce the electric resistance value. In the antistatic shoe of the present invention, the midsole (3) and the outer outsole (2) have a urethane resin mixed with a foaming agent, an antistatic agent, a cross-linking agent, a catalyst, a colorant, and an isocyanate, and 0.1 to 10. 100
The conductivity is improved by using the bottom material adjusted to MΩ, and the foaming agent, antistatic agent, cross-linking agent, catalyst and coloring are applied to the urethane resin considering the cushioning property and abrasion resistance of the inner outsole (1). Mixing agent and isocyanate, 0.1-10
An insole (7) manufactured by a normal manufacturing method is manufactured by an injection molding method or an adhesive method to manufacture a surface sole agent having a resistance of 0 MΩ. The wear resistance of can be improved.

【0006】[0006]

【実施例】次にインソール(6)、中底(5)、中しん
(4)の導電片(8)の同位置に、1ケ所以上、上下面
に折り返して貼り付けし、ミッドソール(3)、内側ア
ウトソール(1)、外側アウトソール(2)を有する帯
電防止用靴の製造方法についての本発明の実施例を、図
1〜図5に表す図面に基づいて説明する。インソール
(6)、中底(5)、中しん(4)は、カーボン繊維を
不織布に混合し、それぞれを10MΩに調整し、常法に
より製造したものを用いる。導電片は、銅メッキした布
地で0.1MΩに調整し、常法により製造し、インソー
ル(6)、中底(5)、中しん(4)のそれぞれの内甲
の土踏まず部の上下面に、折り返して貼り付ける。ミッ
ドソール(3)、外側アウトソール(2)はウレタン樹
脂に発泡剤、帯電防止剤、架橋剤、触媒、着色剤、イソ
シアネートを混合し、0.1〜100MΩに調整した表
底材を用い、内側アウトソール(1)はクッション性、
耐摩耗性を良好にするため、ウレタン樹脂に発泡剤、帯
電防止剤、架橋剤、触媒、着色剤にイソシアネートを混
合し、0.1〜100MΩに調整した表材を用い、通常
の製法で製造した甲被(7)に、射出成形方法で靴底を
接合して帯電防止用靴を作成する。
[Examples] Next, the insole (6), the insole (5), and the midsole (4) were attached to the same position of the conductive piece (8) by folding back and forth one or more places on the midsole (3). ), An inner outsole (1), and an outer outsole (2), an embodiment of the present invention for a method of manufacturing an antistatic shoe will be described with reference to the drawings shown in FIGS. For the insole (6), the insole (5), and the inner shin (4), carbon fibers are mixed with a non-woven fabric, adjusted to 10 MΩ, and manufactured by an ordinary method. The conductive piece is adjusted to 0.1 MΩ with copper-plated fabric and manufactured by a conventional method, and is attached to the upper and lower surfaces of the instep of the insole (6), insole (5) and shin (4). , Wrap and paste. For the midsole (3) and the outer outsole (2), a urethane resin is mixed with a foaming agent, an antistatic agent, a cross-linking agent, a catalyst, a colorant, and an isocyanate, and a bottom sole material adjusted to 0.1 to 100 MΩ is used. The inner outsole (1) has cushioning properties,
To improve abrasion resistance, urethane resin is mixed with foaming agent, antistatic agent, cross-linking agent, catalyst, and colorant, and isocyanate is used. The shoe sole is joined to the instep (7) by an injection molding method to prepare an antistatic shoe.

【0007】[0007]

【発明の効果】本発明は、インソール(6)、中底
(5)、中しん(4)を重ねたそれぞれの同位置の1ケ
所以上に、上下面に折り返して設けられた導電片(8)
により、それぞれの接触を確実にし、ミッドソール
(3)、内側アウトソール(1)、外側アウトソール
(2)を設けることで、電気抵抗変化が少なく、安定し
た足底と靴底の導電効果を発揮し、歩行中の履き心地の
向上や足底の衝撃を緩和することができる。さらに、導
電片(8)をインソール(6)、中底(5)、中しん
(4)のそれぞれの内甲の土踏まず部の上下面に折り返
して貼り付けした場合、足に対する違和感もなく、極め
て履き心地がよい。
According to the present invention, the conductive piece (8) is provided by folding back the upper and lower surfaces at one or more positions in the same position where the insole (6), the insole (5) and the shin (4) are stacked. )
By ensuring the contact of each, and by providing the midsole (3), the inner outsole (1), and the outer outsole (2), there is little change in electrical resistance and a stable conductive effect of the sole and sole is obtained. It is possible to improve the wearing comfort while walking and to reduce the impact on the sole of the foot. Moreover, when the conductive piece (8) is folded back and attached to the upper and lower surfaces of the arch of the instep of the insole (6), insole (5) and shin (4), there is no discomfort to the foot and it is extremely Comfortable to wear.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の一実施例の外観図FIG. 1 is an external view of an embodiment of the present invention.

【図2】本発明の一実施例のA−Aの断面図FIG. 2 is a sectional view taken along line AA of the embodiment of the present invention.

【図3】本発明の一実施例のB−Bの断面図FIG. 3 is a sectional view taken along line BB of the embodiment of the present invention.

【図4】インソール、中底、中しんの外観図[Fig. 4] Appearance of insole, insole, and middle shin

【図5】導電片装着図[Figure 5] Mounting of conductive piece

【符号の説明】[Explanation of symbols]

1 内側アウトソール 2 外側アウトソール 3 ミッドソール 4 中しん 5 中底 6 インソール 7 甲被 8 導電片 9 表底 1 Inner outsole 2 Outer outsole 3 Midsole 4 Middle shin 5 Insole 6 Insole 7 Instep 8 Conductive piece 9 Outsole

Claims (5)

【特許請求の範囲】[Claims] 【請求項1】 金属繊維、金属粉、カーボン繊維等を、
再生革、パルプ材、不織布等を混合した靴のインソール
(6)、中底(5)、中しん(4)に、0.1MΩ以下
のカーボン繊維、アルミ箔、銅メッキした布地等を用い
た導電片(8)を、インソール(6)、中底(5)、中
しん(4)の各層毎に1ケ所以上取り付け、各導電片の
位置が全体、または、一部が重なるように連設され、表
底は導電性を有してなる帯電防止用靴。
1. Metal fiber, metal powder, carbon fiber, etc.
Carbon fiber of 0.1 MΩ or less, aluminum foil, copper-plated cloth, etc. were used for the insole (6), insole (5), and shin (4) of shoes mixed with recycled leather, pulp material, non-woven fabric, etc. The conductive piece (8) is attached to each layer of the insole (6), the insole (5), and the shin (4) at one or more places, and the conductive pieces are continuously or partially overlapped with each other. Anti-static shoes whose outer soles have conductivity.
【請求項2】 金属繊維、金属粉、カーボン繊維等を、
再生革、パルプ材、不織布等を混合した靴のインソール
(6)、中底(5)、中しん(4)に、0.1MΩ以下
のカーボン繊維、アルミ箔、銅メッキした布地等を用い
た導電片(8)を、インソール(6)、中底(5)、中
しん(4)の各層毎に1ケ所以上、上下面に折り返して
貼り付け、縫い付け、または、溶着し、取り付けた導電
片(8)の位置が全体、または、一部が重なるように連
設し、表底(9)には、ウレタン樹脂に発泡剤、帯電防
止剤、架橋剤、触媒、着色剤、イソシアネートを混合し
た表底材を用い、通常の製法で製造した甲被(7)に射
出成形方法、または、接着式成形方法で靴底を接合し
た、帯電防止用靴の製造方法。
2. Metal fiber, metal powder, carbon fiber, etc.
Carbon fiber of 0.1 MΩ or less, aluminum foil, copper-plated cloth, etc. were used for the insole (6), insole (5), and shin (4) of shoes mixed with recycled leather, pulp material, non-woven fabric, etc. The conductive piece (8) is attached to one or more layers of the insole (6), the insole (5), and the shin (4) by folding back and attaching, sewing, or welding to the upper and lower surfaces, and attached. The pieces (8) are continuously arranged so that all or part of them overlap, and urethane foam is mixed with a foaming agent, an antistatic agent, a cross-linking agent, a catalyst, a colorant, and an isocyanate on the outsole (9). A method for producing an antistatic shoe, in which the shoe sole is joined to the instep (7) produced by a usual production method using the above-mentioned outer sole material by an injection molding method or an adhesive molding method.
【請求項3】 表底がミッドソール(3)、アウトソー
ル(2)よりなる請求項1記載の帯電防止用靴。
3. The antistatic shoe according to claim 1, wherein the outsole comprises a midsole (3) and an outsole (2).
【請求項4】 表底がミッドソール(3)、内側アウト
ソール(1)、外側アウトソール(2)よりなる請求項
1記載の帯電防止用靴。
4. The antistatic shoe according to claim 1, wherein the outsole comprises a midsole (3), an inner outsole (1) and an outer outsole (2).
【請求項5】 導電片(8)を、インソール(6)、中
底(5)、中しん(4)の、それぞれの内甲の土踏まず
部の上下面に折り返して貼り付けた、特許請求の範囲、
第1項、第3項、第4項記載の帯電防止用靴。
5. A conductive piece (8) is attached by folding it back to the upper and lower surfaces of the instep (6), the insole (5) and the shin (4) of the instep of each instep. range,
Antistatic shoes according to the first, third and fourth aspects.
JP8125209A 1996-04-10 1996-04-10 Antistatic shoes and manufacture thereof Pending JPH09276002A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP8125209A JPH09276002A (en) 1996-04-10 1996-04-10 Antistatic shoes and manufacture thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP8125209A JPH09276002A (en) 1996-04-10 1996-04-10 Antistatic shoes and manufacture thereof

Publications (1)

Publication Number Publication Date
JPH09276002A true JPH09276002A (en) 1997-10-28

Family

ID=14904594

Family Applications (1)

Application Number Title Priority Date Filing Date
JP8125209A Pending JPH09276002A (en) 1996-04-10 1996-04-10 Antistatic shoes and manufacture thereof

Country Status (1)

Country Link
JP (1) JPH09276002A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1023850A1 (en) * 1999-01-28 2000-08-02 Analco Auxiliar Calzado, S.A. Anti-static sole assembly for footwear
JP2008228850A (en) * 2007-03-19 2008-10-02 Midori Anzen Co Ltd Antistatic shoe
CN112841809A (en) * 2021-01-29 2021-05-28 军事科学院系统工程研究院军需工程技术研究所 Composite sole structure, manufacturing method thereof and anti-static shoes and boots
CN115260747A (en) * 2022-09-01 2022-11-01 南通君江材料科技有限公司 Low-charge accumulation static-conducting anti-static double-layer static safety work shoe and manufacturing method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1023850A1 (en) * 1999-01-28 2000-08-02 Analco Auxiliar Calzado, S.A. Anti-static sole assembly for footwear
JP2008228850A (en) * 2007-03-19 2008-10-02 Midori Anzen Co Ltd Antistatic shoe
CN112841809A (en) * 2021-01-29 2021-05-28 军事科学院系统工程研究院军需工程技术研究所 Composite sole structure, manufacturing method thereof and anti-static shoes and boots
CN115260747A (en) * 2022-09-01 2022-11-01 南通君江材料科技有限公司 Low-charge accumulation static-conducting anti-static double-layer static safety work shoe and manufacturing method thereof

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