JPH09220481A - Metal carrier for electrically-heated catalytic device - Google Patents

Metal carrier for electrically-heated catalytic device

Info

Publication number
JPH09220481A
JPH09220481A JP8030835A JP3083596A JPH09220481A JP H09220481 A JPH09220481 A JP H09220481A JP 8030835 A JP8030835 A JP 8030835A JP 3083596 A JP3083596 A JP 3083596A JP H09220481 A JPH09220481 A JP H09220481A
Authority
JP
Japan
Prior art keywords
honeycomb body
metal carrier
electrically heated
honeycomb
catalyst device
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP8030835A
Other languages
Japanese (ja)
Inventor
Katsunori Matsuoka
克憲 松岡
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Showa Aircraft Industry Co Ltd
Original Assignee
Showa Aircraft Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Showa Aircraft Industry Co Ltd filed Critical Showa Aircraft Industry Co Ltd
Priority to JP8030835A priority Critical patent/JPH09220481A/en
Publication of JPH09220481A publication Critical patent/JPH09220481A/en
Pending legal-status Critical Current

Links

Abstract

PROBLEM TO BE SOLVED: To prevent the telescoping of the rolled electrically-heated first honeycomb body arranged on the upstream side of the rolled second honeycomb body forming the metal carrier for a catalytic device, having an unbonded insulating corrugated sheet and long in the axial direction. SOLUTION: Plural support pins 13 are provided in the space C between the second honeycomb body 12 and electrically-heated first honeycomb body 11 set in series, and the telescoping of the first honeycomb body 11 is blocked by the second honeycomb body 12. The second honeycomb body 12 is not telescoped since it is long in the axial direction. The cylindrical support pins 13 is abutted on the first honeycomb body with its end face 13a and held by the second honeycomb body 12 with a shaft 13c extending from the end face 13b. The total area of the end faces is controlled to <=30% of the total area of the air passage of the honeycomb body. The end face 13a of the support pin 13 is furnished with an insulating coating layer, or the pin is made of a ceramic, etc.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は内燃機関の排気ガス
浄化装置に用いられるハニカム体をなす触媒装置用メタ
ル担体に関し、特に電気加熱式触媒装置用メタル担体に
関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a catalyst carrier metal carrier used in an exhaust gas purifying apparatus for an internal combustion engine, and more particularly to an electrically heated catalyst carrier metal carrier.

【0002】[0002]

【従来の技術】従来の排気ガス浄化装置に用いられる触
媒装置用メタル担体は、薄い金属の平板と波板の間にろ
う材を介在させて、平板と波板を重ねて中心からロール
状に巻き込んでハニカム体を形成し、高真空炉を使用し
てろう材を溶融させ、板材の接触部分において接合を行
っていた。ろう材にはNi基ろう材を用い、平板と波板
にはフェライト系ステンレス材料が使用されていた。そ
のようにして形成されたハニカム体を金属製外筒内に収
容したものが触媒装置用メタル担体として知られている
(例えば特開昭65−4373号公報)。
2. Description of the Related Art A metal carrier for a catalyst device used in a conventional exhaust gas purifying apparatus has a brazing filler metal interposed between a thin metal flat plate and a corrugated plate, and the flat plate and the corrugated plate are superposed and rolled into a roll from the center. A honeycomb body is formed, a brazing material is melted using a high vacuum furnace, and joining is performed at a contact portion of the plate materials. A Ni-based brazing material was used as the brazing material, and a ferritic stainless steel material was used as the flat plate and the corrugated plate. A honeycomb carrier formed in such a manner and housed in a metal outer cylinder is known as a metal carrier for a catalyst device (for example, JP-A-65-4373).

【0003】ハニカム体のハニカム通路表面には触媒担
持層が形成され、その触媒担持層に貴金属触媒が担持さ
れて排気ガス浄化触媒の役目をなす。そして内燃機関の
排気通路に配設されて排気ガス中のHC、CO、NOx
などを浄化する。なお限られた容積中にできるだけ多く
のハニカム通路面積を確保する必要から、平板および波
板の厚さは強度を維持できる範囲内でできるだけ薄くな
っている。
[0003] A catalyst carrying layer is formed on the surface of the honeycomb passage of the honeycomb body, and the noble metal catalyst is carried on the catalyst carrying layer to serve as an exhaust gas purifying catalyst. HC, CO, and NOx contained in the exhaust gas are provided in the exhaust passage of the internal combustion engine.
Etc. Since it is necessary to secure as large a honeycomb passage area as possible in a limited volume, the thickness of the flat plate and the corrugated plate is made as thin as possible within a range where strength can be maintained.

【0004】上述した触媒担持層に担持された貴金属触
媒は、ある程度の高温環境下で触媒反応が促進されるの
で、触媒装置はできるだけ、高温の排気ガスに曝される
ように内燃機関の排気弁の近くに設けられている。
Since the catalytic reaction of the noble metal catalyst supported on the catalyst supporting layer described above is promoted in a high temperature environment to some extent, the exhaust gas of the internal combustion engine is exhausted so that the catalytic device is exposed to the exhaust gas at a temperature as high as possible. It is provided near the.

【0005】また、ハニカム体を通過する排気ガスの流
速がハニカム体の外層部より内層部に至るほど大きく、
したがってハニカム体では高温の排気ガスとの接触、触
媒反応による発熱および外筒からの熱放散により、内層
部ほど高温で外層部ほど低温となる温度分布を生じる。
この温度分布により、温度の高いハニカム体の内層部の
膨張・収縮量が、温度の低い外層部の膨張・収縮量より
大となるため、内層部と外層部との間に熱応力が発生す
る。この熱応力は、ハニカム体の膨張・収縮の度に繰り
返されるが、従来の触媒装置用メタル担体においては、
全ての平板材と波板材とがろう材を介して一体にろう付
けされているため熱応力を逃がすことができず、長期間
の使用により平板材と波板材との接合箇所が破断すると
いう欠点がある。
Further, the flow velocity of the exhaust gas passing through the honeycomb body is higher from the outer layer portion to the inner layer portion of the honeycomb body,
Therefore, in the honeycomb body, due to contact with high-temperature exhaust gas, heat generation due to catalytic reaction, and heat dissipation from the outer cylinder, a temperature distribution is generated in which the inner layer portion is hotter and the outer layer portion is colder.
Due to this temperature distribution, the expansion / contraction amount of the inner layer portion of the high temperature honeycomb body becomes larger than the expansion / contraction amount of the outer layer portion of the low temperature, so that thermal stress is generated between the inner layer portion and the outer layer portion. . This thermal stress is repeated every time the honeycomb body expands and contracts, but in the conventional metal carrier for a catalyst device,
Since all flat plates and corrugated sheets are brazed together via brazing filler metal, thermal stress cannot be released, and the joints between flat sheets and corrugated sheets are broken after long-term use. There is.

【0006】この欠点を除くため、ハニカム体を形成す
る平板を2枚以上重ね、それら平板同志の間は接合せず
単に重ねられており、さらに2枚の平板の間に第2の波
板を接合することなく配設して、接合されない平板の間
および平板と第2の波板の間が、互いに自由に滑って熱
応力が緩和されるメタル担体が開示されている。
In order to eliminate this defect, two or more flat plates forming the honeycomb body are stacked, and the flat plates are simply stacked without being joined, and a second corrugated plate is further placed between the two flat plates. Disclosed is a metal carrier which is disposed without being joined and between which flat plates are not joined and between the flat plate and the second corrugated plate are freely slid to relax thermal stress.

【0007】しかしながら、このような触媒装置用メタ
ル担体においては、内燃機関の始動時には排気ガスの温
度が低いため触媒反応が充分に行われず、そのため排気
ガス中のHC,CO,NOxなどを浄化する能力が不充
分となる。この欠点を除くため種々の電気加熱式触媒装
置用メタル担体が開示されていて、始動時にメタル担体
を電気的に加熱して触媒反応を促進するようになってい
る。
However, in such a metal carrier for a catalyst device, the catalyst reaction is not sufficiently performed because the temperature of the exhaust gas is low at the time of starting the internal combustion engine, so that HC, CO, NOx, etc. in the exhaust gas are purified. Inadequate ability. In order to eliminate this drawback, various metal carriers for electrically heated catalyst devices have been disclosed, and the metal carriers are electrically heated at the time of starting to promote the catalytic reaction.

【0008】上述のように、複数の平板とそれら平板の
間に第2の波板を装入した形式のハニカム体において
は、第2の波板の表面に酸化アルミニウムなどの被膜層
を施して、ハニカム体のロール状に巻き回された層の間
を電気的に絶縁し、ハニカム体の巻き始めと巻き終りの
板材の端部にそれぞれ電源と接続するための電極を設け
て、ハニカム体の巻き取り方向に電流を流す方式が採用
されている。このようなハニカム体全体を加熱する電気
加熱式メタル担体では、同じ外形の場合に軸方向の長さ
が短い方が同じ消費電力に対して所要温度までの加熱時
間は短くなる。
As described above, in the honeycomb body of the type in which a plurality of flat plates and the second corrugated plate are inserted between the flat plates, a coating layer of aluminum oxide or the like is formed on the surface of the second corrugated plate. , Electrically insulating between the layers wound in a roll shape of the honeycomb body, and providing electrodes for connecting to the power source at the ends of the plate material at the beginning and end of the winding of the honeycomb body, respectively. A method of passing an electric current in the winding direction is adopted. In such an electrically heated metal carrier for heating the entire honeycomb body, the shorter the axial length is, the shorter the heating time to the required temperature is for the same power consumption when the outer shape is the same.

【0009】したがって、容量の大きいメタル担体や、
容量は小さいがより少ない消費電力で有効な電気加熱を
行わんとする電気加熱式メタル担体では、図6に示すよ
うにメタル担体30の中のハニカム体を2分割して、電
気加熱するのに適当な容量の第1のメタル担体31と、
加熱部分を含まない主要なメタル担体を形成する第2の
メタル担体32とを直列に配設したものが開示されてい
る。
Therefore, a metal carrier having a large capacity,
In an electrically heated metal carrier which has a small capacity but is intended for effective electric heating with less power consumption, a honeycomb body in the metal carrier 30 is divided into two as shown in FIG. A first metal carrier 31 having an appropriate capacity,
It is disclosed that a second metal carrier 32 forming a main metal carrier that does not include a heating portion is arranged in series.

【0010】第1のメタル担体の構成の一例を挙げると
図8に示すように、1枚の波板41と複数枚の平板42
とが重なり合い、複数枚の平板42の中の隣り合う2枚
の間に電気絶縁性被膜層を有する絶縁用波板43を介在
させてロール状に巻いてハニカム構造をなすメタル担体
を形成し、ロール状に巻回された層間を電気的に絶縁し
て、ハニカム体40の巻始めと巻終りの板材の端部に電
源と接続するための電極を設け、ハニカム体40の巻取
り方向に電流を流すことによってハニカム体40を電気
的に加熱するようになっている。絶縁用波板43は通常
ろう付けによる接合を行なわない。このように形成され
た電気加熱式触媒装置用メタル担体の消費電力すなわち
発熱量の設定は、平板42の枚数を増減して電気抵抗体
の断面積を加減することにより行なっている(以下これ
を平板多重構造という)。
As an example of the structure of the first metal carrier, as shown in FIG. 8, one corrugated plate 41 and a plurality of flat plates 42 are provided.
Are overlapped with each other, and an insulating corrugated plate 43 having an electrically insulating coating layer is interposed between two adjacent ones of a plurality of flat plates 42 and wound in a roll shape to form a metal carrier having a honeycomb structure, Electrodes for electrically connecting the layers wound in a roll shape to each other are provided at the ends of the plate material at the beginning and end of the winding of the honeycomb body 40 to connect to a power source, and a current is applied in the winding direction of the honeycomb body 40. The honeycomb body 40 is electrically heated by flowing. The insulating corrugated sheet 43 is not usually joined by brazing. The power consumption, that is, the heat generation amount, of the metal carrier for an electrically heated catalyst device formed in this manner is set by increasing or decreasing the number of flat plates 42 and adjusting the cross-sectional area of the electric resistor (hereinafter, this will be performed). Plate flat structure).

【0011】さらに別の例として、図9に示すように、
1枚の波板51と少なくとも1枚の平板52を重ねて1
層とし、その層を2層以上重ね合わせ、重ね合わせた層
の中の少なくとも1枚の波板に電気絶縁性被膜層を施し
て絶縁用波板53とし、ロール状に巻き回してハニカム
構造のメタル担体を形成し、ハニカム体50の巻始めと
巻終りの板材の端部に電源と接続するための電極4,5
を設け、ハニカム体50の巻取り方向に電流を流すこと
によってハニカム体50を電気的に加熱するようになっ
ている。このように形成された電気加熱式触媒装置用メ
タル担体の消費電力すなわち発熱量の設定は、重ね合わ
せる層の数を増減することによって行なっている(以下
これを多層構造という)。
As another example, as shown in FIG.
One corrugated plate 51 and at least one flat plate 52 are stacked to form 1
Layers, two or more layers are superposed, and at least one corrugated sheet in the superposed layers is provided with an electrically insulating coating layer to form an insulating corrugated sheet 53, which is wound in a roll shape to form a honeycomb structure. Electrodes 4 and 5 for forming a metal carrier and connecting to the power source at the ends of the plate material at the beginning and end of the winding of the honeycomb body 50.
Is provided and the honeycomb body 50 is electrically heated by passing an electric current in the winding direction of the honeycomb body 50. The power consumption of the metal carrier for an electrically heated catalyst device thus formed, that is, the heat generation amount is set by increasing or decreasing the number of layers to be stacked (hereinafter referred to as a multilayer structure).

【0012】図6において、第1のメタル担体31の容
量が小さく、軸方向の長さが例えば20mm以下のよう
に短い場合には、第1のメタル担体は絶縁用波板に施さ
れた絶縁層のために、絶縁用波板はろう材による接合が
行なわれず、さらにまた、複数枚の平板の間も熱応力を
逃すため通常接合を行なわないので、使用中に層がずれ
て所謂テレスコーピングが生じるという欠点がある。こ
の現象を防止するため、図7に示すように、電気加熱式
の第1のハニカム体21の中心部に設けられた中心電極
26を延長して第2のハニカム体22の中心部に装入
し、第1のハニカム体21の中心部と第2のハニカム体
22の中心部とを結合することによってテレスコーピン
グを防止している。
In FIG. 6, when the capacity of the first metal carrier 31 is small and the axial length thereof is short, for example, 20 mm or less, the first metal carrier 31 is insulated from the insulating corrugated plate. Because of the layers, the insulating corrugated sheet is not joined by the brazing material, and further, because the thermal stress is also released between the flat plates, the joining is not normally performed, so the layers are displaced during use, so-called telescoping. There is a drawback that In order to prevent this phenomenon, as shown in FIG. 7, the central electrode 26 provided in the central portion of the electrically heated first honeycomb body 21 is extended and charged in the central portion of the second honeycomb body 22. However, the central portion of the first honeycomb body 21 and the central portion of the second honeycomb body 22 are joined together to prevent telescoping.

【0013】[0013]

【発明が解決しようとする課題】上述の第1のハニカム
体の中心部の中心電極を延長して第2のハニカム体に結
合し、第1のハニカム体のテレスコーピングを防止する
方法において、第1のハニカム体のうち軸方向に固定さ
れている部分は、中心電極に近い部分と外筒に近い部分
だけで、その他の部分は充分に固定されていないためテ
レスコーピングを完全に防止できないという欠点がある
ほか、第1と第2のハニカム体の中心部分の位置がそれ
ぞれのハニカム体で異なるために、保持筒に装入する場
合無理な心合わせを行うため、加熱の際に第1のハニカ
ム体が変形するという欠点がある。さらに電気加熱を行
わない第2のハニカム体においても絶縁を考慮する必要
があるため構造が複雑になるという欠点がある。
In the method for preventing telescoping of the first honeycomb body by extending the center electrode of the central portion of the first honeycomb body and bonding it to the second honeycomb body, A part of the honeycomb body 1 fixed in the axial direction is only a part close to the center electrode and a part close to the outer cylinder, and the other parts are not sufficiently fixed, so that telescoping cannot be completely prevented. In addition, since the positions of the central portions of the first and second honeycomb bodies are different in the respective honeycomb bodies, the first honeycomb is heated during heating in order to perform unreasonable centering when charging the holding cylinder. It has the drawback of deforming the body. Further, in the second honeycomb body which is not electrically heated, there is a drawback that the structure becomes complicated because it is necessary to consider insulation.

【0014】本発明の目的は、軸方向長さが短くテレス
コーピングを生じ易い電気加熱式メタル担体のテレスコ
ーピングを防止することにある。
An object of the present invention is to prevent telescoping of an electrically heated metal carrier which has a short axial length and is prone to telescoping.

【0015】[0015]

【課題を解決するための手段】本発明の電気加熱式触媒
装置用メタル担体は、帯状をなす薄い金属板を折曲げて
連続的な波形の凹凸を形成した1枚の波板材と、平坦な
帯状をなす薄い金属板からなる少なくとも1枚の平板材
とが相互に当接して重なり合って形成された層が、少な
くとも2層以上積み重ねられてロール状に巻かれて形成
されて多数の網目状通気路を備えたハニカム体をなし、
積み重ねられた層のうちの少なくとも1層の波板材が、
電気絶縁性被膜層を施されて接合されることなくロール
状に巻回された層間を電気的に絶縁し、ハニカム体の中
心部に中心電極を有し、ハニカム体の外周部に中心電極
と逆性の外周電極を有し、中心電極と外周電極の間に電
流を流してハニカム体を加熱する、軸方向長さが短い第
1のハニカム体と、帯状をなす薄い金属板を折り曲げて
連続的な波形の凹凸を形成した波板材と、平坦な帯状を
なす薄い金属板からなる平板材とが相互に当接して重な
り合いロール状に巻かれて形成されて多数の網目状通気
路を備えたハニカム体をなし、第1のハニカム体の下流
に直列にかつ間隔を置いて配設された第2のハニカム体
と、第1と第2のハニカム体を覆って両ハニカム体を保
持する保持筒とを含む、電気加熱式触媒装置用メタル担
体において、第1と第2のハニカム体の対向する軸方向
端部に当接する複数の間隔片を有している。
MEANS FOR SOLVING THE PROBLEMS The metal carrier for an electrically heated catalyst device of the present invention comprises a corrugated sheet material formed by bending a thin metal sheet in the form of a strip to form continuous corrugation, and a flat corrugated sheet material. At least two or more layers, which are formed by abutting and overlapping at least one flat plate material made of a strip-shaped thin metal plate, are stacked and wound in a roll shape to form a large number of mesh-like ventilations. Forming a honeycomb body with passages,
At least one of the stacked layers of corrugated sheet material,
An electrically insulating coating layer is applied to electrically insulate the layers wound in a roll shape without being bonded, and a central electrode is provided at the center of the honeycomb body, and a central electrode is provided at the outer peripheral portion of the honeycomb body. A first honeycomb body having a reverse axial electrode and a current flowing between the center electrode and the peripheral electrode for heating the honeycomb body, which has a short axial length, and a thin metal plate in a band shape are continuously bent. The corrugated sheet material with the irregular corrugations and the flat sheet material made of a thin metal plate in the shape of a flat strip are in contact with each other and overlap each other and are wound in a roll shape to form a large number of mesh-like ventilation passages. A second honeycomb body, which is in the form of a honeycomb body and is arranged downstream of the first honeycomb body in series and at a distance, and a holding cylinder which covers the first and second honeycomb bodies and holds both the honeycomb bodies. A metal carrier for an electrically heated catalyst device, comprising: And a plurality of spacing pieces in contact with the axial end portion facing the second honeycomb body.

【0016】前述の間隔片は、ハニカム体の軸に直角な
両端面を有し、端面の大きさは、第1のハニカム体を形
成する通気路1個の寸法より大なる寸法を有し、両端面
の一方が、ハニカム体の軸に平行な軸部を有し、軸部が
第2のハニカム体を形成する通気路の中の1個に装入可
能で、かつ通気路とろう付けにより接合可能な形状を有
しており、軸部は、第2のハニカム体の端部から通気路
の中に5mm以上装入されることが好適である。
The above-mentioned spacing piece has both end surfaces perpendicular to the axis of the honeycomb body, and the size of the end surface is larger than the size of one ventilation passage forming the first honeycomb body, One of both end surfaces has a shaft portion parallel to the axis of the honeycomb body, and the shaft portion can be inserted into one of the air passages forming the second honeycomb body, and by the air passage and brazing. It has a shape capable of being joined, and it is preferable that the shaft portion is inserted into the ventilation passage from the end portion of the second honeycomb body by 5 mm or more.

【0017】また、複数の間隔片の端面の面積の合計
が、ハニカム体の通気路の断面積合計の30%以下にす
ることが好ましい。
Further, the total area of the end faces of the plurality of spacing pieces is preferably 30% or less of the total cross-sectional area of the ventilation passages of the honeycomb body.

【0018】間隔片の材料には金属材料が用いられ、そ
の第1のハニカム体に当接する端面には電気絶縁性被膜
層が施される。さらに代わりの材料として耐熱性のある
電気絶縁材料も用いることができる。
A metal material is used as the material of the spacer pieces, and an electrically insulating coating layer is applied to the end faces of the spacer pieces that come into contact with the first honeycomb body. Further, a heat resistant electrically insulating material can be used as an alternative material.

【0019】[0019]

【発明の実施の形態】本発明の電気加熱式触媒装置用メ
タル担体は、1枚の波板と少なくとも1枚の平板とを重
ね合わせた層を、少なくとも2層以上積み重ね、積み重
ねた層のうちの少なくとも1層の波板に電気絶縁性被膜
層を施し、絶縁用波板として層間を電気的に絶縁し、積
み重ねた層の一方の端部を中心としてロール状に巻いて
ハニカム体を形成し、ハニカム体の巻取り方向に電流を
流すことによってハニカム体の加熱を行なうようにした
第1のハニカム体と、別の波板材と平板材とを重ね合わ
せてロール状に巻いて第2のハニカム体とを形成し、第
1のハニカム体の下流に直列に、所定の間隔をおいて第
2のハニカム体を配設し、所定の間隔内に両ハニカム体
の端部に当接する複数個の間隔片を配置するものであ
る。
BEST MODE FOR CARRYING OUT THE INVENTION The metal carrier for an electrically heated catalyst device according to the present invention comprises at least two or more layers obtained by stacking one corrugated plate and at least one flat plate, and among the stacked layers. Of at least one corrugated sheet, an electrically insulating coating layer is applied to electrically insulate the layers as an insulating corrugated sheet, and one end of the stacked layers is wound as a center to form a honeycomb body. A first honeycomb body for heating the honeycomb body by passing an electric current in a winding direction of the honeycomb body, and another corrugated sheet material and a flat sheet material are superposed and rolled in a roll shape to form a second honeycomb body. And a second honeycomb body is arranged at a predetermined interval in series downstream of the first honeycomb body, and a plurality of abutting end portions of both honeycomb bodies are contacted within the predetermined interval. The spacing pieces are arranged.

【0020】軸方向長さが短く、かつ絶縁用波板をロー
ルの間に接合せずに介在させている第1のハニカム体で
も、第2のハニカム体に保持されている複数個の間隔片
によって、軸方向下流に向かっての動きが止められるか
ら、使用中排気ガスの流れによるテレスコーピングを発
生するおそれがなくなる。
Even in the first honeycomb body having a short axial length and the insulating corrugated sheet interposed between the rolls without being joined, a plurality of spacing pieces held by the second honeycomb body are provided. As a result, the movement toward the downstream in the axial direction is stopped, so there is no possibility of telescoping due to the flow of exhaust gas during use.

【0021】さらに、本発明によるメタル担体を上述の
構成としたため、電気的に加熱される第1のハニカム体
の構造が、互いに接合されない複数の平板材を有する平
板多重構造の場合や、2層以上の層が重ね合わされて形
成された多層構造の場合のような、板材の軸方向の拘束
力が極めて小なる場合であっても、テレスコーピングが
発生することはない。
Further, since the metal carrier according to the present invention has the above-mentioned structure, the structure of the electrically heated first honeycomb body is a flat plate multiple structure having a plurality of flat plate members which are not joined to each other, or two layers. Telescoping does not occur even when the axial restraining force of the plate material is extremely small as in the case of a multilayer structure formed by stacking the above layers.

【0022】従って、第1のハニカム体の消費電力を設
計するに際し、多層構造において積み重ねる層の数の増
減や、さらに各層の板材の全長の増減によって、比較的
大幅な消費電力の増減を行なうことができ、また平板多
重構造において平板の枚数の増減によって比較的小幅の
消費電力の増減が可能となるので、これらの組み合せに
よって更に細かい客先の消費電力のニーズに合致したハ
ニカム体を提供することが出来る。
Therefore, in designing the power consumption of the first honeycomb body, a relatively large power consumption increase / decrease is performed by increasing / decreasing the number of layers to be stacked in the multilayer structure and further increasing / decreasing the total length of the plate material of each layer. In addition, since it is possible to increase and decrease the power consumption in the flat plate multiplex structure by changing the number of flat plates, it is possible to provide a honeycomb body that meets the more detailed power consumption needs of customers by combining these. Can be done.

【0023】積み重ねた層のうちの少なくとも1層を形
成する波板に電気絶縁性被膜層を施して絶縁用波板を形
成する場合、その被膜層は波板の片面又は両面に施すこ
とが出来る。両面に被膜層を施した場合には平板と接合
しないが、片面のみに被膜層を施した場合には、被膜層
を施さない面を平板と接合できるので、テレスコーピン
グの防止に効果がある。
When an electrically insulating coating layer is applied to a corrugated sheet forming at least one of the stacked layers to form an insulating corrugated sheet, the coating layer can be applied to one side or both sides of the corrugated sheet. . When the coating layer is provided on both sides, it is not joined to the flat plate, but when the coating layer is provided on only one side, the surface without the coating layer can be joined to the flat plate, which is effective in preventing telescoping.

【0024】電気絶縁性被膜層を間隔片及び波板に施す
方法には、下記の方法がある。すなわち、 イ.物理的方法(PVD)例えば真空蒸着、スパッタ、
イオンプレーティングによって絶縁被膜をコーティン
グ、 ロ.化学的方法(CVD)によって絶縁被膜をコーティ
ング、 ハ.大気焼成によって絶縁性被膜層に変化する材料、例
えばアルミニウムをコーティングした後大気焼成、 ニ.波板又は間隔片の母材にアルミニウムを含有するス
テンレスを用い、形成後大気焼成するか又はろう付け後
大気焼成して、酸化アルミニウム被膜を析出、 ホ.形成後又はろう付け後の状態で溶融アルミニウム中
に浸漬し、浸漬中にアルミニウム(Al)と母材中の鉄
(Fe)とを相互拡散させることによって表面に合金層
を形成し、その後大気焼成して酸化アルミニウム被膜を
析出させる。
There are the following methods for applying the electrically insulating coating layer to the spacer and the corrugated plate. That is, a. Physical methods (PVD) such as vacuum deposition, sputtering,
Insulation coating by ion plating, b. Coating an insulating film by a chemical method (CVD), c. A material that changes to an insulating coating layer by atmospheric baking, such as aluminum, and then baked in air, d. A stainless steel containing aluminum is used as the base material of the corrugated plate or the interval piece, and after the formation, it is baked in air or after brazing is baked in air to deposit an aluminum oxide film. After being formed or after brazing, it is immersed in molten aluminum, and during the immersion, aluminum (Al) and iron (Fe) in the base material are mutually diffused to form an alloy layer on the surface, and then air baking is performed. Then, an aluminum oxide film is deposited.

【0025】間隔片には、少なくとも第1のハニカム体
に当接する端面に絶縁性被膜を施すものとする。
The spacing pieces are provided with an insulating coating on at least the end faces that abut the first honeycomb body.

【0026】上述の方法によって電気絶縁性被膜層を両
面に施した絶縁用波板を用いて形成したロール状ハニカ
ム体において、絶縁用波板の巻き始め及び巻き終りの部
分を平板材とろう付けすることにより、絶縁用波板にも
電流を流して発熱体とすることが出来るので消費電力を
増加させる方法として効果がある。また片面のみに被膜
層を施した絶縁用波板は、平板と片面を接合出来るので
発熱体とすることが出来同様の効果が得られる。
In the roll-shaped honeycomb body formed by using the insulating corrugated sheet whose both surfaces are coated with the electrically insulating coating layer by the above-mentioned method, the winding start portion and the winding end portion of the insulating corrugated sheet are brazed to the flat plate material. By doing so, an electric current can be made to flow through the insulating corrugated plate as a heating element, which is effective as a method of increasing power consumption. In addition, the insulating corrugated sheet having the coating layer on only one side can be joined to the flat plate on one side, so that it can be used as a heating element and the same effect can be obtained.

【0027】[0027]

【実施例】次に本発明の実施例について図面を参照して
説明する。図1(A)は本発明の電気加熱式触媒装置用
メタル担体の軸を含む断面略図、図1(B)はサポート
ピンの外観の斜視図、図1(C)は図1(A)の第2の
ハニカム体の外観の斜視略図で、サポートピンが装入さ
れた状態を示す図、図2は、図1(A)の電気加熱式第
1のハニカム体の板材の構成を示す模式的断面図であ
る。
Next, an embodiment of the present invention will be described with reference to the drawings. 1 (A) is a schematic cross-sectional view including a shaft of a metal carrier for an electrically heated catalyst device of the present invention, FIG. 1 (B) is a perspective view of an outer appearance of a support pin, and FIG. 1 (C) is of FIG. FIG. 2 is a schematic perspective view of the appearance of the second honeycomb body, showing a state in which support pins are inserted, and FIG. 2 is a schematic diagram showing the configuration of the plate material of the electrically heated first honeycomb body of FIG. FIG.

【0028】図1(A)において、電気加熱式触媒装置
用メタル担体10には、電気加熱式の第1のハニカム体
11と、第1のハニカム体11の下流に同軸に所定の間
隔Cを隔てて第2のハニカム体12が配設されており、
所定の間隔Cには、間隔片である円筒状のサポートピン
13が複数個設けられている。第1のハニカム体11と
第2のハニカム体12の外側面は、それぞれ外筒11
a,12aで覆われ、さらに電気絶縁体14を介して共
通の保持筒15内に装入されている。
In FIG. 1 (A), a metal carrier 10 for an electrically heated catalyst device is provided with a first electrically heated honeycomb body 11 and a predetermined space C coaxially downstream of the first honeycomb body 11. The second honeycomb body 12 is arranged at a distance,
A plurality of cylindrical support pins 13, which are spacing pieces, are provided at a predetermined spacing C. The outer surfaces of the first honeycomb body 11 and the second honeycomb body 12 are the outer cylinder 11 respectively.
It is covered with a and 12a, and is further inserted into a common holding cylinder 15 via an electric insulator 14.

【0029】第1のハニカム体11は、図2に示すよう
な、帯状をなす薄い金属板を折り曲げて連続的な波形の
凹凸を形成した1枚の波板材1と、平坦な帯状をなす薄
い金属板からなる1枚の平板材21 とで形成される層
と、1枚の平板材22 と帯状をなす薄い金属板を折り曲
げて連続的な波形の凹凸を形成した電気絶縁性被膜層を
有する絶縁用波板3とで形成される層とが積み重ねら
れ、平板材21 ,22 と絶縁用波板3との間はろう材で
接合されることなく、ロール状に巻かれて形成されてい
る。第1のハニカム体11の中心部には、断面が円形で
細長い棒状の中心電極16が配設されて波板材1および
平板材21 ,22 に接合されている。第1のハニカム体
11のロール状の各層は、絶縁用波板3によって絶縁さ
れているから、波板材1と平板材21 ,22 のロールの
外周部の端末に外周電極17を設けることにより、中心
電極16と外周電極17との間の板材はロール状の電気
抵抗体を形成する。したがって、中心電極16と外周電
極17とをそれぞれ不図示の電源に接続すれば、第1の
ハニカム体11は電気加熱式のメタル担体となる。
As shown in FIG. 2, the first honeycomb body 11 includes a corrugated sheet material 1 in which a strip-shaped thin metal plate is bent to form continuous corrugations, and a flat strip-shaped thin sheet. A layer formed by one flat plate material 2 1 made of a metal plate and an electrically insulating coating layer formed by bending a flat metal plate 2 2 and a strip-shaped thin metal plate to form a continuous wavy pattern And the corrugated sheet 3 for insulation having a layer formed on top of each other are stacked, and the flat plate materials 2 1 and 2 2 and the corrugated sheet 3 for insulation are wound in a roll shape without being joined with a brazing material. Has been formed. At the center of the first honeycomb body 11, an elongated rod-shaped center electrode 16 having a circular cross section is arranged and joined to the corrugated sheet material 1 and the flat sheet materials 2 1 and 2 2 . Since each roll-shaped layer of the first honeycomb body 11 is insulated by the insulating corrugated plate 3, the outer peripheral electrode 17 is provided at the end of the outer peripheral portion of the roll of the corrugated plate material 1 and the flat plate materials 2 1 and 2 2. Thus, the plate material between the center electrode 16 and the outer peripheral electrode 17 forms a roll-shaped electric resistor. Therefore, by connecting the central electrode 16 and the outer peripheral electrode 17 to power sources (not shown), the first honeycomb body 11 becomes an electrically heated metal carrier.

【0030】第2のハニカム体12は、第1のハニカム
体11と同様に、波板材と平板材とを重ねてロール状に
巻き回して形成したハニカム体であるが、必ずしも平板
二重構造や多層構造である必要はない。また絶縁用波板
は配設されない。第2のハニカム体12は主要な触媒装
置用メタル担体としての役目を果たすものであるから、
第1のハニカム体11に比べ軸方向長さは長くなってい
る。したがって一部の板材間がろう材によって接合され
ていない場合、または平板二重構造や多層構造の場合で
も、テレスコーピングを起こすことはない。
Similar to the first honeycomb body 11, the second honeycomb body 12 is a honeycomb body formed by stacking a corrugated sheet material and a flat sheet material and winding them in a roll shape. It need not be a multi-layer structure. Also, no insulating corrugated sheet is provided. Since the second honeycomb body 12 serves as a main metal carrier for a catalyst device,
The axial length is longer than that of the first honeycomb body 11. Therefore, even if some of the plate materials are not joined by the brazing material, or even in the case of the flat plate double structure or the multilayer structure, telescoping does not occur.

【0031】サポートピン13は、第1と第2のハニカ
ム体の間の所定の間隔Cの中に配設される間隔片であっ
て、図1(B)に示すように、軸方向に二つの端面13
a,13bを有する円筒形状をなし、一方の端面13b
にはハニカム体の軸に平行な軸部13cが固設されてい
る。軸部13cの軸に直角な方向の断面の形状は、第2
のハニカム体12の1個の通気路の中に装入してろう材
によって通気路に接合可能な形状とする。軸部13cの
長さは、通気路の中に少なくとも5mm装入できる長さ
とする。他方の端面13aは、第1のハニカム体11の
端部に当接して、第1のハニカム体11がガス流による
テレスコーピングを生じるのを防止している。端面13
aの面積は、第1のハニカム体11の1個の通気路の面
積に等しいかまたは僅かに大きくする。すなわち通気路
の密度に応じて寸法が定められるが、通常その直径は1
〜10mmの範囲である。
The support pins 13 are spacing pieces arranged in a predetermined spacing C between the first and second honeycomb bodies, and as shown in FIG. One end face 13
a cylindrical shape having a and 13b, one end surface 13b
A shaft portion 13c parallel to the axis of the honeycomb body is fixedly provided in the. The cross-sectional shape of the shaft portion 13c in the direction perpendicular to the axis is the second
The honeycomb body 12 is charged into one of the ventilation passages and has a shape that can be joined to the ventilation passages by a brazing material. The length of the shaft portion 13c is set such that at least 5 mm can be inserted into the ventilation passage. The other end surface 13a abuts on the end portion of the first honeycomb body 11 to prevent the first honeycomb body 11 from telescoping due to the gas flow. End face 13
The area of a is equal to or slightly larger than the area of one ventilation passage of the first honeycomb body 11. That is, the size is determined according to the density of the ventilation passage, but the diameter is usually 1
It is in the range of 10 mm.

【0032】サポートピン13の形状は、図1(B)に
示すような円筒状のほか、断面形状が多角形や十文字形
のものも用いられるが、その端面の最大寸法は、図1
(B)の円筒の直径Aの円に内接する寸法以上とするこ
とが必要である。
The shape of the support pin 13 is not limited to the cylindrical shape as shown in FIG. 1 (B), and the cross-sectional shape is polygonal or cross-shaped, but the maximum dimension of the end face is shown in FIG.
It is necessary that the size is equal to or larger than the size inscribed in the circle of diameter A of the cylinder of (B).

【0033】サポートピンの所要個数は、第1のハニカ
ム体11の容量、構造によって異なるが、その端面の面
積の総和が第1のハニカム体11の通気路断面積合計の
30%以下とすることが好ましい。その理由は、30%
を越えるとガス流に対する抵抗が大となって圧力損失を
増大させるほか、メタル担体に触媒を担持させる際の目
詰まりの原因となり、またサポートピンが設けられた通
気路の触媒層の担持が不充分となったり、サポートピン
の下流の部分のガスの流れが悪くなって触媒効率が低下
するからである。
The required number of support pins varies depending on the capacity and structure of the first honeycomb body 11, but the total area of the end faces is 30% or less of the total cross-sectional area of the air passages of the first honeycomb body 11. Is preferred. The reason is 30%
If it exceeds the range, resistance to gas flow becomes large, increasing pressure loss, causing clogging when supporting the catalyst on the metal carrier, and not supporting the catalyst layer in the air passage provided with the support pin. This is because the catalyst efficiency becomes insufficient and the gas flow in the downstream portion of the support pin becomes poor, so that the catalyst efficiency decreases.

【0034】第1と第2のハニカム体の間の間隔Cの寸
法、すなわちサポートピン13の円筒部分の軸方向長さ
は、両ハニカム体間の絶縁および加熱式メタル担体とし
ての熱効率を考慮して2〜30mmの間に設定すること
が望ましい。
The dimension of the distance C between the first and second honeycomb bodies, that is, the axial length of the cylindrical portion of the support pin 13 is taken into consideration in terms of insulation between both honeycomb bodies and thermal efficiency as a heating type metal carrier. It is desirable to set the distance between 2 and 30 mm.

【0035】サポートピン13の配置は、図1(c)に
示すように、電気加熱を行う第1のハニカム体11の絶
縁用波板3の端部に沿うように渦巻状に配列することが
望ましいが、このほかテレスコーピングを防止可能な、
どのような配置を行ってもよい。
As shown in FIG. 1C, the support pins 13 may be arranged in a spiral shape along the end of the insulating corrugated plate 3 of the first honeycomb body 11 to be electrically heated. Although desirable, it is possible to prevent telescoping as well,
Any arrangement may be used.

【0036】サポートピン13の材質に鉄、ステンレス
などの導電性のある材料を使用した場合には、電気加熱
式の第1のハニカム体11と接する少なくとも一方の端
面13aに電気絶縁処理を施す必要がある。電気絶縁処
理の方法として、サポートピン単独に行う場合には、P
VD,CVDまたはイオンプレーティング法によって、
酸化アルミニウム(Al23 )またはその他の絶縁性
被膜層をコーティングするか、またはアルミニウムを含
有する材料や、溶融アルミニウム中に浸漬して鉄とアル
ミニウムの合金層を生成させた材料からなるピンを大気
焼成することによって、絶縁性被膜層を得る。サポート
ピンをハニカム体に組み付けた後に絶縁性被膜層を得る
には、あらかじめサポートピンにアルミニウムを含有す
る材料か溶融アルミニウムに浸漬した材料を用いて、大
気焼成法により酸化アルミニウムの絶縁性被膜層を得
る。
When a conductive material such as iron or stainless steel is used as the material of the support pin 13, at least one end face 13a contacting the electrically heated first honeycomb body 11 needs to be electrically insulated. There is. If the support pin is used alone as a method of electrical insulation, P
By VD, CVD or ion plating method,
A pin made of a material coated with aluminum oxide (Al 2 O 3 ) or another insulating coating layer or containing aluminum or a material obtained by immersing in molten aluminum to form an iron-aluminum alloy layer is used. An insulating coating layer is obtained by firing in the air. In order to obtain an insulating coating layer after assembling the support pins to the honeycomb body, a material containing aluminum in advance in the support pins or a material dipped in molten aluminum is used to form an insulating coating layer of aluminum oxide by an atmospheric firing method. obtain.

【0037】サポートピン13の材質に、セラミックな
どの耐熱性のある電気絶縁材料を使用することもでき
る。
As the material of the support pin 13, an electrically insulating material having heat resistance such as ceramic can be used.

【0038】第1のハニカム体11と第2のハニカム体
12とを固定するには、図1(A)に示すような保持筒
15が用いられるが、保持筒15の使用方法には、さら
に図3(A)、図3(B)に示すようなものがある。図
3(A)に示す実施例では、第1のハニカム体11の外
筒を延長して第2のハニカム体12の外筒12aを覆
い、保持筒15を形成するものであり、図3(B)に示
す実施例では、第2のハニカム体12の外筒を延長して
第1のハニカム体11の外筒11aを覆い、保持筒15
を形成するものである。これらの保持筒15はそれぞれ
の外筒12aまたは11aと溶接などによって固定す
る。
A holding cylinder 15 as shown in FIG. 1 (A) is used to fix the first honeycomb body 11 and the second honeycomb body 12. The holding cylinder 15 is used in the following manner. There are those as shown in FIG. 3 (A) and FIG. 3 (B). In the embodiment shown in FIG. 3 (A), the outer cylinder of the first honeycomb body 11 is extended to cover the outer cylinder 12a of the second honeycomb body 12 and the holding cylinder 15 is formed. In the embodiment shown in B), the outer cylinder of the second honeycomb body 12 is extended to cover the outer cylinder 11a of the first honeycomb body 11, and the holding cylinder 15
Is formed. These holding cylinders 15 are fixed to the outer cylinders 12a or 11a by welding or the like.

【0039】触媒担持を行うには、第1と第2のハニカ
ム体を組み付け後同時に行うことも可能であるが、第1
と第2のハニカム体について別個の触媒担持を行って異
なる担持仕様とし、または第1のハニカム体に触媒担持
を行わないなど、種々の方法をとることができる。
In order to carry the catalyst, it is possible to carry out it simultaneously after assembling the first and second honeycomb bodies.
Various methods can be adopted, such as separately carrying the catalyst on the second honeycomb body so as to have different carrying specifications, or not carrying the catalyst on the first honeycomb body.

【0040】本発明によるサポートピンを、第1と第2
のハニカム体の間に設けることにより、電気加熱式の第
1のハニカム体のテレスコーピングの発生を防止するこ
とができるので、第1のハニカム体を電気加熱するに適
した形状とし、さらに客先の消費電力のニーズに合致す
るように、軸方向長さの短縮、多層構造、平板多重構造
の採用を行なうことができる。
The support pin according to the present invention has first and second support pins.
Since it is possible to prevent the occurrence of telescoping of the electrically heated first honeycomb body by providing it between the honeycomb bodies, the shape of the first honeycomb body is suitable for electrically heating. The axial length can be shortened, and a multi-layer structure or a flat plate multiplex structure can be adopted to meet the power consumption needs.

【0041】次に、電気加熱式のハニカム体の設計にお
いて、種々の消費電力を設定する為の板材の構成を説明
する。
Next, in the design of the electrically heated honeycomb body, the construction of the plate material for setting various power consumption will be described.

【0042】図4は本発明の電気加熱式触媒装置用メタ
ル担体の種々の板材の構成を示す模式的断面の図であっ
て、従来の技術による全長がlで各1枚の平板と波板を
含む1層からなるハニカム体を基準層とし、以下この基
準層を分割して長さl/2ないしl/8の層としてそれ
ら各層を積み重ねたときの板材の構成を示す断面略図
と、基準層及び2層積み重ねた本発明の基本形式の層を
基準とした夫々の比較消費電力(発熱量)とを示してい
る。この際層毎の各板材の電気抵抗値を同一と仮定し、
また波板のうち少なくとも1枚に絶縁被膜層を施して、
全ての板材に対し巻取り方向に電流を流しうるようにし
てある。
FIG. 4 is a schematic cross-sectional view showing the construction of various plate materials of the metal carrier for an electrically heated catalyst device according to the present invention, which is a conventional flat plate having a total length of 1 and a corrugated plate. A honeycomb body consisting of one layer including a reference layer is used as a reference layer, and the reference layer is divided into layers having a length of l / 2 to 1/8, and the respective layers are stacked to form a plate material, Fig. 3 shows the respective comparative power consumption (heat generation amount) based on a layer and a layer of the basic type of the present invention in which two layers are stacked. At this time, assuming that the electric resistance value of each plate material for each layer is the same,
In addition, at least one of the corrugated sheets is provided with an insulating coating layer,
An electric current can be applied to all the plate materials in the winding direction.

【0043】図4に於て、従来の技術による全長lで波
板1と平板2各1枚からなる「基準層」を、長手方向に
1/2に切断して積み重ねて、本発明の基本形式である
2層積み重ね構造を形成すれば、板材の断面積の合計は
基準層に比し2倍となり、全長は1/2であるため電気
抵抗値は1/4となり、従って消費電力を4倍とするこ
とができるのに対して、重量と圧力損失は不変であり、
加熱速度は速くなる。以下同様に全長lを1/3ないし
1/8に切断して3層ないし8層に積み重ねれば、板材
の断面積は3倍ないし8倍となり、全長は1/3ないし
1/8となるため、従来の技術の基準層に対し電気抵抗
値は1/9ないし1/64となり、従って消費電力を9
倍ないし64倍とすることができる。
In FIG. 4, a "reference layer" consisting of a corrugated plate 1 and a flat plate 2 with a total length 1 according to the prior art is cut in half in the longitudinal direction and stacked to form a basic structure of the present invention. If a two-layer stacked structure is formed, the total cross-sectional area of the plate material will be twice as large as that of the reference layer, and since the total length is 1/2, the electrical resistance value will be 1/4, and therefore the power consumption will be 4 Can be doubled, while the weight and pressure loss remain unchanged,
The heating rate becomes faster. Similarly, if the total length 1 is cut into 1/3 to 1/8 and stacked in 3 to 8 layers, the sectional area of the plate material becomes 3 to 8 times, and the total length becomes 1/3 to 1/8. Therefore, the electric resistance value is 1/9 to 1/64 with respect to the reference layer of the conventional technique, and therefore the power consumption is 9
It can be doubled to 64 times.

【0044】このようにして形成した本発明による多層
構造のハニカム体は、重量及び圧力損失を増加させるこ
となく大幅な消費電力の増加を計ることができる。
The honeycomb body having a multilayer structure according to the present invention formed in this manner can significantly increase power consumption without increasing weight and pressure loss.

【0045】さらに本発明の基本形式の2層構造を基準
にとれば、3層に積み重ねた場合の消費電力は2.25
倍となる。この場合2.25倍迄の間に更に細かい段階
の消費電力を設定が必要な場合には、図5に示すよう
に、本発明の基本構造である2層積み重ね構造に於て、
板材の全長を変えずに平板1枚を追加することによって
板材の断面積が5/4倍となり、従って消費電力も5/
4倍=1.25倍となる。同様にして2層積み重ね構造
の平板をさらに1枚づつ増すことによって1.5倍、
1.75倍、2.0倍と細かい消費電力の増加設定が可
能となる。
Further, based on the basic two-layer structure of the present invention, the power consumption when stacked in three layers is 2.25.
Double. In this case, when it is necessary to set the power consumption in finer steps up to 2.25 times, in the two-layer stacking structure which is the basic structure of the present invention, as shown in FIG.
By adding one flat plate without changing the total length of the plate material, the cross-sectional area of the plate material becomes 5/4 times, and therefore the power consumption is 5 /
4 times = 1.25 times. In the same way, by adding one more flat plate with a two-layer stack structure one by one,
It is possible to finely increase the power consumption by 1.75 times and 2.0 times.

【0046】このように本発明により2層構造を基本形
式として層の数と平板の枚数の少なくとも何れか一方の
数を増減し、さらに層の巻き取り方向長さを増減するこ
とを併せて行えば、所望の消費電力を有するハニカム体
が得られる。
As described above, according to the present invention, the number of layers and / or the number of flat plates is increased / decreased and the length in the winding direction of the layers is further increased / decreased based on the two-layer structure as a basic form. Then, a honeycomb body having desired power consumption can be obtained.

【0047】[0047]

【発明の効果】以上説明したように本発明は1枚の波板
材と少なくとも1枚の平板材とが重なり合って形成され
た層を少なくとも2層重ねて、少なくとも1層の波板材
が電気絶縁性被膜を施されて接合されることなく配設さ
れ、ロール状に巻かれて形成された、軸方向長さが短い
電気加熱式の第1のハニカム体を形成し、その下流に直
列に所定の間隔を隔てて、主要な触媒担体をなす第2の
ハニカム体を配設して、両ハニカム体の対向する端部の
間に複数の間隔片を設けたため、第1のハニカム体がガ
ス流によってテレスコーピングを発生するのを防止でき
るという効果がある。
As described above, according to the present invention, at least two layers formed by overlapping one corrugated sheet material and at least one flat sheet material are stacked, and at least one corrugated sheet material is electrically insulating. A first electrically heated honeycomb body having a short axial length, which is formed by coating without being bonded and is wound into a roll, is formed. The second honeycomb body, which is the main catalyst carrier, is arranged at intervals, and the plurality of spacing pieces are provided between the opposite ends of both the honeycomb bodies. There is an effect that it is possible to prevent the occurrence of telescoping.

【0048】したがって第1のハニカム体に設けた中心
電極を第2のハニカム体まで延長して保持させる必要が
ないため、第2のハニカム体に電気的絶縁を考慮する必
要がなくて構造が簡単となり、かつ第1のハニカム体と
第2のハニカム体を同一の保持筒の中へ無理なく装入で
き、また両ハニカム体の熱による膨張・収縮に際しても
無理がかからないため、耐久性が向上するという効果を
奏する。
Therefore, since it is not necessary to extend and hold the center electrode provided in the first honeycomb body to the second honeycomb body, it is not necessary to consider electrical insulation in the second honeycomb body, and the structure is simple. In addition, the first honeycomb body and the second honeycomb body can be charged into the same holding cylinder without difficulty, and since the honeycomb body can be expanded and contracted by heat, durability is improved. Has the effect.

【0049】さらにまた、第1のハニカム体の積み重ね
た層の数と平板材の枚数のうちの少なくとも何れか一方
の数を増減するか、或いはさらに層の巻き取り方向の長
さを増減することによって、設計時の消費電力を広範囲
にかつ細かく設定出来るようにしたため、ハニカム体の
重量や圧力損失を増加させず、均一に加熱可能でろう付
け部分が過熱せず、加熱速度が速く、テレスコーピング
を生じる恐れがなく、かつ消費電力に対する客先の細か
いニーズに対応できるという効果がある。
Furthermore, the number of at least one of the number of stacked layers and the number of flat plate materials of the first honeycomb body is increased or decreased, or the length of the layers in the winding direction is increased or decreased. As a result, the power consumption during design can be set in a wide range and finely, so that the weight and pressure loss of the honeycomb body can not be increased, the heating can be done uniformly, the brazing part does not overheat, the heating speed is fast, and telescoping is possible. It is possible to meet the detailed needs of customers regarding power consumption without fear of causing power consumption.

【図面の簡単な説明】[Brief description of drawings]

【図1】(A)は本発明の電気加熱式触媒装置用メタル
担体の軸を含む断面略図、(B)はサポートピンの外観
の斜視図、(C)は(A)の中の第2のハニカム体の外
観の斜視略図である。
FIG. 1 (A) is a schematic cross-sectional view including a shaft of a metal carrier for an electrically heated catalyst device of the present invention, (B) is a perspective view of an outer appearance of a support pin, and (C) is a second part of (A). 2 is a schematic perspective view of the appearance of the honeycomb body of FIG.

【図2】図1(A)の第1のハニカム体の板材の構成を
示す模式的断面図である。
FIG. 2 is a schematic cross-sectional view showing the configuration of the plate material of the first honeycomb body of FIG. 1 (A).

【図3】(A),(B)は本発明のそれぞれ別の実施例
の軸を含む断面略図である。
3 (A) and 3 (B) are schematic cross-sectional views including axes of different embodiments of the present invention.

【図4】本発明の電気加熱式触媒装置用メタル担体の、
種々の多層構造を示す模式的断面と、基準層と比較した
各多層構造の消費電力の比較を示す図表である。
FIG. 4 shows a metal carrier for an electrically heated catalyst device according to the present invention,
3 is a schematic cross-sectional view showing various multilayer structures and a chart showing a comparison of power consumption of each multilayer structure in comparison with a reference layer.

【図5】本発明の電気加熱式触媒装置用メタル担体の、
多層+平板多重構造の消費電力の比較を示す図表であ
る。
FIG. 5 shows a metal carrier for an electrically heated catalyst device according to the present invention,
It is a chart which shows the comparison of power consumption of a multilayer + flat plate multiplex structure.

【図6】従来の技術による電気加熱式触媒装置用メタル
担体の軸を含む断面略図である。
FIG. 6 is a schematic cross-sectional view including a shaft of a metal carrier for an electrically heated catalyst device according to a conventional technique.

【図7】従来の技術による別の電気加熱式触媒装置用メ
タル担体の軸を含む断面略図である。
FIG. 7 is a schematic cross-sectional view including a shaft of another metal carrier for an electrically heated catalyst device according to the related art.

【図8】従来の技術による電気加熱式触媒装置用メタル
担体の図で、(A)は板材の構成を示す模式図、(B)
はハニカム体の軸に直角な断面略図である。
FIG. 8 is a diagram of a metal carrier for an electrically heated catalyst device according to a conventional technique, (A) is a schematic diagram showing a configuration of a plate material, and (B) is a diagram.
[Fig. 3] is a schematic cross-sectional view perpendicular to the axis of the honeycomb body.

【図9】従来の技術による電気加熱式触媒装置用メタル
担体の図で、(A)は板材の構成を示す図、(B)はハ
ニカム体の斜視図である。
[Fig. 9] Fig. 9 is a view of a metal carrier for an electrically heated catalyst device according to a conventional technique, (A) is a view showing a configuration of a plate material, and (B) is a perspective view of a honeycomb body.

【符号の説明】[Explanation of symbols]

1,41,51 波板材/波板 21 ,22 ,42,52 平板材/平板 3,43,53, 絶縁用波板 4,5 電極 10,30 メタル担体 11,21 第1のハニカム体 12,22 第2のハニカム体 11a,12a 外筒 13 間隔片/サポートピン 13a,13b 端面 13c 軸部 14 絶縁体 15 保持筒 16,26 中心電極 17 外周電極 31 第1のメタル担体 32 第2のメタル担体 40,50 ハニカム体1,41,51 Corrugated sheet material / corrugated sheet 2 1 , 2 2 , 42,52 Flat plate material / flat plate 3,43,53, Corrugated sheet for insulation 4,5 Electrode 10,30 Metal carrier 11,21 First honeycomb body 12, 22 Second honeycomb body 11a, 12a Outer cylinder 13 Spacing piece / support pin 13a, 13b End face 13c Shaft portion 14 Insulator 15 Holding cylinder 16,26 Center electrode 17 Outer peripheral electrode 31 First metal carrier 32 Second Metal carrier 40,50 Honeycomb body

Claims (7)

【特許請求の範囲】[Claims] 【請求項1】 帯状をなす薄い金属板を折曲げて連続的
な波形の凹凸を形成した1枚の波板材と、平坦な帯状を
なす薄い金属板からなる少なくとも1枚の平板材とが相
互に当接して重なり合って形成された層が、少なくとも
2層以上積み重ねられてロール状に巻かれて形成されて
多数の網目状通気路を備えたハニカム体をなし、 前記積み重ねられた層のうちの少なくとも1層の前記波
板材が、電気絶縁性被膜層を施されて接合されることな
く前記ロール状に巻回された層間を電気的に絶縁し、前
記ハニカム体の中心部に中心電極を有し、前記ハニカム
体の外周部に前記中心電極と逆性の外周電極を有し、前
記中心電極と前記外周電極との間に電流を流すことによ
り前記ハニカム体を加熱する、軸方向長さが短い第1の
ハニカム体と、 帯状をなす薄い金属板を折り曲げて連続的な波形の凹凸
を形成した波板材と、平坦な帯状をなす薄い金属板から
なる平板材とが相互に当接して重なり合いロール状に巻
かれて形成されて多数の網目状通気路を備えたハニカム
体をなし、前記第1のハニカム体の下流に直列にかつ間
隔を置いて配設された第2のハニカム体と、 前記第1と第2のハニカム体を覆って両ハニカム体を保
持する保持筒とを含む、電気加熱式触媒装置用メタル担
体において、 前記第1と第2のハニカム体の、対向する軸方向端部に
当接する複数の間隔片を有することを特徴とする、電気
加熱式触媒装置用メタル担体。
1. A corrugated sheet material in which a strip-shaped thin metal plate is bent to form continuous corrugations and at least one flat plate material made of a flat strip-shaped thin metal plate are mutually provided. A layer formed by abutting on and overlapping with each other to form a honeycomb body having a large number of mesh-like ventilation passages formed by stacking and winding at least two layers, At least one layer of the corrugated sheet material is provided with an electrically insulating coating layer to electrically insulate the layers wound in the roll shape without being joined, and has a center electrode at the center of the honeycomb body. The outer peripheral portion of the honeycomb body has an outer peripheral electrode that is reverse to the center electrode, and the honeycomb body is heated by passing a current between the center electrode and the outer peripheral electrode. A short first honeycomb body and a strip shape A corrugated sheet material formed by bending a thin metal plate to form continuous corrugations and a flat sheet material made of a thin metal sheet in a flat band shape are abutted against each other and overlapped and wound into a roll shape. A honeycomb body having a mesh-like ventilation path is formed, and a second honeycomb body is provided downstream of the first honeycomb body in series and at a distance, and covers the first and second honeycomb bodies. In the metal carrier for an electrically heated catalyst device, which includes a holding cylinder for holding both honeycomb bodies, a plurality of spacing pieces abutting the facing axial ends of the first and second honeycomb bodies. A metal carrier for an electrically heated catalyst device, comprising:
【請求項2】 前記間隔片は、前記ハニカム体の軸に直
角な両端面を有し、該端面の大きさは、第1のハニカム
体を形成する前記通気路1個の寸法より大なる寸法を有
し、前記両端面の一方が、前記軸に平行な軸部を有し、
該軸部が第2のハニカム体を形成する前記通気路1個に
装入可能でかつ該通気路とろう付けにより接合可能な形
状を有する、請求項1に記載の電気加熱式触媒装置用メ
タル担体。
2. The spacing piece has both end faces perpendicular to the axis of the honeycomb body, and the size of the end faces is larger than the size of one ventilation passage forming the first honeycomb body. And one of the both end surfaces has a shaft portion parallel to the shaft,
The metal for an electrically heated catalyst device according to claim 1, wherein the shaft portion has a shape that can be inserted into the one ventilation passage forming the second honeycomb body and can be joined to the ventilation passage by brazing. Carrier.
【請求項3】 前記間隔片の前記軸部が、第2のハニカ
ム体の前記端部から5mm以上装入される、請求項2に
記載の電気加熱式触媒装置用メタル担体。
3. The metal carrier for an electrically heated catalyst device according to claim 2, wherein the shaft portion of the spacing piece is inserted from the end portion of the second honeycomb body by 5 mm or more.
【請求項4】 前記複数の間隔片の前記端面の面積の合
計が、ハニカム体の通気路断面積合計の30%以下であ
る、請求項1ないし3に記載の電気加熱式触媒装置用メ
タル担体。
4. The metal carrier for an electrically heated catalyst device according to claim 1, wherein the total area of the end faces of the plurality of spacing pieces is 30% or less of the total cross-sectional area of the ventilation passages of the honeycomb body. .
【請求項5】 前記間隔片の材料が金属材料である、請
求項1ないし4に記載の電気加熱式触媒装置用メタル担
体。
5. The metal carrier for an electrically heated catalyst device according to claim 1, wherein the material of the spacing piece is a metal material.
【請求項6】 前記間隔片の、少なくとも前記第1のハ
ニカム体に当接する前記端面が、電気絶縁性被膜層を有
する、請求項1ないし5に記載の電気加熱式触媒装置用
メタル担体。
6. The metal carrier for an electrically heated catalyst device according to claim 1, wherein at least the end surface of the spacing piece that is in contact with the first honeycomb body has an electrically insulating coating layer.
【請求項7】 前記間隔片の材料が耐熱電気絶縁材料で
ある、請求項1ないし4に記載の電気加熱式触媒装置用
メタル担体。
7. The metal carrier for an electrically heated catalyst device according to claim 1, wherein the material of the spacing piece is a heat resistant electrical insulating material.
JP8030835A 1996-02-19 1996-02-19 Metal carrier for electrically-heated catalytic device Pending JPH09220481A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP8030835A JPH09220481A (en) 1996-02-19 1996-02-19 Metal carrier for electrically-heated catalytic device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP8030835A JPH09220481A (en) 1996-02-19 1996-02-19 Metal carrier for electrically-heated catalytic device

Publications (1)

Publication Number Publication Date
JPH09220481A true JPH09220481A (en) 1997-08-26

Family

ID=12314765

Family Applications (1)

Application Number Title Priority Date Filing Date
JP8030835A Pending JPH09220481A (en) 1996-02-19 1996-02-19 Metal carrier for electrically-heated catalytic device

Country Status (1)

Country Link
JP (1) JPH09220481A (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
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JP2010528219A (en) * 2007-05-31 2010-08-19 エミテック ゲゼルシヤフト フユア エミツシオンス テクノロギー ミツト ベシユレンクテル ハフツング Electrothermal honeycomb construction with support pins
JP2013036468A (en) * 2007-05-31 2013-02-21 Emitec Ges Fuer Emissionstechnologie Mbh Electrothermic honeycomb structure with support pin
JP2013538678A (en) * 2010-08-13 2013-10-17 エミテック ゲゼルシヤフト フユア エミツシオンステクノロギー ミツト ベシユレンクテル ハフツング Holder for at least one electrode of the exhaust gas line
JP2014503344A (en) * 2010-11-26 2014-02-13 エミテック ゲゼルシヤフト フユア エミツシオンステクノロギー ミツト ベシユレンクテル ハフツング Interconnection of two exhaust gas treatment equipment
DE102011120720A1 (en) * 2011-12-12 2013-06-13 Emitec Gesellschaft Für Emissionstechnologie Mbh Support pin for an electrically heatable honeycomb body
JP2015500937A (en) * 2011-12-12 2015-01-08 エミテック ゲゼルシヤフト フユア エミツシオンステクノロギー ミツト ベシユレンクテル ハフツング Support pins for electrically heatable honeycomb bodies
US9316134B2 (en) 2011-12-12 2016-04-19 Emitec Gesellschaft Fuer Emissionstechnologie Mbh Supporting pin for an electrically heatable honeycomb body

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