JPH09192499A - Metal carrier for electrically-heated catalytic device - Google Patents
Metal carrier for electrically-heated catalytic deviceInfo
- Publication number
- JPH09192499A JPH09192499A JP8010008A JP1000896A JPH09192499A JP H09192499 A JPH09192499 A JP H09192499A JP 8010008 A JP8010008 A JP 8010008A JP 1000896 A JP1000896 A JP 1000896A JP H09192499 A JPH09192499 A JP H09192499A
- Authority
- JP
- Japan
- Prior art keywords
- honeycomb body
- honeycomb
- flat
- metal carrier
- stopper assembly
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 69
- 239000002184 metal Substances 0.000 title claims abstract description 69
- 230000003197 catalytic effect Effects 0.000 title claims abstract description 5
- 238000005096 rolling process Methods 0.000 claims abstract description 3
- 239000000463 material Substances 0.000 claims description 53
- 239000003054 catalyst Substances 0.000 claims description 35
- 239000010410 layer Substances 0.000 claims description 30
- 230000004323 axial length Effects 0.000 claims description 15
- 238000009423 ventilation Methods 0.000 claims description 14
- 239000011247 coating layer Substances 0.000 claims description 9
- 230000002093 peripheral effect Effects 0.000 claims description 9
- 238000000429 assembly Methods 0.000 claims description 3
- 230000000712 assembly Effects 0.000 claims description 3
- 238000005452 bending Methods 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 abstract description 5
- 238000000576 coating method Methods 0.000 abstract description 5
- 238000011144 upstream manufacturing Methods 0.000 abstract 1
- 238000005219 brazing Methods 0.000 description 10
- 238000000034 method Methods 0.000 description 8
- 229910052782 aluminium Inorganic materials 0.000 description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 7
- 238000004804 winding Methods 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 230000008646 thermal stress Effects 0.000 description 5
- 238000002485 combustion reaction Methods 0.000 description 4
- 238000005485 electric heating Methods 0.000 description 4
- 238000009413 insulation Methods 0.000 description 4
- 238000005304 joining Methods 0.000 description 4
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 4
- 238000003466 welding Methods 0.000 description 4
- 238000006555 catalytic reaction Methods 0.000 description 3
- 239000012212 insulator Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 230000008602 contraction Effects 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000010292 electrical insulation Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000007733 ion plating Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910000510 noble metal Inorganic materials 0.000 description 2
- 238000005240 physical vapour deposition Methods 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000003989 dielectric material Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
Landscapes
- Catalysts (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は内燃機関の排気ガス
浄化装置に用いられるハニカム体をなす触媒装置用メタ
ル担体に関し、特に電気加熱式触媒装置用メタル担体に
関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a catalyst carrier metal carrier used in an exhaust gas purifying apparatus for an internal combustion engine, and more particularly to an electrically heated catalyst carrier metal carrier.
【0002】[0002]
【従来の技術】従来の排気ガス浄化装置に用いられる触
媒装置用メタル担体は、薄い金属の平板と波板の間にろ
う材を介在させて、平板と波板を重ねて中心からロール
状に巻き込んでハニカム体を形成し、高真空炉を使用し
てろう材を溶融させ、板材の接触部分において接合を行
っていた。ろう材にはNi基ろう材を用い、平板と波板
にはフェライト系ステンレス材料が使用されていた。そ
のようにして形成されたハニカム体を金属製外筒内に収
容したものが触媒装置用メタル担体として知られている
(例えば特開昭65−4373号公報)。2. Description of the Related Art A metal carrier for a catalyst device used in a conventional exhaust gas purifying apparatus has a brazing filler metal interposed between a thin metal flat plate and a corrugated plate, and the flat plate and the corrugated plate are superposed and rolled into a roll from the center. A honeycomb body is formed, a brazing material is melted using a high vacuum furnace, and joining is performed at a contact portion of the plate materials. A Ni-based brazing material was used as the brazing material, and a ferritic stainless steel material was used as the flat plate and the corrugated plate. A honeycomb carrier formed in such a manner and housed in a metal outer cylinder is known as a metal carrier for a catalyst device (for example, JP-A-65-4373).
【0003】ハニカム体のハニカム通路表面には触媒担
持層が形成され、その触媒担持層に貴金属触媒が担持さ
れて排気ガス浄化触媒の役目をなす。そして内燃機関の
排気通路に配設されて排気ガス中のHC、CO、NOx
などを浄化する。なお限られた容積中にできるだけ多く
のハニカム通路面積を確保する必要から、平板および波
板の厚さは強度を維持できる範囲内でできるだけ薄くな
っている。[0003] A catalyst carrying layer is formed on the surface of the honeycomb passage of the honeycomb body, and the noble metal catalyst is carried on the catalyst carrying layer to serve as an exhaust gas purifying catalyst. HC, CO, and NOx contained in the exhaust gas are provided in the exhaust passage of the internal combustion engine.
Etc. Since it is necessary to secure as large a honeycomb passage area as possible in a limited volume, the thickness of the flat plate and the corrugated plate is made as thin as possible within a range where strength can be maintained.
【0004】上述した触媒担持層に担持された貴金属触
媒は、ある程度の高温環境下で触媒反応が促進されるの
で、触媒装置はできるだけ、高温の排気ガスに曝される
ように内燃機関の排気弁の近くに設けられている。Since the catalytic reaction of the noble metal catalyst supported on the catalyst supporting layer described above is promoted in a high temperature environment to some extent, the exhaust gas of the internal combustion engine is exhausted so that the catalytic device is exposed to the exhaust gas at a temperature as high as possible. It is provided near the.
【0005】また、ハニカム体を通過する排気ガスの流
速がハニカム体の外層部より内層部に至るほど大きく、
したがってハニカム体では高温の排気ガスとの接触、触
媒反応による発熱および外筒からの熱放散により、内層
部ほど高温で外層部ほど低温となる温度分布を生じる。
この温度分布により、温度の高いハニカム体の内層部の
膨張・収縮量が、温度の低い外層部の膨張・収縮量より
大となるため、内層部と外層部との間に熱応力が発生す
る。この熱応力は、ハニカム体の膨張・収縮の度に繰り
返されるが、従来の触媒装置用メタル担体においては、
全ての平板材と波板材とがろう材を介して一体にろう付
けされているため熱応力を逃がすことができず、長期間
の使用により平板材と波板材との接合箇所が破断すると
いう欠点がある。Further, the flow velocity of the exhaust gas passing through the honeycomb body is higher from the outer layer portion to the inner layer portion of the honeycomb body,
Therefore, in the honeycomb body, due to contact with high-temperature exhaust gas, heat generation due to catalytic reaction, and heat dissipation from the outer cylinder, a temperature distribution is generated in which the inner layer portion is hotter and the outer layer portion is colder.
Due to this temperature distribution, the expansion / contraction amount of the inner layer portion of the high temperature honeycomb body becomes larger than the expansion / contraction amount of the outer layer portion of the low temperature, so that thermal stress is generated between the inner layer portion and the outer layer portion. . This thermal stress is repeated every time the honeycomb body expands and contracts, but in the conventional metal carrier for a catalyst device,
Since all flat plates and corrugated sheets are brazed together via brazing filler metal, thermal stress cannot be released, and the joints between flat sheets and corrugated sheets are broken after long-term use. There is.
【0006】この欠点を除くため、ハニカム体を形成す
る平板を2枚以上重ね、それら平板同志の間は接合せず
単に重ねられており、さらに2枚の平板の間に第2の波
板を接合することなく配設して、接合されない平板の間
および平板と第2の波板の間が、互いに自由に滑って熱
応力が緩和されるメタル担体が開示されている。In order to eliminate this defect, two or more flat plates forming the honeycomb body are stacked, and the flat plates are simply stacked without being joined, and a second corrugated plate is further placed between the two flat plates. Disclosed is a metal carrier which is disposed without being joined and between which flat plates are not joined and between the flat plate and the second corrugated plate are freely slid to relax thermal stress.
【0007】しかしながら、このような触媒装置用メタ
ル担体においては、内燃機関の始動時には排気ガスの温
度が低いため触媒反応が充分に行われず、そのため排気
ガス中のHC,CO,NOxなどを浄化する能力が不充
分となる。この欠点を除くため種々の電気加熱式触媒装
置用メタル担体が開示されていて、始動時にメタル担体
を電気的に加熱して触媒反応を促進するようになってい
る。However, in such a metal carrier for a catalyst device, the catalyst reaction is not sufficiently performed because the temperature of the exhaust gas is low at the time of starting the internal combustion engine, so that HC, CO, NOx, etc. in the exhaust gas are purified. Inadequate ability. In order to eliminate this drawback, various metal carriers for electrically heated catalyst devices have been disclosed, and the metal carriers are electrically heated at the time of starting to promote the catalytic reaction.
【0008】上述のように、複数の平板とそれら平板の
間に第2の波板を装入した形式のハニカム体において
は、第2の波板の表面に酸化アルミニウムなどの被膜層
を施して、ハニカム体のロール状に巻き回された層の間
を電気的に絶縁し、ハニカム体の巻き始めと巻き終りの
板材の端部にそれぞれ電源と接続するための電極を設け
て、ハニカム体の巻き取り方向に電流を流す方式が採用
されている。このようなハニカム体全体を加熱する電気
加熱式メタル担体では、同じ外形の場合に軸方向の長さ
が短い方が同じ消費電力に対して所要温度までの加熱時
間は短くなる。As described above, in the honeycomb body of the type in which a plurality of flat plates and the second corrugated plate are inserted between the flat plates, a coating layer of aluminum oxide or the like is formed on the surface of the second corrugated plate. , Electrically insulating between the layers wound in a roll shape of the honeycomb body, and providing electrodes for connecting to the power source at the ends of the plate material at the beginning and end of the winding of the honeycomb body, respectively. A method of passing an electric current in the winding direction is adopted. In such an electrically heated metal carrier for heating the entire honeycomb body, the shorter the axial length is, the shorter the heating time to the required temperature is for the same power consumption when the outer shape is the same.
【0009】したがって、容量の大きいメタル担体や、
容量は小さいがより少ない消費電力で有効な電気加熱を
行わんとする電気加熱式メタル担体では、図4に示すよ
うにメタル担体30の中のハニカム体を2分割して、電
気加熱するのに適当な容量の第1のメタル担体31と、
加熱部分を含まない主要なメタル担体を形成する第2の
メタル担体32とを直列に配設したものが開示されてい
る。Therefore, a metal carrier having a large capacity,
In the electric heating type metal carrier which has a small capacity but is effective for electric heating with less power consumption, a honeycomb body in the metal carrier 30 is divided into two as shown in FIG. A first metal carrier 31 having an appropriate capacity,
It is disclosed that a second metal carrier 32 forming a main metal carrier that does not include a heating portion is arranged in series.
【0010】図4において、第1のメタル担体31の容
量が小さく、軸方向の長さが例えば20mm以下のよう
に短い場合には、第1のメタル担体は絶縁用波板に施さ
れた絶縁層のために、絶縁用波板はろう材による接合が
行なわれず、さらにまた、複数枚の平板の間も熱応力を
逃すため通常接合を行なわないので、使用中に層がずれ
て所謂テレスコーピングが生じるという欠点がある。こ
の現象を防止するため、図5に示すように、電気加熱式
の第1のハニカム体21の中心部に設けられた中心電極
26を延長して第2のハニカム体22の中心部に装入
し、第1のハニカム体21の中心部と第2のハニカム体
22の中心部とを結合することによってテレスコーピン
グを防止している。In FIG. 4, when the capacity of the first metal carrier 31 is small and the axial length thereof is short, for example, 20 mm or less, the first metal carrier 31 is insulated from the insulating corrugated plate. Because of the layers, the insulating corrugated sheet is not joined by the brazing material, and further, because the thermal stress is also released between the flat plates, the joining is not normally performed, so the layers are displaced during use, so-called telescoping. There is a drawback that In order to prevent this phenomenon, as shown in FIG. 5, the central electrode 26 provided in the central portion of the electrically heated first honeycomb body 21 is extended and charged into the central portion of the second honeycomb body 22. However, the central portion of the first honeycomb body 21 and the central portion of the second honeycomb body 22 are joined together to prevent telescoping.
【0011】[0011]
【発明が解決しようとする課題】上述の第1のハニカム
体の中心部の中心電極を延長して第2のハニカム体に結
合し、第1のハニカム体のテレスコーピングを防止する
方法において、第1のハニカム体のうち軸方向に固定さ
れている部分は、中心電極に近い部分と外筒に近い部分
だけで、その他の部分は充分に固定されていないためテ
レスコーピングを完全に防止できないという欠点がある
ほか、第1と第2のハニカム体の中心部分の位置がそれ
ぞれのハニカム体で異なるために、保持筒に装入する場
合無理な心合わせを行うため、加熱の際に第1のハニカ
ム体が変形するという欠点がある。さらに電気加熱を行
わない第2のハニカム体においても絶縁を考慮する必要
があるため構造が複雑になるという欠点がある。In the method for preventing telescoping of the first honeycomb body by extending the center electrode of the central portion of the first honeycomb body and bonding it to the second honeycomb body, A part of the honeycomb body 1 fixed in the axial direction is only a part close to the center electrode and a part close to the outer cylinder, and the other parts are not sufficiently fixed, so that telescoping cannot be completely prevented. In addition, since the positions of the central portions of the first and second honeycomb bodies are different in the respective honeycomb bodies, the first honeycomb is heated during heating in order to perform unreasonable centering when charging the holding cylinder. It has the drawback of deforming the body. Further, in the second honeycomb body which is not electrically heated, there is a drawback that the structure becomes complicated because it is necessary to consider insulation.
【0012】本発明の目的は、軸方向長さが短くテレス
コーピングを生じ易い電気加熱式メタル担体のテレスコ
ーピングを防止することにある。An object of the present invention is to prevent telescoping of an electrically heated metal carrier which has a short axial length and tends to cause telescoping.
【0013】[0013]
【課題を解決するための手段】本発明の電気加熱式触媒
装置用メタル担体は、帯状をなす薄い金属板を折曲げて
連続的な波形の凹凸を形成した1枚の波板材と、平坦な
帯状をなす薄い金属板からなる複数枚の平板材とが相互
に当接して重なり合い、かつ複数枚の平板材の中の隣り
合う2枚の間に、電気絶縁性被膜層を有する絶縁用波板
が接合されることなく配設され、ロール状に巻かれて形
成されて多数の網目状通気路を備えたハニカム体をな
し、ハニカム体のロール状に巻き回された層間が電気的
に絶縁され、ハニカム体の中心部に中心電極を有し、ハ
ニカム体の外周部に中心電極と逆性の外周電極を有す
る、軸方向長さが短い第1のハニカム体と、帯状をなす
薄い金属板を折曲げて連続的な波形の凹凸を形成した波
板材と、平坦な帯状をなす薄い金属板からなる平板材と
が相互に当接して重なり合い、ロール状に巻かれて形成
されて多数の網目状通気路を備えたハニカム体をなし、
第1のハニカム体の下流に直列にかつ間隔を置いて配設
された第2のハニカム体と、第1と第2のハニカム体を
覆って両ハニカム体を保持する保持筒とを含む、電気加
熱式触媒装置用メタル担体において、第1のハニカム体
と第2のハニカム体の間の所定の間隔内に配設されて保
持筒に保持され、両ハニカム体の対向する軸方向両端面
に当接し、また少なくとも第1のハニカム体に当接する
部分が電気的に絶縁された、第1のハニカム体が第2の
ハニカム体の方向へ軸方向に移動するのを防止するため
の、ストッパ組立体を有している。MEANS FOR SOLVING THE PROBLEMS The metal carrier for an electrically heated catalyst device of the present invention comprises a corrugated sheet material formed by bending a thin metal sheet in the form of a strip to form continuous corrugation, and a flat corrugated sheet material. An insulating corrugated plate having a plurality of flat plate members made of thin metal plates in a belt shape and abutting on each other, and having an electrically insulating coating layer between two adjacent flat plate members. Are arranged without being joined, and form a honeycomb body provided with a large number of mesh-like ventilation passages formed by being wound in a roll shape, and the layers wound in a roll shape of the honeycomb body are electrically insulated from each other. A first honeycomb body having a short axial length and having a central electrode in the central portion of the honeycomb body and an outer peripheral electrode opposite to the central electrode in the outer peripheral portion of the honeycomb body; A corrugated sheet material that is bent to form a continuous corrugated surface and a flat strip A plate material made to a thin metal plate overlap in contact with each other, forms a honeycomb body having a large number of mesh-like air passage is formed is wound into a roll,
An electric machine including a second honeycomb body arranged in series at a distance downstream of the first honeycomb body, and a holding cylinder that covers the first and second honeycomb bodies and holds both the honeycomb bodies. In a metal carrier for a heating-type catalyst device, the honeycomb carrier is arranged in a predetermined space between a first honeycomb body and a second honeycomb body and is held by a holding cylinder, and both end faces of the honeycomb body facing each other in an axial direction are contacted with each other. A stopper assembly for preventing the first honeycomb body from moving axially in the direction of the second honeycomb body, which is electrically insulated at least in contact with the first honeycomb body. have.
【0014】前述のストッパ組立体は、帯状をなす薄い
金属板を折曲げて連続的な波形の凹凸を形成した波板材
と、平坦な帯状をなす薄い金属板からなる平板材とが、
相互に当接して重なり合って、ロール状に巻かれて形成
された多数の網目状通気路を備え、軸方向長さが所定の
間隔に等しいハニカム体をなし、別のストッパ組立体
は、第1と第2のハニカム体の対向する両端面に当接す
る長辺と、保持筒に内接する短辺とを有する長方形の、
薄い金属板からなる複数の平板と、長方形の平板の間を
連結して平板を第1と第2のハニカム体の対向する両端
面に垂直に保持する、中心軸とほぼ同心に配設された薄
い金属板からなる少なくとも1個の円筒とを含んで形成
されている。In the stopper assembly described above, a corrugated sheet material in which a strip-shaped thin metal plate is bent to form continuous corrugated irregularities, and a flat sheet material made of a flat strip-shaped thin metal plate are provided.
A honeycomb body is provided which has a plurality of mesh-shaped ventilation passages formed by being wound in a roll shape so as to be in contact with each other and overlapped with each other, and a honeycomb body having an axial length equal to a predetermined interval is formed. And a rectangular shape having long sides in contact with the opposite end surfaces of the second honeycomb body and short sides inscribed in the holding cylinder,
A plurality of flat plates made of thin metal plates and rectangular flat plates are connected to each other to hold the flat plates perpendicularly to opposite end faces of the first and second honeycomb bodies, and are arranged substantially concentric with the central axis. It is formed by including at least one cylinder made of a thin metal plate.
【0015】またハニカム体をなすストッパ組立体の網
目状通気路の密度は、第1のハニカム体の網目状通気路
の密度に等しいか又はそれ以下であることが好ましい。The density of the mesh-like ventilation passages of the stopper assembly forming the honeycomb body is preferably equal to or lower than the density of the mesh-like ventilation passages of the first honeycomb body.
【0016】[0016]
【発明の実施の形態】本発明の電気加熱式触媒装置用メ
タル担体は、巾の狭い金属板で形成された1枚の波板材
と複数枚の平板材とを重ね合わせ、さらに複数枚の平板
材の中の隣り合う2枚の間に、電気絶縁被膜層を有する
絶縁用波板を接合されることなく配設して、ロール状に
巻き回して軸方向長さが短いハニカム体を形成し、ロー
ルの巻き始めと巻き終りにそれぞれ電極を設けて電気加
熱を可能とした第1のハニカム体を形成し、別の波板材
と平板材とを重ね合わせてロール状に巻いて第2のハニ
カム体を形成して、第1のハニカム体の下流に直列に、
所定の間隔を隔てて配設し、所定の間隔内には、対向す
る両ハニカム体の端部に当接する1個のストッパ組立体
を配設して、第1、第2のハニカム体およびストッパ組
立体を、それらの外径と等しい内径を有する保持筒の中
に収容して形成される。BEST MODE FOR CARRYING OUT THE INVENTION The metal carrier for an electrically heated catalyst device of the present invention comprises a corrugated sheet material formed of a narrow metal plate and a plurality of flat sheet materials, and a plurality of flat sheets. An insulating corrugated sheet having an electric insulating coating layer is provided between two adjacent sheets of the material without being joined and wound in a roll shape to form a honeycomb body having a short axial length. Forming a first honeycomb body that can be electrically heated by providing electrodes at the beginning and the end of winding of the roll, and stacking another corrugated plate material and a flat plate material on each other to form a second honeycomb body Form a body, in series downstream of the first honeycomb body,
The first and second honeycomb bodies and the stoppers are arranged at predetermined intervals, and one stopper assembly that abuts against the end portions of the two honeycomb bodies facing each other is arranged within the predetermined space. The assembly is formed by being housed in a retaining tube having an inner diameter equal to their outer diameter.
【0017】第2のハニカム体は、触媒を担持する主担
体であるため、通常軸方向長さを外径よりも大きくとる
ので、ガス流による軸方向下流へ向かってテレスコーピ
ングが発生することは極めて少ない。これに反し第1の
ハニカム体は、上述の如く電気加熱式ハニカム体であっ
て、より少ない消費電力で有効な電気加熱を行なう必要
があるため、軸方向長さを外径に比べて極めて短くし、
さらにまた互いに接合されない複数の平板材を有する平
板多重構造や、平板材と波板材を重ね合わせた層が2層
以上積み重ねられて形成される多層構造のハニカム体の
ような、板材の軸方向の拘束力が極めて小さい構造をと
るので、ガス流によるテレスコーピングが発生し易い構
造となっている。Since the second honeycomb body is the main carrier for supporting the catalyst, it usually has a length in the axial direction larger than the outer diameter, so that telescoping does not occur downstream in the axial direction due to the gas flow. Very few. On the contrary, the first honeycomb body is an electric heating type honeycomb body as described above, and since it is necessary to perform effective electric heating with less power consumption, the axial length is extremely shorter than the outer diameter. Then
Furthermore, in the flat plate multiple structure having a plurality of flat plate members that are not joined to each other, or in the axial direction of the plate members such as a honeycomb body having a multilayer structure formed by stacking two or more layers in which flat plate members and corrugated plate members are stacked. Since the binding force is extremely small, telescoping due to the gas flow is likely to occur.
【0018】本発明による上述のストッパ組立体は、第
1のハニカム体と第2のハニカム体の間の所定の間隔内
に配設されて、両ハニカム体の対向する端面に当接して
保持筒の中に収容されているから、第1のハニカム体が
ガス流により第2のハニカム体に向ってテレスコーピン
グを起こしたとき、これを防止することができる。The above-mentioned stopper assembly according to the present invention is arranged within a predetermined space between the first honeycomb body and the second honeycomb body, and abuts against the opposing end faces of both honeycomb bodies to hold the holding cylinder. Since the first honeycomb body is telescoped toward the second honeycomb body by the gas flow, this can be prevented.
【0019】本発明によるストッパ組立体の構造は、 1.波板材と平板材とを重ね合せてロール状に巻いて形
成したハニカム構造であって、外径が第1、第2のハニ
カム体と同一であり、軸方向長さが第1と第2のハニカ
ム体の間の所定の間隔と同じで、かつ両端面に於て第1
と第2のハニカム体の対向する端面に当接するように形
成され、かつ少なくとも第1のハニカム体に接する端面
の部分には電気絶縁層が施されており、または、 2.第1と第2のハニカム体の対向する両端面に当接す
る長辺と、保持筒に内接する短辺とを有する長方形の薄
い金属板からなる複数の平板と、これら平板の間を連結
して平板を第1と第2のハニカム体の対向する両端面に
垂直に保持する少なくとも1個の、中心軸と同軸に配設
された円筒とを含んで形成されている。The structure of the stopper assembly according to the present invention is as follows: The honeycomb structure is formed by stacking a corrugated sheet material and a flat sheet material and winding them in a roll shape. The honeycomb structure has the same outer diameter as that of the first and second honeycomb bodies, and has the first and second axial lengths. It is the same as the predetermined spacing between the honeycomb bodies, and the first
And an electric insulating layer is formed on at least a portion of the end face that is in contact with the opposing end faces of the second honeycomb body and that is in contact with the first honeycomb body, or A plurality of flat plates made of a rectangular thin metal plate having long sides that abut on opposite end surfaces of the first and second honeycomb bodies and short sides that are inscribed in the holding cylinder, and these flat plates are connected to each other. It is formed by including at least one cylinder that holds the flat plate perpendicularly to the opposite end faces of the first and second honeycomb bodies and that is arranged coaxially with the central axis.
【0020】上述のストッパ組立体は、ガス流に対する
通気抵抗が出来るだけ小さい方が好ましく、ハニカム体
をなすストッパ組立体の網目状通気路の密度は、第1の
ハニカム体の密度に対し、等しいか又はそれ以下とす
る。The above-mentioned stopper assembly preferably has as low a ventilation resistance as possible to the gas flow, and the density of the mesh-like ventilation passages of the stopper assembly forming the honeycomb body is equal to the density of the first honeycomb body. Or less.
【0021】さらに、本発明によるメタル担体を上述の
構成としたため、電気的に加熱される第1のハニカム体
の構造が、互いに接合されない複数の平板材を有する平
板多重構造の場合や、2層以上の層が重ね合わされて形
成された多層構造の場合のような、板材の軸方向の拘束
力が極めて小なる場合であっても、テレスコーピングが
発生することはない。Further, since the metal carrier according to the present invention has the above-mentioned structure, the structure of the electrically heated first honeycomb body is a flat plate multiple structure having a plurality of flat plate members which are not joined to each other, or two layers. Telescoping does not occur even when the axial restraining force of the plate material is extremely small as in the case of a multilayer structure formed by stacking the above layers.
【0022】従って、第1のハニカム体の消費電力を設
計するに際し、多層構造において積み重ねる層の数の増
減や、さらに各層の板材の全長の増減によって、比較的
大幅な消費電力の増減を行なうことができ、また平板多
重構造において平板の枚数の増減によって比較的小幅の
消費電力の増減が可能となるので、これらの組み合せに
よって更に細かい客先の消費電力のニーズに合致したハ
ニカム体を提供することが出来る。Therefore, in designing the power consumption of the first honeycomb body, a relatively large power consumption increase / decrease is performed by increasing / decreasing the number of layers to be stacked in the multilayer structure and further increasing / decreasing the total length of the plate material of each layer. In addition, since it is possible to increase and decrease the power consumption in the flat plate multiplex structure by changing the number of flat plates, it is possible to provide a honeycomb body that meets the more detailed power consumption needs of customers by combining these. Can be done.
【0023】導電性の金属材料から作られるストッパ組
立体は、少なくとも電気加熱式の第1のハニカム体に当
接する側の部分に、電気絶縁性被膜層を施す必要があ
る。電気絶縁性被膜層をストッパ組立体に施す方法には
下記の方法がある。すなわち、 イ.物理的方法(PVD)例えば真空蒸着、スパッタ、
イオンプレーティングによって絶縁被膜をコーティン
グ、 ロ.化学的方法(CVD)によって絶縁被膜をコーティ
ング、 ハ.大気焼成によって絶縁性被膜層に変化する材料、例
えばアルミニウムをコーティングした後大気焼成、 ニ.波板又はストッパ組立体の母材に、アルミニウムを
含有するステンレスを用い、形成後大気焼成するか又は
ろう付け後大気焼成して、酸化アルミニウム被膜を析
出、 ホ.形成後又はろう付け後の状態で溶融アルミニウム中
に浸漬し、浸漬中にアルミニウム(Al)と母材中の鉄
(Fe)とを相互拡散させることによって表面に合金層
を形成し、その後大気焼成して酸化アルミニウム被膜を
析出させるなどの方法がある。In the stopper assembly made of a conductive metal material, it is necessary to apply an electrically insulating coating layer to at least a portion of the stopper assembly which comes into contact with the electrically heated first honeycomb body. There are the following methods for applying the electrically insulating coating layer to the stopper assembly. That is, a. Physical methods (PVD) such as vacuum deposition, sputtering,
Insulation coating by ion plating, b. Coating an insulating film by a chemical method (CVD), c. A material that changes to an insulating coating layer by atmospheric baking, such as aluminum, and then baked in air, d. A stainless steel containing aluminum is used as a base material of the corrugated plate or the stopper assembly, and after forming, it is baked in air or after brazing is baked in air to deposit an aluminum oxide film. After being formed or after brazing, it is immersed in molten aluminum, and during the immersion, aluminum (Al) and iron (Fe) in the base material are mutually diffused to form an alloy layer on the surface, and then air baking is performed. Then, the aluminum oxide film is deposited.
【0024】[0024]
【実施例】次に本発明の実施例について図面を参照して
説明する。図1(A)は本発明の電気加熱式触媒装置用
メタル担体の一実施例の軸を含む断面略図、図1(B)
はロール状のハニカム体をなすストッパ組立体の外観の
斜視図、図1(C)は、図1(A)の電気加熱式第1の
ハニカム体の板材の構成を示す模式的断面図である。Next, an embodiment of the present invention will be described with reference to the drawings. FIG. 1 (A) is a schematic cross-sectional view including a shaft of an embodiment of a metal carrier for an electrically heated catalyst device of the present invention, FIG. 1 (B).
Is a perspective view of the appearance of a stopper assembly that forms a roll-shaped honeycomb body, and FIG. 1C is a schematic cross-sectional view showing the configuration of the plate material of the electrically heated first honeycomb body of FIG. .
【0025】図1(A)において、電気加熱式触媒装置
用メタル担体10には、電気加熱式の第1のハニカム体
11と、第1のハニカム体11の下流に同軸に所定の間
隔Cを隔てて第2のハニカム体12が配設されており、
所定の間隔Cには、ロール状のハニカム体をなすストッ
パ組立体13が設けられている。第1のハニカム体11
と第2のハニカム体12の外側面は、それぞれ外筒11
a,12aで覆われ、さらに電気絶縁体14を介して共
通の保持筒15内に装入されている。In FIG. 1A, the electrically heated metal carrier 10 for a catalytic device is provided with a first electrically heated honeycomb body 11 and a predetermined space C coaxially downstream of the first honeycomb body 11. The second honeycomb body 12 is arranged at a distance,
A stopper assembly 13 that is a roll-shaped honeycomb body is provided at a predetermined interval C. First honeycomb body 11
The outer surface of the second honeycomb body 12 is
It is covered with a and 12a, and is further inserted into a common holding cylinder 15 via an electric insulator 14.
【0026】第1のハニカム体11は、図1(C)に示
すような、帯状をなす薄い金属板を折り曲げて連続的な
波形の凹凸を形成した1枚の波板材1と、平坦な帯状を
なす薄い金属板からなる1枚の平板材21 とで形成され
る層と、1枚の平板材22 と帯状をなす薄い金属板を折
り曲げて連続的な波形の凹凸を形成した電気絶縁性被膜
層を有する絶縁用波板3とで形成される層とが積み重ね
られ、平板材21 ,2 2 と絶縁用波板3との間はろう材
で接合されることなく、ロール状に巻かれて形成されて
いる。第1のハニカム体11の中心部には、断面が円形
で細長い棒状の中心電極16が配設されて、波板材1お
よび平板材21 ,22 の端部に接合されている。第1の
ハニカム体11のロール状の各層は、絶縁用波板3によ
って絶縁されているから、波板材1と平板材21 ,22
のロールの外周部の端末に外周電極17を設けることに
より、中心電極16と外周電極17との間の板材はロー
ル状の電気抵抗体を形成する。したがって、中心電極1
6と外周電極17とをそれぞれ不図示の電源に接続すれ
ば、第1のハニカム体11は電気加熱が可能なハニカム
体となる。The first honeycomb body 11 is shown in FIG. 1 (C).
A thin metal plate in the shape of a strip
One corrugated sheet material 1 with corrugated irregularities and a flat strip
One flat plate material 2 made of thin metal plate1 Formed by and
Layer and one flat plate material 2Two Fold a thin metal plate in the shape of a strip
Electrically insulative film that is bent to form continuous corrugations
Insulation corrugated sheet 3 having layers and layers formed by stacking
Flat plate material 21 , 2 Two Between the insulating corrugated sheet 3 and the insulating corrugated sheet 3
It is formed by rolling in a roll without being joined by
I have. The central portion of the first honeycomb body 11 has a circular cross section.
The elongated rod-shaped center electrode 16 is arranged in the
And flat plate material 21 , 2Two Is joined to the end of. First
Each roll-shaped layer of the honeycomb body 11 is formed by the insulating corrugated plate 3.
Since it is insulated, corrugated sheet material 1 and flat sheet material 21 , 2Two
To provide the outer peripheral electrode 17 at the end of the outer peripheral portion of the roll
Therefore, the plate material between the center electrode 16 and the outer peripheral electrode 17 is low.
Forming an electric resistor in the shape of a rod. Therefore, the center electrode 1
6 and the peripheral electrode 17 should be connected to a power source (not shown).
For example, the first honeycomb body 11 is a honeycomb that can be electrically heated.
Become a body.
【0027】第2のハニカム体12は、第1のハニカム
体11と同様に、波板材と平板材とを重ねてロール状に
巻き回して形成したハニカム体であるが、必ずしも平板
二重構造や多層構造である必要はない。また絶縁用波板
は配設されない。第2のハニカム体12は主要な触媒装
置用メタル担体としての役目を果たすものであるから、
第1のハニカム体11に比べ軸方向長さは長くなってい
る。したがって一部の板材間がろう材によって接合され
ていない場合、または平板二重構造や多層構造の場合で
も、テレスコーピングを起こすことはない。Similar to the first honeycomb body 11, the second honeycomb body 12 is a honeycomb body formed by stacking a corrugated sheet material and a flat sheet material and winding them in a roll shape, but is not necessarily a flat plate double structure or It need not be a multi-layer structure. Also, no insulating corrugated sheet is provided. Since the second honeycomb body 12 serves as a main metal carrier for a catalyst device,
The axial length is longer than that of the first honeycomb body 11. Therefore, even if some of the plate materials are not joined by the brazing material, or even in the case of the flat plate double structure or the multilayer structure, telescoping does not occur.
【0028】ストッパ組立体13は、第2のハニカム体
と同様に、波板材と平板材とを重ねてロール状に巻き回
して形成したハニカム体であって、板材間のろう付けは
必ずしも必要としない。ストッパ組立体13の外形寸法
は、直径が絶縁体14又は保持筒15に内接する寸法
で、軸方向長さは第1のハニカム体11と第2のハニカ
ム体12の間に形成される所定の間隔Cと同一とする。
したがってストッパ組立体13は、軸方向端面13a、
13bがそれぞれ第1のハニカム体11と第2のハニカ
ム体12との対向する端面に当接するから、第1のハニ
カム体11がガス流によって第2のハニカム体12に向
かって軸方向に移動したりテレスコーピングを生じるの
を防止することができる。The stopper assembly 13 is, like the second honeycomb body, a honeycomb body formed by stacking a corrugated plate material and a flat plate material and winding them in a roll shape, and brazing between the plate materials is not always necessary. do not do. The outer dimensions of the stopper assembly 13 are such that the diameter is inscribed in the insulator 14 or the holding cylinder 15, and the axial length is a predetermined length formed between the first honeycomb body 11 and the second honeycomb body 12. It is the same as the interval C.
Therefore, the stopper assembly 13 includes the axial end surface 13a,
Since 13b abuts on the opposite end faces of the first honeycomb body 11 and the second honeycomb body 12, respectively, the first honeycomb body 11 moves axially toward the second honeycomb body 12 by the gas flow. It is possible to prevent the occurrence of telescoping.
【0029】第1と第2のハニカム体の間の間隔Cの寸
法、すなわちストッパ組立体13の軸方向長さは、両ハ
ニカム体間の絶縁および加熱式メタル担体としての熱効
率を考慮して2〜30mmの間に設定することが望まし
い。The dimension of the interval C between the first and second honeycomb bodies, that is, the axial length of the stopper assembly 13 is 2 in consideration of the insulation between both honeycomb bodies and the thermal efficiency as a heating type metal carrier. It is desirable to set it within a range of up to 30 mm.
【0030】ハニカム体をなすストッパ組立体13の材
質に鉄、ステンレスなどの導電性のある材料を使用する
ので、電気加熱式の第1のハニカム体11と接する少な
くとも一方の端面13aに電気絶縁処理を施す必要があ
る。電気絶縁処理の方法として、ストッパ組立体単独に
行う場合には、PVD,CVDまたはイオンプレーティ
ング法によって、酸化アルミニウム(Al2 O3 )また
はその他の絶縁性被膜層をコーティングするか、または
アルミニウムを含有する材料や、溶融アルミニウム中に
浸漬して鉄とアルミニウムの合金層を生成させた材料を
用いてストッパ組立体を形成し、大気焼成することによ
って絶縁性被膜層を得る。Since the stopper assembly 13 forming the honeycomb body is made of an electrically conductive material such as iron or stainless steel, at least one end face 13a in contact with the electrically heated first honeycomb body 11 is electrically insulated. Need to be applied. When the stopper assembly alone is used as a method for electrical insulation, PVD, CVD or ion plating is used to coat aluminum oxide (Al 2 O 3 ) or another insulating coating layer, or aluminum is used. A stopper assembly is formed using the contained material or the material in which the alloy layer of iron and aluminum is formed by immersing it in molten aluminum, and the insulating coating layer is obtained by firing in the air.
【0031】ハニカム体をなすストッパ組立体13に形
成された網目状通気路の密度は、第1のハニカム体11
の網目状通気路の密度に等しいか、又はそれ以下として
通気抵抗を極力減らすことが好ましい。The density of the mesh-like ventilation passages formed in the stopper assembly 13 forming the honeycomb body is such that the first honeycomb body 11
It is preferable to reduce the ventilation resistance as much as possible by setting the density to be equal to or less than the density of the mesh ventilation passage.
【0032】第1のハニカム体11と第2のハニカム体
12及びストッパ組立体13を配設するには、図1
(A)に示すような保持筒15が用いられるが、保持筒
15の使用方法には、さらに図2(A)、(B)、
(C)に示すようなものがある。図2(A)に示す実施
例では、第1のハニカム体11の外筒を延長して第2の
ハニカム体12の外筒12aを覆い、保持筒15を形成
するものであり、図2(B)に示す実施例では、第2の
ハニカム体12の外筒を延長して第1のハニカム体11
の外筒11aを覆い、保持筒15を形成するものであ
る。これらの保持筒15はそれぞれの外筒12aまたは
11aと溶接などによって固定する。図2(C)に示す
実施例は、図2(B)に示すストッパ組立体13の外周
を絶縁性のある材料例えばセラミックスペーパーなどよ
りなる環状の保持体18によって保持している。To dispose the first honeycomb body 11, the second honeycomb body 12 and the stopper assembly 13,
Although the holding cylinder 15 as shown in FIG. 2A is used, the method of using the holding cylinder 15 is as shown in FIGS.
There is one as shown in (C). In the embodiment shown in FIG. 2A, the outer cylinder of the first honeycomb body 11 is extended to cover the outer cylinder 12a of the second honeycomb body 12 to form the holding cylinder 15. In the example shown in B), the outer cylinder of the second honeycomb body 12 is extended to extend the first honeycomb body 11
The holding cylinder 15 is formed by covering the outer cylinder 11a. These holding cylinders 15 are fixed to the outer cylinders 12a or 11a by welding or the like. In the embodiment shown in FIG. 2C, the outer periphery of the stopper assembly 13 shown in FIG. 2B is held by an annular holder 18 made of an insulating material such as ceramic paper.
【0033】触媒担持を行うには、第1と第2のハニカ
ム体を組み付け後同時に行うことも可能であるが、第1
と第2のハニカム体について別個の触媒担持を行って異
なる担持仕様とし、または第1のハニカム体に触媒担持
を行わないなど、種々の方法をとることができる。In order to carry the catalyst, it is possible to carry out simultaneously after the assembling of the first and second honeycomb bodies.
Various methods can be adopted, such as separately carrying the catalyst on the second honeycomb body so as to have different carrying specifications, or not carrying the catalyst on the first honeycomb body.
【0034】本発明の第2の実施例として、図3に示す
ような、金属の薄板で形成された種々の形式のストッパ
組立体131ないし134を使用することができる。これ
らのストッパ組立体は、長方形の薄い金属板からなる複
数の平板2aと、これら平板の間を連結して平板を第1
と第2のハニカム体の対向する端面に垂直に保持するよ
うに配設された円筒4aとが、溶接等で固定されて形成
されている。この円筒4aは平板2aと同様の薄い金属
板からなり、円筒4aの中心軸は第1、第2のハニカム
体の中心軸にほぼ一致するように配設されている。As a second embodiment of the present invention, various types of stopper assemblies 13 1 to 13 4 formed of a thin metal plate can be used as shown in FIG. In these stopper assemblies, a plurality of flat plates 2a made of a rectangular thin metal plate are connected to each other and the flat plates are connected to each other.
And a cylinder 4a arranged so as to be held perpendicularly to the opposing end faces of the second honeycomb body, are formed by being fixed by welding or the like. The cylinder 4a is made of a thin metal plate similar to the flat plate 2a, and is arranged so that the center axis of the cylinder 4a substantially coincides with the center axes of the first and second honeycomb bodies.
【0035】図3(A)に示すストッパ組立体131
は、中心軸に於て互いに等しい角度で交叉する4枚の長
方形の平板2aの両端を、保持筒15又は絶縁体14に
内接しうる円筒4aの内面に於て溶接などにより接合し
て形成されたものであり、図3(B)に示すストッパ組
立体132 は、長さの異る長方形の4枚の平板2aの両
端を円筒4aの内面に溶接等により接合して、中心軸と
平行にかつ等間隔に保持して形成されたものであり、図
3(C)に示すストッパ組立体133 は、図3(B)に
使用した平板2aを井げた状に組んで、円筒4aの内側
に於て平板2aの両端を接合し形成されたものであり、
図3(D)に示すストッパ組立体134 は、直径の長さ
が異る4個の円筒4aを同心に配設して、1枚の平板2
aによって保持し接合して形成されたものである。The stopper assembly 13 1 shown in FIG.
Is formed by welding both ends of four rectangular flat plates 2a that intersect each other at the same angle on the central axis on the inner surface of the cylinder 4a that can be inscribed in the holding cylinder 15 or the insulator 14. The stopper assembly 13 2 shown in FIG. 3 (B) is parallel to the central axis by joining both ends of four rectangular flat plates 2a having different lengths to the inner surface of the cylinder 4a by welding or the like. The stopper assembly 13 3 shown in FIG. 3 (C) is formed by holding the flat plate 2a used in FIG. Is formed by joining both ends of the flat plate 2a.
A stopper assembly 13 4 shown in FIG. 3D has four cylinders 4a having different diameters arranged concentrically to form one flat plate 2
It is formed by holding and bonding by a.
【0036】上述の第2の実施例の各ストッパ組立体
の、少なくとも第1のハニカム体11に当接する部分に
は、第1の実施例にて述べたものと同様の方法で電気絶
縁性被膜層を施す。At least a portion of each stopper assembly of the above-mentioned second embodiment that abuts on the first honeycomb body 11 is subjected to an electrically insulating coating in the same manner as that described in the first embodiment. Apply layers.
【0037】上述の図3に示した第2の実施例と同様の
形状を有する各ストッパ組立体を焼結金属によって成形
し、その後焼結して形成することもできる。It is also possible to form each stopper assembly having the same shape as that of the second embodiment shown in FIG. 3 described above by molding the sintered metal and then sintering it.
【0038】本発明によるストッパ組立体を、第1と第
2のハニカム体の間に設けることにより、電気加熱式の
第1のハニカム体のテレスコーピングの発生を防止する
ことができるので、第1のハニカム体を電気加熱するに
適した形状とするとともに、さらに客先の消費電力のニ
ーズに合致するように、軸方向長さの短縮を図ったり、
多層構造や平板多重構造のハニカム体を自由に採用する
ことができる。By providing the stopper assembly according to the present invention between the first and second honeycomb bodies, the occurrence of telescoping of the electrically heated first honeycomb body can be prevented. In addition to having a shape suitable for electrically heating the honeycomb body of, the axial length can be shortened to further meet the power consumption needs of customers.
A honeycomb body having a multilayer structure or a flat plate multiple structure can be freely adopted.
【0039】[0039]
【発明の効果】以上説明したように本発明は、1枚の波
板材と複数枚の平板材とが重なり合い、かつ隣り合う2
枚の平板材の間に電気絶縁性被膜を施された絶縁用波板
が接合されることなく配設され、ロール状に巻かれて形
成された、軸方向長さが短い電気加熱式の第1のハニカ
ム体を形成し、その下流に直列に所定の間隔を隔てて、
主要な触媒担体をなす第2のハニカム体を配設して、両
ハニカム体の対向する端部の間に絶縁性を有するストッ
パ組立体を設けたため、第1のハニカム体がガス流によ
ってテレスコーピングを発生するのを防止できるという
効果がある。As described above, according to the present invention, one corrugated plate member and a plurality of flat plate members are overlapped and adjacent to each other.
An electrically heated first corrugated sheet having a short axial length formed by arranging an insulating corrugated sheet with an electrically insulating coating without being joined between two flat plate materials and winding it in a roll shape. 1 honeycomb body is formed, and at a downstream of the honeycomb body, a predetermined space is provided,
Since the second honeycomb body serving as the main catalyst carrier is arranged and the stopper assembly having the insulating property is provided between the opposite ends of both the honeycomb bodies, the first honeycomb body is telescoping by the gas flow. It is possible to prevent the occurrence of.
【0040】したがって第1のハニカム体に設けた中心
電極を、従来のように第2のハニカム体まで延長して保
持させる必要がないため、第2のハニカム体に電気的絶
縁を考慮する必要がなくて構造が簡単となり、かつ第1
のハニカム体と第2のハニカム体を同一の保持筒の中へ
無理なく装入でき、また両ハニカム体の熱による膨張・
収縮に際しても無理がかからないため、耐久性が向上す
るという効果を奏する。Therefore, since it is not necessary to extend and hold the center electrode provided in the first honeycomb body to the second honeycomb body as in the conventional case, it is necessary to consider electrical insulation in the second honeycomb body. Without the need for a simple structure, and
The honeycomb body and the second honeycomb body can be charged into the same holding cylinder without difficulty, and the expansion of both honeycomb bodies due to heat
Since there is no difficulty in shrinking, the durability is improved.
【0041】また従来の中心電極を延長するタイプでは
不可能であった触媒の担持仕様、すなわち第1のハニカ
ム体には触媒を担持しない仕様や、第1と第2のハニカ
ム体に別個の触媒を担持させる仕様が可能となるほか、
さらに第1と第2のハニカム体を別々の工程で触媒担持
させることが可能となるため、製作工程の自由度が大き
くなるという効果を奏する。Further, it is impossible to carry the catalyst by the conventional type in which the center electrode is extended, that is, the catalyst is not carried on the first honeycomb body, or the separate catalyst is provided on the first and second honeycomb bodies. In addition to being able to carry specifications,
Furthermore, since it becomes possible to support the catalysts on the first and second honeycomb bodies in separate steps, there is an effect that the degree of freedom in the manufacturing steps is increased.
【図1】(A)は本発明の電気加熱式触媒装置用メタル
担体の軸を含む断面略図、(B)はハニカム体をなすス
トッパ組立体の外観の斜視図、(C)は、(A)の第1
のハニカム体の板材の構成を示す摸式的断面図である。FIG. 1A is a schematic cross-sectional view including a shaft of a metal carrier for an electrically heated catalyst device according to the present invention, FIG. 1B is a perspective view of an outer appearance of a stopper assembly forming a honeycomb body, and FIG. ) First
FIG. 3 is a schematic cross-sectional view showing a configuration of a plate material of the honeycomb body of
【図2】(A),(B),(C)は本発明において保持
筒の使用方法を示す断面略図である。2 (A), (B) and (C) are schematic cross-sectional views showing a method of using a holding cylinder in the present invention.
【図3】本発明のストッパ組立体の第2の実施例を示す
斜視略図である。FIG. 3 is a schematic perspective view showing a second embodiment of the stopper assembly of the present invention.
【図4】従来の技術による電気加熱式触媒装置用メタル
担体の軸を含む断面略図である。FIG. 4 is a schematic cross-sectional view including a shaft of a metal carrier for an electrically heated catalyst device according to a conventional technique.
【図5】従来の技術による別の電気加熱式触媒装置用メ
タル担体の軸を含む断面略図である。FIG. 5 is a schematic cross-sectional view including a shaft of another metal support for an electrically heated catalyst device according to the prior art.
1 波板材 21 ,22 平板材 2a 平板 3 絶縁用波板 4a 円筒 10,30 メタル担体 11 第1のハニカム体 12 第2のハニカム体 11a,12a 外筒 13,131 ,132 ,133 ,134 ストッパ組
立体 13a,13b 端面 14 絶縁体 15 保持筒 16 中心電極 17 外周電極 18 保持体 31 第1のメタル担体 32 第2のメタル担体 C 間隔DESCRIPTION OF SYMBOLS 1 Corrugated plate material 2 1 , 2 2 Flat plate material 2a Flat plate 3 Insulating corrugated plate 4a Cylinder 10,30 Metal carrier 11 First honeycomb body 12 Second honeycomb body 11a, 12a Outer cylinder 13, 13 1 , 13 2 , 13 3 , 13 4 Stopper assembly 13a, 13b End surface 14 Insulator 15 Holding cylinder 16 Center electrode 17 Peripheral electrode 18 Holding body 31 First metal carrier 32 Second metal carrier C Interval
Claims (4)
な波形の凹凸を形成した1枚の波板材と、平坦な帯状を
なす薄い金属板からなる複数枚の平板材とが相互に当接
して重なり合い、かつ前記複数枚の平板材の中の隣り合
う2枚の間に、電気絶縁性被膜層を有する絶縁用波板が
接合されることなく配設され、ロール状に巻かれて形成
されて多数の網目状通気路を備えたハニカム体をなし、
該ハニカム体のロール状に巻き回された層間が電気的に
絶縁され、前記ハニカム体の中心部に中心電極を有し、
前記ハニカム体の外周部に前記中心電極と逆性の外周電
極を有する、軸方向長さが短い第1のハニカム体と、 帯状をなす薄い金属板を折曲げて連続的な波形の凹凸を
形成した波板材と、平坦な帯状をなす薄い金属板からな
る平板材とが相互に当接して重なり合い、ロール状に巻
かれて形成されて多数の網目状通気路を備えたハニカム
体をなし、前記第1のハニカム体の下流に直列にかつ所
定の間隔を置いて配設された第2のハニカム体と、 前記第1と第2のハニカム体を覆って両ハニカム体を保
持する保持筒とを含む、電気加熱式触媒装置用メタル担
体において、 前記第1と第2のハニカム体の間の前記所定の間隔内に
配設されて前記保持筒に保持され、前記両ハニカム体の
対向する軸方向両端面に当接し、また少なくとも第1の
ハニカム体に当接する部分が電気的に絶縁された、前記
第1のハニカム体が第2のハニカム体の方向へ移動する
ことを防止するための、ストッパ組立体を有することを
特徴とする、電気加熱式触媒装置用メタル担体。1. A single corrugated sheet material in which a strip-shaped thin metal plate is bent to form continuous corrugated irregularities, and a plurality of flat sheet materials made of flat strip-shaped thin metal plates are mutually disposed. An insulating corrugated plate having an electrically insulating coating layer is provided between two adjacent sheets of the plurality of flat plate members that are in contact with each other and overlap each other, and are wound in a roll shape. A honeycomb body formed with a large number of mesh-like ventilation passages is formed,
The layers wound in a roll shape of the honeycomb body are electrically insulated from each other, and the honeycomb body has a center electrode in the central portion,
A first honeycomb body having a short axial length having an outer peripheral electrode opposite to the center electrode on the outer peripheral portion of the honeycomb body, and a thin metal plate in a band shape are bent to form continuous wavy irregularities. The corrugated sheet material and the flat sheet material made of a thin strip-shaped flat metal plate are in contact with each other and overlapped with each other to form a honeycomb body having a large number of mesh-like ventilation passages formed by being rolled. A second honeycomb body arranged in series at a predetermined interval downstream of the first honeycomb body, and a holding cylinder for covering the first and second honeycomb bodies and holding both the honeycomb bodies. In a metal carrier for an electrically heated catalyst device, including: a metal carrier disposed in the predetermined space between the first and second honeycomb bodies and held by the holding cylinder, the axial directions of the two honeycomb bodies facing each other. Abutting on both end faces, and at least the first honeycomb An electrically heated type having a stopper assembly for preventing the first honeycomb body from moving toward the second honeycomb body, the portion abutting against Metal carrier for catalytic devices.
金属板を折曲げて連続的な波形の凹凸を形成した波板材
と、平坦な帯状をなす薄い金属板からなる平板材とが、
相互に当接して重なり合ってロール状に巻かれて形成さ
れた多数の網目状通気路を備えたハニカム体をなし、該
ハニカム体の軸方向長さが前記所定の間隔に等しい、請
求項1に記載の電気加熱式触媒装置用メタル担体。2. The stopper assembly includes a corrugated sheet material formed by bending a thin metal plate in a strip shape to form continuous corrugation and a flat plate material made of a thin metal sheet in a flat strip shape.
The honeycomb body is provided with a large number of mesh-like ventilation passages formed by rolling in a roll shape so as to be in contact with each other and overlap each other, and the axial length of the honeycomb body is equal to the predetermined interval. A metal carrier for an electrically heated catalyst device as described above.
のハニカム体の対向する両端面に当接する長辺と、前記
保持筒に内接する短辺とを有する長方形の薄い金属板か
らなる複数の平板と、 該長方形の平板の間を連結して該平板を前記第1と第2
のハニカム体の対向する両端面に垂直に保持する、前記
第1と第2のハニカム体の中心軸とほぼ同心に配設され
た薄い金属板からなる少なくとも1個の円筒とを含む、
請求項1に記載の電気加熱式触媒装置用メタル担体。3. The stopper assembly includes the first and second stopper assemblies.
A plurality of flat plates made of rectangular thin metal plates having long sides abutting opposite end surfaces of the honeycomb body and short sides inscribed in the holding cylinder, and the flat plates connecting the rectangular flat plates to each other. The first and second
At least one cylinder made of a thin metal plate arranged substantially concentrically with the central axis of the first and second honeycomb bodies, which is held perpendicularly to the opposite end surfaces of the honeycomb body.
The metal carrier for an electrically heated catalyst device according to claim 1.
度は、前記第1のハニカム体の網目状通気路の密度に等
しいか又はそれ以下である、請求項2に記載の電気加熱
式触媒装置用メタル担体。4. The electrically heated catalyst according to claim 2, wherein the density of the mesh ventilation passages of the stopper assembly is equal to or less than the density of the mesh ventilation passages of the first honeycomb body. Metal carrier for equipment.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP8010008A JPH09192499A (en) | 1996-01-24 | 1996-01-24 | Metal carrier for electrically-heated catalytic device |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP8010008A JPH09192499A (en) | 1996-01-24 | 1996-01-24 | Metal carrier for electrically-heated catalytic device |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH09192499A true JPH09192499A (en) | 1997-07-29 |
Family
ID=11738381
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP8010008A Pending JPH09192499A (en) | 1996-01-24 | 1996-01-24 | Metal carrier for electrically-heated catalytic device |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH09192499A (en) |
-
1996
- 1996-01-24 JP JP8010008A patent/JPH09192499A/en active Pending
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