JPH09216327A - Laminated synthetic resin decorative material and its manufacture - Google Patents
Laminated synthetic resin decorative material and its manufactureInfo
- Publication number
- JPH09216327A JPH09216327A JP4565496A JP4565496A JPH09216327A JP H09216327 A JPH09216327 A JP H09216327A JP 4565496 A JP4565496 A JP 4565496A JP 4565496 A JP4565496 A JP 4565496A JP H09216327 A JPH09216327 A JP H09216327A
- Authority
- JP
- Japan
- Prior art keywords
- synthetic resin
- layer
- resin
- decorative material
- pattern layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Application Of Or Painting With Fluid Materials (AREA)
- Laminated Bodies (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、建築物、車両等の
内装のための表面材、または、家具、住宅設備機器、家
電製品等の外装のための表面材として用いられる、複数
の合成樹脂基材からなる積層合成樹脂化粧材およびその
製造方法に関し、特に、基材が合成樹脂製のシート又は
フィルムからなり、艶消し部分とこれより艶のある部分
との間の光沢差により視覚的に凹凸感又は立体感を与え
る積層合成樹脂化粧材およびその製造方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a plurality of synthetic resins used as a surface material for the interior of buildings, vehicles, etc., or a surface material for the exterior of furniture, housing equipment, home appliances and the like. The present invention relates to a laminated synthetic resin decorative material made of a base material and a method for manufacturing the same, and in particular, the base material is made of a synthetic resin sheet or film, and is visually recognized due to a difference in gloss between a matte portion and a glossy portion. TECHNICAL FIELD The present invention relates to a laminated synthetic resin decorative material that gives unevenness or a three-dimensional effect and a method for manufacturing the same.
【０００２】[0002]
【従来の技術】この種の化粧材およびその製造方法は、
例えば、特開平６−１９８８３１号公報に記載されてい
る。この公報に記載の製造方法によれば、下層のフィル
ム基材上に着色ベタ層、絵柄層、接着剤層を形成した
後、上層のフィルム基材を積層し、該上層のフィルム基
材の表面にエンボス、ワイピンングを加工し、艶調整ト
ップコート層を形成する。この方法により製造された化
粧材は、艶のあるトップコート層と艶消しの絵柄層との
間に光沢の差があることによって絵柄に凹凸感又は立体
感を生じさせる。2. Description of the Related Art A cosmetic material of this type and a method for producing the same are disclosed in US Pat.
For example, it is described in JP-A-6-198831. According to the production method described in this publication, after forming a colored solid layer, a pattern layer, and an adhesive layer on a lower film substrate, an upper film substrate is laminated, and the surface of the upper film substrate is laminated. And embossing and wiping to form a gloss adjusting top coat layer. The decorative material produced by this method causes a pattern to have an unevenness or a three-dimensional effect due to a difference in gloss between the glossy top coat layer and the matte picture layer.
【０００３】[0003]
【発明が解決しようとする課題】前記の従来の製造方法
は、エンボス工程を行う際に及ぼされる熱圧を利用して
上層のフィルム基材と下層のフィルム基材とを一体化さ
せることができる点では有利である。しかし、この従来
方法は、上層のフィルム基材に絵柄模様、例えば木目の
導管模様をエンボスとワイピングによって表現するもの
であるため、エンボスをつき板における導管模様におけ
るように横断面で見て階段状に深さ方向へ変化させるよ
うなことは困難であるから、微細な導管模様を濃淡で豊
かに表現することは困難であり、結局、エンボスとワイ
ピングによって、つき板における導管模様に忠実な導管
模様をフィルム基材上に表現することは困難であるとい
う問題がある。したがって、本発明の目的は、積層合成
樹脂化粧材に表す絵柄模様に微細な濃淡の調子と光沢差
による立体感を生じさせることにあり、また、エンボス
とワイピングによらないで、絵柄模様を豊かに表現しか
つこれに光沢差による立体感を生じさせる積層合成樹脂
化粧材およびその製造方法を提供することにある。In the above-mentioned conventional manufacturing method, the upper film base and the lower film base can be integrated by utilizing the heat pressure exerted during the embossing step. It is advantageous in that respect. However, in this conventional method, since a pattern pattern, for example, a conduit pattern of wood grain is expressed by embossing and wiping on the upper film base material, the emboss is stepped in a cross section as in the conduit pattern of the plate. Since it is difficult to change in the depth direction, it is difficult to express a fine conduit pattern in a rich and shaded way, and after all, by embossing and wiping, a conduit pattern that is faithful to the conduit pattern on the attached plate Is difficult to express on a film substrate. Therefore, an object of the present invention is to generate a three-dimensional effect due to a fine tone of tone and a difference in gloss in a pattern represented on a laminated synthetic resin decorative material, and to enhance the pattern without embossing and wiping. It is an object of the present invention to provide a laminated synthetic resin decorative material that expresses the above-mentioned item and produces a three-dimensional effect due to the difference in gloss, and a manufacturing method thereof.
【０００４】[0004]
【課題を解決するための手段】本発明は、エンボスとワ
イピングに代えて、上層の合成樹脂基材に印刷によって
絵柄層を設けることによって前記目的を達成することを
基本構想とするものであり、本発明にかかる積層合成樹
脂化粧材は、それぞれが絵柄層を有する複数の合成樹脂
基材からなる積層合成樹脂化粧材であって、上層の合成
樹脂基材は、透明又は半透明で、熱硬化性樹脂又はラジ
カル重合型樹脂を含むインキ又は樹脂による、艶消し部
分とこれより艶のある部分とを有することを特徴とす
る。SUMMARY OF THE INVENTION The present invention has a basic concept to achieve the above object by providing a pattern layer on an upper synthetic resin substrate by printing, instead of embossing and wiping. The laminated synthetic resin decorative material according to the present invention is a laminated synthetic resin decorative material composed of a plurality of synthetic resin base materials each having a pattern layer, and the upper synthetic resin base material is transparent or translucent and thermoset. It is characterized by having a matte portion and a glossier portion due to an ink or resin containing a polymerizable resin or a radical polymerization type resin.
【０００５】また、本発明に係る積層合成樹脂化粧材の
製造方法は、上層の透明又は半透明の合成樹脂基材の表
面に熱硬化性樹脂又はラジカル重合型樹脂でコート層を
設け、該コート層上に該コート層の樹脂より光沢度の低
い熱硬化性樹脂又はラジカル重合型樹脂を含むインキで
絵柄層を印刷し、前記上層の合成樹脂基材の裏面と下層
の合成樹脂基材の絵柄層とを接着又は熱融着することを
特徴とする。Further, in the method for producing a laminated synthetic resin decorative material according to the present invention, a coating layer is provided on the surface of an upper transparent or translucent synthetic resin base material with a thermosetting resin or a radical polymerization type resin, and the coating layer is formed. A pattern layer is printed on the layer with an ink containing a thermosetting resin or a radical polymerization type resin having a gloss lower than that of the resin of the coating layer, and the pattern on the back surface of the upper synthetic resin substrate and the pattern of the lower synthetic resin substrate. It is characterized in that the layer is adhered or heat-sealed.
【０００６】さらに、本発明に係る積層合成樹脂化粧材
の製造方法は、上層の透明又は半透明の合成樹脂基材の
表面に絵柄層を印刷し、該絵柄層及び前記表面の上に熱
硬化性樹脂又はラジカル重合型樹脂で第１コート層を設
け、前記絵柄層のネガ版を用いて、前記第１コート層上
に該コート層の樹脂より光沢度の高い熱硬化性樹脂又は
ラジカル重合型樹脂で第２コート層を設け、前記上層の
合成樹脂基材の裏面と下層の合成樹脂基材の絵柄層とを
接着又は熱融着することを特徴とする。Further, in the method for producing a laminated synthetic resin decorative material according to the present invention, a pattern layer is printed on the surface of an upper transparent or translucent synthetic resin base material, and heat curing is performed on the pattern layer and the surface. Of a thermosetting resin or a radical-polymerizable resin having a gloss higher than that of the resin of the coating layer on the first coating layer by using a negative plate of the pattern layer by providing a first coating layer of a resin or a radical-polymerizable resin. A second coat layer is provided with a resin, and the back surface of the synthetic resin base material of the upper layer and the picture layer of the synthetic resin base material of the lower layer are bonded or heat-sealed.
【０００７】さらに、本発明に係る積層合成樹脂化粧材
の製造方法は、上層の透明又は半透明の合成樹脂基材の
表面に熱硬化性樹脂又はラジカル重合型樹脂を含むマッ
トインキで絵柄層を印刷し、次いでトップコート層を、
ドライ状態において前記合成樹脂基材表面からトップコ
ート層表面までの距離（dt) が該合成樹脂基材表面から
前記絵柄層表面までの距離(d0)と等しいか又はこれより
小さいように、前記絵柄層のマットインキより光沢度の
高い熱硬化性樹脂又はラジカル重合型樹脂で設け、前記
上層の合成樹脂基材の裏面と下層の合成樹脂基材の印刷
層とを接着又は熱融着することをすることを特徴とす
る。さらに、前記合成樹脂基材表面からトップコート層
表面までの距離（dt) を該合成樹脂基材表面から前記絵
柄層表面までの距離(d0)と等しいか又はこれより小さく
するために、前記トップコート層の版深度を調整し、ま
たは、前記トップコート層に使用する樹脂中の固形分の
量を調整することを特徴とする。Further, in the method for producing a laminated synthetic resin decorative material according to the present invention, a pattern layer is formed on the surface of an upper transparent or translucent synthetic resin substrate with a matte ink containing a thermosetting resin or a radical polymerization type resin. Print, then topcoat layer,
In the dry state, the distance (d t ) from the surface of the synthetic resin substrate to the surface of the top coat layer is equal to or smaller than the distance (d 0 ) from the surface of the synthetic resin substrate to the surface of the pattern layer, It is provided with a thermosetting resin or a radical polymerization type resin having a gloss higher than that of the mat ink of the pattern layer, and the back surface of the upper synthetic resin substrate and the printed layer of the lower synthetic resin substrate are bonded or heat-sealed. It is characterized by doing things. Further, in order to make the distance (d t ) from the surface of the synthetic resin substrate to the surface of the top coat layer equal to or smaller than the distance (d 0 ) from the surface of the synthetic resin substrate to the surface of the pattern layer, It is characterized in that the plate depth of the top coat layer is adjusted, or the amount of solid content in the resin used in the top coat layer is adjusted.
【０００８】[0008]
【作用効果】本発明によれば、積層合成樹脂化粧材にそ
の上層における２つの部分すなわち絵柄層及びコート層
が光沢度を異にしたことによる立体感が得られると共
に、その絵柄層を印刷によって設けたことによりこれを
濃淡豊かに表現することができるから、立体感と表現力
とに富んだ積層合成樹脂化粧材を得ることができる。According to the present invention, it is possible to obtain a three-dimensional effect in the laminated synthetic resin decorative material due to the difference in the glossiness of the two parts in the upper layer, that is, the picture layer and the coat layer, and to print the picture layer by printing. By providing this, it is possible to express this richly and shadedly, and it is possible to obtain a laminated synthetic resin decorative material rich in three-dimensional appearance and expressiveness.
【０００９】ところで、凹凸感又は立体感は、視覚的に
光沢のない部位が深く見え、光沢のある部位が浅く見え
ることにより生じる。しかも、光沢のない部位の表面と
光沢のある部位の表面との間の隔たりが小さければ小さ
いほど、光沢のない部位が深く見えまた光沢のある部位
が浅く見え、これにより凹凸感又は立体感が深まる。こ
れに関して、前記公報に記載の化粧材は、艶のあるトッ
プコート層と艶消し絵柄層との間には複数の層が介在し
ていることから、光沢のない部位の表面と光沢のある部
位の表面との間の隔たりを小さくして絵柄の凹凸感を深
めるためには、艶消し絵柄層を限りなく薄くすることが
求められる。しかし、それでは絵柄が不鮮明となって所
望の化粧効果を失ってしまうおそれがある。このため、
艶のあるトップコート層と該トップコート層の表面上に
設けた艶消し絵柄層とによっては、その間の光沢差が与
える凹凸感又は立体感を深めまたは強くするには限度が
ある。しかし、請求項５に記載の発明によれば、化粧材
の表面に現れる絵柄層を薄くすることなしに、合成樹脂
基材表面からトップコート層表面までの距離と該合成樹
脂基材表面から前記絵柄層表面までの距離との差をゼロ
としまたは小さくすることができるから、光沢のない絵
柄表面が一層深く見え、これにより凹凸感又は立体感を
一層深めることができる。[0009] By the way, the unevenness or the three-dimensional effect is caused by the fact that a visually dull portion looks deep and a glossy portion looks shallow. Moreover, the smaller the distance between the surface of the non-glossy area and the surface of the glossy area, the deeper the non-glossy area and the shallower the glossy area, resulting in unevenness or three-dimensional appearance. Deepen. In this regard, since the cosmetic material described in the above publication has a plurality of layers interposed between the glossy top coat layer and the matte pattern layer, the surface of the non-glossy portion and the glossy portion In order to reduce the distance between the matte picture layer and the surface of the matte picture and to enhance the unevenness of the picture, it is required to make the matte picture layer as thin as possible. However, there is a possibility that the pattern becomes unclear and the desired cosmetic effect is lost. For this reason,
Depending on the glossy top coat layer and the matte picture layer provided on the surface of the top coat layer, there is a limit in deepening or strengthening the unevenness or three-dimensional effect given by the difference in gloss between them. However, according to the invention of claim 5, the distance from the surface of the synthetic resin substrate to the surface of the topcoat layer and the distance from the surface of the synthetic resin substrate to Since the difference from the distance to the surface of the design layer can be made zero or small, the dull design surface can be seen deeper, and the unevenness or the stereoscopic effect can be further enhanced.
【００１０】[0010]
【実施の形態】図１，３及び５には、それぞれ、接着又
は熱融着された上層１０と下層３０からなる積層合成樹
脂化粧材（図２，４，６）の上層１０が示されており、
該上層を構成する合成樹脂基材１２は、透明又は半透明
の、ポリエチレン、ポリプロピレン、ポリエステル、ポ
リ塩化ビニル、ポリ塩化ビニリデン、ポリスチレン、ポ
リカーボネート、ポリビニルアルコール、ナイロン、セ
ロファン又はＥＶＡのシート又はフィルムからなる。DESCRIPTION OF THE PREFERRED EMBODIMENTS FIGS. 1, 3 and 5 show an upper layer 10 of a laminated synthetic resin decorative material (FIGS. 2, 4, 6) comprising an upper layer 10 and a lower layer 30 which are bonded or heat-sealed, respectively. Cage,
The synthetic resin substrate 12 that constitutes the upper layer is a transparent or semitransparent sheet or film of polyethylene, polypropylene, polyester, polyvinyl chloride, polyvinylidene chloride, polystyrene, polycarbonate, polyvinyl alcohol, nylon, cellophane or EVA. .
【００１１】図１に示す例では、合成樹脂基材１２に
は、その表面に熱硬化性樹脂又はラジカル重合型樹脂で
コート層１４を設け、該コート層上に該コート層の樹脂
より光沢度の低い熱硬化性樹脂又はラジカル重合型樹脂
を含むインキで絵柄層１６を印刷してあり、絵柄層１６
及びコート層１４は、それぞれ、艶消し部分及びこれよ
り艶のある部分を構成している。絵柄層１６の印刷イン
キとして、前記した熱硬化性樹脂又はラジカル重合型樹
脂を含むインキを使用するが、ここにいう熱硬化性樹脂
には、フェノール系樹脂、尿素系樹脂、メラミン系樹
脂、エポキシ系樹脂、ポリエステル系樹脂、ポリウレタ
ン系樹脂等が含まれる。In the example shown in FIG. 1, a synthetic resin substrate 12 is provided with a coat layer 14 on its surface with a thermosetting resin or a radical polymerization type resin, and a glossiness higher than that of the resin of the coat layer is provided on the coat layer 14. The pattern layer 16 is printed with an ink containing a low thermosetting resin or a radical polymerization type resin.
The coat layer 14 constitutes a matte portion and a glossy portion, respectively. As the printing ink for the pattern layer 16, an ink containing the above-mentioned thermosetting resin or radical polymerization type resin is used. The thermosetting resin referred to here is phenol resin, urea resin, melamine resin, epoxy. Resins, polyester resins, polyurethane resins and the like are included.
【００１２】次に、図３に示す例では、合成樹脂基材１
２には、その表面に絵柄層１８を印刷し、該絵柄層及び
前記表面の上に熱硬化性樹脂又はラジカル重合型樹脂で
第１コート層２０を設け、絵柄層１８のネガ版を用い
て、第１コート層２０上に該コート層の樹脂より光沢度
の高い熱硬化性樹脂又はラジカル重合型樹脂で第２コー
ト層２２を設けてある。第１コート層２０及び第２コー
ト層２２は、それぞれ、艶消し部分及びこれより艶のあ
る部分を構成している。Next, in the example shown in FIG. 3, the synthetic resin substrate 1
2, a pattern layer 18 is printed on the surface, a first coat layer 20 is provided on the pattern layer and the surface with a thermosetting resin or a radical polymerization type resin, and a negative plate of the pattern layer 18 is used. The second coat layer 22 is provided on the first coat layer 20 with a thermosetting resin or a radical polymerization type resin having a gloss higher than that of the resin of the coat layer. The first coat layer 20 and the second coat layer 22 form a matte portion and a glossier portion, respectively.
【００１３】さらに、図５に示す例では、合成樹脂基材
１２には、その表面に熱硬化性樹脂又はラジカル重合型
樹脂を含むマットインキで絵柄層２４を印刷し、次いで
トップコート層２６を、ドライ状態において合成樹脂基
材表面からトップコート層表面までの距離（dt) が該合
成樹脂基材表面から絵柄層表面までの距離(d0)と等しい
か又はこれより小さいように、絵柄層２４のマットイン
キより光沢度の高い熱硬化性樹脂又はラジカル重合型樹
脂で設けてあり、絵柄層２４及びトップコート層２６
は、それぞれ、艶消し部分及びこれより艶のある部分を
構成している。Further, in the example shown in FIG. 5, a pattern layer 24 is printed on the surface of the synthetic resin substrate 12 with a matte ink containing a thermosetting resin or a radical polymerization type resin, and then a top coat layer 26 is formed. , The pattern so that the distance (d t ) from the surface of the synthetic resin substrate to the surface of the top coat layer in the dry state is equal to or smaller than the distance (d 0 ) from the surface of the synthetic resin substrate to the surface of the pattern layer (d 0 ). The pattern layer 24 and the top coat layer 26 are made of a thermosetting resin or a radical polymerization type resin having a gloss higher than that of the matte ink of the layer 24.
Respectively constitute a matte portion and a glossier portion.
【００１４】図５に示した例においては、トップコート
層２６の版深度を調整することにより、合成樹脂基材１
２の表面からトップコート層２６の表面までの距離
（dt) を合成樹脂基材表面から絵柄層表面までの距離(d
0)と等しいか又はこれより小さくすることができる。こ
れに代えて、トップコート層２６に使用する樹脂中の固
形分の量を調整することによっても、合成樹脂基材１０
の表面からトップコート層２６の表面までの距離（dt)
を合成樹脂基材表面から絵柄層表面までの距離(d0)と等
しいか又はこれより小さくすることができる。また、ト
ップコート層２６を設けるための樹脂の塗布は、グラビ
ヤロール（ベタ版）、ロールコート又はエアナイフコー
トによることができる。In the example shown in FIG. 5, by adjusting the plate depth of the top coat layer 26, the synthetic resin substrate 1
2 is the distance from the surface of the top coat layer 26 (d t ) to the surface of the synthetic resin substrate (d)
It can be equal to or less than 0 ). Alternatively, by adjusting the amount of solids in the resin used for the top coat layer 26, the synthetic resin substrate 10
From surface of top coat layer 26 to surface (d t ).
Can be equal to or smaller than the distance (d 0 ) from the surface of the synthetic resin substrate to the surface of the pattern layer. The application of the resin for providing the top coat layer 26 can be performed by gravure roll (solid printing), roll coating, or air knife coating.
【００１５】図２，４，６に示すように、積層合成樹脂
化粧材の下層３０を構成する合成樹脂基材３２には、そ
の表面に着色ベタ層３４を含む絵柄層３６が印刷され
る。着色ベタ層３４は、これを設けなくてもよい。ま
た、絵柄層は３６は、例えば、上層１０の絵柄層１６
（図１），１８（図３）又は２４（図５）が木目の導管
模様であるときは、木目の柄模様とする。As shown in FIGS. 2, 4 and 6, a pattern layer 36 including a colored solid layer 34 is printed on the surface of the synthetic resin base material 32 constituting the lower layer 30 of the laminated synthetic resin decorative material. The colored solid layer 34 may not be provided. The design layer 36 is, for example, the design layer 16 of the upper layer 10.
When (FIG. 1), 18 (FIG. 3) or 24 (FIG. 5) is a conduit pattern of wood grain, it is a pattern pattern of wood grain.
【００１６】合成樹脂基材３２としては、合成樹脂基材
１２と同じく、ポリエチレン、ポリプロピレン、ポリエ
ステル、ポリ塩化ビニル、ポリ塩化ビニリデン、ポリス
チレン、ポリカーボネート、ポリビニルアルコール、ナ
イロン、セロファン又はＥＶＡのシート又はフルムを使
用することができる。これらのうち、ポリエチレン、ポ
リプロピレンのような極性の低い材料を合成樹脂基材３
２として、使用する場合、材料の表面に、該表面への着
色ベタ層３４の印刷に先立って、コロナ放電処理、オゾ
ン処理又は炎処理を施し、材料表面を活性化させる。着
色ベタ層３４に用いる印刷インキとしては、例えば、樹
脂を溶剤に溶かしたいわゆるビヒクルに顔料、染料等の
着色剤及び体質顔料を添加し、さらに可塑剤、安定剤、
充填剤等の添加剤を任意に添加し、十分に練肉してな
る、公知のインキ組成物を使用することができる。As the synthetic resin base material 32, as with the synthetic resin base material 12, polyethylene, polypropylene, polyester, polyvinyl chloride, polyvinylidene chloride, polystyrene, polycarbonate, polyvinyl alcohol, nylon, cellophane or EVA sheet or flume. Can be used. Among these, a low-polarity material such as polyethylene or polypropylene is used for the synthetic resin base material 3.
Second, when used, a corona discharge treatment, an ozone treatment or a flame treatment is applied to the surface of the material prior to the printing of the colored solid layer 34 on the surface to activate the material surface. As the printing ink used for the colored solid layer 34, for example, a coloring agent such as a pigment and a dye and an extender are added to a so-called vehicle in which a resin is dissolved in a solvent, and further, a plasticizer, a stabilizer,
A well-known ink composition obtained by arbitrarily adding additives such as a filler and kneading the mixture can be used.
【００１７】図１，３，５に示す上層１０の合成樹脂基
材１２と、下層３０の合成樹脂基材３２とは、合成樹脂
基材１２の裏面と合成樹脂基材３２の絵柄層３６とを接
着又は熱融着することにより結合され、図２，４，６に
示すように、一体の積層合成樹脂化粧材を構成する。The synthetic resin base material 12 of the upper layer 10 and the synthetic resin base material 32 of the lower layer 30 shown in FIGS. 1, 3 and 5 are the back surface of the synthetic resin base material 12 and the pattern layer 36 of the synthetic resin base material 32. Are bonded or bonded by heat fusion to form an integral laminated synthetic resin decorative material as shown in FIGS.
【図１】図１は本発明に係る積層合成樹脂化粧材の上層
の構造例を示す部分横断面図。FIG. 1 is a partial cross-sectional view showing a structural example of an upper layer of a laminated synthetic resin decorative material according to the present invention.
【図２】図２は図１に示した上層を含む積層合成樹脂化
粧材の部分横断面図。FIG. 2 is a partial cross-sectional view of the laminated synthetic resin decorative material including the upper layer shown in FIG.
【図３】図３は本発明に係る積層合成樹脂化粧材の上層
の他の構造例を示す部分横断面図。FIG. 3 is a partial cross-sectional view showing another example of the structure of the upper layer of the laminated synthetic resin decorative material according to the present invention.
【図４】図４は図３に示した上層を含む積層合成樹脂化
粧材の部分横断面図。FIG. 4 is a partial cross-sectional view of the laminated synthetic resin decorative material including the upper layer shown in FIG. 3;
【図５】図５は本発明に係る積層合成樹脂化粧材の上層
のさらに他の構造例を示す部分横断面図。FIG. 5 is a partial cross-sectional view showing still another structural example of the upper layer of the laminated synthetic resin decorative material according to the present invention.
【図６】図６は図５に示した上層を含む積層合成樹脂化
粧材の部分横断面図。6 is a partial cross-sectional view of a laminated synthetic resin decorative material including the upper layer shown in FIG.
１０ 積層合成樹脂化粧材の上層 １２，３２ 合成樹脂基材 １４，２０，２２，２６ コート層 １６，１８，２４ 絵柄層 ３０ 積層合成樹脂化粧材の下層 ３４ 着色ベタ層 ３６ 絵柄層 10 Upper layer of laminated synthetic resin decorative material 12,32 Synthetic resin base material 14, 20, 22, 26 Coat layer 16, 18, 24 Picture layer 30 Lower layer of laminated synthetic resin decorative material 34 Colored solid layer 36 Pattern layer
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 ＦＩ 技術表示箇所 Ｂ３２Ｂ 27/30 １０１ Ｂ３２Ｂ 27/30 １０１ １０２ １０２ ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification code Internal reference number FI technical display location B32B 27/30 101 B32B 27/30 101 102 102
Claims (7)
脂基材からなる積層合成樹脂化粧材であって、上層の合
成樹脂基材は、透明又は半透明で、熱硬化性樹脂又はラ
ジカル重合型樹脂を含むインキ又は樹脂による、艶消し
部分とこれより艶のある部分とを有する、積層合成樹脂
化粧材。1. A laminated synthetic resin decorative material comprising a plurality of synthetic resin base materials each having a printed layer, wherein the upper synthetic resin base material is transparent or translucent, and is a thermosetting resin or a radical polymerization type. A laminated synthetic resin decorative material having a matte portion and a glossy portion, which is formed by an ink containing a resin or a resin.
材は、ポリエチレン、ポリプロピレン、ポリエステル、
ポリ塩化ビニル、ポリ塩化ビニリデン、ポリスチレン、
ポリカーボネート、ポリビニルアルコール、ナイロン、
セロファン又はＥＶＡのシート又はフィルムである、請
求項１に記載の積層合成樹脂化粧材。2. The transparent or translucent synthetic resin substrate of the upper layer is made of polyethylene, polypropylene, polyester,
Polyvinyl chloride, polyvinylidene chloride, polystyrene,
Polycarbonate, polyvinyl alcohol, nylon,
The laminated synthetic resin decorative material according to claim 1, which is a cellophane or EVA sheet or film.
脂基材からなる積層合成樹脂化粧材の製造方法であっ
て、上層の透明又は半透明の合成樹脂基材の表面に熱硬
化性樹脂又はラジカル重合型樹脂でコート層を設け、該
コート層上に該コート層の樹脂より光沢度の低い熱硬化
性樹脂又はラジカル重合型樹脂を含むインキで絵柄層を
印刷し、前記上層の合成樹脂基材の裏面と下層の合成樹
脂基材の絵柄層とを接着又は熱融着することを含む、積
層合成樹脂化粧材の製造方法。3. A method for producing a laminated synthetic resin decorative material comprising a plurality of synthetic resin base materials each having a pattern layer, wherein a thermosetting resin or a thermosetting resin is formed on the surface of an upper transparent or translucent synthetic resin base material. A coating layer is provided with a radical polymerization type resin, a pattern layer is printed on the coating layer with an ink containing a thermosetting resin or a radical polymerization type resin having a lower gloss than the resin of the coating layer, and the synthetic resin base of the upper layer is printed. A method for producing a laminated synthetic resin decorative material, which comprises bonding or heat-sealing a back surface of the material and a pattern layer of a lower synthetic resin substrate.
脂基材からなる積層合成樹脂化粧材の製造方法であっ
て、上層の透明又は半透明の合成樹脂基材の表面に絵柄
層を印刷し、該絵柄層及び前記表面の上に熱硬化性樹脂
又はラジカル重合型樹脂で第１コート層を設け、前記絵
柄層のネガ版を用いて、前記第１コート層上に該コート
層の樹脂より光沢度の高い熱硬化性樹脂又はラジカル重
合型樹脂で第２コート層を設け、前記上層の合成樹脂基
材の裏面と下層の合成樹脂基材の絵柄層とを接着又は熱
融着することを含む、積層合成樹脂化粧材の製造方法。4. A method for producing a laminated synthetic resin decorative material comprising a plurality of synthetic resin substrates each having a pattern layer, wherein a pattern layer is printed on the surface of an upper transparent or translucent synthetic resin substrate. A first coat layer is provided on the pattern layer and the surface with a thermosetting resin or a radical polymerization type resin, and a negative plate of the pattern layer is used to form a resin of the coat layer on the first coat layer. A second coating layer is provided with a thermosetting resin or a radical polymerization type resin having a high glossiness, and the back surface of the upper synthetic resin substrate and the pattern layer of the lower synthetic resin substrate are bonded or heat fused. A method for producing a laminated synthetic resin decorative material, including:
脂基材からなる積層合成樹脂化粧材の製造方法であっ
て、上層の透明又は半透明の合成樹脂基材の表面に熱硬
化性樹脂又はラジカル重合型樹脂を含むマットインキで
絵柄層を印刷し、次いでトップコート層を、ドライ状態
において前記合成樹脂基材表面からトップコート層表面
までの距離（dt) が該合成樹脂基材表面から前記絵柄層
表面までの距離(d0)と等しいか又はこれより小さいよう
に、前記絵柄層のマットインキより光沢度の高い熱硬化
性樹脂又はラジカル重合型樹脂で設け、前記上層の合成
樹脂基材の裏面と下層の合成樹脂基材の印刷層とを接着
又は熱融着することを含む、積層合成樹脂化粧材の製造
方法。5. A method for producing a laminated synthetic resin decorative material comprising a plurality of synthetic resin base materials each having a printed layer, wherein a thermosetting resin or a thermosetting resin is formed on the surface of an upper transparent or translucent synthetic resin base material. A pattern layer is printed with a matte ink containing a radical-polymerizable resin, and then the topcoat layer is dried so that the distance (d t ) from the surface of the synthetic resin substrate to the surface of the synthetic resin substrate is in the dry state. Provided with a thermosetting resin or a radical polymerization type resin having a gloss higher than that of the matte ink of the pattern layer so as to be equal to or smaller than the distance (d 0 ) to the surface of the pattern layer, and the synthetic resin group of the upper layer. A method for producing a laminated synthetic resin decorative material, which comprises bonding or heat-sealing a back surface of the material and a printing layer of a lower synthetic resin substrate.
ことにより、前記合成樹脂基材表面からトップコート層
表面までの距離（dt) を該合成樹脂基材表面から前記絵
柄層表面までの距離(d0)と等しいか又はこれより小さく
する、請求項５に記載の製造方法。6. The distance (d t ) from the surface of the synthetic resin substrate to the surface of the topcoat layer is adjusted by adjusting the plate depth of the topcoat layer from the surface of the synthetic resin substrate to the surface of the pattern layer. The manufacturing method according to claim 5, wherein the distance is equal to or smaller than the distance (d 0 ).
固形分の量を調整することにより、前記合成樹脂基材表
面からトップコート層表面までの距離（dt)を該合成樹
脂基材表面から前記絵柄層表面までの距離(d0)と等しい
か又はこれより小さくする、請求項５に記載の製造方
法。7. The distance (d t ) from the surface of the synthetic resin substrate to the surface of the topcoat layer is adjusted by adjusting the amount of solids in the resin used for the topcoat layer. The manufacturing method according to claim 5, wherein the distance (d 0 ) from the surface to the surface of the pattern layer is equal to or smaller than the distance (d 0 ).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8045654A JP2810011B2 (en) | 1996-02-08 | 1996-02-08 | Manufacturing method of laminated synthetic resin decorative material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8045654A JP2810011B2 (en) | 1996-02-08 | 1996-02-08 | Manufacturing method of laminated synthetic resin decorative material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH09216327A true JPH09216327A (en) | 1997-08-19 |
| JP2810011B2 JP2810011B2 (en) | 1998-10-15 |
Family
ID=12725375
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8045654A Expired - Lifetime JP2810011B2 (en) | 1996-02-08 | 1996-02-08 | Manufacturing method of laminated synthetic resin decorative material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2810011B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100446561B1 (en) * | 1997-12-26 | 2004-10-14 | 고려화학 주식회사 | Method for surface coating pvc floor materials with ultraviolet surface treating agent to provide surface luminous effect or surface luminous and non-luminous effect |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52115876A (en) * | 1976-03-26 | 1977-09-28 | Toppan Printing Co Ltd | Process for manufacture of foamed decorative material |
| JPH02128843A (en) * | 1988-11-10 | 1990-05-17 | Dainippon Printing Co Ltd | Decorative material |
| JPH04135853A (en) * | 1990-09-28 | 1992-05-11 | Dainippon Printing Co Ltd | Grain pattern decorative sheet |
| JPH07186355A (en) * | 1993-12-24 | 1995-07-25 | Dainippon Printing Co Ltd | Decorative panel for building material |
-
1996
- 1996-02-08 JP JP8045654A patent/JP2810011B2/en not_active Expired - Lifetime
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52115876A (en) * | 1976-03-26 | 1977-09-28 | Toppan Printing Co Ltd | Process for manufacture of foamed decorative material |
| JPH02128843A (en) * | 1988-11-10 | 1990-05-17 | Dainippon Printing Co Ltd | Decorative material |
| JPH04135853A (en) * | 1990-09-28 | 1992-05-11 | Dainippon Printing Co Ltd | Grain pattern decorative sheet |
| JPH07186355A (en) * | 1993-12-24 | 1995-07-25 | Dainippon Printing Co Ltd | Decorative panel for building material |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100446561B1 (en) * | 1997-12-26 | 2004-10-14 | 고려화학 주식회사 | Method for surface coating pvc floor materials with ultraviolet surface treating agent to provide surface luminous effect or surface luminous and non-luminous effect |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2810011B2 (en) | 1998-10-15 |
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