JPH09208410A - Noxious insect repellent - Google Patents

Noxious insect repellent

Info

Publication number
JPH09208410A
JPH09208410A JP8015761A JP1576196A JPH09208410A JP H09208410 A JPH09208410 A JP H09208410A JP 8015761 A JP8015761 A JP 8015761A JP 1576196 A JP1576196 A JP 1576196A JP H09208410 A JPH09208410 A JP H09208410A
Authority
JP
Japan
Prior art keywords
repellent
cockroaches
heat
phenoxybenzyl
attraction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP8015761A
Other languages
Japanese (ja)
Other versions
JP3745432B2 (en
Inventor
Toshiichi Tomioka
冨岡  敏一
Atsushi Nishino
西野  敦
Yutaka Hironaka
豊 弘中
Isamu Nitta
勇 新田
Tatsue Ito
達栄 伊藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Earth Corp
Panasonic Holdings Corp
Original Assignee
Earth Chemical Co Ltd
Matsushita Electric Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Earth Chemical Co Ltd, Matsushita Electric Industrial Co Ltd filed Critical Earth Chemical Co Ltd
Priority to JP01576196A priority Critical patent/JP3745432B2/en
Publication of JPH09208410A publication Critical patent/JPH09208410A/en
Application granted granted Critical
Publication of JP3745432B2 publication Critical patent/JP3745432B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

PROBLEM TO BE SOLVED: To obtain a noxious insect repellent, capable of manifesting repellent effects effective against cockroaches, having the repellent effects even on attraction by heat and capable of preventing especially household appliances from being infested with the cockroaches by combining four active ingredients different in characteristics. SOLUTION: This noxious insect repellent is obtained by combining α-cyano-3- phenoxybenzyl chrysanthemate (1-50wt.%) with 2-(4-ethoxyphenyl)-2- methylpropyl-3-phenoxybenzil (1-80wt.%), o-phenylphenol (1-70wt.%) and p-t- octylphenol (1-70wt.%). The repellent has not only both contact repellency and repellency due to olfactory irritation of a volatilized gas to cockroaches but also repellent effects on attraction by heat. Since the toxicity to the cockroaches is relatively low, the cockroaches are not caused to die and a dirty feeling is not caused without leaving carcasses in apparatuses. Since the vapor pressure is relatively low, the repellent in advantageous without any malodor.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は、ゴキブリなどの不
快・衛生害虫忌避を目的とする忌避剤に関するものであ
る。
TECHNICAL FIELD The present invention relates to a repellent for the purpose of repelling unpleasant and hygienic pests such as cockroaches.

【0002】[0002]

【従来の技術】家庭内、特に台所で使用する機器は、ゴ
キブリを始めとする不快害虫あるいは衛生害虫の侵入に
より大きな被害を被る場合がある。ゴキブリは、餌によ
り誘引されるばかりでなく、熱にも誘引される。代表的
なチャバネゴキブリの集合至適温度は27±5℃であ
る。台所にある調理用をはじめとする電化製品は、内部
に食品くずが残るなどゴキブリの誘引物質があり、さら
に内部に発熱部を有するかあるいは保温・蓄熱機能を有
するため、不快害虫の誘引至適温度となっている。特
に、これら家電製品の底部と床面には1cm前後の間隙
が設けられ、物の陰に隠れようという性質を有するゴキ
ブリの生息環境を作っている。また、機器は完全密閉に
しようとしても、放熱部や開閉部などがあるから、完全
な密閉構造を取りにくい。そこで、ゴキブリを始めとす
る不快害虫あるいは衛生害虫の機器への侵入を防止する
ため、各種の忌避剤が提案されている。
2. Description of the Related Art Devices used at home, particularly in kitchens, may be greatly damaged by invasion of unpleasant insects such as cockroaches or sanitary insects. Cockroaches are not only attracted by food, but also by heat. The typical optimum temperature for the assembly of German cockroaches is 27 ± 5 ° C. Electric appliances such as those for cooking in the kitchen have an attractant for cockroaches such as food scraps left inside, and also have a heat generating part inside or have a heat retaining / storing function, which is optimal for attracting unpleasant pests. It's temperature. In particular, a gap of about 1 cm is provided between the bottom and the floor of these home appliances to create a habitat for cockroaches that has the property of hiding behind objects. In addition, even if the device is to be completely sealed, it is difficult to take a completely sealed structure because of the heat radiation part and the opening / closing part. Therefore, various repellents have been proposed in order to prevent invasion of unpleasant insects such as cockroaches or sanitary insects into the equipment.

【0003】[0003]

【発明が解決しようとする課題】しかし、熱による誘引
に対して十分な忌避効果があり、しかも機器の発熱部付
近に設置しても長期間忌避効果を発揮する忌避剤は得ら
れていない。また、殺虫作用の強い薬剤であると、機器
内に侵入した害虫が死骸として残存し、不衛生である。
そこで、熱による誘引に対して忌避効果があり、かつ薬
剤に短時間触れても殺虫作用の少ない薬剤が要望されて
いた。本発明は、そのような要望に応える害虫忌避剤を
提供することを目的とする。
However, no repellent which has a sufficient repellent effect against attraction by heat and has a long-term repellent effect even when it is installed near the heat-generating part of the device has not been obtained. In addition, if the drug has a strong insecticidal action, the harmful insects that have entered the device remain as carcasses, which is unsanitary.
Therefore, there has been a demand for a drug that has a repellent effect against attraction by heat and has a small insecticidal action even if the drug is touched for a short time. The object of the present invention is to provide a pest repellent that meets such a demand.

【0004】[0004]

【課題を解決するための手段】本発明の害虫忌避剤は、
α−シアノ−3−フェノキシベンジルクリサンテマー
ト、2−(4−エトキシフェニル)−2−メチルプロピ
ルー3−フェノキシベンジル、o−フェニルフェノー
ル、およびp−t−オクチルフェノールを有効成分とす
る。これら有効成分の混合割合は、α−シアノ−3−フ
ェノキシベンジルクリサンテマートが1〜50重量%、
2−(4−エトキシフェニル)−2−メチルプロピルー
3−フェノキシベンジルが1〜80重量%、o−フェニ
ルフェノールが1〜70重量%、p−t−オクチルフェ
ノールが1〜70重量%の範囲が適当である。
The insect pest repellent of the present invention comprises:
α-Cyano-3-phenoxybenzyl chrysanthemate, 2- (4-ethoxyphenyl) -2-methylpropyl-3-phenoxybenzyl, o-phenylphenol, and pt-octylphenol are used as active ingredients. The mixing ratio of these active ingredients is 1 to 50% by weight of α-cyano-3-phenoxybenzyl chrysanthemate,
The range of 2- (4-ethoxyphenyl) -2-methylpropyl-3-phenoxybenzyl is 1 to 80% by weight, o-phenylphenol is 1 to 70% by weight, and pt-octylphenol is 1 to 70% by weight. Appropriate.

【0005】本発明の忌避剤に用いるα−シアノ−3−
フェノキシベンジルクリサンテマートおよび2−(4−
エトキシフェニル)−2−メチルプロピルー3−フェノ
キシベンジルは、ゴキブリに対しては接触により忌避効
果を発揮する。室温では揮散性が殆どないから持続期間
が長い。o−フェニルフェノールは、室温では揮散性を
有し、接触による忌避および揮散した気体の嗅覚刺激に
よる忌避の双方に効果を有する。また、p−t−オクチ
ルフェノールは、室温では幾分の揮散性を有し、接触に
よる忌避および揮散した気体の嗅覚刺激による忌避の双
方に効果を有する。
Α-Cyano-3-used in the repellent of the present invention
Phenoxybenzyl chrysanthemate and 2- (4-
Ethoxyphenyl) -2-methylpropyl-3-phenoxybenzyl exerts a repellent effect upon contact with cockroaches. It has a long duration because it has almost no volatility at room temperature. o-Phenylphenol is volatile at room temperature, and is effective in both repelling by contact and repelling an olfactory stimulus of the vaporized gas. Further, p-t-octylphenol has some volatility at room temperature, and is effective in both repelling by contact and repelling volatilized gas by olfactory stimulation.

【0006】本発明の忌避剤は、上記有効成分の組み合
わせにより、ゴキブリに対して接触忌避および揮散した
気体の嗅覚刺激による忌避の双方に効果を有するばかり
でなく、熱誘引に対する忌避効果をも有し、しかも機器
の発熱部付近に設置しても長期間忌避効果を発揮する。
また、ゴキブリに対して毒性が比較的低いので、死亡さ
せるに至らず、機器内に死骸を残すことなく不潔感を生
じさせない。さらに、蒸気圧が比較的低いので、異臭感
を与えず、生活空間に設置する家電機器への適用が可能
である
The repellent of the present invention has not only an effect of contact repelling cockroaches and repelling a volatilized gas by olfactory stimulation, but also a repellent effect of heat attraction by the combination of the above active ingredients. Moreover, even if it is installed near the heat-generating part of the device, it has a long-term repellent effect.
In addition, since it is relatively low in toxicity to cockroaches, it does not cause death and leaves no carcass in the device and does not cause filthiness. Furthermore, since the vapor pressure is relatively low, it does not give a strange odor and can be applied to home appliances installed in living spaces.

【0007】[0007]

【発明の実施の形態】本発明の忌避剤の上記有効成分
は、室温において、組み合わせにより固体から液体まで
の状態であり、これらの混合物をそのままゴキブリ忌避
の要求される区域等に適用することができるが、通常好
ましくは適当な担体、その他の配合剤を用いて適用区
域、適用方法等に適した各種の形態、例えば液剤、固剤
等に調製して利用される。液剤の形態に調製するに当た
り用いられる担体としては、例えばメチルアルコール、
エチルアルコール等のアルコール類、アセトン等のケト
ン類、ケロシン、パラフィン、石油ベンジン等の脂肪族
炭化水素類、ベンゼン、トルエン等の芳香族炭化水素類
等を例示できる。また、固剤の形態に調製するに当たり
用いられる担体としては、例えばケイ酸、カオリン、活
性炭、ベントナイト、珪藻土、タルク、クレー、炭酸カ
ルシウム、陶磁器粉等の鉱物質粉末や、木粉、大豆粉、
小麦粉、でん粉等の植物質粉末やシクロデキストリン等
の包接化合物等を例示できる。ただし、上記の有効成分
の量は、忌避剤を適用する部位または基材の面積100
cm2当たりα−シアノ−3−フェノキシベンジルクリ
サンテマートを0.5〜15mg、2−(4−エトキシ
フェニル)−2−メチルプロピルー3−フェノキシベン
ジルを0.5〜30mg、o−フェニルフェノールを1
〜10mg、p−t−オクチルフェノールを2〜20m
gとすることにより、優れた忌避効果が得られる。なか
でも、α−シアノ−3−フェノキシベンジルクリサンテ
マートを2〜10mg、2−(4−エトキシフェニル)
−2−メチルプロピルー3−フェノキシベンジルを5〜
20mg、o−フェニルフェノールを2〜15mg、p
−t−オクチルフェノールを4〜20mgとなるように
混合したもので最も優れた忌避性能が得られた。
BEST MODE FOR CARRYING OUT THE INVENTION The above-mentioned active ingredients of the repellent of the present invention are in a state of solid to liquid depending on the combination at room temperature, and it is possible to apply the mixture as it is to an area or the like where cockroach repulsion is required. However, it is usually preferably prepared by using a suitable carrier or other compounding agent in various forms suitable for the application area, application method and the like, for example, a liquid formulation, a solid formulation and the like. Examples of the carrier used for preparing the liquid form include methyl alcohol,
Examples thereof include alcohols such as ethyl alcohol, ketones such as acetone, aliphatic hydrocarbons such as kerosene, paraffin and petroleum benzine, and aromatic hydrocarbons such as benzene and toluene. Further, as a carrier used in preparing a solid formulation, for example, silicic acid, kaolin, activated carbon, bentonite, diatomaceous earth, talc, clay, calcium carbonate, mineral powder such as ceramic powder, wood flour, soybean flour,
Examples thereof include plant powders such as wheat flour and starch, inclusion compounds such as cyclodextrin, and the like. However, the amount of the above-mentioned active ingredient depends on the area of the site or substrate to which the repellent is applied.
0.5 to 15 mg of α-cyano-3-phenoxybenzyl chrysanthemate, 0.5 to 30 mg of 2- (4-ethoxyphenyl) -2-methylpropyl-3-phenoxybenzyl, and o-phenylphenol per cm 2. 1
-10 mg, pt-octylphenol 2-20 m
By setting g, an excellent repellent effect can be obtained. Among them, 2 to 10 mg of α-cyano-3-phenoxybenzyl chrysanthemate, 2- (4-ethoxyphenyl)
2-Methylpropyl-3-phenoxybenzyl 5 to
20 mg, o-phenylphenol 2-15 mg, p
The best repellent performance was obtained with a mixture of -t-octylphenol in an amount of 4 to 20 mg.

【0008】[0008]

【実施例】以下、本発明の実施例について説明する。 《実施例1》α−シアノ−3−フェノキシベンジルクリ
サンテマート、2−(4−エトキシフェニル)−2−メ
チルプロピルー3−フェノキシベンジル、o−フェニル
フェノール、およびp−t−オクチルフェノールの混合
比率を変えて、大きさ10×10cmのNo.2の濾紙
に塗工し、忌避剤試料とした。そして、チャバネゴキブ
リに対する接触忌避性および熱誘引忌避性等について評
価した。
Embodiments of the present invention will be described below. Example 1 Mixing ratio of α-cyano-3-phenoxybenzyl chrysanthemate, 2- (4-ethoxyphenyl) -2-methylpropyl-3-phenoxybenzyl, o-phenylphenol, and pt-octylphenol No. of 10 × 10 cm in size. It was applied to the filter paper of No. 2 and used as a repellent sample. Then, contact repellency and heat attraction repellency against German cockroaches were evaluated.

【0009】まず、接触忌避性については、法面に逃亡
防止処理を施した大きさ100×100cmの箱内に、
忌避剤で処理をしていない濾紙(A)、上記の忌避剤試
料(B)、および上記の忌避剤試料の上にこれを覆う大
きさのポリエステル製メッシュを積層したもの(C)を
それぞれ離して設置し、それらの上に餌として約6gの
角砂糖をのせ、ゴキブリ雌雄各100匹ずつを放し、2
日後の餌の減少量を調べた。そして、減少量の比較に基
づき以下の基準で接触忌避性を表した。
First, regarding contact repellency, in a box of 100 × 100 cm in size, the slope of which has been subjected to escape prevention treatment,
Separate the filter paper (A) not treated with repellent, the repellent sample (B), and the repellent sample with a polyester mesh of a size covering the repellent sample (C), separated from each other. Place about 6g of sugar cubes as bait on them and release 100 cockroaches each
The amount of food reduced after the day was examined. Then, the contact repellency was expressed based on the following criteria based on the comparison of the reduction amounts.

【0010】[接触忌避性の評価基準] ◎:試料AおよびCにおける減少量がほぼ同じで、Aの
減少量とBの減少量の比A/Bが15以上、○:同じく
A/Bが3以上15未満、×:同じくA/Bが3未満、
または試料BおよびCにおける減少量がほぼ同じ。
[Evaluation Criteria for Contact Repellency] ⊚: The reduction amounts of Samples A and C are almost the same, and the ratio A / B of the reduction amount of A and the reduction amount of B is 15 or more. 3 or more and less than 15, x: Similarly, A / B is less than 3,
Alternatively, the reduction amounts in Samples B and C are almost the same.

【0011】持続性については、上記の忌避剤試料
(B)の初期効果を確認した後、これを40℃の雰囲気
に2カ月間放置した。この試料をB’とし、忌避剤で処
理をしていない濾紙(A)とともに前記と同様の箱内に
設置し、同様の試験をした。
Regarding the sustainability, after confirming the initial effect of the repellent sample (B), it was left in an atmosphere of 40 ° C. for 2 months. This sample was designated as B ', and placed in the same box as above with the filter paper (A) not treated with a repellent, and the same test was conducted.

【0012】[持続性の評価基準] ◎:試料Aの減少量とB’の減少量の比A/B’が15
以上、○:同じくA/B’が3以上15未満、×:同じ
くA/Bが3未満。
[Evaluation Criteria for Sustainability] ⊚: The ratio A / B ′ of the amount of decrease of sample A and the amount of decrease of B ′ is 15
Above, ◯: A / B 'is 3 or more and less than 15 similarly, ×: A / B is also less than 3

【0013】熱誘引忌避性については、大きさ50×5
0cmの箱内に、右半分中央には上記の忌避剤試料
(B)を配置し、その中央に27±5℃に制御されたヒ
ーターをのせる。一方、箱の左半分中央には忌避剤で処
理をしていない濾紙(A)を配置し、その中央に27±
5℃に制御されたヒーターをのせる。この箱内にチャバ
ネゴキブリ雌雄各100匹ずつを放し、試料AまたはB
に侵入するゴキブリの個体数を24時間のビデオテープ
レコーダーの記録から計数した。
Regarding the heat attracting and repelling property, the size is 50 × 5.
The repellent sample (B) is placed in the center of the right half in a 0 cm box, and a heater controlled at 27 ± 5 ° C. is placed in the center. On the other hand, filter paper (A) not treated with repellent is placed in the center of the left half of the box, and 27 ±
Place a heater controlled at 5 ° C. 100 male and female German cockroaches were released in this box, and sample A or B
The number of cockroaches invading the worm was counted from a 24-hour videotape recorder recording.

【0014】[熱誘引忌避性の評価基準] ◎:試料Aへ侵入した個体数と試料Bへ侵入した個体数
の比A/Bが50以上、○:同じくA/Bが5以上50
未満、×:同じくA/Bが5未満。
[Evaluation Criteria for Heat-Attractive Repellent Property] ◎: Ratio A / B of the number of individuals invading sample A and the number of individuals invading sample B is 50 or more, ◯: A / B is also 5 or more 50
Less than, x: Similarly, A / B is less than 5.

【0015】生存率については、忌避剤試料(B)のみ
を設置した箱を用いた上記と同様の接触忌避試験による
ゴキブリの死亡した個体数の割合で表した。これらの結
果を表1に示す。
The survival rate was expressed as the ratio of the number of dead cockroaches in the same contact repellent test as described above using a box containing only the repellent sample (B). Table 1 shows the results.

【0016】[0016]

【表1】 [Table 1]

【0017】《実施例2》表2に本発明の忌避剤の幾つ
かの好ましい処方例を示す。
Example 2 Table 2 shows some preferred prescription examples of the repellent of the present invention.

【0018】[0018]

【表2】 [Table 2]

【0019】[0019]

【発明の効果】以上のように本発明の忌避剤は、ゴキブ
リに対して有効な忌避効果を発揮するとともに、熱誘引
に対しても忌避効果を有し、しかも機器の発熱部付近に
設置しても長期間忌避効果を発揮する。従って、特に家
電機器にゴキブリ忌避機能を付与するのに有効である。
INDUSTRIAL APPLICABILITY As described above, the repellent of the present invention has an effective repellent effect against cockroaches and also has a repellent effect against heat attraction, and is installed near the heat-generating part of the device. However, it has a long-term repellent effect. Therefore, it is particularly effective in providing a home appliance with a cockroach repellent function.

フロントページの続き (72)発明者 弘中 豊 赤穂市元禄橋町20 アコーデリア元禄201 号 (72)発明者 新田 勇 赤穂市塩屋1269−11 (72)発明者 伊藤 達栄 赤穂市本水尾町10−20Continuation of the front page (72) Yutaka Hironaka 20 Genrokubashicho, Ako-shi 20 Accorderia Genroku 201 (72) Inventor Isamu Nitta 1269-11 Shioya, Ako-shi Tatsuei Ito 10 Motomizuo-cho, Ako-shi -20

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 α−シアノ−3−フェノキシベンジルク
リサンテマート、2−(4−エトキシフェニル)−2−
メチルプロピルー3−フェノキシベンジル、o−フェニ
ルフェノール、およびp−t−オクチルフェノールを有
効成分とする害虫忌避剤。
1. α-Cyano-3-phenoxybenzyl chrysanthemate, 2- (4-ethoxyphenyl) -2-
A pest repellent containing methylpropyl-3-phenoxybenzyl, o-phenylphenol, and pt-octylphenol as active ingredients.
【請求項2】 1〜50重量%のα−シアノ−3−フェ
ノキシベンジルクリサンテマート、1〜80重量%の2
−(4−エトキシフェニル)−2−メチルプロピルー3
−フェノキシベンジル、1〜70重量%のo−フェニル
フェノール、および1〜70重量%のp−t−オクチル
フェノールからなる害虫忌避剤。
2. 1 to 50% by weight of α-cyano-3-phenoxybenzyl chrysanthemate, 1 to 80% by weight of 2.
-(4-Ethoxyphenyl) -2-methylpropyl-3
An insect repellent consisting of phenoxybenzyl, 1-70% by weight o-phenylphenol, and 1-70% by weight pt-octylphenol.
JP01576196A 1996-01-31 1996-01-31 Pest repellent Expired - Fee Related JP3745432B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP01576196A JP3745432B2 (en) 1996-01-31 1996-01-31 Pest repellent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP01576196A JP3745432B2 (en) 1996-01-31 1996-01-31 Pest repellent

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JPH09208410A true JPH09208410A (en) 1997-08-12
JP3745432B2 JP3745432B2 (en) 2006-02-15

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JP01576196A Expired - Fee Related JP3745432B2 (en) 1996-01-31 1996-01-31 Pest repellent

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009061341A3 (en) * 2007-11-07 2010-07-22 Bayer Cropscience Lp Insecticidal compositions with disinfectant

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009061341A3 (en) * 2007-11-07 2010-07-22 Bayer Cropscience Lp Insecticidal compositions with disinfectant

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JP3745432B2 (en) 2006-02-15

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