JPH09176340A - Production of film of liquid crystal polyester resin composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To stably and continuously obtain a thin liquid crystal polyester film having gas-barrier properties by dissolving a thermotropic liquid crystal polyester resin composition in an organic solvent, adding a non-solvent of the composition to the resultant solution and film-forming. SOLUTION: A composition comprising (A) 56-99wt.% of a thermotropic liquid crystal polyester preferably containing a structural unit expressed by the formula in an amount of >=30mol% of total and (B) 44-1wt.% of at least one kind of a thermoplastic resin selected from among polycarbonate, a polyester and polymethyl methacrylate, etc., is dissolved in an organic solvent (preferably tetrafluorophenol, etc.) and resultant solution is added with a non-solvent of the composition (preferably acetone, methanol or ethanol) to form a two-phase state, then a film of the composition generated on the interface is taken off. As the component B, an ethylene copolymer having a reaction group reactive with the component A by melt-blending and more preferably an epoxy group- containing ethylene copolymer are exemplified.

Description

Detailed Description of the Invention

[0001]

TECHNICAL FIELD The present invention relates to a method for producing a liquid crystal polyester resin composition film. More specifically, a stable and continuous method for producing a thin film of a liquid crystal resin polyester composition having gas barrier properties, which comprises adding a non-solvent of the composition to a solution of the liquid crystal polyester resin composition to form a film. Regarding

[0002]

2. Description of the Related Art Liquid crystal polyesters form domains having a liquid crystal state, but since the molecules are rigid, they do not become entangled even in the molten state, and their molecular chains exhibit a behavior in which they are significantly oriented in the flow direction due to a low shear rate. It is called a fused liquid crystal (thermotropic liquid crystal) polymer. Liquid crystal polyester has excellent melt flowability due to this peculiar behavior, and 300 ° C depending on the structure due to higher molecular orientation.
It has the above-mentioned thermal deformation resistance, and it is used for electronic parts, OA, A
It is used for molded products such as V parts and heat-resistant tableware.

On the other hand, a film made of a liquid crystal polyester is known to have an excellent gas barrier property in addition to the above-mentioned properties, but since an appropriate film processing technique has not been established, it is possible to develop applications utilizing the properties. Little was done. Regarding the production of a liquid crystal polyester film, for example, Japanese Patent Application Laid-Open No. 63-49415 discloses a method for producing an extruded film using a uniaxial extruder, but the liquid crystal polyester has a characteristic of being oriented in the extrusion direction. In addition, compared with the tensile strength and tensile modulus of the film in the machine direction (flow direction), there was a defect that they were weaker in the transverse direction. Further, since liquid crystal polyester generally has a high solidification rate, it has been extremely difficult to stably produce an extruded film using an extruder.

In order to alleviate the anisotropy of the mechanical properties of such a liquid crystal polyester film, it is necessary to use the method described in Japanese Patent Publication No.
In 6779, a film is extruded using a plurality of dies having annular flow paths having different rotation directions, whereby a bonded product of films whose alignment directions are substantially perpendicular to each other is obtained, and the above-mentioned problems Is disclosed. However, also in this case, it was difficult to reduce the thickness of the obtained film, and it was substantially difficult to manufacture a film having a thickness of 30 μm or less.

On the other hand, as a method for obtaining a liquid crystal polyester film, there are disclosed in JP-A-62-648832 and JP-A-5-4832.
No. 186614 discloses a method of dissolving a liquid crystal polyester in an organic solvent and casting the solution to obtain a film, but since it is not a method of continuously forming a film, the production efficiency is low and it is practical. There wasn't.

[0006]

An object of the present invention is to provide a method for stably and continuously producing a thin film of a liquid crystal polyester resin composition having a gas barrier property.

[0007]

Means for Solving the Problems As a result of intensive studies to solve these problems, the present inventors have found that a liquid crystal polyester resin composition is dissolved in an organic solvent and a non-solvent of the composition is added to the solution. In addition, a method of continuously forming a liquid crystal polyester resin composition by forming a two-phase state and collecting the liquid crystal polyester resin composition film formed at the interface was found, and the present invention was completed.

That is, the present invention comprises (A) a liquid crystal polyester and (B) a polycarbonate, at least one thermoplastic resin selected from polyesters, polymethylmethacrylate, polystyrene, ethylene copolymers and polyolefins, A method for producing a liquid crystal polyester resin composition film, wherein the ratio of (A) to component (B) is 56 to 99% by weight of component (A) and 44 to 1% by weight of component (B). A method for producing a liquid crystal polyester resin composition film, wherein a non-solvent of the composition is added to a solution obtained by dissolving the product in an organic solvent to form a two-phase state, and the composition film formed at the interface is taken off. is there.

[0009]

BEST MODE FOR CARRYING OUT THE INVENTION The present invention will be described in detail below.

The liquid crystal polyester used in the present invention is a polyester called a thermotropic liquid crystal polymer, which is derived from a combination of (1) an aromatic dicarboxylic acid, an aromatic diol and an aromatic hydroxycarboxylic acid, (2) ) Those derived from different aromatic hydroxycarboxylic acids, (3) those obtained by reacting polyesters such as polyethylene terephthalate with aromatic hydroxycarboxylic acids, etc., and anisotropic melts at temperatures of 400 ° C. or lower. Is formed. Incidentally, instead of these aromatic dicarboxylic acids, their ester-forming derivatives may be used.

Examples of the repeating structural unit of the liquid crystal polyester include the followings, but the present invention is not limited thereto.

Repeating structural unit derived from aromatic hydroxycarboxylic acid

Embedded image

Repeating structural unit derived from aromatic dicarboxylic acid:

Embedded image

Repeating structural unit derived from aromatic diol:

Embedded image

[0015]

Embedded image

From the viewpoint of balance between heat resistance, mechanical properties and processability, a particularly preferable polyester is _one containing at least 30 mol% of repeating structural units represented by the following formula A ₁ .

[Chemical 6]

Specifically, the following combinations of repeating structural units (a) to (f) are preferred.

(A): (A ₁ ), (B ₁ ) or a mixture of (B ₁ ) and (B ₁ ) and (C ₁ ). (B): (A ₁ ) and (A ₂ ). (C) in those combinations of the structural units of :( a), obtained by replacing a part of A ₁ in A _2. (D): A combination of the structural units shown in (a) in which a part of B ₁ is replaced with B ₃ . (E): A combination of the structural units shown in (a) in which a part of C ₁ is replaced with C ₃ . (F): a combination of the structural units of (b) with the addition of the structural units of B ₁ and C ₁ .

The liquid crystal polyesters of (a) and (b) which are the basic structures are, for example, Japanese Patent Publication No. 47-4.
No. 7870, Japanese Patent Publication No. 63-3888, and the like.

The component (B) thermoplastic resin used in the present invention is at least one thermoplastic resin selected from polycarbonate, polyester, polymethylmethacrylate, polystyrene, ethylene copolymer and polyolefin. When the liquid crystal polyester resin composition is obtained by melt-kneading, the melt temperature of the liquid crystal polyester is high, and thus the melt viscosities of the component (A) and the component (B) are significantly different. Since there is concern about poor dispersion in A), preferably an ethylene copolymer having a reactive group capable of reacting with component (A) in melt kneading, more preferably an epoxy group-containing ethylene copolymer. Polymers may be mentioned.

Specific examples of the polyester include polybutylene terephthalate and polyethylene terephthalate, and specific examples of the polyolefin include polypropylene and polyisobutylene.

As a preferred example of the ethylene copolymer which is the thermoplastic resin (B) used in the present invention, the ethylene unit is from 50 to 99.9% by weight, preferably from 60 to 9.
90% by weight, (b) an unsaturated carboxylic acid glycidyl ester unit or an unsaturated carboxylic acid glycidyl ether unit is 0.1 to 30% by weight, preferably 0.5 to 25% by weight, and (c) an ethylenically unsaturated ester compound. Unit is 0
The epoxy group-containing ethylene copolymer is 50% by weight, preferably 0.5-40% by weight. Component (a), (b) and (c) of the epoxy group-containing copolymer
Is preferably within the above range in terms of heat resistance and film forming processability of the obtained liquid crystal polyester resin composition.

The compounds (b) which give the unsaturated carboxylic acid glycidyl ester unit and the unsaturated glycidyl ether unit in the epoxy group-containing ethylene copolymer are represented by the following general formulas 7 and 8, respectively.

[0024]

Embedded image (R is a hydrocarbon having an ethylenically unsaturated bond and having 2 to 13 carbon atoms)

[0025]

Embedded image (R is a hydrocarbon group having 2 to 18 carbon atoms which has an ethylenically unsaturated bond, X is -CH ₂ -O- or

Embedded image It is. )

Specific examples include glycidyl arylate, glycidyl methacrylate, itaconic acid glycidyl ester, allyl glycidyl ether, 2-methylallyl glycidyl ether, and styrene-p-glycidyl ether.

The epoxy group-containing ethylene copolymer includes ternary or more of (a) ethylene, (b) unsaturated carboxylic acid glycidyl ester or unsaturated glycidyl ether, and (c) ethylenically unsaturated ester compound. Can be used.

Examples of the ethylenically unsaturated ester compound (c) include carboxylic acids such as vinyl acetate, vinyl propionate, methyl acrylate, ethyl acrylate, butyl acrylate, methyl methacrylate, ethyl methacrylate and butyl methacrylate. Vinyl ester, α, β
-Unsaturated carboxylic acid alkyl ester etc. are mentioned.
Particularly, vinyl acetate, methyl acrylate and ethyl acrylate are preferred.

Specific examples of the epoxy group-containing ethylene copolymer include, for example, a copolymer composed of an ethylene unit, a glycidyl methacrylate unit and an ethyl acrylate unit, a copolymer composed of an ethylene unit, a glycidyl methacrylate unit and a vinyl acetate unit. Examples thereof include copolymers, but from the viewpoint of thermal stability, a copolymer composed of an ethylene unit, a glycidyl methacrylate unit and a methyl acrylate unit is preferably used.

Further, the melt index of the epoxy group-containing ethylene copolymer [hereinafter sometimes referred to as MFR. Measured according to JIS K6760 (190 ° C, 2.16k
g load)] is preferably 0.5 to 100 g / 1
It is 0 minutes, more preferably 2 to 50 g / 10 minutes. The melt index may be out of this range, but if the melt index exceeds 100 g / 10 minutes, it is not preferable in terms of mechanical properties when the composition is prepared, and 0.5 g / 10
If it is less than minutes, the compatibility with the liquid crystal polyester of the component (A) is poor, which is not preferable.

The epoxy group-containing ethylene copolymer is usually obtained by copolymerizing an unsaturated epoxy compound and ethylene in the presence of a radical generator at 500 to 4000 at 100 to 300 ° C. in the presence of a suitable solvent or chain transfer agent. It is produced by a method of polymerizing. It can also be prepared by a method of mixing an unsaturated epoxy compound and a radical generator with polyethylene and performing melt graft polymerization in an extruder.

The ratio of the component (A) to the component (B) in the liquid crystal polyester resin composition used in the present invention is such that the component (A) is 56 to 99% by weight, preferably 70 to 98% by weight, and the component (B). 44-1%, preferably 30-2% by weight
It is. When the content of the component (A) is less than 56% by weight, the gas barrier property of the film obtained from the composition is deteriorated, which is not preferable.

The method for producing the liquid crystal polyester resin composition in the present invention is not particularly limited, and known methods can be used. For example, mixing each component in a solution state,
The method of evaporating a solvent or precipitating in a solvent is mentioned. From an industrial point of view, a method of kneading each component in a molten state is preferable. For the melt kneading, kneading apparatuses such as a single-screw or twin-screw extruder and various kneaders which are generally used can be used. In particular, a biaxial high kneader is preferred. At the time of melt kneading, the cylinder set temperature of the kneading device is preferably in the range of 200 to 360 ° C, more preferably 230 to 340 ° C. When the components are mixed in a solution state, a nonsolvent may be added to the solution to form a film.

Upon kneading, the respective components may be mixed in advance by an apparatus such as a tumbler or a Henschel mixer, or a method of omitting the mixing and separately feeding each of the ingredients to the kneading apparatus may be used. it can.

The organic solvent that dissolves the liquid crystal polyester resin composition of the present invention is not limited to a single solvent or a mixed solvent, and is not particularly limited as long as the liquid crystal polyester resin composition can be dissolved. Examples of the organic solvent include those in which a part or all of the nucleus-substituted hydrogen of phenol is replaced with fluorine, or a derivative thereof. Preferred are tetrafluorophenol and pentafluorophenol.

Further, as the organic solvent, a mixed solvent obtained by adding a halide of chloroform, methylene chloride, tetrachloroethane or the like to these solvents as long as the solubility of the aromatic polyester is not significantly lowered can be used. Considering that the liquid crystal polyester resin composition has low solubility in an organic solvent, it is preferable to add these solvents after once dissolving in a single solvent having high solubility. When a solvent such as tetrafluorophenol, pentafluorophenol or the like having a high melting point of around 40 ° C. is used as the organic solvent, it is preferable to add the above-mentioned solvent to the solidification of the solution after the preparation.

The method of dissolving the liquid crystal polyester resin composition in these solvents is not particularly limited, but it is preferable to add the liquid crystal polyester resin composition to these solvents and stir while heating.

The concentration of the liquid crystal polyester resin composition solution prepared in the present invention may be any concentration as long as the liquid crystal polyester resin composition is dissolved and a film can be formed. The preferred polymer concentration range depends on the weight% of the liquid crystal polyester contained in the resin composition. Specifically, when the liquid crystal polyester resin composition contains x weight% of the liquid crystal polyester, the range is 0. .005x-0.
05x% is preferable, and 0.005x to 0.03x% is more preferable. If the polymer concentration exceeds 0.05x%, it may take too long to dissolve the liquid crystal polyester resin composition and it may not completely dissolve. If it is less than 0.005x%, it is difficult to obtain a continuous film, which is not preferable.

Next, in the present invention, a non-solvent for the liquid crystal polyester resin composition is added to a solution prepared by dissolving the liquid crystal polyester resin composition in an organic solvent to form a two-phase state.

The non-solvent of the liquid crystal polyester resin composition in the present invention is a solvent in which the liquid crystal polyester resin composition is not substantially dissolved, and is a solvent having a high solubility of 0.01% by weight. . Specifically, a solvent containing any one of acetone, methanol, ethanol, water, etc. as a main component can be used. Among these, acetone, methanol, and ethanol are compatible with the organic solvent capable of dissolving the liquid crystal polyester resin composition, and by precipitating the dissolved liquid crystal polyester resin composition, it is easy to form a film at the interface. Is preferred.

In order for the non-solvent and the solution in which the liquid crystal polyester resin composition is dissolved to form a two-phase state, it is necessary that the two have a density difference.

A new film of the liquid crystal polyester resin composition is formed at the interface between the solution in which the liquid crystal polyester resin composition is dissolved in the organic solvent and the non-solvent of the liquid crystal polyester resin composition. Obtainable.

One embodiment is shown in FIG. By using the apparatus as shown in this figure, the liquid crystal polyester resin composition film is sequentially drawn and the liquid crystal polyester resin composition solution is sequentially replenished into the system, so that the liquid interface is kept stable and the film is taken off. Can be continuously continued, and a continuous film of the liquid crystal polyester resin composition can be stably produced. In addition, the thickness of the produced film can be controlled by changing the solution concentration and the film take-up speed.

The film thus formed may be immediately dried with hot air to remove the solvent, but once the liquid crystal polyester resin composition is not dissolved, a solvent compatible with the organic solvent, such as acetone, is used. It is also preferable that the solvent is recovered by passing it through the film in the solvent (1), followed by hot air drying.

With respect to the liquid crystal polyester resin composition used in the present invention, to the extent that the object of the present invention is not impaired,
Colorants such as dyes, pigments, etc., unless dissolved in a non-solvent;
Conventional additives such as an antioxidant, a heat stabilizer, an antistatic agent, and a surfactant can be added.

[0046]

EXAMPLES Examples of the present invention will be described below, but the present invention is not limited to these examples.

Regarding the method for measuring the oxygen transmission rate of the formed liquid crystal polyester resin composition film, JIS K71
It measured by the method according to the 26A method. The unit is cc / m ² ·
It was 24 hr · 1 atm and converted into a film thickness of 25 μm.

[Component (B) Thermoplastic Resin, Ethylene Copolymer Component] Physical Properties of Epoxy Group-Containing Ethylene Copolymer, Polybutylene Terephthalate, and Polyethylene Terephthalate Used in Examples and Epoxy Group-Containing Ethylene Copolymer The composition is as follows. B-1: Copolymer produced by high-pressure radical polymerization method Composition: ethylene / glycidyl methacrylate / methyl acrylate = 67/3/30 (weight ratio) MFR (190 ° C., load 2.16 kg) = 9 Bending rigidity = 69 kg / cm2 (based on ASTM D747) -B-2: Polyethylene terephthalate (Mitsubishi Rayon Co., Ltd., trade name: Diamond Alloy TW90E) -B-3: Polycarbonate (Sumitomo Dow Co., Ltd., trade name CALIBER 200) -6) MFR (300 ° C, load 1.2kg) = 6

Reference Example 1 [Liquid Crystal Polyester (A-1) of Component (A)] p-acetoxybenzoic acid 10.8 kg (60 mol), terephthalic acid 2.49 kg (15 mol), isophthalic acid 0.83 k
g (5 mol) and 4,4'-diacetoxydiphenyl 5.45 kg (20.2 mol) were charged into a polymerization tank having a comb-shaped stirring blade, and strong stirring was performed while heating while stirring under a nitrogen gas atmosphere. Polymerized below. Thereafter, the system was gradually cooled, and the polymer obtained at 200 ° C. was taken out of the system. The obtained polymer was pulverized with a hammer mill manufactured by Hosokawa Micron Co., Ltd. to obtain particles of 2.5 mm or less. By further treating this in a rotary kiln in a nitrogen atmosphere at 280 ° C. for 3 hours, the repeating unit consists of A ₁ , B ₁ , B ₂ and C ₂ , and A ₁ : B ₁ : B ₂ :
A particulate liquid crystalline polyester having a C ₂ molar ratio of 60: 15: 5: 20 and a flow initiation temperature of 324 ° C. was obtained. Hereinafter, the obtained liquid crystal polyester is abbreviated as A-1. This polymer showed optical anisotropy at 340 ° C. or more under pressure.

Reference Example 2 [Liquid Crystal Polyester (A-2) of Component (A)] p-Hydroxybenzoic acid 16.6 kg (12.1 mol) and 6-hydroxy-2-naphthoic acid 8.4 kg (4.5 Mol) and 18.6 kg (18.2 mol) of acetic anhydride are charged into a polymerization tank equipped with comb-shaped stirring blades and heated under stirring in a nitrogen gas atmosphere at 320 ° C. for 1 hour and further 2.0 t.
Polymerization was performed at 320 ° C. for 1 hour under reduced pressure of orr. During this time, acetic acid produced as a by-product was continuously distilled out of the system. Thereafter, the system was gradually cooled, and the polymer obtained at 180 ° C. was taken out of the system. After the resulting polymer was ground in the same manner as A-1 above, by further 5 hours at 240 ° C. under a nitrogen atmosphere in a rotary kiln, it is repeating units from the A _1, A _2, A ₁ A particulate liquid crystalline polyester having a molar ratio of: A ₂ of 73:27 and a flow starting temperature of 270 ° C. was obtained. The obtained liquid crystal polyester is abbreviated as A-2. This polymer is 28 under pressure
It exhibited an optical anisotropy of 0 ° C or higher.

Example 1 After mixing each component together with a stabilizer in a Henschel mixer, the composition was 85% by weight of liquid crystal polyester (A-1) and 15% by weight of epoxy group-containing ethylene copolymer (B-1). Using a TEX-30 type twin screw extruder manufactured by Nippon Steel Co., Ltd., kneading was performed at a cylinder setting temperature of 3000 ° C. to 360 ° C. and a screw rotation speed of 200 rpm to obtain pellets of the resin composition. After dissolving 1.0 g of the resin composition pellets in 128 g of tetrafluorophenol, the solution was placed in a glass container as shown in FIG. 1 and acetone was poured onto the solution. The solution and acetone were separated into two phases. It was observed that a film formed at the phase interface.

In this way, the liquid crystal polyester resin composition was continuously formed by successively taking the films formed at the interface. Tetrafluorophenol remained on the film taken off, especially on the surface in contact with the solution side. When the film was passed through acetone, tetrafluorophenol was dissolved in acetone and removed.

Further, the film formation could be continuously performed by replenishing the lower layer composition solution. After removing the solvent, the film was stretched on glass and naturally dried at room temperature. The thickness of the obtained film was 3 to 7 μm. Oxygen permeability of this film is 1.4cc / m ² · 24hr · 1a
tm.

Example 2 After mixing liquid crystal polyester (A-2) with 85% by weight and epoxy group-containing ethylene copolymer (B-1) with 15% by weight, each component was mixed with a stabilizer in a Henschel mixer. Using a TEX-30 type twin-screw extruder manufactured by Nippon Steel Co., Ltd., the mixture was kneaded at a cylinder set temperature of 300 to 360 ° C. and a screw rotation speed of 200 rpm to obtain pellets of the resin composition. 1.0 g of the resin composition pellets was dissolved in the same manner as in Example 1 except that 120 g of tetrafluorophenol was used, and acetone was added to this solution to form two phases of the solution and acetone. It was confirmed that a film was formed at the interface.

The film thus obtained in the same manner as in Example 1 had a thickness of 4 to 7 μm. The oxygen transmission rate of this film was 1.4 cc / m ² · 24 hr · 1 atm.

Example 3 0.9 g of liquid crystalline polyester (A-1) and 0.1 g of polyethylene terephthalate (B-2) were dissolved in 130 g of tetrafluorophenol in the same manner as in Example 1,
When acetone was added to this solution to form two phases of the solution and acetone, it was confirmed that a film was formed at the interface.

Thereafter, a film was formed in the same manner as in Example 1, and the thickness of the obtained film was 4 to 8 μm. Oxygen permeability of this film is 1.4cc / m ² · 24hr · 1at
m.

Example 4 0.95 g of liquid crystal polyester (A-1) and 0.05 g of polycarbonate (B-3) were dissolved in 158 g of tetrafluorophenol in the same manner as in Example 1, and methanol was added to this solution. When the two phases of the solution and methanol were formed, it was confirmed that a film was formed at the interface.

The film thus obtained in the same manner as in Example 1 had a thickness of 4 to 7 μm. The oxygen transmission rate of this film was 1.3 cc / m ² · 24 hr · 1 atm.

[0060]

According to the method for producing a liquid crystal polyester resin composition film of the present invention, a thin liquid crystal polyester resin composition film having a gas barrier property can be stably and continuously produced. Also, the polymer concentration of the solution,
The film thickness of the liquid crystal polyester resin composition film can be controlled by controlling the take-up speed of the film from the interface between the two phases, and a thin film which cannot be obtained by the conventional method can be obtained.

[Brief description of the drawings]

FIG. 1 is a schematic view showing an example of an apparatus used in the method for producing a liquid crystal polyester resin composition film of the present invention.

[Explanation of symbols]

1 ... A solution in which a liquid crystal polyester resin composition is dissolved. 2 ... Interface between the solution in which the liquid crystal polyester resin composition is dissolved and the non-solvent of the liquid crystal polyester resin composition. 3 ... A non-solvent for the liquid crystal polyester resin composition. 4 ... Liquid crystal polyester resin composition film pulled out. 5 ... A solution in which a liquid crystal polyester resin composition for replenishment is dissolved.

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Claims (5)

[Claims] 1. A liquid crystal polyester (A) and a polycarbonate (B), polyester, polymethyl methacrylate,
It contains at least one thermoplastic resin selected from polystyrene, ethylene copolymer, and polyolefin, and the ratio of the component (A) to the component (B) is 56 to 99 for the component (A).
A method for producing a liquid crystal polyester resin composition film, wherein the composition (B) is contained in an amount of 44 to 1% by weight, wherein a non-solvent of the composition is added to a solution prepared by dissolving the composition in an organic solvent to form a two-phase composition. A method for producing a liquid crystal polyester resin composition film, which comprises forming a state and collecting the composition film formed at the interface. 2. The liquid crystal polyester resin composition film according to claim 1, wherein the liquid crystal polyester (A) contains at least 30 mol% of repeating structural units represented by the following formula A ₁ in the entire liquid crystal polyester (A). Manufacturing method. Embedded image 3. An ethylene copolymer having (a) an ethylene unit of 50 to 99.9% by weight, (b) an unsaturated carboxylic acid glycidyl ester unit or an unsaturated glycidyl ether unit of 0.1 to 30% by weight, ( The method for producing a liquid crystal polyester resin composition film according to claim 1, wherein c) the epoxy group-containing ethylene copolymer comprises 0 to 50% by weight of an ethylenically unsaturated ester unit. 4. The organic solvent in which the liquid crystal polyester resin composition is dissolved is one in which some or all of the nucleus-substituted hydrogen of phenol has been replaced with fluorine, or a derivative thereof. A method for producing a liquid crystal polyester resin composition film. 5. The method for producing a liquid crystal polyester film according to claim 1, wherein the non-solvent is at least one selected from the group consisting of acetone, methanol, ethanol and water.