JPH09108913A - Composite cutting tip whose cutting edge piece has excellent joining strength - Google Patents

Composite cutting tip whose cutting edge piece has excellent joining strength

Info

Publication number
JPH09108913A
JPH09108913A JP7289275A JP28927595A JPH09108913A JP H09108913 A JPH09108913 A JP H09108913A JP 7289275 A JP7289275 A JP 7289275A JP 28927595 A JP28927595 A JP 28927595A JP H09108913 A JPH09108913 A JP H09108913A
Authority
JP
Japan
Prior art keywords
cutting edge
cutting
edge piece
composite
tip
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP7289275A
Other languages
Japanese (ja)
Inventor
Fumihiro Ueda
文洋 植田
Chuichi Ohashi
忠一 大橋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Materials Corp
Original Assignee
Mitsubishi Materials Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Materials Corp filed Critical Mitsubishi Materials Corp
Priority to JP7289275A priority Critical patent/JPH09108913A/en
Publication of JPH09108913A publication Critical patent/JPH09108913A/en
Withdrawn legal-status Critical Current

Links

Abstract

PROBLEM TO BE SOLVED: To increase joining strength of a cutting edge piece to a tip main body by directly brazing a cubic system baron nitride sintered material-made cutting edge piece to a cutting edge part of a tungsten carbide group cemented carbide-made tip main body through an Ni alloy brazing material. SOLUTION: A composite cutting tip contains Ti: 0.5 to 10% and/or Zr: 0.5 to 10%, and Cr: 5 to 20% in weight%, and also contains one kind or two or more kinds: 2 to 10 % among P, B and Si according to its necessity, and a residual part is formed by directly brazing a CBN sintered material-made cutting edge piece to a cutting edge part of a WC group cemented carbide-made tip main body by using an Ni alloy brazing material having the composition composed of Ni and unavoidable impurity. A component of Ti and Zr has an action which improves joining strength by further improving wettability to a tip main body of the brazing material and the cutting edge piece.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】この発明は、炭化タングステ
ン(以下、WCで示す)基超硬合金製チップ本体の切刃
部に対する立方晶窒化ほう素(以下、CBNで示す)焼
結材料製切刃片の接合強度が高く、したがって高速切削
に用いても上記切刃片に剥離の発生がなく、長期に亘っ
てすぐれた切削性能を発揮する複合切削チップに関する
ものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a cutting edge of cubic boron nitride (hereinafter referred to as CBN) sintered material for a cutting edge portion of a tungsten carbide (hereinafter referred to as WC) -based cemented carbide chip body. The present invention relates to a composite cutting tip which has a high joining strength of pieces and therefore does not cause peeling of the cutting edge piece even when used for high speed cutting and exhibits excellent cutting performance for a long period of time.

【0002】[0002]

【従来の技術】従来、例えば特開昭59−134665
号公報に記載され、かつ図1に概略斜視図で示されるよ
うに、CBN焼結材料層3aとWC基超硬合金層3bの
複合体からなる切刃片3を通常の超高圧焼結装置を用い
て製造し、これを、WC基超硬合金製チップ本体の切刃
部に、重量%(以下、%は重量%を示す)で、例えばC
u:19%、Pd:14%、Ti:5%を含有し、残り
がAgと不可避不純物からなる組成を有するAg合金ろ
う材を用いてろう付けしてなる構造の複合切削チップが
広く知られており、これが合金成分としてCrおよびW
を高い割合で含有する高硬度Co基合金(ステライト)
などの切削に用いられることも知られている。
2. Description of the Related Art Conventionally, for example, JP-A-59-134665.
1 and in a schematic perspective view in FIG. 1, a cutting blade piece 3 made of a composite of a CBN sintered material layer 3a and a WC-based cemented carbide layer 3b is provided in a conventional ultra-high pressure sintering apparatus. Manufactured by using, for example, C at the cutting edge portion of the WC-based cemented carbide chip body in% by weight (hereinafter,% means% by weight).
A composite cutting tip having a structure in which u: 19%, Pd: 14%, Ti: 5%, and the rest are brazed using an Ag alloy brazing material having a composition of Ag and inevitable impurities is widely known. Which contains Cr and W as alloy components.
High hardness Co-based alloy (Stellite) containing a high proportion of
It is also known to be used for cutting such as.

【0003】[0003]

【発明が解決しようとする課題】一方、近年の切削加工
装置の高性能化はめざましく、かつ切削加工の省力化に
対する要求も強く、これに伴なって、切削加工は高速化
の傾向にあるが、上記従来複合切削チップはじめ、その
他多くの複合切削チップにおいては、これを高速切削に
用いると、チップ本体と切刃片のろう付け部は、それぞ
れがWC基超硬合金で構成されているので接合上問題は
ないが、CBN焼結材料層とWC基超硬合金層との接合
強度が不十分であるために、この部分から剥離が発生し
易く、比較的短時間で使用寿命に至るのが現状である。
On the other hand, in recent years, cutting machines have been remarkably improved in performance, and there is a strong demand for labor saving in cutting. Accordingly, cutting tends to be speeded up. In the above-mentioned conventional composite cutting tip and many other composite cutting tips, when this is used for high-speed cutting, the brazing portion of the tip body and the cutting edge piece are each made of WC-based cemented carbide. Although there is no problem in joining, since the joining strength between the CBN sintered material layer and the WC-based cemented carbide layer is insufficient, peeling easily occurs from this portion, and the service life is reached in a relatively short time. Is the current situation.

【0004】[0004]

【課題を解決するための手段】そこで、本発明者等は、
上述のような観点から、切刃片全体をCBN焼結材料で
構成し、これをWC基超硬合金製チップ本体の切刃部に
強固な接合強度で直接ろう付けすることができるろう材
を開発すべく研究を行なった結果、Ti:0.5〜10
%および/またはZr:0.5〜10%、Cr:5〜2
0%、を含有し、さらに必要に応じて、P,B、および
Siのうちの1種または2種以上:2〜10%、を含有
し、残りがNiと不可避不純物からなる組成を有するN
i合金ろう材を用いて、WC基超硬合金製チップ本体の
切刃部に直接CBN焼結材料製切刃片をろう付けする
と、前記チップ本体と前記切刃片の間にはすぐれた接合
強度が確保されるようになり、したがってこの結果の複
合切削チップは、これを高速切削に用いても前記切刃片
に剥離の発生なく、長期に亘ってすぐれた切削性能を発
揮するという研究結果を得たのである。
Means for Solving the Problems Accordingly, the present inventors have
From the above viewpoint, a brazing filler metal that can be brazed directly to the cutting edge of the WC-based cemented carbide chip body with a strong bonding strength by constructing the entire cutting edge piece with a CBN sintered material. As a result of research for development, Ti: 0.5 to 10
% And / or Zr: 0.5 to 10%, Cr: 5 to 2
0%, and if necessary, one or more of P, B, and Si: 2 to 10%, and the balance N, which has a composition of Ni and inevitable impurities.
When the cutting edge piece of the WC-based cemented carbide chip body is directly brazed to the cutting edge portion of the WC-based cemented carbide chip body by using the i alloy brazing material, excellent joining is achieved between the chip body and the cutting edge piece. As a result, research has shown that the strength is ensured, and therefore the resulting composite cutting tip exhibits excellent cutting performance over a long period of time without peeling of the cutting edge piece even when it is used for high-speed cutting. Is obtained.

【0005】この発明は、上記の研究結果にもとづいて
なされたものであって、CBN焼結材料製切刃片を、T
i:0.5〜10%および/またはZr:0.5〜10
%、Cr:5〜20%、を含有し、さらに必要に応じ
て、P,B、およびSiのうちの1種または2種以上:
2〜10%、を含有し、残りがNiと不可避不純物から
なる組成を有するNi合金ろう材を介して、WC基超硬
合金製チップ本体の切刃部に直接ろう付けしてなる、切
刃片がすぐれた接合強度を有する複合切削チップに特徴
を有するものである。
The present invention has been made based on the above-mentioned research results, and a cutting blade piece made of a CBN sintered material is
i: 0.5 to 10% and / or Zr: 0.5 to 10
%, Cr: 5 to 20%, and, if necessary, one or more of P, B, and Si:
A cutting edge formed by directly brazing to a cutting edge portion of a WC-based cemented carbide chip body through a Ni alloy brazing material containing 2 to 10% and the balance being Ni and inevitable impurities. The piece is characterized by a composite cutting tip having excellent bonding strength.

【0006】つぎに、この発明の複合切削チップにおい
て、これを構成するNi合金ろう材の成分組成を上記の
通りに限定した理由を説明する。 (a) TiおよびZr これらの成分には、ろう材のチップ本体と切刃片に対す
るぬれ性を一段と向上させ、もって接合強度を向上させ
る作用があるが、その含有量がそれぞれ0.5%未満で
は前記作用に所望の効果が得られず、一方その含有量が
いずれも10%を越えると、ろう付け部の強度が低下す
るようになることから、その含有量をそれぞれ0.5〜
10%、望ましくは5〜7%と定めた。
Next, the reason why the component composition of the Ni alloy brazing material constituting the composite cutting tip of the present invention is limited as described above will be explained. (A) Ti and Zr These components have the effect of further improving the wettability of the brazing material with respect to the chip body and the cutting edge piece, thereby improving the bonding strength, but their contents are each less than 0.5%. However, the desired effect cannot be obtained in the above-mentioned action, and on the other hand, if the content of each exceeds 10%, the strength of the brazed portion will be reduced, so that the content of each of the content is 0.5-0.5%.
It was set to 10%, preferably 5 to 7%.

【0007】(b) Cr Cr成分には、ろう材の硬さを向上させる作用がある
が、その含有量が5%未満では所望の硬さ向上効果が得
られず、一方その含有量が20%を越えると圧延性が急
激に低下するようになることから、その含有量を5〜2
0%、望ましくは10〜15%と定めた。
(B) Cr The Cr component has the effect of improving the hardness of the brazing material, but if the content of Cr is less than 5%, the desired hardness-improving effect cannot be obtained, while the content of Cr is 20. %, The rollability will rapidly decrease, so the content should be 5 to 2
It was set to 0%, preferably 10 to 15%.

【0008】(c) P,B、およびSi これらの成分には、ろう材の融点を下げ、もって流動性
を増して、より少量でのろう材使用でろう付け接合を可
能ならしめる作用があるので必要に応じて含有される
が、その含有量が2%未満では前記作用に所望の効果が
得られず、一方その含有量が1%を越えると、ろう付け
部の強度が低下するようになることから、その含有量を
2〜10%、望ましくは3〜8%と定めた。
(C) P, B, and Si These components have the effect of lowering the melting point of the brazing material, thereby increasing the fluidity, and enabling brazing joining with a smaller amount of brazing material. Therefore, if the content is less than 2%, the desired effect on the above action cannot be obtained. On the other hand, if the content exceeds 1%, the strength of the brazed part decreases. Therefore, the content is defined as 2 to 10%, preferably 3 to 8%.

【0009】[0009]

【発明の実施の形態】原料粉末として、平均粒径:5μ
mおよび純度:99.95%の六方晶窒化ほう素粉末を
用い、これを1ton /cm2 の圧力で圧粉体にプレス成形
し、この圧粉体を通常のベルト型超高圧焼結装置に装入
し、圧力:7GPa、温度:2200℃、保持時間:3
0分の条件で焼結して直径:10mmφ×厚さ:2mmの寸
法をもったCBN焼結材料素材を形成し、これを超音波
カッタにて厚さ:1.9mmにして一辺長さが5mmの正三
角形に加工することにより切刃片を製造した。
BEST MODE FOR CARRYING OUT THE INVENTION As raw material powder, average particle diameter: 5 μ
m and purity: 99.95% hexagonal boron nitride powder was used, and this was pressed into a green compact at a pressure of 1 ton / cm 2 , and this green compact was applied to an ordinary belt type ultra-high pressure sintering device. Charge, pressure: 7 GPa, temperature: 2200 ° C, holding time: 3
Sintering was performed for 0 minutes to form a CBN sintered material having a diameter of 10 mmφ and a thickness of 2 mm, which was then cut with an ultrasonic cutter to a thickness of 1.9 mm and a side length. A cutting edge piece was manufactured by processing into a 5 mm regular triangle.

【0010】また、原料粉末として、平均粒径:3μm
のWC粉末および同4μmのCo粉末を用い、これら原
料粉末を所定の割合に配合し、ボールミルで72時間湿
式混合し、乾燥した後、1ton /cm2 の圧力で圧粉体に
プレス成形し、この圧粉体を、1×10-3torrの真空
中、1400℃に1時間保持の条件で焼結してTNGA
3 32(厚さ:3.18mmにして、一辺長さが16mmの
正三角形)の形状をおよびWC−8%Coの組成をもっ
たWC基超硬合金素材を形成し、これの一角を占める切
刃部に深さ:1.4mmにして一辺長さが5mmの正三角形
ざぐりを形成することによりチップ本体を製造した。
As the raw material powder, the average particle diameter is 3 μm.
WC powder and Co powder of 4 μm were mixed in a predetermined ratio, wet mixed in a ball mill for 72 hours, dried, and then pressed into a green compact at a pressure of 1 ton / cm 2 , This green compact was sintered in a vacuum of 1 × 10 -3 torr and kept at 1400 ° C. for 1 hour to obtain TNGA.
3 32 (thickness: In 3.18 mm, one side length 16mm equilateral triangle) to form a WC-based cemented carbide material having a shape and composition of WC-8% Co, and occupy this one corner A chip body was manufactured by forming an equilateral triangular counterbore having a depth of 1.4 mm and a side length of 5 mm in the cutting edge portion.

【0011】さらに、通常の溶解法を用いて表1,2に
示される成分組成をもったNi合金溶湯およびAg合金
溶湯を調製し、いすれも通常の条件で、インゴットに鋳
造し、熱間圧延と冷間圧延を施して厚さ:0.35mmの
本発明複合切削チップ用Ni合金ろう材(以下、本発明
ろう材という)a〜w、および従来複合切削チップ用A
g合金ろう材(以下、従来ろう材という)をそれぞれ製
造した。
Furthermore, a Ni alloy molten metal and an Ag alloy molten metal having the component compositions shown in Tables 1 and 2 were prepared by a usual melting method, and each was cast into an ingot under normal conditions and hot-melted. Ni alloy brazing filler metal for composite cutting tip of the present invention (hereinafter referred to as brazing filler metal of the present invention) a to w having a thickness of 0.35 mm after being subjected to rolling and cold rolling, and conventional composite cutting tip A
A g-alloy brazing material (hereinafter referred to as a conventional brazing material) was manufactured.

【0012】ついで、上記切刃片を、上記チップ本体
に、本発明ろう材a〜wを介してそれぞれセットし、ホ
ットプレスを用いて1Kg/cm2 の圧力で加圧し、1×1
-3torrの真空中、1250−1350℃に5分間保持
の条件でろう付け接合することにより本発明複合切削チ
ップ(以下、本発明チップという)1〜23をそれぞれ
製造した。
Next, the cutting blade pieces are set in the chip body via the brazing filler metals a to w of the present invention, and pressed at a pressure of 1 kg / cm 2 using a hot press to 1 × 1.
The composite cutting tips of the present invention (hereinafter, referred to as the present chips) 1 to 23 were manufactured by brazing and joining at a temperature of 1250-1350 ° C. for 5 minutes in a vacuum of 0 −3 torr.

【0013】また、比較の目的で、原料粉末として、上
記の六方晶窒化ほう素粉末、並びに上記のWC粉末とC
o粉末の混合粉末(Co粉末の配合割合は8%)を用
い、これから六方晶窒化ほう素粉末層の厚さが、2mmに
して前記混合粉末層の厚さが、1.5mmの複合圧粉体を
1ton /cm2 の圧力でプレス成形し、この複合圧粉体
を、上記のCBN焼結材料製切刃片の製造条件と同じ条
件で焼結し、加工することにより従来複合切削チップ用
複合体切刃片を製造し、この複合体切刃片を、上記の従
来ろう材を用い、同一のろう付け条件で上記WC基超硬
合金製チップ本体の切刃部にろう付けすることにより従
来複合切削チップ(以下、従来チップという)を製造し
た。
Further, for comparison purposes, the above hexagonal boron nitride powder, and the above WC powder and C are used as raw material powders.
o Composite powder with a mixed powder of O powder (Co powder content 8%) and a hexagonal boron nitride powder layer having a thickness of 2 mm and a mixed powder layer having a thickness of 1.5 mm. The body was press-molded at a pressure of 1 ton / cm 2 , and the composite green compact was sintered and processed under the same conditions as those for the cutting edge piece made of the CBN sintered material described above. By manufacturing a composite cutting blade piece and brazing this composite cutting blade piece to the cutting edge portion of the WC-based cemented carbide chip body using the above conventional brazing material under the same brazing conditions. A conventional composite cutting tip (hereinafter referred to as a conventional tip) was manufactured.

【0014】つぎに、この結果得られた各種のチップに
ついて、 被削材:Co−28%Cr−4%W−1%Cの組成を有
するCo基合金の丸棒、 切削速度:300m/min.、 切込み:0.25mm、 送り:0.05mm/rev.、 切削時間:5分、 の条件で乾式連続高速切削試験を行ない、切刃の逃げ面
摩耗幅を測定した。これらの測定結果を表3に示した。
Next, with respect to the various chips obtained as a result, a work material: a round bar of a Co-based alloy having a composition of Co-28% Cr-4% W-1% C, cutting speed: 300 m / min ., Depth of cut: 0.25 mm, feed: 0.05 mm / rev., Cutting time: 5 minutes, and a dry continuous high-speed cutting test was performed to measure the flank wear width of the cutting edge. Table 3 shows the results of these measurements.

【0015】[0015]

【表1】 [Table 1]

【0016】[0016]

【表2】 [Table 2]

【0017】[0017]

【表3】 [Table 3]

【0018】[0018]

【発明の効果】表3に示される結果から、本発明チップ
1〜24は、いずれも切刃片のチップ本体に対する接合
強度がきわめて高いので、難削材であるCo基合金の高
速切削でも切刃片に剥離の発生なく、すぐれた切削性能
を発揮するのに対して、従来チップは、切削開始後比較
的短時間で切刃片のCBN焼結材料層とWC基超硬合金
層間に剥離が発生し、使用寿命に至ることが明らかであ
る。上述のように、この発明の複合切削チップは、切刃
片のチップ本体に対する接合強度がきわめて高いので、
高速切削に用いても切刃片が剥離することがなく、した
がって切削加工の高速化および省力化に十分満足に対応
することができるものである。
From the results shown in Table 3, since all of the chips 1 to 24 of the present invention have extremely high bonding strength of the cutting blade piece to the chip body, they can be cut even at high speed cutting of a Co-based alloy which is a difficult-to-cut material. The cutting edge exhibits excellent cutting performance without peeling, whereas the conventional tip peels between the CBN sintered material layer of the cutting edge and the WC-based cemented carbide layer in a relatively short time after the start of cutting. Occurs, and it is clear that the service life is reached. As described above, the composite cutting tip of the present invention has extremely high bonding strength to the tip body of the cutting blade piece,
Even when used for high-speed cutting, the cutting edge piece does not peel off, and therefore, it is possible to satisfactorily deal with high-speed cutting and labor saving.

【図面の簡単な説明】[Brief description of the drawings]

【図1】従来複合切削チップを示す概略斜視図である。FIG. 1 is a schematic perspective view showing a conventional composite cutting tip.

【符号の説明】[Explanation of symbols]

1 チップ本体 2 Ag合金ろう材 3 切刃片 3a CBN焼結材料層 3b WC基超硬合金層 1 Chip Body 2 Ag Alloy Brazing Material 3 Cutting Edge Piece 3a CBN Sintered Material Layer 3b WC Based Cemented Carbide Layer

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 FI 技術表示箇所 C04B 35/583 C04B 37/02 B 37/02 35/58 103Y ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification code Internal reference number FI Technical display area C04B 35/583 C04B 37/02 B 37/02 35/58 103Y

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 立方晶窒化ほう素焼結材料製切刃片を、
重量%で、 Ti:0.5〜10%および/またはZr:0.5〜1
0%、 Cr:5〜20%、を含有し、残りがNiと不可避不純
物からなる組成を有するNi合金ろう材を介して、炭化
タングステン基超硬合金製チップ本体の切刃部に直接ろ
う付けしてなる切刃片がすぐれた接合強度を有する複合
切削チップ。
1. A cutting edge piece made of cubic boron nitride sintered material,
%, Ti: 0.5-10% and / or Zr: 0.5-1
0%, Cr: 5 to 20%, and the rest is directly brazed to the cutting edge portion of the tungsten carbide based cemented carbide chip body through a Ni alloy brazing material having a composition of Ni and inevitable impurities. Composite cutting tip with excellent joining strength.
【請求項2】 立方晶窒化ほう素焼結材料製切刃片を、
重量%で、 Ti:0.5〜10%および/またはZr:0.5〜1
0%、 Cr:5〜20%、を含有し、さらに、 P,B、およびSiのうちの1種または2種以上:2〜
10%、を含有し、残りがNiと不可避不純物からなる
組成を有するNi合金ろう材を介して、炭化タングステ
ン基超硬合金製チップ本体の切刃部に直接ろう付けして
なる切刃片がすぐれた接合強度を有する複合切削チッ
プ。
2. A cutting edge piece made of a cubic boron nitride sintered material,
%, Ti: 0.5-10% and / or Zr: 0.5-1
0%, Cr: 5 to 20%, and one or more of P, B, and Si: 2 to
A cutting edge piece obtained by directly brazing to a cutting edge portion of a tungsten carbide-based cemented carbide chip body through a Ni alloy brazing material containing 10% of Ni and the balance of Ni and inevitable impurities. A composite cutting tip with excellent joint strength.
JP7289275A 1995-10-11 1995-10-11 Composite cutting tip whose cutting edge piece has excellent joining strength Withdrawn JPH09108913A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP7289275A JPH09108913A (en) 1995-10-11 1995-10-11 Composite cutting tip whose cutting edge piece has excellent joining strength

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP7289275A JPH09108913A (en) 1995-10-11 1995-10-11 Composite cutting tip whose cutting edge piece has excellent joining strength

Publications (1)

Publication Number Publication Date
JPH09108913A true JPH09108913A (en) 1997-04-28

Family

ID=17741063

Family Applications (1)

Application Number Title Priority Date Filing Date
JP7289275A Withdrawn JPH09108913A (en) 1995-10-11 1995-10-11 Composite cutting tip whose cutting edge piece has excellent joining strength

Country Status (1)

Country Link
JP (1) JPH09108913A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007034646A1 (en) * 2005-09-22 2007-03-29 Nippon Steel Materials Co., Ltd. Dresser for polishing cloth
WO2015160523A3 (en) * 2014-04-14 2015-12-30 Siemens Energy, Inc. Structural braze for superalloy material
JP2017052019A (en) * 2015-09-07 2017-03-16 新日鉄住金マテリアルズ株式会社 Dresser for abrasive cloth

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007034646A1 (en) * 2005-09-22 2007-03-29 Nippon Steel Materials Co., Ltd. Dresser for polishing cloth
US8096858B2 (en) 2005-09-22 2012-01-17 Nippon Steel Materials Co., Ltd. Polishing pad conditioner
WO2015160523A3 (en) * 2014-04-14 2015-12-30 Siemens Energy, Inc. Structural braze for superalloy material
CN106170368A (en) * 2014-04-14 2016-11-30 西门子能源有限公司 Structure soldering for superalloy materials
CN106170368B (en) * 2014-04-14 2019-01-04 西门子能源有限公司 Structure for superalloy materials is brazed
US11344977B2 (en) 2014-04-14 2022-05-31 Siemens Energy, Inc. Structural braze for superalloy material
JP2017052019A (en) * 2015-09-07 2017-03-16 新日鉄住金マテリアルズ株式会社 Dresser for abrasive cloth

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