JPH0862144A - Surface inspection method for molding - Google Patents

Surface inspection method for molding

Info

Publication number
JPH0862144A
JPH0862144A JP22563294A JP22563294A JPH0862144A JP H0862144 A JPH0862144 A JP H0862144A JP 22563294 A JP22563294 A JP 22563294A JP 22563294 A JP22563294 A JP 22563294A JP H0862144 A JPH0862144 A JP H0862144A
Authority
JP
Japan
Prior art keywords
molded product
molding
housing
ultraviolet rays
defect
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP22563294A
Other languages
Japanese (ja)
Inventor
Yasuki Orito
泰樹 折戸
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tokai Rika Co Ltd
Original Assignee
Tokai Rika Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tokai Rika Co Ltd filed Critical Tokai Rika Co Ltd
Priority to JP22563294A priority Critical patent/JPH0862144A/en
Publication of JPH0862144A publication Critical patent/JPH0862144A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE: To obtain a surface inspection method for molding in which the surface of a molding can be inspected prior to painting. CONSTITUTION: A switch 22 is turned on to actuate an ultraviolet light 14 and to irradiate an objective molding 24 with ultraviolet rays 28. An inspector then observes the molding 24 placed in a housing 12 through a window 18 made in the top face of the housing 12. In this regard, a defective part on the surface of the molding 24 looms in white but the ground color appears as it is at other parts.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、合成樹脂から成る成形
品の表面における不具合、特に合成樹脂の熱分解による
劣化等の有無を、成形品の表面に塗装を施す前に検査す
る成形品表面検査方法に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a molded product surface for inspecting the surface of a molded product made of a synthetic resin for defects, particularly deterioration of the synthetic resin due to thermal decomposition before coating the surface of the molded product. It relates to the inspection method.

【0002】[0002]

【従来の技術】従来、射出成形によって合成樹脂の成形
品を作り、その成形品の表面に塗装を施した後に、温水
浸漬を所定日数行う耐水試験を行った場合に、成形品の
表面の或る部分にブリスタ(塗膜膨れ;塗膜が浮き上が
ったり、剥がれたりする現象)を生じることがあった。
2. Description of the Related Art Conventionally, when a synthetic resin molded article is produced by injection molding, and the surface of the molded article is coated, a water resistance test in which it is immersed in warm water for a predetermined number of days is performed. Blister (coating swelling; a phenomenon in which the coating film floats or peels off) may occur in the part where the coating film is formed.

【0003】このようなブリスタの発生は成形品の表面
の不具合に起因するものであり、その不具合としては、
特に、合成樹脂の熱分解による劣化を挙げることができ
る。
The occurrence of such blister is caused by a defect on the surface of the molded product.
In particular, deterioration due to thermal decomposition of the synthetic resin can be mentioned.

【0004】例えば、ホットランナ金型を用いて射出成
形により合成樹脂の成形品を作る場合に、ホットランナ
金型のホットランナ部分の温度が適正温度より高すぎる
と、樹脂がその部分を通過した時に熱分解を起こし、そ
の熱分解を起こした樹脂が成形品の表面に現われた場合
に、上記不具合が生じることになる。例えば、上記合成
樹脂が芳香族ナイロンである場合、その軟化温度は約2
70℃〜280℃であるが、加熱温度が約300℃以上
になると、芳香属ナイロンは熱分解を起こしてしまう。
For example, when a molded product of synthetic resin is produced by injection molding using a hot runner die, if the temperature of the hot runner portion of the hot runner die is higher than the appropriate temperature, the resin passes through that portion. At times, thermal decomposition occurs, and when the thermally decomposed resin appears on the surface of the molded article, the above-mentioned problems occur. For example, when the synthetic resin is aromatic nylon, its softening temperature is about 2
Although it is 70 ° C. to 280 ° C., when the heating temperature is about 300 ° C. or higher, the aromatic nylon causes thermal decomposition.

【0005】また、ホットランナ部分の温度が適正温度
である場合でも、射出成形機の動作停止などによりホッ
トランナ部分に樹脂が滞留し、その滞留時間が長くなっ
た場合に、その滞留した樹脂が加熱されて熱分解を起こ
し、その後、射出成形機の動作が開始され、その熱分解
を起こした樹脂が成形品の表面に現われた場合にも、上
記不具合が生じることになる。
Even when the temperature of the hot runner portion is an appropriate temperature, when the resin stays in the hot runner portion due to the operation stop of the injection molding machine or the like and the staying time becomes long, the stayed resin is The above problem also occurs when the resin is heated to cause thermal decomposition and then the operation of the injection molding machine is started and the thermally decomposed resin appears on the surface of the molded product.

【0006】このような成形品の表面の不具合、すなわ
ち、合成樹脂の熱分解による劣化は、成形品の表面の形
状変化や色・艶の変化として現われるものではなく、合
成樹脂の結晶化度の低下や分子量の低下となって現われ
るものであるため、人間が視覚や触覚によって容易に発
見できるものでない。
Such a defect on the surface of the molded product, that is, deterioration due to thermal decomposition of the synthetic resin does not appear as a change in the shape of the surface of the molded product or a change in color and luster, but rather the crystallinity of the synthetic resin. Since it appears as a decrease or a decrease in molecular weight, it cannot be easily detected by human eyes or touch.

【0007】[0007]

【発明が解決しようとする課題】上記したように、成形
品の表面に不具合があると、その表面に塗装を施した場
合にその不具合部分で塗装の強度が低下し、その表面が
長期に水などにさらされた場合に、その表面に上記した
ブリスタを生じる可能性がある。
As described above, if the surface of the molded product is defective, the strength of the coating will be reduced at the defective portion when the surface is coated, and the surface will not be exposed to water for a long time. When exposed to the like, the above-mentioned blisters may occur on the surface.

【0008】しかしながら、上述したように、成形品の
表面の不具合、すなわち、合成樹脂の熱分解による劣化
は、人間が視覚や触覚によって容易に発見できるもので
ないため、従来においては、成形品の表面に塗装を施し
た後、耐水試験を行って、その成形品の表面にブリスタ
が生じたどうかを確認するまでは、その表面に不具合が
あるかどうかを検知することができなかった。
However, as described above, the surface defect of the molded product, that is, the deterioration due to the thermal decomposition of the synthetic resin, cannot be easily detected by human eyes or tactile sensation. It was not possible to detect whether or not there was a defect on the surface of the molded product until a blister was confirmed on the surface of the molded product after the coating was applied to the product and a water resistance test was performed.

【0009】すなわち、従来においては、成形品の表面
に不具合があったとしても、それを検知できるのは、成
形品の表面に塗装を施して耐水試験を行った後、つま
り、成形を行ってから少なくとも所定日数を経た後であ
るため、それまでの間は、その不具合に対して、それを
解消する対策を施すことができないという問題があっ
た。
That is, conventionally, even if there is a defect on the surface of a molded product, it can be detected only after coating the surface of the molded product and conducting a water resistance test, that is, after molding. Since at least a predetermined number of days have passed since then, there was a problem that until that time, it was not possible to take measures to solve the defect.

【0010】そこで、本発明の目的は、上記した従来技
術の問題点を解決し、成形品の表面に塗装を施す前に、
その成形品の表面の不具合の有無を検査することのでき
る成形品表面検査方法を提供することにある。
Therefore, an object of the present invention is to solve the above-mentioned problems of the prior art and to apply the coating to the surface of the molded product,
It is an object of the present invention to provide a method for inspecting the surface of a molded product, which is capable of inspecting the surface of the molded product for defects.

【0011】[0011]

【課題を解決するための手段及びその作用】上記した目
的を達成するために、請求項1に記載の発明は、合成樹
脂から成る成形品の表面における不具合の有無を検査す
る成形品表面検査方法において、塗装を施す前の前記成
形品の表面に紫外線を照射し、照射した際の前記表面の
各部の色の違いに基づいて、前記表面の不具合の有無を
検査することを特徴としている。
In order to achieve the above-mentioned object, the invention according to claim 1 is a method for inspecting the surface of a molded article for inspecting the surface of the molded article made of synthetic resin for defects. In the above, the surface of the molded article before coating is irradiated with ultraviolet rays, and the presence or absence of defects on the surface is inspected based on the difference in color of each part of the surface at the time of irradiation.

【0012】すなわち、成形品の表面に不具合が生じて
いると、紫外線を照射した際に、その不具合を生じてい
る部分が例えば白く浮き出て見え、不具合を生じていな
い部分は地色のままに見える。従って、人間の視覚によ
って容易に、成形品の表面に不具合があるかどうかを検
査することができる。
That is, if a defect occurs on the surface of the molded product, when ultraviolet rays are irradiated, the defective part appears, for example, as white, and the non-defective part remains the ground color. appear. Therefore, it is possible to easily inspect whether or not there is a defect on the surface of the molded product by human eyes.

【0013】なお、請求項1に記載の発明において、紫
外線とは約1nm〜約400nmの波長範囲の電磁波を
いい、色とは色相,明度,彩度の属性によって表わされ
るものをいう。また、成形品を構成する上記合成樹脂と
しては、例えば、熱可塑性樹脂であるポリアミド(ナイ
ロン),ポリエチレン,ポリプロピレン,塩化ビニル樹
脂,ポリスチレン,ABS,メタクリル樹脂,ポリカー
ボネート,ポリアセタール,熱可塑性ポリエステル,繊
維素系プラスチック,フェニレンオキサイド樹脂,フッ
素樹脂などが考えられる。
In the invention described in claim 1, ultraviolet rays mean electromagnetic waves in a wavelength range of about 1 nm to about 400 nm, and colors mean those expressed by attributes of hue, brightness and saturation. Examples of the above-mentioned synthetic resin constituting the molded product include thermoplastic resins such as polyamide (nylon), polyethylene, polypropylene, vinyl chloride resin, polystyrene, ABS, methacrylic resin, polycarbonate, polyacetal, thermoplastic polyester, and fibrin. Based plastics, phenylene oxide resin, fluororesin, etc. are considered.

【0014】[0014]

【実施例】以下、本発明の実施例について図面を用いて
説明する。図1は本発明の一実施例としての成形品表面
検査方法によって成形品の表面の不具合の有無を検査す
る際に用いる成形品表面検査装置の構成を概略的に示し
た断面図である。
Embodiments of the present invention will be described below with reference to the drawings. FIG. 1 is a cross-sectional view schematically showing the configuration of a molded product surface inspection device used when inspecting the surface of a molded product for defects by the molded product surface inspection method as one embodiment of the present invention.

【0015】図1に示す成形品表面検査装置10は、主
として、筐体12と、その筐体12の上面に取り付けら
れた紫外線ライト14及び紫外線フィルタ16と、で構
成されている。
The molded product surface inspection apparatus 10 shown in FIG. 1 mainly comprises a housing 12, and an ultraviolet light 14 and an ultraviolet filter 16 mounted on the upper surface of the housing 12.

【0016】紫外線ライト14にはスイッチ22を介し
て交流電源20が接続されており、スイッチ22がオン
されることにより、紫外線ライト14は発光して、筐体
12の内部に向かって、例えば、約366nmの波長の
紫外線28を照射する。
An alternating current power source 20 is connected to the ultraviolet light 14 via a switch 22, and when the switch 22 is turned on, the ultraviolet light 14 emits light, toward the inside of the housing 12, for example, Ultraviolet rays 28 having a wavelength of about 366 nm are irradiated.

【0017】また、紫外線フィルタ16は検査者の眼2
6を紫外線から保護するためものであり、筐体12の内
部で反射した紫外線は遮断するが、筐体12の内部から
の可視光は通過させる。
Further, the ultraviolet filter 16 is provided in the eye 2 of the inspector.
The purpose is to protect 6 from ultraviolet rays, and the ultraviolet rays reflected inside the housing 12 are blocked, but visible light from the inside of the housing 12 passes through.

【0018】また、筐体12の側面には、矢印A方向に
回動可能な扉12aが設けられており、検査対象である
成形品24の筐体12の内部への出し入れが可能となっ
ている。
Further, a door 12a rotatable in the direction of arrow A is provided on the side surface of the housing 12, so that the molded product 24 to be inspected can be taken in and out of the housing 12. There is.

【0019】では、本実施例の成形品表面検査方法につ
いて図1を参照しながら説明する。まず、検査対象とな
る成形品24を用意する。この成形品24としては、ホ
ットランナ金型を用いて射出成形により作られた合成樹
脂の成形品であって、塗装を施す前の成形品を用意す
る。
Now, the method for inspecting the surface of the molded article of this embodiment will be described with reference to FIG. First, the molded product 24 to be inspected is prepared. As the molded product 24, a synthetic resin molded product produced by injection molding using a hot runner mold, which is not yet coated, is prepared.

【0020】次に、検査者が筐体12の扉12aを開け
て、用意した成形品24を筐体12の底面の所定の位置
にセットする。その後、スイッチ22をオンして、紫外
線ライト14を発光させ、検査対象である成形品24に
紫外線28を照射し、検査者が筐体12の上面にあるの
ぞき窓18より筐体12の内部をのぞき、成形品24を
観察する。
Next, the inspector opens the door 12a of the housing 12 and sets the prepared molded product 24 at a predetermined position on the bottom surface of the housing 12. Thereafter, the switch 22 is turned on to cause the ultraviolet light 14 to emit light, and the molded product 24 to be inspected is irradiated with ultraviolet rays 28, so that the inspector can view the inside of the housing 12 through the observation window 18 on the upper surface of the housing 12. Peep and observe the molded product 24.

【0021】観察が終了したら、スイッチ22をオフし
て、紫外線ライト14の発光を停止させ、検査者が筐体
12の扉12aを開けて、筐体12の内部にある成形品
24を取り出す。
When the observation is completed, the switch 22 is turned off to stop the emission of the ultraviolet light 14, the inspector opens the door 12a of the housing 12, and the molded product 24 inside the housing 12 is taken out.

【0022】図2は通常状態で観察される成形品24の
表面の様子と紫外線照射中に観察される成形品24の表
面の様子を示す斜視図である。
FIG. 2 is a perspective view showing a state of the surface of the molded product 24 observed in a normal state and a state of the surface of the molded product 24 observed during irradiation of ultraviolet rays.

【0023】図2(a)は通常状態(すなわち、可視光
中)で観察される成形品24の表面の様子を示してい
る。上記したように、成形品24の表面に例え不具合、
すなわち、熱分解による劣化があったとしても、通常の
状態では、検査者の眼26によっては検知することとが
できないため、図2(a)に示すように、成形品24の
表面の形状,色,艶は何れも均一に見える。
FIG. 2A shows the appearance of the surface of the molded product 24 observed in a normal state (that is, in visible light). As described above, for example, a defect on the surface of the molded product 24,
That is, even if there is deterioration due to thermal decomposition, it cannot be detected by the inspector's eye 26 in a normal state, so as shown in FIG. Both the color and luster look uniform.

【0024】図2(b)は紫外線照射中に観察される成
形品24の表面の様子を示している。成形品24の表面
に紫外線28を照射し、その表面を紫外線フィルタ16
を介して観察すると、図2(b)に示すように、その表
面の色が白く浮き出る部分Wと地色の部分Nとに分かれ
て見える。このうち、白く浮き出る部分Wは不具合、す
なわち、熱分解による劣化が生じている部分であり、そ
れ以外の地色の部分Nは不具合の生じていない部分であ
る。なお、図2(b)では白く浮き出る部分Wと地色の
部分Nとの境界は明確に描いてあるが、実際にはその境
界部分で色が徐々に変化している場合もある。
FIG. 2B shows the appearance of the surface of the molded product 24 observed during the irradiation of ultraviolet rays. The surface of the molded product 24 is irradiated with ultraviolet rays 28, and the surface is irradiated with the ultraviolet filter 16
2B, the surface color is divided into a white portion W and a ground color portion N, as shown in FIG. 2B. Of these, the white portion W is a defect, that is, a portion that is deteriorated by thermal decomposition, and the other ground-colored portion N is a portion that is not defective. In FIG. 2B, the boundary between the white portion W and the ground color portion N is clearly drawn, but in reality, the color may gradually change at the boundary portion.

【0025】ところで、何故、このように熱分解による
劣化の生じている部分が白く浮き出るように見えるかと
いうと、それは、その部分の樹脂の光学的な性質が熱分
解によって変化し、蛍光反応を示すようになるからであ
ると考えられる。すなわち、熱分解による劣化が生じて
いる部分に紫外線28が照射されると、その部分で蛍光
が発せられる。そして、その蛍光は可視光であるため紫
外線フィルタ18を透過して検査者の眼26に到達し、
その結果、検査者には白く浮き出たように見えるのであ
る。
By the way, the reason why the portion where the deterioration due to the thermal decomposition appears to appear white is that the optical property of the resin in the portion changes due to the thermal decomposition and the fluorescent reaction is caused. It is thought that this is because it becomes as shown. That is, when the ultraviolet ray 28 is applied to a portion where deterioration due to thermal decomposition occurs, the portion emits fluorescence. Since the fluorescence is visible light, it passes through the ultraviolet filter 18 and reaches the inspector's eye 26.
As a result, it looks white to the inspector.

【0026】また、実際の試行結果を見ても、その成形
品24の表面に塗装を施し耐水試験を行った場合に、そ
の成形品24の表面においてブリスタの生じる部分は、
上記した白く浮き出る部分Wと確かに一致している。
Also, looking at the actual trial results, when the surface of the molded product 24 is coated and subjected to a water resistance test, the portion where blisters occur on the surface of the molded product 24 is
It surely coincides with the above-mentioned part W that appears white.

【0027】図2(c)は紫外線照射中に観察される他
の成形品24’の表面の様子を示している。この成形品
24’の場合は、その表面に不具合を生じている部分が
ないため、その表面に紫外線28を照射し、その表面を
紫外線フィルタ16を介して観察しても、図2(c)に
示すように、その表面の色は地色の部分Nのみで、白く
浮き出る部分Wは見えない。
FIG. 2C shows the appearance of the surface of another molded article 24 'observed during the irradiation of ultraviolet rays. In the case of this molded product 24 ′, since there is no defective portion on the surface thereof, even if the surface is irradiated with ultraviolet rays 28 and the surface is observed through the ultraviolet filter 16, it is possible to obtain the result shown in FIG. As shown in, the surface color is only the background color portion N, and the white portion W is not visible.

【0028】このように、本実施例の成形品表面検査方
法によれば、成形品の表面に塗装を施す前に、その成形
品の表面の不具合の有無を検査することができる。従っ
て、例えば、成形を行った直後でも、図2(b)に示し
たように成形品の表面に不具合の生じていることが検知
された場合には、その不具合を解消するような対策、例
えば、ホットランナ金型のホットランナ部分の温度を適
正温度になるように制御するなどの対策を直ちに施すこ
とができる。
As described above, according to the molded product surface inspection method of this embodiment, it is possible to inspect the surface of the molded product for defects before the surface of the molded product is coated. Therefore, for example, if it is detected that the surface of the molded product has a defect as shown in FIG. 2B even immediately after the molding, a measure for eliminating the defect, for example, It is possible to immediately take measures such as controlling the temperature of the hot runner portion of the hot runner mold so as to be an appropriate temperature.

【0029】[0029]

【発明の効果】以上説明したように、請求項1に記載の
発明によれば、成形品の表面に塗装を施す前に、その成
形品の表面の不具合の有無を検査することのできるの
で、従来のように成形を行ってから10日間も待つ必要
はなく、成形品の表面に不具合があった場合の対策を成
形を行った直後でも施すことができる。
As described above, according to the first aspect of the present invention, it is possible to inspect the surface of the molded product for defects before the surface of the molded product is coated. It is not necessary to wait for 10 days after molding as in the conventional case, and measures can be taken even when the surface of the molded product is defective immediately after molding.

【0030】また、請求項1に記載の発明によれば、表
面の各部の色の違いに基づき、人間の視覚によって不具
合の有無を検査しているため、容易に検査することがで
きる。さらにまた、検査を行うには紫外線を照射するだ
けでよいため、請求項1に記載の発明を実施する際に用
いる装置としては簡単な構成で済む。
According to the first aspect of the invention, the presence or absence of a defect is visually inspected by human eyes based on the difference in color of each portion of the surface, so that the inspection can be easily performed. Furthermore, since it suffices to irradiate ultraviolet rays to perform the inspection, the device used when carrying out the invention described in claim 1 has a simple structure.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の一実施例としての成形品表面検査方法
によって成形品の表面の不具合の有無を検査する際に用
いる成形品表面検査装置の構成を概略的に示した断面図
である。
FIG. 1 is a cross-sectional view schematically showing a configuration of a molded product surface inspection device used for inspecting the surface of a molded product for defects by a molded product surface inspection method as one embodiment of the present invention.

【図2】通常状態で観察される成形品24の表面の様子
と紫外線照射中に観察される成形品24の表面の様子を
示す斜視図である。
FIG. 2 is a perspective view showing a state of a surface of a molded article 24 observed in a normal state and a state of a surface of a molded article 24 observed during irradiation of ultraviolet rays.

【符号の説明】[Explanation of symbols]

10…成形品表面検査装置 12…筐体 12a…扉 14…紫外線ライト 16…紫外線フィルタ 18…窓 20…交流電源 22…スイッチ 24,24’…成形品 26…眼 28…紫外線 10 ... Molded product surface inspection device 12 ... Housing 12a ... Door 14 ... UV light 16 ... UV filter 18 ... Window 20 ... AC power supply 22 ... Switch 24, 24 '... Molded product 26 ... Eye 28 ... UV light

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 合成樹脂から成る成形品の表面における
不具合の有無を検査する成形品表面検査方法であって、 塗装を施す前の前記成形品の表面に紫外線を照射し、照
射した際の前記表面の各部の色の違いに基づいて、前記
表面の不具合の有無を検査することを特徴とする成形品
表面検査方法。
1. A method of inspecting a surface of a molded article made of a synthetic resin for the presence or absence of defects, the method comprising: irradiating the surface of the molded article before coating with ultraviolet rays, A method for inspecting a surface of a molded article, which comprises inspecting whether or not there is a defect on the surface based on a difference in color of each part of the surface.
JP22563294A 1994-08-25 1994-08-25 Surface inspection method for molding Pending JPH0862144A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP22563294A JPH0862144A (en) 1994-08-25 1994-08-25 Surface inspection method for molding

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP22563294A JPH0862144A (en) 1994-08-25 1994-08-25 Surface inspection method for molding

Publications (1)

Publication Number Publication Date
JPH0862144A true JPH0862144A (en) 1996-03-08

Family

ID=16832354

Family Applications (1)

Application Number Title Priority Date Filing Date
JP22563294A Pending JPH0862144A (en) 1994-08-25 1994-08-25 Surface inspection method for molding

Country Status (1)

Country Link
JP (1) JPH0862144A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006317272A (en) * 2005-05-12 2006-11-24 Toyo Seikan Kaisha Ltd Inspection device of degree of crystallization and inspection method of degree of crystallization
WO2017018111A1 (en) * 2015-07-29 2017-02-02 株式会社イシダ Inspection apparatus
JP2020176854A (en) * 2019-04-16 2020-10-29 コニカミノルタ株式会社 Resin deterioration degree evaluation test method and resin recycle system using the same

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006317272A (en) * 2005-05-12 2006-11-24 Toyo Seikan Kaisha Ltd Inspection device of degree of crystallization and inspection method of degree of crystallization
WO2017018111A1 (en) * 2015-07-29 2017-02-02 株式会社イシダ Inspection apparatus
JPWO2017018111A1 (en) * 2015-07-29 2018-05-17 株式会社イシダ Inspection device
JP2020176854A (en) * 2019-04-16 2020-10-29 コニカミノルタ株式会社 Resin deterioration degree evaluation test method and resin recycle system using the same

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