JPH0861B2 - Defoaming agent for beverage and beverage using the same - Google Patents

Defoaming agent for beverage and beverage using the same

Info

Publication number
JPH0861B2
JPH0861B2 JP3088671A JP8867191A JPH0861B2 JP H0861 B2 JPH0861 B2 JP H0861B2 JP 3088671 A JP3088671 A JP 3088671A JP 8867191 A JP8867191 A JP 8867191A JP H0861 B2 JPH0861 B2 JP H0861B2
Authority
JP
Japan
Prior art keywords
beverage
fatty acid
positive pressure
cans
acid ester
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP3088671A
Other languages
Japanese (ja)
Other versions
JPH04320654A (en
Inventor
晋 深山
伸二 加藤
信行 諏訪
彰夫 西村
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical Corp
Mitsubishi Materials Corp
Original Assignee
Mitsubishi Chemical Corp
Mitsubishi Materials Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Chemical Corp, Mitsubishi Materials Corp filed Critical Mitsubishi Chemical Corp
Priority to JP3088671A priority Critical patent/JPH0861B2/en
Priority to FR9204715A priority patent/FR2675346B1/en
Priority to US07/869,952 priority patent/US5378484A/en
Priority to KR1019920006509A priority patent/KR100196254B1/en
Priority to GB9208528A priority patent/GB2254771B/en
Priority to TW081103311A priority patent/TW223009B/zh
Publication of JPH04320654A publication Critical patent/JPH04320654A/en
Publication of JPH0861B2 publication Critical patent/JPH0861B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Landscapes

  • Tea And Coffee (AREA)
  • General Preparation And Processing Of Foods (AREA)
  • Non-Alcoholic Beverages (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は特定のショ糖脂肪酸エス
テルを含有する飲料に関する。詳しくは、構成脂肪酸が
炭素数12〜22の飽和脂肪酸及び/又は不飽和脂肪酸
であって、かつ平均置換度が4〜7であるショ糖脂肪酸
エステルを含有する陽圧缶入り飲料に関する。
The present invention relates to a specific sucrose fatty acid ester.
The present invention relates to a beverage containing tell . Specifically, the present invention relates to a positive pressure canned beverage containing a sucrose fatty acid ester whose constituent fatty acids are saturated fatty acids and / or unsaturated fatty acids having 12 to 22 carbon atoms and whose average degree of substitution is 4 to 7.

【0002】[0002]

【従来の技術】従来から、密封容器入り飲料として、缶
入りの各種乳飲料や、清涼飲料が販売されている。これ
らの飲料缶詰は、自動販売機などにより、冷却または加
温されて販売されている。缶の材質は、スチールまたは
アルミ缶がほとんどであり、一部にビン、プラスチック
缶も使用されている。上下の蓋と缶胴の3部分で構成さ
れた通常のスリーピーススチール缶飲料の場合は、缶胴
の板厚が厚く、中が陰圧になっても、缶胴のへこみに対
する強度が保たれている。これに対し、缶胴と蓋の2部
分で構成されたツーピースアルミ缶、ツーピーススチー
ル缶の場合は、コーラ、ビールに見られるように、薄肉
化された缶胴のへこみを防止するため、炭酸ガスにより
缶中の内圧を高くして販売されている。この為、この様
な陽圧アルミ缶に充填されたコーラやビールは、振とう
して開缶した場合、内圧が高いため、缶内のヘッドスペ
ースに起泡した泡や、内容物が噴き出し、消費者の手や
衣服を汚すと言う事態が生ずる。また、最近では、ミル
クコーヒー、ミルク紅茶、ウーロン茶、チョコレートド
リンク、スポーツドリンクといった飲料が、液体窒素と
共に、ツーピースアルミ缶、スチール缶に充填され、内
圧が高い陽圧缶として販売されるようになってきた。
2. Description of the Related Art Conventionally, various kinds of canned milk drinks and soft drinks have been sold as drinks in sealed containers. These canned beverages are cooled or heated by an automatic vending machine or the like before being sold. Most of the cans are steel or aluminum cans, and some of them are bottles and plastic cans. In the case of a normal three-piece steel canned beverage composed of three parts, the upper and lower lids and the can body, the can body has a thick plate thickness, and even if the inside is negative pressure, the strength against the dent of the can body is maintained. There is. On the other hand, in the case of two-piece aluminum cans and two-piece steel cans, which consist of a can body and a lid, carbon dioxide gas is used to prevent dents in the thinned can body, as seen in cola and beer. It is sold by increasing the internal pressure in the can. For this reason, the cola and beer filled in such a positive pressure aluminum can have a high internal pressure when opened by shaking, so bubbles generated in the head space inside the can and the contents spout out, The situation occurs where the consumer's hands and clothes are soiled. In addition, recently, beverages such as milk coffee, milk tea, oolong tea, chocolate drink, and sports drink have been filled with liquid nitrogen into two-piece aluminum cans and steel cans, and have been sold as positive pressure cans with high internal pressure. It was

【0003】このように、陽圧缶として販売される飲料
の場合、消費者が開缶前に缶を振とうしたり、自動販売
機からの取り出し、車による運搬などの要因で振とうさ
れた場合に、缶内のヘッドペースに相当量の泡が発生
し、開缶と同時に泡が飛沫となり、開口部より周辺に飛
散して、消費者に不快感を与えるという問題がある。特
に、従来よりミルクコーヒーなどでは、内容物の分散を
はかるため、振ってから飲用するように表示してあるも
のもあって、消費者の慣習になっている場合もあり、特
に問題となる。
As described above, in the case of beverages sold as positive pressure cans, consumers have shaken the cans before opening the cans, taking them out from the vending machine, carrying them by car, etc. In this case, there is a problem that a considerable amount of bubbles are generated in the head pace in the can, and the bubbles become droplets at the same time when the can is opened, and the bubbles are scattered from the opening to the periphery, which gives a consumer discomfort. In particular, milk coffee and the like are conventionally displayed so that they may be shaken before drinking in order to disperse the contents, which may be a consumer's custom, which is a particular problem.

【0004】この様な問題を解決するためには、缶の開
口部に、新たな機能を付与して、内容物が噴き出さない
ように改良することが考えられるが、技術的困難が多
く、いまだ充分満足のいく結果は得られていない。ま
た、仮に振とうしたとしても、発泡性が低い、低発泡性
の飲料処方とすることが考えられる。しかしながら、原
料が本来起泡しやすいコーヒーや紅茶、粉乳を使用する
場合は、技術的困難がある。
In order to solve such a problem, it is considered that a new function is added to the opening of the can to improve the contents so as not to spout, but there are many technical difficulties. We have not yet obtained satisfactory results. In addition, even if shaken, it is possible to make a low-foaming beverage formulation having low foamability. However, there are technical difficulties in using coffee, tea, or milk powder, which is a raw material that easily foams.

【0005】[0005]

【発明が解決しようとする課題】本発明の目的は、この
様な噴き出しや飛散を解決する陽圧缶入り飲料を提供す
るものである。
SUMMARY OF THE INVENTION An object of the present invention is to provide a positive pressure canned beverage which solves such spouting and scattering.

【0006】[0006]

【課題を解決するための手段】本発明者らは、上記実情
に鑑み鋭意検討した結果、特定のショ糖脂肪酸エステル
含有せしめることにより、飲料缶詰において、開缶前
の振とうによる開缶時に内容物が缶外に噴き出し飛散す
る現象が防止できること見い出し、本発明に到達し
た。すなわち、本発明の要旨は、構成脂肪酸が炭素数1
2〜22の飽和脂肪酸及び/又は不飽和脂肪酸であり、
かつ平均置換度が4〜7であるショ糖脂肪酸エステル舎
有する陽圧缶入り飲料に存する。以下、本発明を詳細に
説明する。
The present inventors have SUMMARY OF THE INVENTION As a result of intensive study in view of the above circumstances, the Rukoto for the additional inclusion of particular sucrose fatty acid esters, can opening by the beverage canning, shaking before can opening It has been found that the phenomenon that the contents sometimes spout out of the can can be prevented, and the present invention has been accomplished. That is, the gist of the present invention is that the constituent fatty acid has 1 carbon atoms.
2 to 22 saturated and / or unsaturated fatty acids,
And it exists in the positive pressure canned drink which has a sucrose fatty acid ester house whose average degree of substitution is 4-7. Hereinafter, the present invention will be described in detail.

【0007】本発明で使用されるショ糖脂肪酸エステル
は、構成脂肪酸が炭素数12〜22の飽和脂肪酸及び/
又は不飽和脂肪酸であって、その平均置換度が4〜7で
あるものが用いられる。ここで平均置換度とは、ショ糖
脂肪酸エステルを構成するショ糖1分子にエステル化さ
れた脂肪酸の平均結合数を言う。結合脂肪酸としては、
例えば、ラウリン酸、ミリスチン酸、パルミチン酸、ス
テアリン酸、オレイン酸、リシノール酸、エルカ酸等の
1種または2種以上の混合物が挙げられる。これらのシ
ョ糖脂肪酸エステルは、その平均置換度が4〜7である
もの、すなわちトリ、テトラ、ペンタ、ヘキサ及びヘプ
タエステルを多く含有するものである。モノおよびジエ
ステルを多く含有するもの、即ち、平均置換度が3以下
となるものでは水に対する溶解性が著しく増加して、消
泡効果が期待できない。また平均置換度が7を超える
と、水に対する分散性が悪くなって有効な効果が期待で
きない。
The sucrose fatty acid ester used in the present invention comprises a saturated fatty acid having 12 to 22 carbon atoms and / or a constituent fatty acid.
Alternatively, unsaturated fatty acids having an average degree of substitution of 4 to 7 are used. Here, the average degree of substitution refers to the average number of bonds of the fatty acid esterified to one molecule of sucrose constituting the sucrose fatty acid ester. As a bound fatty acid,
Examples thereof include one kind or a mixture of two or more kinds of lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, ricinoleic acid, erucic acid and the like. These sucrose fatty acid esters are those having an average degree of substitution of 4 to 7, that is, those containing a large amount of tri, tetra, penta, hexa and hepta esters. Those containing a large amount of mono- and diesters, that is, those having an average degree of substitution of 3 or less, the solubility in water remarkably increases and the defoaming effect cannot be expected. If the average degree of substitution exceeds 7, the dispersibility in water deteriorates and an effective effect cannot be expected.

【0008】本発明の陽圧缶入り飲料としては、飲料缶
コーヒー(加糖または無糖のコーヒー、ミルクコーヒ
ー)、ウーロン茶、緑茶、ココア、紅茶、ミルクココ
ア、ミルク紅茶などの低酸性飲料の缶詰、ビン詰、他の
密封容器入り飲料等を挙げることができる。ショ糖脂肪
エステルは飲料缶詰の製造に際し、加温された原液を使
用する場合は、直接原液に添加して混合すればよく、ま
た30℃以下の温度に冷却された液の場合は、乳化液と
して添加することにより均一に飲料中に添加できる。消
泡剤を添加した飲料原液は、充填機により空缶に充填さ
れ、液体窒素を流下又は滴下して巻締めすることにより
陽圧缶とすることが出来る。
The positive pressure canned beverages of the present invention include beverage canned coffee (sweetened or unsweetened coffee, milk coffee), oolong tea, green tea, cocoa, black tea, milk cocoa, canned low acid beverages such as milk black tea, bottled, other sealed container beverages, and the like can be given. Sucrose fat
Ester may be added directly to the undiluted solution and mixed in the case of using a warmed undiluted solution in the production of beverage cans, and it may be added as an emulsion in the case of a solution cooled to a temperature of 30 ° C or lower. As a result, it can be uniformly added to the beverage. The beverage stock solution to which the defoaming agent has been added is filled in an empty can by a filling machine, and a positive pressure can can be obtained by flowing or dropping liquid nitrogen and winding it.

【0009】ショ糖脂肪エステルの使用量は、飲料に対
して、通常0.001〜0.05重量%、好ましくは
0.005〜0.02重量%が用いられる。0.05重
量%以上では、コスト高を招き、0.001重量%以下
では、本発明の消泡効果が期待できない。ショ糖脂肪エ
ステルは、1種のみを単独で用いてもよいし2種以上を
組み合わせて用いてもよい。本発明の飲料には、その使
用目的に応じて適宜他の乳化剤、例えばレシチン、グリ
セリン脂肪酸エステル、ポリグリセリン脂肪酸エステ
ル、ソルビタン脂肪酸エステル、プロピレングリコール
脂肪酸エステル等を混合することができる。
The amount of sucrose fatty acid ester used is usually 0.001 to 0.05% by weight, preferably 0.005 to 0.02% by weight, based on the beverage. If it is 0.05% by weight or more, the cost is increased, and if it is 0.001% by weight or less, the defoaming effect of the present invention cannot be expected. Sucrose fat
The stell may be used alone or in combination of two or more. The beverage of the present invention can be appropriately mixed with other emulsifiers, such as lecithin, glycerin fatty acid ester, polyglycerin fatty acid ester, sorbitan fatty acid ester, propylene glycol fatty acid ester, etc., depending on the purpose of use.

【0010】[0010]

【実施例】以下に本発明を実施例により更に詳細に説明
するが、本発明はその要旨を越えない限り以下の実施例
に限定されるものでない。以下において、%とあるのは
重量%、部とあるのは重量部を示す。実施例1〜7およ
び比較例1〜3インスタントコーヒー2%、脱脂粉乳
0.8%、全粉乳0.16%、砂糖10%、の処方にて
調整したミルクコーヒーに、後記表1に示したとおり、
ショ糖脂肪酸エステルをはじめとする消泡剤を0.02
%加え、60℃以上に加温して、分散させた。このミル
クコーヒーを、250ml容アルミ缶に、液体窒素と共に
充填して缶詰とした。缶内圧は1.2kg/cm2に調整し
た。これを、レトルト殺菌(125℃×20分)後、5
5℃に1日間保存した。このものを、ヤヨイ(株)製振
とう機にて、10回振とうした直後、開缶して開缶前後
の重量差から、内容物の噴き出し重量を測定した。結果
を、表1に示す。尚、実施例1〜7および比較例1〜3
で用いたショ糖脂肪酸エステル等消泡剤の名称について
は、後記表2に示した通りである。
EXAMPLES The present invention will be described in more detail with reference to examples below, but the present invention is not limited to the following examples as long as the gist thereof is not exceeded. In the following,% means% by weight and part means part by weight. Examples 1-7 and Comparative Examples 1-3 Instant milk 2%, skim milk powder 0.8%, whole milk powder 0.16%, sugar 10%, prepared in the formula of milk coffee, shown in Table 1 below. Street,
Defoaming agents such as sucrose fatty acid ester 0.02
%, And heated to 60 ° C. or higher to disperse. A 250 ml aluminum can was filled with this milk coffee together with liquid nitrogen to make a can. The internal pressure of the can was adjusted to 1.2 kg / cm 2 . After retort sterilization (125 ° C x 20 minutes), this is 5
Stored at 5 ° C for 1 day. Immediately after shaking this product 10 times with a shaker manufactured by Yayoi Co., Ltd., the cans were opened, and the weight of the contents blown out was measured from the weight difference before and after the opening of the cans. The results are shown in Table 1. Incidentally, Examples 1 to 7 and Comparative Examples 1 to 3
The names of the defoaming agents such as the sucrose fatty acid ester used in the above are as shown in Table 2 below.

【0011】[0011]

【発明の効果】本発明によれば、優れた飲料用消泡剤が
提供され、陽圧缶においても噴き出しの防止された飲料
の製造に寄与するところが大である。
EFFECTS OF THE INVENTION According to the present invention, an excellent antifoaming agent for beverages is provided, which largely contributes to the production of beverages which are prevented from being blown out even in a positive pressure can.

【表1】 [Table 1]

【表2】 [Table 2]

───────────────────────────────────────────────────── フロントページの続き (72)発明者 諏訪 信行 神奈川県横浜市緑区鴨志田町1000番地 三 菱化成株式会社総合研究所内 (72)発明者 西村 彰夫 神奈川県横浜市緑区鴨志田町1000番地 三 菱化成株式会社総合研究所内 (56)参考文献 特開 昭62−205757(JP,A) 特開 昭49−32887(JP,A) ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Nobuyuki Suwa 1000, Kamoshida-cho, Midori-ku, Yokohama-shi, Kanagawa Sanryoh Kasei Co., Ltd. (72) Akio Nishimura 1000, Kamoshida-cho, Midori-ku, Yokohama, Kanagawa Prefecture (56) References Japanese Patent Laid-Open No. 62-205757 (JP, A) Japanese Patent Laid-Open No. 49-32887 (JP, A)

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 構成脂肪酸が炭素数12〜22の飽和脂
肪酸及び/又は不飽和脂肪酸であり、かつ平均置換度が
4〜7であるショ糖脂肪酸エステルを有効成分とする飲
料用消泡剤を含有する陽圧缶入り飲料。
1. A constituent fatty acid is a saturated fatty acid and / or unsaturated fatty acids having 12 to 22 carbon atoms and an average degree of substitution of the beverage antifoaming agent comprising, as an active ingredient, sucrose fatty acid ester is a 4 to 7 Beverage with positive pressure can contained.
【請求項2】 飲料用消泡剤を、飲料に対し0.001
〜0.05重量%含有することを特徴とする請求項
載の陽圧缶入り飲料。
2. A defoaming agent for beverages is added to 0.001 with respect to the beverage.
The positive pressure canned beverage according to claim 1 , wherein the beverage is contained in an amount of about 0.05% by weight.
JP3088671A 1991-04-19 1991-04-19 Defoaming agent for beverage and beverage using the same Expired - Lifetime JPH0861B2 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
JP3088671A JPH0861B2 (en) 1991-04-19 1991-04-19 Defoaming agent for beverage and beverage using the same
FR9204715A FR2675346B1 (en) 1991-04-19 1992-04-16 BEVERAGE CONTAINING ANTIFOAMING AGENT.
US07/869,952 US5378484A (en) 1991-04-19 1992-04-17 Process for making an anti-foaming agent-containing beverage
KR1019920006509A KR100196254B1 (en) 1991-04-19 1992-04-18 Beverages containing defoaming agent
GB9208528A GB2254771B (en) 1991-04-19 1992-04-21 Beverages containing defoaming agent
TW081103311A TW223009B (en) 1991-04-19 1992-04-28

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3088671A JPH0861B2 (en) 1991-04-19 1991-04-19 Defoaming agent for beverage and beverage using the same

Publications (2)

Publication Number Publication Date
JPH04320654A JPH04320654A (en) 1992-11-11
JPH0861B2 true JPH0861B2 (en) 1996-01-10

Family

ID=13949285

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3088671A Expired - Lifetime JPH0861B2 (en) 1991-04-19 1991-04-19 Defoaming agent for beverage and beverage using the same

Country Status (1)

Country Link
JP (1) JPH0861B2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5415203B2 (en) * 2009-09-29 2014-02-12 第一工業製薬株式会社 Sucrose fatty acid ester mixture, oil and fat modifier and oil composition using the same
US20220010179A1 (en) * 2018-11-21 2022-01-13 Greentech Global Pte. Ltd. Novel aqueous adhesives using saccharide fatty acid esters

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS523349B2 (en) * 1972-07-25 1977-01-27
JPH0693824B2 (en) * 1986-03-06 1994-11-24 第一工業製薬株式会社 Powder defoaming composition for food

Also Published As

Publication number Publication date
JPH04320654A (en) 1992-11-11

Similar Documents

Publication Publication Date Title
US6159513A (en) Package and method for packaging and preparing a mixed drink
US2977231A (en) Packaging and dispensing beverage concentrates
EP0227213B1 (en) A beverage package and a method of packaging a beverage containing gas in solution
RU2460381C2 (en) Improvement of carbonated beverages or in connection with carbonated beverages
US5378484A (en) Process for making an anti-foaming agent-containing beverage
US6024996A (en) Packaged carbonated coffee beverage
US20110151068A1 (en) Improvements in or relating to gassed beverages
JP3417181B2 (en) Antifoaming agent and canned beverage using the same
EP1226078B1 (en) Beverage container
JPH0861B2 (en) Defoaming agent for beverage and beverage using the same
JPH0227967A (en) Canned beverage
WO2014148213A1 (en) Carbonated beverage
JPH0716386B2 (en) Defoaming agent for beverage and beverage using the same
JPH04320667A (en) Defoaming agent for drink and drink using the same agent
JPH10295339A (en) Sparking beverage filled in container
JP3042240B2 (en) Canned beverage
JP3037079B2 (en) Defoamer for beverage, canned beverage to which it is added, and method for producing the same
JP3417189B2 (en) Defoamer and beverage in positive pressure can using the same
WO2009133392A1 (en) Foam control
JPS61173771A (en) Method for dropping liquid nitrogen on beer surface in container
CA2311835A1 (en) Carton dispensing machine
JPH0676016U (en) A canister for drinks that has a substantially rectangular tubular shape

Legal Events

Date Code Title Description
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 19981110

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20080110

Year of fee payment: 12

S111 Request for change of ownership or part of ownership

Free format text: JAPANESE INTERMEDIATE CODE: R313115

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20080110

Year of fee payment: 12

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20090110

Year of fee payment: 13

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20090110

Year of fee payment: 13

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20100110

Year of fee payment: 14

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20110110

Year of fee payment: 15

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20110110

Year of fee payment: 15

S531 Written request for registration of change of domicile

Free format text: JAPANESE INTERMEDIATE CODE: R313531

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20110110

Year of fee payment: 15

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20110110

Year of fee payment: 15

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20120110

Year of fee payment: 16

EXPY Cancellation because of completion of term
FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20120110

Year of fee payment: 16