JPH083880A - Buff-type artificial leather having pearl-like appearance - Google Patents
Buff-type artificial leather having pearl-like appearanceInfo
- Publication number
- JPH083880A JPH083880A JP15952494A JP15952494A JPH083880A JP H083880 A JPH083880 A JP H083880A JP 15952494 A JP15952494 A JP 15952494A JP 15952494 A JP15952494 A JP 15952494A JP H083880 A JPH083880 A JP H083880A
- Authority
- JP
- Japan
- Prior art keywords
- buff
- artificial leather
- pearl
- carbon black
- appearance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、パール調の光沢を有す
るバフタイプの皮革様シート状物に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a buff type leather-like sheet material having a pearly luster.
【０００２】[0002]
【従来の技術】従来パール調の光沢を有する人工皮革の
様なシート状物としては、その表面仕上げ層がポリウレ
タン等の合成樹脂に着色顔料及び真珠光沢顔料を分散含
有してなる物が知られている。2. Description of the Related Art Conventionally, as a sheet material such as an artificial leather having a pearly luster, there is known a material in which a surface finishing layer contains a synthetic resin such as polyurethane in which a color pigment and a pearlescent pigment are dispersed. ing.
【０００３】しかしながら表面をサンディング切削する
バフタイプの場合は、上述の仕上げ層も同時に切削され
てしまいパール調光沢が得られない。一方、サンディン
グ切削後パール調仕上げ加工を施すと、バフタイプ特有
のルックス及びタッチ感が、該仕上げ層に隠ぺいされて
しまう。However, in the case of the buff type in which the surface is sanded, the above-mentioned finishing layer is also cut at the same time, and a pearly luster cannot be obtained. On the other hand, if a pearly finish is applied after sanding, the look and touch peculiar to the buff type is hidden by the finish layer.
【０００４】この事からパール調バフタイプは、従来得
る事が出来なかった。For this reason, a pearl-like buff type could not be obtained conventionally.
【０００５】[0005]
【発明が解決しようとする課題】従って本発明の目的と
するところは、パール調光沢及びサンディング切削によ
るバフタイプのルックス、タッチ感を同時に有する皮革
様シート状物を提供するにある。SUMMARY OF THE INVENTION Therefore, an object of the present invention is to provide a leather-like sheet material having a pearly luster and a buff type look and touch feeling by sanding.
【０００６】[0006]
【課題を解決するための手段】上述の目的は基材と銀面
を有するバフタイプの人工皮革であって、銀面層にカー
ボンブラックトナーの凝集物が有り、且つ銀面表層の該
凝集物がサンディングにより切削されている事を特徴と
する人工皮革によって達成される。The above-mentioned object is a buff type artificial leather having a base material and a silver surface, wherein the silver surface layer has carbon black toner aggregates and the silver surface layer has the aggregates. It is achieved by artificial leather characterized by being cut by sanding.
【０００７】本発明で云う基材とは、不織布、織布、編
布等からなる繊維質基体に高分子弾性体の有機溶剤溶液
又はエマルジョンを付与し、凝固させて繊維質基体内に
高分子弾性体を充填させた物で、その製造は公知の適宜
な方法によればよい。The base material referred to in the present invention means that a polymer elastic body organic solvent solution or emulsion is applied to a fibrous base material such as a non-woven fabric, a woven fabric, a knitted fabric, etc. and solidified to form a polymer in the fibrous base material. The elastic body is filled, and its production may be carried out by a known appropriate method.
【０００８】上記高分子弾性体としては、例えばポリウ
レタン、塩化ビニル樹脂、アクリル酸エステル・スチレ
ン共重合体、スチレン・ブタジエン共重合体、ウレタン
・塩化ビニル共重合体等の重合体及びそれらの混合物等
を挙げることができ、好ましいものとしてはポリウレタ
ン及びポリウレタンとウレタン・塩化ビニル共重合体の
混合物が挙げられる。Examples of the elastic polymer include polyurethane, vinyl chloride resin, acrylic ester / styrene copolymer, styrene / butadiene copolymer, urethane / vinyl chloride copolymer, and the like, and mixtures thereof. The preferred examples include polyurethane and a mixture of polyurethane and a urethane / vinyl chloride copolymer.
【０００９】本発明に用いるカーボンブラックトナーと
しては、約０．１〜１０μｍの粒径をもつカーボンをビ
ヒクルと呼ばれる高分子弾性体で包み、水に溶解する有
機溶剤、例えばジメチルホルムアミド等の分散剤に分散
させたもの等が用いられる。As the carbon black toner used in the present invention, carbon having a particle size of about 0.1 to 10 μm is wrapped with a polymer elastic body called a vehicle, and an organic solvent soluble in water, for example, a dispersant such as dimethylformamide. Those dispersed in are used.
【００１０】本発明のポイントは、通常であれば分散さ
せているカーボンブラックトナーを逆に凝集させてしま
うところにある。その凝集方法としては、カーボンブラ
ックトナーにアニオン系界面活性剤を数％添加するだけ
で良い。カーボンブラックトナーの凝集物の粒径は１０
０〜１０００μｍであることが好ましい。The point of the present invention is that the carbon black toner which is normally dispersed is agglomerated to the contrary. As the aggregation method, it is sufficient to add a few% of an anionic surfactant to the carbon black toner. The particle size of the aggregate of carbon black toner is 10
It is preferably 0 to 1000 μm.
【００１１】また、該凝集物は人工皮革の単位面積当た
り１〜１００個／ｍ2 であることが好ましく、更に好ま
しくは５〜３０個／ｍ2 である。The aggregate is preferably 1 to 100 pieces / m 2 per unit area of the artificial leather, and more preferably 5 to 30 pieces / m 2 .
【００１２】アニオン系界面活性剤は、陰イオンを持つ
界面活性剤であれば種類は問わないが、例えばジアルキ
ルスルホコハク酸ナトリウム、アルキルナフタレンスル
ホン酸ナトリウム、ドデシルベンゼンスルホン酸ナトリ
ウム等が挙げられ、なかでもジアルキルスルホコハク酸
ナトリウムが好ましい。The anionic surfactant may be of any type as long as it has an anion, and examples thereof include sodium dialkylsulfosuccinate, sodium alkylnaphthalenesulfonate, sodium dodecylbenzenesulfonate, and the like. Sodium dialkyl sulfosuccinate is preferred.
【００１３】該凝集物を含有させた銀面層を、サンディ
ングペーパー等により切削する。The silver surface layer containing the agglomerates is cut with sanding paper or the like.
【００１４】[0014]
【作用】トナー凝集物中のビヒクルが切削され、中のカ
ーボンブラックが露出することによって、パール調を呈
する。．The vehicle in the toner agglomerate is cut off and the carbon black therein is exposed to give a pearly tone. ．
【００１５】[0015]
【実施例】以下に実施例を示す。尚、実施例及び比較例
に於いて「％」、「部」とあるのは、特に断りのない限
り「重量％」、「重量部」を意味する。Examples are shown below. In Examples and Comparative Examples, "%" and "parts" mean "% by weight" and "parts by weight" unless otherwise specified.
【００１６】パール調光沢性及びバフ調タッチ感の評価
は測定者を１０人ランダムに抽出し、目視判定を行い”
○”＝良好、”△”＝中間、”×”＝不良の３段階評価
をして、その平均をとった。For the evaluation of the pearly luster and the touch feeling of the buff, ten persons are randomly selected and visually judged.
A three-level evaluation of “◯” = good, “Δ” = intermediate, and “x” = bad was performed, and the average thereof was taken.
【００１７】実施例１ ナイロン繊維不織布に、ブチレンアジペート系エステル
型ポリウレタンエラストマーを充填して厚み１．１０ｍ
ｍ、目付け３９０ｇ／ｍ2 、見かけ密度０．３５ｇ／ｃ
ｍ3 の基材（Ａ）を得た。Example 1 A nylon fiber non-woven fabric was filled with butylene adipate ester type polyurethane elastomer to obtain a thickness of 1.10 m.
m, basis weight 390 g / m 2 , apparent density 0.35 g / c
A base material (A) of m 3 was obtained.
【００１８】ついで、ブチレンアジペート系エステル型
ポリウレタンエラストマーに、カーボンブラックトナー
１０部及びペレックスＯＴ−Ｐ（花王株式会社製のアニ
オン系界面活性剤）を１部添加し、固形分濃度２５％に
なるようにジメチルホルムアミドを加えた溶液（Ｂ）を
作成した。Next, 10 parts of carbon black toner and 1 part of Perex OT-P (anionic surfactant made by Kao Corporation) were added to butylene adipate ester type polyurethane elastomer so that the solid content concentration became 25%. A solution (B) was prepared by adding dimethylformamide to.
【００１９】この溶液（Ｂ）を基材（Ａ）にコーティン
グし、凝固、乾燥を行い銀付き基材（Ｃ）を得た。更に
この銀付き基材（Ｃ）の表面をサンディングペーパーで
切削するとバフ調仕上げになるとともに、パール調光沢
のある人工皮革が得られた。This solution (B) was coated on the substrate (A), coagulated and dried to obtain a substrate with silver (C). Further, when the surface of the silver-coated substrate (C) was cut with sanding paper, a buff-like finish was obtained and artificial leather having a pearly luster was obtained.
【００２０】比較例１ 実施例１に於いて、ペレックスＯＴ−Ｐを添加しない以
外はすべて同様の方法で人工皮革を得た。このバフ調仕
上げを施した人工皮革の表面に、パール粉を添加したポ
リウレタンエラストマーのＤＭＦ溶液をグラビア法にて
コーティングし、人工皮革を得た。しかしながらこの従
来法による人工皮革は、パール調光沢はあるものの、バ
フ調タッチ感が不良であった。Comparative Example 1 An artificial leather was obtained in the same manner as in Example 1 except that Perex OT-P was not added. The surface of this buff-finished artificial leather was coated with a DMF solution of a polyurethane elastomer containing pearl powder by a gravure method to obtain an artificial leather. However, the artificial leather produced by this conventional method has a pearly luster, but has a poor buff-like touch feeling.
【００２１】比較例２ 実施例１に於いて、ペレックスＯＴ−Ｐを添加しない以
外はすべて同様の方法で人工皮革を得た。しかしながら
この人工皮革は、バフ調タッチ感はあるものの、銀面層
にカーボンブラックの凝集物が存在しない為にパール調
光沢は得られなかった。Comparative Example 2 An artificial leather was obtained in the same manner as in Example 1 except that Perex OT-P was not added. However, although this artificial leather has a buff-like touch feeling, it does not have a pearly luster because there are no carbon black aggregates in the silver surface layer.
【００２２】以上の結果を表１に示す。The above results are shown in Table 1.
【００２３】[0023]
【表１】 [Table 1]
【００２４】[0024]
【発明の効果】本発明の最大の特徴は、従来法では製造
不可能であったバフ調のルックス、タッチ感とパール調
光沢を併せ持つという事である。The greatest feature of the present invention is that it has a buff-like look, touch feeling and pearly luster that cannot be produced by the conventional method.
─────────────────────────────────────────────────────
─────────────────────────────────────────────────── ───
【手続補正書】[Procedure amendment]
【提出日】平成６年８月１０日[Submission date] August 10, 1994
【手続補正１】[Procedure Amendment 1]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】０００９[Correction target item name] 0009
【補正方法】変更[Correction method] Change
【補正内容】[Correction content]
【０００９】本発明に用いるカーボンブラックトナーと
しては、約０．１〜１０μｍの粒径をもつカーボンをビ
ヒクルと呼ばれる高分子弾性体で包み、水に溶解する有
機溶剤、例えばジメチルホルムアミド等に分散剤により
分散させたもの等が用いられる。As the carbon black toner used in the present invention, carbon having a particle size of about 0.1 to 10 μm is wrapped with a polymer elastic body called a vehicle, and is dispersed in an organic solvent such as dimethylformamide which is soluble in water. more <br/> like are dispersed is used.
【手続補正２】[Procedure Amendment 2]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】００１４[Correction target item name] 0014
【補正方法】変更[Correction method] Change
【補正内容】[Correction content]
【００１４】[0014]
【作用】トナー凝集物が切削され、カーボンブラックの
切削断面が露出することによって、パール調を呈する。[Action] toner aggregates are cut, mosquito over carbon black
The exposed cut section gives a pearly tone.
【手続補正３】[Procedure 3]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】００２０[Correction target item name] 0020
【補正方法】変更[Correction method] Change
【補正内容】[Correction content]
【００２０】比較例１ 実施例１に於いて、ペレックスＯＴ−Ｐを添加しない以
外はすべて同様の方法で人工皮革を得た。このバフ調仕
上げを施した人工皮革の表面に、パール粉を添加したポ
リウレタンエラストマーの有機溶剤溶液をグラビア法に
てコーティングし、人工皮革を得た。しかしながらこの
従来法による人工皮革は、パール調光沢はあるものの、
バフ調タッチ感が不良であった。Comparative Example 1 An artificial leather was obtained in the same manner as in Example 1 except that Perex OT-P was not added. The surface of this buff-finished artificial leather was coated with an organic solvent solution of a polyurethane elastomer containing pearl powder by a gravure method to obtain an artificial leather. However, although the artificial leather produced by this conventional method has a pearly luster,
The buff-like touch feeling was poor.
Claims (1)
革であって、銀面層にカーボンブラックトナーの凝集物
が有り、且つ銀面表層の該凝集物がサンディングにより
切削されている事を特徴とする人工皮革。1. A buff-type artificial leather having a base material and a silver surface, wherein the silver surface layer has aggregates of carbon black toner, and the aggregates of the silver surface layer are cut by sanding. Characteristic artificial leather.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15952494A JPH083880A (en) | 1994-06-17 | 1994-06-17 | Buff-type artificial leather having pearl-like appearance |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15952494A JPH083880A (en) | 1994-06-17 | 1994-06-17 | Buff-type artificial leather having pearl-like appearance |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH083880A true JPH083880A (en) | 1996-01-09 |
Family
ID=15695655
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15952494A Pending JPH083880A (en) | 1994-06-17 | 1994-06-17 | Buff-type artificial leather having pearl-like appearance |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH083880A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6196104B1 (en) | 1998-04-23 | 2001-03-06 | Premark Rwp Holdings, Inc. | Apparatus for producing sheets of solid surfacing |
| CN109322169A (en) * | 2018-10-18 | 2019-02-12 | 清远市齐力合成革有限公司 | A kind of aqueous cloudy surface, scratch resistance, soft synthetic leather |
-
1994
- 1994-06-17 JP JP15952494A patent/JPH083880A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6196104B1 (en) | 1998-04-23 | 2001-03-06 | Premark Rwp Holdings, Inc. | Apparatus for producing sheets of solid surfacing |
| CN109322169A (en) * | 2018-10-18 | 2019-02-12 | 清远市齐力合成革有限公司 | A kind of aqueous cloudy surface, scratch resistance, soft synthetic leather |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US5134178A (en) | Animal protein resin-plastic compositions and manufactures incorporating animal skins and/or leather and/or gelatin powder therein, the powder therein, and method of producing the same | |
| US4699820A (en) | Decorative materials comprising crinkled chips | |
| US4605584A (en) | Decorative materials comprising crinkled chips | |
| DE1769317A1 (en) | Improved plastic sheet material with a structured surface and method for its manufacture | |
| JPH083880A (en) | Buff-type artificial leather having pearl-like appearance | |
| JP2935705B2 (en) | Leather powder and its production | |
| JPH03287880A (en) | Leather-like sheet material | |
| US3595685A (en) | Method for preparing suede-like material | |
| JPH05331500A (en) | Antistatic natural leather | |
| JPH05279967A (en) | Leather-like molded article | |
| JP2526045B2 (en) | Method for manufacturing leather-like material | |
| JPH08199483A (en) | Surface-treating composition containing natural product powder | |
| AU595435B2 (en) | Leather powder, process for producing the same, leather-resin composition containing the leather powder, and process for producing paint containing the leather powder | |
| JPS63315678A (en) | Product having leather-like surface | |
| JP2533978B2 (en) | Thermoplastic floor material with a grain pattern | |
| JPS63154765A (en) | Leather-like molding | |
| JP3006908B2 (en) | Leather powder-containing resin film, laminate having this resin film, and methods for producing these | |
| Wilshire et al. | Development of latent fingerprints on paper using magnetic flakes | |
| JPH08217890A (en) | Sheet-like resin molding improved in moisture permeability | |
| JP3111290B2 (en) | Leather-like molded product | |
| JPH07506878A (en) | floor covering | |
| JPS5841974A (en) | Patterned suede leather and production thereof | |
| JPH0543703A (en) | Collagen fibrous powder | |
| JPS59218463A (en) | Developer for electrostatic charge image | |
| JPH0620762B2 (en) | Method for producing stone-tone rubber flooring |