JPH083686A - Cold rolled steel sheet excellent in uniformity of workability and its production - Google Patents

Cold rolled steel sheet excellent in uniformity of workability and its production

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Publication number
JPH083686A
JPH083686A JP30666394A JP30666394A JPH083686A JP H083686 A JPH083686 A JP H083686A JP 30666394 A JP30666394 A JP 30666394A JP 30666394 A JP30666394 A JP 30666394A JP H083686 A JPH083686 A JP H083686A
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JP
Japan
Prior art keywords
cold
steel sheet
temperature
amount
hot
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP30666394A
Other languages
Japanese (ja)
Other versions
JP3291639B2 (en
Inventor
Natsuko Hashimoto
夏子 橋本
Naoki Yoshinaga
直樹 吉永
Satoru Nishimura
哲 西村
Kazuo Koyama
一夫 小山
Manabu Takahashi
学 高橋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
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Nippon Steel Corp
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  • Heat Treatment Of Sheet Steel (AREA)

Abstract

PURPOSE:To prevent the occurrence of material deterioration at the edges in the width and the longitudinal direction of a rolled coil and to improve rolling yield by adding Ti to an ultralow carbon steel and optimizing S content and Ti content in the steel, respectively. CONSTITUTION:This steel has a composition which consists of, by weight ratio, 0.0005 to 0.007% C, 0.03 to 0.15% Mn, 0.005 to 0.8% Si, 0.005 to 0.1% Al, <=0.2% P, 0.004 to 0.02% S, <=0.007% N, 0.01 to 0.1% Ti, and the balance Fe with inevitable impurities and satisfies the condition of Ti*/S=1.5 when Ti* represents (Ti-3.42N) and in which the proportion of the quantity of S precipitated in the form of MnS in the total S quantity, K=(S% as MnS)/(total S%), is regulated to <=0.2. Further, preferred quantity of precipitated C is 0.0003%. This steel is hot-rolled at heating temp. of <=1200 deg.C and at finishing temp. of >=(Ar3-100) deg.C, coiled at a temp. between room temp. and 800 deg.C, cold-rolled at 60% draft, and annealed at a temp. not lower than the recrystallization temp.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、コイル内における加工
性のばらつきが極めて少ない冷延鋼板、溶融亜鉛メッキ
鋼板およびその製造方法に関わり、これらの鋼板の用途
は、自動車、家電、建材等である。また、本発明の高強
度鋼板を自動車用として適用した場合には、板厚を軽減
することができるため、燃費の向上をもたらし、近年大
きな問題となっている地球環境問題にも寄与することが
できる。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a cold-rolled steel sheet, a hot-dip galvanized steel sheet and a method for producing the same, in which the workability in the coil is extremely small. The applications of these steel sheets are automobiles, home appliances, building materials, etc. is there. Further, when the high-strength steel plate of the present invention is applied to an automobile, the plate thickness can be reduced, which leads to an improvement in fuel consumption and a global environmental problem that has become a serious problem in recent years. it can.

【0002】[0002]

【従来の技術】特開昭58−185752号公報に開示
されているように、極低炭素鋼板は優れた加工性を有す
るため、自動車などの用途に広く用いられている。ま
た、極低炭素鋼の成分や製造方法を規定することによっ
て、加工性をさらに改善するための工夫がなされてき
た。例えば、特開平3−130323号公報、特開平4
−143228号公報および特開平4−116124号
公報では、Tiを添加した極低炭素鋼中のC、Mn、P
等の量を極力低減させることによって優れた加工性を得
られることが開示されている。しかしながら、これらの
発明においては、コイルの幅および長手方向における端
部での歩留りを向上させる観点からの記述はなく、また
本発明のようなTi硫化物を積極的に活用する技術でも
ない。材質のばらつきを低減するという観点からは、特
開平3−170618号公報および特開平4−5222
9号公報記載の技術がある。しかしながら、これらの発
明は、仕上熱延での圧下率を大きくしたり、熱延後の巻
取温度を高める必要があり、熱延工程に大きな負荷をか
けることとなる。
2. Description of the Related Art As disclosed in Japanese Patent Application Laid-Open No. 58-185752, an ultra-low carbon steel sheet has excellent workability and is therefore widely used in applications such as automobiles. Further, by defining the composition and manufacturing method of the ultra-low carbon steel, measures have been taken to further improve the workability. For example, JP-A-3-130323 and JP-A-4
In JP-A-143228 and JP-A-4-116124, C, Mn, and P in an ultra-low carbon steel containing Ti are added.
It has been disclosed that excellent workability can be obtained by reducing the amount of the like. However, in these inventions, there is no description from the viewpoint of improving the width of the coil and the yield at the end in the longitudinal direction, and it is not the technique of positively utilizing the Ti sulfide as in the present invention. From the viewpoint of reducing variations in materials, JP-A-3-170618 and JP-A-4-5222 are used.
There is a technique described in Japanese Patent No. 9 publication. However, in these inventions, it is necessary to increase the rolling reduction in finishing hot rolling and to raise the winding temperature after hot rolling, which imposes a heavy load on the hot rolling process.

【0003】本発明の効果は、PやSiで強化した良加
工性高強度冷延鋼板においても同様に発揮されるもので
ある。これらの鋼板に関する技術としては、特開昭59
−31827号公報、特開昭59−38337号公報、
特公昭57−57945号公報、特開昭61−2769
31号公報などに代表されるが、いずれもコイルの幅お
よび長手方向における端部での歩留りを向上させるため
の工夫はなされておらず、また本発明のようなTi硫化
物を積極的に活用する技術でもない。
The effect of the present invention is similarly exhibited in a good workability high strength cold rolled steel sheet reinforced with P or Si. A technique relating to these steel sheets is disclosed in Japanese Patent Laid-Open No. 59-59
-31827, JP-A-59-38337,
JP-B-57-57945, JP-A-61-2769
No. 31, etc., but none of them has been devised to improve the yield of the coil in the width and end portions in the longitudinal direction, and the Ti sulfide as in the present invention is positively utilized. It is not a technique to do.

【0004】[0004]

【発明が解決しようとする課題】Ti添加またはTi、
Nb添加極低炭素鋼においては、熱延後の高温巻取りに
よってCをTiCあるいはNbCとして析出せしめ、固
溶Cを低減させることにより冷延焼鈍後の材質を確保す
ることが通常の方法となっていた。これは、PやSiで
強化した場合においても同様である。しかしながら、熱
延コイルの幅端部および長手方向の端部においては、巻
取り時および巻取り後の冷却が著しく速く進行するた
め、TiCやNbCの析出が充分でなく、これらの部分
では材質が劣化してしまうという問題があった。従っ
て、実際には熱延板あるいは冷延板の端部は切り捨てら
れることが多く、これが極低炭素鋼の製造コストを上昇
させる原因となっていた。
Problems to be Solved by the Invention Addition of Ti or Ti,
In the case of Nb-added ultra-low carbon steel, it is a normal method to precipitate C as TiC or NbC by high temperature winding after hot rolling and reduce the solid solution C to secure the material after cold rolling and annealing. Was there. This is the same when strengthening with P or Si. However, at the width end and the lengthwise end of the hot-rolled coil, cooling during winding and after winding proceeds remarkably rapidly, so precipitation of TiC and NbC is not sufficient, and the material in these portions is There was a problem of deterioration. Therefore, in practice, the ends of the hot-rolled sheet or the cold-rolled sheet are often cut off, which has been a cause of increasing the manufacturing cost of the ultra-low carbon steel.

【0005】本発明は、コイルの幅および長手方向端部
における材質劣化が極めて少ない冷延鋼板、溶融亜鉛メ
ッキ鋼板およびその製造方法を提供することを目的とす
るものである。
It is an object of the present invention to provide a cold-rolled steel sheet, a hot-dip galvanized steel sheet, and a method for producing the same, in which deterioration of the material in the width and the longitudinal end portion of the coil is extremely small.

【0006】[0006]

【課題を解決するための手段】上記の課題を解決するた
めに、本発明者らは、極低炭素鋼中においてSを積極的
に活用するとともに、Ti量とS量との比を最適化する
こと、Mn量を規定することにより特定の析出物を析出
せしめ、さらに微細析出物を低減させることによって加
工性の均一性に優れた冷延鋼板を得ることについて鋭意
検討した。
In order to solve the above-mentioned problems, the inventors of the present invention positively utilize S in ultra-low carbon steel and optimize the ratio between the Ti amount and the S amount. In order to obtain a cold-rolled steel sheet excellent in uniformity of workability by precipitating a specific precipitate by defining the Mn content and further reducing fine precipitates.

【0007】その結果、S≧0.004%とし、Ti*
=Ti−3.42NとしたときTi*/S≧1.5と
し、かつMn≦0.15%とすることが有効であること
を見出した。さらに、熱延後の巻取りの後に、全Sのう
ちMnSとして析出するSの割合K=(S% as M
nS)/(全S%)がK≦0.2を満たすことが材質の
均一性を得る上で極めて重要であることが判明した。こ
れは、全S量のうちMnSとして析出する量を極力低減
せしめ、Ti4 2 2 を積極的に析出させることによ
り、仕上熱延までに固溶Cを低減させることができ、こ
れにより熱延後の巻取り時にコイルの端部が急速に冷却
されても、巻取り以前に固溶Cが充分に固定されている
ため、コイル端部で固溶Cが多量に残存したり、微細炭
化物が析出することによる材質の劣化が軽減されるとい
う機構に基づくものと考えられる。
As a result, S ≧ 0.004% and Ti *
= Ti-3.42N, it was found that Ti * / S ≧ 1.5 and Mn ≦ 0.15% are effective. Furthermore, after winding after hot rolling, the proportion of S precipitated as MnS in the total S is K = (S% as M
It has been found that it is extremely important that nS) / (total S%) satisfies K ≦ 0.2 in order to obtain the uniformity of the material. This is because the amount of MnS precipitated out of the total amount of S is reduced as much as possible, and Ti 4 C 2 S 2 is positively precipitated, so that the solid solution C can be reduced before the hot rolling for finishing. Even if the end of the coil is rapidly cooled during winding after hot rolling, the solid solution C is sufficiently fixed before winding, so a large amount of solid solution C remains at the coil end, It is considered to be based on the mechanism that the deterioration of the material due to the precipitation of carbide is reduced.

【0008】また、本発明鋼の場合、巻取り前の熱延工
程で多くのCはTi4 2 2 として固定されるので、
熱延の巻取り前にわずかに残存する固溶Cを高温巻取り
によって微細析出物として析出させるよりも、むしろ微
細炭化物の析出を避ける目的で巻取温度を積極的に低温
化させた方が、より良好で均一な材質が得られる場合が
あることも判明した。
Further, in the case of the steel of the present invention, a large amount of C is fixed as Ti 4 C 2 S 2 in the hot rolling process before winding,
It is better to positively lower the coiling temperature for the purpose of avoiding the precipitation of fine carbides, rather than precipitating a slight amount of the solid solution C remaining as a fine precipitate by hot coiling before the coiling in hot rolling. It has also been found that a better and more uniform material may be obtained.

【0009】本発明は、これらの知見に基づいてなされ
たもので、その要旨とするところは下記のとおりであ
る。 (1)重量%で、C:0.0005〜0.007%、M
n:0.03〜0.15%、Si:0.005〜0.8
%、Al:0.005〜0.1%、P:0.2%以下、
S:0.004〜0.02%、N:0.007%以下、
Ti:0.01〜0.1%かつTi*=Ti−3.42
NとしたときTi*/S≧1.5を満たす範囲で含有
し、残部は鉄および不可避的不純物よりなり、さらに全
S量のうちMnSとして析出するS量の割合K=(S%
as MnS)/(全S%)がK≦0.2であること
を特徴とする加工性の均一性に優れた冷延鋼板。
The present invention has been made on the basis of these findings, and the gist thereof is as follows. (1)% by weight, C: 0.0005 to 0.007%, M
n: 0.03 to 0.15%, Si: 0.005 to 0.8
%, Al: 0.005 to 0.1%, P: 0.2% or less,
S: 0.004 to 0.02%, N: 0.007% or less,
Ti: 0.01 to 0.1% and Ti * = Ti-3.42
When N is set, Ti is contained in a range that satisfies Ti * / S ≧ 1.5, the balance is iron and inevitable impurities, and the ratio of the amount of S precipitated as MnS in the total amount of K is K = (S%
As MnS) / (total S%) is K ≦ 0.2, which is a cold-rolled steel sheet excellent in uniformity of workability.

【0010】(2)さらに、炭化物として析出するC量
が0.0003%以下であることを特徴とする前記
(1)記載の加工性の均一性に優れた冷延鋼板。 (3)さらに、Nb:0.002〜0.05%を含有す
ることを特徴とする前記(1)または(2)記載の加工
性の均一性に優れた冷延鋼板。 (4)さらに、B:0.0001〜0.0030%を含
有することを特徴とする前記(1)〜(3)の何れか1
項に記載の加工性の均一性に優れた冷延鋼板。
(2) Further, the cold-rolled steel sheet excellent in workability uniformity according to the above (1), characterized in that the amount of C precipitated as carbide is 0.0003% or less. (3) The cold rolled steel sheet having excellent workability uniformity according to (1) or (2), further containing Nb: 0.002 to 0.05%. (4) Any one of the above (1) to (3), further containing B: 0.0001 to 0.0030%.
The cold-rolled steel sheet having excellent uniformity of workability according to the item.

【0011】(5)前記(1)〜(4)の何れか1項に
記載の成分を有する鋼を加熱温度≦1200℃、仕上温
度≧(Ar3 −100)℃の熱間圧延を施し、室温から
800℃の温度範囲で巻取り、圧下率≧60%の冷間圧
延を施し、さらに再結晶温度以上で焼鈍することを特徴
とする加工性の均一性に優れた冷延鋼板の製造方法。 (6)前記(1)〜(4)の何れか1項に記載の成分を
有する鋼を加熱温度≦1200℃、仕上温度≧(Ar3
−100)℃の熱間圧延を施し、室温から800℃の温
度範囲で巻取り、次いで圧下率≧60%の冷間圧延を施
した後、ライン内焼鈍炉を有する連続溶融亜鉛メッキラ
インで再結晶温度以上で焼鈍を施し、冷却過程中に亜鉛
メッキを施すことを特徴とする加工性の均一性に優れた
溶融亜鉛メッキ鋼板の製造方法。
(5) A steel having the composition described in any one of (1) to (4) is hot-rolled at a heating temperature ≤1200 ° C and a finishing temperature ≥ (Ar 3 -100) ° C, A method for producing a cold-rolled steel sheet excellent in uniformity of workability, which comprises winding in a temperature range from room temperature to 800 ° C., cold rolling with a rolling reduction ≧ 60%, and further annealing at a recrystallization temperature or higher. . (6) Heating temperature of steel having the component described in any one of (1) to (4) above ≦ 1200 ° C., finishing temperature ≧ (Ar 3
After hot rolling at −100) ° C., winding in the temperature range from room temperature to 800 ° C., and then cold rolling at a rolling reduction ≧ 60%, re-rolling in a continuous hot dip galvanizing line with an in-line annealing furnace. A method for producing a hot-dip galvanized steel sheet having excellent workability uniformity, which comprises performing annealing at a crystallization temperature or higher and performing galvanization during a cooling process.

【0012】(7)亜鉛メッキを施した後、400〜6
00℃の温度範囲で合金化処理を行うことを特徴とする
前記(6)記載の加工性の均一性に優れた溶融亜鉛メッ
キ鋼板の製造方法。
(7) 400 to 6 after galvanizing
The method for producing a hot-dip galvanized steel sheet excellent in uniformity of workability according to (6), wherein the alloying treatment is performed in a temperature range of 00 ° C.

【0013】[0013]

【作用】本発明における冷延鋼板およびその製造方法
は、TiやNbを添加した極低炭素鋼、あるいはそれを
PやSiで強化したものをベースとして、S量、Mn
量、Ti量と特定の硫化物の量を限定し、熱延後の巻取
り以前にCを充分に析出させることによってコイルの長
手方向および幅方向の加工性の均一性に優れた高強度冷
延鋼板を提供するものである。以下にその限定理由を述
べる。
The cold-rolled steel sheet and the method for producing the same according to the present invention are based on an ultra-low carbon steel containing Ti or Nb, or a steel obtained by strengthening it with P or Si, based on the amount of S and Mn.
Amount, Ti amount and specific sulfide amount are limited, and by sufficiently precipitating C after hot rolling and before winding, a high-strength cold steel with excellent uniformity in workability in the longitudinal and width directions of the coil. It provides a rolled steel sheet. The reasons for the limitation will be described below.

【0014】まず、化学成分の限定理由について説明す
る。Cは、その量が増加するに従い、それを固定するた
めのTi、Nb等の炭化物形成元素量を増大させねばな
らないことから、コスト上昇を招き、また熱延コイルの
端部において固溶Cが残存したり、TiC、NbC等の
微細炭化物が粒内に数多く析出するため、粒成長性を妨
げ、加工性を劣化させる。従って、C量は0.007%
以下とするが、好ましくは0.003%以下がよい。一
方、真空脱ガス処理コストの観点からは、C量の下限は
0.0005%とする。
First, the reasons for limiting the chemical components will be described. As the amount of C increases, the amount of carbide-forming elements such as Ti and Nb for fixing it must be increased, which leads to an increase in cost and the amount of solid solution C at the end of the hot-rolled coil. Since it remains or a large amount of fine carbides such as TiC and NbC are precipitated in the grains, the grain growth property is hindered and the workability is deteriorated. Therefore, the C content is 0.007%
The content is set below, but preferably 0.003% or less. On the other hand, from the viewpoint of vacuum degassing treatment cost, the lower limit of the C content is 0.0005%.

【0015】Siは安価な高強度化元素として有効であ
るので、目的とする強度レベルに応じて活用する。ただ
し、その量が0.8%を超えるとYPが急激に上昇し、
伸びが低下し、メッキ性を著しく損なうので、上限を
0.8%とする。溶融亜鉛メッキ用としては、メッキ性
の観点から、Si量は0.3%以下とすることが好まし
い。高強度(TSで350MPa以上)を必要としない
場合には、0.1%以下がさらに好ましい。Si量の下
限は、製鋼コスト上の理由から、0.005%とする。
Since Si is effective as an inexpensive strengthening element, it is used depending on the intended strength level. However, when the amount exceeds 0.8%, YP rises sharply,
The elongation lowers and the plating properties are significantly impaired, so the upper limit is made 0.8%. For hot dip galvanizing, the Si content is preferably 0.3% or less from the viewpoint of plating properties. If high strength (350 MPa or more in TS) is not required, 0.1% or less is more preferable. The lower limit of the amount of Si is 0.005% for reasons of steelmaking costs.

【0016】Mnは本発明において最も重要な元素の1
つである。すなわち、Mn量が0.15%を超えるとM
nSの析出量が増加し、結果として、Ti4 2 2
析出量が低下するため、たとえ高温巻取りを行ったとし
ても熱延コイルの端部では、冷却速度が速く、固溶Cが
多量に残存したり、微細炭化物が多数析出して、著しく
材質を劣化させる。従って、Mn量は0.15%以下と
し、さらに好ましくは0.10%未満がよい。一方、M
n量を0.03%未満としても格別の効果は得られず、
また製鋼コストの上昇を招くので、下限を0.03%と
する。
Mn is one of the most important elements in the present invention.
One. That is, when the Mn amount exceeds 0.15%, M
The nS precipitation amount increases, and as a result, the Ti 4 C 2 S 2 precipitation amount decreases. Therefore, even if high temperature winding is performed, the cooling rate is high at the end of the hot-rolled coil and the solid solution C Remains in a large amount, or a large number of fine carbides are deposited, which significantly deteriorates the material. Therefore, the Mn content is 0.15% or less, and more preferably less than 0.10%. On the other hand, M
Even if the amount of n is less than 0.03%, no special effect is obtained,
In addition, the steelmaking cost is increased, so the lower limit is made 0.03%.

【0017】PもSiと同様に安価な高強度化元素とし
て目的とする強度レベルに応じて積極的に活用する。し
かし、P量が0.2%超では熱間あるいは冷間加工時の
割れの原因となり、2次加工性も著しく劣化させる。ま
た、溶融亜鉛メッキの合金化速度が著しく遅滞化される
ため、0.2%を上限とする。以上の観点から、より好
ましくは、0.08%以下がよい。また、高い強度を必
要としない場合には、0.03%以下がさらに好まし
い。
Similar to Si, P is also positively utilized as an inexpensive strengthening element depending on the target strength level. However, if the amount of P exceeds 0.2%, it causes cracking during hot or cold working, and the secondary workability is significantly deteriorated. Further, the alloying rate of hot dip galvanization is significantly delayed, so the upper limit is 0.2%. From the above viewpoint, it is more preferably 0.08% or less. Further, when high strength is not required, 0.03% or less is more preferable.

【0018】Sは本発明において極めて重要な元素であ
り、その添加量を0.004〜0.02%とする。S量
が0.004%未満になるとTi4 2 2 の析出量が
充分ではなく、低温で巻取った際にはもちろんのこと、
たとえ高温で巻取ってもコイルの端部では固溶Cが多量
に残存したり、TiCやNbCの微細な析出により焼鈍
時の粒成長性が阻害され、加工性が著しく劣化する。一
方、S量が0.02%超では、熱間割れが生じ易くな
り、またTi4 2 2 の析出よりもMnSやTiSが
多く析出するため同様の問題が生じ、加工性の均一性が
確保されない。なお、S量は0.004〜0.012%
がより好ましい範囲である。
S is an extremely important element in the present invention, and its addition amount is 0.004 to 0.02%. When the amount of S is less than 0.004%, the amount of precipitation of Ti 4 C 2 S 2 is not sufficient, and of course when winding at low temperature,
Even if wound at a high temperature, a large amount of solute C remains at the end of the coil, and fine precipitation of TiC and NbC hinders grain growth during annealing, resulting in significant deterioration of workability. On the other hand, if the amount of S exceeds 0.02%, hot cracking tends to occur, and more MnS and TiS precipitate than the precipitation of Ti 4 C 2 S 2 , causing the same problem, resulting in uniform workability. Is not secured. The S content is 0.004 to 0.012%
Is a more preferable range.

【0019】ところで、SはTi量との関係が重要であ
り、Ti*=Ti−3.42NとしたときTi*/S≧
1.5とする。Ti*/Sが1.5未満ではTi4 2
2の析出が充分でなく、TiSやMnSが多く析出す
るので熱延後の巻取りの前にCを析出させることが困難
となる。従って、熱延コイルの端部では、巻取温度を高
めても多量の固溶Cが残存したり、微細炭化物が析出し
たりして極端な材質劣化を招く。Ti*/Sは2超とす
ることが好ましく、より一層の効果が望まれる場合には
3以上とすることが好ましい。
By the way, S has an important relationship with the amount of Ti, and when Ti * = Ti-3.42N, Ti * / S ≧
Set to 1.5. When Ti * / S is less than 1.5, Ti 4 C 2
Precipitation of S 2 is not sufficient and a large amount of TiS and MnS are precipitated, so that it becomes difficult to precipitate C before winding after hot rolling. Therefore, at the end of the hot-rolled coil, a large amount of solid solution C remains or fine carbide precipitates even if the coiling temperature is increased, resulting in extreme deterioration of the material. Ti * / S is preferably more than 2, and more preferably 3 or more when a further effect is desired.

【0020】Alは脱酸剤として少なくとも0.005
%を添加する必要がある。しかし、Al量が0.1%を
超えるとコストアップとなるばかりか介在物の増加を招
き、加工性を劣化させる。NはCと同様にその増加とと
もにTi、Al等の窒化物形成元素を増量させねばなら
ないためコスト高となり、また析出物の増加により延性
の劣化を招くので少ないほど望ましい。従って、N量は
0.007%以下とするが、好ましくは0.003%以
下がよい。
Al is at least 0.005 as a deoxidizer.
% Must be added. However, if the amount of Al exceeds 0.1%, not only the cost will increase, but also inclusions will increase and the workability will deteriorate. As with C, N needs to increase the amount of nitride-forming elements such as Ti and Al as in the case of C, which increases the cost, and the increase of precipitates leads to deterioration of ductility, so the smaller the content of N, the better. Therefore, the N content is set to 0.007% or less, preferably 0.003% or less.

【0021】Tiは0.01〜0.1%添加する。Ti
量が0.01%未満ではTi4 22 を巻取りの前に
析出させることができず、また0.1%を超える量を添
加してもCを固定する効果が飽和するばかりかプレス成
形時のメッキ層の耐剥離性を確保することが困難にな
る。Ti4 2 2 を充分に析出させるという観点から
は、Ti量は0.025%超添加することが好ましい。
Ti is added in an amount of 0.01 to 0.1%. Ti
If the amount is less than 0.01%, Ti 4 C 2 S 2 cannot be precipitated before winding, and even if the amount exceeds 0.1%, the effect of fixing C is saturated. It becomes difficult to secure the peeling resistance of the plated layer during press molding. From the viewpoint of sufficiently precipitating Ti 4 C 2 S 2 , it is preferable to add Ti in an amount of more than 0.025%.

【0022】また、コイル端部での材質を確保するため
には、全S量のうちMnSとして析出するS量の割合K
=(S% as MnS)/(全S%)がK≦0.2で
なければならない。さらには、K<0.15とすること
が望ましい。この(S% as MnS)は、次のよう
にして求められる。すなわち、硫化物が溶解しないよう
な溶媒(例えば非水溶媒)によって析出物を電解抽出す
る。得られた抽出残査を化学分析に供し、Mn量を測定
(=X(g)とする)する。このときサンプル全体の電
解量をY(g)とすると、(S% as MnS)=X
/Y×32/55×100(%)となる。
In order to secure the material at the coil ends, the ratio of the amount of S precipitated as MnS in the total amount of S, K
= (S% as MnS) / (total S%) must be K ≦ 0.2. Furthermore, it is desirable that K <0.15. This (S% as MnS) is obtained as follows. That is, the precipitate is electrolytically extracted with a solvent that does not dissolve the sulfide (for example, a nonaqueous solvent). The obtained extraction residue is subjected to chemical analysis, and the Mn amount is measured (= X (g)). At this time, when the amount of electrolysis of the entire sample is Y (g), (S% as MnS) = X
/ Y × 32/55 × 100 (%).

【0023】Nbは熱延板を細粒化し、かつCを固着さ
せる効果を持ち、深絞り性を向上させるので、必要に応
じて0.002〜0.05%の範囲で添加する。添加量
が0.002%未満では加工性を向上させる効果はわず
かである。一方、Nbが0.05%超となると深絞り性
の向上効果は飽和し、延性が著しく劣化する。Bは粒界
を強化して2次加工性を良好にするので、必要に応じて
0.0001〜0.0030%添加する。B量が0.0
001%未満ではその効果は乏しく、また0.003%
超添加してもその効果は飽和し、延性が劣化する。
Nb has the effect of atomizing the hot rolled sheet and fixing C and improves the deep drawability, so it is added in an amount of 0.002 to 0.05% if necessary. If the added amount is less than 0.002%, the effect of improving the workability is slight. On the other hand, if Nb exceeds 0.05%, the effect of improving the deep drawability is saturated, and the ductility is significantly deteriorated. B strengthens the grain boundary and improves secondary workability, so 0.0001 to 0.0030% is added if necessary. B amount is 0.0
If less than 001%, the effect is poor, and 0.003%
Even if added excessively, its effect is saturated and ductility deteriorates.

【0024】炭化物として析出するC量が0.0003
%より増えると、微細析出物が増加し、焼鈍中の結晶粒
の成長が抑制されてr値が低下するため、必要に応じて
炭化物として析出するC量を0.0003%以下にす
る。このような観点から、直径10nm以下の炭化物と
して析出するC量は0.0001%以下であることが望
ましく、また20nm以下の炭化物として析出するC量
は0.0002%以下であることが好ましい。炭化物と
して析出するC量(=C%とする)は、非水溶媒中で電
解抽出することにより得られた全析出物を化学分析し、
Tiの化合物として分析されたTi量(=T%とする)
からTiNとして析出するTi量(=T1%とする)お
よびTi4 2 2 として析出するTi量(=T2%と
する)を差し引いたTi量により算出される。また、同
化学分析によってNbが検出される場合には、その量
(=N1%とする)も加算する。従って、C=(T−T
1−T2)/4+12/93×N1となる。ここで、T
1はT1=全N%×3.42で与えられ、T2は抽出残
査中のS量(=Sとする)を分析することにより、T2
=S×3で与えられる。
The amount of C precipitated as carbide is 0.0003
%, The amount of fine precipitates increases, the growth of crystal grains during annealing is suppressed, and the r value decreases. Therefore, if necessary, the amount of C precipitated as carbides is set to 0.0003% or less. From such a viewpoint, the amount of C precipitated as carbide having a diameter of 10 nm or less is preferably 0.0001% or less, and the amount of C precipitated as carbide having a diameter of 20 nm or less is preferably 0.0002% or less. The amount of C precipitated as carbide (= C%) is determined by chemical analysis of all precipitates obtained by electrolytic extraction in a non-aqueous solvent,
Ti content analyzed as a compound of Ti (= T%)
Is calculated by subtracting the amount of Ti precipitated as TiN (= T1%) and the amount of Ti precipitated as Ti 4 C 2 S 2 (= T2%). Further, when Nb is detected by the same chemical analysis, its amount (= N1%) is also added. Therefore, C = (T-T
1−T2) / 4 + 12/93 × N1. Where T
1 is given by T1 = total N% × 3.42, and T2 is T2 by analyzing the amount of S (= S) in the extraction residue.
= S × 3.

【0025】上記成分を得るための原料は特に限定しな
いが、鉄鉱石を原料として、高炉、転炉により成分を調
製する方法以外にスクラップを原料としてもよいし、こ
れを電炉で溶製してもよい。スクラップを原料の全部ま
たは一部として使用する際には、Cu、Cr、Ni、S
n、Sb、Zn、Pb、Mo等の元素を含有してもよ
い。
The raw materials for obtaining the above components are not particularly limited, but scraps may be used as raw materials other than the method of preparing the components by using iron ore as the raw material and by a blast furnace or a converter. Good. When scrap is used as all or part of the raw material, Cu, Cr, Ni, S
Elements such as n, Sb, Zn, Pb and Mo may be contained.

【0026】次に製造プロセスに関する限定理由を述べ
る。熱間圧延に供するスラブは、特に限定するものでは
ない。すなわち、連続鋳造スラブや薄スラブキャスター
で製造したものなどであればよい。また、鋳造後に直ち
に熱間圧延を行う、連続鋳造−直接圧延(CC−DR)
のようなプロセスにも適合する。
Next, the reasons for limitation regarding the manufacturing process will be described. The slab used for hot rolling is not particularly limited. That is, it may be a continuous cast slab or a thin slab caster. Further, continuous casting-direct rolling (CC-DR) in which hot rolling is performed immediately after casting
Suitable for processes like.

【0027】熱間圧延における加熱温度は、Ti4 2
2 の析出量をなるべく増やすために、1200℃以下
とすることが必須である。この観点からは、好ましくは
1150℃以下がよい。熱間圧延における仕上温度は、
プレス成形性を確保するために(Ar3 −100)℃以
上とする必要がある。また、熱間圧延は、粗圧延終了後
にバー接合して連続的に仕上熱延を行っても構わない。
The heating temperature in hot rolling is Ti 4 C 2
In order to increase the precipitation amount of S 2 as much as possible, it is essential to set the temperature to 1200 ° C or lower. From this viewpoint, it is preferably 1150 ° C. or lower. The finishing temperature in hot rolling is
In order to secure press formability, it is necessary to set the temperature to (Ar 3 -100) ° C or higher. Further, in the hot rolling, bar finishing may be performed after the rough rolling is completed and continuous hot rolling may be performed.

【0028】本発明は、熱延後の巻取温度が低くても加
工性を確保できるという特徴を有する。すなわち、本発
明によれば、Cの多くは、熱延の加熱時〜熱延後の冷却
までの過程でTi4 2 2 として析出しており、高温
巻取りしても大きく材質が向上することはない。従っ
て、巻取りは操業上適当な温度で行えばよく、室温から
800℃の範囲で行う。室温未満で巻取ることは過剰な
設備が必要となるばかりで特段の効果もない。また、8
00℃超となると熱延板の結晶粒が粗大化したり、表面
の酸化スケールが厚くなり、酸洗コストの上昇を招くの
で800℃を上限とする。本発明鋼の場合、巻取温度が
高いと、わずかに残存していた固溶Cが微細炭化物とし
て析出したり、Pの化合物が析出したりして、材質がむ
しろ劣化する傾向にある。従って、巻取りは650℃以
下の温度で行うことが好ましい。これらの有害な化合物
の析出を完全に避けるためには、500℃以下の温度で
巻取ることがさらに好ましい。さらに、巻取り後に室温
付近まで温度が下がる時間を短縮するためには、100
℃以下で巻取ることが好ましい。このような低温巻取り
化によって、製造コストの削減が計れることは言うまで
もない。
The present invention is characterized in that workability can be secured even if the coiling temperature after hot rolling is low. That is, according to the present invention, most of C is precipitated as Ti 4 C 2 S 2 in the process from the heating of hot rolling to the cooling after hot rolling. There is nothing to do. Therefore, the winding may be carried out at a temperature suitable for the operation, and is carried out in the range of room temperature to 800 ° C. Winding at less than room temperature requires not only excessive equipment but also no particular effect. Also, 8
If the temperature exceeds 00 ° C, the crystal grains of the hot-rolled sheet become coarse and the oxide scale on the surface becomes thick, which causes an increase in pickling cost. Therefore, the upper limit is 800 ° C. In the case of the steel of the present invention, when the coiling temperature is high, the slightly remaining solid solution C is precipitated as fine carbide or the compound of P is precipitated, and the material tends to be rather deteriorated. Therefore, the winding is preferably performed at a temperature of 650 ° C or lower. To completely avoid the precipitation of these harmful compounds, it is more preferable to wind at a temperature of 500 ° C. or lower. Furthermore, in order to shorten the time taken for the temperature to drop to around room temperature after winding, 100
It is preferable to wind it at a temperature of not more than ° C. It goes without saying that such low-temperature winding can reduce the manufacturing cost.

【0029】冷間圧延の圧下率は、深絞り性を確保する
という観点から60%以上とする。連続焼鈍における焼
鈍温度は、加工性を確保するために、再結晶温度以上と
する。連続溶融亜鉛メッキラインにおける再結晶焼鈍温
度も同様の理由で再結晶温度以上とする。溶融亜鉛メッ
キは、メッキ性、メッキ密着性の観点から420〜50
0℃がよい。その後の合金化処理温度は、低過ぎると合
金化反応が遅過ぎて生産性を損なうばかりか耐食性、溶
接性が劣悪になり、高過ぎると耐メッキ剥離性が劣化す
るので、400〜600℃で行うのが好ましい。より密
着性の優れたメッキ層を得るためには、480〜550
℃の範囲で合金化を行うのがよい。
The rolling reduction of cold rolling is 60% or more from the viewpoint of ensuring deep drawability. The annealing temperature in continuous annealing is higher than the recrystallization temperature in order to secure workability. The recrystallization annealing temperature in the continuous hot-dip galvanizing line is also set to the recrystallization temperature or higher for the same reason. The hot dip galvanizing is 420 to 50 from the viewpoint of plating property and plating adhesion.
0 ° C is good. If the alloying treatment temperature after that is too low, not only the alloying reaction will be too slow to impair the productivity but also the corrosion resistance and weldability will be poor, and if it is too high, the plating peeling resistance will be deteriorated. It is preferable to carry out. In order to obtain a plated layer with better adhesion, 480-550
It is preferable to carry out alloying in the range of ° C.

【0030】連続焼鈍や連続溶融亜鉛メッキラインにお
ける加熱速度は特に限定するものではなく、通常の速度
でもよいし、1000℃/s以上の超急速加熱を行って
もよい。なお、溶融亜鉛メッキ以外にも電気メッキ等種
々の表面処理を施してもよい。
The heating rate in the continuous annealing or continuous hot dip galvanizing line is not particularly limited, and may be a normal rate or ultra-rapid heating at 1000 ° C./s or more. In addition to hot dip galvanizing, various surface treatments such as electroplating may be performed.

【0031】[0031]

【実施例】以下に本発明を実施例をもって詳細に述べ
る。 (実施例1)表1、表2(表1のつづき−1)、表3
(表1のつづき−2)および表4(表1のつづき−3)
に示す化学成分を有するTi添加極低炭素鋼およびT
i、Nb添加極低炭素鋼を転炉にて出鋼し、連続鋳造機
にてスラブとした後、表5、表7(表5のつづき−
2)、表10(表5のつづき−5)および表13(表5
のつづき−8)に示したような条件で熱間圧延を行い、
その後種々の巻取温度でコイルに巻取った。このコイル
の長手方向中心部から試料を切り出し、以下のような処
理を行った。すなわち、実験室にて酸洗後0.8mmま
で冷間圧延を行い、連続焼鈍相当の熱処理を施した。焼
鈍条件は表5、表8(表5のつづき−3)、表11(表
5のつづき−6)および表14(表5のつづき−9)に
示す。その後、表6(表5のつづき−1)、表9(表5
のつづき−4)、表12(表5のつづき−7)および表
15(表5のつづき−10)に示した圧下率で調質圧延
を行い、引張試験に供した。ここで、引張試験および平
均ランクフォード値(以下r値)の測定は、JIS5号
試験片を用いて行った。なお、r値は伸び15%で評価
し、圧延方向(L方向)、圧延方向に垂直な方向(C方
向)および圧延方向に対して45°方向(D方向)の値
を測定し、下式により算出した。
EXAMPLES The present invention will be described in detail below with reference to examples. (Example 1) Table 1, Table 2 (continued-1 of Table 1), Table 3
(Continued-2 of Table 1) and Table 4 (Continued-3 of Table 1)
Ti-added ultra-low carbon steel having the chemical composition shown in T and T
i, Nb-added ultra-low carbon steel was tapped in a converter and made into a slab by a continuous casting machine, and then Table 5 and Table 7 (continued in Table 5-
2), Table 10 (continued from Table 5-5) and Table 13 (Table 5)
(8) Hot rolling is performed under the conditions shown in 8),
Then, the coil was wound at various winding temperatures. A sample was cut out from the center of the coil in the longitudinal direction, and the following treatment was performed. That is, after pickling in the laboratory, cold rolling was performed to 0.8 mm and heat treatment equivalent to continuous annealing was performed. Annealing conditions are shown in Table 5, Table 8 (continuation-3 of Table 5), Table 11 (continuation-6 of Table 5) and Table 14 (continuation-9 of Table 5). After that, Table 6 (continued from Table 5-1), Table 9 (Table 5
Continuation-4), Table 12 (Continuation-7 in Table 5) and Table 15 (Continuation-10 in Table 5) were subjected to temper rolling at a reduction rate and subjected to a tensile test. Here, the tensile test and the measurement of the average Rankford value (hereinafter referred to as r value) were performed using JIS No. 5 test pieces. The r value was evaluated at an elongation of 15%, and the values in the rolling direction (L direction), the direction perpendicular to the rolling direction (C direction) and the 45 ° direction (D direction) with respect to the rolling direction were measured. It was calculated by

【0032】r=(rL +2rD +rC )/4 試験結果を表6、表9、表12および表15にまとめて
示す。
R = (r L + 2r D + r C ) / 4 The test results are summarized in Table 6, Table 9, Table 12 and Table 15.

【0033】[0033]

【表1】 [Table 1]

【0034】[0034]

【表2】 [Table 2]

【0035】[0035]

【表3】 [Table 3]

【0036】[0036]

【表4】 [Table 4]

【0037】[0037]

【表5】 [Table 5]

【0038】[0038]

【表6】 [Table 6]

【0039】[0039]

【表7】 [Table 7]

【0040】[0040]

【表8】 [Table 8]

【0041】[0041]

【表9】 [Table 9]

【0042】[0042]

【表10】 [Table 10]

【0043】[0043]

【表11】 [Table 11]

【0044】[0044]

【表12】 [Table 12]

【0045】[0045]

【表13】 [Table 13]

【0046】[0046]

【表14】 [Table 14]

【0047】[0047]

【表15】 [Table 15]

【0048】表5〜表15から明らかなように、本発明
の成分を有する鋼では、800℃以下の温度で巻取るこ
とによって、優れた材質が得られることが分かる。特に
巻取温度が低くなり、炭化物として析出するC量が0.
0003%以下になると、極めて優れた材質が得られ
る。これに対して比較鋼では、低温巻き取りでは材質が
劣悪となることが明らかとなった。
As is clear from Tables 5 to 15, it is understood that the steels having the components of the present invention can obtain excellent materials by being wound at a temperature of 800 ° C. or lower. In particular, the coiling temperature becomes low, and the amount of C precipitated as carbides is 0.
If it is less than 0003%, an extremely excellent material can be obtained. On the other hand, it was revealed that the comparative steel was inferior in material quality at low temperature winding.

【0049】(実施例2)表16および表18(表16
のつづき−2)に示したような条件で製造した表1〜表
4の鋼No.1、2、3、6、11、12、13、1
4、21、24、25、28、33、35、38、39
の冷延鋼板(熱延で4mm厚にした後、冷延で0.8m
m厚としたもの)を用いて冷延コイル長手方向における
材質特性を調査した。
Example 2 Tables 16 and 18 (Table 16)
No. 2 of the steel Nos. 1 to 4 manufactured under the conditions shown in (2). 1, 2, 3, 6, 11, 12, 13, 1
4, 21, 24, 25, 28, 33, 35, 38, 39
Cold rolled steel sheet (after hot rolling to 4 mm thick, cold rolling 0.8 m
Material thickness in the longitudinal direction of the cold-rolled coil was investigated by using (thickness of m).

【0050】試験結果を表17(表16のつづき−1)
および表19(表16のつづき−3)にまとめて示す。
The test results are shown in Table 17 (continued from Table 16-1).
And Table 19 (continued from Table 16-3).

【0051】[0051]

【表16】 [Table 16]

【0052】[0052]

【表17】 [Table 17]

【0053】[0053]

【表18】 [Table 18]

【0054】[0054]

【表19】 [Table 19]

【0055】表16〜表19から明らかなように、本発
明の範囲によって製造された鋼は、コイルの中央部はも
ちろんのこと、その端部10mにおいても優れた特性を
示している。これに対して比較鋼の場合には、コイル端
部になるにつれて材質が著しく劣化し、また低温巻取り
の場合には、コイル全長で材質が劣悪になった。この傾
向が端部になるほど顕著になるのは明白である。
As is clear from Tables 16 to 19, the steel manufactured according to the scope of the present invention exhibits excellent characteristics not only in the central portion of the coil but also in the end portion 10m thereof. On the other hand, in the case of the comparative steel, the material was remarkably deteriorated toward the coil end, and in the case of low temperature winding, the material was inferior in the entire length of the coil. It is clear that this tendency becomes more prominent toward the edges.

【0056】(実施例3)表1〜表4の試料2、11、
22、34(実機出鋼スラブ)を用いて冷延焼鈍後の材
質特性に及ぼす熱延加熱温度の影響について調査した。
すなわち、スラブを実機にて1000〜1300℃に加
熱し、仕上温度940℃で、板厚が4.0mmとなるよ
うな熱間圧延を行った。ランアウトテーブルでの平均冷
却速度は20℃/sであり、その後690℃でコイルに
巻取った。なお、コイルの全長は約200mであった。
同コイルより実施例1と同様の位置からサンプルを切り
出し、酸洗後0.8mmまで冷間圧延を行い、続いて実
験室において連続焼鈍相当の熱処理を施した。焼鈍条件
は、焼鈍温度:790℃、均熱:50s、冷却速度:室
温まで60℃/sとした。その後、1.0%の圧下率で
調質圧延を行い、引張試験に供した。
(Example 3) Samples 2 and 11 of Tables 1 to 4
The effects of hot rolling heating temperature on the material properties after cold rolling and annealing were investigated using Nos. 22 and 34 (exposed steel slabs).
That is, the slab was heated to 1000 to 1300 ° C. in an actual machine, and hot rolling was performed at a finishing temperature of 940 ° C. so that the plate thickness became 4.0 mm. The average cooling rate on the run-out table was 20 ° C / s, after which the coil was wound at 690 ° C. The total length of the coil was about 200 m.
A sample was cut out from the same coil from the same position as in Example 1, pickled, cold-rolled to 0.8 mm, and subsequently subjected to heat treatment equivalent to continuous annealing in a laboratory. The annealing conditions were annealing temperature: 790 ° C., soaking: 50 s, cooling rate: 60 ° C./s up to room temperature. Then, temper rolling was performed at a rolling reduction of 1.0%, and the steel was subjected to a tensile test.

【0057】試験結果を表20および表21(表20の
つづき)にまとめて示す。
The test results are summarized in Tables 20 and 21 (continued from Table 20).

【0058】[0058]

【表20】 [Table 20]

【0059】[0059]

【表21】 [Table 21]

【0060】表20および表21から明らかなように、
本発明の範囲によって製造された鋼は、熱延コイルの中
央部はもちろんのこと、その端部においても冷延焼鈍後
の材質が優れている。これに対して、加熱温度が120
0℃超の場合には、コイル端部において冷延焼鈍後の材
質が著しく劣化した。 (実施例4)表1〜表4中の鋼No.5、10、11、
12、22、24、41、42を用いて表22に示した
条件で熱間圧延を施し、引き続き実機にて酸洗し、圧下
率80%の冷間圧延を行い、ライン内焼鈍方式の連続溶
融亜鉛メッキラインに通板した。このときのメッキ条件
を表22に示す。同様に表22に示された圧延率で調質
圧延を施した後、機械的性質、メッキ密着性を評価し
た。得られた結果を表23(表22のつづき)に示す。
As is clear from Tables 20 and 21,
The steel manufactured according to the scope of the present invention is excellent not only in the central portion of the hot rolled coil but also in the end portion thereof after the cold rolling and annealing. On the other hand, the heating temperature is 120
When the temperature was higher than 0 ° C, the material after cold rolling annealing was significantly deteriorated at the coil end. (Example 4) Steel Nos. In Tables 1 to 4 5, 10, 11,
12, 22, 24, 41, 42 were hot-rolled under the conditions shown in Table 22, followed by pickling with an actual machine, cold-rolling with a reduction rate of 80%, and continuous in-line annealing method. It was passed through a hot dip galvanizing line. Table 22 shows the plating conditions at this time. Similarly, after performing temper rolling at the rolling rate shown in Table 22, mechanical properties and plating adhesion were evaluated. The obtained results are shown in Table 23 (continued from Table 22).

【0061】ここで、メッキ密着性は180℃密着曲げ
を行い、亜鉛皮膜の剥離状況を曲げ加工部に粘着テープ
を接着した後、これを剥がしてテープに付着した剥離メ
ッキ量から判定した。評価は、下記の5段階とした。 1:剥離大、2:剥離中、3:剥離小、4:剥離微量、
5:剥離なし
Here, the adhesion of the plating was determined by determining the peeling condition of the zinc coating after the adhesive tape was adhered to the bent portion after peeling the zinc coating at 180 ° C. and peeling it off. The evaluation was made into the following 5 grades. 1: Large peeling, 2: During peeling, 3: Small peeling, 4: Small amount of peeling,
5: No peeling

【0062】[0062]

【表22】 [Table 22]

【0063】[0063]

【表23】 [Table 23]

【0064】表22および表23から明らかなように、
本発明の範囲によって製造された合金化溶融亜鉛メッキ
鋼板はコイルの部位に関わらず優れた特性を示してい
る。これに対して比較鋼では、コイルの部位による加工
性のばらつきが大きかった。
As is clear from Tables 22 and 23,
The galvannealed steel sheet produced according to the scope of the present invention exhibits excellent properties regardless of the coil position. On the other hand, in the comparative steel, the workability varied greatly depending on the coil portion.

【0065】[0065]

【発明の効果】以上のように本発明によれば、熱延後の
巻取温度を低温化することができ、しかもコイルの長手
方向および幅方向に均一に優れた材質が得られ、従来切
捨てられていたコイル端部を製品とすることができる。
また、本発明の高強度鋼板を自動車用として適用した場
合には、板厚を軽減することができるため、燃費の向上
をもたらし、近年大きな問題となっている地球環境問題
にも貢献し得るので、その価値は大きい。
As described above, according to the present invention, the coiling temperature after hot rolling can be lowered, and moreover, a material excellent in the longitudinal direction and the width direction of the coil can be uniformly obtained, and the conventional cutting method has been adopted. The former coil end can be made into a product.
Further, when the high-strength steel sheet of the present invention is applied to an automobile, the sheet thickness can be reduced, which leads to an improvement in fuel consumption and can contribute to a global environmental problem that has become a serious problem in recent years. , Its value is great.

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 FI 技術表示箇所 C23C 2/06 2/28 (72)発明者 小山 一夫 千葉県富津市新富20−1 新日本製鐵株式 会社技術開発本部内 (72)発明者 高橋 学 千葉県富津市新富20−1 新日本製鐵株式 会社技術開発本部内─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification number Reference number within the agency FI Technical indication C23C 2/06 2/28 (72) Inventor Kazuo Koyama 20-1 Shintomi, Futtsu-shi, Chiba Made in Shinnihon (72) Inventor Manabu Takahashi 20-1 Shintomi, Futtsu City, Chiba Nippon Steel Co., Ltd. Technical Development Headquarters

Claims (7)

【特許請求の範囲】[Claims] 【請求項1】 重量%で、C:0.0005〜0.00
7%、Mn:0.03〜0.15%、Si:0.005
〜0.8%、Al:0.005〜0.1%、P:0.2
%以下、S:0.004〜0.02%、N:0.007
%以下、Ti:0.01〜0.1%かつTi*=Ti−
3.42NとしたときTi*/S≧1.5を満たす範囲
で含有し、残部は鉄および不可避的不純物よりなり、さ
らに全S量のうちMnSとして析出するS量の割合K=
(S% as MnS)/(全S%)がK≦0.2であ
ることを特徴とする加工性の均一性に優れた冷延鋼板。
1. C: 0.0005-0.00, by weight.
7%, Mn: 0.03 to 0.15%, Si: 0.005
~ 0.8%, Al: 0.005-0.1%, P: 0.2
% Or less, S: 0.004 to 0.02%, N: 0.007
% Or less, Ti: 0.01 to 0.1% and Ti * = Ti-
When it is 3.42 N, it is contained in a range that satisfies Ti * / S ≧ 1.5, the balance is composed of iron and unavoidable impurities, and the ratio of the amount of S precipitated as MnS in the total amount of S K =
(S% as MnS) / (total S%) is K ≦ 0.2, which is a cold-rolled steel sheet excellent in workability uniformity.
【請求項2】 さらに、炭化物として析出するC量が
0.0003%以下であることを特徴とする請求項1記
載の加工性の均一性に優れた冷延鋼板。
2. The cold-rolled steel sheet excellent in workability uniformity according to claim 1, wherein the amount of C precipitated as carbide is 0.0003% or less.
【請求項3】 さらに、Nb:0.002〜0.05%
を含有することを特徴とする請求項1または2記載の加
工性の均一性に優れた冷延鋼板。
3. Nb: 0.002 to 0.05%
The cold-rolled steel sheet having excellent workability uniformity according to claim 1 or 2, further comprising:
【請求項4】 さらに、B:0.0001〜0.003
0%を含有することを特徴とする請求項1〜3の何れか
1項に記載の加工性の均一性に優れた冷延鋼板。
4. B: 0.0001 to 0.003
The cold-rolled steel sheet having excellent workability uniformity according to any one of claims 1 to 3, wherein the cold-rolled steel sheet contains 0%.
【請求項5】 請求項1〜4の何れか1項に記載の成分
を有する鋼を加熱温度≦1200℃、仕上温度≧(Ar
3 −100)℃の熱間圧延を施し、室温から800℃の
温度範囲で巻取り、圧下率≧60%の冷間圧延を施し、
さらに再結晶温度以上で焼鈍することを特徴とする加工
性の均一性に優れた冷延鋼板の製造方法。
5. A steel having the composition according to any one of claims 1 to 4 is used for heating temperature ≦ 1200 ° C. and finishing temperature ≧ (Ar
3 -100) subjected to hot rolling ° C., winding, a rolling reduction ≧ 60% cold rolling performed in a temperature range of 800 ° C. from room temperature,
A method for producing a cold-rolled steel sheet having excellent workability uniformity, which is characterized by annealing at a recrystallization temperature or higher.
【請求項6】 請求項1〜4の何れか1項に記載の成分
を有する鋼を加熱温度≦1200℃、仕上温度≧(Ar
3 −100)℃の熱間圧延を施し、室温から800℃の
温度範囲で巻取り、次いで圧下率≧60%の冷間圧延を
施した後、ライン内焼鈍炉を有する連続溶融亜鉛メッキ
ラインで再結晶温度以上で焼鈍を施し、冷却過程中に亜
鉛メッキを施すことを特徴とする加工性の均一性に優れ
た溶融亜鉛メッキ鋼板の製造方法。
6. A steel having the composition according to any one of claims 1 to 4 for heating temperature ≦ 1200 ° C. and finishing temperature ≧ (Ar
3 -100) subjected to hot rolling ° C., coiling at a temperature range of 800 ° C. from room temperature, and then was subjected to rolling reduction ≧ 60% cold rolling, a continuous galvanizing line having a line within the annealing furnace A method for producing a hot-dip galvanized steel sheet having excellent workability uniformity, which comprises performing annealing at a recrystallization temperature or higher and galvanizing during a cooling process.
【請求項7】 亜鉛メッキを施した後、400〜600
℃の温度範囲で合金化処理を行うことを特徴とする請求
項6記載の加工性の均一性に優れた溶融亜鉛メッキ鋼板
の製造方法。
7. 400 to 600 after galvanizing
The method for producing a hot-dip galvanized steel sheet excellent in workability uniformity according to claim 6, wherein the alloying treatment is performed in a temperature range of ° C.
JP30666394A 1994-01-21 1994-12-09 Cold rolled steel sheet excellent in workability uniformity and method for producing the same Expired - Fee Related JP3291639B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP30666394A JP3291639B2 (en) 1994-01-21 1994-12-09 Cold rolled steel sheet excellent in workability uniformity and method for producing the same

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
JP510394 1994-01-21
JP2934594 1994-02-28
JP6-29345 1994-04-22
JP8513494 1994-04-22
JP6-85134 1994-04-22
JP6-5103 1994-04-22
JP30666394A JP3291639B2 (en) 1994-01-21 1994-12-09 Cold rolled steel sheet excellent in workability uniformity and method for producing the same

Publications (2)

Publication Number Publication Date
JPH083686A true JPH083686A (en) 1996-01-09
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008110386A (en) * 2006-10-31 2008-05-15 Nippon Steel Corp Method for producing cold rolled steel sheet having excellent ductility and cold aging resistance
WO2019105041A1 (en) * 2017-11-30 2019-06-06 宝山钢铁股份有限公司 Non-oriented electrical steel sheet with excellent magnetism and manufacturing method therefor

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008110386A (en) * 2006-10-31 2008-05-15 Nippon Steel Corp Method for producing cold rolled steel sheet having excellent ductility and cold aging resistance
WO2019105041A1 (en) * 2017-11-30 2019-06-06 宝山钢铁股份有限公司 Non-oriented electrical steel sheet with excellent magnetism and manufacturing method therefor
US11371111B2 (en) 2017-11-30 2022-06-28 Baoshan Iron & Steel Co., Ltd. Non-oriented electrical steel sheet with excellent magnetic properties and manufacturing method thereof

Also Published As

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