JPH08333224A - Hair dye - Google Patents
Hair dyeInfo
- Publication number
- JPH08333224A JPH08333224A JP16682095A JP16682095A JPH08333224A JP H08333224 A JPH08333224 A JP H08333224A JP 16682095 A JP16682095 A JP 16682095A JP 16682095 A JP16682095 A JP 16682095A JP H08333224 A JPH08333224 A JP H08333224A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- hair
- hair dye
- dye
- red
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Cosmetics (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は染毛性に優れ、かつ安定
性の高い染毛料に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hair dye having excellent hair dyeing properties and high stability.
【０００２】[0002]
【従来の技術】従来汎用されている酸化染毛料は施術
時、アルカリ性下に過酸化水素水を作用させるために、
扱い方によっては毛髪損傷や一次皮膚刺激を起こす危険
性がある。このため頭皮や頭髪に対して影響の少ない酸
性染料を用いた染毛料が開発されてきた。2. Description of the Prior Art Oxidized hair dyes that have been widely used in the past are used in order to allow the hydrogen peroxide solution to act under alkaline conditions during treatment.
There is a risk of hair damage and primary skin irritation depending on how to handle. For this reason, hair dyes using acid dyes that have little effect on the scalp and hair have been developed.
【０００３】[0003]
【発明が解決しょうとする課題】酸性染料を用いた染毛
料においては強酸性にするほど染毛効果が高い。しかし
ｐＨ３以下の強酸性に耐えうる増粘剤がほとんどなく経
時的に不安定なものであつた。唯一強酸性下で安定であ
るキサンタンガムは、染毛料の出来上りがチキソトロピ
ックであり、使用性に欠けるものであった。又、高級ア
ルコールで固めた染毛料は強酸性下でも安定であるが、
油分が多い為染毛効果が若干落ちるという欠点がある。
従って、本発明の目的は染毛性に優れ、かつ安定性の高
い染毛料を提供することにある。DISCLOSURE OF INVENTION Problems to be Solved by the Invention In a hair dye containing an acid dye, the stronger the acidity, the higher the hair dyeing effect. However, there was almost no thickener capable of withstanding strong acidity of pH 3 or less, and it was unstable over time. Only xanthan gum, which is stable under strong acidity, had a thixotropic finish in the hair dye, and lacked usability. Also, hair dyes hardened with higher alcohols are stable even under strong acidity,
There is a drawback that the hair dyeing effect is slightly reduced due to the large amount of oil.
Therefore, an object of the present invention is to provide a hair dye having excellent hair dyeing properties and high stability.
【０００４】[0004]
【課題を解決するための手段】本発明者等は種々検討し
た結果、（ａ）水溶性高分子０．１〜１．５重量％、
（ｂ）酸性染料０．０２〜２．０重量％、（ｃ）ベント
ナイト３．０〜１０．０重量％、（ｄ）ベンジルアルコ
ール２．０〜１５．０重量％（e）Ｎーメチルーピロリ
ドン１．０〜１０．０重量％を含有し、ｐＨ１．０〜
３．０に調整することにより前記目的を達成する染毛料
が得られることを知見した。水溶性高分子０．１〜１．
５重量％ベントナイト３．０〜１０．０重量％、Ｎ−メ
チル−ピロリドン１．０〜１０．０重量％を配合するこ
とにより染毛剤組成物の安定性が飛躍的に上がり、かつ
ベースがなめらかで商品価値の高いものである。特に、
水溶性高分子、ベントナイト及びＮ−メチル−ピロリド
ンの両方が同一系に存在して初めて飛躍的に安定性が増
すのである。As a result of various studies by the present inventors, (a) a water-soluble polymer of 0.1 to 1.5% by weight,
(B) Acid dye 0.02 to 2.0% by weight, (c) Bentonite 3.0 to 10.0% by weight, (d) Benzyl alcohol 2.0 to 15.0% by weight (e) N-methyl- Pyrrolidone 1.0-10.0% by weight, pH 1.0-
It was found that a hair dye that achieves the above object can be obtained by adjusting the amount to 3.0. Water-soluble polymer 0.1-1.
By blending 5% by weight of bentonite 3.0 to 10.0% by weight and N-methyl-pyrrolidone 1.0 to 10.0% by weight, the stability of the hair dye composition is dramatically improved, and the base is It is smooth and has high commercial value. In particular,
The stability is dramatically increased only when both the water-soluble polymer, bentonite and N-methyl-pyrrolidone are present in the same system.
【０００５】本発明の染毛料の（ａ）成分である水溶性
高分子は、ヒドロキシエチルセルロース、メチルセルロ
ース、カルボキシメチルセルロース、ヒドロキシプロピ
ルセルロース等セルロース系水溶性高分子化合物；キサ
ンタンガム、グアーガム、プルラン、ペクチン、タマリ
ンド種子、トラガントガム、アラビアガム等のガム系水
溶性高分子化合物；デンプン類、デキストリン、カルボ
キシメチルデンプン、ジアルデヒドデンプン等のデンプ
ン系水溶性高分子化合物；アルギン酸ナトリウム等の天
然系水溶性高分子化合物；ポリアクリル酸ナトリウム、
カルボキシビニルポリマー、ポリビニルアルコール、ポ
リビニルピロリドン等の合成系水溶性高分子化合物等の
アニオン性及び非イオン性水溶性高分子化合物が挙げら
れ、これらの中でもセルロース系水溶性高分子化合物、
ガム系水溶性高分子化合物が好ましい。さらに好ましく
はキサンタンガムである。キサンタンガムは炭水化物を
キサントモナス属菌を用いて発酵させて得られる多糖類
であり、化粧品原料として汎用されているものである。
上記水溶性高分子の含有量は染毛料中０．１〜１．５重
量％、好ましくは０．３〜1．０重量％である。上記含
有量が０．１重量％未満であると、充分な粘度が得られ
ず、また１．５重量％以上であると含有量の増加に伴う
効果の向上がみられない。The water-soluble polymer which is the component (a) of the hair dye of the present invention includes cellulose-based water-soluble polymer compounds such as hydroxyethyl cellulose, methyl cellulose, carboxymethyl cellulose, hydroxypropyl cellulose; xanthan gum, guar gum, pullulan, pectin and tamarind. Gum-based water-soluble polymer compounds such as seeds, tragacanth gum, and gum arabic; Starch-based water-soluble polymer compounds such as starches, dextrin, carboxymethyl starch, and dialdehyde starch; Natural water-soluble polymer compounds such as sodium alginate; Sodium polyacrylate,
Carboxyvinyl polymers, polyvinyl alcohol, anionic and nonionic water-soluble polymer compounds such as synthetic water-soluble polymer compounds such as polyvinylpyrrolidone, among them, cellulose-based water-soluble polymer compound,
Gum-based water-soluble polymer compounds are preferred. Xanthan gum is more preferred. Xanthan gum is a polysaccharide obtained by fermenting carbohydrates using a bacterium of the genus Xanthomonas and is widely used as a raw material for cosmetics.
The content of the water-soluble polymer in the hair dye is 0.1 to 1.5% by weight, preferably 0.3 to 1.0% by weight. When the content is less than 0.1% by weight, sufficient viscosity cannot be obtained, and when the content is 1.5% by weight or more, the effect due to the increase in content cannot be improved.
【０００６】本発明の染毛料の（ｂ）成分である酸性染
料としては、ニトロ染料、アゾ染料、ニトロン染料、ト
リフェニルメタン染料、キサンテン染料、キノリン染
料、アントラキノン染料、インジゴ染料等が挙げられ、
具体的には、赤色２号、赤色３号、赤色１０２号、赤色
１０４号、赤色１０５号、赤色１０６号、黄色４号、黄
色５号、緑色３号、青色１号、青色２号、赤色２０１
号、赤色２２０号、赤色２２７号、赤色２３０号、赤色
２３１号、赤色２３２号、橙色２０５号、橙色２０７
号、黄色２０２号、黄色２０３号、緑色２０１号、緑色
２０４号、緑色２０５号、青色２０２号、青色２０３
号、青色２０５号、かっ色２０１号、赤色４０１号、赤
色５０２号、赤色５０３号、赤色５０４号、赤色５０６
号、橙色４０２号、黄色４０２号、黄色４０３号、黄色
４０６、黄色４０７号、緑色４０１号、緑色４０２号、
紫色４０１号、黒色４０１号等が用いられる。上記酸性
染料の含有量は染毛料中、０．０２〜２．０重量％、好
ましくは０．１〜１．０重量％である。上記含有量が
０．０２重量％未満であると、充分な染毛効果が得られ
ず、また２.０重量％以上であると、溶解性が低下する
おそれがあり、また染料含有量の増加に伴う染色効果の
向上もみられない。Examples of the acid dye which is the component (b) of the hair dye of the present invention include nitro dyes, azo dyes, nitrone dyes, triphenylmethane dyes, xanthene dyes, quinoline dyes, anthraquinone dyes and indigo dyes.
Specifically, Red No. 2, Red No. 3, Red No. 102, Red No. 104, Red No. 105, Red No. 106, Yellow No. 4, Yellow No. 5, Green No. 3, Blue No. 1, Blue No. 2, Red 201
No., Red 220, Red 227, Red 230, Red 231, Red 232, Orange 205, Orange 207
No., Yellow No. 202, Yellow No. 203, Green No. 201, Green No. 204, Green No. 205, Blue No. 202, Blue No. 203
No. 205, Blue No. 205, Brown No. 201, Red No. 401, Red No. 502, Red No. 503, Red No. 504, Red No. 506.
No. 402, orange No. 402, yellow No. 402, yellow No. 403, yellow 406, yellow No. 407, green No. 401, green No. 402,
Purple No. 401, black No. 401, etc. are used. The content of the acid dye in the hair dye is 0.02 to 2.0% by weight, preferably 0.1 to 1.0% by weight. When the content is less than 0.02% by weight, a sufficient hair dyeing effect cannot be obtained, and when it is 2.0% by weight or more, the solubility may decrease, and the dye content increases. There is no improvement in the dyeing effect associated with.
【０００７】本発明の染毛料の（ｃ）成分であるベント
ナイトは、天然に産するコロイド性含水ケイ酸アルミニ
ウムであり、化粧品原料として汎用されている。上記ベ
ントナイトの含有量は染毛料中３．０〜１０．０重量
％、好ましく４．０〜８．０重量％である。上記含有量
が３．０重量％以下では、満足のいく粘度が得られず、
また１０．０重量％以上では染毛料ベースが固くなり使
用性に難がある。Bentonite, which is the component (c) of the hair dye of the present invention, is a naturally occurring colloidal hydrous aluminum silicate and is widely used as a raw material for cosmetics. The content of bentonite in the hair dye is 3.0 to 10.0% by weight, preferably 4.0 to 8.0% by weight. When the content is 3.0% by weight or less, a satisfactory viscosity cannot be obtained,
On the other hand, if it is 10.0% by weight or more, the hair dye base becomes hard and there is a problem in usability.
【０００８】本発明の染毛料の（ｄ）成分であるベンジ
ルアルコールは染毛促進剤として用いられている。上記
ベンジルアルコールの含有量は染毛料中１．０〜１５．
０重量％、好ましくは２．０〜１０．０重量％である。
上記含有量が１．０重量％未満では充分な染毛性が得ら
れず、１５．０重量％以上では安全性に問題があり、ま
た含有量の増加に伴う効果の増強も見られない。また、
本発明の染毛料のｐＨは１．０〜３．０、好ましくは
１．０〜２．５に調整する。ｐＨ３.０以上では充分な
染毛効果が得られないからである。上記ｐＨの調整は、
例えば乳酸、酒石酸 、グリコール酸、クエン酸、シュ
ウ酸等の有機酸又は、リン酸、塩酸等の無機酸を用いて
行えばよい。Benzyl alcohol, which is the component (d) of the hair dye of the present invention, is used as a hair dye promoting agent. The content of the above benzyl alcohol is 1.0 to 15.
It is 0% by weight, preferably 2.0 to 10.0% by weight.
When the content is less than 1.0% by weight, sufficient hair dyeing properties cannot be obtained, and when the content is 15.0% by weight or more, there is a problem in safety and no increase in the effect due to the increase in the content is observed. Also,
The pH of the hair dye of the present invention is adjusted to 1.0 to 3.0, preferably 1.0 to 2.5. This is because at a pH of 3.0 or higher, a sufficient hair dyeing effect cannot be obtained. The above pH adjustment is
For example, organic acids such as lactic acid, tartaric acid, glycolic acid, citric acid and oxalic acid, or inorganic acids such as phosphoric acid and hydrochloric acid may be used.
【０００９】本発明の染毛料の（ｅ）成分であるＮ−メ
チル−ピロリドンは染毛促進剤及び粘度安定剤として用
いられている。上記Ｎ−メチル−ピロリドンの含有量に
１．０〜１０．０重量％、好ましくは２．０〜７．０重
量％である。１．０重量％以下では安定性に乏しく、１
０．０重量％以上では効果の増強がないからである。ま
た本発明の染毛料には系の安定性、ｐＨ値を損なわない
範囲であれば前記の必須成分の他に、低級アルコール、
多価アルコール、防腐剤、キレート剤、紫外線吸収剤、
香料等を適宜配合することができる。本発明の染毛料を
用いて毛髪等の角質繊維の染色を実施するには、例えば
本発明の染毛料を角質繊維に１５〜５０℃で適用し、１
〜３０分前後の作用時間をおいた後、角質繊維を洗浄し
乾燥すればよい。N-methyl-pyrrolidone, which is the component (e) of the hair dye of the present invention, is used as a hair dye accelerator and a viscosity stabilizer. The content of N-methyl-pyrrolidone is 1.0 to 10.0% by weight, preferably 2.0 to 7.0% by weight. If it is less than 1.0% by weight, the stability is poor and 1
This is because the effect is not enhanced when the content is 0.0% by weight or more. In the hair dye of the present invention, in addition to the above essential components, a lower alcohol, as long as the stability of the system and the pH value are not impaired,
Polyhydric alcohol, preservative, chelating agent, ultraviolet absorber,
A fragrance or the like can be appropriately mixed. To carry out dyeing of keratinous fibers such as hair using the hair dyeing agent of the present invention, for example, applying the hair dyeing agent of the present invention to keratinous fibers at 15 to 50 ° C.
After a working time of about 30 minutes, the keratinous fibers may be washed and dried.
【００１０】[0010]
【実施例】以下に 実施例を挙げ、本発明を更に詳細に
説明する。下記組成からなる混合物のｐＨをリン酸で
２．０に調整して染毛料を得た。これらの染毛料それぞ
れについて、白髪混じりの人毛に塗布し、常温で１０分
間放置した後、毛髪を通常のシャンプーで洗浄し、乾燥
して染毛性及び処理した毛髪のしなやかさを官能評価し
た。又、これら染毛料を４０゜保温器に３ヶ月放置した
後の安定性についても評価した。 以下余白EXAMPLES The present invention will be described in more detail with reference to the following examples. The pH of the mixture having the following composition was adjusted to 2.0 with phosphoric acid to obtain a hair dye. Each of these hair dyes was applied to human hair mixed with white hair, allowed to stand at room temperature for 10 minutes, washed with a normal shampoo, dried, and subjected to a sensory evaluation of hair dyeability and suppleness of treated hair. . Further, the stability of these hair dyes after being left in a 40 ° incubator for 3 months was also evaluated. Margin below
【表１】 ◎；非常に良い、 ○；よい、 △；普通、 ×；悪い [Table 1] ◎: Very good, ○: Good, △: Normal, ×: Bad
【表２】 [Table 2]
【００１１】 実施例７ （重量％） 紫色４０１号 ０．７ 橙色２０５号 ０．２ 赤色２０４号 ０．０１ 黒色４０１号 ０．０３ キサンタンガム ０．４ ベントナイト ５．０ ベンジルアルコール ５．０ Ｎ−メチル−ピロリドン ３．０ 水 バランス 香料 微量 上記組成からなる染毛料のｐＨをリン酸で、１．５に調
整して、ブラウン系染毛料を得た。このブラウン系染毛
料を用いて染毛したところ、染毛性及び染め上がりの毛
髪の感触の何れも良好であった。又、４０゜保温器にお
いても３ヶ月間良好であつた。Example 7 (wt%) Purple No. 401 0.7 Orange No. 205 0.2 Red No. 204 0.01 Black No. 401 0.03 Xanthan gum 0.4 Bentonite 5.0 Benzyl alcohol 5.0 N-methyl -Pyrrolidone 3.0 Water Balance Fragrance Trace amount The pH of the hair dye having the above composition was adjusted to 1.5 with phosphoric acid to obtain a brown hair dye. When hair was dyed using this brown hair dye, both the dyeability and the feel of the dyed hair were good. Also, the 40 ° incubator was good for 3 months.
【００１２】[0012]
【発明の効果】本発明の染毛料は、ベース状態がなめら
かで色調のバリエーションがあって、染色性に優れ、且
つ毛髪に良好な感触を付与し、しかも飛躍的に安定性の
高いものである。EFFECTS OF THE INVENTION The hair dye of the present invention has a smooth base and variations in color tone, is excellent in dyeability, imparts a good feel to the hair, and is extremely highly stable. .
───────────────────────────────────────────────────── フロントページの続き (72)発明者 北原 路朗 名古屋市西区鳥見町２丁目130番地 日本 メナード化粧品株式会社中央研究所内 (72)発明者 中田 悟 名古屋市西区鳥見町２丁目130番地 日本 メナード化粧品株式会社中央研究所内 ─────────────────────────────────────────────────── ─── Continuation of front page (72) Inventor Miro Kitahara 2-130 Torimi-cho, Nishi-ku, Nagoya City Central Research Institute, Menard Cosmetics Co., Ltd. (72) Satoru Nakata 2-130 Torimi-cho, Nishi-ku, Nagoya Japan Menard Central Research Institute of Cosmetics Co., Ltd.
Claims (2)
％、（ｂ）酸性染料０．０２〜２．０重量％、（ｃ）ベ
ントナイト３．０〜１０．０重量％、（ｄ）ベンジルア
ルコール１．０〜１５．０重量％、（e）Ｎーメチルー
ピロリドン１．０〜１０．０重量％ を含有し、ｐＨを
１．０〜３．０に調整したことを特徴とする染毛料。1. A water-soluble polymer 0.1 to 1.5% by weight, (b) an acid dye 0.02 to 2.0% by weight, and (c) bentonite 3.0 to 10.0% by weight. , (D) benzyl alcohol 1.0 to 15.0% by weight, (e) N-methyl-pyrrolidone 1.0 to 10.0% by weight, and the pH was adjusted to 1.0 to 3.0. A hair dye.
％、（ｂ）酸性染料０．１〜１．０重量％、（ｃ）ベン
トナイト４．０〜８．０重量％、（ｄ）ベンジルアルコ
ール１．０〜１０．０重量％（e）Ｎーメチルーピロリ
ドン２．０〜７．０重量％を含有しpＨを１．０〜２．
５に調整したことを特徴とする染毛料。2. (a) Xanthan gum 0.3 to 1.0% by weight, (b) acid dye 0.1 to 1.0% by weight, (c) bentonite 4.0 to 8.0% by weight, (d) ) Benzyl alcohol 1.0-10.0% by weight (e) N-methyl-pyrrolidone 2.0-7.0% by weight and pH 1.0-2.
A hair dye that is adjusted to 5.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16682095A JP3589745B2 (en) | 1995-06-07 | 1995-06-07 | Hair dye |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16682095A JP3589745B2 (en) | 1995-06-07 | 1995-06-07 | Hair dye |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH08333224A true JPH08333224A (en) | 1996-12-17 |
| JP3589745B2 JP3589745B2 (en) | 2004-11-17 |
Family
ID=15838277
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP16682095A Expired - Fee Related JP3589745B2 (en) | 1995-06-07 | 1995-06-07 | Hair dye |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3589745B2 (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998015256A1 (en) * | 1996-10-08 | 1998-04-16 | Kao Corporation | Hairtreatment composition |
| JP2004535409A (en) * | 2001-05-29 | 2004-11-25 | アヴェダ コーポレーション | Semi-permanent hair dyeing system using vat dye |
| US9339451B2 (en) | 2013-08-23 | 2016-05-17 | The Procter & Gamble Company | Hair colouring methods and kits thereof |
| US9339666B2 (en) | 2013-08-23 | 2016-05-17 | The Procter & Gamble Company | Hair colouring methods and kits thereof |
| US9345658B2 (en) | 2013-08-23 | 2016-05-24 | The Procter & Gamble Company | Hair colouring method |
| US9358201B2 (en) | 2013-08-23 | 2016-06-07 | The Procter & Gamble Company | Hair colouring methods and kits thereof |
| US9468778B2 (en) | 2013-08-27 | 2016-10-18 | The Procter & Gamble Company | Hair treatment method, kit, recipient, and use thereof |
| US9468278B2 (en) | 2013-08-23 | 2016-10-18 | The Procter & Gamble Company | Hair colouring methods and kits thereof |
| US9532937B2 (en) | 2013-08-23 | 2017-01-03 | Noxell Corporation | Hair treatment methods and kits thereof |
| JP2017222138A (en) * | 2016-06-17 | 2017-12-21 | 共同印刷株式会社 | Laminate and tube container |
-
1995
- 1995-06-07 JP JP16682095A patent/JP3589745B2/en not_active Expired - Fee Related
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998015256A1 (en) * | 1996-10-08 | 1998-04-16 | Kao Corporation | Hairtreatment composition |
| US6099828A (en) * | 1996-10-08 | 2000-08-08 | Kao Corporation | Hair treatment composition comprising a lactam compound and a water-soluble macromolecule |
| JP2004535409A (en) * | 2001-05-29 | 2004-11-25 | アヴェダ コーポレーション | Semi-permanent hair dyeing system using vat dye |
| US9339451B2 (en) | 2013-08-23 | 2016-05-17 | The Procter & Gamble Company | Hair colouring methods and kits thereof |
| US9339666B2 (en) | 2013-08-23 | 2016-05-17 | The Procter & Gamble Company | Hair colouring methods and kits thereof |
| US9345658B2 (en) | 2013-08-23 | 2016-05-24 | The Procter & Gamble Company | Hair colouring method |
| US9358201B2 (en) | 2013-08-23 | 2016-06-07 | The Procter & Gamble Company | Hair colouring methods and kits thereof |
| US9468278B2 (en) | 2013-08-23 | 2016-10-18 | The Procter & Gamble Company | Hair colouring methods and kits thereof |
| US9532937B2 (en) | 2013-08-23 | 2017-01-03 | Noxell Corporation | Hair treatment methods and kits thereof |
| US9468778B2 (en) | 2013-08-27 | 2016-10-18 | The Procter & Gamble Company | Hair treatment method, kit, recipient, and use thereof |
| JP2017222138A (en) * | 2016-06-17 | 2017-12-21 | 共同印刷株式会社 | Laminate and tube container |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3589745B2 (en) | 2004-11-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4808190A (en) | Process for dyeing keratinous fibres with 5,6-dihydroxy-indole and hydrogen peroxide, preceded or followed by a treatment with an iodide | |
| US5474578A (en) | Erasable hair dyeing process | |
| JP2001192326A (en) | Treating composition for dyed hair | |
| US5011500A (en) | Process for dyeing keratinous fibres and dye composition employing indole derivatives and direct nitro dyes | |
| JPS63284114A (en) | Method of dyeing keratinic fiber | |
| GB1583086A (en) | Hair style holding cosmetic preparation | |
| DE3824122A1 (en) | METHOD FOR COLORING KERATINIC FIBERS WITH AT LEAST ONE DYE OF THE INDOLE RANGE | |
| JPH08333224A (en) | Hair dye | |
| JPH05339134A (en) | Hair dye | |
| US6096099A (en) | Hair dye composition comprising acid dyes | |
| JPH08245348A (en) | Hair dyeing agent | |
| JPH08165226A (en) | Acidic hair dye composition | |
| JP3619988B2 (en) | Acid hair dye composition | |
| JPH07300407A (en) | Composition and method for temporaily dyeing hair using chemically or biologically synthesized water-soluble melanin | |
| JP3454938B2 (en) | Hair dye | |
| JPS63239209A (en) | Hair dyeing agent | |
| JPH11217319A (en) | Hair dye composition | |
| JPH04342518A (en) | Hair dyeing agent | |
| JPS62246510A (en) | Method of dyeing keratin fiber | |
| JP4352362B2 (en) | Hair dye composition for hair | |
| JP3577841B2 (en) | Hair treatment composition | |
| JP3009958B2 (en) | Hair rinse composition | |
| JPH0686371B2 (en) | Hair dye composition | |
| JPH10287535A (en) | Semipermanent hair dye composition | |
| JP2000178148A (en) | Dye for fiber containing 1,3-indandione |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A131 | Notification of reasons for refusal |
Effective date: 20040127 Free format text: JAPANESE INTERMEDIATE CODE: A131 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20040817 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20040818 |
|
| R150 | Certificate of patent (=grant) or registration of utility model |
Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313111 |
|
| R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Year of fee payment: 3 Free format text: PAYMENT UNTIL: 20070827 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Year of fee payment: 6 Free format text: PAYMENT UNTIL: 20100827 |
|
| LAPS | Cancellation because of no payment of annual fees |