JPH08333224A - Hair dye - Google Patents

Hair dye

Info

Publication number
JPH08333224A
JPH08333224A JP16682095A JP16682095A JPH08333224A JP H08333224 A JPH08333224 A JP H08333224A JP 16682095 A JP16682095 A JP 16682095A JP 16682095 A JP16682095 A JP 16682095A JP H08333224 A JPH08333224 A JP H08333224A
Authority
JP
Japan
Prior art keywords
weight
hair
hair dye
dye
red
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP16682095A
Other languages
Japanese (ja)
Other versions
JP3589745B2 (en
Inventor
Kunihiro Miyamoto
國寛 宮本
Haruyo Tsuge
晴予 柘植
Yasunori Matsumoto
康典 松本
Michiaki Kitahara
路朗 北原
Satoru Nakada
悟 中田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nonogawa Shoji Ltd
Original Assignee
Nonogawa Shoji Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nonogawa Shoji Ltd filed Critical Nonogawa Shoji Ltd
Priority to JP16682095A priority Critical patent/JP3589745B2/en
Publication of JPH08333224A publication Critical patent/JPH08333224A/en
Application granted granted Critical
Publication of JP3589745B2 publication Critical patent/JP3589745B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Cosmetics (AREA)

Abstract

PURPOSE: To obtain a hair dye, excellent in hair dyeability and good in stability. CONSTITUTION: This hair dye contains (a) 0.1-1.5wt.% water-soluble polymer, (b) 0.02-2.0wt.% acid dye, (c) 3.0-10.0wt.% bentonite, (d) 1.0-15.0wt.% benzyl alcohol and (e) 1.0-10.0wt.% N-methyl-pyrrolidone and is regulated to pH1.0-3.0.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は染毛性に優れ、かつ安定
性の高い染毛料に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hair dye having excellent hair dyeing properties and high stability.

【0002】[0002]

【従来の技術】従来汎用されている酸化染毛料は施術
時、アルカリ性下に過酸化水素水を作用させるために、
扱い方によっては毛髪損傷や一次皮膚刺激を起こす危険
性がある。このため頭皮や頭髪に対して影響の少ない酸
性染料を用いた染毛料が開発されてきた。
2. Description of the Prior Art Oxidized hair dyes that have been widely used in the past are used in order to allow the hydrogen peroxide solution to act under alkaline conditions during treatment.
There is a risk of hair damage and primary skin irritation depending on how to handle. For this reason, hair dyes using acid dyes that have little effect on the scalp and hair have been developed.

【0003】[0003]

【発明が解決しょうとする課題】酸性染料を用いた染毛
料においては強酸性にするほど染毛効果が高い。しかし
pH3以下の強酸性に耐えうる増粘剤がほとんどなく経
時的に不安定なものであつた。唯一強酸性下で安定であ
るキサンタンガムは、染毛料の出来上りがチキソトロピ
ックであり、使用性に欠けるものであった。又、高級ア
ルコールで固めた染毛料は強酸性下でも安定であるが、
油分が多い為染毛効果が若干落ちるという欠点がある。
従って、本発明の目的は染毛性に優れ、かつ安定性の高
い染毛料を提供することにある。
DISCLOSURE OF INVENTION Problems to be Solved by the Invention In a hair dye containing an acid dye, the stronger the acidity, the higher the hair dyeing effect. However, there was almost no thickener capable of withstanding strong acidity of pH 3 or less, and it was unstable over time. Only xanthan gum, which is stable under strong acidity, had a thixotropic finish in the hair dye, and lacked usability. Also, hair dyes hardened with higher alcohols are stable even under strong acidity,
There is a drawback that the hair dyeing effect is slightly reduced due to the large amount of oil.
Therefore, an object of the present invention is to provide a hair dye having excellent hair dyeing properties and high stability.

【0004】[0004]

【課題を解決するための手段】本発明者等は種々検討し
た結果、(a)水溶性高分子0.1〜1.5重量%、
(b)酸性染料0.02〜2.0重量%、(c)ベント
ナイト3.0〜10.0重量%、(d)ベンジルアルコ
ール2.0〜15.0重量%(e)Nーメチルーピロリ
ドン1.0〜10.0重量%を含有し、pH1.0〜
3.0に調整することにより前記目的を達成する染毛料
が得られることを知見した。水溶性高分子0.1〜1.
5重量%ベントナイト3.0〜10.0重量%、N−メ
チル−ピロリドン1.0〜10.0重量%を配合するこ
とにより染毛剤組成物の安定性が飛躍的に上がり、かつ
ベースがなめらかで商品価値の高いものである。特に、
水溶性高分子、ベントナイト及びN−メチル−ピロリド
ンの両方が同一系に存在して初めて飛躍的に安定性が増
すのである。
As a result of various studies by the present inventors, (a) a water-soluble polymer of 0.1 to 1.5% by weight,
(B) Acid dye 0.02 to 2.0% by weight, (c) Bentonite 3.0 to 10.0% by weight, (d) Benzyl alcohol 2.0 to 15.0% by weight (e) N-methyl- Pyrrolidone 1.0-10.0% by weight, pH 1.0-
It was found that a hair dye that achieves the above object can be obtained by adjusting the amount to 3.0. Water-soluble polymer 0.1-1.
By blending 5% by weight of bentonite 3.0 to 10.0% by weight and N-methyl-pyrrolidone 1.0 to 10.0% by weight, the stability of the hair dye composition is dramatically improved, and the base is It is smooth and has high commercial value. In particular,
The stability is dramatically increased only when both the water-soluble polymer, bentonite and N-methyl-pyrrolidone are present in the same system.

【0005】本発明の染毛料の(a)成分である水溶性
高分子は、ヒドロキシエチルセルロース、メチルセルロ
ース、カルボキシメチルセルロース、ヒドロキシプロピ
ルセルロース等セルロース系水溶性高分子化合物;キサ
ンタンガム、グアーガム、プルラン、ペクチン、タマリ
ンド種子、トラガントガム、アラビアガム等のガム系水
溶性高分子化合物;デンプン類、デキストリン、カルボ
キシメチルデンプン、ジアルデヒドデンプン等のデンプ
ン系水溶性高分子化合物;アルギン酸ナトリウム等の天
然系水溶性高分子化合物;ポリアクリル酸ナトリウム、
カルボキシビニルポリマー、ポリビニルアルコール、ポ
リビニルピロリドン等の合成系水溶性高分子化合物等の
アニオン性及び非イオン性水溶性高分子化合物が挙げら
れ、これらの中でもセルロース系水溶性高分子化合物、
ガム系水溶性高分子化合物が好ましい。さらに好ましく
はキサンタンガムである。キサンタンガムは炭水化物を
キサントモナス属菌を用いて発酵させて得られる多糖類
であり、化粧品原料として汎用されているものである。
上記水溶性高分子の含有量は染毛料中0.1〜1.5重
量%、好ましくは0.3〜1.0重量%である。上記含
有量が0.1重量%未満であると、充分な粘度が得られ
ず、また1.5重量%以上であると含有量の増加に伴う
効果の向上がみられない。
The water-soluble polymer which is the component (a) of the hair dye of the present invention includes cellulose-based water-soluble polymer compounds such as hydroxyethyl cellulose, methyl cellulose, carboxymethyl cellulose, hydroxypropyl cellulose; xanthan gum, guar gum, pullulan, pectin and tamarind. Gum-based water-soluble polymer compounds such as seeds, tragacanth gum, and gum arabic; Starch-based water-soluble polymer compounds such as starches, dextrin, carboxymethyl starch, and dialdehyde starch; Natural water-soluble polymer compounds such as sodium alginate; Sodium polyacrylate,
Carboxyvinyl polymers, polyvinyl alcohol, anionic and nonionic water-soluble polymer compounds such as synthetic water-soluble polymer compounds such as polyvinylpyrrolidone, among them, cellulose-based water-soluble polymer compound,
Gum-based water-soluble polymer compounds are preferred. Xanthan gum is more preferred. Xanthan gum is a polysaccharide obtained by fermenting carbohydrates using a bacterium of the genus Xanthomonas and is widely used as a raw material for cosmetics.
The content of the water-soluble polymer in the hair dye is 0.1 to 1.5% by weight, preferably 0.3 to 1.0% by weight. When the content is less than 0.1% by weight, sufficient viscosity cannot be obtained, and when the content is 1.5% by weight or more, the effect due to the increase in content cannot be improved.

【0006】本発明の染毛料の(b)成分である酸性染
料としては、ニトロ染料、アゾ染料、ニトロン染料、ト
リフェニルメタン染料、キサンテン染料、キノリン染
料、アントラキノン染料、インジゴ染料等が挙げられ、
具体的には、赤色2号、赤色3号、赤色102号、赤色
104号、赤色105号、赤色106号、黄色4号、黄
色5号、緑色3号、青色1号、青色2号、赤色201
号、赤色220号、赤色227号、赤色230号、赤色
231号、赤色232号、橙色205号、橙色207
号、黄色202号、黄色203号、緑色201号、緑色
204号、緑色205号、青色202号、青色203
号、青色205号、かっ色201号、赤色401号、赤
色502号、赤色503号、赤色504号、赤色506
号、橙色402号、黄色402号、黄色403号、黄色
406、黄色407号、緑色401号、緑色402号、
紫色401号、黒色401号等が用いられる。上記酸性
染料の含有量は染毛料中、0.02〜2.0重量%、好
ましくは0.1〜1.0重量%である。上記含有量が
0.02重量%未満であると、充分な染毛効果が得られ
ず、また2.0重量%以上であると、溶解性が低下する
おそれがあり、また染料含有量の増加に伴う染色効果の
向上もみられない。
Examples of the acid dye which is the component (b) of the hair dye of the present invention include nitro dyes, azo dyes, nitrone dyes, triphenylmethane dyes, xanthene dyes, quinoline dyes, anthraquinone dyes and indigo dyes.
Specifically, Red No. 2, Red No. 3, Red No. 102, Red No. 104, Red No. 105, Red No. 106, Yellow No. 4, Yellow No. 5, Green No. 3, Blue No. 1, Blue No. 2, Red 201
No., Red 220, Red 227, Red 230, Red 231, Red 232, Orange 205, Orange 207
No., Yellow No. 202, Yellow No. 203, Green No. 201, Green No. 204, Green No. 205, Blue No. 202, Blue No. 203
No. 205, Blue No. 205, Brown No. 201, Red No. 401, Red No. 502, Red No. 503, Red No. 504, Red No. 506.
No. 402, orange No. 402, yellow No. 402, yellow No. 403, yellow 406, yellow No. 407, green No. 401, green No. 402,
Purple No. 401, black No. 401, etc. are used. The content of the acid dye in the hair dye is 0.02 to 2.0% by weight, preferably 0.1 to 1.0% by weight. When the content is less than 0.02% by weight, a sufficient hair dyeing effect cannot be obtained, and when it is 2.0% by weight or more, the solubility may decrease, and the dye content increases. There is no improvement in the dyeing effect associated with.

【0007】本発明の染毛料の(c)成分であるベント
ナイトは、天然に産するコロイド性含水ケイ酸アルミニ
ウムであり、化粧品原料として汎用されている。上記ベ
ントナイトの含有量は染毛料中3.0〜10.0重量
%、好ましく4.0〜8.0重量%である。上記含有量
が3.0重量%以下では、満足のいく粘度が得られず、
また10.0重量%以上では染毛料ベースが固くなり使
用性に難がある。
Bentonite, which is the component (c) of the hair dye of the present invention, is a naturally occurring colloidal hydrous aluminum silicate and is widely used as a raw material for cosmetics. The content of bentonite in the hair dye is 3.0 to 10.0% by weight, preferably 4.0 to 8.0% by weight. When the content is 3.0% by weight or less, a satisfactory viscosity cannot be obtained,
On the other hand, if it is 10.0% by weight or more, the hair dye base becomes hard and there is a problem in usability.

【0008】本発明の染毛料の(d)成分であるベンジ
ルアルコールは染毛促進剤として用いられている。上記
ベンジルアルコールの含有量は染毛料中1.0〜15.
0重量%、好ましくは2.0〜10.0重量%である。
上記含有量が1.0重量%未満では充分な染毛性が得ら
れず、15.0重量%以上では安全性に問題があり、ま
た含有量の増加に伴う効果の増強も見られない。また、
本発明の染毛料のpHは1.0〜3.0、好ましくは
1.0〜2.5に調整する。pH3.0以上では充分な
染毛効果が得られないからである。上記pHの調整は、
例えば乳酸、酒石酸 、グリコール酸、クエン酸、シュ
ウ酸等の有機酸又は、リン酸、塩酸等の無機酸を用いて
行えばよい。
Benzyl alcohol, which is the component (d) of the hair dye of the present invention, is used as a hair dye promoting agent. The content of the above benzyl alcohol is 1.0 to 15.
It is 0% by weight, preferably 2.0 to 10.0% by weight.
When the content is less than 1.0% by weight, sufficient hair dyeing properties cannot be obtained, and when the content is 15.0% by weight or more, there is a problem in safety and no increase in the effect due to the increase in the content is observed. Also,
The pH of the hair dye of the present invention is adjusted to 1.0 to 3.0, preferably 1.0 to 2.5. This is because at a pH of 3.0 or higher, a sufficient hair dyeing effect cannot be obtained. The above pH adjustment is
For example, organic acids such as lactic acid, tartaric acid, glycolic acid, citric acid and oxalic acid, or inorganic acids such as phosphoric acid and hydrochloric acid may be used.

【0009】本発明の染毛料の(e)成分であるN−メ
チル−ピロリドンは染毛促進剤及び粘度安定剤として用
いられている。上記N−メチル−ピロリドンの含有量に
1.0〜10.0重量%、好ましくは2.0〜7.0重
量%である。1.0重量%以下では安定性に乏しく、1
0.0重量%以上では効果の増強がないからである。ま
た本発明の染毛料には系の安定性、pH値を損なわない
範囲であれば前記の必須成分の他に、低級アルコール、
多価アルコール、防腐剤、キレート剤、紫外線吸収剤、
香料等を適宜配合することができる。本発明の染毛料を
用いて毛髪等の角質繊維の染色を実施するには、例えば
本発明の染毛料を角質繊維に15〜50℃で適用し、1
〜30分前後の作用時間をおいた後、角質繊維を洗浄し
乾燥すればよい。
N-methyl-pyrrolidone, which is the component (e) of the hair dye of the present invention, is used as a hair dye accelerator and a viscosity stabilizer. The content of N-methyl-pyrrolidone is 1.0 to 10.0% by weight, preferably 2.0 to 7.0% by weight. If it is less than 1.0% by weight, the stability is poor and 1
This is because the effect is not enhanced when the content is 0.0% by weight or more. In the hair dye of the present invention, in addition to the above essential components, a lower alcohol, as long as the stability of the system and the pH value are not impaired,
Polyhydric alcohol, preservative, chelating agent, ultraviolet absorber,
A fragrance or the like can be appropriately mixed. To carry out dyeing of keratinous fibers such as hair using the hair dyeing agent of the present invention, for example, applying the hair dyeing agent of the present invention to keratinous fibers at 15 to 50 ° C.
After a working time of about 30 minutes, the keratinous fibers may be washed and dried.

【0010】[0010]

【実施例】以下に 実施例を挙げ、本発明を更に詳細に
説明する。下記組成からなる混合物のpHをリン酸で
2.0に調整して染毛料を得た。これらの染毛料それぞ
れについて、白髪混じりの人毛に塗布し、常温で10分
間放置した後、毛髪を通常のシャンプーで洗浄し、乾燥
して染毛性及び処理した毛髪のしなやかさを官能評価し
た。又、これら染毛料を40゜保温器に3ヶ月放置した
後の安定性についても評価した。 以下余白
EXAMPLES The present invention will be described in more detail with reference to the following examples. The pH of the mixture having the following composition was adjusted to 2.0 with phosphoric acid to obtain a hair dye. Each of these hair dyes was applied to human hair mixed with white hair, allowed to stand at room temperature for 10 minutes, washed with a normal shampoo, dried, and subjected to a sensory evaluation of hair dyeability and suppleness of treated hair. . Further, the stability of these hair dyes after being left in a 40 ° incubator for 3 months was also evaluated. Margin below

【表1】 ◎;非常に良い、 ○;よい、 △;普通、 ×;悪い [Table 1] ◎: Very good, ○: Good, △: Normal, ×: Bad

【表2】 [Table 2]

【0011】 実施例7 (重量%) 紫色401号 0.7 橙色205号 0.2 赤色204号 0.01 黒色401号 0.03 キサンタンガム 0.4 ベントナイト 5.0 ベンジルアルコール 5.0 N−メチル−ピロリドン 3.0 水 バランス 香料 微量 上記組成からなる染毛料のpHをリン酸で、1.5に調
整して、ブラウン系染毛料を得た。このブラウン系染毛
料を用いて染毛したところ、染毛性及び染め上がりの毛
髪の感触の何れも良好であった。又、40゜保温器にお
いても3ヶ月間良好であつた。
Example 7 (wt%) Purple No. 401 0.7 Orange No. 205 0.2 Red No. 204 0.01 Black No. 401 0.03 Xanthan gum 0.4 Bentonite 5.0 Benzyl alcohol 5.0 N-methyl -Pyrrolidone 3.0 Water Balance Fragrance Trace amount The pH of the hair dye having the above composition was adjusted to 1.5 with phosphoric acid to obtain a brown hair dye. When hair was dyed using this brown hair dye, both the dyeability and the feel of the dyed hair were good. Also, the 40 ° incubator was good for 3 months.

【0012】[0012]

【発明の効果】本発明の染毛料は、ベース状態がなめら
かで色調のバリエーションがあって、染色性に優れ、且
つ毛髪に良好な感触を付与し、しかも飛躍的に安定性の
高いものである。
EFFECTS OF THE INVENTION The hair dye of the present invention has a smooth base and variations in color tone, is excellent in dyeability, imparts a good feel to the hair, and is extremely highly stable. .

───────────────────────────────────────────────────── フロントページの続き (72)発明者 北原 路朗 名古屋市西区鳥見町2丁目130番地 日本 メナード化粧品株式会社中央研究所内 (72)発明者 中田 悟 名古屋市西区鳥見町2丁目130番地 日本 メナード化粧品株式会社中央研究所内 ─────────────────────────────────────────────────── ─── Continuation of front page (72) Inventor Miro Kitahara 2-130 Torimi-cho, Nishi-ku, Nagoya City Central Research Institute, Menard Cosmetics Co., Ltd. (72) Satoru Nakata 2-130 Torimi-cho, Nishi-ku, Nagoya Japan Menard Central Research Institute of Cosmetics Co., Ltd.

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】(a)水溶性高分子0.1〜1.5重量
%、(b)酸性染料0.02〜2.0重量%、(c)ベ
ントナイト3.0〜10.0重量%、(d)ベンジルア
ルコール1.0〜15.0重量%、(e)Nーメチルー
ピロリドン1.0〜10.0重量% を含有し、pHを
1.0〜3.0に調整したことを特徴とする染毛料。
1. A water-soluble polymer 0.1 to 1.5% by weight, (b) an acid dye 0.02 to 2.0% by weight, and (c) bentonite 3.0 to 10.0% by weight. , (D) benzyl alcohol 1.0 to 15.0% by weight, (e) N-methyl-pyrrolidone 1.0 to 10.0% by weight, and the pH was adjusted to 1.0 to 3.0. A hair dye.
【請求項2】(a)キサンタンガム0.3〜1.0重量
%、(b)酸性染料0.1〜1.0重量%、(c)ベン
トナイト4.0〜8.0重量%、(d)ベンジルアルコ
ール1.0〜10.0重量%(e)Nーメチルーピロリ
ドン2.0〜7.0重量%を含有しpHを1.0〜2.
5に調整したことを特徴とする染毛料。
2. (a) Xanthan gum 0.3 to 1.0% by weight, (b) acid dye 0.1 to 1.0% by weight, (c) bentonite 4.0 to 8.0% by weight, (d) ) Benzyl alcohol 1.0-10.0% by weight (e) N-methyl-pyrrolidone 2.0-7.0% by weight and pH 1.0-2.
A hair dye that is adjusted to 5.
JP16682095A 1995-06-07 1995-06-07 Hair dye Expired - Fee Related JP3589745B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP16682095A JP3589745B2 (en) 1995-06-07 1995-06-07 Hair dye

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP16682095A JP3589745B2 (en) 1995-06-07 1995-06-07 Hair dye

Publications (2)

Publication Number Publication Date
JPH08333224A true JPH08333224A (en) 1996-12-17
JP3589745B2 JP3589745B2 (en) 2004-11-17

Family

ID=15838277

Family Applications (1)

Application Number Title Priority Date Filing Date
JP16682095A Expired - Fee Related JP3589745B2 (en) 1995-06-07 1995-06-07 Hair dye

Country Status (1)

Country Link
JP (1) JP3589745B2 (en)

Cited By (10)

* Cited by examiner, † Cited by third party
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WO1998015256A1 (en) * 1996-10-08 1998-04-16 Kao Corporation Hairtreatment composition
JP2004535409A (en) * 2001-05-29 2004-11-25 アヴェダ コーポレーション Semi-permanent hair dyeing system using vat dye
US9339451B2 (en) 2013-08-23 2016-05-17 The Procter & Gamble Company Hair colouring methods and kits thereof
US9339666B2 (en) 2013-08-23 2016-05-17 The Procter & Gamble Company Hair colouring methods and kits thereof
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JP2004535409A (en) * 2001-05-29 2004-11-25 アヴェダ コーポレーション Semi-permanent hair dyeing system using vat dye
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