JPH08325697A - Hot-dip plated ferritic stainless steel sheet excellent in bending workability and its production - Google Patents

Hot-dip plated ferritic stainless steel sheet excellent in bending workability and its production

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Publication number
JPH08325697A
JPH08325697A JP13688895A JP13688895A JPH08325697A JP H08325697 A JPH08325697 A JP H08325697A JP 13688895 A JP13688895 A JP 13688895A JP 13688895 A JP13688895 A JP 13688895A JP H08325697 A JPH08325697 A JP H08325697A
Authority
JP
Japan
Prior art keywords
hot
plated
dip
alloy layer
stainless steel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP13688895A
Other languages
Japanese (ja)
Other versions
JP3202539B2 (en
Inventor
Tetsuya Shimada
鉄也 島田
Keiichi Omura
圭一 大村
Hidehiko Sumitomo
秀彦 住友
Hiroyuki Hiramatsu
博之 平松
Kazuhiro Tano
和広 田野
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Nippon Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Steel Corp filed Critical Nippon Steel Corp
Priority to JP13688895A priority Critical patent/JP3202539B2/en
Publication of JPH08325697A publication Critical patent/JPH08325697A/en
Application granted granted Critical
Publication of JP3202539B2 publication Critical patent/JP3202539B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Abstract

PURPOSE: To produce a hot-dip plated ferritic stainless steel excellent in bending workability. CONSTITUTION: A hot-dip plated steel sheet in which an alloy layer present on the boundary between a ferritic stainless steel as a base material contg., by weight, <=0.08% C, <=1% Si, <=1% Mn, 11 to 25% Cr and <=0.03% N and furthermore contg. one or >= two kinds among <=1.5% Nb, <=0.5% Ti, <=2.5% Mo and <=0.5% Cu and a hot-dip plating layer is present by >=60% area ratio is subjected to one or, combinedly, >= two kinds among skinpass rolling of >=0.5% draft, bending type leveller straightening with a roll of <=100mm radius and tension type leveller straightening of >=0.2% elongation percentage, by which fine cracks are made present by >=90 lines/mm over the whole thickness of the alloy layer.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、建築外装材、自動車部
材等、曲げ加工や比較的軽度のプレス加工を受ける用途
に適用される溶融めっきフェライト系ステンレス鋼板お
よびその製造法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hot-dip ferritic stainless steel sheet and its manufacturing method, which are applied to building exterior materials, automobile members, etc., which are subject to bending and relatively light pressing.

【0002】[0002]

【従来の技術】Al系やZn系の溶融めっきを施したフ
ェライト系ステンレス鋼板は、その優れた耐食性、耐候
性に加え、外観の美麗さや色調、防眩性等いわゆる意匠
性の上でも種々の表面を比較的容易に提供できることか
ら、近年外装用建材を主としてその適用範囲が急速に広
まりつつある。
2. Description of the Related Art Ferrite-based stainless steel sheets that have been hot-dipped with Al or Zn are not only excellent in corrosion resistance and weather resistance but also have various appearances such as appearance, color tone and antiglare property. Since the surface can be provided relatively easily, the range of its application is expanding rapidly mainly in exterior building materials in recent years.

【0003】ステンレス鋼の表面はいわゆる不動態皮膜
で覆われているために、また溶融めっきを施す際の製造
工程内における加熱処理によって生成する表面酸化皮膜
のために、一般に溶融めっきした場合のめっき密着性の
確保や点状のめっき欠陥の回避が難しく、従来この点を
改良し健全な溶融めっき鋼板を製造するためのさまざま
な工夫が提案されてきた。
The surface of stainless steel is covered with a so-called passive film, and because of the surface oxide film formed by the heat treatment in the manufacturing process during hot dipping, the plating used in hot dipping is generally used. It is difficult to secure adhesion and avoid spot-like plating defects, and various ideas have been proposed to improve this point and manufacture sound hot-dip steel sheets.

【0004】例えば、Cr含有鋼の溶融めっき密着性の
改善手段として、特開昭60−262950号公報、特
開昭61−147865号公報には予めNiを電気めっ
きすることでその後の溶融めっき層の健全性を確保する
技術が、また特開昭64−28351号公報には同様の
目的でFe−B合金をプレめっきする技術が開示されて
いる。さらには、特開平2−250948号、特開平3
−28358号、特開平3−28359号、特開平3−
36250号、特開平3−56654号、特開平3−6
4437号、特開平3−64438号及び特開平3−6
4439号の各公報にはいずれもCr含有鋼の溶融めっ
きに際し、工程中の加熱処理時に生成する表面酸化物の
還元をより容易にし、かつめっき金属と母材との間に形
成する脆弱な合金層の厚さを減ずることで、曲げ加工時
のめっき密着性を改善しようとする技術が開示されてい
る。
[0004] For example, as means for improving the hot-dip plating adhesion of Cr-containing steel, JP-A-60-262950 and JP-A-61-147865 disclose electroplating of Ni in advance to form a hot-dip plated layer thereafter. Japanese Patent Application Laid-Open No. 64-28351 discloses a technique for pre-plating Fe—B alloy for the same purpose. Furthermore, JP-A-2-250948 and JP-A-3-250948
-28358, JP-A-3-28359, and JP-A-3-28359
36250, JP-A-3-56654, JP-A-3-6.
4437, JP-A-3-64438, and JP-A-3-6.
No. 4439 discloses a fragile alloy that facilitates reduction of surface oxides generated during heat treatment during the process during hot-dip plating of Cr-containing steel and forms between the plated metal and the base metal. A technique has been disclosed that attempts to improve plating adhesion during bending by reducing the layer thickness.

【0005】[0005]

【発明が解決しようとする課題】しかしながら、こうし
ためっき密着性や溶融めっき鋼板としての加工性が改善
された溶融めっきフェライト系ステンレス鋼板にあって
も、曲げ加工された場合、基材のフェライト系ステンレ
ス鋼板が劈開破面を呈する脆性割れが発生するという問
題がある。
However, even in the hot-dip ferritic stainless steel sheet having improved plating adhesion and workability as a hot-dipped steel sheet, when it is bent, the ferritic stainless steel of the substrate is used. There is a problem that brittle cracking occurs in which the steel sheet exhibits a cleavage fracture surface.

【0006】ことに、近年のように種々の排気ガスや煤
煙等による大気腐食環境が厳しくなりつつある状況下で
は、溶融めっき鋼板の基材自体の耐錆性、耐候性をより
優れたものとする必要性から、基材のCr量の増加や、
Mo,Nb等の元素が添加された、より高合金が使用さ
れるようになってきており、その分必然的に加工性が低
下するため、こうした溶融めっきフェライト系ステンレ
ス鋼は加工割れが発生し易いものとなる。
In particular, under recent circumstances where the atmospheric corrosion environment due to various exhaust gases, soot and the like is becoming severe, the base material itself of the hot dip plated steel sheet is expected to have better rust resistance and weather resistance. To increase the Cr content of the base material,
Higher alloys to which elements such as Mo and Nb have been added have come to be used, and the workability inevitably decreases by that amount. Therefore, such hot-dip ferritic stainless steel causes work cracking. It will be easy.

【0007】さらに、建築外装材の中で特に溶融めっき
フェライト系ステンレス鋼板の用途として急速に適用が
拡大しつつある屋根材では、より長尺の部材が施工上も
有利であることから、その加工は素材の長手方向に連続
的に施すロールフォーミングが主流であり、曲げ形状が
比較的複雑で局部的な曲げ半径が板厚と同等程度の厳し
いものが多くかつその加工速度も比較的速いことから、
溶融めっきフェライト系ステンレス鋼板の加工割れが発
生し易い状況となっている。
Further, in the roofing material, which is rapidly expanding its application as a material for hot-dip ferritic stainless steel sheet among building exterior materials, a longer member is advantageous in construction. The mainstream is roll forming, which is performed continuously in the longitudinal direction of the material, and the bending shape is relatively complicated and the local bending radius is often as severe as the plate thickness, and the processing speed is also relatively high. ,
Work cracking of hot dip ferritic stainless steel sheets is likely to occur.

【0008】このような加工割れについて、例えば溶融
Alめっきフェライト系ステンレス鋼板の場合をみる
と、基材とめっき層の境界部には、脆弱な合金層を形成
するが、この合金層が厚くなり過ぎると加工の際に容易
に割れを発生し、めっき層の破断を誘発することが知ら
れており、このことから合金層の過度な成長を抑える作
用を有するSiが10wt%程度Al浴に添加され、Al
−Fe−Siを主成分とする合金層を3μm程度の厚さ
に止めることが通常行われている。しかし、この合金層
は非常に硬くかつ脆いので、厳しい加工が行われる際に
は割れが入ることが避けられない。一方で、この合金層
が存在しない場合には加工部のめっき層の密着性に問題
があり、例えば平板の状態で実施されるいわゆるボール
インパクトテスト等のめっき剥離テストでは不具合がな
くとも、曲げ加工後の特に外側表面のテープ剥離テスト
では容易にめっき剥離が認められるようになる。
Regarding such work cracking, for example, in the case of hot-dip Al-plated ferritic stainless steel sheet, a fragile alloy layer is formed at the boundary between the base material and the plating layer, but this alloy layer becomes thicker. It is known that if it is too much, cracks easily occur during processing to induce fracture of the plating layer. From this fact, Si having an action of suppressing excessive growth of the alloy layer is added to the Al bath at about 10 wt%. And Al
It is usual to stop the alloy layer containing -Fe-Si as a main component to have a thickness of about 3 [mu] m. However, since this alloy layer is extremely hard and brittle, cracking is inevitable when severe working is performed. On the other hand, if this alloy layer does not exist, there is a problem with the adhesion of the plated layer in the processed part, for example, even if there is no problem in the plating peeling test such as the so-called ball impact test performed in the state of a flat plate, the bending process Subsequent tape peeling tests, especially on the outer surface, allow easy peeling of the plating.

【0009】しかしながら、こうした曲げ後のめっき密
着性の悪いものにあっては、基材ステンレスにまで達す
る割れは発生しないことが明らかとなった。すなわち、
溶融めっきフェライト系ステンレス鋼板における合金層
は、加工部のめっき密着性の確保の上では有用であるも
のの、加工割れを誘発する起点となり易いという有害な
作用を併せ持つのである。
However, it has become clear that cracks that reach the base material stainless steel do not occur in such a material having poor plating adhesion after bending. That is,
Although the alloy layer in the hot-dip ferritic stainless steel sheet is useful for ensuring the plating adhesion of the worked part, it also has a harmful effect that it tends to become a starting point for inducing work cracking.

【0010】さらに、本発明者らの検討によれば、こう
した溶融めっきフェライト系ステンレス鋼板の曲げ加工
において基材にまで割れが発生する場合には、まず、一
旦合金層に脆性的な割れが発生し、そこが起点となって
めっき層および基材ステンレス層内に伝播するのである
が、この際とくに基材側に伝播する割れは、その初期に
おいて脆性破面を呈するものであることが明らかとなっ
た。さらに、一般に曲げ加工性の改善には延性の改善が
有効とされているが、溶融めっきフェライト系ステンレ
ス鋼板にあっては、基材の延性を改善しただけでは上記
のような、合金層を起点として基材内部への脆性破壊の
進展を抑えることが困難であることが判明した。すなわ
ち、溶融めっきフェライト系ステンレス鋼板の曲げ性改
善のためには、従来知見による延性向上対策とは異な
る、新しい知見に基づいた改善が必要である。
Further, according to the study by the present inventors, when a crack occurs even in the base material during bending of such a hot-dip ferritic stainless steel sheet, first, a brittle crack occurs in the alloy layer. Then, there is a starting point and it propagates into the plating layer and the base material stainless steel layer. At this time, it is clear that the cracks that particularly propagate to the base material side are brittle fracture surfaces at the initial stage. became. In addition, it is generally said that improvement of ductility is effective for improving bending workability, but in the case of hot dip ferritic stainless steel sheet, just improving the ductility of the base material causes the alloy layer to start as described above. It was found that it was difficult to suppress the progress of brittle fracture inside the substrate. That is, in order to improve the bendability of the hot-dip ferritic stainless steel sheet, it is necessary to make an improvement based on new knowledge, which is different from the ductility improvement measures based on the conventional knowledge.

【0011】本発明は、上記のような状況に鑑み、ロー
ルフォーミングの如き比較的速い加工速度で曲げ半径が
板厚程度の厳しい曲げ加工を連続的に施した場合でも、
加工割れが発生せずかつ曲げ加工部のめっき密着性にも
優れた溶融めっきフェライト系ステンレス鋼板を提供す
ることを目的とするものである。
In view of the above situation, the present invention provides a continuous bending process such as roll forming at a relatively high processing speed with a bending radius of about the plate thickness.
An object of the present invention is to provide a hot-dip ferritic stainless steel sheet which is free from work cracking and has excellent plating adhesion in a bent part.

【0012】[0012]

【課題を解決するための手段】本発明は、上述したよう
に従来の考え方とは異なる新しい知見に基づいてなされ
たもので、フェライト系ステンレス鋼板にAlあるいは
Zn等のいわゆる溶融めっきを施した際にめっき層と基
材ステンレス鋼板との境界部に形成する硬質かつ脆弱な
合金層内に微細な亀裂がある一定以上の頻度で存在した
ものでは、曲げ加工によって発生する応力が、合金層内
に存在する微細亀裂が開口することで解放されるため
に、基材内部への脆性的な亀裂の伝播が必然的に回避さ
れることとなり、従って、溶融フェライト系ステンレス
鋼板として、その合金層内に一定の頻度以上の微小亀裂
を含むものは、厳しい曲げ加工を受けても基材ステンレ
スに割れが発生し難く、まためっき層の割れも最少に維
持できるのみならず、めっき層の密着性も良好という優
れた特性を具備することを知見し、完成したものであ
る。
The present invention has been made on the basis of a new finding that is different from the conventional idea as described above. When a ferritic stainless steel plate is subjected to so-called hot dip plating such as Al or Zn. In the hard and brittle alloy layer formed at the boundary between the plating layer and the base material stainless steel plate, there are fine cracks at a certain frequency or more, and the stress generated by bending is generated in the alloy layer. Since the existing microcracks are released by opening, the propagation of brittle cracks inside the base material is inevitably avoided, and therefore, as a molten ferritic stainless steel sheet, in its alloy layer. Those that contain microcracks of a certain frequency or more are less likely to cause cracks in the base stainless steel even when subjected to severe bending, and not only can cracks in the plating layer be kept to a minimum Adhesiveness of the plating layer was found that having a good property of good, has been completed.

【0013】すなわち本発明は、フェライト系ステンレ
ス被めっき鋼板表面と溶融めっき層との境界面に、前記
ステンレス鋼と溶融めっき金属との合金層が存在し、か
つ前記合金層中に亀裂を有することを特徴とする曲げ加
工性に優れた溶融めっきフェライト系ステンレス鋼板お
よびその製造法を要旨とする。
That is, according to the present invention, an alloy layer of the stainless steel and the hot dip plated metal is present at the interface between the surface of the ferritic stainless steel plated steel sheet and the hot dip plated layer, and cracks are present in the alloy layer. The gist is a hot-dip ferritic stainless steel sheet excellent in bending workability and a method for producing the same.

【0014】すなわち具体的には、フェライト系ステン
レス被めっき鋼板と溶融めっき層との境界面に、前記ス
テンレス鋼と溶融めっき金属との合金層が面積率で少な
くとも60%以上存在し、かつめっき鋼板表面に垂直な
任意の断面から見て前記合金層厚みの50%以上の長さ
を有する微細な亀裂を被めっき鋼板表面に平行な長さ1
mm当たり50本以上前記合金層中に有することを特徴と
する曲げ加工性に優れた溶融めっきフェライト系ステン
レス鋼板であり、また、フェライト系ステンレス被めっ
き鋼板と溶融めっき層との境界面に、前記ステンレス鋼
と溶融めっき金属との合金層が面積率で少なくとも60
%以上存在し、必要に応じて350〜400℃の温度に
5時間以上保定した後、被めっき鋼板と溶融めっき金属
との合金層に、最大伸び率0.1%以上を加えることに
よって、めっき鋼板表面に垂直な任意の断面から見て前
記合金層厚みの50%以上の長さを有する微細な亀裂を
被めっき鋼板表面に平行な長さ1mm当たり50本以上前
記合金層中に存在させることを特徴とする曲げ加工性に
優れた溶融めっきフェライト系ステンレス鋼板の製造法
である。
That is, specifically, the alloy layer of the stainless steel and the hot dip plated metal is present at an area ratio of at least 60% or more on the boundary surface between the ferritic stainless steel plated steel sheet and the hot dip plated layer, and the galvanized steel sheet is formed. A length 1 parallel to the surface of the steel sheet to be plated with fine cracks having a length of 50% or more of the thickness of the alloy layer when viewed from an arbitrary cross section perpendicular to the surface 1
It is a hot-dip ferritic stainless steel sheet having excellent bending workability, characterized in that it has 50 or more pieces per mm in the alloy layer, and further, at the interface between the ferritic stainless steel-plated steel sheet and the hot-dip layer, The area ratio of the alloy layer of stainless steel and hot dip metal is at least 60
% Or more, if necessary, after holding at a temperature of 350 to 400 ° C. for 5 hours or more, the maximum elongation rate of 0.1% or more is added to the alloy layer of the steel sheet to be plated and the hot dip plated metal, thereby plating. Presence of 50 or more fine cracks having a length of 50% or more of the alloy layer thickness in the alloy layer parallel to the surface of the steel sheet to be plated per 1 mm length viewed from an arbitrary cross section perpendicular to the steel sheet surface. Is a method for producing a hot dip ferritic stainless steel sheet having excellent bending workability.

【0015】上記方法において、最大伸び率0.1%以
上を加える手段として、スキンパス圧延、半径100mm
以下のロールを1本以上通過させるベンディング型レベ
ラー矯正、テンション型レベラー矯正の何れかまたは2
種以上を施すことができる。また、上記フェライト系ス
テンレス鋼板は重量%でC :0.08%以下、
Si:1.0%以下、Mn:1.0%以下、
Cr:11〜25%、N :0.03%以下を含有
し、さらに必要に応じてNb:1.5%以下、
Ti:0.5%以下、Mo:2.5%以下、
Cu:0.5%以下の1種または2種以上を含有し、
残部がFeおよび不可避不純物からなることを特徴とす
る。また溶融めっき金属としてはZnを主成分とする金
属、またはAlを主成分とする金属とすることができ
る。
In the above method, as a means for adding a maximum elongation of 0.1% or more, skin pass rolling, radius 100 mm
Either a bending type leveler straightening or a tension type leveler straightening that allows one or more of the following rolls to pass, or 2
More than one seed can be applied. Further, the above ferritic stainless steel sheet has a weight percentage of C: 0.08% or less,
Si: 1.0% or less, Mn: 1.0% or less,
Cr: 11 to 25%, N: 0.03% or less, and if necessary, Nb: 1.5% or less,
Ti: 0.5% or less, Mo: 2.5% or less,
Cu: Contains one or more of 0.5% or less,
The balance is Fe and unavoidable impurities. The hot-dip metal may be a metal containing Zn as a main component or a metal containing Al as a main component.

【0016】[0016]

【作用】次に、本発明についてさらに詳細に説明する。
まず、本発明にいう溶融めっきフェライト系ステンレス
鋼にあっては、溶融めっき層と被めっきステンレス鋼板
との境界部に形成される合金層は、面積率で60%以上
存在することが必要である。これよりも少ない場合には
曲げ加工性によってめっき層が容易に剥離する可能性が
著しく高くなる。合金層は、通常の光学顕微鏡による金
属断面組織観察手法によって200倍程度でその有無を
充分確認できるものである。本発明にいう合金層の面積
率とは鋼板表面に垂直な任意の断面を200倍の視野に
て少なくとも20視野以上観察した結果から決定したも
のであり、観察視野内の鋼板表面に平行な長さ当たりに
合金層が存在する長さの割合のことである。
Next, the present invention will be described in more detail.
First, in the hot-dip ferritic stainless steel according to the present invention, the alloy layer formed at the boundary between the hot-dip layer and the stainless steel plate to be plated needs to be present in an area ratio of 60% or more. . When the amount is less than this, the possibility that the plating layer is easily peeled off due to bending workability becomes extremely high. The presence or absence of the alloy layer can be sufficiently confirmed at a magnification of about 200 by a method for observing a metal cross-section structure with a usual optical microscope. The area ratio of the alloy layer referred to in the present invention is determined from the result of observing an arbitrary cross section perpendicular to the steel plate surface in a visual field of 200 times at least 20 visual fields, and a length parallel to the steel plate surface in the observing visual field. It is the ratio of the length where the alloy layer exists.

【0017】一方、合金層が面積率で60%以上存在す
る場合めっき層の密着性は確保されるけれども、一般に
合金層は非常に脆弱であるため、曲げ加工された場合に
はこの合金層から脆性的な割れが発生し、被めっきステ
ンレス鋼板内部やめっき層へ伝播して、被めっき鋼板自
体の割れやめっき層の割れの原因となる。これを抑える
ためには合金層自体に予め微細な亀裂をある頻度以上で
発生させておくことが重要であることがわかった。すな
わち、種々検討の結果、めっき鋼板表面に垂直な断面観
察した場合鋼板表面に平行な長さ1mm当たり50本以上
が必要でる。これ以下の頻度では、例えば90゜曲げを
行なう場合、被めっきステンレス鋼板表面に割れが発生
する可能性が著しく高くなる。さらに、180゜曲げや
加工速度の速い厳しい加工を施す場合には、微細な亀裂
を長さ1mm当たり90本以上とすることが好ましい。
On the other hand, when the area ratio of the alloy layer is 60% or more, the adhesion of the plating layer is secured, but since the alloy layer is generally very fragile, when it is bent, Brittle cracks are generated and propagate inside the stainless steel plate to be plated or to the plating layer, causing cracks in the steel plate to be plated itself or cracks in the plating layer. In order to suppress this, it has been found that it is important to previously generate fine cracks in the alloy layer itself at a certain frequency or more. That is, as a result of various studies, when observing a cross section perpendicular to the surface of the plated steel sheet, 50 or more pieces are required per 1 mm in length parallel to the surface of the steel sheet. If the frequency is less than this, for example, when 90 ° bending is performed, the possibility that cracks will occur on the surface of the stainless steel plate to be plated becomes extremely high. Furthermore, in the case of 180 ° bending or severe processing with a high processing speed, it is preferable that the number of fine cracks be 90 or more per 1 mm in length.

【0018】なお、ここでいう合金層中の微細な亀裂と
は、図1の模式図に示すように、合金層厚みの50%以
上の長さを有し、通常の光学顕微鏡による金属断面組織
観察手法によって200倍程度で充分確認できるもので
あり、本発明にいう長さ1mm当たり50本とは200倍
の視野にて少なくとも20視野以上観察した結果から決
定したものである。合金層中の亀裂の長さが合金層厚み
の50%未満の亀裂も含めて1mm当たり50本以上とし
ても、曲げ加工によって被めっきステンレス鋼板に割れ
が生ずることがあることから、亀裂の長さは合金層厚み
の50%以上とした。
The fine cracks in the alloy layer mentioned here have a length of 50% or more of the thickness of the alloy layer, as shown in the schematic view of FIG. It can be sufficiently confirmed by an observing method at about 200 times, and "50 lines per 1 mm in length" in the present invention is determined from the result of observing at least 20 fields in the field of view of 200 times. Even if the crack length in the alloy layer is 50 or more per 1 mm including cracks less than 50% of the alloy layer thickness, cracking may occur in the plated stainless steel sheet due to bending, so the crack length Is 50% or more of the alloy layer thickness.

【0019】次に、被めっきステンレス鋼の成分の限定
理由について述べる。Cはフェライト系ステンレス鋼の
靭性を低下させる元素であり、本発明の場合0.08wt
%がその上限となる。この範囲を超えてCが含有される
溶融めっきフェライト系ステンレス鋼板にあっては、例
え合金層中の微小亀裂の存在頻度が90本/mm以上あっ
ても基材靭性が劣るため曲げ加工時に割れが発生し易く
なる。NもCと全く同様の理由でその上限は0.03wt
%となる。
Next, the reasons for limiting the components of the plated stainless steel will be described. C is an element that reduces the toughness of ferritic stainless steel, and in the case of the present invention, it is 0.08 wt.
% Is the upper limit. In hot-dip ferritic stainless steel sheets containing C in excess of this range, even if the frequency of microcracks in the alloy layer is 90 cracks / mm or more, the toughness of the base material is poor and cracking occurs during bending. Is likely to occur. The upper limit of N is 0.03wt for exactly the same reason as C.
%.

【0020】Siは、過剰に含有すると冷間での加工性
を著しく損なうばかりでなく、ホットコイルの靭性をも
低下させ、基材自体の製造性を低下させるため1.0wt
%以下とする。Mnは、脱酸剤およびSの粒界への偏析
抑制に有効な元素であるが、過剰添加は素材の延性を低
下させるため1.0wt%以下とする。
If Si is contained excessively, not only the workability in cold is significantly impaired, but also the toughness of the hot coil is deteriorated and the manufacturability of the base material itself is deteriorated.
% Or less. Mn is an element effective in suppressing the segregation of the deoxidizer and S to the grain boundaries, but excessive addition thereof lowers the ductility of the raw material, so Mn is made 1.0 wt% or less.

【0021】Crはステンレス鋼にあっては、その耐食
性の上で必須の基本添加元素である。この意味から下限
は11wt%となる。一方、その含有量に応じてステンレ
ス鋼としての耐食性は向上するが25%を超えて添加さ
れても、その耐食性向上効果が飽和し、曲げ加工性は著
しく劣化するため、本発明にあっては25wt%をその上
限とする。
In stainless steel, Cr is a basic additive element essential for its corrosion resistance. From this meaning, the lower limit is 11 wt%. On the other hand, the corrosion resistance as stainless steel is improved depending on its content, but even if it is added in excess of 25%, its corrosion resistance improving effect is saturated and bending workability is significantly deteriorated. The upper limit is 25 wt%.

【0022】Nbは一般には溶接部の耐食性特に耐粒界
腐食性の確保、素材結晶粒の粗大化抑制、素材の強化に
有効な添加元素であり、フェライト系ステンレス鋼にあ
ってもこれらの目的で添加される場合が多い。本発明に
あっては、特に基材のフェライト系ステンレス鋼板の製
造性確保の点からホットコイル段階における靭性向上の
目的で、また製品板での加工性や強度確保の点から結晶
粒粗大化抑制の目的で、さらには溶接部耐食性確保のた
めに選択的に添加することができる。しかし、1.5wt
%を超えて添加するとこれらの効果は飽和するばかりで
なく、基材ステンレス鋼板の靭性を著しく劣化させるこ
とから、1.5wt%を上限とした。
Nb is an additive element which is generally effective for ensuring the corrosion resistance of welds, especially the intergranular corrosion resistance, suppressing the coarsening of material crystal grains, and strengthening the material. Even for ferritic stainless steel, Nb is used for these purposes. Often added in. In the present invention, especially in order to improve the toughness in the hot coil stage from the viewpoint of ensuring the manufacturability of the base material ferritic stainless steel sheet, and from the viewpoint of ensuring workability and strength in the product plate, suppression of crystal grain coarsening For the purpose of, and further for ensuring the corrosion resistance of the welded portion, it can be selectively added. However, 1.5wt
If added in excess of%, not only these effects will be saturated, but also the toughness of the base stainless steel sheet will be significantly deteriorated, so 1.5 wt% was made the upper limit.

【0023】TiはNbと同様の目的で本発明にあって
は選択的に添加することができる。しかし、0.5wt%
を超えて添加してもこれらの効果は飽和し、いたずらに
合金コストを上昇させることから、上限を0.5wt%と
した。
In the present invention, Ti can be selectively added for the same purpose as Nb. However, 0.5 wt%
Even if added in excess, the effects are saturated and the alloy cost is unnecessarily increased, so the upper limit was made 0.5 wt%.

【0024】Moは、耐食性向上に有効な元素で、特に
Cr添加だけでは得られない局部腐食に対する抵抗力を
向上させる効果が大きいため、耐候性ステンレス鋼にあ
っては広く使用されており、本発明のような溶融めっき
フェライト系ステンレス鋼板の主たる利用目的からMo
についても選択的に添加できる。しかし、2.5wt%を
超えて添加しても、これらの効果は飽和し、いたずらに
合金コストを増大させることから、2.5wt%を上限と
した。
Mo is an element effective for improving the corrosion resistance, and since it has a great effect of improving the resistance to local corrosion that cannot be obtained only by adding Cr, it is widely used in weather-resistant stainless steel. From the main purpose of using hot-dip ferritic stainless steel sheet as in the invention, Mo
Can also be selectively added. However, even if added in excess of 2.5 wt%, these effects saturate and unnecessarily increase the alloy cost, so 2.5 wt% was made the upper limit.

【0025】CuはMoと同様の目的で本発明にあって
は選択的に添加することができる。しかし、0.5wt%
を超えて添加するとこれらの効果は飽和するばかりでは
なく、基材ステンレス鋼板の靭性を著しく劣化させるこ
とから、0.5wt%を上限とした。
Cu can be selectively added in the present invention for the same purpose as Mo. However, 0.5 wt%
If added in excess of 0.5 wt%, not only will these effects be saturated, but the toughness of the base stainless steel plate will be significantly deteriorated, so 0.5 wt% was made the upper limit.

【0026】なお、Nb,Ti,MoおよびCuについ
てはそれぞれ上述したとおり、本発明にあっては選択的
に添加できるものであるが、本発明の溶融めっきフェラ
イト系ステンレス鋼板が主としてその耐候性を利用する
ものであること、また複雑な形状に加工される場合がほ
とんどであることから、これらの4元素は少なくとも1
種以上含むことが好ましい。
As described above, Nb, Ti, Mo and Cu can be selectively added in the present invention, but the hot dip ferritic stainless steel sheet of the present invention mainly has the weather resistance. At least 1 of these 4 elements is used because they are used and are often processed into complicated shapes.
It is preferable to include one or more kinds.

【0027】溶融めっき処理後、350〜400℃の温
度に5時間以上保定することが好ましい。350℃以上
に加熱保持することによって、めっき合金層が軟化し、
めっき鋼板の加工性が向上することから、下限を350
℃とした。しかし、400℃を超えて加熱保持すると、
被めっきステンレス鋼原板が脆化し、逆に曲げ加工性が
著しく阻害されることから、400℃を上限とした。ま
た、加熱保定時間が、5時間未満では、めっき合金層が
十分に軟化せず、曲げ加工性が十分に向上しないことか
ら、5時間以上とした。
After the hot dipping treatment, the temperature is preferably kept at 350 to 400 ° C. for 5 hours or more. By heating and holding at 350 ° C or higher, the plating alloy layer softens,
Since the workability of the plated steel sheet is improved, the lower limit is set to 350
° C. However, if heated and held above 400 ° C,
Since the original stainless steel plate to be plated becomes brittle and conversely the bending workability is significantly impaired, 400 ° C. was set as the upper limit. In addition, when the heat retention time is less than 5 hours, the plating alloy layer is not sufficiently softened and the bending workability is not sufficiently improved, so the time was set to 5 hours or more.

【0028】次に、溶融めっきフェライト系ステンレス
鋼板の合金層に50本/mm以上の微細な亀裂を存在させ
るための手段の限定理由について述べる。被めっき鋼板
と溶融めっき金属との合金層に加える最大伸び率を0.
1%以上とした。ここで、最大伸び率とは、スキンパス
圧延、レベラー矯正などによって前記合金層の表裏面い
ずれかに直接加わる伸び変形率の最大値をいう。前記合
金層は、硬質で非常に脆弱であることから、わずかな最
大伸び率によっても容易に破砕される。0.1%以上の
最大伸び率によって合金層中の微細な亀裂を50本/mm
以上とすることが可能であることから、前記合金層に加
える最大伸び率の下限を0.1%とした。
Next, the reasons for limiting the means for making 50 cracks / mm or more of fine cracks exist in the alloy layer of the hot dip ferritic stainless steel sheet will be described. The maximum elongation to be added to the alloy layer of the steel sheet to be plated and the hot-dip metal is 0.
It was set to 1% or more. Here, the maximum elongation refers to the maximum value of the elongation deformation directly applied to either the front surface or the back surface of the alloy layer by skin pass rolling, leveler straightening, or the like. Since the alloy layer is hard and very brittle, it is easily crushed even with a small maximum elongation. 50 cracks / mm of fine cracks in the alloy layer due to the maximum elongation of 0.1% or more
Since it is possible to set the above, the lower limit of the maximum elongation added to the alloy layer is set to 0.1%.

【0029】また、前述したように合金層は被めっき鋼
板や溶融めっき金属に比べて硬質であることから、合金
層に0.1%以上の最大伸びを加える手段として、スキ
ンパス圧延、半径100mm以下のロールを1本以上通過
させるベンディング型レベラー矯正、テンション型レベ
ラー矯正の1種または2種以上を施すことが好ましい。
スキンパス圧延は、めっき合金層の微細分断に有効であ
ることから、圧下率を0.1%以上とすることが望まし
い。しかし、あまり圧下率が大きいと、加工硬化し、逆
に曲げ加工性が劣化することから、3.0%以下とする
ことが望ましい。レベラー矯正もめっき合金層の微細分
断に有効である。レベラー矯正を行なう場合、ベンディ
ング型レベラーとテンション型レベラーの2種類があ
る。ベンディング型レベラー矯正を行なう場合、ロール
半径が100mmを超えるものは、めっき合金層に十分な
曲げ変形が加わらず、最大伸び率0.1%以上とするこ
とが困難で、めっき合金層の微細分断に至らないため、
ロール半径は100mm以下とした。また、テンション型
レベラー矯正を行なう場合、伸び率が0.1%未満で
は、合金層に0.1%以上の最大伸び率が加わらず、め
っき合金層の微細分断に至らないので、伸び率は0.1
%以上であることが望ましい。
Further, as described above, the alloy layer is harder than the steel sheet to be plated or the hot dip plated metal, and therefore skin pass rolling, radius 100 mm or less is used as a means for adding maximum elongation of 0.1% or more to the alloy layer. It is preferable to perform one or more of bending-type leveler straightening and tension-type leveler straightening, in which one or more rolls of (1) are passed.
Since the skin pass rolling is effective in finely dividing the plated alloy layer, it is desirable that the rolling reduction is 0.1% or more. However, if the rolling reduction is too large, work hardening occurs and conversely bending workability deteriorates. Therefore, it is desirable to set it to 3.0% or less. Leveler straightening is also effective for fine division of the plated alloy layer. When performing leveler straightening, there are two types, a bending type leveler and a tension type leveler. When performing bending type leveler straightening, if the roll radius is more than 100 mm, it is difficult to achieve a maximum elongation of 0.1% or more without sufficient bending deformation of the plating alloy layer, resulting in fine fragmentation of the plating alloy layer. Because it does not reach
The roll radius was 100 mm or less. Further, when performing tension type leveler straightening, if the elongation percentage is less than 0.1%, the maximum elongation percentage of 0.1% or more is not added to the alloy layer, and the fine division of the plated alloy layer does not occur. 0.1
% Is desirable.

【0030】[0030]

【実施例】表1に示す化学成分を有するフェライト系ス
テンレス鋼の0.8mm厚の冷延焼鈍板を用いてAlある
いはZnの溶融めっきフェライト系ステンレス鋼板を製
造した。その後、この溶融めっきフェライト系ステンレ
ス鋼板に表2に示す熱処理あるいはレベラー矯正、スキ
ンパス圧延を施して、t/2−90゜,180゜曲げを
行い、曲げ面の割れの有無を評価した。この結果を表2
に併せて示した。曲げ面の観察評価は、Al系のめっき
ではNaOHの濃厚水溶液でめっき金属層をさらにりん
酸水溶液でめっき合金層を溶解した後、またZn系のめ
っきでは硝酸水溶液でめっき金属層をさらにりん酸水溶
液でめっき合金層を溶解した後、肉眼で行なった。割れ
の評価は、全く割れのないものを評点1、逆に2枚に分
離するほどの割れは評点5とし、その間を官能的に3段
階に分類評価した。
EXAMPLE A hot-rolled annealed 0.8 mm thick ferritic stainless steel having the chemical composition shown in Table 1 was used to produce a hot dip plated ferritic stainless steel sheet of Al or Zn. Then, this hot-dip ferritic stainless steel sheet was heat-treated, leveled, and skin-pass-rolled as shown in Table 2, bent at t / 2-90 ° and 180 °, and evaluated for cracks on the bent surface. The results are shown in Table 2.
Are also shown. In the observation and evaluation of the bent surface, in the Al-based plating, the plating metal layer was further dissolved with a concentrated aqueous solution of NaOH and the plating alloy layer was dissolved with a phosphoric acid aqueous solution, and with the Zn-based plating, the plating metal layer was further doped with a nitric acid aqueous solution. After the plating alloy layer was dissolved with an aqueous solution, it was visually observed. Regarding the evaluation of cracks, a score of 1 having no cracks was given, and a score of 5 which was enough to separate two cracks was given a score of 5, and the intervals between them were sensually classified into 3 grades.

【0031】[0031]

【表1】 [Table 1]

【0032】[0032]

【表2】 [Table 2]

【0033】[0033]

【表3】 [Table 3]

【0034】[0034]

【表4】 [Table 4]

【0035】[0035]

【表5】 [Table 5]

【0036】[0036]

【表6】 [Table 6]

【0037】その結果、溶融めっき金属と被めっきステ
ンレス鋼板の境界に生成した合金層の長さ1mmあたり5
0本以上クラックが発生しているNo.1〜42の試料
は、90゜曲げの曲げ面が健全で割れの発生もなく良好
な曲げ性を示した。特に、合金層の長さ1mmあたり90
本クラックが発生しているNo.2〜12、No.15
〜20、No.22〜30、No.32〜33、No.
35〜40、No.43〜46の試料は、180゜曲げ
においても曲げ面が健全で割れの発生もなく極めて良好
な曲げ性を示した。一方、比較に実施したレベラー矯正
およびスキンパス圧延を施すことなく合金層の長さ1mm
あたりのクラック数が50本未満のNo.47〜70の
試料は、90゜曲げおよび180゜曲げのいずれの曲げ
加工においても脆性破面を呈するクラックが発生した。
As a result, the length of the alloy layer formed at the boundary between the hot-dip metal and the stainless steel plate to be plated was 5 mm per 1 mm.
No. with 0 or more cracks The samples of Nos. 1 to 42 had sound bending surfaces at 90 ° bending and showed good bendability without cracking. Especially 90 per 1 mm of alloy layer length
No. where this crack has occurred 2-12, No. 15
~ 20, No. 22-30, No. 32-33, No.
35-40, No. The samples of Nos. 43 to 46 showed a very good bendability without bending even when the bend surface was sound even when bent by 180 °. On the other hand, the length of the alloy layer was 1 mm without leveler straightening and skin pass rolling, which were carried out for comparison.
No. with less than 50 cracks per hit In the samples of Nos. 47 to 70, cracks exhibiting a brittle fracture surface were generated in both 90 ° bending and 180 ° bending.

【0038】[0038]

【発明の効果】本発明により、曲げ加工性の優れた溶融
めっきフェライト系ステンレス鋼板の製造が可能になっ
た。従来、曲げ加工性の不良な製品は歩留り落ちとせざ
るを得なかったが、本発明により製品歩留りが増大し、
工業的な利益は極めて大きい。従来、溶融めっきフェラ
イト系ステンレス鋼は、主として軽加工の部材に用いら
れることを期待して製造されたものである。しかし、簡
単な曲げ加工でも割れが生ずるため、例え割れのない状
態で使用されたとしても、石がぶつかるなどの頻繁に起
こり得る軽度の事故によって破壊が生ずる危険性を払拭
できず、広範に使用されることはなかった。このような
場合、従来Niを多量に含んだオーステナイト系ステン
レス鋼をめっき原板とした溶融めっきオーステナイト系
ステンレス鋼が用いられてきた。本発明により、溶融め
っきフェライト系ステンレス鋼の曲げ加工性が向上し、
しかも簡単な事故でも懸念された破壊の危険性が解消し
たため、Niを含む高価な溶融めっきオーステナイト系
ステンレス鋼板の必要がなくなる。特に屋根材では、熱
膨張率の低い溶融めっきフェライト系ステンレス鋼が使
用できるため、構造体としての設計も容易になった。こ
のように、本発明により間接的に得られる経済的な効果
も大きい。
According to the present invention, it becomes possible to manufacture a hot dip ferritic stainless steel sheet having excellent bending workability. Conventionally, products with poor bending workability had to be reduced in yield, but the present invention increased product yield,
Industrial benefits are extremely high. Conventionally, hot-dip ferritic stainless steel has been manufactured mainly with the expectation that it will be used for light-worked members. However, even if it is used in a state where there is no crack, even if it is used without cracks, the risk of destruction due to frequent minor accidents such as stone collision cannot be wiped out and it is widely used. It was never done. In such a case, conventionally, hot-dip austenitic stainless steel using an austenitic stainless steel containing a large amount of Ni as a plating original plate has been used. According to the present invention, the bending workability of hot-dip ferritic stainless steel is improved,
Moreover, the risk of destruction, which has been a concern even in a simple accident, has been eliminated, so that there is no need for an expensive hot-dip austenitic stainless steel sheet containing Ni. Especially for roofing materials, since hot-dip ferritic stainless steel having a low coefficient of thermal expansion can be used, the design as a structure is facilitated. As described above, the economic effect indirectly obtained by the present invention is large.

【図面の簡単な説明】[Brief description of drawings]

【図1】めっきステンレス鋼板のめっき部分の断面を示
す模式図。
FIG. 1 is a schematic diagram showing a cross section of a plated portion of a plated stainless steel plate.

───────────────────────────────────────────────────── フロントページの続き (72)発明者 平松 博之 福岡県北九州市戸畑区飛幡町1番1号 新 日本製鐵株式会社八幡製鐵所内 (72)発明者 田野 和広 福岡県北九州市戸畑区飛幡町1番1号 新 日本製鐵株式会社八幡製鐵所内 ─────────────────────────────────────────────────── ─── Continuation of front page (72) Hiroyuki Hiramatsu Inventor Hiroyuki Hiramatsu 1-1 Tobahata-cho, Tobata-ku, Kitakyushu, Fukuoka Inside the Nippon Steel Co., Ltd. Yawata Works (72) Kazuhiro Tano Inaba, Kitakyushu, Kitakyushu-shi, Fukuoka No. 1 town No. 1 Nippon Steel Corporation Yawata Works

Claims (10)

【特許請求の範囲】[Claims] 【請求項1】 フェライト系ステンレス被めっき鋼板表
面と溶融めっき層との境界面に、前記ステンレス鋼と溶
融めっき金属との合金層が存在し、かつ前記合金層中に
亀裂を有することを特徴とする曲げ加工性に優れた溶融
めっきフェライト系ステンレス鋼板。
1. An alloy layer of the stainless steel and the hot dip plated metal is present at the interface between the surface of the ferritic stainless steel plated steel sheet and the hot dip plated layer, and cracks are present in the alloy layer. Hot-dip ferritic stainless steel sheet with excellent bending workability.
【請求項2】 フェライト系ステンレス被めっき鋼板と
溶融めっき層との境界面に、前記ステンレス鋼と溶融め
っき金属との合金層が面積率で少なくとも60%以上存
在し、かつめっき鋼板表面に垂直な任意の断面から見て
前記合金層厚みの50%以上の長さを有する微細な亀裂
を被めっき鋼板表面に平行な長さ1mm当たり50本以上
前記合金層中に有することを特徴とする曲げ加工性に優
れた溶融めっきフェライト系ステンレス鋼板。
2. An alloy layer of the stainless steel and the hot dip plated metal is present in an area ratio of at least 60% or more at the interface between the ferritic stainless steel plated steel sheet and the hot dip plated layer, and is perpendicular to the surface of the hot dip plated steel sheet. Bending process characterized by having in the alloy layer 50 or more fine cracks having a length of 50% or more of the thickness of the alloy layer viewed from an arbitrary cross section per 1 mm length parallel to the surface of the steel plate to be plated. Hot-dip ferritic stainless steel sheet with excellent properties.
【請求項3】 重量%で C :0.08%以下、 Si:1.0%以下、 Mn:1.0%以下、 Cr:11〜25%、 N :0.03%以下を含有し、残部がFeおよび不可
避不純物からなるフェライト系ステンレス被めっき鋼板
と溶融めっき層との境界面に、前記ステンレス鋼と溶融
めっき金属との合金層が面積率で少なくとも60%以上
存在し、かつめっき鋼板表面に垂直な任意の断面から見
て前記合金層厚みの50%以上の長さを有する微細な亀
裂を被めっき鋼板表面に平行な長さ1mm当たり50本以
上前記合金層中に有することを特徴とする曲げ加工性に
優れた溶融めっきフェライト系ステンレス鋼板。
3. By weight%, C: 0.08% or less, Si: 1.0% or less, Mn: 1.0% or less, Cr: 11 to 25%, N: 0.03% or less, At least 60% or more in area ratio of the alloy layer of the stainless steel and the hot-dip galvanized metal is present at the interface between the hot-dip galvanized steel sheet and the ferritic stainless steel plated steel sheet with the balance being Fe and unavoidable impurities, and Characterized in that it has 50 or more fine cracks having a length of 50% or more of the thickness of the alloy layer viewed from an arbitrary cross section perpendicular to Hot-dip ferritic stainless steel sheet with excellent bending workability.
【請求項4】 重量%で C :0.08%以下、 Si:1.0%以下、 Mn:1.0%以下、 Cr:11〜25%、 N :0.03%以下を含有し、さらにNb:1.5%
以下、 Ti:0.5%以下、 Mo:2.5%以下、 Cu:0.5%以下の
1種または2種以上を含有し、残部がFeおよび不可避
不純物からなるフェライト系ステンレス被めっき鋼板と
溶融めっき層との境界面に、前記ステンレス鋼と溶融め
っき金属との合金層が面積率で少なくとも60%以上存
在し、かつめっき鋼板表面に垂直な任意の断面から見て
前記合金層厚みの50%以上の長さを有する微細な亀裂
を被めっき鋼板表面に平行な長さ1mm当たり50本以上
前記合金層中に有することを特徴とする曲げ加工性に優
れた溶融めっきフェライト系ステンレス鋼板。
4. C: 0.08% or less by weight%, Si: 1.0% or less, Mn: 1.0% or less, Cr: 11 to 25%, N: 0.03% or less, Further Nb: 1.5%
Hereinafter, Ti: 0.5% or less, Mo: 2.5% or less, Cu: 0.5% or less, one or two or more, and the balance is Fe and inevitable impurities. The alloy layer of the stainless steel and the hot-dip galvanized metal is present in the interface between the hot-dip galvanized layer and the hot-dip galvanized layer at an area ratio of at least 60% or more, and the thickness of the alloy layer is A hot-dip ferritic stainless steel sheet having excellent bending workability, which has 50 or more fine cracks having a length of 50% or more in the alloy layer per 1 mm in length parallel to the surface of the steel sheet to be plated.
【請求項5】 フェライト系ステンレス被めっき鋼板と
溶融めっき層との境界面に、前記ステンレス鋼と溶融め
っき金属との合金層が面積率で少なくとも60%以上存
在する溶融めっきを施した後、被めっき鋼板と溶融めっ
き金属との合金層に、最大伸び率0.1%以上を加える
ことによって、被めっきステンレス鋼板表面に垂直な任
意の断面から見て前記合金層厚みの50%以上の長さを
有する微細な亀裂を被めっき鋼板表面に平行な長さ1mm
当たり50本以上前記合金層中に存在させることを特徴
とする曲げ加工性に優れた溶融めっきフェライト系ステ
ンレス鋼板の製造法。
5. The surface of the interface between the ferritic stainless steel plated steel sheet and the hot dip plated layer is subjected to hot dip coating in which an alloy layer of the stainless steel and hot dip plated metal is present in an area ratio of at least 60% or more, By adding a maximum elongation of 0.1% or more to the alloy layer of the plated steel sheet and the hot dip plated metal, a length of 50% or more of the thickness of the alloy layer as viewed from an arbitrary section perpendicular to the surface of the stainless steel plate to be plated. 1mm parallel to the surface of the steel plate to be coated with fine cracks
A method for producing a hot-dip ferritic stainless steel sheet having excellent bending workability, characterized in that 50 or more pieces are present in the alloy layer.
【請求項6】 フェライト系ステンレス被めっき鋼板と
溶融めっき層との境界面に、前記ステンレス鋼と溶融め
っき金属との合金層が面積率で少なくとも60%以上存
在する溶融めっきを施し、350〜400℃の温度に5
時間以上保定した後、被めっき鋼板と溶融めっき金属と
の合金層に、最大伸び率0.1%以上を加えることによ
って、被めっき鋼板表面に垂直な任意の断面から見て前
記合金層厚みの50%以上の長さを有する微細な亀裂を
被めっき鋼板表面に平行な長さ1mm当たり50本以上前
記合金層中に存在させることを特徴とする曲げ加工性に
優れた溶融めっきフェライト系ステンレス鋼板の製造
法。
6. A hot-dip coating in which an alloy layer of the stainless steel and the hot-dip metal is present in an area ratio of at least 60% or more is applied to a boundary surface between the ferritic stainless steel plated steel sheet and the hot-dip plated layer, and 350 to 400 is applied. 5 to ℃ temperature
After holding for at least the time, by adding a maximum elongation of 0.1% or more to the alloy layer of the steel sheet to be plated and the hot dip plated metal, the alloy layer thickness of the alloy layer thickness as viewed from an arbitrary cross section perpendicular to the surface of the steel sheet to be plated is added. Hot-dip ferritic stainless steel sheet with excellent bending workability, characterized in that fine cracks having a length of 50% or more are present in the alloy layer at 50 or more per 1 mm length parallel to the surface of the steel sheet to be plated. Manufacturing method.
【請求項7】 重量%で C :0.08%以下、 Si:1.0%以下、 Mn:1.0%以下、 Cr:11〜25%、 N :0.03%以下を含有し残部がFeおよび不可避
不純物からなるフェライト系ステンレス被めっき鋼板と
溶融めっき層との境界面に、前記ステンレス鋼と溶融め
っき金属との合金層が面積率で少なくとも60%以上存
在する溶融めっきを施し、350〜400℃の温度に5
時間以上保定した後、被めっき鋼板と溶融めっき金属と
の合金層に、最大伸び率0.1%以上を加えることによ
って、めっき鋼板表面に垂直な任意の断面から見て前記
合金層厚みの50%以上の長さを有する微細な亀裂を被
めっき鋼板表面に平行な長さ1mm当たり50本以上前記
合金層中に存在させることを特徴とする曲げ加工性に優
れた溶融めっきフェライト系ステンレス鋼板の製造法。
7. A balance of C: 0.08% or less, Si: 1.0% or less, Mn: 1.0% or less, Cr: 11 to 25%, N: 0.03% or less by weight%. Is applied to the interface between the ferritic stainless steel plated steel sheet consisting of Fe and unavoidable impurities and the hot-dip galvanized layer, and an alloy layer of the stainless steel and the hot-dip galvanized metal is present at an area ratio of at least 60% or more, and 350 5 to a temperature of ~ 400 ° C
After holding for at least the time, by adding a maximum elongation of 0.1% or more to the alloy layer of the steel sheet to be plated and the hot dip plated metal, 50% of the alloy layer thickness as seen from an arbitrary cross section perpendicular to the surface of the plated steel sheet. % Of 50% or more per minute 1 mm in length parallel to the surface of the steel sheet to be plated in the alloy layer. Manufacturing method.
【請求項8】 重量%で C :0.08%以下、 Si:1.0%以下、 Mn:1.0%以下、 Cr:11〜25%、 N :0.03%以下を含有し、さらにNb:1.5%
以下、 Ti:0.5%以下、 Mo:2.5%以下、 Cu:0.5%以下の
1種または2種以上を含有し、残部がFeおよび不可避
不純物からなるフェライト系ステンレス被めっき鋼板と
溶融めっき層との境界面に、前記ステンレス鋼と溶融め
っき金属との合金層が面積率で少なくとも60%以上存
在する溶融めっきを施し、350〜400℃の温度に5
時間以上保定した後、被めっき鋼板と溶融めっき金属と
の合金層に、最大伸び率0.1%以上を加えることによ
って、めっき鋼板表面に垂直な任意の断面から見て前記
合金層厚みの50%以上の長さを有する微細な亀裂を被
めっき鋼板表面に平行な長さ1mm当たり50本以上前記
合金層中に存在させることを特徴とする曲げ加工性に優
れた溶融めっきフェライト系ステンレス鋼板の製造法。
8. By weight%, C: 0.08% or less, Si: 1.0% or less, Mn: 1.0% or less, Cr: 11 to 25%, N: 0.03% or less, Further Nb: 1.5%
Hereinafter, Ti: 0.5% or less, Mo: 2.5% or less, Cu: 0.5% or less, one or two or more, and the balance is Fe and inevitable impurities. The interface between the hot-dip galvanized layer and the hot-dip galvanized layer is subjected to hot-dip galvanizing in which the alloy layer of the stainless steel and the hot-dip galvanized metal is present at an area ratio of at least 60% or more, and the temperature is set to 350 to 400 ° C.
After holding for at least the time, by adding a maximum elongation of 0.1% or more to the alloy layer of the steel sheet to be plated and the hot dip plated metal, 50% of the alloy layer thickness as seen from an arbitrary cross section perpendicular to the surface of the plated steel sheet. % Of 50% or more per minute 1 mm in length parallel to the surface of the steel sheet to be plated in the alloy layer. Manufacturing method.
【請求項9】 最大伸び率0.1%以上を加える手段と
して、スキンパス圧延、半径100mm以下のロールを1
本以上通過させるベンディング型レベラー矯正、テンシ
ョン型レベラー矯正の1種または2種以上を施すことを
特徴とする請求項4,5,6あるいは7のそれぞれに記
載の曲げ加工性に優れた溶融めっきステンレス鋼板の製
造法。
9. Skin pass rolling, rolls with a radius of 100 mm or less are used as a means for adding a maximum elongation of 0.1% or more.
One or more of bending-type leveler straightening and tension-type leveler straightening for passing more than one line are applied, and hot-dip stainless steel excellent in bending workability according to claim 4, 5, 6 or 7, respectively. Steel plate manufacturing method.
【請求項10】 溶融めっき金属がZnを主成分とする
金属またはAlを主成分とする金属であることを特徴と
する請求項1,2,3,4,5,6,7、あるいは8の
それぞれに記載の曲げ加工性に優れた溶融めっきステン
レス鋼板またはその製造法。
10. The hot dip plated metal is a metal containing Zn as a main component or a metal containing Al as a main component, according to claim 1, 2, 3, 4, 5, 6, 7, or 8. A hot-dip galvanized stainless steel sheet excellent in bending workability described in each of them or a method for producing the same.
JP13688895A 1995-03-27 1995-06-02 Hot-dip ferritic stainless steel sheet excellent in bending workability and method for producing the same Expired - Lifetime JP3202539B2 (en)

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JP7-68413 1995-03-27
JP6841395 1995-03-27
JP13688895A JP3202539B2 (en) 1995-03-27 1995-06-02 Hot-dip ferritic stainless steel sheet excellent in bending workability and method for producing the same

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JP3202539B2 JP3202539B2 (en) 2001-08-27

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11200000A (en) * 1998-01-06 1999-07-27 Sumitomo Metal Ind Ltd Hot dip galvannealed steel sheet excellent in low temperature chipping resistance and workability and its production
JP2002317258A (en) * 2001-04-19 2002-10-31 Nippon Steel Corp Hot dip aluminum plated steel sheet having excellent corrosion resistance after working and production method therefor
EP3467131A4 (en) * 2016-05-30 2019-06-05 JFE Steel Corporation Ferritic stainless steel sheet

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11200000A (en) * 1998-01-06 1999-07-27 Sumitomo Metal Ind Ltd Hot dip galvannealed steel sheet excellent in low temperature chipping resistance and workability and its production
JP2002317258A (en) * 2001-04-19 2002-10-31 Nippon Steel Corp Hot dip aluminum plated steel sheet having excellent corrosion resistance after working and production method therefor
EP3467131A4 (en) * 2016-05-30 2019-06-05 JFE Steel Corporation Ferritic stainless steel sheet
US10821706B2 (en) 2016-05-30 2020-11-03 Jfe Steel Corporation Ferritic stainless steel sheet

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