JPH08285255A - Refining treatment for gas being generated in melting furnace, and waste melting furnace - Google Patents

Refining treatment for gas being generated in melting furnace, and waste melting furnace

Info

Publication number
JPH08285255A
JPH08285255A JP7089810A JP8981095A JPH08285255A JP H08285255 A JPH08285255 A JP H08285255A JP 7089810 A JP7089810 A JP 7089810A JP 8981095 A JP8981095 A JP 8981095A JP H08285255 A JPH08285255 A JP H08285255A
Authority
JP
Japan
Prior art keywords
furnace
melting furnace
air
gas
waste
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP7089810A
Other languages
Japanese (ja)
Other versions
JP3746807B2 (en
Inventor
Yoshihiro Ishida
吉浩 石田
Kazutake Murahashi
一毅 村橋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Nippon Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Steel Corp filed Critical Nippon Steel Corp
Priority to JP08981095A priority Critical patent/JP3746807B2/en
Publication of JPH08285255A publication Critical patent/JPH08285255A/en
Application granted granted Critical
Publication of JP3746807B2 publication Critical patent/JP3746807B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/34Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery

Landscapes

  • Incineration Of Waste (AREA)
  • Gasification And Melting Of Waste (AREA)

Abstract

PURPOSE: To dispose tar in an exhaust gas by cracking at a high temperature by a method wherein in a shaft furnace type waste melting furnace, air is fed from an air feeding nozzle being provided in a refining zone upper than a waste stock level, and a flammable gas which ascends from the furnace lower part is partially burned. CONSTITUTION: For a melting furnace 1, a plurality of lower tuyeres 2 and upper tuyeres 3 are respectively provided around a furnace at a lower part of its shaft part (1a), and oxygen enriched air is fed from the lower tuyere 2 which is provided on a furnace bed part (1b). Also, air for combustion is fed into a furnace from the upper tuyere 3 which is provided on a bosh shaped part (1c) at on the top of the bed furnace bed part (1b). Also, the upper part of the shaft (1a) is made a refining zone, and a nozzle 4 which feeds air to an area higher than the stock level of an article to be charged is provided in the refining zone, and an injection port 5 for flammable dust being spread is provided on the top of the nozzle 4. Then, by partially burning the flammable gas which ascends from the lower part of the refining zone, tar in the furnace top gas is well disposed by cracking.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本願発明は、一般廃棄物あるいは
産業廃棄物等を処理する廃棄物溶融炉の操業方法に関
し、特に、廃棄物溶融炉発生ガスの改質方法及び装置に
関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for operating a waste melting furnace for treating general waste or industrial waste, and more particularly to a method and an apparatus for reforming the gas generated from the waste melting furnace.

【0002】[0002]

【従来の技術】廃棄物溶融炉による廃棄物処理は、炉に
装入された一般廃棄物あるいは産業廃棄物等を乾燥、熱
分解、燃焼、溶融の過程を経て、廃棄物をスラグとして
取り出すものである。
2. Description of the Related Art The waste treatment in a waste melting furnace is a method in which general waste or industrial waste loaded in the furnace is dried, pyrolyzed, burned, and melted, and then taken out as slag. Is.

【0003】例えば、特公昭60ー11766号公報に
は、図2に示すように、廃棄物溶融炉1は、円形断面の
シャフト型の炉体をしており、炉内に装入された廃棄物
を乾燥、熱分解、燃焼及び溶融させるために、燃料であ
るコークスを燃焼させる。前記コークス燃焼のために、
炉体の下部には複数段の羽口が設けられ、これら羽口の
うち、炉床部近くに配置された下段羽口2は酸素を富化
した空気を吹き込み、また、下段羽口の上に配置された
上段羽口3は空気を吹き込むようになっている。
For example, in Japanese Patent Publication No. 60-11766, as shown in FIG. 2, a waste melting furnace 1 has a shaft-shaped furnace body having a circular cross section, and the waste is charged into the furnace. The coke, which is a fuel, is burned in order to dry, pyrolyze, burn and melt the product. Because of the coke burning,
The lower part of the furnace body is provided with a plurality of stages of tuyeres. Of these tuyeres, the lower stage tuyeres 2 located near the hearth blow the oxygen-enriched air and the upper stage of the lower stage tuyeres. Air is blown into the upper tuyeres 3 arranged in the.

【0004】前記廃棄物溶融炉の操業では、炉内におい
て、装入物中の可燃分が熱分解して熱分解残渣が発生す
る。発生した熱分解残渣は羽口から送られてきた空気に
よって燃焼するかあるいは炉内に堆積していくが、微細
なものは、羽口から送られてきた空気によって燃焼され
ることなく、気流にのって炉から可燃性ダストとして飛
散し、排ガスとともに後段の2次燃焼室で処理される。
In the operation of the waste melting furnace, combustible components in the charge are pyrolyzed in the furnace to generate a pyrolysis residue. The generated pyrolysis residue is burned by the air sent from the tuyere or is accumulated in the furnace, but the fine particles are not burned by the air sent from the tuyere After that, it scatters from the furnace as combustible dust and is treated in the secondary combustion chamber in the latter stage together with the exhaust gas.

【0005】[0005]

【発明が解決しようとする課題】ところが、溶融炉で
は、炉頂排ガス温度が100〜500°Cと低いため、
排ガス中にタール分を多く含む。そのため、2次燃焼室
を設置する場合は、途中のダクトがタールにより閉塞し
易く定期的に掃除が必要となることや排ガスを燃料とし
て回収する場合には、スクラバー等のガス洗浄装置がタ
ールによって閉塞するという不都合があるため、実際に
は燃料回収はされていないのが現状である。また、熱分
解で発生した熱分解残渣が可燃性ダストとして飛散して
いくため、ガス化効率が悪化するという不都合があっ
た。
However, in the melting furnace, since the temperature of the exhaust gas at the top of the furnace is as low as 100 to 500 ° C,
Exhaust gas contains a large amount of tar. Therefore, when a secondary combustion chamber is installed, the duct in the middle is apt to be clogged with tar and periodical cleaning is required, and when recovering exhaust gas as fuel, a gas cleaning device such as a scrubber uses tar. Due to the inconvenience of blockage, the current situation is that fuel is not actually collected. Further, since the pyrolysis residue generated by the pyrolysis scatters as combustible dust, there is a disadvantage that the gasification efficiency deteriorates.

【0006】そこで、本願発明は、廃棄物溶融炉の後段
に設置されている排ガスダクトやガス洗浄装置などの排
ガス処理設備を閉塞する排ガス中のタールを高温でクラ
ッキング処理すると共に飛散した可燃性ダストをガス化
処理する方法及びその処理装置を提供するものである。
In view of this, the invention of the present application cracks the tar in the exhaust gas, which blocks the exhaust gas treatment equipment such as the exhaust gas duct and the gas cleaning device installed at the latter stage of the waste melting furnace, at a high temperature and scatters the combustible dust. The present invention provides a method for gasifying gas and a processing device therefor.

【0007】[0007]

【課題を解決するための手段】本願発明による処理方法
は、溶融炉のシャフトのストックレベルより上部に改質
ゾーンを設け、改質ゾーンには空気を吹き込む羽口を設
け、溶融炉の下部から上昇してくる100〜500°C
のガスを部分燃焼させ、改質ゾーンの温度を800°C
以上に調整し、また、改質ゾーンでのガス滞留時間を1
秒以上確保することにより炉頂ガス中のタールのクラッ
キング処理が十分に行なわれる。改質ゾーンに供給する
空気量は、温度指示調節計(TIC)により制御され
る。なお、可燃性ダストのガス化を促進するために、水
蒸気を添加することも有効である。また、改質ゾーンに
リサイクルするガスとサイクロンにより捕集された排ガ
ス中の可燃性ダストをサイクロン下部より吸引し、その
ガスをエジェクターにより空気又は不活性ガスと共に改
質ゾーンに供給して可燃性ダストをガス化処理する。
According to the treatment method of the present invention, a reforming zone is provided above the stock level of a shaft of a melting furnace, and tuyeres for blowing air are provided in the reforming zone, and a reforming zone is provided from the bottom of the melting furnace. 100-500 ° C rising
Partial combustion of the gas in the reforming zone at 800 ° C
Adjusted as above and set the gas retention time in the reforming zone to 1
By securing at least 2 seconds, the cracking treatment of tar in the furnace top gas is sufficiently performed. The amount of air supplied to the reforming zone is controlled by a temperature indicating controller (TIC). It is also effective to add water vapor in order to accelerate the gasification of combustible dust. In addition, the gas to be recycled to the reforming zone and the combustible dust in the exhaust gas collected by the cyclone are sucked from the lower part of the cyclone, and the gas is supplied to the reforming zone together with air or an inert gas by the ejector to burn the combustible dust. Is gasified.

【0008】さらに、改質ゾーンで反応しきれない可燃
性ダスト分は、排ガスダクトの途中に設置したサイクロ
ンによって大部分捕集され、改質ゾーンにリサイクルす
ることにより、さらに可燃性ダスト分の少ない可燃性ガ
スを供することができる。
[0008] Further, most of the combustible dust which cannot be completely reacted in the reforming zone is collected by a cyclone installed in the middle of the exhaust gas duct, and is recycled to the reforming zone to further reduce the combustible dust content. A combustible gas can be provided.

【0009】本願発明による処理装置は、炉体の下部に
酸素富化空気を吹き込む下段羽口と空気を吹き込む上段
羽口を有する廃棄物溶融炉において、炉体上部であって
廃棄物のストックレベルより上方の改質ゾーンに空気吹
き込み羽口を設けたもので、さらに、廃棄物溶融炉の炉
頂からの排ガス除塵装置で捕集された可燃性ダストを改
質ゾーンに戻す可燃性ダスト吹き込み口を改質ゾーンに
設けてもよい。
The treatment apparatus according to the present invention is a waste melting furnace having a lower tuyere for blowing oxygen-enriched air into the lower part of the furnace body and an upper tuyere for blowing air into the furnace body. An air blowing tuyere is installed in the upper reforming zone.Furthermore, the combustible dust blowing port that returns the combustible dust collected by the exhaust gas dust removal device from the furnace top of the waste melting furnace to the reforming zone. May be provided in the reforming zone.

【0010】[0010]

【作用】本願発明により、廃棄物溶融炉の下部から上昇
するタール含有の可燃性ガスが燃焼することにより、タ
ールが分解され、飛散した可燃性ダストが溶融炉へリサ
イクルされて燃焼されるので、飛散する可燃性ダストも
少なくなる。
According to the present invention, the tar-containing combustible gas rising from the lower part of the waste melting furnace is burned, the tar is decomposed, and the scattered combustible dust is recycled to the melting furnace and burned. Fewer combustible dust is also scattered.

【0011】[0011]

【実施例】本願発明の実施例を図1を用いて説明する。Embodiment An embodiment of the present invention will be described with reference to FIG.

【0012】本願発明による可燃性ダスト処理方法を実
施するための廃棄物処理設備としては、シャフト炉方式
の溶融炉を用いるもので、溶融炉1はシャフト部1aの
上部に設けられた廃棄物装入装置により廃棄物が炉内へ
装入できるように構成されている。
As a waste treatment facility for carrying out the method for treating combustible dust according to the present invention, a melting furnace of a shaft furnace type is used, and the melting furnace 1 is provided with a waste device provided above the shaft portion 1a. It is configured so that the waste can be charged into the furnace by the charging device.

【0013】溶融炉1のシャフト部1aの下部には、下
段羽口2及び上段羽口3が炉の周囲にそれぞれ複数本設
けられている。下段羽口2は炉床部1bに設けられ、炉
底に降りてきたコークスを燃焼させるために、下段羽口
2から酸素を富化した空気が炉内へ吹き込まれる。他
方、上段羽口3は炉床部の上部にある朝顔部1cに設け
られ、燃焼用空気が上段羽口2から炉内へ吹き込まれ
る。なお、上段羽口2は、2段以上設けてもよい。
A plurality of lower tuyeres 2 and upper tuyeres 3 are provided around the furnace at the lower portion of the shaft portion 1a of the melting furnace 1. The lower tuyeres 2 are provided in the hearth 1b, and oxygen-enriched air is blown into the furnace from the lower tuyeres 2 in order to burn the coke that has descended to the bottom of the furnace. On the other hand, the upper tuyeres 3 are provided in the bosh section 1c above the hearth floor, and combustion air is blown into the furnace from the upper tuyeres 2. The upper tuyeres 2 may be provided in two or more stages.

【0014】溶融炉1のシャフト1aの上部には、改質
ゾーンが形成され、装入物のストックレベルより上部に
空気を吹き込むノズル4が設けられ、ノズル4のさらに
上部に飛散した可燃性ダストの吹き込み口5が設けられ
ている。
A reforming zone is formed in the upper portion of the shaft 1a of the melting furnace 1, a nozzle 4 for injecting air is provided above the stock level of the charge, and flammable dust scattered further above the nozzle 4 is provided. Blow-in port 5 is provided.

【0015】炉頂から排出された排ガス中の可燃性ダス
トは、排ガスダクトの途中に設置されたサイクロン等の
除塵器6によって大部分が捕集され、エジェクタ7によ
り可燃性ダスト吹き込み口5から溶融炉に戻されて燃焼
される。
Most of the combustible dust in the exhaust gas discharged from the furnace top is collected by a dust remover 6 such as a cyclone installed in the middle of the exhaust gas duct, and melted from the combustible dust blowing port 5 by an ejector 7. It is returned to the furnace and burned.

【0016】ノズル4から改質ゾーンへ吹き込む空気の
量及び可燃性ダスト吹き込み口5から改質ゾーンに吹き
込む可燃性ダストの量は、温度調節計(TC)により調
整弁8の開度を調節して行なう。
The amount of air blown from the nozzle 4 into the reforming zone and the amount of combustible dust blown into the reforming zone from the combustible dust inlet 5 are controlled by the temperature controller (TC) to adjust the opening of the regulating valve 8. Do it.

【0017】前記溶融炉において、炉体上部の装入ホッ
パから装入された廃棄物は、炉体を降下するにしたがっ
て乾燥され、次いで可燃物が熱分解して熱分解残渣が発
生する。熱分解残渣は上部羽口から吹き込まれる空気と
接して燃焼するが、未燃焼の熱分解残渣は堆積して行
き、微細な熱分解残渣(可燃性ダスト)は、炉下部から
の可燃性ガス気流にのって上昇していく。改質ゾーンで
は、可燃性ダストを含有する可燃性ガスは、温度が約1
00〜500°Cで、成分はカロリー換算で可燃ガス約
50%、タール分約30%、可燃性ダスト約20%から
なり、改質ゾーンに上部羽口から空気を吹き込み部分燃
焼し、改質ゾーンを約800°C以上に調節することに
より、タールがCnHm等にクラッキングされる。
In the melting furnace, the waste material charged from the charging hopper on the upper part of the furnace body is dried as it descends in the furnace body, and then the combustible material is thermally decomposed to generate a thermal decomposition residue. The thermal decomposition residue burns in contact with the air blown from the upper tuyere, but the uncombusted thermal decomposition residue accumulates, and the fine thermal decomposition residue (combustible dust) is a combustible gas stream from the lower part of the furnace. Climbs up. In the reforming zone, the temperature of the combustible gas containing combustible dust is about 1
At 00 to 500 ° C, the components consist of about 50% combustible gas, about 30% tar, and about 20% combustible dust in terms of calories. Air is blown from the upper tuyere into the reforming zone to partially burn and reform. By adjusting the zone to about 800 ° C or higher, tar is cracked to CnHm or the like.

【0018】また、可燃性ダストは、熱分解と、CO2
+C→2CO等の反応でガス化が促進される。その結
果、飛散する可燃性ダスト分が減少し、可燃性ダスト分
が少ない高カロリーの可燃性ガスを得ることができる。
さらに、排ガス中へ飛散した可燃性ダストは、炉頂から
の排ガスダクトに設置されたサイクロンによって大部分
が捕集され、改質ゾーンの可燃性ダスト吹き込み口から
溶融炉に戻されて燃焼する。その結果、飛散する可燃性
ダスト分が減少し、可燃性ダスト分が少ない高カロリー
の可燃性ガスを得ることができる。
Combustible dust is decomposed by thermal decomposition and CO 2
Gasification is promoted by a reaction such as + C → 2CO. As a result, the amount of combustible dust that scatters is reduced, and a high-calorie combustible gas with a small amount of combustible dust can be obtained.
Further, most of the combustible dust scattered in the exhaust gas is collected by the cyclone installed in the exhaust gas duct from the furnace top, and returned to the melting furnace from the combustible dust blowing port of the reforming zone and burned. As a result, the amount of combustible dust that scatters is reduced, and a high-calorie combustible gas with a small amount of combustible dust can be obtained.

【0019】[0019]

【発明の効果】本願発明の効果は、次のとおりである。The effects of the present invention are as follows.

【0020】(1) 本願発明により、炉の下部から上
昇してくるガス中のタールが改質ゾーンにおいて高温で
クラッキング処理されて、排ガス中のタールが分解され
るので、溶鉱炉の後段に設けられている排ガスダクトや
ガス洗浄装置などの排ガス処理設備がタールで閉鎖され
ることはない。
(1) According to the present invention, the tar in the gas rising from the lower part of the furnace is cracked at a high temperature in the reforming zone to decompose the tar in the exhaust gas, so that it is provided in the latter stage of the blast furnace. Exhaust gas treatment equipment such as exhaust gas ducts and gas cleaning equipment will not be closed by tar.

【0021】(2) 排ガス中に含まれている可燃性ダ
ストを捕集して、改質ゾーンに再循環させて燃焼させる
ので、ガス化効率がよい。
(2) Since the combustible dust contained in the exhaust gas is collected, recirculated to the reforming zone and burned, the gasification efficiency is good.

【0022】(3) 本願発明の溶融炉の排ガスを後段
に設置される2次燃焼炉で完全燃焼する場合には、排ガ
ス温度が高いために燃焼は安定し、さらに、可燃性ダス
トもきわめて少ないので、燃焼は安定し、公害問題も少
なくなる。
(3) When the exhaust gas of the melting furnace of the present invention is completely combusted in the secondary combustion furnace installed in the latter stage, the combustion is stable because the exhaust gas temperature is high, and the combustible dust is extremely small. Therefore, combustion is stable and pollution problems are reduced.

【図面の簡単な説明】[Brief description of drawings]

【図1】本願発明による廃棄物溶融炉の説明図。FIG. 1 is an explanatory view of a waste melting furnace according to the present invention.

【図2】従来の廃棄物溶融炉の概略図。FIG. 2 is a schematic view of a conventional waste melting furnace.

【符号の説明】[Explanation of symbols]

1 溶融炉、 1a シャフト、 1b 炉床部、 1
c 朝顔部、 2 下段羽口、 3 上段羽口、 4
ノズル、 5 可燃性ダスト吹き込み口、 6除塵器、
7 エジェクタ、 8 調整弁
1 melting furnace, 1a shaft, 1b hearth, 1
c Morning glory, 2 lower tuyeres, 3 upper tuyeres, 4
Nozzle, 5 flammable dust inlet, 6 dust remover,
7 ejector, 8 adjusting valve

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 シャフト炉方式の廃棄物溶融炉の廃棄物
のストックレベルより上方の改質ゾーンに設けられた空
気吹き込みノズルから空気を炉内に吹き込み、炉の下部
から上昇してくる可燃性ガスを部分燃焼させることを特
徴とする溶融炉発生ガスの改質処理方法。
1. A flammable material which blows air into a furnace from an air blowing nozzle provided in a reforming zone above a stock level of waste in a shaft furnace type waste melting furnace and rises from a lower part of the furnace. A method for reforming a gas generated from a melting furnace, which comprises partially burning the gas.
【請求項2】 シャフト炉方式の廃棄物溶融炉の炉頂か
ら排出される可燃性ダストを含む排ガスを除塵処理し、
捕集された可燃性ダストを改質ゾーンに戻して燃焼させ
ることを特徴とする請求項1記載の溶融炉発生ガスの改
質処理方法。
2. Exhaust gas containing combustible dust discharged from the top of a shaft furnace type waste melting furnace is dedusted,
The method for reforming a gas generated from a melting furnace according to claim 1, wherein the collected combustible dust is returned to the reforming zone and burned.
【請求項3】 炉体の下部に酸素富化空気を吹き込む下
段羽口と空気を吹き込む上段羽口を有する廃棄物溶融炉
において、炉体上部であって廃棄物のストックレベルよ
り上方の改質ゾーンに空気吹き込みノズルを設けたこと
を特徴とする廃棄物溶融炉。
3. A waste melting furnace having a lower tuyeres for blowing oxygen-enriched air into the lower part of the furnace body and an upper tuyeres for blowing air, and reforming above the furnace body and above the stock level of waste. A waste melting furnace characterized in that an air blowing nozzle is provided in the zone.
【請求項4】 シャフト炉方式の廃棄物溶融炉の炉頂か
らの排ガス除塵装置で捕集された可燃性ダストを改質ゾ
ーンに戻す可燃性ダスト吹き込み口が改質ゾーンに設け
られていることを特徴とする請求項3記載の廃棄物溶融
炉。
4. The reforming zone is provided with a combustible dust blowing port for returning the combustible dust collected by the exhaust gas dust removing device from the furnace top of the shaft furnace type waste melting furnace to the reforming zone. The waste melting furnace according to claim 3, wherein:
JP08981095A 1995-04-14 1995-04-14 Method for reforming melting furnace gas and waste melting furnace Expired - Fee Related JP3746807B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP08981095A JP3746807B2 (en) 1995-04-14 1995-04-14 Method for reforming melting furnace gas and waste melting furnace

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP08981095A JP3746807B2 (en) 1995-04-14 1995-04-14 Method for reforming melting furnace gas and waste melting furnace

Publications (2)

Publication Number Publication Date
JPH08285255A true JPH08285255A (en) 1996-11-01
JP3746807B2 JP3746807B2 (en) 2006-02-15

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002267127A (en) * 2001-03-08 2002-09-18 Nippon Steel Corp Method and apparatus for blowing combustible dust in waste melting furnace
CN105864782A (en) * 2016-04-26 2016-08-17 山东大学 Device and method for heating and melting rubbish under oxygen-rich condition
CN108728172A (en) * 2017-04-14 2018-11-02 上海电气集团股份有限公司 A kind of aditus structure and the biomass gasifying furnace containing the aditus structure

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002267127A (en) * 2001-03-08 2002-09-18 Nippon Steel Corp Method and apparatus for blowing combustible dust in waste melting furnace
JP4537602B2 (en) * 2001-03-08 2010-09-01 新日鉄エンジニアリング株式会社 Combustible dust injection method in waste melting furnace
CN105864782A (en) * 2016-04-26 2016-08-17 山东大学 Device and method for heating and melting rubbish under oxygen-rich condition
CN108728172A (en) * 2017-04-14 2018-11-02 上海电气集团股份有限公司 A kind of aditus structure and the biomass gasifying furnace containing the aditus structure

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