JPH08283054A - Heat resistant high strength composite material - Google Patents

Heat resistant high strength composite material

Info

Publication number
JPH08283054A
JPH08283054A JP8814195A JP8814195A JPH08283054A JP H08283054 A JPH08283054 A JP H08283054A JP 8814195 A JP8814195 A JP 8814195A JP 8814195 A JP8814195 A JP 8814195A JP H08283054 A JPH08283054 A JP H08283054A
Authority
JP
Japan
Prior art keywords
heat
high strength
graphite
composite material
strength
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP8814195A
Other languages
Japanese (ja)
Inventor
Yoshinari Hasegawa
善成 長谷川
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP8814195A priority Critical patent/JPH08283054A/en
Publication of JPH08283054A publication Critical patent/JPH08283054A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/022Carbon
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/38Fibrous materials; Whiskers
    • C04B14/386Carbon

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Nanotechnology (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Panels For Use In Building Construction (AREA)
  • Reinforced Plastic Materials (AREA)

Abstract

PURPOSE: To obtain a heat resistant high strength composite material capable of exhibiting high strength even at high temp. CONSTITUTION: A binder as a base material is mixed with carbon fibers made from polyacrylonitrile as a reinforcing material and graphite as a strengthening material. The resultant mixture is molded by a molding means such as injection molding and is solidified to obtain a high strength heat resistant molded body having tensile strength and a modulus of tensile elasticity considerably increased by the dynamic characteristics of the carbon fibers and heat resistance considerably improved by mixing with the graphite.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、耐熱性高強度複合材料
に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a heat resistant and high strength composite material.

【0002】[0002]

【従来の技術】従来より、各種の分野で広く用いられて
いる強度素材としてセメントや樹脂等が良く知られてい
る。
2. Description of the Related Art Conventionally, cement, resin and the like have been well known as strength materials widely used in various fields.

【0003】[0003]

【発明が解決しようとする課題】しかしながら、一般的
にセメントや樹脂等から成る強度素材は、高温下におい
て機械的物性が低下して脆性が現れるという傾向があ
り、強度耐熱性能に欠けるという問題があった。
However, in general, a strength material made of cement, resin or the like tends to exhibit mechanical strength and brittleness at high temperatures, and thus has a problem of lacking strength and heat resistance. there were.

【0004】本発明は上述の実情に鑑みてなしたもの
で、高温下でも高い強度を発揮し得る耐熱性高強度複合
材料を提供することを目的としている。
The present invention has been made in view of the above circumstances, and an object of the present invention is to provide a heat-resistant high-strength composite material capable of exhibiting high strength even at high temperatures.

【0005】[0005]

【課題を解決するための手段】本発明は、母材となる結
合材中に、補強材としてポリアクリロニルトリル系炭素
繊維が混合され且つ強化材としてグラファイトが混合さ
れていることを特徴とする耐熱性高強度複合材料、に係
るものである。
The present invention is characterized in that a polyacrylonyl tolyl-based carbon fiber is mixed as a reinforcing material and graphite is mixed as a reinforcing material in a binder as a base material. The present invention relates to a heat resistant and high strength composite material.

【0006】また、母材となる結合材には、セメントを
主原料とするものを採用したり、耐熱性樹脂を主原料と
するものを採用したりすることが可能である。
Further, as the binder serving as the base material, it is possible to adopt one having cement as a main raw material or one having a heat resistant resin as a main raw material.

【0007】[0007]

【作用】従って本発明の耐熱性高強度複合材料では、ポ
リアクリロニルトリル系炭素繊維が有する力学的特性に
より引張り強度と引張り弾性率が大幅に向上され、しか
も、グラファイトの混合により耐熱性が大幅に向上され
るので、ポリアクリロニルトリル系炭素繊維とグラファ
イトとを混合したことによる相乗的な作用により強度耐
熱性能が大幅に向上され、高温下でも高い強度を発揮す
ることが可能となる。
Therefore, in the heat-resistant and high-strength composite material of the present invention, the mechanical properties of the polyacrylonyl tolyl-based carbon fiber significantly improve the tensile strength and the tensile elastic modulus, and the addition of graphite significantly improves the heat resistance. Since the polyacrylonyl tolyl-based carbon fiber and graphite are mixed together, the strength and heat resistance performance are significantly improved by the synergistic action, and high strength can be exhibited even at high temperature.

【0008】特に、セメントを主原料として水を混ぜて
混練した結合材中に、補強材としてポリアクリロニルト
リル系炭素繊維を混合し、且つ強化材としてグラファイ
トを混合し、その混合物を射出成形等の成形手段を用い
て成形し、これを養生させることにより固化して成形体
とした場合には、通常のセメント成形体と比較して高い
強度耐熱性能を有する成形体が得られる。
In particular, a polyacrylonyl tolyl-based carbon fiber as a reinforcing material and a graphite as a reinforcing material are mixed in a binder obtained by mixing and mixing water with cement as a main raw material, and the mixture is injection molded or the like. When the molded product is molded by using the above-mentioned molding means and is cured to be solidified into a molded product, a molded product having higher strength and heat resistance than the ordinary cement molded product can be obtained.

【0009】また、粉体又は顆粒状とした耐熱性樹脂を
主原料として溶融軟化した結合材中に、補強材としてポ
リアクリロニルトリル系炭素繊維を混合し、且つ強化材
としてグラファイトを混合し、その混合物を射出成形等
の成形手段を用いて成形し、これを冷却させることによ
り固化して成形体とした場合には、通常の耐熱性樹脂成
形体と比較して高い強度耐熱性能を有する成形体が得ら
れる。
Further, a polyacrylonyl tolyl-based carbon fiber is mixed as a reinforcing material and a graphite is mixed as a reinforcing material in a binder which is melted and softened by using a powder or granular heat-resistant resin as a main raw material. When the mixture is molded using a molding means such as injection molding, and when it is solidified by cooling it into a molded body, it has higher strength and heat resistance than ordinary heat-resistant resin molded bodies. The body is obtained.

【0010】[0010]

【実施例】以下本発明の実施例を説明する。EXAMPLES Examples of the present invention will be described below.

【0011】セメントを主原料として細骨材(砂)やケ
イ酸白土等のシリカ系混合材、炭酸カルシンウム粉末等
を加えたものに水を混ぜて混練した結合材中に、ポリア
クリロニルトリル(PAN)を不燃化した上で無酸素状
態で約1000℃で蒸し焼きにして得たポリアクリロニ
ルトリル系炭素繊維を補強材として混合し、且つ粉末化
したグラファイトを強化材として混合し、その混合物を
射出成形して養生させることにより固化して成形体を得
る。
Polyacrylonyl tril (in a binder obtained by mixing fine aggregate (sand), silica-based admixture such as silicate clay, calcium carbonate powder, etc. with cement as a main raw material and water and kneaded. PAN) is made incombustible and then steam-baked in an oxygen-free state at about 1000 ° C. to obtain a mixture of polyacrylonyl tolyl-based carbon fibers as a reinforcing material, and powdered graphite as a reinforcing material. It is solidified by injection molding and curing to obtain a molded body.

【0012】ここで、前記ポリアクリロニルトリル系炭
素繊維とグラファイトは、各々6:4の割合とし、結合
材中に適宜な量で混ぜると良い。
Here, the polyacrylonyl tolyl-based carbon fiber and graphite are preferably mixed in a ratio of 6: 4, and mixed in an appropriate amount in the binder.

【0013】以上の如くして得られた成形体は、ポリア
クリロニルトリル系炭素繊維が有する力学的特性によっ
て、特に引張り強度と引張り弾性率が大幅に向上され、
しかも、グラファイトの混合により耐熱性が大幅に向上
されるので、ポリアクリロニルトリル系炭素繊維とグラ
ファイトとを混合したことによる相乗的な作用により強
度耐熱性能が大幅に向上され、高温下でも高い強度を発
揮することが可能となる。
The molded product obtained as described above has a significantly improved tensile strength and tensile modulus due to the mechanical properties of the polyacrylonyl tolyl carbon fiber.
Moreover, since the heat resistance is greatly improved by mixing graphite, the strength and heat resistance performance is significantly improved by the synergistic effect of mixing the polyacrylonyl tolyl-based carbon fiber and graphite, and high strength even at high temperatures. Can be demonstrated.

【0014】特に、本実施例の如く、セメントを主原料
として水を混ぜて混練した結合材中に、補強材としてポ
リアクリロニルトリル系炭素繊維を混合し、且つ強化材
としてグラファイトを混合し、その混合物を射出成形
し、これを養生させることにより固化して成形体とした
場合には、通常のセメント成形体と比較して高い強度耐
熱性能を有する成形体が得られる。
In particular, as in this embodiment, a binder obtained by mixing water with cement as a main raw material and kneading is mixed with polyacrylonyl tolyl-based carbon fiber as a reinforcing material and graphite as a reinforcing material, When the mixture is injection-molded and cured to be solidified into a molded body, a molded body having higher strength and heat resistance than a normal cement molded body can be obtained.

【0015】更に付言すれば、セメントを主原料とした
結合材から成る成形体は、元々圧縮強度が高いという物
性を有しているので、前記ポリアクリロニルトリル系炭
素繊維の混合により引張り強度と引張り弾性率が大幅に
向上されれば、強度素材として極めて優れたものとな
り、しかもグラファイトの混合により耐熱性が大幅に向
上されれば、ビルの外壁や外装といった建材等としての
有用性が極めて高いものとなる。
In addition, since a molded body made of a binder whose main material is cement has a high compressive strength, it is possible to obtain a tensile strength by mixing the polyacrylonyl tolyl carbon fiber. If the tensile elastic modulus is greatly improved, it will be extremely excellent as a strength material, and if the heat resistance is greatly improved by mixing graphite, it will be extremely useful as a building material such as the outer wall or exterior of a building. Will be things.

【0016】また、結合材には、耐熱性樹脂を主原料と
したものを用いても良く、粉体又は顆粒状とした耐熱性
樹脂を主原料として溶融軟化した結合材中に、補強材と
してポリアクリロニルトリル系炭素繊維を混合し、且つ
強化材としてグラファイトを混合し、その混合物を射出
成形し、これを冷却させることにより固化して成形体と
した場合には、通常の耐熱性樹脂成形体と比較して高い
強度耐熱性能を有する成形体が得られる。
As the binder, a heat-resisting resin as a main raw material may be used, and a powder or granular heat-resisting resin as a main raw material is melted and softened in the binder to be used as a reinforcing material. When polyacrylonyl tolyl-based carbon fibers are mixed and graphite is mixed as a reinforcing material, the mixture is injection-molded, and the mixture is cooled to solidify into a molded body. A molded product having high strength and heat resistance as compared with the product can be obtained.

【0017】従って上記実施例によれば、高温下でも高
い強度を発揮し得る耐熱性高強度複合材料を得ることが
できるので、各種分野において従来のセメント製品や耐
熱樹脂製品に換えて広く用いることができる。
Therefore, according to the above-mentioned embodiment, it is possible to obtain a heat-resistant high-strength composite material capable of exhibiting high strength even at high temperatures, so that it can be widely used in various fields in place of conventional cement products and heat-resistant resin products. You can

【0018】尚、本発明の耐熱性高強度複合材料は、上
述の実施例にのみ限定されるものではなく、ポリアクリ
ロニルトリル系炭素繊維とグラファイトの配合比は6:
4を基準として目的や用途に応じて任意に変更すること
が可能であり、母材となる結合材に対する混合比率も任
意であること、その他、本発明の要旨を逸脱しない範囲
内において種々変更を加え得ることは勿論である。
The heat-resistant and high-strength composite material of the present invention is not limited to the above examples, and the compounding ratio of polyacrylonyl tolyl-based carbon fiber and graphite is 6:
It is possible to arbitrarily change it in accordance with the purpose and application based on 4, and the mixing ratio with respect to the binder as the base material is also arbitrary, and other various changes within the scope not departing from the gist of the present invention. Of course, it can be added.

【0019】[0019]

【発明の効果】上記した本発明の耐熱性高強度複合材料
によれば、高温下でも高い強度を発揮し得る耐熱性高強
度複合材料を得ることができるので、各種分野において
従来のセメント製品や耐熱樹脂製品に換えて広く用いる
ことができるという優れた効果を奏し得る。
The heat-resistant high-strength composite material of the present invention as described above makes it possible to obtain a heat-resistant high-strength composite material capable of exhibiting high strength even at high temperatures. It has an excellent effect that it can be widely used in place of the heat-resistant resin product.

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 FI 技術表示箇所 C08J 5/10 C08J 5/10 E04C 2/04 E04C 2/04 F 2/20 2/20 F // C08K 7/02 KCJ C08K 7/02 KCJ ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification code Internal reference number FI Technical display area C08J 5/10 C08J 5/10 E04C 2/04 E04C 2/04 F 2/20 2/20 F / / C08K 7/02 KCJ C08K 7/02 KCJ

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】 母材となる結合材中に、補強材としてポ
リアクリロニルトリル系炭素繊維が混合され且つ強化材
としてグラファイトが混合されていることを特徴とする
耐熱性高強度複合材料。
1. A heat-resistant and high-strength composite material comprising a binder as a base material, a polyacrylonyl tolyl-based carbon fiber as a reinforcing material, and graphite as a reinforcing material.
【請求項2】 母材となる結合材が、セメントを主原料
とするものであることを特徴とする請求項1に記載の耐
熱性高強度複合材料。
2. The heat-resistant high-strength composite material according to claim 1, wherein the binder as a base material is mainly composed of cement.
【請求項3】 母材となる結合材が、耐熱性樹脂を主原
料とするものであることを特徴とする請求項1に記載の
耐熱性高強度複合材料。
3. The heat-resistant high-strength composite material according to claim 1, wherein the binder serving as a base material is a heat-resistant resin as a main raw material.
JP8814195A 1995-04-13 1995-04-13 Heat resistant high strength composite material Pending JPH08283054A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP8814195A JPH08283054A (en) 1995-04-13 1995-04-13 Heat resistant high strength composite material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP8814195A JPH08283054A (en) 1995-04-13 1995-04-13 Heat resistant high strength composite material

Publications (1)

Publication Number Publication Date
JPH08283054A true JPH08283054A (en) 1996-10-29

Family

ID=13934665

Family Applications (1)

Application Number Title Priority Date Filing Date
JP8814195A Pending JPH08283054A (en) 1995-04-13 1995-04-13 Heat resistant high strength composite material

Country Status (1)

Country Link
JP (1) JPH08283054A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01167268A (en) * 1987-12-23 1989-06-30 Kawasaki Refract Co Ltd Carbon-containing uncalcined refractory
JPH02141452A (en) * 1988-11-24 1990-05-30 Shinagawa Refract Co Ltd Refractory containing carbon
JPH04219354A (en) * 1990-11-13 1992-08-10 Kazuji Fukunaga Hardening of mortar and concrete
JPH05286748A (en) * 1992-04-10 1993-11-02 Sekisui Chem Co Ltd Production of hydraulic composition and conductive hardened body

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01167268A (en) * 1987-12-23 1989-06-30 Kawasaki Refract Co Ltd Carbon-containing uncalcined refractory
JPH02141452A (en) * 1988-11-24 1990-05-30 Shinagawa Refract Co Ltd Refractory containing carbon
JPH04219354A (en) * 1990-11-13 1992-08-10 Kazuji Fukunaga Hardening of mortar and concrete
JPH05286748A (en) * 1992-04-10 1993-11-02 Sekisui Chem Co Ltd Production of hydraulic composition and conductive hardened body

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