JPH08279628A - Electroluminescent element - Google Patents

Electroluminescent element

Info

Publication number
JPH08279628A
JPH08279628A JP10324295A JP10324295A JPH08279628A JP H08279628 A JPH08279628 A JP H08279628A JP 10324295 A JP10324295 A JP 10324295A JP 10324295 A JP10324295 A JP 10324295A JP H08279628 A JPH08279628 A JP H08279628A
Authority
JP
Japan
Prior art keywords
transport layer
hole transport
conductive layer
layer
electroluminescent device
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP10324295A
Other languages
Japanese (ja)
Inventor
Tomoyuki Shirasaki
友之 白嵜
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Casio Computer Co Ltd
Original Assignee
Casio Computer Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Casio Computer Co Ltd filed Critical Casio Computer Co Ltd
Priority to JP10324295A priority Critical patent/JPH08279628A/en
Publication of JPH08279628A publication Critical patent/JPH08279628A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00Organic light-emitting devices
    • H10K50/10OLEDs or polymer light-emitting diodes [PLED]
    • H10K50/14Carrier transporting layers
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00Organic light-emitting devices
    • H10K50/10OLEDs or polymer light-emitting diodes [PLED]
    • H10K50/17Carrier injection layers

Landscapes

  • Electroluminescent Light Sources (AREA)
  • Led Devices (AREA)

Abstract

PURPOSE: To provide an electroluminecent element which is large in light emission quantity per unit area. CONSTITUTION: A porous conductive layer 13 is formed on a transparent electrode 12, and a hole transfer layer 14 formed of organic semiconductor material is provided onto the conductive layer 13. As the hole transfer layer 14 is filled into porosities inside the porous conductive layer 13, holes injected into the conductive layer 13 from the transparent electrode 12 are injected into the hole transfer layer 14 through the inner walls of the porosities. As the inner walls of the porosities are large in total area, a large amount of holes can be injected into the hole transfer layer 14, and light emitted at an interface between the hole transfer layer 14 and the electron transfer layer 15 is increased in quantity and brightness.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】この発明は、電界発光素子に関す
る。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an electroluminescent device.

【0002】[0002]

【従来の技術】従来、この種の電界発光素子としては、
図7に示すような構造の発光ダイオード(LED)が知
られている。この発光ダイオードは、同図に示すよう
に、ガラスなどでなる透明基板1上に透明電極(アノー
ド電極)2が形成され、透明電極2上に有機材料からな
る正孔輸送層(P型半導体層)3が形成されている。そ
して、この正孔輸送層3上には、有機材料からなる電子
輸送層(N型半導体層)4が接合され、電子輸送層4の
上にアルミニウムなどでなる背面電極(カソード電極)
5が形成されることにより、発光ダイオードが構成され
ている。なお、上記した透明電極2は、その透明性や仕
事関数の値を主な理由としてITO(IndiumTin Oxid
e)が用いられている。
2. Description of the Related Art Conventionally, as an electroluminescent device of this type,
A light emitting diode (LED) having a structure as shown in FIG. 7 is known. As shown in the figure, in this light emitting diode, a transparent electrode (anode electrode) 2 is formed on a transparent substrate 1 made of glass or the like, and a hole transport layer (P-type semiconductor layer) made of an organic material is formed on the transparent electrode 2. ) 3 is formed. An electron transport layer (N-type semiconductor layer) 4 made of an organic material is bonded onto the hole transport layer 3, and a back electrode (cathode electrode) made of aluminum or the like is formed on the electron transport layer 4.
The formation of 5 forms a light emitting diode. The above-mentioned transparent electrode 2 is mainly made of ITO (Indium Tin Oxid) mainly because of its transparency and work function value.
e) is used.

【0003】このような構成において、透明電極2から
はその界面を介して正孔輸送層3へ正孔が注入され、背
面電極5からはその界面を介して電子輸送層4へ電子が
注入される。正孔輸送層3からは正孔が、電子輸送層4
からは電子がPN接合に移動して、正孔と電子とが再結
合し、その際に光を発するようになっている。
In such a structure, holes are injected from the transparent electrode 2 into the hole transport layer 3 through its interface, and electrons are injected from the back electrode 5 into the electron transport layer 4 through its interface. It Holes from the hole transport layer 3 and electrons from the electron transport layer 4
From this point, the electrons move to the PN junction, the holes and the electrons are recombined, and at that time, light is emitted.

【0004】[0004]

【発明が解決しようとする課題】このような電界発光素
子においては、正孔の注入効率は単位発光面積当たりの
注入界面面積が大きいことが好ましいが、透明電極(I
TO膜)2が一般的に蒸着、スパッタなどの手段により
透明基板1の平坦な表面上に形成されているため、形成
される透明電極表面も同様に平坦なものであり、単位発
光面積当たりの注入界面面積の増大という改善を行うこ
とは困難であった。また、透明電極2上の正孔輸送層3
と電子輸送層4との界面も同様に平坦な面であるため、
その接合面積を大きくして発光量を増大させるのに素子
の大型化を招くという問題があった。
In such an electroluminescent device, the hole injection efficiency is preferably such that the injection interface area per unit light emitting area is large, but the transparent electrode (I
Since the TO film) 2 is generally formed on the flat surface of the transparent substrate 1 by means such as vapor deposition or sputtering, the surface of the transparent electrode formed is also flat, which is It was difficult to make the improvement of increasing the injection interface area. In addition, the hole transport layer 3 on the transparent electrode 2
Since the interface between the electron transport layer 4 and the electron transport layer 4 is also a flat surface,
There is a problem in that the element is upsized in order to increase the amount of light emission by increasing the bonding area.

【0005】この発明は、単位面積当たりの発光量が大
きな高輝度の電界発光素子を提供することを目的として
いる。
An object of the present invention is to provide a high-brightness electroluminescent device which emits a large amount of light per unit area.

【0006】[0006]

【課題を解決するための手段】請求項1記載の発明は、
アノード電極上に正孔輸送層が形成され、前記正孔輸送
層上に電子輸送層が接合され、前記電子輸送層上にカソ
ード電極が形成されてなる電界発光素子において、前記
アノード電極は複数の孔が形成された導電層からなり、
前記孔の表面に前記正孔輸送層が接触していることを特
徴としている。請求項2記載の発明は、前記導電層が、
P型の不純物を導入した半導体材料でなることを特徴と
している。請求項3記載の発明は、アノード電極上に正
孔輸送層が形成され、前記正孔輸送層上に電子輸送層が
接合され、前記電子輸送層上にカソード電極が形成され
てなる電界発光素子において、前記正孔輸送層の前記電
子輸送層と接合する面に凹凸が形成されていることを特
徴としている。請求項4記載の発明は、前記正孔輸送層
は、アモルファスシリコンからなり前記凹凸が、正孔輸
送層の表面を陽極酸化した後にエッチングして形成され
たことを特徴としている。
According to the first aspect of the present invention,
In an electroluminescent device having a hole transport layer formed on an anode electrode, an electron transport layer bonded on the hole transport layer, and a cathode electrode formed on the electron transport layer, the anode electrode is composed of a plurality of anode electrodes. Consisting of a conductive layer with holes formed,
The hole transport layer is in contact with the surface of the hole. In the invention according to claim 2, the conductive layer is
It is characterized by being made of a semiconductor material into which a P-type impurity is introduced. According to a third aspect of the present invention, an electroluminescent device having a hole transport layer formed on an anode electrode, an electron transport layer bonded to the hole transport layer, and a cathode electrode formed on the electron transport layer. In the above, the surface of the hole transport layer which is joined to the electron transport layer is formed with irregularities. The invention according to claim 4 is characterized in that the hole transport layer is made of amorphous silicon, and the irregularities are formed by etching after anodizing the surface of the hole transport layer.

【0007】[0007]

【作用】請求項1および請求項2記載の発明において
は、アノード電極と正孔輸送層との間に設けられた導電
層にアノード電極から正孔が注入され、導電層から正孔
輸送層へ正孔が注入される。特に、導電層には孔が形成
され、かつこの孔内に正孔輸送層が入り込んでいる構成
であるため、導電層と正孔輸送層との接触面積(注入界
面面積)が単なる平面での接触に比較して大きくなり、
この接触面を介して多量の正孔が正孔輸送層へ注入され
る。このため、素子の単位面積当たりの発光量が増加
し、高輝度化を図ることができる。請求項3および4記
載の発明においては、正孔輸送層の電子輸送層と接合す
る面に凹凸が形成されているため、正孔及び電子が再結
合する面積が大きく発光面積が増加する。
In the inventions of claims 1 and 2, holes are injected from the anode electrode into the conductive layer provided between the anode electrode and the hole transport layer, and the conductive layer is transferred to the hole transport layer. Holes are injected. In particular, since the hole is formed in the conductive layer and the hole transport layer is in the hole, the contact area (injection interface area) between the conductive layer and the hole transport layer is a simple plane. It becomes bigger compared to contact,
A large amount of holes are injected into the hole transport layer via this contact surface. Therefore, the amount of light emission per unit area of the device is increased, and high brightness can be achieved. In the inventions of claims 3 and 4, since the surface of the hole transporting layer that is in contact with the electron transporting layer is provided with irregularities, the area where holes and electrons are recombined is large and the light emitting area is increased.

【0008】[0008]

【実施例】以下、この発明に係る電界発光素子の詳細を
図面に示す各実施例に基づいて説明する。 (実施例1)図1は、本発明の電界発光素子の実施例1
を示す断面図である。図中、10は本実施例の電界発光
素子を示している。この電界発光素子10では、ガラス
などでなる透明基板11上に、ITOでなるアノード電
極としての透明電極12が形成されている。透明電極1
2上には、高密度な細孔が広がっている(連続)多孔質
な導電層13が形成されている。なお、この細孔は導電
層13の上下方向に曲がりくねりながらも貫通するよう
になっている。この導電層13は、例えばボロン(B)
などのP型不純物を導入したアモルファスシリコンでな
る。そして、導電層13上には、P型の有機半導体材料
でなる正孔輸送層14が設けられると共に、この正孔輸
送層14は導電層13内に形成された細孔内にも密に充
填されている。なお、このように導電層13内の細孔内
に正孔輸送層14を充填するには、正孔輸送層14を湿
式の成膜法で形成することで可能となる。また、正孔輸
送層14上には、N型の半導体材料でなる電子輸送層1
5が接合するように形成されている。さらに、電子輸送
層15上には、例えばアルミニウムなどでなるカソード
電極としての背面電極16が形成されている。
DESCRIPTION OF THE PREFERRED EMBODIMENTS The details of the electroluminescent device according to the present invention will be described below with reference to the embodiments shown in the drawings. (Embodiment 1) FIG. 1 shows Embodiment 1 of the electroluminescent device of the present invention.
FIG. In the figure, 10 indicates the electroluminescent element of the present embodiment. In this electroluminescent device 10, a transparent electrode 12 made of ITO as an anode electrode is formed on a transparent substrate 11 made of glass or the like. Transparent electrode 1
On (2), a (continuous) porous conductive layer 13 in which high-density pores are spread is formed. The pores are formed so that they penetrate the conductive layer 13 while winding in the vertical direction. The conductive layer 13 is, for example, boron (B).
It is made of amorphous silicon introduced with P-type impurities such as. A hole transport layer 14 made of a P-type organic semiconductor material is provided on the conductive layer 13, and the hole transport layer 14 is also densely filled in the pores formed in the conductive layer 13. Has been done. The hole transport layer 14 can be filled in the pores in the conductive layer 13 as described above by forming the hole transport layer 14 by a wet film forming method. The electron transport layer 1 made of an N-type semiconductor material is formed on the hole transport layer 14.
5 are formed so as to be joined. Further, on the electron transport layer 15, a back electrode 16 made of, for example, aluminum as a cathode electrode is formed.

【0009】本実施例では、導電層13が連続多孔質の
構造を有するため、正孔輸送層14と導電層13との接
触面積は著しく大きくなり、透明電極12から正孔輸送
層14に導電層13を介して注入される正孔の量も増大
する。このため、電子輸送層15との界面に移動できる
正孔の量が多く、背面電極16から電子輸送層15に注
入された電子と、正孔輸送層14からの正孔とが界面で
多くの再結合を行うため、正孔輸送層14と電子輸送層
15との接合の単位面積当たりの発光量が増大し、高輝
度化を達成することができる。
In this embodiment, since the conductive layer 13 has a continuous porous structure, the contact area between the hole transport layer 14 and the conductive layer 13 is significantly increased, and the transparent electrode 12 conducts to the hole transport layer 14. The amount of holes injected through layer 13 also increases. Therefore, a large amount of holes can move to the interface with the electron transport layer 15, and many electrons injected from the back electrode 16 into the electron transport layer 15 and holes from the hole transport layer 14 are present at the interface. Since recombination is performed, the amount of light emission per unit area of the junction between the hole transport layer 14 and the electron transport layer 15 is increased, and high brightness can be achieved.

【0010】(実施例2)図2は本発明の電界発光素子
の実施例2を示す断面図であり、図3は本実施例の電界
発光素子の導電層13の斜視図である。本実施例では、
図に示すように、透明電極12上に形成する導電層13
を、複数の突堤部13Aを平行に並べた構造としてい
る。そして、図2に示すように、導電層12上に正孔輸
送層14が形成されると共に、導電層12を構成する突
堤部13Aどうしの間に正孔輸送層14が充填されるよ
うになっている。このような導電層13を形成するに
は、リソグラフィー技術およびエッチング技術を用いる
ことにより、突堤部13A…をパターニングすることが
できる。本実施例における他の構成は、上記実施例1と
同様である。本実施例においても、上記実施例と同様の
作用、効果を得ることができる。
(Embodiment 2) FIG. 2 is a sectional view showing Embodiment 2 of the electroluminescent device of the present invention, and FIG. 3 is a perspective view of the conductive layer 13 of the electroluminescent device of this embodiment. In this embodiment,
As shown in the figure, the conductive layer 13 formed on the transparent electrode 12
Has a structure in which a plurality of jetty portions 13A are arranged in parallel. Then, as shown in FIG. 2, the hole transport layer 14 is formed on the conductive layer 12, and the hole transport layer 14 is filled between the jetty portions 13A forming the conductive layer 12. ing. In order to form such a conductive layer 13, the jetty portions 13A ... Can be patterned by using a lithography technique and an etching technique. Other configurations in this embodiment are similar to those in the above-mentioned first embodiment. Also in this embodiment, it is possible to obtain the same actions and effects as those of the above embodiment.

【0011】(実施例3)図4は、本発明の電界発光素
子の実施例3における導電層13の構造を示す斜視図で
ある。この導電層13は、上下方向(背面電極16と透
明電極12とを結ぶ方向)に貫通する横断面矩形状の孔
13Bが多数形成された構造である。本実施例において
も、他の構成は上記実施例1と同様であり、作用、効果
も同様である。
(Embodiment 3) FIG. 4 is a perspective view showing the structure of the conductive layer 13 in Embodiment 3 of the electroluminescent device of the present invention. The conductive layer 13 has a structure in which a large number of holes 13B having a rectangular cross section are formed so as to penetrate in the up-down direction (direction connecting the back electrode 16 and the transparent electrode 12). Also in this embodiment, the other structure is the same as that of the first embodiment, and the operation and effect are also the same.

【0012】(実施例4)図5は、本発明の電界発光素
子の実施例4を示す断面図であり、図6は本実施例の電
界発光素子の正孔輸送層を示す平面図である。本実施例
は、ガラスなどでなる透明基板11上にITOでなる透
明電極12が形成され、透明電極12上に、上面に凹部
14Aと凸部14Bが形成された正孔輸送層14が形成
されている。そして、この正孔輸送層14上には、湿式
の成膜法によりEL特性を示す有機半導体材料でなる電
子輸送層15が形成されている。さらに、電子輸送層1
5上には、アルミニウムなどでなる背面電極16が形成
されている。
(Embodiment 4) FIG. 5 is a sectional view showing an embodiment 4 of the electroluminescent device of the present invention, and FIG. 6 is a plan view showing a hole transport layer of the electroluminescent device of the present embodiment. . In this embodiment, the transparent electrode 12 made of ITO is formed on the transparent substrate 11 made of glass, and the hole transport layer 14 having the concave portions 14A and the convex portions 14B formed on the upper surface is formed on the transparent electrode 12. ing. An electron transport layer 15 made of an organic semiconductor material exhibiting EL characteristics is formed on the hole transport layer 14 by a wet film forming method. Further, the electron transport layer 1
A back electrode 16 made of aluminum or the like is formed on the surface 5.

【0013】本実施例においては、正孔輸送層14がP
型のアモルファスシリコンでなる。この正孔輸送層14
の上面に凹部14Aおよび凸部14Bを形成するには、
アモルファスシリコンの表面を陽極酸化して表面にポー
ラス形皮膜を形成し、このポーラス形皮膜をウェットエ
ッチングで除去することにより、図5に示すような凹凸
を有する正孔輸送層14形成できる。凹部14Aは、図
6に示すように、多数が開設されており、電子輸送層1
5がこの凹部14A内に入り込むようになっている。こ
のため、正孔輸送層14と電子輸送層15とのPN接合
面の面積は、単に平面で接合するものに比較して大幅に
大きくなっている。この結果、発光面積が増大し、1素
子当たりの発光量が大幅に大きくなっている。
In this embodiment, the hole transport layer 14 is P
Type of amorphous silicon. This hole transport layer 14
To form the concave portions 14A and the convex portions 14B on the upper surface of
The surface of the amorphous silicon is anodized to form a porous film on the surface, and the porous film is removed by wet etching to form the hole transport layer 14 having irregularities as shown in FIG. As shown in FIG. 6, a large number of recesses 14A are provided, and the electron transport layer 1
5 enters into this recess 14A. For this reason, the area of the PN junction surface between the hole transport layer 14 and the electron transport layer 15 is significantly larger than that of a mere mere plane junction. As a result, the light emitting area is increased, and the light emission amount per element is significantly increased.

【0014】以上、実施例1〜実施例4について説明し
たが、本発明はこれらに限定されるものではなく、構成
の要旨に付随する各種の設計変更が可能である。
Although the first to fourth embodiments have been described above, the present invention is not limited to these, and various design changes associated with the gist of the configuration can be made.

【0015】[0015]

【発明の効果】以上の説明から明らかなように、請求項
1および請求項2記載の発明によれば、効果を正孔輸送
層へ多くの正孔を注入することが可能となり、単位面積
当たりの発光量を増加させる効果を奏する。また、所望
の輝度を得るために、より低い電圧での駆動が可能にな
る。このため、本発明をディスプレイに適用すれば高輝
度な表示で消費電力の少ないディスプレイを実現するこ
とができる。また、請求項3〜6記載の発明において
は、正孔輸送層と電子輸送層との接合面積を実質的に増
加させることができるため、発光面積を増やすことがで
き、1素子当たりの発光量を増加させる効果を奏する。
As is apparent from the above description, according to the first and second aspects of the present invention, it is possible to inject a large number of holes into the hole transport layer, and it is possible to increase the number of holes per unit area. The effect of increasing the light emission amount of is produced. In addition, it is possible to drive at a lower voltage in order to obtain a desired brightness. Therefore, by applying the present invention to a display, a display with high brightness and low power consumption can be realized. Further, in the inventions according to claims 3 to 6, since the junction area between the hole transport layer and the electron transport layer can be substantially increased, the light emitting area can be increased, and the amount of light emitted per element is increased. Has the effect of increasing.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の実施例1の断面図。FIG. 1 is a sectional view of a first embodiment of the present invention.

【図2】本発明の実施例2の断面図。FIG. 2 is a sectional view of a second embodiment of the present invention.

【図3】本発明の実施例2の導電層の斜視図。FIG. 3 is a perspective view of a conductive layer according to a second embodiment of the present invention.

【図4】本発明の実施例3の導電層の斜視図。FIG. 4 is a perspective view of a conductive layer according to a third embodiment of the present invention.

【図5】本発明の実施例4の断面図。FIG. 5 is a sectional view of a fourth embodiment of the present invention.

【図6】本発明の実施例4の正孔輸送層の平面図。FIG. 6 is a plan view of a hole transport layer of Example 4 of the present invention.

【図7】従来の電界発光素子の断面図。FIG. 7 is a cross-sectional view of a conventional electroluminescent device.

【符号の説明】[Explanation of symbols]

12 透明電極 13 導電層 13A 突堤部 13B 孔 14 正孔輸送層 14A 凹部 14B 凸部 15 電子輸送層 16 背面電極 12 Transparent Electrode 13 Conductive Layer 13A Jetty 13B Hole 14 Hole Transport Layer 14A Recess 14B Convex 15 Electron Transport Layer 16 Back Electrode

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 アノード電極上に正孔輸送層が形成さ
れ、前記正孔輸送層上に電子輸送層が接合され、前記電
子輸送層上にカソード電極が形成されてなる電界発光素
子において、 前記アノード電極は複数の孔が形成された導電層からな
り、前記孔の表面に前記正孔輸送層が接触していること
を特徴とするの電界発光素子。
1. An electroluminescent device comprising a hole transport layer formed on an anode electrode, an electron transport layer bonded on the hole transport layer, and a cathode electrode formed on the electron transport layer. The electroluminescent device, wherein the anode electrode comprises a conductive layer having a plurality of holes formed therein, and the hole transport layer is in contact with the surface of the holes.
【請求項2】 前記導電層は、P型の不純物を導入した
半導体材料でなることを特徴とする請求項1記載の電界
発光素子。
2. The electroluminescent device according to claim 1, wherein the conductive layer is made of a semiconductor material into which a P-type impurity is introduced.
【請求項3】 アノード電極上に正孔輸送層が形成さ
れ、前記正孔輸送層上に電子輸送層が接合され、前記電
子輸送層上にカソード電極が形成されてなる電界発光素
子において、 前記正孔輸送層の前記電子輸送層と接合する面に凹凸が
形成されていることを特徴とする電界発光素子。
3. An electroluminescent device comprising a hole transport layer formed on an anode electrode, an electron transport layer bonded on the hole transport layer, and a cathode electrode formed on the electron transport layer. An electroluminescent device, characterized in that unevenness is formed on a surface of the hole transport layer which is joined to the electron transport layer.
【請求項4】 前記正孔輸送層は、アモルファスシリコ
ンからなり、前記凹凸は、正孔輸送層の表面を陽極酸化
した後にエッチングして形成されたことを特徴とする請
求項3記載の電界発光素子。
4. The electroluminescence according to claim 3, wherein the hole transport layer is made of amorphous silicon, and the irregularities are formed by etching the surface of the hole transport layer after anodizing. element.
JP10324295A 1995-04-05 1995-04-05 Electroluminescent element Pending JPH08279628A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP10324295A JPH08279628A (en) 1995-04-05 1995-04-05 Electroluminescent element

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10324295A JPH08279628A (en) 1995-04-05 1995-04-05 Electroluminescent element

Publications (1)

Publication Number Publication Date
JPH08279628A true JPH08279628A (en) 1996-10-22

Family

ID=14348978

Family Applications (1)

Application Number Title Priority Date Filing Date
JP10324295A Pending JPH08279628A (en) 1995-04-05 1995-04-05 Electroluminescent element

Country Status (1)

Country Link
JP (1) JPH08279628A (en)

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