JPH08267887A - Manufacture of penetration stamp - Google Patents

Manufacture of penetration stamp

Info

Publication number
JPH08267887A
JPH08267887A JP972596A JP972596A JPH08267887A JP H08267887 A JPH08267887 A JP H08267887A JP 972596 A JP972596 A JP 972596A JP 972596 A JP972596 A JP 972596A JP H08267887 A JPH08267887 A JP H08267887A
Authority
JP
Japan
Prior art keywords
stamp
melting
heat
stamp material
substance
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP972596A
Other languages
Japanese (ja)
Other versions
JP2946456B2 (en
Inventor
Yoichi Ando
陽一 安藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Pencil Co Ltd
Original Assignee
Mitsubishi Pencil Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Pencil Co Ltd filed Critical Mitsubishi Pencil Co Ltd
Priority to JP972596A priority Critical patent/JP2946456B2/en
Publication of JPH08267887A publication Critical patent/JPH08267887A/en
Application granted granted Critical
Publication of JP2946456B2 publication Critical patent/JP2946456B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Manufacture Or Reproduction Of Printing Formes (AREA)

Abstract

PURPOSE: To obtain a manufacturing method for a penetration stamp having open cell, simple in process and a device for manufacturing, and provide a penetration stamp capable of obtaining fresh and clear image and excellent in handling convenience. CONSTITUTION: A heat generating and melting substance 5, obtained by applying a hot melt substance 5, generating heat by the projection of infrared rays and molten at a temperature higher than the temperature of a stamp material, on an infrared rays penetratable film by the thickness of 0.5-10μm, is superposed on the surface of a stamp material S7, made of an elastic resin having a stamp ink impregnatable open cell, so that the hot melt substance 5 is contacted with the surface of the stamp material S7, then, a desired image copy L is superposed thereon while coating a liquid substance so as to obtain a mirror image. Then, a flash of light, including infrared rays, is projected from the upper part of the copy L under a condition that the stamp material S7 is compressed by 5-70% whereby the hot melt substance 5 on a part corresponding to a part B on the image copy L, on which the copy image is not existing, is heated and molten while the hot melt substance, generating heat in such a manner, as is impregnated into the stamp material and the surface layer of the stamp material S7 is molten thereby forming an impregnated and molten part H, in which the open cell is blocked.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は浸透印版の作製法に
関する。さらに詳しくは、あらかじめスタンプ材にスタ
ンプインキを含浸させておくことにより長時間スタプイ
ンキを補給することなく、捺印を繰り返すことができる
連続気泡を有するスポンジ材からなる浸透印版の作製法
の改良に関する。
TECHNICAL FIELD The present invention relates to a method for producing a permeation printing plate. More specifically, the present invention relates to an improvement in a method for producing a permeation printing plate made of a sponge material having open cells that can repeat printing without replenishing the stap ink for a long time by impregnating the stamp material with the stamp ink in advance.

【0002】[0002]

【従来の技術】印判、スタンプを捺印する際にスタンプ
インキを印面にその都度付着する手間を省くため連続気
泡を有するスポンジゴムを印材として、これにあらかじ
めスタプインキを吸蔵させたスタンプが知られている。
そのスタンプの作製法として特開昭60−193686
号公報には、スポンジの表面の印影を形成する部分を除
いた全面箇所を加熱型押加工により凹状に陥没させ押し
固め、凸部をスタプインキ吸蔵部として印影形成部とす
るスタンプの作製法が開示され、特開昭50−1553
23号にも同様の加熱板上に多孔質体を圧着する方法が
開示されている。しかし、これらの方法は、加熱板とす
る金型とそれに文字、記号、図形などを彫刻もしくは蝕
刻する手間が必要である。
2. Description of the Related Art A stamp is known in which a sponge rubber having open cells is used as a printing material in order to save the time and effort of adhering the stamp ink to the printing surface each time a stamp or stamp is imprinted, and the stap ink is absorbed therein in advance. .
As a method for producing the stamp, JP-A-60-193686
Japanese Patent Publication discloses a method for producing a stamp in which the entire surface of the sponge except for the portion where the imprint is formed is depressed by heat embossing and pressed, and the convex portion is used as the stamp ink storage portion and the imprint forming portion. Japanese Patent Application Laid-Open No. 50-1553
No. 23 also discloses a method of pressing a porous body on a similar heating plate. However, these methods require a die as a heating plate and a labor for engraving or etching letters, symbols, figures and the like on the die.

【0003】また、特開昭57−136652号公報、
特開昭49−7003号公報には、スタンプ材の表面に
光重合性液状樹脂を塗布し、この上面にポジフィルムを
置き上方より紫外線を照射して光重合反応をおこさせ、
未反応の樹脂を洗浄して除去し、除去した部分よりスタ
ンプ材の表面に露出させる印版の作製法が開示され、ま
た実開昭52−71710号には、ネガフィルムを用い
て同様の方法による平版印判が開示されている。しか
し、これらの方法は、ネガまたはポジフィルムの作成、
樹脂の塗布、光重合、水洗など工程が複雑であり、所望
のスタンプを迅速に提供できる作製法が望まれている。
すなわち、小さな閃光照射エネルギーで製版可能で簡単
な工程の印版作製法が望まれる。また、特開平3−96
383には、つぎのようなことが開示されている。「製
版済みの孔版原紙を多孔材の表面に重合密着させ、この
孔版原紙の表面にスタンプインキ通過の阻止手段として
の目詰まり用樹脂をのせスキージによって印刷する。こ
の目詰まり用樹脂は孔版原紙の画像開口部を通り、画像
開口部に対応した形状で多孔材の表面に含浸しその部分
の気孔が目詰りする。この目詰まり用樹脂が硬化した
後、多孔材全体にスタンプインキを含浸させてスタンプ
として使用することが可能である。」以上のように、従
来の連続気泡を有する浸透印版の作製法は手数がかかっ
たり、鮮明な印影が得られず、印影の鮮明な所望のスタ
ンプを迅速に提供できる作製法が望まれている。
Further, Japanese Patent Laid-Open No. 57-136652,
In JP-A-49-7003, a photopolymerizable liquid resin is applied to the surface of a stamp material, a positive film is placed on the upper surface of the stamp material, and ultraviolet rays are irradiated from above to cause a photopolymerization reaction.
A method for producing a printing plate is disclosed in which unreacted resin is removed by washing, and the removed portion is exposed on the surface of the stamp material. Further, Japanese Utility Model Publication No. 52-71710 discloses a similar method using a negative film. A lithographic stamp is disclosed. However, these methods are used to make negative or positive films,
Processes such as resin coating, photopolymerization, and water washing are complicated, and a manufacturing method capable of rapidly providing a desired stamp is desired.
That is, it is desired to provide a printing plate manufacturing method that enables plate making with a small flash irradiation energy and has a simple process. In addition, JP-A-3-96
383 discloses the following. “A stencil sheet that has been prepressed is polymerized and adhered to the surface of the porous material, and a clogging resin as a means for preventing the passage of stamp ink is placed on the surface of the stencil sheet and printed with a squeegee. After passing through the image opening, the surface of the porous material is impregnated with a shape corresponding to the image opening, and the pores in that area are clogged.After the resin for clogging is cured, the entire porous material is impregnated with the stamp ink. It is possible to use it as a stamp. "As described above, the conventional method for producing a permeation printing plate having open cells does not take a lot of time and a clear imprint cannot be obtained, and a desired stamp with a clear imprint can be obtained. A production method that can be provided promptly is desired.

【0004】[0004]

【発明が解決しようとする課題】本発明の目的は、上記
の問題点を解決することにあり、作製工程、装置が簡便
で連続気泡を有する浸透印版の作製法と、さらに鮮明な
印影が得られ、使い勝手のよい浸透印版を提供すること
にある。
SUMMARY OF THE INVENTION An object of the present invention is to solve the above-mentioned problems, and a method of manufacturing a permeation printing plate having continuous cells with a simple manufacturing process and apparatus, and a clearer impression. The object is to provide a penetrating printing plate that is obtained and is easy to use.

【0005】[0005]

【課題を解決するための手段】本発明者は、上記目的を
達成するために、鋭意研究を重ねた結果、赤外線の照射
で発熱しスタンプ材に浸透可能な熱溶融性物質の塗布さ
れた発熱溶融シートを使用すること、スタンプ材を加圧
しながら赤外線を照射すること、印影原稿に水を含む液
状物質を塗布するなどの方法を見出し、本発明の浸透印
版の作製法を完成するに至った。
The inventors of the present invention have conducted extensive studies in order to achieve the above-mentioned object, and as a result, heat generated by irradiation of infrared rays and applied with a heat-melting substance capable of penetrating a stamp material is applied. Using a fused sheet, irradiating infrared rays while pressing the stamp material, applying a liquid substance containing water to the imprint original, and the like, have led to the completion of the method for producing the permeation printing plate of the present invention. It was

【0006】すなわち、本発明の浸透印版の作製法は、
スタンプインキ含浸可能な連続気泡を有する弾性樹脂製
のスタンプ材の表面に、赤外線の照射により発熱して該
スタンプ材の溶融温度以上で溶融する熱溶融性物質が赤
外線透過可能なフィルムに0.5〜10μの厚みに塗布
された発熱溶融シートを、該熱溶融性物質がスタンプ材
表面と接するように重ね、その上に所望の印影原稿を鏡
像となるように重ね、該スタンプ材を5〜70%圧縮し
た状態で該原稿の上方より赤外線を含む閃光を照射する
ことにより、印影原稿の原稿像不在部分は赤外線を透過
して発熱溶融シートに到達した赤外線が前記原稿像不在
部分に対応する部分の熱溶融性物質を発熱溶融させ、こ
の発熱した熱溶融性物質がスタンプ材に浸透するととも
にスタンプ材表層を溶融して連続気泡の閉塞された浸透
溶融部(スタンプインキ非滲出部)を形成し、一方印影
原稿の原稿像部分は赤外線を遮断もしくは吸収して、こ
れと対応する発熱溶融シートの部分の熱溶融性物質は発
熱溶融せずに対応するスタンプ材の表面の気泡閉塞に至
らず非溶融部(スタンプインキ滲出部)を形成し、スタ
ンプ材の非溶融部に対し浸透溶融部を0.01mm以上
の凹部とすることを特徴とする。用いるスタンプ材とし
ては、溶融温度が50〜150℃であり立体網目構造の
平均気孔径2〜10μの微細連続気孔を有し気孔率30
〜80%のポリオレフィン系フォームの0.5〜30mm
厚のシートが好ましく、発熱溶融シートは少なくともカ
ーボンまたは高分子物質を含み溶融温度が50〜200
℃であり溶融粘度が50〜2000mPa・sである熱
溶融性物質を赤外線透過可能なシートに塗布したものが
好ましい。さらに印影原稿に液状物質を塗布するのが好
ましい。
That is, the method for producing the penetrating printing plate of the present invention is as follows:
The surface of a stamp material made of an elastic resin having open cells that can be impregnated with the stamp ink is heated to a temperature above the melting temperature of the stamp material by being heated by the irradiation of infrared rays to form a heat-meltable substance in an infrared permeable film. A heat-melting sheet applied to a thickness of 10 μm is overlaid so that the heat-fusible substance is in contact with the surface of the stamp material, and a desired imprint original document is overlaid thereon so as to form a mirror image. By irradiating a flash containing infrared rays from above the original in a compressed state, the original image absent portion of the imprint original passes through the infrared rays and reaches the heat-melting sheet. The infrared rays correspond to the original image absent portion. The heat-fusible substance is melted by heat, and the heat-melted substance that has generated heat permeates the stamp material and also melts the surface layer of the stamp material to block the open-cells. Non-bleeding area), while the original image portion of the imprint original blocks or absorbs infrared rays, and the corresponding heat-melting material in the heat-melting sheet portion does not heat-melt and does not melt in the corresponding stamp material. It is characterized in that a non-melting portion (stamp ink exuding portion) is formed without causing air bubbles to be blocked on the surface, and the permeation-melting portion is a recess of 0.01 mm or more with respect to the non-melting portion of the stamp material. The stamp material used has a melting temperature of 50 to 150 ° C. and has fine continuous pores having an average pore diameter of 2 to 10 μ having a three-dimensional network structure and a porosity of 30.
~ 80% of polyolefin foam 0.5 ~ 30mm
A thick sheet is preferable, and the exothermic melting sheet contains at least carbon or a polymer material and has a melting temperature of 50 to 200.
It is preferable to apply a heat-meltable substance having a melt viscosity of 50 to 2000 mPa · s at a temperature of ℃ to an infrared ray permeable sheet. Furthermore, it is preferable to apply a liquid substance to the imprint original.

【0007】本発明の浸透印版は、スタンプインキ含浸
可能な連続気泡を有する弾性樹脂製のスタンプ材からな
るスタンプインキ含浸部、および該スタンプ材表面で形
成されるスタンプインキ滲出部と該インキ滲出部より
0.01mm以上の凹部を形成してなるスタンプインキ
非滲出部とからなる印面を有し、該スタンプインキ非滲
出部が熱溶融性物質浸透部とスタンプ材溶融部との混在
する浸透溶融混合部およびスタンプ材溶融部からなるこ
とを特徴とする。好ましくは、スタンプ材が、溶融温度
が50〜150℃、平均気孔径2〜10μ、気孔率30
〜80%、厚み0.5〜30mmのポリオレフィン系フォ
ームシートからなる。またスタンプ材は、長さ5〜50
0mm、幅5〜200mmであるのが好ましい。
The permeation printing plate of the present invention comprises a stamp ink impregnated portion made of an elastic resin stamp material having open cells capable of impregnating the stamp ink, a stamp ink exudation portion formed on the stamp material surface and the ink exudation. Portion having a stamp ink non-bleeding portion in which a recessed portion of 0.01 mm or more is formed, and the stamp ink non-bleeding portion is a mixture of a heat-melting substance-permeating portion and a stamp material-melting portion. It is characterized by comprising a mixing section and a stamp material melting section. Preferably, the stamp material has a melting temperature of 50 to 150 ° C., an average pore diameter of 2 to 10 μm, and a porosity of 30.
It is composed of a polyolefin foam sheet having a thickness of -80% and a thickness of 0.5 to 30 mm. Also, the stamp material is 5 to 50 in length.
It is preferable that the width is 0 mm and the width is 5 to 200 mm.

【0008】[0008]

【発明の実施の形態】本発明の印版の作製法に用いるス
タンプインキ含浸可能な連続気泡を有するスタンプ材と
は、スタプインキ自己保持能力の優れた連続気孔体であ
れば如何なる材質でもよいが、例えば、天然ゴム、合成
ゴム系のスポンジゴム、合成樹脂発泡体などが示される
が、好ましくは溶融温度が50〜150℃をもつ平均気
孔径2〜10μの微細連続気孔を有し気孔率30〜80
%のポリオレフィン系フォームの0.5〜30mm厚(よ
り好ましくは0.5〜10mm厚)のシートが用いられ
る。
BEST MODE FOR CARRYING OUT THE INVENTION The stamp material having open cells capable of being impregnated with a stamp ink used in the method for producing a printing plate of the present invention may be any material as long as it is a continuous pore body having excellent stap ink self-holding ability. For example, natural rubber, synthetic rubber-based sponge rubber, synthetic resin foam, and the like are shown, but preferably, they have fine continuous pores having an average pore diameter of 2 to 10 μm and a melting temperature of 50 to 150 ° C. 80
%, A 0.5 to 30 mm thick (more preferably 0.5 to 10 mm thick) sheet of polyolefinic foam is used.

【0009】本発明の作製法における赤外線を含む閃光
の照射は、クセノン閃光器、フォトストロボフラッシュ
やフラッシュバルブなどを光源とする閃光を用いる。
The irradiation of flash light containing infrared rays in the manufacturing method of the present invention uses flash light using a xenon flash device, a photostrobe flash, a flash bulb or the like as a light source.

【0010】本発明の作製法における発熱溶融シート
は、赤外線の透過可能なフィルムに赤外線の照射により
少くとも発熱するカーボンまたは高分子物質を含む熱溶
融性樹脂液などを塗布したもの、赤外線により発熱する
物質をホットメルトまたは有機溶剤で溶解した熱溶融性
物質溶液をフィルムに塗工したものなどである。具体的
には、ワックス、樹脂、カーボンブラックからなる熱溶
融性物質をアセテートフイルムに0.5〜10μの厚さ
にホットメルト塗工したものである。熱溶融性物質はス
タンプ材の溶融温度より高い融点50〜160℃をも
ち、その溶融粘度が50〜2000mPa・sとなるよ
うに配合される。
The heat-melting sheet in the production method of the present invention comprises a film capable of transmitting infrared rays, coated with a heat-meltable resin liquid containing carbon or a polymer substance which generates at least heat by irradiation of infrared rays, and heat generated by infrared rays. The film is a hot-melt or hot-melt or organic solvent solution of a hot-melt material solution applied to a film. Specifically, a hot-melt substance composed of wax, resin and carbon black is hot-melt coated on an acetate film to a thickness of 0.5 to 10 μm. The heat-fusible substance has a melting point of 50 to 160 ° C., which is higher than the melting temperature of the stamp material, and is mixed so that its melt viscosity is 50 to 2000 mPa · s.

【0011】本発明で用いる発熱溶融シートの熱溶融性
物質の厚みは0.5〜10μ、好ましくは2〜5μ、よ
り好ましくは4〜5μである。発熱溶融シートの熱溶融
性物質の厚さは赤外線照射条件の重要な要素であり、薄
すぎると該熱溶融性物質の浸透によるスタンプ材の気泡
閉塞の効果が期待できない。厚すぎると過大な閃光照射
エネルギーが必要であるばかりでなく、溶融した熱溶融
性物質がスタンプ材の気泡中に浸透しきれず、スタンプ
材の表面が凹凸となってしまったり、気泡が閉塞しない
非溶融部との断差が逆転し捺印できない印版となる。ま
た、厚すぎると塗工が困難で、熱溶融性物質がフイルム
から剥離し易く取り扱いが悪いなどの欠点がある。赤外
線を透過可能なフィルムとしては赤外線の透過率の高い
アセテートフィルムが良好であり、この厚さが薄いほど
閃光照射エネルギーの効率がよいが閃光照射後にフィル
ムとスタンプ材が熱溶融性物質を介して接着されている
ので剥がす必要があり、このときフィルムが破損しない
ために10μ以上の厚さが好ましい。
The thickness of the heat-fusible substance of the heat-melting sheet used in the present invention is 0.5 to 10 μm, preferably 2 to 5 μm, more preferably 4 to 5 μm. The thickness of the heat-fusible substance of the heat-melting sheet is an important factor for the infrared irradiation conditions. If the thickness is too thick, not only excessive flash irradiation energy is required, but also the molten heat-melting substance cannot penetrate into the bubbles of the stamp material and the surface of the stamp material becomes uneven, and the bubbles do not clog. The gap with the fusion zone is reversed and the printing plate cannot be imprinted. On the other hand, if it is too thick, the coating is difficult and the heat-fusible substance easily peels off from the film, resulting in poor handling. As a film capable of transmitting infrared rays, an acetate film having a high infrared transmittance is preferable. The thinner the thickness, the better the efficiency of flash irradiation energy, but after flash irradiation, the film and stamp material are intercalated by a heat-meltable substance. Since it is adhered, it must be peeled off. At this time, a thickness of 10 μm or more is preferable so that the film is not damaged.

【0012】本発明の作製法に用いる印影原稿は赤外線
を遮断して発熱しないシートを印影原稿像に切り抜いた
ものが最良であり、次善として、赤外線により発熱せず
透過効率の良い透明なフィルムなどに赤外線を透過せず
発熱しないインキ、トナーなどの記録材で画像を形成し
たものである。すなわち、紙、フィルムなどに記録材で
文字、記号、図形などを表したものであるが、紙、フィ
ルムは赤外線の透過率の高いこと、また、文字、記号、
図形などの描線は赤外線を反射する記録材で描かれてい
ることが原理的に好ましい。本発明の作製法において、
最良の印影原稿を制作するためには、PPC複写機で制
作した印影原稿を標準に使用するのが好ましい。現在、
企業、学校、コンビニエンスストアーなどでPPC複写
機を自由に利用可能な状態であるので、制約が多い一般
ユーザーでも簡便に印影原稿が失敗なしに製作できる。
The imprint original used in the manufacturing method of the present invention is best prepared by cutting out a sheet which does not generate heat by cutting off infrared rays into an image of the imprint original, and second best is a transparent film which does not generate heat due to infrared rays and has good transmission efficiency. An image is formed with a recording material such as ink or toner that does not transmit infrared rays to the above and does not generate heat. That is, characters, symbols, figures, etc. are represented by recording materials on paper, film, etc., but paper, film has high infrared transmittance, and characters, symbols,
In principle, it is preferable that the lines such as figures are drawn with a recording material that reflects infrared rays. In the production method of the present invention,
In order to produce the best imprint document, it is preferable to use a standard imprint document produced by a PPC copier. Current,
Since the PPC copier can be freely used in companies, schools, convenience stores, etc., even general users who have many restrictions can easily produce imprint manuscripts without failure.

【0013】このPPC複写機を用いた印影原稿とは、
所望の元の原稿をPPC複写機で複写してトナーにより
文字、記号、図形などが描かれたものである。赤外線の
吸収率による問題となる性能差は、市販の各種のトナー
にはないが、複写機によって厚みのばらつきのある用紙
にはある。そのため、PPC複写機でPPC複写用紙に
複写して制作した印影原稿に液状物質を塗布することに
よってPPC複写用紙の赤外線の透過率を高めると共に
用紙の厚さのばらつきを吸収してほぼ均一な赤外線の透
過率とすることができる。この方法は、複写原稿に限る
ものでなく、同様な用紙に鉛筆、サインペンなどの筆記
具で書かれた原稿やプリンタで出力した原稿にでも同様
に行うことができるものである。液状物質としては、水
にアルコール類20〜50%を添加した液体が示され
る。ここでアルコール類は水が紙に浸透し易くする助剤
であり、アルコール類に限るものではなく、水のみでも
浸透に時間がかかるのみで効果は変わらない。ここで印
影原稿に塗布する液体は水に限るものでなく紙に浸透し
水と同等の熱伝導率を持つものであれば同様の性能を示
すものであり、そうでない場合には細線の再現性が劣る
ということもありうるが閃光照射エネルギーの大幅な節
約になることは変わりない(液体が水であれば原稿像に
発熱があった場合でもその熱が発熱溶融シートへ伝わり
にくく、鮮明な印影が得られる)。液状物質は、PPC
複写用紙、原稿用紙などに用いて用紙自体を赤外線透過
性(透明性)を増すと共に記録材の発熱を抑制するもの
である。
The imprint original using this PPC copying machine is
A desired original document is copied by a PPC copying machine and characters, symbols, figures, etc. are drawn with toner. The problematic difference in performance due to the infrared absorptivity is not found in various commercially available toners, but is present in papers of varying thickness depending on the copying machine. Therefore, by applying a liquid substance to the imprint original produced by copying on a PPC copying paper with a PPC copying machine, the infrared transmittance of the PPC copying paper is increased and the variation in the thickness of the paper is absorbed to obtain a substantially uniform infrared. Can be a transmittance of This method is not limited to copy originals, and can be similarly applied to originals written on a similar sheet with writing instruments such as pencils and felt-tip pens, or originals output by a printer. As the liquid substance, a liquid obtained by adding 20 to 50% of alcohols to water is shown. Here, alcohols are auxiliary agents for facilitating the permeation of water into the paper, and are not limited to alcohols, and even water alone takes a long time to permeate, and the effect does not change. Here, the liquid applied to the imprint original is not limited to water, but shows the same performance as long as it penetrates the paper and has a thermal conductivity equivalent to that of water, and if it is not the reproducibility of fine lines. However, even if the liquid is water, even if the original image has heat, it is difficult for that heat to be transferred to the heat-melting sheet, resulting in a clear imprint. Is obtained). Liquid substance is PPC
It is used for copy paper, original paper, etc. to increase the infrared transparency (transparency) of the paper itself and to suppress heat generation of the recording material.

【0014】本発明の浸透印版は、たとえばスタンプ材
の表面に熱溶融性物質の厚み0.5〜10μの発熱溶融
シートを熱溶融性物質面が接触するように重ね合わせ、
その上に少なくとも水を含む液状物質を塗布した印影原
稿を鏡像となるように重ね、該スタンプ材を5〜70%
圧縮した状態(すなわち、スタンプ材の95〜30%の
厚みにした状態)で該原稿の上方から赤外線を含む閃光
を照射すると、浸透溶融部(スタンプインキ非滲出部)
と非溶融部(スタンプインキ滲出部)を形成して作製さ
れる。該印影原稿の印影原稿像以外の部分は赤外線が印
影原稿を透過して発熱溶融シートまで到達し熱溶融性物
質を発熱し溶融する。該熱溶融性物質の溶融温度はスタ
ンプ材の溶融温度以上なので、熱溶融性物質がスタンプ
材の表層に浸透するとともに該熱溶融性物質の熱でスタ
ンプ材の表層を溶融することができ、スタンプ材を圧縮
することによって気泡が圧縮されてスタンプ材表層の溶
融とともに気泡の閉塞が強化される。この圧縮によつて
閃光の照射エネルギーを少なくすることができる。
In the permeation printing plate of the present invention, for example, a heat-melting sheet having a thickness of 0.5 to 10 μm of a heat-melting substance is superposed on the surface of a stamp material so that the surface of the heat-melting substance is in contact with the sheet.
A stamp imprint original coated with a liquid substance containing at least water is superposed thereon so as to form a mirror image, and the stamp material is 5 to 70%.
When a flash light containing infrared rays is irradiated from above the original in a compressed state (that is, in a state where the thickness of the stamp material is 95 to 30%), the permeation fusion portion (stamp ink non-exudation portion)
And a non-melting portion (stamp ink exuding portion) are formed. In the portion of the imprint document other than the image of the imprint document, infrared rays pass through the imprint document and reach the heat-melting sheet to generate heat and melt the heat-meltable substance. Since the melting temperature of the heat-meltable substance is equal to or higher than the melting temperature of the stamp material, the heat-meltable substance can penetrate into the surface layer of the stamp material and the heat of the heat-meltable substance can melt the surface layer of the stamp material. By compressing the material, the bubbles are compressed, and the surface layer of the stamp material is melted, and the blockage of the bubbles is strengthened. By this compression, the irradiation energy of flash light can be reduced.

【0015】本発明の浸透溶融部(スタンプインキ非滲
出部)は、熱溶融性物質浸透部とスタンプ材溶融部とが
混在する浸透溶融混在部があるのが特徴である。熱溶融
性物質部のみで熱溶融性物質浸透部、スタンプ材溶融部
がない場合は、熱溶融性物質部の膜厚を厚くする必要が
あるので本発明の方法に比べて閃光照射エネルギー必要
となり不経済である。すなわち、本発明は少ない閃光照
射エネルギーでスタンプインキ非滲出部を形成するため
経済的であるばかりでなく、一方のスタンプインキ滲出
部への熱的影響も少なくなるので細かい印影原稿像の再
現も可能となり、鮮明な印影が得られる。熱溶融性物質
の溶融温度がスタンプ材の溶融温度より高いので、スタ
ンプ材を圧縮して閃光を照射することでスタンプ材自体
が気泡のない密着状態になり溶融するので複数層の気泡
を閉塞して浸透溶融混合部を形成する。そのため、熱溶
融性物質部のみでスタンプインキ非滲出部を形成する場
合は発熱溶融シートの熱溶融性物質の膜厚を厚くする必
要があるが、本願発明の方法は発熱溶融シートの膜厚が
薄くてもスタンプインキ非滲出部としての性能を得るこ
とができるので閃光照射エネルギーを小さくできる。
The permeation fusion portion (stamp ink non-exudation portion) of the present invention is characterized in that it has a permeation fusion mixture portion in which the heat-fusible substance permeation portion and the stamp material fusion portion coexist. When only the heat-fusible substance portion does not have the heat-fusible substance-penetrating portion and the stamp material-melting portion, it is necessary to increase the film thickness of the heat-fusible substance portion, and therefore, flash light irradiation energy is required as compared with the method of the present invention. It is uneconomical. That is, the present invention is not only economical because it forms the non-bleeding portion of the stamp ink with a small amount of flash irradiation energy, but also the thermal influence on one stamp ink bleeding portion is reduced, so that it is possible to reproduce a fine imprint original image. And a clear imprint is obtained. Since the melting temperature of the heat-fusible substance is higher than the melting temperature of the stamp material, compressing the stamp material and irradiating it with a flash of light causes the stamp material itself to come into a close contact state with no bubbles and melts, thus blocking multiple layers of bubbles. To form an infiltration-melt mixing section. Therefore, when the stamp ink non-bleeding portion is formed only by the heat-meltable substance portion, it is necessary to increase the film thickness of the heat-meltable substance of the heat-melting sheet. Even if it is thin, the performance as a stamp ink non-bleeding portion can be obtained, so that the flash irradiation energy can be reduced.

【0016】スタンプ材表面は平滑度が高いと、上記圧
縮は軽減でき、閃光照射エネルギーを小さくできて、優
れた印影を得ることができる。本発明に用いられるスタ
ンプ材の気孔径は2〜10μであり、3〜5μが好まし
い。気孔径が大きいと気孔を閉塞するために大きい閃光
照射エネルギーが必要となり、そのため不必要な部分の
気孔が閉塞する弊害がある。一方、気孔径が小さいとわ
ずかの閃光照射エネルギーの増加でも不必要な部分の気
孔が閉塞するので照射エネルギーの調整が困難である。
上記のスタンプ材を前記方法で5〜70%程度圧縮して
得られる印版の浸透溶融部と非熔融部との段差は0.0
1mm以上好ましくは0.05mm〜0.1mmである。本
発明において、例えば、気孔径3μ程度のスタンプ材
(30mm×50mm×1.6mm)で、浸透溶融部と非熔融
部との段差が0.01mm程度となるようにを製版した場
合、粘度が1000mPa・s程度のスタンプインキが
2グラム程度充填できて、捺印時に非滲出部での紙面の
汚れの発生がなく、寿命が長いスタンプが得られる。し
かし、この熱熔融性物質がない状態で上記と同エネルギ
ーで0.01mm程度以下となるように製版した場合、ス
タンプインキが0.2グラム程度しか維持することがで
きない。
If the surface of the stamp material has a high degree of smoothness, the above-mentioned compression can be reduced, the flash irradiation energy can be reduced, and an excellent imprint can be obtained. The stamp material used in the present invention has a pore size of 2 to 10 μm, preferably 3 to 5 μm. If the pore diameter is large, a large flash light irradiation energy is required to close the pores, which has the adverse effect of closing the pores in unnecessary portions. On the other hand, if the pore diameter is small, it is difficult to adjust the irradiation energy because even if the flash irradiation energy is slightly increased, unnecessary pores are blocked.
The difference between the permeation-melting portion and the non-melting portion of the printing plate obtained by compressing the above stamp material by about 5 to 70% by the above method is 0.0.
It is 1 mm or more, preferably 0.05 mm to 0.1 mm. In the present invention, for example, when a stamp material (30 mm × 50 mm × 1.6 mm) having a pore diameter of about 3 μ is prepared so that the difference between the permeation-melted portion and the non-melted portion is about 0.01 mm, the viscosity is A stamp ink of about 1000 mPa · s can be filled in about 2 grams, and a stamp with a long life can be obtained without causing stains on the paper surface at the non-bleeding portion during printing. However, in the absence of this heat-meltable substance, when the plate is made with the same energy as described above to about 0.01 mm or less, the stamp ink can maintain only about 0.2 g.

【0017】本発明の作製法で得られる浸透印版は、他
の部材と組みつけなくてもスタンプとして機能する利点
があるが、印版を台木に装着することにより通常のスタ
ンプとすることができる。その使用は、印版にあらかじ
めスタンプインキを含浸もしくは吸蔵させておくことに
より、長時間スタンプインキを補充することなく、繰り
返し鮮明な印影を捺印することができる。スタンプが吸
蔵するスタンプインキは常温での揮発性がなく粘度が1
00〜3,500mPa・sのものが好ましい捺印性能を示
す。特に500〜1,500mPa・sスタンプインキは印
材への充填の容易さ、捺印時のスタプインキ滲出量から
好ましいものである。
The permeation printing plate obtained by the manufacturing method of the present invention has an advantage that it can function as a stamp even if it is not assembled with other members, but it can be made into a normal stamp by mounting the printing plate on a rootstock. You can For its use, a stamp can be impregnated with the stamp ink in advance or occluded with the stamp ink so that a clear impression can be imprinted repeatedly without replenishing the stamp ink for a long time. The stamp ink stored by the stamp is not volatile at room temperature and has a viscosity of 1
Those having a printing capacity of 00 to 3,500 mPa · s exhibit preferable marking performance. In particular, 500 to 1,500 mPa · s stamp ink is preferable because it is easy to fill the printing material and the amount of the stap ink bleeds at the time of printing.

【0018】また、印版と台木の間に印版のスタンプ材
より高発泡度のスタンプインキ吸蔵体を設けることで捺
印寿命を延ばしたり、スタンプインキの補給を容易にす
ることができる。また、本発明の浸透印版は、ロール表
面に装着してロールを回転することにより連続印刷も可
能である。
Further, by providing a stamp ink occlusion body having a foaming degree higher than that of the stamp material of the printing plate between the printing plate and the stock, it is possible to extend the life of printing and to easily replenish the stamp ink. Further, the permeation printing plate of the present invention can be continuously printed by mounting it on the surface of a roll and rotating the roll.

【0019】[0019]

【実施例】以下、本発明の実施例を図面に基づき説明す
る。 印影原稿の作製:印刷物をPPC複写機で複写して印影
原稿像Lを有する印影原稿M3を作成した。 印版の作製:50ジュールの発光エネルギーをもつクセ
ノン閃光発光器1の透明ガラス板2上に印影原稿M3の
印影原稿像Lが正像となるように重ね、この印影原稿M
3に液状物質(エチアルコール50容量%水溶液)を塗
布した後、さらに熱溶融性物質面5を上向きとして発熱
溶融シート4を重ね、この上に立体網目構造の3μの微
細連続気泡をもち、気孔率60%、溶融温度が約70℃
である厚さ1.6mmのスタンプ材(発泡ポリエチレンシ
ート)S7を重ねて置く〔図1(a)参照〕。ここで用
いた発熱溶融シート4は、ワックス、樹脂、カーボンブ
ラックからなる熱溶融性物質5(溶融温度80℃、溶融
粘度100mPa・Sを有する)をアセテートフィルム6
(厚さ20μm)に3μmの厚さに塗布したものを用い
た。 熱溶融性物質の粘度は、低いほど浸透しやすく、
好ましいが、アセテートフィルムに塗工が難しく100
mPa・S程度が塗工、浸透でバランスの良い結果が得られ
た。つぎにスタンプ材S7に厚さ方向で弾性変形を50
%程度与えるように圧力をかけた状態で閃光を照射し
た。図1(b)に示すように、熱溶融性物質をもつ発熱
溶融シート4を用いた場合には、印影原稿M3の印影原
稿像Lの対応する該スタンプ材S7の表面は非溶融部I
となり鏡像として残り、その他の表面は浸透溶融部Hと
して熱溶融性物質の発熱により該スタンプ材シートS7
の表面で溶融するとともに、熱溶融性物質がスタンプ材
を溶融し、気泡が閉塞されるが、熱溶融性物質の浸透に
よって気泡の閉塞がより強固になる。(図2参照) スタンプ材が圧縮されているために気泡が圧縮されて該
スタンプ材自体が密着した状態で熱溶融物質がスタンプ
材シート表面に浸透し、同時に該発熱により複数層の連
続気泡を溶融閉塞する。前記発熱溶融シート4の熱溶融
性物質5の厚みが、2〜5μの時に閃光照射のエネルギ
ー効率が高く、捺印の印影も鮮明であった。しかし、
0.5μ程度の厚みであっても発熱溶融シート4に塗布
される熱溶融性物質5が熱溶融性物質5でない場合に比
べ閃光照射エネルギーの省力効果が認められる。 一方
その厚さが10μ程度となっても製版は可能であるが、
大きな閃光照射エネルギーが必要であり、さらに印面の
段差を設けるためにはさらに一層のスタンプ材の圧縮が
必要となる。
Embodiments of the present invention will be described below with reference to the drawings. Preparation of Imprint Original: A printed matter was copied by a PPC copying machine to prepare an imprint original M3 having an imprint original image L. Production of a printing plate: The imprinting document image L of the imprinting document M3 is superposed on the transparent glass plate 2 of the xenon flash light emitting device 1 having an emission energy of 50 joules so as to be a normal image, and the imprinting document M is printed.
3 is coated with a liquid substance (50% by volume of ethialcohol aqueous solution), a heat-melting substance surface 5 is further faced upward, and a heat-melting sheet 4 is superposed thereon. 60%, melting temperature is about 70 ℃
The stamp material (foamed polyethylene sheet) S7 having a thickness of 1.6 mm is stacked and placed [see FIG. 1 (a)]. The heat-melting sheet 4 used here is composed of a heat-melting substance 5 (having a melting temperature of 80 ° C. and a melt viscosity of 100 mPa · S) made of wax, resin and carbon black, which is an acetate film 6.
(Thickness 20 μm) applied to a thickness of 3 μm was used. The lower the viscosity of the heat-fusible substance, the easier it is to penetrate,
Preferred, but difficult to apply to acetate film
A good balance of coating and penetration was obtained at mPa · S level. Next, the stamp material S7 is elastically deformed by 50 in the thickness direction.
Flash light was applied while pressure was applied so as to give about%. As shown in FIG. 1B, when the heat-melting sheet 4 having a heat-melting substance is used, the surface of the stamp material S7 corresponding to the imprint original image L of the imprint original M3 has a non-melting portion I.
The other surface remains as a mirror image, and the other surface serves as the permeation fusion portion H due to the heat generated by the heat-fusible substance and the stamp material sheet S7.
While the heat-melting substance melts the stamp material as well as the surface of the, the air bubbles are blocked, and the bubbles are more strongly blocked by the penetration of the heat-melting substance. (Refer to FIG. 2) Since the stamp material is compressed, the air bubbles are compressed, and the heat-melting substance permeates the surface of the stamp material sheet in a state where the stamp material itself is in close contact, and at the same time, the heat generation causes the continuous bubbles of a plurality of layers to be formed. Melt and block. When the thickness of the heat-melting substance 5 of the heat-melting sheet 4 was 2 to 5 μ, the energy efficiency of flash irradiation was high and the imprint of the seal was clear. But,
Even if the thickness is about 0.5 μm, the labor saving effect of the flash irradiation energy is recognized as compared with the case where the heat-melting substance 5 applied to the heat-melting sheet 4 is not the heat-melting substance 5. On the other hand, plate making is possible even if the thickness is about 10μ,
A large amount of flash irradiation energy is required, and further compression of the stamp material is required to provide a step on the printing surface.

【0020】[0020]

【発明の効果】本発明の浸透印版の作製法は工程が簡単
であり、金型などを必要としないため、目的にあった高
品位のスタンプが迅速に提供できるものである。印影原
稿に水を含む液体を塗布することにより赤外線の透過効
率が向上し、印影原稿の厚みにばらつきがあっても安定
した浸透印版を得ることができる。また、閃光照射の際
にスタンプ材を圧縮することにより、熱溶融性物質の浸
透だけでなくスタンプ材をその気泡を圧縮して溶融する
ので完全に気泡が閉塞されて明確な浸透溶融部(すなわ
ちスタンプインキ非滲出部)が形成されるので、鮮明な
印影を得ることができる。
EFFECTS OF THE INVENTION The method for producing a permeation printing plate of the present invention has a simple process and does not require a mold, and therefore a high-quality stamp suitable for the purpose can be promptly provided. By applying a liquid containing water to the imprint original, the infrared transmission efficiency is improved, and a stable permeation printing plate can be obtained even if the thickness of the imprint original varies. In addition, when the stamp material is compressed during flash light irradiation, not only the heat-melting substance penetrates but also the stamp material melts by compressing the bubbles of the stamp material. Since the stamp ink non-bleeding portion) is formed, a clear imprint can be obtained.

【図面の簡単な説明】[Brief description of drawings]

【図1】スタンプ印版の作製模式図であり、(a)は閃
光を照射前、(b)は照射後の発熱溶融シートとスタン
プ材の状況を模式的に示した図である。
FIG. 1 is a schematic diagram of the production of a stamp printing plate, wherein (a) is a diagram schematically showing a state of a heat-melting sheet and a stamp material before irradiation with flash light and (b) after irradiation.

【図2】スタンプインキ非滲出部(浸透溶融部)[浸透
溶融混合部(熱溶融性物質浸透部およびスタンプ材溶融
部との混在する部分)とスタンプ材溶融部とからなる]
とスタンプインキ滲出部(非溶融部)の拡大断面図であ
る。
[FIG. 2] Stamp ink non-bleeding portion (penetration fusion portion) [consisting of a penetration fusion mixing portion (a portion in which a heat-fusible substance permeation portion and a stamp material fusion portion coexist) and a stamp material fusion portion]
FIG. 3 is an enlarged cross-sectional view of a stamp ink bleeding portion (non-melting portion).

【符号の説明】[Explanation of symbols]

1 閃光発光部 2 ガラス板 M3 印影原稿 4 発熱溶融シート 5 熱溶融性物質 6 アセテートフィルム S7 スタンプ材(発泡ポリエチレンシート) L 印影原稿像 B 印影原稿像不在部分 11 浸透溶融混合部(熱溶融性物質浸透部とスタンプ
材溶融部との混在) 12 スタンプ材溶融部 H 浸透溶融部(スタンプインキ非滲出部) I 非溶融部(スタンプインキ滲出部)
1 Flash emission part 2 Glass plate M3 Imprint manuscript 4 Heat-melting sheet 5 Heat-melting substance 6 Acetate film S7 Stamping material (foam polyethylene sheet) L Imprinting manuscript image B Imprinting manuscript image absent part 11 Penetrating fusion mixing part (heat-melting substance Mixing of permeation part and stamp material fusion part) 12 Stamp material fusion part H Permeation fusion part (stamp ink non-exudation part) I Non-fusion part (stamp ink exudation part)

Claims (6)

【特許請求の範囲】[Claims] 【請求項1】 スタンプインキ含浸可能な連続気泡を有
する弾性樹脂製のスタンプ材の表面に、赤外線の照射に
より発熱して該スタンプ材以上の温度で溶融する熱溶融
性物質が赤外線透過可能なフィルムに0.5〜10μの
厚みに塗布された発熱溶融シートを、該熱溶融性物質が
スタンプ材表面と接するように重ね、その上に所望の印
影原稿を鏡像となるように重ね、該スタンプ材を5〜7
0%圧縮した状態で該原稿の上方より赤外線を含む閃光
を照射することにより、印影原稿の原稿像不在部分は赤
外線を透過して発熱溶融シートに到達した赤外線が前記
原稿像不在部分に対応する部分の熱溶融性物質を発熱溶
融させ、この熱溶融性物質がスタンプ材に浸透するとと
もにスタンプ材表層を溶融して連続気泡の閉塞された浸
透溶融部(スタンプインキ非滲出部)を形成し、一方印
影原稿の原稿像部分は赤外線を遮断又は吸収して、これ
と対応する発熱溶融シートの部分の熱溶融性物質は発熱
溶融せずに対応するスタンプ材の表面の気泡閉塞に至ら
ず非溶融部(スタンプインキ滲出部)を形成し、スタン
プ材の非溶融部に対し浸透溶融部を0.01mm以上の
凹部とすることを特徴とする浸透印版の作製法。
1. A film capable of transmitting infrared rays through a surface of a stamp material made of an elastic resin having open cells which can be impregnated with the stamp ink, and a heat-melting substance which is heated by irradiation of infrared rays and melts at a temperature higher than the temperature of the stamp material. A heat-melting sheet applied in a thickness of 0.5 to 10 μm on the stamp material so that the heat-melting material is in contact with the surface of the stamp material, and a desired imprint original is mirror-imaged on the stamp material. 5 to 7
By irradiating flash light containing infrared rays from above the original in a state of 0% compression, the original image absent portion of the imprint original passes through the infrared rays and reaches the heat-melting sheet. The infrared rays correspond to the original image absent portion. The part of the heat-meltable substance is melted by heat, and the heat-meltable substance permeates the stamp material and melts the surface layer of the stamp material to form a permeation-melting part (stamp ink non-exuding part) in which continuous bubbles are blocked, On the other hand, the original image portion of the imprinted original cuts off or absorbs infrared rays, and the corresponding heat-melting substance in the heat-melting sheet portion does not heat-melt and does not reach the blockage of bubbles on the surface of the corresponding stamp material and does not melt. Part (stamp ink exuding part) is formed, and the permeation-melting part is a recess of 0.01 mm or more with respect to the non-melting part of the stamp material.
【請求項2】 スタンプ材は、溶融温度が50〜150
℃であり立体網目構造の平均気孔径2〜10μの微細連
続気孔を有し気孔率30〜80%のポリオレフィン系フ
ォームの0.5〜30mm厚のシートであり、発熱溶融シ
ートは少なくともカーボンまたは高分子物質を含み溶融
温度が50〜200℃であり溶融粘度が50〜2000
mPa・sである熱溶融性物質を赤外線透過可能なシー
トに塗布したものである請求項1記載の浸透印版の作製
法。
2. The stamp material has a melting temperature of 50 to 150.
It is a 0.5 to 30 mm-thick sheet of polyolefin foam having a solid network structure and fine continuous pores having an average pore diameter of 2 to 10 μm and a porosity of 30 to 80%. It contains a molecular substance and has a melting temperature of 50 to 200 ° C. and a melt viscosity of 50 to 2000.
The method for producing a permeation printing plate according to claim 1, wherein the sheet is a sheet which is permeable to infrared rays and which has a heat-melting substance of mPa · s.
【請求項3】 印影原稿に液状物質を塗布することから
なる請求項1記載の浸透印版の作製法。
3. The method for producing a permeation printing plate according to claim 1, which comprises applying a liquid substance to the imprint original.
【請求項4】スタンプインキ含浸可能な連続気泡を有す
る弾性樹脂製のスタンプ材からなるスタンプインキ含浸
部、および該スタンプ材表面で形成されるスタンプイン
キ滲出部と該インキ滲出部より0.01mm以上の凹部
を形成してなるスタンプインキ非滲出部とからなる印面
を有し、該スタンプインキ非滲出部が熱溶融性物質浸透
部とスタンプ材溶融部との混在する浸透溶融混合部およ
びスタンプ材溶融部からなる浸透印版。
4. A stamp ink impregnated portion made of an elastic resin stamp material having open cells capable of impregnating the stamp ink, a stamp ink exudation portion formed on the surface of the stamp material, and 0.01 mm or more from the ink exudation portion. Of the stamp ink non-bleeding portion formed with the concave portion of the stamp ink, and the stamp ink non-bleeding portion is a mixture of the permeation-melting mixture portion and the stamp material-melting portion in which the heat-melting substance permeation portion and the stamp material-melting portion coexist. Penetration plate made of parts.
【請求項5】スタンプ材が、溶融温度が50〜150
℃、平均気孔径2〜10μ、気孔率30〜80%、厚み
0.5〜30mmのポリオレフィン系フォームシートから
なる請求項4記載の浸透印版。
5. The stamp material has a melting temperature of 50 to 150.
The permeation printing plate according to claim 4, which is formed of a polyolefin foam sheet having a temperature of 0 ° C., an average pore diameter of 2 to 10 μm, a porosity of 30 to 80%, and a thickness of 0.5 to 30 mm.
【請求項6】スタンプ材が長さ5〜500mm、幅5〜
200mmであることからなる請求項5記載の浸透印
版。
6. A stamp material is 5 to 500 mm long and 5 to wide.
The permeation printing plate according to claim 5, which has a length of 200 mm.
JP972596A 1995-02-03 1996-01-24 How to make a penetration printing plate Expired - Fee Related JP2946456B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP972596A JP2946456B2 (en) 1995-02-03 1996-01-24 How to make a penetration printing plate

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP7-17357 1995-02-03
JP1735795 1995-02-03
JP972596A JP2946456B2 (en) 1995-02-03 1996-01-24 How to make a penetration printing plate

Publications (2)

Publication Number Publication Date
JPH08267887A true JPH08267887A (en) 1996-10-15
JP2946456B2 JP2946456B2 (en) 1999-09-06

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ID=26344493

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Country Link
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4589538B2 (en) * 2001-01-16 2010-12-01 シヤチハタ株式会社 How to make stamped surface of thermoplastic resin

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4589538B2 (en) * 2001-01-16 2010-12-01 シヤチハタ株式会社 How to make stamped surface of thermoplastic resin

Also Published As

Publication number Publication date
JP2946456B2 (en) 1999-09-06

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