JPH08226060A - Production of fiber layer material - Google Patents

Production of fiber layer material

Info

Publication number
JPH08226060A
JPH08226060A JP7301601A JP30160195A JPH08226060A JP H08226060 A JPH08226060 A JP H08226060A JP 7301601 A JP7301601 A JP 7301601A JP 30160195 A JP30160195 A JP 30160195A JP H08226060 A JPH08226060 A JP H08226060A
Authority
JP
Japan
Prior art keywords
fiber
fibers
layer material
fiber layer
web
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP7301601A
Other languages
Japanese (ja)
Inventor
Kenichi Kita
謙一 喜多
Kazuhiro Miki
一弘 三木
Yoshihisa Sonobe
佳寿 園部
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
UENO KOGYO KK
Japan Felt Industrial Co Ltd
Original Assignee
UENO KOGYO KK
Japan Felt Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by UENO KOGYO KK, Japan Felt Industrial Co Ltd filed Critical UENO KOGYO KK
Priority to JP7301601A priority Critical patent/JPH08226060A/en
Publication of JPH08226060A publication Critical patent/JPH08226060A/en
Pending legal-status Critical Current

Links

Landscapes

  • Mattresses And Other Support Structures For Chairs And Beds (AREA)
  • Filtering Materials (AREA)
  • Nonwoven Fabrics (AREA)

Abstract

PURPOSE: To provide a method for producing a fibrous layer material suitable as a mat, a filter medium, comprising fibers arranged in the thickness direction, having rigidity and hardly loosening. CONSTITUTION: A fiber web comprising thermally bondable fibers 2 arranged in one direction is formed. The fiber web is heated to a temperature equal to or higher than the melt point of the thermally bondable fibers 2 so that the fibers constituting the fiber web are mutually and partially bonded 3 to form a fiber sheet 5. Then the fiber sheet 5 is folded in the vertical direction based on the direction of the fiber arrangement. Then the folded material is compressed approximately at a right angle to the folding direction, reheated to a temperature equal to or higher than the melt point of the thermally bondable fibers 2, mutually and partially bonded and integrated to give a fiber lump. Then the fiber lump is cut approximately in the vertical direction based on the fiber arrangement direction to produce the objective fiber layer material.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、密度が小さく、保形性
に富みヘタリ性が少なく、剛直性に富み、クッション
性、通気性に富み、バラけにくい繊維層材の製造方法に
関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for producing a fibrous layer material which has a low density, a high shape-retaining property, a low settling property, a high rigidity, a high cushioning property, a high air permeability, and is hard to come loose.

【0002】[0002]

【従来の技術及び発明が解決しようとする課題】繊維層
材は、マット材或いはフィルター材などとして従来から
種々の用途に使用されている。従来の繊維層材において
は、図4に示すように、繊維層材を構成する相互に接着
3した繊維2が、繊維層材の表面と略平行に、すなわち
繊維層材の厚さ方向と略直角方向に配列されている。そ
のため密度が0.1g/cm3以下と小さい繊維層材の
場合、厚さ方向からの荷重に対して変形しやすく、また
保形性に乏しく、ヘタリが大きい欠点があった。そし
て、これらの変形を防止し、ヘタリを解消し、或いはク
ッション性をよくするには、繊維層材の密度を0.1g
/cm3以上の高い密度にする必要があった。また、繊
維層材は、各種空調向けフィルターとして使用されるこ
とが多いが、繊維が繊維層の厚さ方向と略直角方向に配
列させた従来の繊維層材をフィルターに使用した場合に
は、空気の流れによる圧力損失により、フィルター材が
圧縮され、圧力損失の上昇が早くなり、ダストの保持量
が多く取れない等の欠点を有していた。本発明は上記の
如き従来の繊維層材の欠点を解消し、密度が0.1g/
cm3以下と小さい場合でも、保形性に富み、厚さ方向
への荷重に対する変形性が小さく、ヘタリが少なく、弾
力、復元力が強く、クッション性に富み、しかも通気性
がよくマットやフィルター材に好適な繊維層材の製造方
法を提供することを目的とする。
2. Description of the Related Art Fiber layer materials have hitherto been used in various applications as mat materials or filter materials. In the conventional fiber layer material, as shown in FIG. 4, the fibers 2 constituting the fiber layer material and bonded to each other 3 are substantially parallel to the surface of the fiber layer material, that is, substantially in the thickness direction of the fiber layer material. They are arranged at right angles. Therefore, in the case of a fiber layer material having a small density of 0.1 g / cm 3 or less, it has a defect that it is easily deformed by a load from the thickness direction, has poor shape retention, and has a large settling. To prevent these deformations, eliminate settling, or improve cushioning properties, the density of the fiber layer material should be 0.1 g.
It was necessary to make the density as high as / cm 3 or more. Further, the fiber layer material is often used as a filter for various air conditioning, but when a conventional fiber layer material in which fibers are arranged in a direction substantially perpendicular to the thickness direction of the fiber layer is used for the filter, Due to the pressure loss due to the flow of air, the filter material is compressed, the pressure loss rises quickly, and a large amount of dust cannot be retained. The present invention solves the drawbacks of the conventional fiber layer material as described above, and has a density of 0.1 g /
Even when it is as small as cm 3 or less, it has excellent shape retention, small deformability with respect to the load in the thickness direction, little settling, strong elasticity and resilience, rich cushioning property, and good breathability and mats and filters. An object of the present invention is to provide a method for producing a fiber layer material suitable for the material.

【0003】また、合成繊維を主体とする非バインダー
繊維と、バインダー繊維とが配合されたカード紡出ウエ
ッブをクロスレイヤーで折り畳みながら略水平に積層
し、この積層体をウエッブの積層方向に圧縮しつつ、バ
インダー繊維の溶融点以上、非バインダー繊維の溶融点
以下の温度で熱処理し、バインダー繊維を溶融し構成繊
維同士を接着させウエッブを成形固着した敷ぶとんの詰
め物材料用の繊維構造体及びこの繊維の配向を特定の方
向に配向させた植物栽培用の繊維構造体が知られている
(特開平1−118656号公報)。本発明は、かかる
繊維構造体の剛直性を高め、また構成繊維のバラけを改
善したマットやフィルター材に好適な繊維層材を効率良
く生産する製造方法を提供することを目的とする。
Further, a card-spun web containing a non-binder fiber composed mainly of synthetic fibers and a binder fiber is folded in a cross layer to be laminated substantially horizontally, and the laminate is compressed in the laminating direction of the web. While heat-treating at a temperature not lower than the melting point of the binder fiber and not higher than the melting point of the non-binder fiber, the binder fiber is melted and the constituent fibers are adhered to each other to form the web, and the web is molded and fixed. Also, a fiber structure for plant cultivation in which the orientation of the fibers is oriented in a specific direction is known (JP-A-1-118656). It is an object of the present invention to provide a manufacturing method for efficiently producing a fiber layer material suitable for a mat or a filter material, in which the rigidity of such a fiber structure is improved and dispersion of constituent fibers is improved.

【0004】[0004]

【課題を解決するための手段】すなわち本発明は、熱接
着性繊維を含み、且つ繊維が一方向に配列した繊維ウェ
ッブを形成し、この繊維ウェッブを熱接着性繊維の溶融
点以上の温度で加熱して繊維ウェッブを構成する繊維相
互を部分的に接着させて繊維シートとなし、その後該繊
維シートを繊維配列方向に対し垂直方向に折り畳み、次
いでこの折り畳み物を折り畳み方向の略直角方向に圧縮
し、再び熱接着性繊維の溶融点以上の温度に加熱し繊維
相互を部分的に接着させて一体化した繊維塊となし、そ
の後該繊維塊を繊維配列方向に対しほぼ垂直方向に切断
することを特徴とする繊維層材の製造方法である。
Means for Solving the Problems That is, the present invention forms a fiber web containing heat-adhesive fibers and having fibers arranged in one direction. By heating, the fibers constituting the fiber web are partially adhered to each other to form a fiber sheet, and then the fiber sheet is folded in a direction perpendicular to the fiber arrangement direction, and then this folded product is compressed in a direction substantially perpendicular to the folding direction. Then, by heating again to a temperature higher than the melting point of the heat-adhesive fiber to partially bond the fibers to each other to form an integrated fiber mass, and then cutting the fiber mass in a direction substantially perpendicular to the fiber arrangement direction. And a method for producing a fiber layer material.

【0005】本発明の繊維層材の製造方法について詳し
く説明する。本発明で使用する熱接着性繊維は、加熱に
より溶融し接着性を発揮する繊維であり、加熱した際に
繊維相互を接着する作用をなすものである。熱接着時の
条件又は出来上がりの風合いにもよるが、繊維全体の少
なくとも10%以上混入する必要がある。10%未満で
あると、繊維層材に切断した時、接着されてない部分よ
りバラけが生じ形態保持性が悪くなる。熱接着性繊維と
しては、繊維層材を構成する主繊維よりも低い温度で溶
融する合成繊維であればいずれでも良いが、好ましいの
は例えばポリエステル又はポリプロピレンを芯とし低融
点ポリエステルやポリエチレンを鞘とした芯鞘型或はこ
れらのサイドバイサイド型の複合繊維である。また繊維
に低融点樹脂を付着或は被覆したものも使用できる。こ
れらの複合繊維を熱接着性繊維に用いた場合は、繊維ウ
ェッブを熱接着性繊維のみで構成させても良い。そし
て、熱接着性繊維の混入量、加熱処理条件によって、繊
維層材の剛性を適宜に変えることができ、繊維相互の接
着の割合いを多くするほど繊維層材の剛性は大きくな
る。また繊維相互の接着には熱溶融性合成樹脂粒子を使
用してもよい。
The method for producing the fiber layer material of the present invention will be described in detail. The heat-adhesive fiber used in the present invention is a fiber that is melted by heating and exhibits adhesiveness, and has a function of adhering fibers to each other when heated. Although it depends on the condition at the time of heat bonding or the texture of the finished product, it is necessary to mix at least 10% or more of the entire fiber. When it is less than 10%, when cut into a fibrous layer material, it is more distorted than the non-bonded portion, and the shape retention is deteriorated. As the heat-adhesive fiber, any synthetic fiber may be used as long as it is a synthetic fiber that melts at a temperature lower than that of the main fiber constituting the fiber layer material, but it is preferable to use, for example, polyester or polypropylene as a core and low melting point polyester or polyethylene as a sheath. These are core-sheath type or side-by-side type composite fibers thereof. Further, a fiber having a low melting point resin adhered or coated thereon can also be used. When these composite fibers are used as the heat-adhesive fibers, the fiber web may be composed of only the heat-adhesive fibers. The rigidity of the fiber layer material can be appropriately changed depending on the mixing amount of the heat-adhesive fibers and the heat treatment condition, and the rigidity of the fiber layer material increases as the ratio of adhesion between the fibers increases. Further, heat-meltable synthetic resin particles may be used for adhering the fibers to each other.

【0006】また、本発明で熱接着性繊維と混合して使
用する繊維は、ポリエステル繊維、ポリプロピレン繊
維、アクリル系繊維、レーヨン、アセテート繊維、ガラ
ス繊維、炭素繊維、各種天然繊維等の単独又は複数から
なる繊維で、熱接着性繊維より溶融点の高い繊維であ
る。これら繊維は単独で用いても又は二種以上併用して
もよい。また、加熱により捲縮する捲縮繊維を使用する
こともできる。繊維の太さは用途に応じて適宜に決める
ことができ、特に限定されない。例えば自動車の座席マ
ット材として使用するときには、繊維の剛性が確保しや
すい15デニール以上の太い繊維がよく、フィルター材
として特に捕集効率を上げる場合は、1デニール前後の
極細の繊維を使用する。
The fibers used in the present invention mixed with the heat-adhesive fibers are polyester fibers, polypropylene fibers, acrylic fibers, rayon, acetate fibers, glass fibers, carbon fibers, various natural fibers, etc., alone or in combination. Is a fiber having a higher melting point than the heat-adhesive fiber. These fibers may be used alone or in combination of two or more. Further, crimped fibers that are crimped by heating can also be used. The thickness of the fiber can be appropriately determined according to the application and is not particularly limited. For example, when it is used as a seat mat material for automobiles, a thick fiber having a denier of 15 denier or more, which is easy to secure the rigidity of the fiber, is preferable, and an extremely fine fiber having a denier of about 1 denier is used as a filter material in order to particularly improve collection efficiency.

【0007】繊維を一方向に配列させた繊維ウエッブを
製造するには種々の方法が採用できる。例えば、長繊維
を一方向に引き揃えてなる繊維ウエッブ、或いは短繊維
をカーデングして一方向に配列させてなる繊維ウエッブ
を、繊維配列方向が同一方向になるように所望の厚さに
重ね合わせて製造する。上記の繊維ウエッブを形成させ
る際、ウェッブ構成繊維全部を完全に一方向に配向させ
ると、得られた最終製品の繊維層材は、繊維が厚さ方向
に完全に配向したものとなる。本発明の繊維層材の繊維
の配向は、全ての繊維が厚さ方向になる配向する必要は
ないが、繊維本来の弾性を利用するため、また通気性を
よくするため、全体の繊維のうちの50%以上が厚さ方
向に配列されている必要がある。したがって、その原料
たる上記の繊維ウエッブは全体の繊維のうちの50%以
上を一方向に配列させる必要がある。この繊維ウエッブ
の繊維配向性をチェックするには、顕微鏡で一定視野の
繊維を観察し、一方向に配列している繊維の本数を数え
その割合を算出しても良いし、繊維ウエッブの縦及び横
の強度を測定しその割合を算出して繊維の配向性を調べ
る方法でもよい。例えば繊維ウエッブの縦及び横の強度
がそれぞれ30Kgf/5cmW及び15Kgf/5c
mWであれば、繊維ウエッブの繊維の縦方向の配向性は
30/(30+15)=66.7%となる。そして、こ
の配向性はまた本発明の繊維層材の厚さ方向の繊維の配
向性となる。また、上記の繊維ウエッブの目付は、後述
のヒダ折り状に折り畳みを行う操作時、均一なになる様
に150g/m2以下、好ましくは30〜80g/m2
よい。
Various methods can be used to manufacture a fiber web in which fibers are arranged in one direction. For example, a fibrous web obtained by aligning long fibers in one direction or a fibrous web obtained by carding short fibers and arranging them in one direction is superposed in a desired thickness so that the fiber arrangement directions are the same direction. To manufacture. When all the fibers constituting the web are completely oriented in one direction when forming the above-mentioned fiber web, the fiber layer material of the final product obtained is such that the fibers are completely oriented in the thickness direction. The orientation of the fibers of the fiber layer material of the present invention does not require that all the fibers be oriented in the thickness direction, but in order to utilize the inherent elasticity of the fibers and improve the air permeability, the total fibers It is necessary that 50% or more of them be arranged in the thickness direction. Therefore, it is necessary to arrange 50% or more of all the fibers in one direction in the fiber web as the raw material. In order to check the fiber orientation of this fiber web, the fibers in a fixed field of view may be observed with a microscope, the number of fibers arranged in one direction may be counted, and the ratio may be calculated. A method of measuring the lateral strength and calculating the ratio thereof to check the orientation of the fibers may be used. For example, the longitudinal and transverse strengths of the fiber web are 30 Kgf / 5 cmW and 15 Kgf / 5c, respectively.
If it is mW, the longitudinal orientation of the fibers of the fiber web is 30 / (30 + 15) = 66.7%. And this orientation also becomes the orientation of the fibers in the thickness direction of the fiber layer material of the present invention. Also, the basis weight of the fiber webs, when operating to perform a folded below the corrugated, so as to be a uniform 150 g / m 2 or less, preferably from 30 to 80 g / m 2.

【0008】本発明においては、上記の繊維を一方向に
配列した繊維ウエッブを、一旦熱接着性繊維の溶融点以
上他の繊維の溶融点以下の温度で加熱処理し、繊維ウエ
ッブに含ませた熱接着性繊維を溶融させ繊維ウエッブの
繊維相互を接着させて繊維シートにする。繊維を一方向
に配列したままの繊維相互が未接着状態の繊維ウエッブ
も後述のヒダ折り操作の素材に供することができるが、
この未接着状態の繊維ウェッブを素材に用いた場合は、
ソフトな感触を有する繊維層材がえられる。一方、本発
明の如く、前記繊維ウェッブの繊維相互を部分接着させ
た繊維シートを素材に用いた場合は、剛直な感触を有す
る繊維層が得られ、またこの場合は繊維相互の接着部分
が多くなり、繊維のバラけが少ない繊維層が得られる。
すなわち、繊維ウエッブの繊維相互を接着させたものを
素材に用いることにより、上記の繊維相互が未接着状態
の繊維ウエッブを素材に用いた場合に比し、同じ繊維を
原料に用いても、剛直な感触を有する繊維層材が得ら
れ、また繊維相互の接着部分が多くなり、繊維のバラけ
が少ない強固な繊維層材が得られる。
In the present invention, the above-mentioned fiber web in which the fibers are arranged in one direction is heat-treated at a temperature not lower than the melting point of the heat-adhesive fiber and not higher than the melting point of the other fiber, and included in the fiber web. The heat-bondable fibers are melted and the fibers of the fiber web are bonded together to form a fiber sheet. A fiber web in which fibers are not bonded to each other while the fibers are arranged in one direction can also be used as a material for the fold operation described below.
When using this unbonded fiber web as the material,
A fiber layer material having a soft feel is obtained. On the other hand, as in the present invention, when a fiber sheet in which the fibers of the fiber web are partially bonded to each other is used as a material, a fiber layer having a rigid feel is obtained, and in this case, many bonded parts of the fibers are present. As a result, a fiber layer in which the fibers are less scattered can be obtained.
That is, by using as a raw material the fibers of a fibrous web adhered to each other, compared to the case where the above-mentioned fibrous web in which the fibers are not adhered to each other is used as a raw material, even if the same fiber is used as a raw material, It is possible to obtain a fibrous layer material having a good feel, and to obtain a strong fibrous layer material in which the number of bonded portions between the fibers is increased and the fibers are less scattered.

【0009】また、上記の繊維を一方向に配列した繊維
ウエッブをそのまま用いた場合には、嵩高過ぎて後述の
折り畳み工程時に折り畳み数を多くできないため、圧縮
加熱時の圧着力が弱くなり、仕上がった繊維塊の繊維相
互の接着が充分にできず、繊維層材がバラけ易くなる。
上記繊維ウェッブを、加熱して熱接着性繊維で繊維相互
を熱接着した繊維シートは、繊維相互が接着しているの
で嵩高性が少なく比較的緻密であるため、折り畳み数が
多くとれ、円滑に圧縮加熱が行え、生産効率が良く、し
かもバラけにくい繊維層材が得られる。そこで、本発明
では繊維を一方向に配列した繊維ウエッブを、一旦加熱
処理し、繊維ウエッブに含ませた熱接着性繊維を加熱溶
融させて繊維相互を接着させた繊維シートにして、次の
折り畳み工程に移行させる。
Further, when the above-mentioned fiber web in which the fibers are arranged in one direction is used as it is, since it is too bulky and the number of folds cannot be increased during the folding step which will be described later, the crimping force at the time of compression heating becomes weak and the finish Further, the fibers of the lump of fibers cannot be sufficiently adhered to each other, and the fiber layer material is likely to come apart.
The above-mentioned fibrous web is heated, and the fibrous sheet in which the fibers are heat-bonded to each other with the heat-adhesive fibers is relatively dense because the fibers are bonded to each other, and thus the number of folds is large and the fibers can be smoothly moved. It is possible to obtain a fiber layer material that can be compressed and heated, has good production efficiency, and is resistant to variation. Therefore, in the present invention, a fiber web in which fibers are arranged in one direction is once subjected to heat treatment, and the heat-adhesive fibers contained in the fiber web are heated and melted to form a fiber sheet in which the fibers are adhered to each other, and the following folding is performed. Shift to process.

【0010】本発明では、上記の如くして得た繊維シー
トを繊維配列方向に対し垂直方向に折り畳み、次いでこ
の折り畳み物を折り畳み方向の略直角方向に圧縮し、再
び熱接着性繊維の溶融点以上他の繊維の溶融点以下の温
度で加熱する。この圧縮加熱によって繊維相互が部分的
に接着し一体化した繊維塊が得られる。この操作は具体
的には、一定の幅を有する長尺の繊維シートを順次繊維
配列方向に対し垂直方向にヒダ折り状に折り畳み、折り
畳み方向の略直角方向に圧縮し所定の密度となし、次い
で熱風を吹付貫通させて、予め混入したウエッブ中の熱
接着性合成繊維又は熱溶融性合成樹脂粒子を溶融させて
繊維相互を接着し、一体化する方法を採用するのが好ま
しく、この方法によるとウエッブ積層体を連続的に製造
することができる。また、繊維シートをヒダ折り加工す
る際に、繊維シートの表面に熱融着性樹脂を少量付着さ
せておくと繊維シート同士の接着がより強固になるた
め、強度の良い繊維層材が得られる。上記のヒダ折り高
さが繊維層材の厚さとなり、この厚みが大きければ大き
い程スライスして本発明の繊維層材を数多く生産できる
が、熱接着処理時に熱を均一に内部まで行き渡らせるの
が困難になる。そのため通常は10〜200mm程度の
厚さが好ましい。
In the present invention, the fiber sheet obtained as described above is folded in a direction perpendicular to the fiber arrangement direction, and then this folded product is compressed in a direction substantially perpendicular to the folding direction, and the melting point of the heat-adhesive fiber is again obtained. The heating is performed at a temperature below the melting point of the other fibers. By this compression heating, a fiber mass in which the fibers are partially adhered and integrated is obtained. Specifically, this operation is performed by sequentially folding a long fiber sheet having a constant width into a fold shape in a direction perpendicular to the fiber arrangement direction and compressing it in a direction substantially perpendicular to the folding direction to obtain a predetermined density. It is preferable to adopt a method in which hot air is blown through and the heat-adhesive synthetic fibers or heat-meltable synthetic resin particles in the web mixed in advance are melted to bond the fibers to each other and integrate them. According to this method, The web laminate can be manufactured continuously. Further, when the fiber sheet is fold-folded, if a small amount of the heat-fusible resin is adhered to the surface of the fiber sheet, the adhesion between the fiber sheets becomes stronger, so that a fiber layer material with good strength can be obtained. . The above-mentioned fold height becomes the thickness of the fiber layer material, and the larger this thickness is, the more the fiber layer material of the present invention can be produced by slicing, but the heat can be uniformly spread to the inside during the heat bonding process. Becomes difficult. Therefore, a thickness of about 10 to 200 mm is usually preferable.

【0011】上記の如くして得た繊維塊を、マットやフ
ィルター材に使用するために、繊維配列方向に対しほぼ
垂直方向に切断する。この繊維配列方向と切断方向の角
度はその用途により任意に選ぶことができる。また、こ
の切断は、スライスにより行われるが、その際の厚さ
は、繊維層材の用途によって適宜に変える。本発明の繊
維層材の表面及び/又は裏面は切断面であるため、その
感触は芝生様の感触であり、摩擦係数が高い。例えば、
経、緯ともに56番、双糸で構成した目付165g/m
2の布地に対する動摩擦係数を測定したところ、切断面
は1.2〜1.7あり、切断しない面の約0.6〜0.
7の約2倍以上であった。
The fiber mass obtained as described above is cut in a direction substantially perpendicular to the fiber arrangement direction for use in a mat or a filter material. The angle between the fiber arrangement direction and the cutting direction can be arbitrarily selected depending on the application. The cutting is performed by slicing, and the thickness at that time is appropriately changed depending on the use of the fiber layer material. Since the front surface and / or the back surface of the fiber layer material of the present invention is a cut surface, the feeling is like a lawn and the friction coefficient is high. For example,
No. 56 for both warp and weft, and basis weight 165g / m
When the dynamic friction coefficient for the fabric No. 2 was measured, the cut surface was 1.2 to 1.7, and the cut surface was about 0.6 to 0.
It was about 2 times or more than 7.

【0012】図1は、本発明の製造方法で得られた繊維
層材を、一部模式的に拡大して示した斜視図である。1
は繊維層材、2は繊維層材を構成する厚さ方向に配列し
た繊維である。3は繊維相互の接着部分である。4は繊
維層材の表面で、切断面であり、この面において、繊維
層材を構成する各繊維2は繊維軸に対し直角方向に切断
されている。このように本発明の繊維層材は、繊維が厚
さ方向に配列し且つその繊維相互が部分的に接着してい
る。そしてまた、繊維層材の表面及び又は裏面は、繊維
層材を構成する各繊維の横切断面の集合体で構成されて
いる。
FIG. 1 is a partially enlarged schematic perspective view of a fiber layer material obtained by the manufacturing method of the present invention. 1
Is a fiber layer material, and 2 is a fiber constituting the fiber layer material and arranged in the thickness direction. Reference numeral 3 is an adhesion portion between fibers. Reference numeral 4 denotes a surface of the fiber layer material, which is a cut surface, and in this surface, each fiber 2 constituting the fiber layer material is cut in a direction perpendicular to the fiber axis. As described above, in the fiber layer material of the present invention, the fibers are arranged in the thickness direction and the fibers are partially bonded to each other. Further, the front surface and / or the back surface of the fiber layer material is composed of an aggregate of transversely cut surfaces of each fiber constituting the fiber layer material.

【0013】本発明の製造方法でえられた繊維層材は、
繊維が厚さ方向に配列し且つその繊維相互が部分的に接
着しているため、繊維層材が厚さ方向の荷重を受けて
も、個々の繊維がバネの役割をはたして、弾力、復元力
がよく、ヘタリの少ないものとなり、繊維層材全体とし
ては極めて変形し難く、剛直な感触を有し、バラけにく
く、クッション性の良いものとなるのでクッション材に
適する。また、本発明の繊維層材は、その表面の感触は
芝生様の感触であり、摩擦係数が高いので、例えば自動
車の座席マット材として使用した時には、その表面に設
けた他のシート材の動きが抑えられる利点があり、また
繊維が厚さ方向に並んでいるため、通気性がよく、長時
間使用しても汗ばむことがない利点がある。
The fiber layer material obtained by the production method of the present invention is
Since the fibers are arranged in the thickness direction and the fibers are partially adhered to each other, even if the fiber layer material receives a load in the thickness direction, each fiber acts as a spring, and elastic force and restoring force are exerted. The fiber layer material is suitable for a cushioning material because it has a good durability, is less likely to be settled, is extremely hard to be deformed as a whole of the fiber layer material, has a rigid feel, is hard to come loose, and has a good cushioning property. Further, the fiber layer material of the present invention has a grass-like surface feel and a high friction coefficient, and therefore, when used as a seat mat material for automobiles, for example, movement of other sheet materials provided on the surface thereof Has the advantage that it is suppressed, and because the fibers are arranged in the thickness direction, it has good breathability and does not sweat even after long-term use.

【0014】本発明の製造方法でえられた繊維層材は、
厚さ方向に配列した繊維で構成され、厚さ方向の荷重に
対し弾力性があり、復元力がよく、ヘタリが少なく、バ
ラけにくく、しかも繊維層材の表面及び/又は裏面を切
断面とし、この切断面を各繊維の切断面の集合体で構成
されているから、流体が通過し易く、各種のフィルター
材として好適である。この繊維層材フィルター材に用い
た場合には、流体が表面又は裏面からスムースに入り、
厚さ方向に繊維方向が揃っているため、流体の流通性が
優れている。
The fiber layer material obtained by the manufacturing method of the present invention is
Composed of fibers arranged in the thickness direction, it has elasticity with respect to the load in the thickness direction, good restoring force, little settling, and is hard to disperse, and moreover, the front surface and / or the back surface of the fiber layer material is the cut surface. Since this cut surface is composed of an aggregate of cut surfaces of each fiber, a fluid easily passes therethrough, which is suitable as various filter materials. When used for this fiber layer material filter material, the fluid smoothly enters from the front or back surface,
Since the fiber directions are aligned in the thickness direction, the fluid flowability is excellent.

【0015】この繊維層材をフィルターに用いるときに
は、流体を繊維方向に通す場合と流体を繊維と直角方向
に通す場合とがあるが、前記の性質を有する点からし
て、流体が繊維方向に通るように使用した場合は特に好
ましい。すなわち、繊維層の厚さ方向と略直角方向に配
列させた従来の繊維層材をフィルターに使用した場合に
は、流体の流れによる圧力損失により、フィルター材が
圧縮され、圧力損失の上昇が早くなり、ダストの保持量
が多く取れない等の欠点があったが、本発明の繊維層材
を流体が繊維方向に通るようにしてフィルターに用いる
場合にはかかる欠点がない。そのため、本発明の繊維層
材は、フィルター材として使用した時、従来の繊維層の
フィルター材に比し、同じ厚みで比較した場合、ほぼ2
倍以上寿命の長いフィルター材が得られる。また、本発
明の繊維層材を流体が繊維と直角方向に通すようにして
フィルターに用いる場合には、圧力損失が高く、ダスト
保持量が低くなるが、捕集率は高くなる。
When this fiber layer material is used in a filter, there are cases where the fluid is passed in the fiber direction and cases where the fluid is passed in the direction perpendicular to the fiber. From the point of having the above-mentioned properties, the fluid is passed in the fiber direction. It is particularly preferable when used so as to pass through. That is, when the conventional fiber layer material arranged in a direction substantially perpendicular to the thickness direction of the fiber layer is used for the filter, the filter material is compressed due to the pressure loss due to the flow of fluid, and the pressure loss increases quickly. However, there is a drawback in that a large amount of dust cannot be retained, but there is no such drawback when the fiber layer material of the present invention is used in a filter so that a fluid passes in the fiber direction. Therefore, the fiber layer material of the present invention, when used as a filter material, has a thickness of approximately 2 when compared with a filter material having a conventional fiber layer when compared at the same thickness.
A filter material with a life more than twice as long can be obtained. Further, when the fiber layer material of the present invention is used in a filter so that a fluid passes in a direction perpendicular to the fibers, the pressure loss is high and the dust holding amount is low, but the collection rate is high.

【0016】[0016]

【実施例及び比較例】 実施例1 図を用いて本発明の実施例を説明する。太さ4デニー
ル、長さ51mmのポリエステル系熱接着性繊維(商品
名メルテイ、ユニチカ株式会社製、ポリエステル繊維を
芯とした芯鞘構造繊維)を100%使用して、カード機
にて繊維が長手方向に配向したウェッブを作った。この
ウエッブを150℃の加熱処理機中で3分間加熱処理し
て、熱接着繊維相互を部分的に溶融接着させシート状繊
維層を得た。シート状繊維層は目付け52g/m2、厚
さ0.86mmであり、また繊維の配向度は長手(縦)
方向の強度と幅(横)方向の強度より計算して91.7
%であった。
Examples and Comparative Examples Example 1 An example of the present invention will be described with reference to the drawings. 100% polyester heat-bonding fibers with a thickness of 4 denier and a length of 51 mm (product name Melty, Unitika Ltd., core-sheath structure fibers with polyester fibers as the core) are used to lengthen the fibers in a card machine. A directional oriented web was made. This web was heat-treated in a heat treatment machine at 150 ° C. for 3 minutes to partially melt-bond the heat-bonded fibers to each other to obtain a sheet-shaped fiber layer. The sheet-like fiber layer has a basis weight of 52 g / m 2 and a thickness of 0.86 mm, and the degree of fiber orientation is longitudinal (longitudinal).
91.7 calculated from the strength in the width direction and the strength in the width (width) direction
%Met.

【0017】図2に示すごとく、上記のシート状繊維層
5を、その繊維方向が垂直になるようにヒダ折り加工し
た。ヒダ折りの折り部6、6間、すなわちヒダ折りの高
さは45mmであった。ヒダ折り配列したシート状繊維
層5の折り部6、6間の繊維は垂直方向に配列されてい
た。次いで、ヒダ折り配列したシート状繊維層5を折り
畳み方向の略直角方向に、すなわち左右から圧縮して、
130℃で加熱処理機中にて10分間加熱処理した。厚
さ45mm、目付け2250g/m2の一体化した繊維
塊が得られた。図3はこの繊維塊7の斜視図である。熱
処理によって隣接したシート状繊維層5、5の繊維相互
も部分接着し、シート状繊維層5、5同士が強固に接着
している。したがって、繊維塊7は一体化されたものと
なった。また、この繊維塊7はその構成繊維相互が接着
しているため、剛性を有しており、丁度硬質発泡スチロ
ールの如き感触を有するものであった。
As shown in FIG. 2, the sheet-like fiber layer 5 was fold-folded so that its fiber direction was vertical. The folds 6 and 6 between the folds, that is, the fold height was 45 mm. The fibers between the folded portions 6, 6 of the sheet-shaped fiber layer 5 arranged in a fold arrangement were arranged in the vertical direction. Next, the sheet-shaped fiber layer 5 in which the folds are arranged is compressed in a direction substantially perpendicular to the folding direction, that is, from the left and right,
It heat-processed for 10 minutes in a heat processing machine at 130 degreeC. An integrated fiber mass with a thickness of 45 mm and a basis weight of 2250 g / m 2 was obtained. FIG. 3 is a perspective view of the fiber mass 7. The fibers of the adjacent sheet-shaped fiber layers 5 and 5 are also partially bonded by the heat treatment, and the sheet-shaped fiber layers 5 and 5 are firmly bonded to each other. Therefore, the fiber lump 7 was integrated. Further, since the constituent fibers of the fiber lump 7 are adhered to each other, the fiber lump 7 has rigidity, and has a feeling just like that of rigid polystyrene foam.

【0018】この繊維塊7を繊維配列方向に垂直方向
に、すなわち図3では水平方向にスライスして本発明の
繊維層材1を得た。この繊維層材のバラけ性をみるため
に、繊維層材1を厚さ35mmにスライスし、この繊維
層材の厚さ方向に引張り応力をかけ繊維層がバラけるま
での荷重を測定したところ、2.0kg/cm幅であっ
た。また、この繊維塊7を繊維配列方向と垂直の方向に
厚さ約10mm、厚さ約5mm及び厚さ約3mmにスラ
イスして3種の繊維層材を作成した。そして、圧縮率、
変形率、圧縮弾性率、通気性及びD.H.Cを測定し
た。その結果を表1のNo.1〜3に示す。圧縮率、変
形率、圧縮弾性率の測定はJIS L1096に従っ
た。また、通気性はJIS L1096のフラジール法
に従った。また、D.H.Cは、ダスト消石灰を速度3
m/分で濾過し、圧損上昇が150mmAqになる迄の
ダスト保持量である。
This fiber mass 7 was sliced in the direction perpendicular to the fiber arrangement direction, that is, in the horizontal direction in FIG. 3, to obtain the fiber layer material 1 of the present invention. In order to check the dispersibility of this fiber layer material, the fiber layer material 1 was sliced into a thickness of 35 mm, and tensile load was applied in the thickness direction of this fiber layer material, and the load until the fiber layer was dislocated was measured. The width was 2.0 kg / cm. Further, three kinds of fiber layer materials were prepared by slicing this fiber lump 7 into a thickness of about 10 mm, a thickness of about 5 mm and a thickness of about 3 mm in the direction perpendicular to the fiber arrangement direction. And the compression ratio,
Deformation rate, compression modulus, breathability and D.I. H. C was measured. The result is shown in No. 1 of Table 1. 1 to 3. The compression rate, deformation rate, and compression elastic modulus were measured according to JIS L1096. Further, the air permeability was in accordance with the Frazier method of JIS L1096. D. H. C, dust slaked lime speed 3
It is the amount of dust retained until the pressure loss rises to 150 mmAq after filtration at m / min.

【0019】比較例 比較のため、上記実施例1で使用したポリエステル系熱
接着繊維を100%使用して、カード機で繊維が水平方
向にアトランダムに配列しているウェッブを作り、15
0℃の熱処理機中にて3分間熱処理して、熱接着繊維の
一部を溶融接着させ、それぞれ厚さ約10mm、約5m
m、約3mmで、目付け約500、250、160g/
2の3種の繊維シートを作成した。各繊維シートの構
成繊維はその厚さ方向と直角方向にアトランダムに並ん
でいた。各繊維シートについて物性値を、実施例1と同
様に測定した。その結果を表1のNo.4〜6に示す。
Comparative Example For comparison, 100% of the polyester-based heat-bonded fibers used in Example 1 were used to prepare a web in which the fibers were arranged at random at random in a card machine.
Heat treatment for 3 minutes in a heat treatment machine at 0 ° C to melt and bond a part of the heat-bonded fiber, and the thickness is about 10 mm and about 5 m, respectively.
m, about 3 mm, basis weight about 500, 250, 160 g /
It was created three kinds of fiber sheet of m 2. The constituent fibers of each fiber sheet were arranged at random in the direction perpendicular to the thickness direction. Physical properties of each fiber sheet were measured in the same manner as in Example 1. The result is shown in No. 1 of Table 1. 4 to 6.

【0020】また、比較のため、上記実施例1で使用し
たポリエステル系熱接着繊維を100%使用して、カー
ド機にて繊維が長手方向に配向した繊維ウェッブを作っ
た。この繊維ウエッブの目付けは50g/m2、厚さ1
0mmであり、また繊維の配向度は長手(縦)方向の強
度と幅(横)方向の強度より計算して91.7%であっ
た。この繊維ウエッブをそのまま実施例1と同様に、そ
の繊維方向が垂直になるようにヒダ折り加工した。ヒダ
折りの高さは45mmであった。次いで、ヒダ折り配列
したものを折り畳み方向の略直角方向に、すなわち左右
から圧縮して、130℃で加熱処理機中にて10分間加
熱処理した。厚さ45mm、目付け2000g/m2
一体化した繊維塊が得られた。この繊維塊をスライスし
て繊維層材となした。この繊維層材のバラけ性をみるた
めに、厚さ35mmの繊維層材にスライスし、この繊維
層材の厚さ方向に引張り応力をかけ繊維層がバラけるま
での荷重を測定したところ、1.0kg/cm幅であっ
た。実施例1の繊維層材に比しバラけ易かった。また、
この繊維塊を繊維配列方向と垂直の方向に厚さ約3mm
にスライスして繊維層材を作成した。そして、その物性
値を実施例1と同様に測定した。その結果を表1のN
o.7に示す。
For comparison, a 100% polyester heat-bonded fiber used in Example 1 was used to prepare a fiber web in which the fibers were oriented in the longitudinal direction by a card machine. This fiber web has a basis weight of 50 g / m 2 and a thickness of 1.
The fiber orientation degree was 91.7% as calculated from the strength in the longitudinal (longitudinal) direction and the strength in the width (lateral) direction. This fibrous web was fold-processed as in Example 1 so that the fiber direction was vertical. The fold height was 45 mm. Next, the fold-fold arrangement was compressed in a direction substantially perpendicular to the folding direction, that is, from the left and right, and heat-treated at 130 ° C. in a heat treatment machine for 10 minutes. An integrated fiber mass having a thickness of 45 mm and a basis weight of 2000 g / m 2 was obtained. This fiber mass was sliced to form a fiber layer material. In order to check the dispersibility of this fiber layer material, it was sliced into a fiber layer material having a thickness of 35 mm, tensile stress was applied in the thickness direction of this fiber layer material, and the load until the fiber layer was dislocated was measured, The width was 1.0 kg / cm. Compared to the fiber layer material of Example 1, it was easy to separate. Also,
This fiber mass is approximately 3 mm thick in the direction perpendicular to the fiber arrangement direction.
It was sliced into a fiber layer material. Then, the physical property values were measured in the same manner as in Example 1. The result is N in Table 1.
o. 7 shows.

【0021】[0021]

【表1】 [Table 1]

【0022】表1から分かるように、本発明の繊維層材
は、比較例のNo.4〜6の繊維シートに比較して密度
が小さいにもかかわらず、圧縮率、変形率が極めて小さ
く、圧縮弾性率が大きい。圧縮率は、一定の荷重を掛け
た時の厚さ方向のヘタリ状態を表し、この数値が小さい
と厚さ方向のヘタリが少ないことを示す。変形率は、一
定時間荷重後除重した時の元の厚さよりどの程度変形し
ているかの尺度であり、この数値が小さい程繰返し荷重
に耐え、厚さ方向に対するヘタリが少ないことを示す。
また圧縮弾性率は、一定時間荷重後除重した時の厚さ方
向の復現力を表し、その値が100%の場合は完全に元
の厚さに戻ること意味する。
As can be seen from Table 1, the fibrous layer material of the present invention is No. 1 of the comparative example. Despite having a lower density than the fiber sheets of Nos. 4 to 6, the compression rate and the deformation rate are extremely small, and the compression elastic modulus is large. The compressibility represents a settling state in the thickness direction when a constant load is applied, and a smaller value indicates less settling in the thickness direction. The deformation rate is a measure of how much the material is deformed from the original thickness when the material is unloaded after being loaded for a certain period of time, and the smaller this value is, the more the material can withstand repeated loading and the less the settling in the thickness direction.
Further, the compressive elastic modulus represents the restoring force in the thickness direction when the load is removed after being loaded for a certain period of time, and when the value is 100%, it means that the original thickness is completely restored.

【0023】[0023]

【発明の効果】本発明の繊維層材の製造方法では、熱接
着性繊維を含み、且つ繊維が一方向に配列した繊維ウェ
ッブを形成させ、この繊維ウェッブを一旦熱接着性繊維
の溶融点以上の温度で加熱して繊維ウェッブを構成する
繊維相互を部分的に接着させて繊維シートとなし、この
繊維シートを素材にして繊維層材を製造したので、得ら
れた繊維層材は、従来の上記繊維ウェッブを素材にして
製造した繊維層材に比し、同じ繊維を原料を用いても剛
直な感触に富み、また負荷がかかってもバラけにくい繊
維層材が得られる。
According to the method for producing a fiber layer material of the present invention, a fiber web containing heat-adhesive fibers and having fibers unidirectionally arranged is formed, and the fiber web is once melted or above the melting point of the heat-adhesive fibers. Since the fibers constituting the fiber web are partially adhered to each other to form a fiber sheet by producing the fiber layer material by using this fiber sheet as a raw material, the fiber layer material obtained is Compared with a fiber layer material produced using the above-mentioned fiber web as a raw material, a fiber layer material can be obtained which is rich in a rigid feel even when the same fiber is used as a raw material and which is hard to be separated even when a load is applied.

【0024】また、上記の繊維を一方向に配列した繊維
ウエッブをそのまま素材に用いた場合には、嵩高過ぎ
て、折り畳み工程でのテンションが余り掛けられないた
め、折り工程に長時間必要となり、また仕上がった繊維
塊の繊維相互の接着が充分にできず、繊維層材がバラけ
易くなったり、反発弾性が弱く、ヘタリ易いものにな
る。更に折り畳み数が多く取れないために、繊維量が少
なくなり、フィルター材としての特性も得られない。本
発明の製造方法では、上記繊維ウェッブを一旦加熱して
熱接着性繊維で繊維相互を熱接着した繊維シートにして
いるので、折り畳み時のテンションにも充分耐えるた
め、折り工程時間を短縮でき、また折り畳み数が多くと
れ、円滑に圧縮加熱が行え、しかもバラけにくい繊維層
材が得られる。そして、本発明の製造方法で得られた繊
維層材は、マットやフィルター材として好適である。
Further, when the above-mentioned fiber web in which the fibers are arranged in one direction is used as it is as a material, it is too bulky and the tension in the folding process cannot be applied so much that the folding process requires a long time. In addition, the fibers of the finished fiber mass cannot be sufficiently adhered to each other, and the fiber layer material is likely to be loosened, or the impact resilience is weak, and the fibers are easily set. Furthermore, since the number of folds cannot be increased, the amount of fibers becomes small and the characteristics as a filter material cannot be obtained. In the production method of the present invention, the fiber web is once heated to form a fiber sheet in which the fibers are heat-bonded to each other with the heat-adhesive fiber, so that the fiber sheet sufficiently withstands the tension at the time of folding, the folding step time can be shortened, In addition, a large number of folds can be obtained, compression and heating can be performed smoothly, and a fiber layer material that does not easily come loose can be obtained. The fiber layer material obtained by the manufacturing method of the present invention is suitable as a mat or a filter material.

【図面の簡単な説明】[Brief description of drawings]

【図1】一部模式的に拡大した本発明の繊維層材の斜視
図。
FIG. 1 is a perspective view of a fiber layer material of the present invention, which is partially enlarged schematically.

【図2】本発明の繊維層材の製造過程におけるシート状
繊維層繊維層のヒダ折り状態を示す斜視図。
FIG. 2 is a perspective view showing a fold-folded state of the sheet-like fiber layer fiber layer in the process of manufacturing the fiber layer material of the present invention.

【図3】本発明の繊維層材の製造過程における繊維塊の
斜視図。
FIG. 3 is a perspective view of a fiber mass in the process of manufacturing the fiber layer material of the present invention.

【図4】一部模式的に拡大した従来の繊維層シートの斜
視図。
FIG. 4 is a perspective view of a conventional fiber layer sheet, which is partially and schematically enlarged.

【符号の説明】 1 繊維層材、2 繊維、3 繊維相互の接着部、4
切断面 5 シート状繊維層、6 ヒダ折り部、7 繊維塊
[Explanation of reference numerals] 1 fiber layer material, 2 fibers, 3 adhesive parts between fibers, 4
Cut surface 5 Sheet-like fiber layer, 6 Folded portion, 7 Fiber mass

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】熱接着性繊維を含み、且つ繊維が一方向に
配列した繊維ウェッブを形成し、この繊維ウェッブを熱
接着性繊維の溶融点以上の温度で加熱して繊維ウェッブ
を構成する繊維相互を部分的に接着させて繊維シートと
なし、その後該繊維シートを繊維配列方向に対し垂直方
向に折り畳み、次いでこの折り畳み物を折り畳み方向の
略直角方向に圧縮し、再び熱接着性繊維の溶融点以上の
温度に加熱し繊維相互を部分的に接着させて一体化した
繊維塊となし、その後該繊維塊を繊維配列方向に対しほ
ぼ垂直方向に切断することを特徴とする繊維層材の製造
方法。
1. A fiber comprising a heat-adhesive fiber and forming a fiber web in which the fibers are arranged in one direction, and the fiber web is heated at a temperature higher than the melting point of the heat-adhesive fiber to form the fiber web. The fibers are partially adhered to each other to form a fibrous sheet, and then the fibrous sheet is folded in a direction perpendicular to the fiber arrangement direction, and then this folded product is compressed in a direction substantially perpendicular to the folding direction, and the heat-adhesive fiber is melted again. Production of a fiber layer material characterized by heating to a temperature above a point to partially bond the fibers to each other to form an integrated fiber mass, and then cutting the fiber mass in a direction substantially perpendicular to the fiber arrangement direction. Method.
JP7301601A 1995-11-20 1995-11-20 Production of fiber layer material Pending JPH08226060A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP7301601A JPH08226060A (en) 1995-11-20 1995-11-20 Production of fiber layer material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP7301601A JPH08226060A (en) 1995-11-20 1995-11-20 Production of fiber layer material

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
JP4243277A Division JPH05263345A (en) 1991-09-12 1992-09-11 Fibrous layer material and its production

Publications (1)

Publication Number Publication Date
JPH08226060A true JPH08226060A (en) 1996-09-03

Family

ID=17898916

Family Applications (1)

Application Number Title Priority Date Filing Date
JP7301601A Pending JPH08226060A (en) 1995-11-20 1995-11-20 Production of fiber layer material

Country Status (1)

Country Link
JP (1) JPH08226060A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000047807A1 (en) * 1999-02-09 2000-08-17 Kanebo Limited Cushion material
GB2440663A (en) * 2006-07-28 2008-02-06 Du Pont Fibre-on-end material
WO2012059042A1 (en) * 2010-11-03 2012-05-10 东莞泰力斯高分子材料科技有限公司 Cellucotton having vertical structure that enables bi-directional elasticity, production device and method thereof
CN103382626A (en) * 2012-05-04 2013-11-06 郑宏明 Electrostatic adsorption type upright cellucotton molding method

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000047807A1 (en) * 1999-02-09 2000-08-17 Kanebo Limited Cushion material
GB2440663A (en) * 2006-07-28 2008-02-06 Du Pont Fibre-on-end material
US7964049B2 (en) 2006-07-28 2011-06-21 E. I. Du Pont De Nemours And Company Processes for making fiber-on-end materials
GB2440663B (en) * 2006-07-28 2011-09-07 Du Pont Fiber-on-end materials
WO2012059042A1 (en) * 2010-11-03 2012-05-10 东莞泰力斯高分子材料科技有限公司 Cellucotton having vertical structure that enables bi-directional elasticity, production device and method thereof
CN103382626A (en) * 2012-05-04 2013-11-06 郑宏明 Electrostatic adsorption type upright cellucotton molding method

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