JPH08225431A - Perfumery composition - Google Patents

Abstract

PURPOSE: To obtain a perfumery composition having lasting fragrance and excellent effect to prevent the influence of ultraviolet rays to the skin by using an ultraviolet absorber in combination with a water base composed of a perfumery component, an emulsifier and a water-soluble polymer and absolutely free from ethyl alcohol. CONSTITUTION: This liquid or jelly perfumery composition essentially free from alcohol is produced by adding preferably 0.01-30wt.% of an ultraviolet absorber to a system composed of 0.5-30wt.% (especially 1-10wt.%) of a perfumery component, 0.1-20wt.% of an emulsifier, 50-99wt.% of water and 0.001-10wt.% of a water-soluble polymer. The composition has excellent lasting property of fragrance and effect for preventing the influence of ultraviolet rays to the skin by the ultraviolet absorber compounded to the composition. It has excellent skin-treatment effect and good stability. The ultraviolet absorber is e.g. p- aminobenzoic acid or 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid salt. The system of the above composition may be incorporated with 0.1-30wt.% of a humectant component and 0.1-30wt.% of an oily component.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention is a fragrance product for enjoying scents, which is a liquid or gel-like fragrance composition having a sunburn-preventing effect due to an ultraviolet absorber, excellent fragrance durability, and a skin treatment effect. Regarding things.

[0002]

BACKGROUND OF THE INVENTION Perfume materials generally include natural flavors obtained from animals or plants and synthetic flavors produced by chemical synthesis means. In order to create an excellent scent, Perfumer combines years of experience, sense and inspiration to combine these fragrance materials,
For example, in the case of various flower scents, the natural flower scent itself is reproduced, and in the case of an oriental scent, the oriental image is expressed in the scent. All of these fragrance materials are dissolved in ethyl alcohol to become fragrance products that enjoy the scent.

[0003]

The sensation of use of such an alcohol-based fragrance composition is not sticky, and is characterized by a refreshing sensation due to alcohol and a refreshing sensation. However, on rare occasions, when a fragrance containing alcohol is used, some people may have rough skin, and there is a layer in which a product with a high alcohol content cannot or cannot be used. Therefore, it is expected that the fragrance product will contain the alcohol as little as possible or contain no alcohol. However, natural and mixed flavors generally contain a wide variety of substances, from highly polar to non-polar, and when water-based, even with a surfactant, 0.5% It was extremely difficult to dissolve the above fragrances and to obtain a stable product which does not separate over time even with an emulsion system.

On the other hand, recently, the number of people who enjoy outdoor sports is increasing, and there is a demand for a fragrance that can be used anytime and anywhere, but it is possible to enjoy the scent for a long time while protecting the skin from ultraviolet rays in the sun. There are no known fragrance products that can be produced and that do not give a sweaty odor to sweat.

[0005]

[Means for Solving the Problems] The inventors of the present invention have conducted diligent studies on a method for enhancing the fragrance persistence of fragrance products and an ultraviolet protection effect, and as a result, have found that ethyl alcohol, which has not been considered by common sense up to now, is used. By adding a UV absorber to a water base that does not contain any fragrance, it is possible to obtain a fragrance composition that is excellent in the persistence of fragrance and the effect of preventing the effects of UV rays on the skin, and also has an excellent skin treatment effect and stability. The present invention has been completed and the present invention has been completed.

That is, the present invention contains 0.5 to 30% by weight of a perfume ingredient, 0.1 to 20% by weight of an emulsifier, 50 to 99% by weight of water, 0.001 to 10% by weight of a water-soluble polymer, and an ultraviolet absorber, and Characterized by containing substantially no alcohol,
It is a liquid or gel-like fragrance composition. The fragrance composition according to claim 2 has a content of the ultraviolet absorber of 0.01 to
It is characterized by being 30% by weight. The fragrance composition according to claim 3 is characterized by containing 0.1 to 30% by weight of a moisturizing component. Furthermore, the fragrance composition according to claim 4 is characterized by containing 0.1 to 30% by weight of an oily component.

The present invention will be described in detail below. As the fragrance used in the present invention, any of animal-based, plant-based, mineral-based natural fragrances and synthetic fragrances can be used. The amount of the fragrance compounded is such that a sufficient fragrance can be obtained as a fragrance product, but it is generally 0.5 to 30% by weight, and preferably 1 to 10% by weight.

The emulsifier used in the present invention is an anionic surfactant and / or a nonionic surfactant, and these may be used alone or in combination. Examples of the anionic surfactant include various fatty acid soaps, lauric acid, myristic acid, palmitic acid,
A sodium salt, a potassium salt, a triethanolamine salt, an amino acid-based salt of a fatty acid such as stearic acid, oleic acid, isostearic acid, and behenic acid is used. As the hydrophilic nonionic surfactant, PO
POE glycerin fatty acid esters such as E glycerin monostearate, POE glycerin monoisostearate, POE glycerin triisostearate, POE monooleate, POE distearate, POE monodioleate, POE fatty acid esters such as POE distearate ethylene glycol, POE lauryl Ether, P
OE oleyl ether, POE stearyl ether, P
POE alkyl ethers such as OE behenyl ether, POE 2-octyldodecyl ether, POE cholestanol ether, POE octyl phenyl ether, P
POE alkyl phenyl ethers such as OE nonyl phenyl ether and POE dinonyl phenyl ether, PO
E hydrogenated castor oil derivative, POE sucrose fatty acid ester,
A POE sterol derivative etc. are mentioned. Examples of the lipophilic nonionic activator include polyhydric alcohol fatty acid ester represented by glycerin fatty acid ester, glycerin higher alcohol ether, polyglycerin fatty acid ester, hydrogenated castor oil derivative and the like. The content of these emulsifiers is 0.1 to 20% by weight, preferably 0.1 to 10% by weight from the viewpoint of safety. If it is less than 0.1% by weight, a stable composition cannot be obtained, and if it is added up to 20% by weight, a sufficient effect can be obtained.

Examples of the water-soluble polymer used in the present invention include the following. Examples of natural water-soluble polymers include gum arabic, gum tragacanth,
Galactan, guar gum, carob gum, karaya gum, carrageenan, pectin, agar, quince seed (quince), algecoloid (cassius extract), starch (rice, corn, potato, wheat), plant-based polymers such as glycyrrhizinic acid, xanthan gum, dextran, Examples thereof include microbial polymers such as succinoglucan and pullulan, and animal polymers such as collagen, casein, albumin and gelatin. Examples of the semi-synthetic water-soluble polymer include starch-based polymers such as carboxymethyl starch and methyl hydroxypropyl starch,
Cellulose polymers such as methyl cellulose, nitrocellulose, ethyl cellulose, methyl hydroxypropyl cellulose, hydroxyethyl cellulose, sodium cellulose sulfate, hydroxypropyl cellulose, sodium carboxymethyl cellulose, crystalline cellulose, cellulose powder, sodium alginate, propylene glycol alginate, etc. Examples include molecules. As the synthetic water-soluble polymer, for example, polyvinyl alcohol, polyvinyl methyl ether, polyvinyl pyrrolidone, carboxy vinyl polymer, vinyl-based polymer such as acrylate alkyl methacrylate copolymer, polyethylene glycol 20,000, 4,000,000, 60
Examples thereof include polyoxyethylene-based polymers such as 0,000, polyoxyethylene polyoxypropylene copolymer-based polymers, acrylic polymers such as sodium polyacrylate, polyethyl acrylate and polyacrylamide, polyethyleneimine, cationic polymers and the like. Examples of the inorganic water-soluble polymer include bentonite and silicic acid AIMg.
(Veegum), laponite, hectorite, silicic acid anhydride and the like. The amount of these water-soluble polymers is 0.001
~ 10 wt%, preferably stability and in use,
0.01 to 1% by weight is suitable from the skin feel after use.

As the ultraviolet absorber used in the present invention, para-aminobenzoic acid (hereinafter abbreviated as PABA), PABA monoglycerin ester, N, N-dipropoxy PABA ethyl ester, N, N-diethoxy PABA ethyl ester, N, N -Dimethyl PABA ethyl ester, N, N-dimethyl PABA butyl ester and other benzoic acid ultraviolet absorbers, homomenthyl-N-acetylanthranilate and other anthranilic acid ultraviolet absorbers, amyl salicylate, menthyl salicylate, homomenthyl salicylate, Salicylic acid UV absorbers such as octyl salicylate, phenyl salicylate, benzyl salicylate, p-isopropanol phenyl salicylate, octyl cinnamate, ethyl-4-isopropyl cinnamate, methyl-2,5-diisopropyl cinnamate, ethyl-2,4- Diisopropyl cinnamme Methyl-2,4-diisopropyl cinnamate, propyl -p- methoxycinnamate, isopropyl -p- methoxycinnamate, isoamyl -p- meth Kishishin'nameto, octyl -p- methoxycinnamate (2-ethylhexyl -p-
Methoxycinnamate), 2-ethoxyethyl-p-methoxycinnamate, cyclohexyl-p-methoxycinnamate, ethyl-α-cyano-β-phenylcinnamate, 2-ethylhexyl-α-cyano-β-phenylcinnamate, Ginceryl mono-2-ethylhexanoyl-diparamethoxycinnamate and other cinnamic acid type UV absorbers,
2,4-dihydroxybenzophenone, 2,2'-dihydroxy
-4-Methoxybenzophenone, 2,2'-dihydroxy-4,
4'-dimethoxybenzophenone, 2,2 ', 4,4'-tetrahydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxy-4'-methylbenzophenone, 2-hydroxy-4-methoxy Benzophenone
-5-sulfonate, 4-phenylbenzophenone, 2-ethylhexyl-4'-phenyl-benzophenone-2-carboxylate, 2-hydroxy-4-n-octoxybenzophenone, 4-hydroxy-3-carboxybenzophenone, etc. Benzophenone type UV absorber, 3- (4'-methylbenzylidene) -d, 1-camphor, 3-benzylidene-d, 1-camphor, urocanic acid, urocanic acid ethyl ester, 2-phenyl-5-methylbenzoxazole , 2,2'-hydroxy
-5-Methylphenylbenzotriazole, 2- (2'-hydroxy-5'-t-octylphenyl) benzotriazole, 2-
(2'-hydroxy-5'-methylphenylbenzotriazole, dibenzalazine, dianisoylmethane, 4-methoxy
-4'-t-butyldibenzoylmethane, 5- (3,3-dimethyl-2
-Norbornylidene) -3-pentan-2-one and the like. The blending amount of the ultraviolet absorber is 0.01 to 30% by weight,
It is preferably 0.1 to 20% by weight.

The moisturizing component used in the present invention is glycerin, 1,3-butylene glycol, propylene glycol, polyethylene glycol 300, polyethylene glycol 400, polyethylene 1500, polyethylene glycol 4000, polyethylene glycol 6000,
Polyethylene glycol 15000, dipropylene glycol, sorbitol and the like can be mentioned, and the compounding amount is 0.1 to 30.
%, Preferably 1 to 15% by weight from the skin feel after use.

The oil component used in the present invention is, for example,
Avocado oil, camellia oil, turtle oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, persic oil, wheat germ oil, sasanqua oil, castor oil, linseed oil, safflower oil, cottonseed oil,
Liquid oils such as eno oil, soybean oil, peanut oil, tea seed oil, kaya oil, rice bran oil, cinnamon oil, Japanese tung oil, jojoba oil, germ oil, triglycerin oil, glyceryl trioctanoate, glycerin triisopalmitate, etc., Liquid paraffin,
Hydrocarbons such as squalene, pristane, squalane, oleic acid, tall oil, higher fatty acids such as isostearic acid, lauryl alcohol, oleyl alcohol, isostearyl alcohol, higher alcohols such as octyldodecanol, methylpolysiloxane, methylphenylpolysiloxane, Silicon such as methylhydrogenpolysiloxane, decamethylpolysiloxane, isopropyl myristate, isopropyl palmitate, hexyl laurate, octyldodecyl myristate, hexyldecyl dimethyloctanoate, diethyl phthalate, dibutyl phthalate, isopropyl sebacate, sebacine Acid diisopropyl, di-2-ethylhexyl sebacate, glyceryl triisostearate, trimethylolpropane triisostearate, Li-2-ethylhexanoate glycerin, tri-2-ethylhexanoate trimethylolpropane, neopentyl glycol dicaprate, di-2
Esters such as glycerin heptyl undecanoate, cetyl 2-ethylhexanoate, myristyl myristate, olein oleate, hexyl oleate, and decyl oleate can be mentioned. The compounding amount is 0.1 to 30% by weight, preferably 0.1 to 10% by weight from the skin feel after use.
Is good.

The perfume composition of the present invention can be prepared by a normal homomixer, but a more stable and highly transparent perfume composition can be obtained by applying a strong shearing force with a high-pressure homogenizer or nanomizer to form a fine emulsion. To be

In the fragrance composition of the present invention, vitamins generally used in cosmetics within a range not impairing quality,
Antioxidants, plant extracts, drugs, stabilizers, polymer compounds, colorants and the like can be added.

[0015]

EXAMPLES Next, the present invention will be described in more detail with reference to Examples and Comparative Examples, but the present invention is not limited thereto. Hereinafter, the blending amount is% by weight. Example 1 Cologne (1) Ion-exchanged water 96.38% (2) 1,3BG 1.0 (3) Glycerin 1.0 (4) Corn starch 0.01 (5) Xanthan gum 0.01 (6) Squalane 0.1 (7) POE (40) oleyl ether 0.5 (8) 2-Humanoxy-4-methoxybenzophenone-5-sulfonate 0.5 (9) Fragrance 0.5 (Production method) Part of (1) and part of (2) are mixed to form (A) liquid. . Part of (4) (5) (6) (7) and (9) are mixed (B)
Use as liquid. The liquid (A) was mixed with the liquid (B), an emulsion was obtained with a homomixer, and the remaining raw materials were added thereto and sufficiently stirred to obtain a liquid cologne.

Example 2 (1) Ion-exchanged water 82.0% (2) 1,3BG 10.0 (3) DPG 1.0 (4) Hydroxypropylcellulose 1.0 (5) Liquid paraffin 1.0 (6) POE (60) Glyceryl monoisostear Rate 1.0 (7) 2-Ethylhexyl paramethoxycinnamate 2.0 (8) Perfume 2.0 (Production method) A part of (1) and a part of (2) are mixed to prepare a solution (A). Mix (4), (5), (6), (7) and (8) to prepare solution (B). Liquid (B) was mixed with liquid (A), a fine emulsion was obtained with a high-pressure homogenizer, and the remaining raw materials were added thereto and stirred sufficiently to obtain a slightly viscous cologne.

Example 3 (1) Ion-exchanged water 68.6% (2) 1,3BG 5.0 (3) DPG 5.0 (4) Hydroxypropylcellulose 1.0 (5) Carboxyvinyl polymer 0.3 (6) Liquid paraffin 1.0 (7) Soap Powder 2.0 (8) POE (60) Glyceryl monoisostearate 1.0 (9) Paramethoxy 2-ethylhexyl cinnamate 10.0 (10) 4-Methoxy-4'-t-butylbenzylmethane 2.0 (11) Perfume 4.0 (12) Caustic potash 0.1 (Manufacturing method) A part of (1) and a part of (2) are mixed to prepare a solution (A). (4) (5) (6) (7) (8) (9) and (10) are mixed (B)
Use as liquid. The liquid (B) was mixed with the liquid (A), an emulsion was obtained with a homomixer, and the remaining raw materials were added thereto and sufficiently stirred to obtain a gel-like colon.

Example 4 (1) Ion-exchanged water 72.75% (2) Glycerin 5.0 (3) 1,3BG 5.0 (4) Alkyl acrylate methacrylate copolymer 0.1 (5) Liquid paraffin 2.0 (6) POE (60 ) Glyceryl momo-isostearate 2.0 (7) POE (40) oleyl ether 2.0 (8) 2-Humanoxy-4-methoxybenzophenone 0.1 (9) Paramethoxy 2-ethylhexyl 5.0 (10) Perfume 6.0 (11) Caustic potassium 0.05 (8) Manufacturing method) A part of (1) and a part of (3) are mixed to prepare a solution (A). (4) (5) (6) (7) (8) (9) and (10) are mixed (B)
Use as liquid. The liquid (A) was mixed with the liquid (B), a fine emulsion was obtained with a high-pressure homomixer, and the remaining raw materials were added to this and sufficiently stirred to obtain a slightly viscous cologne.

Example 5 (1) Deionized water 75.6% (2) Glycerin 5.0 (3) 1,3BG 5.0 (4) Dextran 0.5 (5) Casein 0.5 (6) Carboxyvinyl polymer 0.3 (7) Liquid paraffin 2.0 ( 8) Sucrose fatty acid ester 3.0 (9) 2,4-Dihydroxybenzophenone 2.0 (10) Fragrance 6.0 (11) Caustic potassium 0.1 (Production method) Part of (1) and part of (3) are mixed (A) Use as liquid. (4) (5) (6) (7) (8) (9) and (10) are mixed (B)
Use as liquid. The liquid (B) was mixed with the liquid (A), a fine emulsion was obtained with a nanomizer, and the remaining raw materials were added thereto and sufficiently stirred to obtain a gel-like colon.

Example 6 (1) Ion-exchanged water 61.29% (2) Glycerin 5.0 (3) 1,3BG 5.0 (4) Gelatin 0.01 (5) Carboxyvinyl polymer 0.5 (6) Liquid paraffin 2.0 (7) POE (40 ) Hardened castor oil 4.0 (8) Paramethoxy 2-ethylhexyl cinnamate 12.0 (9) 4-Methoxy-4'-t-butyl benzyl methane 2.0 (10) Perfume 8.0 (11) Caustic potassium 0.2 (Manufacturing process) (1) Part of And part of (3) are mixed to form solution (A). (4) (5) (6) (7) (8) (9) and (10) are mixed (B)
Use as liquid. The liquid (B) was mixed with the liquid (A), an emulsion was obtained with a homomixer, and the remaining raw materials were added thereto and sufficiently stirred to obtain a gel-like colon.

[Comparative Example] According to the formulation of Table 1, (1) to (2)
Was added and stirred sufficiently to obtain a comparative example.

[0022]

[Table 1] ────────────────────────── (1) Ethanol (2) Perfume ──────────── Comparative Example 1 99.0% 1.0% Comparative Example 2 98.0 2.0 Comparative Example 3 96.0 4.0 Comparative Example 4 94.0 6.0 Comparative Example 5 92.0 8.0 ────────────────────────── ──────────────────

[Effect Test] Examples 1 to 6 and Comparative Examples 1 to 1
5 was used to compare and evaluate the persistence of the scent 3 hours after application, and the skin treatment effect represented by the moistness and smoothness of the skin, by 10 specialist panels. The results are shown in Tables 2 and 3. The evaluation criteria for the odor persistence and skin treatment effect are as follows.

[0024]

[0025]

[Table 2] Persistence of fragrance ────────────────────────── Score 4 3 2 1 ─────────── ──────────────── Example 1 0 4 5 1 Example 2 5 2 3 0 Example 3 8 2 2 0 0 Example 4 10 0 0 0 Example 5 10 0 0 0 Example 6 10 0 0 ────────────────────────── Comparative Example 1 0 0 1 9 Comparative Example 2 0 0 2 8 8 Comparison Example 3 0 1 3 6 Comparative Example 4 0 1 4 5 Comparative Example 5 0 2 4 4 ───────────────────────────

[0026]

[Table 3] Treatment effect on skin ────────────────────────────────── Score 4 3 2 1 1 ── ──────────────────────────────────────── Example 1 0 Name 3 6 1 Example 2 8 2 0 0 Example 3 10 0 0 0 Example 4 9 1 0 0 Example 5 10 0 0 0 Example 6 10 0 0 0 ────────────────────────── Comparative Example 1 0 0 1 9 Comparative Example 2 0 0 0 10 Comparative Example 3 0 0 2 8 Comparative Example 4 0 0 1 9 Comparative Example 5 0 0 1 9 9 ────── ────────────────────────────

[0027]

The fragrance composition of the present invention is excellent in the sun protection effect and the fragrance lasting property, and in the feeling of use and the effect of improving the skin. Further, according to the present invention, since ethyl alcohol is not blended at all, a fragrance product that can be safely used by people sensitive to alcohol can be obtained.

Claims (4)

[Claims] 1. A fragrance ingredient of 0.5 to 30% by weight and an emulsifier of 0.1 to
Liquid or gel-like fragrance composition comprising 20% by weight, 50 to 99% by weight of water, 0.001 to 10% by weight of a water-soluble polymer, an ultraviolet absorber and substantially no alcohol. . 2. The content of the ultraviolet absorber is 0.01 to 30% by weight.
The perfume composition according to claim 1, which is 3. The fragrance composition according to claim 1, which contains a moisturizing component in an amount of 0.1 to 30% by weight. 4. The fragrance composition according to claim 1, which contains an oily component in an amount of 0.1 to 30% by weight.