JPH08225430A - Perfumery composition - Google Patents

Abstract

PURPOSE: To obtain a perfumery composition for fragrance goods for enjoying the fragrance, having excellent durability of fragrance and exhibiting skin- treatment effect by adding a water-soluble polymer to a water base absolutely free from ethyl alcohol. CONSTITUTION: This liquid or jelly perfumery composition essentially free from ethyl alcohol is produced by adding 0.001-10wt.% of a water-soluble polymer to a system containing 0.5-30wt.% of a perfumery component and 50-99wt.% of water. The water-soluble polymer is e.g. corn starch, xanthan gum or hydroxypropyl cellulose. The system may be further incorporated with 0.1-30wt.% of a humectant component (e.g. glycerol or propylene glycol) and 0.1-30wt.% of an oily component (e.g. avocado oil or squalane). The perfumery composition has lasting fragrance and excellent feeling to the skin and skin- improving effect. Even a person sensitive to alcohol can safely use the composition because the composition is absolutely free from alcohol.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a fragrance product for enjoying a fragrance, and relates to a liquid or gel-like fragrance composition containing a water-soluble polymer, which has an excellent fragrance durability and a skin treatment effect.

[0002]

BACKGROUND OF THE INVENTION Perfume materials generally include natural flavors obtained from animals or plants and synthetic flavors produced by chemical synthesis means. In order to create an excellent scent, Perfumer combines years of experience, sense and inspiration to combine these fragrance materials,
For example, in the case of various flower scents, the natural flower scent itself is reproduced, and in the case of an oriental scent, the oriental image is expressed in the scent. All of these fragrance materials are dissolved in ethyl alcohol to become fragrance products that enjoy the scent.

[0003]

The sensation of use of such an alcohol-based fragrance composition is not sticky, and is characterized by a refreshing sensation due to alcohol and a refreshing sensation. However, on rare occasions, when a fragrance containing alcohol is used, some people may have rough skin, and there is a layer in which a product with a high alcohol content cannot or cannot be used. Therefore, it is expected that the fragrance product will contain the alcohol as little as possible or contain no alcohol. However, a wide variety of substances, from highly polar to non-polar ones, are generally mixed in natural flavors and prepared flavors. As well as dissolving the fragrance of
Even with an emulsified system, it has been extremely difficult to obtain a stable product that does not separate over time. Furthermore, a condition for an excellent fragrance product is that the scent lasts for a long time, but in reality, as the ethanol volatilizes, strongly volatile components escape quickly and the scent changes drastically. There are many.

Therefore, as a basis for perfuming, the perfumer, in addition to the fragrance of each fragrance material itself and the fragrance when combined with other fragrances, animal fragrances such as musk and civet, musk ketone, musk ambrette, Synthetic musk scents such as musk xylol, and macrocyclic compounds, resins such as true balsam, belu balsam and benzoin,
Attempts have been made to combine natural essential oils such as sandalwood, vetiver, and oak moss to improve the fragrance's persistence.However, all of these have their own unique scent, so adding these will give the desired scent. It will be extremely difficult to produce 100%.

[0005]

[Means for Solving the Problems] The inventors of the present invention have made extensive studies as to how to enhance the fragrance persistence of fragrance products, and as a result, have not been considered by conventional wisdom.
A liquid or gel-like fragrance composition that contains a water-based polymer that does not contain ethyl alcohol at all and has a long-lasting fragrance, an excellent skin treatment effect, and a stable fragrance. The inventors have found that a composition can be obtained and completed the present invention.

That is, according to the present invention, the fragrance component is 0.5 to 30% by weight, the water-soluble polymer is 0.001 to 10% by weight, and water is 50 to 99% by weight.
It is a liquid or gel-like fragrance composition characterized by containing the above and substantially not containing alcohol.
Further, the fragrance composition according to claim 2 contains a moisturizing component in an amount of 0.1 to
It is characterized by containing 30% by weight. Furthermore, the fragrance composition according to claim 3 is characterized by containing 0.1 to 30% by weight of an oily component.

The present invention will be described in detail below. As the fragrance used in the present invention, any of animal-based, plant-based, mineral-based natural fragrances and synthetic fragrances can be used. The amount of the fragrance compounded is such that a sufficient fragrance can be obtained as a fragrance product, but it is generally 0.5 to 30% by weight, and preferably 1 to 10% by weight.

Examples of the water-soluble polymer used in the present invention include the following. Examples of natural water-soluble polymers include gum arabic, gum tragacanth,
Galactan, guar gum, carob gum, karaya gum, carrageenan, pectin, agar, quince seed (quince), algecoloid (cassius extract), starch (rice, corn, potato, wheat), plant-based polymers such as glycyrrhizinic acid, xanthan gum, dextran, Examples thereof include microbial polymers such as succinoglucan and pullulan, and animal polymers such as collagen, casein, albumin and gelatin. Examples of the semi-synthetic water-soluble polymer include starch-based polymers such as carboxymethyl starch and methyl hydroxypropyl starch,
Cellulose polymers such as methyl cellulose, nitrocellulose, ethyl cellulose, methyl hydroxypropyl cellulose, hydroxyethyl cellulose, sodium cellulose sulfate, hydroxypropyl cellulose, sodium carboxymethyl cellulose, crystalline cellulose, cellulose powder, sodium alginate, propylene glycol alginate, etc. Examples include molecules. As the synthetic water-soluble polymer, for example, polyvinyl alcohol, polyvinyl methyl ether, polyvinyl pyrrolidone, carboxy vinyl polymer, vinyl-based polymer such as acrylate alkyl methacrylate copolymer, polyethylene glycol 20,000, 4,000,000, 60
Examples thereof include polyoxyethylene-based polymers such as 0,000, polyoxyethylene polyoxypropylene copolymer-based polymers, acrylic polymers such as sodium polyacrylate, polyethyl acrylate and polyacrylamide, polyethyleneimine, cationic polymers and the like. Examples of the inorganic water-soluble polymer include bentonite and silicic acid AIMg.
(Veegum), laponite, hectorite, silicic acid anhydride and the like. The amount of these water-soluble polymers is 0.001
~ 10 wt%, preferably stability and in use,
0.01 to 1% by weight is suitable from the skin feel after use.

The moisturizing component used in the present invention is glycerin, 1,3-butylene glycol, propylene glycol, polyethylene glycol 300, polyethylene glycol 400, polyethylene 1500, polyethylene glycol 4000, polyethylene glycol 6000,
Polyethylene glycol 15000, dipropylene glycol, sorbitol and the like can be mentioned, and the compounding amount is 0.1 to 30.
%, Preferably 1 to 15% by weight from the skin feel after use.

The oily component used in the present invention is, for example,
Avocado oil, camellia oil, turtle oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, persic oil, wheat germ oil, sasanqua oil, castor oil, linseed oil, safflower oil, cottonseed oil,
Liquid oils such as eno oil, soybean oil, peanut oil, tea seed oil, kaya oil, rice bran oil, cinnamon oil, Japanese tung oil, jojoba oil, germ oil, triglycerin oil, glyceryl trioctanoate, glycerin triisopalmitate, etc., Liquid paraffin,
Hydrocarbons such as squalene, pristane, squalane, oleic acid, tall oil, higher fatty acids such as isostearic acid, lauryl alcohol, oleyl alcohol, isostearyl alcohol, higher alcohols such as octyldodecanol, methylpolysiloxane, methylphenylpolysiloxane, Silicon such as methylhydrogenpolysiloxane, decamethylpolysiloxane, isopropyl myristate, isopropyl palmitate, hexyl laurate, octyldodecyl myristate, hexyldecyl dimethyloctanoate, diethyl phthalate, dibutyl phthalate, isopropyl sebacate, sebacine Acid diisopropyl, di-2-ethylhexyl sebacate, glyceryl triisostearate, trimethylolpropane triisostearate, Li-2-ethylhexanoate glycerin, tri-2-ethylhexanoate trimethylolpropane, neopentyl glycol dicaprate, di-2
Esters such as glycerin heptyl undecanoate, cetyl 2-ethylhexanoate, myristyl myristate, olein oleate, hexyl oleate, and decyl oleate can be mentioned. The compounding amount is 0.1 to 30% by weight, preferably 0.1 to 10% by weight from the skin feel after use.
Is good.

The fragrance composition of the present invention can be prepared by an ordinary homomixer, but by applying a strong shearing force with a high pressure homogenizer, a nanomizer or the like to form a fine emulsion, a fragrance composition having higher stability can be obtained.

In the fragrance composition of the present invention, vitamins generally used in cosmetics within a range not impairing quality,
An ultraviolet absorber, an antioxidant, a plant extract, a drug, a stabilizer, a polymer compound, a coloring agent and the like can be added.

[0013]

EXAMPLES Next, the present invention will be described in more detail with reference to Examples and Comparative Examples, but the present invention is not limited thereto. Hereinafter, the blending amount is% by weight. Example 1 (1) Ion-exchanged water 97.38% (2) 1,3BG 1.0 (3) Glycerin 1.0 (4) Corn starch 0.01 (5) Xanthan gum 0.01 (6) Squalane 0.1 (7) Perfume 0.5 (Production method) (1 Part of () and part of (2) are mixed to prepare solution (A). (4) A part of (5), (6) and (7) is mixed to obtain a liquid (B). The liquid (B) was mixed with the liquid (A), a fine emulsion was obtained with a high-pressure homogenizer, and the remaining raw materials were added thereto, followed by sufficient stirring to obtain a liquid cologne.

Example 2 (1) Ion-exchanged water 84.8% (2) 1,3BG 10.0 (3) DPG 1.0 (4) Hydroxypropyl cellulose 1.0 (5) Alkyl methacrylic acid acrylate polymer 0.2 (6) Liquid paraffin 1.0 (7) Fragrance 2.0 (Production method) A part of (1) and a part of (2) are mixed to obtain (A) liquid. Mix (4), (5), (6) and (7) to prepare solution (B). Liquid (B) was mixed with liquid (A), a fine emulsion was obtained with a high-pressure homogenizer, and the remaining raw materials were added thereto and stirred sufficiently to obtain a slightly viscous cologne.

Example 3 (1) Ion-exchanged water 83.6% (2) 1,3BG 5.0 (3) DPG 5.0 (4) Hydroxypropylcellulose 1.0 (5) Carboxyvinyl polymer 0.3 (6) Liquid paraffin 1.0 (7) Perfume 4.0 (8) Caustic potassium 0.1 (Manufacturing method) A part of (1) and a part of (2) are mixed to make (A) liquid. Mix (4), (5), (6) and (7) to prepare solution (B). The liquid (B) was mixed with the liquid (A), an emulsion was obtained with a homomixer, and the remaining raw materials were added thereto and sufficiently stirred to obtain a gel-like colon.

Example 4 (1) Ion-exchanged water 81.55% (2) Glycerin 5.0 (3) 1,3BG 5.0 (4) Alkyl methacrylate alkyl copolymer 0.3 (5) Liquid paraffin 2.0 (6) Fragrance 6.0 ( 7) Caustic potassium 0.15 (Production method) A part of (1) and a part of (3) are mixed to make (A) liquid. (4) Mix (5) and (6) to prepare (B) liquid.
The liquid (A) was mixed with the liquid (B), a fine emulsion was obtained with a high-pressure homomixer, and the remaining raw materials were added to this and sufficiently stirred to obtain a slightly viscous cologne.

Example 5 (1) Ion-exchanged water 80.6% (2) Glycerin 5.0 (3) 1,3BG 5.0 (4) Dextran 0.5 (5) Casein 0.5 (6) Carboxyvinyl polymer 0.3 (7) Liquid paraffin 2.0 ( 8) Fragrance 6.0 (9) Caustic potash 0.1 (Manufacturing method) Part of (1) and part of (3) are mixed to make (A) liquid. Mix (4), (5), (6), (7) and (8) to prepare solution (B). The liquid (B) was mixed with the liquid (A), a fine emulsion was obtained with a nanomizer, and the remaining raw materials were added thereto and sufficiently stirred to obtain a gel-like colon.

Example 6 (1) Deionized water 79.29% (2) Glycerin 5.0 (3) 1,3BG 5.0 (4) Gelatin 0.01 (5) Carboxyvinyl polymer 0.5 (6) Liquid paraffin 2.0 (7) Perfume 8.0 ( 8) Caustic potash 0.2 (Manufacturing method) Part of (1) and part of (3) are mixed to make (A) liquid. Mix (4), (5), (6) and (7) to prepare solution (B). The liquid (B) was mixed with the liquid (A), an emulsion was obtained with a homomixer, and the remaining raw materials were added thereto and sufficiently stirred to obtain a gel-like colon.

[Comparative Example] According to the formulation of Table 1, (1) to (2)
Was added and stirred sufficiently to obtain a comparative example.

[0020]

[Table 1] ────────────────────────── (1) Ethanol (2) Perfume ──────────── Comparative Example 1 99.0% 1.0% Comparative Example 2 98.0 2.0 Comparative Example 3 96.0 4.0 Comparative Example 4 94.0 6.0 Comparative Example 5 92.0 8.0 ────────────────────────── ──────────────────

[Effect Test] Examples 1 to 6 and Comparative Examples 1 to 1
5 was used to compare and evaluate the persistence of the scent 3 hours after application, and the skin treatment effect represented by the moistness and smoothness of the skin, by 10 specialist panels. The results are shown in Tables 2 and 3. The evaluation criteria for the odor persistence and skin treatment effect are as follows.

[0022]

[0023]

[Table 2] Persistence of fragrance ────────────────────────── Score 4 3 2 1 ─────────── ──────────────── Example 1 0 4 0 0 Example 2 4 3 3 0 Example 3 8 2 0 0 Example 4 10 0 0 0 Example 5 10 0 0 0 Example 6 10 0 0 ────────────────────────── Comparative Example 1 0 0 1 9 Comparative Example 2 0 0 2 8 8 Comparison Example 3 0 1 3 6 Comparative Example 4 0 1 4 5 Comparative Example 5 0 2 4 4 ───────────────────────────

[0024]

[Table 3] Treatment effect on skin ────────────────────────────────── Score 4 3 2 1 1 ── ───────────────────────────────────────── Example 1 0 3 0 7 Example 2 8 1 1 0 Example 3 10 0 0 0 Example 4 9 1 0 0 Example 5 10 0 0 0 Example 6 10 0 0 0 ────────────────────────── Comparative Example 1 0 0 1 9 Comparative Example 2 0 0 0 10 Comparative Example 3 0 0 2 8 Comparative Example 4 0 0 1 9 Comparative Example 5 0 0 1 9 9 ────── ────────────────────────────

[0025]

EFFECT OF THE INVENTION The fragrance composition of the present invention has a high scent persistence and is excellent in the feeling of use and the effect of improving the skin. Further, according to the present invention, since ethyl alcohol is not blended at all, a fragrance product that can be safely used by people sensitive to alcohol can be obtained.

Claims (3)

[Claims] 1. A fragrance component of 0.5 to 30% by weight and a water-soluble polymer
A liquid or gel-like fragrance composition comprising 0.001 to 10% by weight and 50 to 99% by weight of water, and substantially containing no alcohol. 2. The fragrance composition according to claim 1, which contains a moisturizing component in an amount of 0.1 to 30% by weight. 3. The perfume composition according to claim 1, which contains 0.1 to 30% by weight of an oily component.