JPH08225429A - Perfumery composition - Google Patents

Abstract

PURPOSE: To provide a perfumery composition for fragrance goods for enjoying the fragrance, having excellent durability of fragrance and exhibiting skin- treatment effect by adding an emulsifying agent and a water-soluble polymer to a water base absolutely free from ethyl alcohol. CONSTITUTION: This liquid or jelly perfumery composition essentially free from ethyl alcohol is produced by adding a water-soluble polymer to a perfumery composition containing 0.5-30wt.% of a perfumery component, 0.1-20wt.% of an emulsifying agent and 50-99wt.% of water. The water-soluble polymer is e.g. corn starch, xanthan gum or polyvinyl alcohol and its amount is preferably 0.001-10wt.%. The system may be further incorporated with 0.1-30wt.% of a humectant component (e.g. glycerol or propylene glycol) and 0.1-30wt.% of an oily component (e.g. avocado oil or squalane). The emulsifier is an anionic surfactant and/or a nonionic surfactant such as lauric acid or POE(40) oleyl ether.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a fragrance product for enjoying a fragrance, and relates to a liquid or gel-like fragrance composition containing a water-soluble polymer, which has an excellent fragrance durability and a skin treatment effect.

[0002]

BACKGROUND OF THE INVENTION Perfume materials generally include natural flavors obtained from animals or plants and synthetic flavors produced by chemical synthesis means. In order to create an excellent scent, Perfumer combines years of experience, sense and inspiration to combine these fragrance materials,
For example, in the case of various flower scents, the natural flower scent itself is reproduced, and in the case of an oriental scent, the oriental image is expressed in the scent. All of these fragrance materials are dissolved in ethyl alcohol to become fragrance products that enjoy the scent.

[0003]

The sensation of use of such an alcohol-based fragrance composition is not sticky, and is characterized by a refreshing sensation due to alcohol and a refreshing sensation. However, on rare occasions, when a fragrance containing alcohol is used, some people may have rough skin, and there is a layer in which a product with a high alcohol content cannot or cannot be used. Therefore, it is expected that the fragrance product will contain the alcohol as little as possible or contain no alcohol. However, a wide variety of substances, from highly polar to non-polar ones, are generally mixed in natural flavors and prepared flavors. As well as dissolving the fragrance of
Even with an emulsified system, it has been extremely difficult to obtain a stable product that does not separate over time. Furthermore, a condition for an excellent fragrance product is that the scent lasts for a long time, but in reality, as the ethanol volatilizes, strongly volatile components escape quickly and the scent changes drastically. There are many.

Therefore, as a basis for perfuming, the perfumer, in addition to the fragrance of each fragrance material itself and the fragrance when combined with other fragrances, animal fragrances such as musk and civet, musk ketone, musk ambrette, Synthetic musk scents such as musk xylol, and macrocyclic compounds, resins such as true balsam, belu balsam and benzoin,
Attempts have been made to combine natural essential oils such as sandalwood, vetiver, and oak moss to improve the fragrance's persistence.However, all of these have their own unique scent, so adding these will give the desired scent. It will be extremely difficult to produce 100%.

[0005]

[Means for Solving the Problems] The inventors of the present invention have made extensive studies as to how to enhance the fragrance persistence of fragrance products, and as a result, have not been considered by conventional wisdom.
It is a liquid or gel-like fragrance composition by blending an emulsifier and a water-soluble polymer in a water base that does not contain ethyl alcohol at all, and has a long-lasting fragrance, excellent skin treatment effect, and stability. They have found that a good fragrance composition can be obtained, and completed the present invention.

That is, the present invention provides a perfume composition comprising 0.5 to 30% by weight of a perfume ingredient, 0.1 to 20% by weight of an emulsifier and 50 to 99% by weight of water, which contains a water-soluble polymer and substantially contains alcohol. It is a liquid or gel-like fragrance composition characterized in that it is not contained in. The fragrance composition according to claim 2 is characterized in that the content of the water-soluble polymer is 0.001 to 10% by weight. The fragrance composition according to claim 3 is characterized by containing 0.1 to 30% by weight of a moisturizing component. Furthermore, the fragrance composition according to claim 4 comprises an oily component.
It is characterized by containing 0.1 to 30% by weight.

The present invention will be described in detail below. As the fragrance used in the present invention, any of animal-based, plant-based, mineral-based natural fragrances and synthetic fragrances can be used. The amount of the fragrance compounded is such that a sufficient fragrance can be obtained as a fragrance product, but it is generally 0.5 to 30% by weight, and preferably 1 to 10% by weight.

The emulsifier used in the present invention is an anionic surfactant and / or a nonionic surfactant, and these may be used alone or in combination. Examples of the anionic surfactant include various fatty acid soaps, lauric acid, myristic acid, palmitic acid,
A sodium salt, a potassium salt, a triethanolamine salt, an amino acid-based salt of a fatty acid such as stearic acid, oleic acid, isostearic acid, and behenic acid is used. As the hydrophilic nonionic surfactant, PO
POE glycerin fatty acid esters such as E glycerin monostearate, POE glycerin monoisostearate, POE glycerin triisostearate, POE monooleate, POE distearate, POE monodioleate, POE fatty acid esters such as POE distearate ethylene glycol, POE lauryl Ether, P
OE oleyl ether, POE stearyl ether, P
POE alkyl ethers such as OE behenyl ether, POE 2-octyldodecyl ether, POE cholestanol ether, POE octyl phenyl ether, P
POE alkyl phenyl ethers such as OE nonyl phenyl ether and POE dinonyl phenyl ether, PO
E hydrogenated castor oil derivative, POE sucrose fatty acid ester,
A POE sterol derivative etc. are mentioned. Examples of the lipophilic nonionic activator include polyhydric alcohol fatty acid ester represented by glycerin fatty acid ester, glycerin higher alcohol ether, polyglycerin fatty acid ester, hydrogenated castor oil derivative and the like. The content of these emulsifiers is 0.1 to 20% by weight, preferably 0.1 to 10% by weight from the viewpoint of safety. If it is less than 0.1% by weight, a stable composition cannot be obtained, and if it is added up to 20% by weight, a sufficient effect can be obtained.

Examples of the water-soluble polymer used in the present invention include the following. Examples of natural water-soluble polymers include gum arabic, gum tragacanth,
Galactan, guar gum, carob gum, karaya gum, carrageenan, pectin, agar, quince seed (quince), algecoloid (cassius extract), starch (rice, corn, potato, wheat), plant-based polymers such as glycyrrhizinic acid, xanthan gum, dextran, Examples thereof include microbial polymers such as succinoglucan and pullulan, and animal polymers such as collagen, casein, albumin and gelatin. Examples of the semi-synthetic water-soluble polymer include starch-based polymers such as carboxymethyl starch and methyl hydroxypropyl starch,
Cellulose polymers such as methyl cellulose, nitrocellulose, ethyl cellulose, methyl hydroxypropyl cellulose, hydroxyethyl cellulose, sodium cellulose sulfate, hydroxypropyl cellulose, sodium carboxymethyl cellulose, crystalline cellulose, cellulose powder, sodium alginate, propylene glycol alginate, etc. Examples include molecules. As the synthetic water-soluble polymer, for example, polyvinyl alcohol, polyvinyl methyl ether, polyvinyl pyrrolidone, carboxy vinyl polymer, vinyl-based polymer such as acrylate alkyl methacrylate copolymer, polyethylene glycol 20,000, 4,000,000, 60
Examples thereof include polyoxyethylene-based polymers such as 0,000, polyoxyethylene polyoxypropylene copolymer-based polymers, acrylic polymers such as sodium polyacrylate, polyethyl acrylate and polyacrylamide, polyethyleneimine, cationic polymers and the like. Examples of the inorganic water-soluble polymer include bentonite and silicic acid AIMg.
(Veegum), laponite, hectorite, silicic acid anhydride and the like. The amount of these water-soluble polymers is 0.001
~ 10 wt%, preferably stability and in use,
0.01 to 1% by weight is suitable from the skin feel after use.

The moisturizing component used in the present invention is glycerin, 1,3-butylene glycol, propylene glycol, polyethylene glycol 300, polyethylene glycol 400, polyethylene 1500, polyethylene glycol 4000, polyethylene glycol 6000,
Polyethylene glycol 15000, dipropylene glycol, sorbitol and the like can be mentioned, and the compounding amount is 0.1 to 30.
%, Preferably 1 to 15% by weight from the skin feel after use.

The oily component used in the present invention is, for example,
Avocado oil, camellia oil, turtle oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, persic oil, wheat germ oil, sasanqua oil, castor oil, linseed oil, safflower oil, cottonseed oil,
Liquid oils such as eno oil, soybean oil, peanut oil, tea seed oil, kaya oil, rice bran oil, cinnamon oil, Japanese tung oil, jojoba oil, germ oil, triglycerin oil, glyceryl trioctanoate, glycerin triisopalmitate, etc., Liquid paraffin,
Hydrocarbons such as squalene, pristane, squalane, oleic acid, tall oil, higher fatty acids such as isostearic acid, lauryl alcohol, oleyl alcohol, isostearyl alcohol, higher alcohols such as octyldodecanol, methylpolysiloxane, methylphenylpolysiloxane, Silicon such as methylhydrogenpolysiloxane, decamethylpolysiloxane, isopropyl myristate, isopropyl palmitate, hexyl laurate, octyldodecyl myristate, hexyldecyl dimethyloctanoate, diethyl phthalate, dibutyl phthalate, isopropyl sebacate, sebacine Acid diisopropyl, di-2-ethylhexyl sebacate, glyceryl triisostearate, trimethylolpropane triisostearate, Li-2-ethylhexanoate glycerin, tri-2-ethylhexanoate trimethylolpropane, neopentyl glycol dicaprate, di-2
Esters such as glycerin heptyl undecanoate, cetyl 2-ethylhexanoate, myristyl myristate, olein oleate, hexyl oleate, and decyl oleate can be mentioned. The compounding amount is 0.1 to 30% by weight, preferably 0.1 to 10% by weight from the skin feel after use.
Is good.

The fragrance composition of the present invention can be prepared by a normal homomixer, but a more stable fragrance composition can be obtained by applying a strong shearing force to a fine emulsion with a high pressure homogenizer or a nanomizer.

In the fragrance composition of the present invention, vitamins generally used in cosmetics within a range not impairing quality,
An ultraviolet absorber, an antioxidant, a plant extract, a drug, a stabilizer, a polymer compound, a coloring agent and the like can be added.

[0014]

EXAMPLES Next, the present invention will be described in more detail with reference to Examples and Comparative Examples, but the present invention is not limited thereto. Hereinafter, the blending amount is% by weight. Example 1 (1) Deionized water 96.88% (2) 1,3BG 1.0 (3) Glycerin 1.0 (4) Corn starch 0.01 (5) Xanthan gum 0.01 (6) Squalane 0.1 (7) POE (40) Oleyl ether 0.5 ( 8) Fragrance 0.5 (Production method) A part of (1) and a part of (2) are mixed to prepare a liquid (A). Part of (4) (5) (6) (7) and (8) are mixed (B)
Use as liquid. The liquid (B) was mixed with the liquid (A), an emulsion was obtained with a high-pressure homomixer, and the remaining raw materials were added thereto and sufficiently stirred to obtain a liquid cologne.

Example 2 (1) Ion-exchanged water 84.0% (2) 1,3BG 10.0 (3) DPG 1.0 (4) Hydroxypropyl cellulose 1.0 (5) Liquid paraffin 1.0 (6) POE (60) Glyceryl monoisostear Rate 1.0 (7) Fragrance 2.0 (Production method) A part of (1) and a part of (2) are mixed to obtain (A) liquid. Mix (4), (5), (6) and (7) to prepare solution (B). Liquid (B) was mixed with liquid (A), a fine emulsion was obtained with a high-pressure homogenizer, and the remaining raw materials were added thereto and stirred sufficiently to obtain a slightly viscous cologne.

Example 3 (1) Deionized water 80.6% (2) 1,3BG 5.0 (3) DPG 5.0 (4) Hydroxypropyl cellulose 1.0 (5) Carboxyvinyl polymer 0.3 (6) Liquid paraffin 1.0 (7) Soap Powder 2.0 (8) POE (60) Glyceryl monoisostearate 1.0 (9) Fragrance 4.0 (10) Caustic potassium 0.1 (Production method) Mix part of (1) and part of (2) with (A) liquid To do. Mix (4), (5), (6), (7), (8), and (9) to prepare solution (B). The liquid (B) was mixed with the liquid (A), an emulsion was obtained with a homomixer, and the remaining raw materials were added thereto and sufficiently stirred to obtain a gel-like colon.

Example 4 (1) Ion-exchanged water 77.85% (2) Glycerin 5.0 (3) 1,3BG 5.0 (4) Alkyl acrylate methacrylate copolymer 0.1 (5) Liquid paraffin 2.0 (6) POE (60 ) Glyceryl momo-isostearate 2.0 (7) POE (40) oleyl ether 2.0 (8) Fragrance 6.0 (9) Caustic potassium 0.05 (Production method) A part of (1) and a part of (3) are mixed (A). Use as liquid. Mix (4), (5), (6), (7) and (8) to prepare solution (B). The liquid (A) was mixed with the liquid (B), a fine emulsion was obtained with a high-pressure homomixer, and the remaining raw materials were added to this and sufficiently stirred to obtain a slightly viscous cologne.

Example 5 (1) Ion-exchanged water 77.6% (2) Glycerin 5.0 (3) 1,3BG 5.0 (4) Dextran 0.5 (5) Casein 0.5 (6) Carboxyvinyl polymer 0.3 (7) Liquid paraffin 2.0 ( 8) Sucrose fatty acid ester 3.0 (9) Fragrance 6.0 (10) Caustic potassium 0.1 (Production method) A part of (1) and a part of (3) are mixed to obtain (A) liquid. Mix (4), (5), (6), (7), (8), and (9) to prepare solution (B). The liquid (B) was mixed with the liquid (A), a fine emulsion was obtained with a nanomizer, and the remaining raw materials were added thereto and sufficiently stirred to obtain a gel-like colon.

Example 6 (1) Ion-exchanged water 75.29% (2) Glycerin 5.0 (3) 1,3BG 5.0 (4) Gelatin 0.01 (5) Carboxyvinyl polymer 0.5 (6) Liquid paraffin 2.0 (7) POE (40 ) Hardened castor oil 4.0 (8) Fragrance 8.0 (9) Caustic potassium 0.2 (Production method) Part of (1) and part of (3) are mixed to form (A) liquid. Mix (4), (5), (6), (7) and (8) to prepare solution (B). The liquid (B) was mixed with the liquid (A), an emulsion was obtained with a homomixer, and the remaining raw materials were added thereto and sufficiently stirred to obtain a gel-like colon.

[Comparative Example] According to the formulation of Table 1, (1) to (2)
Was added and stirred sufficiently to obtain a comparative example.

[0021]

[Table 1] ──────────────────────── (1) Ethanol (2) Perfume ────────────── Comparative Example 1 99.0% 1.0% Comparative Example 2 98.0 2.0 Comparative Example 3 96.0 4.0 Comparative Example 4 94.0 6.0 Comparative Example 5 92.0 8.0 ──────────────────────────── ─────────────

[Effect Test] Examples 1 to 6 and Comparative Examples 1 to 1
5 was used to compare and evaluate the persistence of the scent 3 hours after application, and the skin treatment effect represented by the moistness and smoothness of the skin, by 10 specialist panels. The results are shown in Tables 2 and 3. The evaluation criteria for the odor persistence and skin treatment effect are as follows.

[0023]

[0024]

[Table 2] Persistence of fragrance ────────────────────────── Score 4 3 2 1 ─────────── ──────────────── Example 1 0 4 5 1 Example 2 5 2 3 0 Example 3 8 2 2 0 0 Example 4 10 0 0 0 Example 5 10 0 0 0 Example 6 10 0 0 ────────────────────────── Comparative Example 1 0 0 1 9 Comparative Example 2 0 0 2 8 8 Comparison Example 3 0 1 3 6 Comparative Example 4 0 1 4 5 Comparative Example 5 0 2 4 4 ───────────────────────────

[0025]

[Table 3] Treatment effect on skin ────────────────────────────────── Score 4 3 2 1 1 ── ──────────────────────────────────────── Example 1 0 Name 3 6 1 Example 2 8 2 0 0 Example 3 10 0 0 0 Example 4 9 1 0 0 Example 5 10 0 0 0 Example 6 10 0 0 0 ────────────────────────── Comparative Example 1 0 0 1 9 Comparative Example 2 0 0 0 10 Comparative Example 3 0 0 2 8 Comparative Example 4 0 0 1 9 Comparative Example 5 0 0 1 9 9 ────── ────────────────────────────

[0026]

EFFECT OF THE INVENTION The fragrance composition of the present invention has a high scent persistence and is excellent in the feeling of use and the effect of improving the skin. Further, according to the present invention, since ethyl alcohol is not blended at all, a fragrance product that can be safely used by people sensitive to alcohol can be obtained.

Claims (4)

[Claims] 1. A fragrance ingredient of 0.5 to 30% by weight and an emulsifier of 0.1 to
A liquid or gel-form fragrance composition comprising a water-soluble polymer and substantially no alcohol in a fragrance composition containing 20% by weight and 50 to 99% by weight of water. 2. The perfume composition according to claim 1, wherein the content of the water-soluble polymer is 0.001 to 10% by weight. 3. The fragrance composition according to claim 1, which contains a moisturizing component in an amount of 0.1 to 30% by weight. 4. The fragrance composition according to claim 1, which contains an oily component in an amount of 0.1 to 30% by weight.