JPH08179591A - Electrifying member - Google Patents

Electrifying member

Info

Publication number
JPH08179591A
JPH08179591A JP32540894A JP32540894A JPH08179591A JP H08179591 A JPH08179591 A JP H08179591A JP 32540894 A JP32540894 A JP 32540894A JP 32540894 A JP32540894 A JP 32540894A JP H08179591 A JPH08179591 A JP H08179591A
Authority
JP
Japan
Prior art keywords
charged
charging
image carrier
image bearing
voltage
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP32540894A
Other languages
Japanese (ja)
Inventor
Eiji Funabashi
栄二 船橋
Marekatsu Mizoe
希克 溝江
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Canon Inc
Original Assignee
Canon Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Canon Inc filed Critical Canon Inc
Priority to JP32540894A priority Critical patent/JPH08179591A/en
Publication of JPH08179591A publication Critical patent/JPH08179591A/en
Pending legal-status Critical Current

Links

Landscapes

  • Discharging, Photosensitive Material Shape In Electrophotography (AREA)
  • Electrostatic Charge, Transfer And Separation In Electrography (AREA)

Abstract

PURPOSE: To prevent the melt-sticking of a developer to the surface of an image carrier, its shaving caused by the rubbing of an electrifying member and the surface of the image carrier, contamination, the generation of a noise, etc., by providing a resistant layer of a single layer incorporating a magnetic material, in contact with a conductive substrate. CONSTITUTION: The electrifying member 1 is constituted so that its surface faces the surface of the image carrier 5 with a gap and provided with the resistant layer 3 of the single layer obtained in such a manner that the magnetic material whose powder resistance is preferably >=1×10<3> Ωcm is dispersed in resin or sintered, in the position facing the image carrier 5, of the electrifying member 1, to enable uniform electrification with the gap. The resistant layer 3 of the single layer is in contact with the conductive substrate 2, in the position facing the surface of the image carrier 5 with the gap and formed like a roller or a plate. The surface of the image carrier 5 is uniformly electrified by a discharge from the surface of a layer incorporating the magnetic material of the electrifying member 1. Therefore, all problems caused by the fact that the electrifying member 1 is in contact with a member to be electrified can be eliminated.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、電子写真画像形成装置
に、一次帯電用帯電部材、転写帯電用帯電部材、除電帯
電用帯電部材等として用いられる帯電部材に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a charging member used in an electrophotographic image forming apparatus as a charging member for primary charging, a charging member for transfer charging, a charging member for static elimination charging and the like.

【0002】[0002]

【従来の技術】最近、像担持体(被帯電体)表面に直接
接触(当接)させて帯電を行なう接触帯電装置が提案さ
れている。例えば、特開昭63−7380号公報に記載
されているごとく、帯電部材をローラー状にして像担持
体(被帯電体)表面上に接触従動させて帯電を行なうも
のである。この装置は、印加電圧を低く抑さえる事が出
来ると同時に、オゾン発生量が極めて低いという利点を
有している。この他に、特開昭64−24264号公報
に提案されているような、導電性ブラシを用いる方式が
ある。この方式は、均一な帯電を実現し、かつドラム欠
陥などがあっても帯電装置が損耗を起こさないなどの利
点を有している。更に特開平1−93760号公報に記
載されているように、導電性を有する弾性ブレード上に
電極を配し、このブレードの先端を感光体に押し当てる
方式も提案されている。
2. Description of the Related Art Recently, a contact charging device has been proposed which charges a surface by directly contacting (contacting) the surface of an image bearing member (member to be charged). For example, as described in Japanese Patent Laid-Open No. 63-7380, the charging member is formed into a roller shape and is contact driven on the surface of the image bearing member (member to be charged) for charging. This device has an advantage that the applied voltage can be suppressed low and at the same time, the ozone generation amount is extremely low. In addition to this, there is a method using a conductive brush, as proposed in Japanese Patent Laid-Open No. 64-24264. This method has the advantages that uniform charging is realized and that the charging device does not wear even if there is a drum defect or the like. Further, as described in JP-A-1-93760, there has been proposed a system in which an electrode is arranged on an elastic blade having conductivity and the tip of this blade is pressed against the photoconductor.

【0003】[0003]

【発明が解決しようとする課題】しかしながら、帯電ロ
ーラは像担持体(被帯電体)表面に接触従動しているた
め、現像剤の像担持体(被帯電体)表面への融着、像担
持体(被帯電体)表面の削れといった弊害を誘発するこ
ともある。更に、帯電ローラの印加バイアスは、所望す
る像担持体(被帯電体)表面の表面電位に相当する直流
電圧に、放電開始電圧(Vth)の2倍以上のピーク間
電圧を有する交流電圧を重畳印加するのが一般的であ
り、今日の様により高精細な画像を求めようとする場
合、帯電ローラの狭い放電面積を補うため、印加する交
流電圧の周波数を大きくし、より多くの放電機会を与え
なくてはならない。この場合も帯電ローラが像担持体
(被帯電)表面に接触しているため、振動電界による帯
電ローラの振動が像担持体(被帯電体)表面に伝わり、
印加周波数の2倍の周波数を持った騒音(帯電音)を発
生する。また、ライン走査で画像情報の書き込みをして
画像形成を実行する場合には、走査線の間隔と印加周波
数が近い場合、お互いの干渉によりモアレが発生すると
いう欠点も存在する。
However, since the charging roller is in contact with and driven by the surface of the image bearing member (member to be charged), the developer is fused to the surface of the image bearing member (member to be charged) and the image bearing is carried. It may also induce adverse effects such as scraping of the surface of the body (body to be charged). Further, as the applied bias of the charging roller, an AC voltage having a peak-to-peak voltage that is at least twice the discharge start voltage (Vth) is superimposed on a DC voltage corresponding to the desired surface potential of the surface of the image carrier (charged body). Generally, it is applied, and in order to obtain a higher definition image as in today's day, the frequency of the applied AC voltage is increased to compensate for the narrow discharge area of the charging roller, and more discharge opportunities are created. I have to give it. Also in this case, since the charging roller is in contact with the surface of the image carrier (charged), the vibration of the charging roller due to the oscillating electric field is transmitted to the surface of the image carrier (charged),
Noise (charging sound) having a frequency twice the applied frequency is generated. Further, in the case of writing image information by line scanning to form an image, there is a drawback that moire occurs due to mutual interference when the spacing between scanning lines and the applied frequency are close to each other.

【0004】一方、前述のような帯電部材の製造は、導
電性基体である芯金に、弾性層/抵抗層/保護層(表
層)となる材料をこの順で重ね塗りしていく工程で行わ
れる。すなわち、まず像担持体(被帯電体)表面とのニ
ップを十分得るために、弾性層には導電性顔料を分散し
たゴムを用いる事が一般的である。次いで帯電ローラの
電気抵抗を半導電性にすると共に、像担持体(被帯電
体)表面にピンホールなどの欠陥があった場合でも電流
の集中を防ぐ目的で抵抗層が必要となる。更にゴムはそ
の弾性を発揮させるためや劣化防止のため数種の可塑剤
や活性剤を必要としており、導電性顔料を分散するため
には分散するためには分散助剤を用いる事も少なくな
い。加えて像担持体(被帯電体)の表面はポリカーボネ
ートやアクリルといった非晶性樹脂であるためこれら可
塑剤や活性剤及び分散助剤に対し非常に弱い。そこでこ
れらの漏洩を防止するために保護層が必要となってしま
う。つまり帯電ローラは、以上の様に多層構成にし、各
層の機能を発揮させる事によって目的とする性能が初め
て得られるのである。従ってその製造工程は複雑であ
り、このため帯電ローラーは非常に高価なものとなりや
すい。
On the other hand, the above-mentioned charging member is manufactured by a process of coating a core metal, which is a conductive base material, with an elastic layer / resistive layer / protective layer (surface layer) in this order. Be seen. That is, first, in order to obtain a sufficient nip with the surface of the image bearing member (charged member), it is common to use rubber in which the conductive pigment is dispersed in the elastic layer. Next, a resistance layer is required for the purpose of making the electric resistance of the charging roller semi-conductive and for preventing current concentration even if there is a defect such as a pinhole on the surface of the image bearing member (member to be charged). Furthermore, rubber requires several kinds of plasticizers and activators to exert its elasticity and prevent deterioration, and it is not uncommon to use a dispersion aid to disperse the conductive pigment. . In addition, the surface of the image bearing member (charged member) is an amorphous resin such as polycarbonate or acryl, which is very weak against these plasticizers, activators and dispersion aids. Therefore, a protective layer is required to prevent these leaks. That is, the charging roller has a multi-layered structure as described above, and the desired performance can be obtained for the first time by exhibiting the function of each layer. Therefore, the manufacturing process is complicated, and the charging roller is likely to be very expensive.

【0005】次に導電性ブラシを用いる方式では、ブラ
シの線材の当接圧が低いため、帯電領域に異物などが入
り込み易い。また箇所に於ては線材が一定の方向に揃う
ため帯電不良を起こしやすいことや、像担持体(被帯電
体)表面との接触により線材が担持体から脱落しやすい
などの問題を有している。また線材の表面は放電時に発
生する酸化物に汚染されやすいためにその寿命には限界
があり、長期間一定の性能を保つ事は困難である。
Next, in the method using a conductive brush, since the contact pressure of the wire of the brush is low, foreign matter or the like is likely to enter the charging area. In addition, since the wire rods are aligned in a certain direction at each location, there is a problem that charging defects are likely to occur and that the wire rods easily fall off from the carrier due to contact with the surface of the image bearing member (charged member). There is. Further, the surface of the wire is easily contaminated by oxides generated during discharge, so that its life is limited and it is difficult to maintain constant performance for a long period of time.

【0006】更に弾性ブレード方式は、先に挙げた線材
の脱落などの問題は発生しないが、帯電領域が狭いため
に異物の巻き込みの影響を受けやすいという問題があ
る。また放電時には交流成分の作り出す振動電界の補集
作用によりクリーナーを擦り抜けた微粉トナーや紙粉が
その表面に付着するため、抵抗ムラを生じ、画像不良を
招き易い。加えてその先端は常に感光体と摺擦し続ける
ため、磨耗が激しく、やはりその寿命には限界がある。
Further, the elastic blade method does not cause the above-mentioned problems such as the dropping of the wire rod, but has a problem that it is easily affected by the inclusion of foreign matter because the charging area is narrow. In addition, during discharge, fine powder toner and paper powder that have rubbed through the cleaner adhere to the surface due to the action of collecting the oscillating electric field generated by the AC component, which causes uneven resistance and easily causes image defects. In addition, since its tip constantly rubs against the photoconductor, it wears severely and its life is limited.

【0007】前述のような各帯電部材に伴う問題は全
て、帯電部材が像担持体(被帯電体)表面に接している
事に起因する。このため、 1)現像剤の像担持体(被帯電体)表面への融着。 2)帯電部材と像担持体(被帯電体)表面との摺擦によ
る帯電部材の損耗や像担持体(被帯電体)表面の削れ。 3)像担持体(被帯電体)表面の汚染。 4)直流電圧に交流電圧を重畳した電圧を印加した場合
に、帯電部材の振動が像担持体(被帯電体)表面に伝わ
り、印加周波数の2倍の周波数を持った騒音(帯電音)
を発生する。 と言った問題を伴う。
All the problems associated with each charging member as described above are caused by the charging member being in contact with the surface of the image bearing member (member to be charged). Therefore, 1) fusion of the developer to the surface of the image bearing member (charged member). 2) Wear of the charging member and abrasion of the surface of the image bearing member (charged member) due to rubbing between the charging member and the surface of the image bearing member (charged member). 3) Contamination of the surface of the image bearing member (charged member). 4) When a voltage in which an AC voltage is superimposed on a DC voltage is applied, the vibration of the charging member is transmitted to the surface of the image bearing member (object to be charged), and noise (charging sound) having a frequency twice the applied frequency.
Occurs. With the problem said.

【0008】本発明の目的は、上記のような、帯電部材
と被帯電部材とが接触していることに起因する問題を全
て解消することができる帯電部材を提供することであ
る。
An object of the present invention is to provide a charging member capable of solving all the problems caused by the contact between the charging member and the member to be charged as described above.

【0009】[0009]

【課題を解決するための手段】本発明によれば、少なく
とも導電性基体と、前記導電性基体に接して、磁性体を
含有した単層の抵抗層とを備えていることを特徴とする
帯電部材が提供される。
According to the present invention, there is provided at least a conductive substrate and a single resistance layer containing a magnetic substance, which is in contact with the conductive substrate. A member is provided.

【0010】すなわち本発明による帯電部材は、帯電部
材表面と像担持体(被帯電体)表面に空隙を介して対向
するものであり、この空隙を介して均一な帯電を可能と
するため、帯電部材の像担持体(被帯電体)に対向する
位置に、好ましくは粉体抵抗が1×103Ωcm以上で
ある磁性体を樹脂に分散、または焼結により得られた単
層の抵抗層を有するものである。
That is, the charging member according to the present invention opposes the surface of the charging member and the surface of the image bearing member (object to be charged) via a gap, and enables uniform charging through this gap. A single resistance layer obtained by dispersing or sintering a magnetic material having a powder resistance of 1 × 10 3 Ωcm or more in a resin is preferably provided at a position facing the image bearing member (charged member) of the member. I have.

【0011】詳しく述べると、本発明による帯電部材
は、好ましくは粉体抵抗が1×103Ωcm以上である
磁性体を樹脂に分散、または焼結により得られた単層の
抵抗層が導電性基体に接し、且つ像担持体(被帯電体)
表面に対し空隙を介し対向する位置に存在し、且つその
形状がローラ状または平板状である事を特徴とする帯電
部材である。
More specifically, in the charging member according to the present invention, a single resistance layer obtained by dispersing or sintering a magnetic material having a powder resistance of 1 × 10 3 Ωcm or more in a resin is preferably conductive. Image carrier (charged body) in contact with substrate
A charging member which is present at a position facing a surface with a gap therebetween and has a shape of a roller or a plate.

【0012】つまり本発明による帯電部材は、帯電部材
表面と像担持体(被帯電体)表面を空隙を介して対向さ
せ、この帯電部材の磁性体を含有した層の表面からの放
電により像担持体(被帯電体)表面を均一に帯電するも
のであるため、帯電部材と被帯電部材とが接触している
ことに起因する前述のような問題を全て解消することが
できる。
That is, in the charging member according to the present invention, the surface of the charging member and the surface of the image bearing member (member to be charged) are opposed to each other with a gap, and the image bearing is carried by discharge from the surface of the layer containing the magnetic material of the charging member. Since the surface of the body (object to be charged) is uniformly charged, it is possible to eliminate all the problems as described above due to the contact between the charging member and the member to be charged.

【0013】本発明による帯電部材で問題となるのは、
いかにして空隙を確保するかということである。以下に
述べる様に空隙を介して像担持体表面を一定の電位に帯
電する場合は直接印加電圧の増減に影響するため、出来
るかぎり小さい方が望ましい。しかしながら帯電部材の
精度及び量産時の公差等を考慮すると、実際には100
μm以下での展開は非常に難しい。そこで本発明による
帯電部材は像担持体(被帯電体)表面に対して100μ
m以上の空隙を確保した場合にも均一な帯電が可能であ
る帯電部材を提供するものである。
The problem with the charging member according to the present invention is that
It is how to secure the void. As described below, when the surface of the image bearing member is charged to a constant potential via the void, it directly affects the increase / decrease of the applied voltage, so that it is preferably as small as possible. However, in consideration of the accuracy of the charging member and the tolerance in mass production, it is actually 100
It is very difficult to develop below μm. Therefore, the charging member according to the present invention is 100 .mu.
It is intended to provide a charging member capable of being uniformly charged even when a void of m or more is secured.

【0014】ここで空隙を介しての放電開始電圧はパッ
シェンの法則より導かれた絶縁破壊電圧の近似式 Vth(放電開始電圧)=312+6.2d (d=空隙;μm 但しd=8μm以上の場合) により決まる。即ち理論的には空隙を100μmとする
場合、放電開始電圧(Vth)は932vとなり、これ
に所望の像担持体(被帯電体)表面電位を加えた値の直
流電圧を印加すれば像担持体(被帯電体)表面を所望の
電位に帯電できる。同様に空隙を200μmとすれば放
電開始電圧(Vth)は1552vとなり、直流電圧の
み印加する場合には所望の像担持体(被帯電体)表面電
位を加えた値の直流電圧を印加する事により像担持体
(被帯電体)表面を所望の表面電位に帯電できる事にな
る。
Here, the discharge start voltage through the air gap is an approximate expression of the dielectric breakdown voltage derived from Paschen's law Vth (discharge start voltage) = 312 + 6.2d (d = gap; μm where d = 8 μm or more ). That is, theoretically, when the gap is 100 μm, the discharge start voltage (Vth) is 932 V, and if a DC voltage of a value obtained by adding a desired surface potential of the image carrier (charged member) is applied to the image carrier, (Charge object) The surface can be charged to a desired potential. Similarly, when the gap is 200 μm, the discharge start voltage (Vth) is 1552 v, and when only the DC voltage is applied, by applying the DC voltage of a value including the desired surface potential of the image carrier (charged body). The surface of the image bearing member (charged member) can be charged to a desired surface potential.

【0015】また、直流電圧に交流電圧を重畳した電圧
を印加した場合には所望の像担持体(被帯電体)表面電
位に相当する直流電圧に、その時の空隙に対する放電開
始電圧(Vth)の2倍以上のピーク間電圧を有する交
流電圧を一定の周波数で印加すれば所望する表面電位に
帯電できる。つまり空隙を拡大するに連れ印加電圧を大
きくするだけで像担持体(被帯電体)表面を所望の表面
電位に帯電出来る事になるのであるが、本発明者らは空
隙が拡大するにしたがって、像担持体(被帯電体)表面
の帯電状態、即ち表面電位に斑点状のムラが存在する事
を発見し、そのムラは空隙が100μmをこえると特に
増加し、単純に空隙に応じた電圧を印加するだけでは均
一な帯電は得られない事を確認した。
When a voltage obtained by superimposing an AC voltage on a DC voltage is applied, the DC voltage corresponding to the desired surface potential of the image bearing member (charged member) is changed to the discharge start voltage (Vth) for the air gap at that time. By applying an AC voltage having a peak-to-peak voltage that is twice or more at a constant frequency, it is possible to charge to a desired surface potential. That is, the image carrier (charged body) surface can be charged to a desired surface potential simply by increasing the applied voltage as the voids are expanded. It was discovered that there was spot-like unevenness in the charged state of the surface of the image bearing member (charged member), that is, the surface potential, and the unevenness increased especially when the voids exceeded 100 μm, and the voltage corresponding to the voids was simply applied. It was confirmed that uniform charging cannot be obtained only by applying.

【0016】本発明者らは、この現象を次のように考え
た。従来の帯電部材の放電面の材料は像担持体(被帯電
体)表面にピンホールが存在した場合にも電流の集中
(リーク)を防ぎえる下限の抵抗から、著しい印加電圧
の電圧降下を起こさない上限の抵抗までの範囲として1
×105〜1×1010Ωcmの体積抵抗率範囲が経験的
に知られている。このような所謂、中抵抗の範囲に材料
を調整するには材料自体が前記抵抗範囲に収まるもの
や、絶縁性材料に導電性顔料(導電性カーボン、導電性
酸化錫、導電性酸化チタン、AL粉、Cu粉、Ni粉等
等等)を分散して電気抵抗を調整する方法があるが、前
者はその数が少なくまた、雰囲気による抵抗変動も大き
いため、後者が一般的に広く用いられてきた。ここで絶
縁性材料に導電性顔料を分散した材料を放電面として用
いた場合、印加された電圧は材料中の導電性顔料を伝わ
ってその表面に達する。別の言い方をすれば、細かい針
電極が無数に存在している事となる。
The present inventors considered this phenomenon as follows. The material of the discharge surface of the conventional charging member causes a significant voltage drop of the applied voltage from the lower limit resistance that can prevent current concentration (leakage) even when there is a pinhole on the surface of the image carrier (member to be charged). 1 as the range up to the upper limit of resistance
The volume resistivity range of × 10 5 to 1 × 10 10 Ωcm is empirically known. In order to adjust the material in such a so-called medium resistance range, the material itself falls within the above resistance range, and the conductive material (conductive carbon, conductive tin oxide, conductive titanium oxide, AL, etc.) is used as the insulating material. Powder, Cu powder, Ni powder, etc.) is used to adjust the electric resistance. However, the former is small in number and the resistance fluctuation due to the atmosphere is large, so the latter is generally widely used. It was Here, when a material in which a conductive pigment is dispersed in an insulating material is used as the discharge surface, the applied voltage reaches the surface through the conductive pigment in the material. In other words, there are innumerable fine needle electrodes.

【0017】さて、空間に於て電子は印加電界よりエネ
ルギーを得て抵抗層表面より電離する。更に電離した電
子は空間を形成する気体に付着し荷電粒子を形成してい
く。放電面付近ではエネルギーが高いので荷電粒子の濃
度も高く、これらは衝突を繰り返し密度の高い場所から
低い場所(像担持体表面方向)へと拡散していき、最終
的に像担持体面に到達した荷電粒子は像担持体表面に電
荷を与え中性粒子となる。放電空間内に印加電界により
多数の電子が供給され、その供給の時間間隔が電子の空
間走行時間以内にあり、且つ一定の時間間隔で供給され
る場合に空間内を複数個の電子が走行している状態とな
り、常に安定した拡散条件を満たしている。従ってドラ
ム表面は均一に帯電される。そしてその時の空隙の上限
が100μmであるとの結果を得た。一方、空隙が10
0μm以上になると放電面にかかる電圧が上昇する。こ
こで放電面に用いる材料は導電性顔料を分散したもので
あり、この導電性顔料の導通路を針電極の集合体として
捉え、この1本に注目して考えると針電極に大きな印加
電界を与えた事となり、電子の電離回数が極端に大きく
なりその密度も過剰になると考えられる。従って荷電粒
子に次々と電子が流入してプラズマ部分が形成されてし
まう。
In the space, electrons gain energy from the applied electric field and are ionized from the surface of the resistance layer. Further, the ionized electrons adhere to the gas forming the space and form charged particles. Since the energy is high near the discharge surface, the concentration of charged particles is also high. These particles repeatedly collide and diffuse from a high density area to a low density area (image carrier surface direction) and finally reach the image carrier surface. The charged particles give an electric charge to the surface of the image carrier to become neutral particles. A large number of electrons are supplied to the discharge space by the applied electric field, and the time interval of the supply is within the space travel time of the electrons, and when the electrons are supplied at a constant time interval, a plurality of electrons travel in the space. The stable diffusion condition is always satisfied. Therefore, the drum surface is uniformly charged. And the result that the upper limit of the voids at that time was 100 μm was obtained. On the other hand, the gap is 10
When it is 0 μm or more, the voltage applied to the discharge surface increases. Here, the material used for the discharge surface is one in which a conductive pigment is dispersed, and the conductive path of this conductive pigment is regarded as an assembly of needle electrodes. It is considered that the number of times of ionization of electrons becomes extremely large and the density thereof becomes excessive as well. Therefore, electrons flow into the charged particles one after another to form a plasma portion.

【0018】この様な状態を一般的にはストリーマと称
している。つまり空隙の拡大により放電開始電圧が増加
し、それに対応して印加電圧が上昇する事で、放電面を
形成する針電極にかかる電界の増加により均一帯電に必
要な拡散状態が破壊されストリーマを形成してしまうた
め、像担持体(被帯電体)表面の電位が斑点状のムラに
なってしまうのである。この境界となる空隙が100μ
mであり、100μmの空隙に於ける放電開始電圧+所
望する像担持体(被帯電体)表面電位に相当する高電圧
が印加された場合、従来用いられてきた導電性顔料では
ストリーマの形成を抑さえられないとの結論に達したの
である。
Such a state is generally called a streamer. In other words, the discharge start voltage increases due to the expansion of the air gap, and the applied voltage rises correspondingly, and the diffusion state required for uniform charging is destroyed by the increase in the electric field applied to the needle electrode that forms the discharge surface, forming a streamer. As a result, the potential on the surface of the image bearing member (the member to be charged) becomes spotted unevenness. The void that becomes this boundary is 100μ
m, and when a high voltage corresponding to the discharge start voltage in a void of 100 μm + the desired surface potential of the image bearing member (charged member) is applied, a streamer is formed in the conductive pigment that has been conventionally used. He came to the conclusion that he could not be suppressed.

【0019】本発明者らは、この考えを元に鋭意検討を
重ねた結果、導電性顔料の電気抵抗自体に解を見い出し
た。つまり従来用いられてきた導電性顔料(導電性カー
ボン、導電性酸化錫、導電性酸化チタン、AL粉、Cu
粉、Ni粉等)の粉体抵抗は100Ωcm以下であり、
導電性が高すぎるため、大きな印加電界により電子の電
離回数が極端に大きくなり、従って荷電粒子に次々と電
子が流入して起こるプラズマ部分の形成を抑さえられな
いのである。そこで本発明者らは、粉体抵抗の比較的高
い導電粉を放電面に用いる事とした。具体的には抵抗の
安定性、粒径及び形状の安定性、コスト等を考慮した上
で、磁性体を用いる事が最も望ましいとの結果に到達し
た。これは空隙が100μm以上に於て、放電開始電圧
+像担持体(被帯電体)表面の表面電位に相当する大き
な印加電界が加えられた場合にも粉体抵抗自体が高い、
つまり前記針電極自体の抵抗が高い事により過剰に発生
する電流エネルギーを磁性体が熱エネルギーに変換し、
過剰な電子の発生を抑えられ電子の電離回数を抑制し、
従って荷電粒子に次々と電子が流入して起こるプラズマ
部分の形成を抑さえると考えられる。
As a result of intensive studies based on this idea, the present inventors have found a solution to the electric resistance itself of the conductive pigment. In other words, the conductive pigments that have been conventionally used (conductive carbon, conductive tin oxide, conductive titanium oxide, AL powder, Cu
Powder, Ni powder, etc.) has a powder resistance of 100 Ωcm or less,
Since the conductivity is too high, the number of times of ionization of electrons becomes extremely large due to a large applied electric field, so that the formation of the plasma portion which is caused by the successive inflow of electrons into the charged particles cannot be suppressed. Therefore, the present inventors decided to use conductive powder having a relatively high powder resistance for the discharge surface. Specifically, the inventors have reached the result that it is most desirable to use a magnetic material in consideration of resistance stability, particle size and shape stability, cost, and the like. This is because when the void is 100 μm or more, the powder resistance itself is high even when a large applied electric field corresponding to the discharge start voltage + the surface potential of the surface of the image carrier (charged body) is applied.
That is, the magnetic material converts the current energy generated excessively due to the high resistance of the needle electrode itself into heat energy,
The generation of excessive electrons can be suppressed and the number of times of electron ionization can be suppressed,
Therefore, it is considered that the formation of the plasma part which is caused by the inflow of electrons into the charged particles one after another is suppressed.

【0020】さて、磁性体とは磁場を与えることで磁化
する物質の事であるが、本発明による帯電部材に用いる
磁性体は磁化の有無は関係なく、その粉体抵抗が1×1
3Ωcm以上であれば効果を発揮するものであり、具
体的には酸化鉄、フェライト等が用いられる。本発明に
よる帯電部材に用いる抵抗層の一つの作成法は、磁性体
をバインダー樹脂中に分散し抵抗層を形成する方法であ
る。その場合の磁性体はバインダー樹脂中に均一に分散
される事が望まれるが、その他特に磁性体への制約を受
けるものではない。従って磁性体の形状は球状でも八面
体でも針状でも構わない。磁性体のバインダー樹脂への
添加量(重量パーセント;wt%)は30wt%以上の
範囲にあり好ましくは50wt%以上である。添加量が
30wt%未満では磁性体が少ないためバインダー樹脂
中に導通路が形成されず、いわゆる微細な針電極となり
えない。このような抵抗層の作成法に於て、用いるバイ
ンダー樹脂は、雰囲気による抵抗変動が少ないものを用
いる事が望まれる。具体例を挙げるならば、ポリエステ
ル、ポリウレタン、ナイロン、シリコン、アクリル、ポ
リオレフィン、フェノール等の各樹脂から適宜選ばれる
ものである。
The magnetic substance is a substance which is magnetized by applying a magnetic field. The magnetic substance used in the charging member according to the present invention has a powder resistance of 1 × 1 regardless of the presence or absence of magnetization.
If it is 0 3 Ωcm or more, the effect is exhibited, and specifically, iron oxide, ferrite or the like is used. One method of forming the resistance layer used for the charging member according to the present invention is a method of forming a resistance layer by dispersing a magnetic material in a binder resin. In that case, it is desired that the magnetic material be uniformly dispersed in the binder resin, but there is no particular restriction on the magnetic material. Therefore, the shape of the magnetic body may be spherical, octahedral or needle-like. The amount of the magnetic substance added to the binder resin (weight percent; wt%) is in the range of 30 wt% or more, preferably 50 wt% or more. If the added amount is less than 30 wt%, the magnetic substance is too small to form a conductive path in the binder resin, so that a so-called fine needle electrode cannot be obtained. In the method of forming such a resistance layer, it is desired that the binder resin used has little resistance variation due to the atmosphere. Specific examples thereof include those appropriately selected from resins such as polyester, polyurethane, nylon, silicon, acryl, polyolefin and phenol.

【0021】また、本発明に用いる抵抗層の作成法は、
磁性体を焼結させて所望の形状を得る方法であっても構
わない。但し、上記各作成法に於て得られる抵抗層の表
面粗さは、表面平均粗さ(Ra)が0.5μm以下であ
る事が望ましい。これらの条件を満たした上で用いる磁
性体の粉体抵抗の高低により添加量を調整し、得られた
抵抗層の抵抗値は105〜1010Ωcmに収める必要が
ある。体積抵抗率が1×105Ωcm未満では印加され
た電圧を均一に分圧する事が出来ず局所的な導通回路を
形成するので均一な帯電は行えない。また体積抵抗率が
1×1010Ωcmを越えると、印加電圧の電圧降下を引
き起こし、十分に放電することが出来ない。従って電子
の電離回数が極端に減少してしまうため、帯電性能を著
しく低下させてしまう。なお、前記条件内であれば2種
以上の磁性体を併用してもよい。
The method of forming the resistance layer used in the present invention is as follows.
A method of sintering a magnetic material to obtain a desired shape may be used. However, regarding the surface roughness of the resistance layer obtained by each of the above-mentioned preparation methods, it is desirable that the surface average roughness (Ra) is 0.5 μm or less. It is necessary that the resistance value of the obtained resistance layer is set to 10 5 to 10 10 Ωcm by satisfying these conditions and adjusting the addition amount depending on the level of the powder resistance of the magnetic material used. If the volume resistivity is less than 1 × 10 5 Ωcm, the applied voltage cannot be uniformly divided and a local conduction circuit is formed, so that uniform charging cannot be performed. On the other hand, if the volume resistivity exceeds 1 × 10 10 Ωcm, a voltage drop of the applied voltage is caused and sufficient discharge cannot be performed. Therefore, since the number of times of ionization of electrons is extremely reduced, the charging performance is significantly reduced. It should be noted that two or more kinds of magnetic materials may be used in combination under the above conditions.

【0022】以下、本発明による帯電部材を、図1およ
び図2を参照して説明する。本発明の帯電部材1は、適
当な金属からなる、この例では細長い板状の導電性基体
2の一方の表面に、単層の抵抗層3を設けた構造を有す
るもので、適当なスペーサ4により、像担持体5(被帯
電体)表面に対して所定の空隙6を介して対向する位置
に配置される。
The charging member according to the present invention will be described below with reference to FIGS. 1 and 2. The charging member 1 of the present invention has a structure in which a single-layer resistance layer 3 is provided on one surface of a conductive base plate 2 made of an appropriate metal, which is an elongated plate in this example. Thus, it is arranged at a position facing the surface of the image carrier 5 (member to be charged) with a predetermined gap 6 therebetween.

【0023】この空隙6を介して均一な帯電を可能とす
るため、帯電部材の像担持体5(被帯電体)表面に対向
する位置に、粉体抵抗が1×103Ωcm以上である磁
性体を樹脂に分散、または焼結により得られた単層の抵
抗層3を有するものである。
In order to enable uniform charging through the voids 6, the magnetic powder having a powder resistance of 1 × 10 3 Ωcm or more is located at a position facing the surface of the image bearing member 5 (charged member) of the charging member. It has a single resistance layer 3 obtained by dispersing or sintering the body in a resin.

【0024】詳しくは、本発明の帯電部材1は、粉体抵
抗が1×103Ωcm以上である磁性体を樹脂に分散、
または焼結により得られた単層の抵抗層3が導電性基体
に接して設けられたもので、像担持体(被帯電体)5表
面に対し空隙を介して対向する位置に配置される。
More specifically, in the charging member 1 of the present invention, a magnetic material having a powder resistance of 1 × 10 3 Ωcm or more is dispersed in a resin,
Alternatively, a single resistance layer 3 obtained by sintering is provided in contact with a conductive substrate, and is arranged at a position facing the surface of the image bearing member (member to be charged) 5 with a gap.

【0025】導電性基体2としては、帯電部材1の形状
と、像担持体(被帯電体)5表面との間の空隙を常に一
定に保つため、剛性の高い金属材料からなるものであ
る。
The conductive substrate 2 is made of a metal material having high rigidity so that the space between the shape of the charging member 1 and the surface of the image bearing member (charged member) 5 is always kept constant.

【0026】本発明の帯電部材の形状は、図1および図
2に示したような平板状であってもよく、あるいは図3
および図4に示すように、ローラ状であってもよい。
The charging member of the present invention may have a flat plate shape as shown in FIGS. 1 and 2, or FIG.
Also, as shown in FIG. 4, it may be roller-shaped.

【0027】帯電部材1の形状がローラ状または平板状
のいずれであっても、この帯電部材1の両端部に、被帯
電部材5との間に所定の空隙を確保するために、スペー
サ部材4が設けられる。スペーサ部材4としては摩擦係
数の低いテフロン、高分子ポリエチレン、POM等の材
料が望ましい。
Whether the charging member 1 has a roller shape or a flat plate shape, spacer members 4 are provided at both ends of the charging member 1 in order to secure a predetermined space between the charging member 1 and the member 5 to be charged. Is provided. The spacer member 4 is preferably made of a material having a low friction coefficient such as Teflon, high molecular weight polyethylene, or POM.

【0028】本発明の帯電部材は、設置された電源より
導電性基体に電圧が印加される。印加電圧は導電性基体
に接している単層の抵抗層に伝わりその表面からの放電
により、像担持体(被帯電体)5の表面を均一に帯電さ
せる。
In the charging member of the present invention, a voltage is applied to the conductive substrate from the installed power source. The applied voltage is transmitted to the single resistance layer in contact with the conductive substrate, and the surface of the image bearing member (charged member) 5 is uniformly charged by the discharge from the surface.

【0029】[0029]

【実施例】以下、実施例に基づき本発明を説明する。EXAMPLES The present invention will be described below based on examples.

【0030】(実施例1)ナイロン−12樹脂に、粉体
抵抗が1×105Ωcmで、直径が0.2μm、長さが
5μmの針状の酸化鉄を70wt%配合し、加圧ニーダ
ーにて溶融混練し、その抵抗値が1×108Ωcmであ
る半導電性材料を調製した。この材料を用いて、押出機
での溶融押出しにより、厚さ500μmのシートを連続
的に作成した。なお、その表面平均粗さ(Ra)は0.
08μmであった。
Example 1 Nylon-12 resin was blended with 70 wt% of needle-shaped iron oxide having a powder resistance of 1 × 10 5 Ωcm, a diameter of 0.2 μm and a length of 5 μm. Was melt-kneaded to prepare a semiconductive material having a resistance value of 1 × 10 8 Ωcm. Using this material, a sheet having a thickness of 500 μm was continuously prepared by melt extrusion using an extruder. The surface average roughness (Ra) was 0.
It was 08 μm.

【0031】このようにして作成した単層の抵抗層を所
定の大きさに打ち抜き、ステンレス製の平行平板に導電
性プライマーを介して貼り合わせた。更に像担持体(被
帯電体)と、単層の抵抗層の表面が100μmの空隙を
持つ様に作成したPOM製のスペーサ部材をステンレス
製の平行平板の両端部に取付け、目的とする帯電部材を
得た。
The single resistance layer thus prepared was punched into a predetermined size and attached to a parallel plate made of stainless steel via a conductive primer. Further, a POM spacer member formed so that the surface of the image bearing member (charged member) and the resistance layer of a single layer has a gap of 100 μm is attached to both ends of a parallel plate made of stainless steel, and a target charging member is obtained. Got

【0032】得られた帯電部材を、図5に示す電子写真
用装置の1次帯電器の位置に取り付けた。図5におい
て、1は帯電部材、5は像担持体、12は帯電用電源、
13は現像器、14はクリーナ、15は転写ローラ、1
6は被転写体である。
The charging member thus obtained was attached to the position of the primary charger of the electrophotographic apparatus shown in FIG. In FIG. 5, 1 is a charging member, 5 is an image carrier, 12 is a charging power source,
13 is a developing device, 14 is a cleaner, 15 is a transfer roller, 1
Reference numeral 6 is a transferred material.

【0033】像担持体(被帯電体)5表面とスペーサ部
材(図示せず)との当接圧力が10gとなるように、こ
の両者間にばねを作用させた。なお当接圧力は、像担持
体5表面とスペーサ部材4との間に幅1cmのアルミニ
ウムシートをはさみ、引き抜く時の力を測定した値であ
る。
A spring was actuated between the surface of the image bearing member (charged member) 5 and the spacer member (not shown) so that the contact pressure was 10 g. The contact pressure is a value obtained by sandwiching an aluminum sheet having a width of 1 cm between the surface of the image carrier 5 and the spacer member 4 and measuring the force when the aluminum sheet is pulled out.

【0034】帯電部材1に、電源12から−1650v
の直流電圧(空隙100μmでのVthは−932vで
あり、用いた像担持体の設定された表面電位は−650
vである)を印加し、標準環境(23℃)/(55
%)、高温(32.5℃)/高湿(85%)、及び低温
(15℃)/低湿(10%)の環境下で10000枚の
耐久評価を行った。
From the power supply 12 to the charging member 1, -1650v
DC voltage (Vth in the air gap of 100 μm is −932 v, and the set surface potential of the image carrier used is −650.
v) is applied, and the standard environment (23 ° C.) / (55
%), High temperature (32.5 ° C.) / High humidity (85%), and low temperature (15 ° C.) / Low humidity (10%), 10,000 sheets were subjected to durability evaluation.

【0035】その結果、全ての環境下で、初期と耐久後
で殆ど画像変化は無く、良好な画像を得た。また、像担
持体表面への現像剤の融着、帯電部材の損耗や像担持体
(被帯電体)表面の削れ、及び騒音(帯電音)等の問題
も一切認められなかった。
As a result, in all environments, there was almost no change in the image at the initial stage and after the durability test, and a good image was obtained. Further, no problems such as fusion of the developer on the surface of the image bearing member, wear of the charging member, abrasion of the surface of the image bearing member (member to be charged), and noise (charging noise) were observed.

【0036】(実施例2)実施例1で作成した帯電部材
のスペーサを、像担持体(被帯電体)と、単層の抵抗層
の表面とが、それぞれ200μm及び300μmの空隙
を持つ様に変更し、それぞれ−2200vと−2850
vの直流電圧を印加し、実施例1同様に耐久試験に供し
た。
(Embodiment 2) The spacer of the charging member prepared in Embodiment 1 is arranged so that the image bearing member (the member to be charged) and the surface of the single resistance layer have voids of 200 μm and 300 μm, respectively. Changed to -2200v and -2850 respectively
A DC voltage of v was applied and the durability test was carried out in the same manner as in Example 1.

【0037】その結果、いずれの条件でも、全ての環境
下で初期と耐久後で殆ど画像変化は無く、良好な画像を
得た。また、像担持体表面への現像剤の融着、帯電部材
の損耗や像担持体(被帯電体)表面の削れ、及び騒音
(帯電音)等の問題も一切認められなかった。
As a result, under all conditions, there was almost no change in the image in the initial stage and after the endurance under all environments, and a good image was obtained. Further, no problems such as fusion of the developer on the surface of the image bearing member, wear of the charging member, abrasion of the surface of the image bearing member (member to be charged), and noise (charging noise) were observed.

【0038】(実施例3)実施例1で作成した帯電部材
を用い、−650vの直流電圧に2500vppのピー
ク間電圧を有する交流電圧を200Hzの周波数で重畳
印加し、実施例1同様に耐久試験に供した。
(Example 3) Using the charging member prepared in Example 1, an AC voltage having a peak-to-peak voltage of 2500 vpp was superposed on a DC voltage of -650 V at a frequency of 200 Hz, and a durability test was conducted as in Example 1. I went to

【0039】その結果、全ての環境下で初期と耐久後で
殆ど画像変化は無く良好な画像を得た。また、像担持体
表面への現像剤の融着、帯電部材の損耗や像担持体(被
帯電体)表面の削れ、及び騒音(帯電音)等の問題も一
切認められなかった。
As a result, a good image was obtained under almost all environments, with almost no image change at the initial stage and after the durability test. Further, no problems such as fusion of the developer on the surface of the image bearing member, wear of the charging member, abrasion of the surface of the image bearing member (member to be charged), and noise (charging noise) were observed.

【0040】更にその時の帯電音を騒音計で測定したと
ころ、45dBであり、きわめて静かであった。
Further, when the charging sound at that time was measured with a sound level meter, it was 45 dB, which was extremely quiet.

【0041】(実施例4)粉体抵抗が1×107Ωc
m、平均粒径が30μmのニッケル−亜鉛系フェライト
を、所定の大きさの板状にプレスし600℃で焼結して
単層の抵抗層を作成した。なお、その表面平均粗さ(R
a)は0.15μmであった。次いでステンレス製の平
行平板に導電性プライマーを介して貼り合わせた。更に
像担持体(被帯電体)と単層の抵抗層の表面が100μ
mの空隙を持つ様に作成したPOM製のスペーサ部材を
ステンレス製の平行平板の両端部に取付け、目的とする
帯電部材を得た。以下実施例1同様に耐久試験に供し
た。
Example 4 Powder resistance is 1 × 10 7 Ωc
A nickel-zinc-based ferrite having an average particle size of 30 μm and a diameter of 30 μm was pressed into a plate having a predetermined size and sintered at 600 ° C. to form a single resistance layer. The surface average roughness (R
a) was 0.15 μm. Then, it was attached to a parallel plate made of stainless steel via a conductive primer. Furthermore, the surface of the image bearing member (charged member) and the single resistance layer is 100μ.
Spacer members made of POM prepared so as to have voids of m were attached to both ends of a parallel plate made of stainless steel to obtain a target charging member. The same tests as in Example 1 were performed below.

【0042】その結果、全ての環境下で初期と耐久後で
殆ど画像変化は無く良好な画像を得た。また、像担持体
表面への現像剤の融着、帯電部材の損耗や像担持体(被
帯電体)表面の削れ、及び騒音(帯電音)等の問題も一
切認められなかった。
As a result, good images were obtained under almost all environments, with almost no image change at the initial stage and after the durability test. Further, no problems such as fusion of the developer on the surface of the image bearing member, wear of the charging member, abrasion of the surface of the image bearing member (member to be charged), and noise (charging noise) were observed.

【0043】(実施例5)ポリエステル樹脂に粉体抵抗
が1×104Ωcm、平均粒径が1μmの酸化鉄を65
wt%配合し、加圧ニーダーにて溶融混練し、その抵抗
値が1×107Ωcmである半導電性材料を調製した。
この材料をφ6mmのステンレス製芯金の外周上に射出
成型し、その後研磨によりφ12mmの単層ローラを作
成した。なお、その表面平均粗さ(Ra)は0.10μ
mであった。次いで像担持体(被帯電体)と単層の抵抗
層の表面が100μmの空隙を持つ様に作成したPOM
製のスペーサ部材を単層ローラの両端部に取付け目的と
する帯電部材を得た。
[0043] (Example 5) Powder resistance in the polyester resin is 1 × 10 4 Ωcm, average particle size of 1μm iron oxide 65
wt% was blended and melt-kneaded with a pressure kneader to prepare a semiconductive material having a resistance value of 1 × 10 7 Ωcm.
This material was injection-molded on the outer circumference of a φ6 mm stainless steel cored bar, and then polished to form a φ12 mm single-layer roller. The surface average roughness (Ra) is 0.10 μm.
It was m. Then, the POM was prepared so that the surface of the image bearing member (the member to be charged) and the single resistance layer had a void of 100 μm.
A spacer member made of was attached to both ends of the single-layer roller to obtain an intended charging member.

【0044】以下、実施例1同様に耐久試験に供した。
その結果、全ての環境下で初期と耐久後で殆ど画像変化
は無く良好な画像を得た。また、像担持体表面への現像
剤の融着、帯電部材の損耗や像担持体(被帯電体)表面
の削れ、及び騒音(帯電音)等の問題も一切認められな
かった。
Thereafter, a durability test was conducted in the same manner as in Example 1.
As a result, good images were obtained under almost all environments, with almost no image change at the initial stage and after the durability test. Further, no problems such as fusion of the developer on the surface of the image bearing member, wear of the charging member, abrasion of the surface of the image bearing member (member to be charged), and noise (charging noise) were observed.

【0045】(比較例1)ナイロン−12樹脂に、粉体
抵抗が2Ωcmで平均粒径が0.2μmの導電性酸化チ
タンを50wt%配合し、加圧ニーダーにて溶融混練
し、その抵抗値が1×107Ωcmである半導電性材料
を調製した。この材料を押出機での溶融押し出しにより
厚さ500μmのシートを連続的に作成した。なお、そ
の表面平均粗さ(Ra)は0.12μmであった。この
ようにして作成した単層の抵抗層を所定の大きさに打ち
抜き、ステンレス製の平行平板に導電性プライマーを介
して貼り合わせた。更に像担持体(被帯電体)と、単層
の抵抗層の表面とが100μmの空隙を持つ様に作成し
たPOM製のスペーサ部材をステンレス製の平行平板の
両端部に取付けて帯電部材を得た。以下実施例1同様の
テストに供したが、斑点状のムラが多発し良好な画像は
得られなかった。
Comparative Example 1 Nylon-12 resin was blended with 50 wt% of conductive titanium oxide having a powder resistance of 2 Ωcm and an average particle size of 0.2 μm, melted and kneaded with a pressure kneader, and the resistance value was obtained. A semiconducting material having a value of 1 × 10 7 Ωcm was prepared. This material was melt extruded with an extruder to continuously form a sheet having a thickness of 500 μm. The surface average roughness (Ra) was 0.12 μm. The single-layer resistance layer thus formed was punched out to a predetermined size and attached to a parallel plate made of stainless steel via a conductive primer. Further, spacer members made of POM prepared so that the image carrier (charged body) and the surface of the single resistance layer have a gap of 100 μm are attached to both ends of a parallel plate made of stainless steel to obtain a charging member. It was The same test as in Example 1 was performed below, but a spot-like unevenness was frequently generated, and a good image could not be obtained.

【0046】(比較例2)ポリエステル樹脂に粉体抵抗
が1×10-1Ωcm、平均粒径が0.1μmの導電性カ
ーボンを10wt%配合し、加圧ニーダーにて溶融混練
し、その抵抗値が1×106Ωcmである半導電性材料
を調製した。この材料をφ6mmのステンレス製芯金の
外周上に射出成型し、その後研磨によりφ12mmの単
層ローラを作成した。なお、その表面平均粗さ(Ra)
は0.09μmであった。次いで像担持体(被帯電体)
と単層の抵抗層の表面が100μmの空隙を持つ様に作
成したPOM製のスペーサ部材を単層ローラの両端部に
取付けた帯電部材を得た。実施例1同様のテストに供し
たが斑点状のムラが多発し良好な画像は得られなかっ
た。
(Comparative Example 2) 10 wt% of conductive carbon having a powder resistance of 1 × 10 -1 Ωcm and an average particle size of 0.1 μm was mixed with polyester resin, melted and kneaded with a pressure kneader, and the resistance was measured. A semiconductive material having a value of 1 × 10 6 Ωcm was prepared. This material was injection-molded on the outer circumference of a φ6 mm stainless steel cored bar, and then polished to form a φ12 mm single-layer roller. The surface average roughness (Ra)
Was 0.09 μm. Next image carrier (charged body)
A charging member was obtained in which spacer members made of POM prepared so that the surface of the single resistance layer had voids of 100 μm were attached to both ends of the single layer roller. The same test as in Example 1 was carried out, but spotty unevenness frequently occurred, and a good image could not be obtained.

【0047】[0047]

【発明の効果】本発明による帯電部材は磁性体を分散し
た層の表面からの放電により、像担持体(被帯電体)表
面に対して100μm以上の空隙を確保した場合にも均
一な帯電が可能である帯電部材である。従って 1)現像剤の像担持体(被帯電体)表面への融着。 2)帯電部材と像担持体(被帯電体)表面との摺擦によ
る帯電部材の損耗や像担持体(被帯電体)表面の削れ。 3)像担持体(被帯電体)表面の汚染。 4)直流電圧に交流電圧を重畳した電圧を印加した場合
に、帯電部材の振動が像担持体(被帯電体)表面に伝わ
り、印加周波数の2倍の周波数を持った騒音(帯電音)
を発生する。 といった問題を全て解消する事が可能である。
EFFECT OF THE INVENTION The charging member according to the present invention discharges from the surface of the layer in which the magnetic material is dispersed, so that uniform charging can be achieved even when a space of 100 μm or more is secured on the surface of the image bearing member (charged member). It is a possible charging member. Therefore, 1) fusion of the developer to the surface of the image bearing member (charged member). 2) Wear of the charging member and abrasion of the surface of the image bearing member (charged member) due to rubbing between the charging member and the surface of the image bearing member (charged member). 3) Contamination of the surface of the image bearing member (charged member). 4) When a voltage in which an AC voltage is superimposed on a DC voltage is applied, the vibration of the charging member is transmitted to the surface of the image bearing member (the member to be charged), and noise (charging sound) having a frequency twice the applied frequency.
Occurs. It is possible to solve all such problems.

【0048】しかもその構成は金属基材に磁性体を分
散、または焼結した単層の抵抗層が存在するというシン
プルな構成であるため、非常に低コストである帯電部材
を提供する事が可能となる。
Moreover, since the structure is a simple structure in which the magnetic material is dispersed or sintered on the metal base material, a single resistance layer is present, so that it is possible to provide a charging member at an extremely low cost. Becomes

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明における帯電部材を用いた画像形成装置
の一例の概略的縦断面図。
FIG. 1 is a schematic vertical sectional view of an example of an image forming apparatus using a charging member according to the present invention.

【図2】図1の画像形成装置の横縦断面図。FIG. 2 is a horizontal and vertical sectional view of the image forming apparatus of FIG.

【図3】本発明における他の帯電部材を用いた画像形成
装置の一例の概略的縦断面図。
FIG. 3 is a schematic vertical sectional view of an example of an image forming apparatus using another charging member according to the present invention.

【図4】図3の画像形成装置の横縦断面図。4 is a horizontal and vertical sectional view of the image forming apparatus of FIG.

【図5】本発明による帯電部材を取り付けた画像形成装
置の概略的縦断面図。
FIG. 5 is a schematic vertical sectional view of an image forming apparatus to which a charging member according to the present invention is attached.

【符号の説明】[Explanation of symbols]

1 帯電部材 2 導電性基体 3 抵抗層 4 スペーサ 5 像担持体 6 空隙 12 電源 13 現像器 14 クリーニング手段 16 転写ローラ 17 被転写材 DESCRIPTION OF SYMBOLS 1 Charging member 2 Conductive substrate 3 Resistive layer 4 Spacer 5 Image carrier 6 Void 12 Power source 13 Developing device 14 Cleaning means 16 Transfer roller 17 Transfer material

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 少なくとも導電性基体と、前記導電性基
体に接して、磁性体を含有した単層の抵抗層とを備えて
いることを特徴とする帯電部材。
1. A charging member comprising at least a conductive substrate, and a single-layer resistance layer containing a magnetic material, which is in contact with the conductive substrate.
【請求項2】 前記磁性体の粉体抵抗が1×103Ωc
m以上である請求項1に記載の帯電部材。
2. The powder resistance of the magnetic material is 1 × 10 3 Ωc.
The charging member according to claim 1, which is at least m.
【請求項3】 前記抵抗層が被帯電体表面に対して空隙
を介して対向する位置に配置された請求項1または2に
記載の帯電部材。
3. The charging member according to claim 1, wherein the resistance layer is arranged at a position facing the surface of the member to be charged with a gap therebetween.
【請求項4】 ローラ状または平板状である請求項1〜
3のいずれか1項に記載の帯電部材。
4. A roller-shaped or flat-shaped roller.
The charging member according to any one of 3 above.
JP32540894A 1994-12-27 1994-12-27 Electrifying member Pending JPH08179591A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP32540894A JPH08179591A (en) 1994-12-27 1994-12-27 Electrifying member

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP32540894A JPH08179591A (en) 1994-12-27 1994-12-27 Electrifying member

Publications (1)

Publication Number Publication Date
JPH08179591A true JPH08179591A (en) 1996-07-12

Family

ID=18176515

Family Applications (1)

Application Number Title Priority Date Filing Date
JP32540894A Pending JPH08179591A (en) 1994-12-27 1994-12-27 Electrifying member

Country Status (1)

Country Link
JP (1) JPH08179591A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002037190A1 (en) * 2000-11-02 2002-05-10 Ricoh Company, Limited Imaging apparatus
WO2012042765A1 (en) 2010-09-27 2012-04-05 キヤノン株式会社 Electrification member, process cartridge, and electronic photographic device

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002037190A1 (en) * 2000-11-02 2002-05-10 Ricoh Company, Limited Imaging apparatus
WO2012042765A1 (en) 2010-09-27 2012-04-05 キヤノン株式会社 Electrification member, process cartridge, and electronic photographic device
US8755714B2 (en) 2010-09-27 2014-06-17 Canon Kabushiki Kaisha Charging member, process cartridge and electrophotographic apparatus

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