JPH0816505B2 - High load transmission belt - Google Patents

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to improvement of a high load transmission belt, and more particularly to measures for extending the life of the transmission belt.

[0002]

2. Description of the Related Art Conventionally, as a high load transmission belt used in a transmission of an automobile or the like, for example, a pair of rubber tension bands and fittings for fitting the tension bands on both side surfaces in the belt width direction. A groove and a large number of blocks having abutting portions that come into contact with the belt groove surface of the pulley, and a concave portion and a convex portion formed on the upper and lower surfaces of the tension bands and on the upper and lower surfaces of the fitting groove of each block, respectively. There is known a high-load transmission belt called a block belt, in which each block is locked and fixed to both tension bands side by side in the belt longitudinal direction by engaging with each other (for example, JP-A-60-49151). , JP-A-61-206847 and JP-A-62-62.
No. 54348).

By the way, in this type of block belt, the lateral pressure of the pulley is received by each block and the power transmission is performed by the tension band. The block is made of a hard material, and is capable of high-load transmission without buckling deformation like a general rubber belt. On the other hand, the shape-retaining rubber layer constituting the tension band uses chloroprene rubber (CR) or hydrogenated acrylonitrile butadiene rubber (H-NBR) as a matrix.

[0004]

However, when the block belt is repeatedly used under high tension, excessive shearing / compressing force is applied to the shape-retaining rubber layer of the tension band when the block belt is wound around the pulley, so There is a problem in that the shaped rubber layer is permanently deformed to cause a problem between the tension band and the block, noise is increased, or a crack is generated, which leads to early cutting. This is even more the case when the block belt is used at a high speed because the block belt self-heats and the temperature of the shape-retaining rubber layer rises.

Further, when the block belt is used in a transmission of an automobile, heat from the engine causes the block belt to reach a high temperature, so that heat resistance is required. But,
Since chloroprene rubber lacks heat resistance, it is not suitable for use under high temperature conditions. On the other hand, H-NBR is excellent in heat resistance, but since permanent strain occurs under a high load, a problem occurs between the tension band and the block.

On the other hand, carbon black and short fibers are mixed in the shape-retaining rubber layer for the purpose of improving the permanent set of the shape-retaining rubber layer. However, increasing the mixing amount of these to increase the elastic modulus and reduce the amount of shearing / compressing deformation sacrifices the bending fatigue resistance of the rubber, causing cracks in the shape-retaining rubber layer at an early stage and shortening the belt life. It gets shorter.

The present invention has been made in view of the above points, and an object thereof is to improve heat resistance and bending fatigue resistance by improving the material of the shape-retaining rubber layer constituting the tension band. Moreover, it is to obtain a high load transmission belt with a small permanent strain.

[0008]

In order to achieve the above object, a first solution of the present invention comprises a shape-retaining rubber layer in which short fibers are mixed, and a core wire is provided inside the shape-retaining rubber layer. In a high load transmission belt composed of a pair of tension bands embedded in each of the tension bands and a large number of blocks attached to the tension bands side by side in the belt longitudinal direction, the shape-retaining rubber layer of each of the tension bands is replaced with an unsaturated carbon. That is, a hydrogenated rubber composed of an ethylenically unsaturated nitrile-conjugated diene copolymer to which an acid metal salt and an organic peroxide are added is constituted as a matrix.

A second solution is that, in the first solution, the rubber hardness of the shape-retaining rubber layer (A type in the JISK 6301 spring hardness test) is 90 ° or more.

A third solution is that the unsaturated carboxylic acid metal salt added to the hydrogenated rubber in the first solution is zinc methacrylate.

A fourth solution is that in the third solution, the amount of zinc methacrylate added is set to 15% or more with respect to the total amount of hydrogenated rubber and zinc methacrylate.

[0012]

With the above-mentioned constitution, in the first to fourth means for solving the problems of the present invention, the polymerization of zinc methacrylate in the shape-retaining rubber layer of the tension band proceeds during the cross-linking of the hydrogenated rubber, and the polymerized zinc methacrylate is used. The reinforcing effect increases the rubber strength, and excellent physical properties such as high hardness, high elastic modulus and low compression set can be obtained without mixing carbon black. Also,
The amount of short fibers mixed in can be reduced and flex fatigue resistance is not impaired. Furthermore, heat resistance is improved by organic peroxide vulcanization.

[0013]

Embodiments of the present invention will be described below with reference to the drawings.

1 and 2 show a block belt A as a high load transmission belt according to an embodiment of the present invention. 1 and 2, reference numerals 1 and 1 denote a pair of left and right tension bands, and each tension band 1 includes a shape-retaining rubber layer 3 in which short fibers 2 are mixed. A plurality of core wires 4, 4, ... Are embedded in parallel inside so as to extend in the belt longitudinal direction.

Further, on the upper surface of the shape-retaining rubber layer 3, a plurality of first concave grooves 5, 5, ... As engaging portions are formed side by side at predetermined intervals in the belt longitudinal direction, and the lower surface thereof. Further, a large number of second concave grooves 6, 6, ... As engaging portions are formed side by side at predetermined intervals in the belt longitudinal direction. Further, the shape-retaining rubber layer 3 is covered with a canvas 7.

A large number of metal- or resin-made blocks 8, 8 formed in an "H" shape are arranged in the tension bands 1, 1 side by side in the belt longitudinal direction. Specifically, the fitting grooves 9 and 9 are formed on both side surfaces of each block 8 in the belt width direction.
Is formed in a notch shape in a U shape, and the tension bands 1 are fitted into the fitting grooves 9 and 9. Also,
Abutting portions 10, 10 that abut the belt groove surfaces b1, b1 of the pulley B are formed on both side surfaces of each block 8 in the belt width direction so as to sandwich the fitting grooves 9 therebetween.

The tension band 1 is formed on the upper surface of each fitting groove 9.
, Which are engaged with the respective first concave grooves 5, are formed side by side at predetermined intervals in the longitudinal direction of the belt, and tension bands are also formed on the lower surface. No. 1 second convex portion 1 as a large number of locking portions that engage with each second concave groove 6 of FIG.
Are formed side by side at a predetermined interval in the longitudinal direction of the belt. Then, the tension bands 1, 1 are fitted into the fitting grooves 9, 9 of each of the blocks 8 so that the first
By engaging the convex portion 11 with the first concave groove 5 of each tension band 1 and the second convex portion 12 of each block 8 with the second concave groove 6 of each tension band 1, each block 8 Are aligned and fixed to the tension bands 1 and 1 side by side in the belt longitudinal direction. Then, in this locked and fixed state, each tension band 1 projects from the abutting portion 10 of each block 8 by a predetermined dimension.

Further, as one of the features of the present invention, the shape-retaining rubber layer 3 of the tension band 1 has a rubber hardness (JIS K 63).
01 type A of spring type hardness test) is set to 90 ° or more. The reason for setting such a range is to obtain excellent bending fatigue resistance and wear resistance.

Further, as another feature of the present invention, the shape-retaining rubber layer 3 of the tension band 1 is an ethylenically unsaturated nitrile-conjugated diene system containing an unsaturated carboxylic acid metal salt and an organic peroxide. A hydrogenated rubber made of a copolymer is used as a matrix.

The hydrogenated rubber comprising an ethylenically unsaturated nitrile-conjugated diene copolymer is an ethylenically unsaturated nitrile such as acrylonitrile or methacrylonitrile,
A rubber obtained by adding hydrogen to a copolymer of a conjugated diene such as 1,3-butadiene, isoprene and 1,3-pentadiene to saturate the double bond present in the conjugated diene monomer unit. That is. For example, hydrogenated acrylonitrile butadiene rubber (H-NBR) obtained by hydrogenating a copolymer of acrylonitrile and 1,3-butadiene can be mentioned. Taking this as an example, the proportion of acrylonitrile rubber monomer units in H-NBR is 10 to 60% by weight,
The ratio of the conjugated diene monomer unit is set to 30% by weight or less by means of partial hydrogenation or the like. Also, the molecular weight of H-NBR,
Although the glass transition temperature and the hydrogenation rate are not particularly limited, the hydrogenation rate of the double bond of the conjugated diene monomer unit is usually 10 to 99%, preferably 80 to 95%.

The unsaturated carboxylic acid metal salt is an ionic bond between an unsaturated carboxylic acid having a carboxyl group and a metal, and is preferably zinc acrylate or zinc methacrylate. The content of this unsaturated carboxylic acid metal salt is
Hydrogenated rubber; preferably set to 10 to 100 parts by weight with respect to 100 parts by weight. For example, in the case of zinc methacrylate, the addition amount is 15% with respect to the total amount of hydrogenated rubber and zinc methacrylate. Make the settings as described above. The reason for setting such a range is that if it is less than 15%, the expected rubber strength cannot be obtained.

The organic peroxide is used as a cross-linking agent for hydrogenated rubber, for example, benzoyl peroxide, lauroyl peroxide, ditertiary butyl peroxide, acetyl peroxide, tert-butyl peroxybenzoic acid, dicumyl peroxide. , Peroxybenzoic acid, tertiary butyl peroxypivalate and azobisisobutyronitrile are preferred. These organic peroxides may be used alone or in combination. The content of this organic peroxide is preferably set to 0.2 to 10 parts by weight with respect to 100 parts by weight of hydrogenated rubber. The reason for setting such a range is that if the amount is less than 0.2 parts by weight, the crosslinking cannot be sufficiently performed, while if it exceeds 10 parts by weight, sufficient rubber elasticity cannot be obtained.

The short fibers 2 mixed in the shape-retaining rubber layer 3 are, for example, polyester short fibers, nylon short fibers, and aramid short fibers, and in particular for improving lateral pressure resistance and reducing the friction coefficient. To be added.

A sulfur component may be added if necessary. This sulfur component serves as a co-crosslinking agent during organic peroxide vulcanization, and is used in the form of sulfur, a sulfur compound, a mixture of sulfur and a sulfur compound, or the like. Carbon black with the above components, reinforcing agents such as silica, calcium carbonate, fillers such as talc, crosslinking aids, vulcanization accelerators,
Plasticizers, stabilizers, processing aids, anti-aging agents and colorants, etc.
Various agents ordinarily used in the rubber industry are appropriately blended according to the purpose of use.

Therefore, the shape-retaining rubber layer 3 of the tension band 1 constructed as described above can increase the rubber strength by the reinforcing effect of the zinc methacrylate whose polymerization has progressed during the crosslinking of the hydrogenated rubber, and carbon black can be mixed. Without doing so, excellent physical properties such as high hardness, high elastic modulus and low compression set can be obtained. Further, since the physical properties are excellent as described above, it is not necessary to mix a large amount of the short fibers 2 as the reinforcing material, and the bending fatigue resistance is not impaired. Further, heat resistance can be improved by organic peroxide vulcanization. Due to the excellent heat resistance and shape retention of the shape-retaining rubber layer 3, it is possible to obtain the block belt A that can be used for a long period of time even under severe conditions.

The block belt A shown in FIGS. 3 and 4 is another embodiment, and in this embodiment, one tension belt 1 is used.
Are sandwiched by a plurality of blocks 8, 8, ... From above and below, and spacers 13 and 13 are respectively set on the upper and lower blocks 8 and 8, respectively, and these are skewered vertically with bolts 14 to form bolts 14 and nuts 15. The block belt A is configured by being tightened by. Since the structure of the tension band 1 and the material of the shape-retaining rubber layer 3 are the same as those in the above-mentioned embodiment, the description thereof will be omitted.

Therefore, in this embodiment, it is possible to obtain the same effects as those of the above embodiment.

Next, examples of the present invention will be specifically described.

The H-NBR compositions shown in Table 1 were kneaded in a Banbury mixer and then rolled by a calender roll to give an unvulcanized rubber sheet.
It was vulcanized at 0 ° C. for 30 minutes to obtain a vulcanized rubber sheet. The properties of this vulcanized rubber sheet are shown in Table 1. Further, a block belt as shown in FIG. 1 was prepared by using the above-mentioned unvulcanized rubber sheet for the shape-retaining rubber layer of the tension band, and the belt running life, the initial noise level, the tension band and the block after running for 50 hours. And the rise in sound pressure level after running for 50 hours were examined. Table 1 shows the results.

The procedure for measuring the belt running life is shown in FIG.
As shown in, the block belt A is wound around a pulley 16 having a diameter of 130 mm and a pulley 17 having a diameter of 70 mm,
The time until reaching the end of life was examined by running at a speed of 40 m / sec at an ambient temperature of 85 ° C.

[0031]

[Table 1]

As a result, in the comparative example, the shape-retaining rubber layer was cracked and cut in a short time. This is because the matrix of the shape-retaining rubber layer was chloroprene rubber except for Comparative Example 1, and thus the heat resistance was insufficient and the flex fatigue resistance was also insufficient. Furthermore, in the comparative example, the backlash between the tension band and the block was great after running for 50 hours, and
The increase in sound pressure level after running for 0 hours was also large.
Further, in Comparative Example 1, since the short fibers were not mixed, the coefficient of friction with the pulley was large, and the initial noise level was large.

On the other hand, in this embodiment, the belt running life is longer than that in the comparative example, and the reason for the life is not due to the occurrence of cracks in the rubber, but due to the cutting of the core wire. Therefore, it is possible to expect a longer life by improving the fatigue property of the core wire. Further, the initial noise level was lower than that of the comparative example, and the rattling of the tension band and the block after 50 hours of running and the increase of the sound pressure level after running of 50 hours were also smaller than those of the comparative example.

[0034]

As described above, according to the present invention as set forth in claims 1 to 4, the shape-retaining rubber layer in the tension band is made of an ethylenic non-ionic compound containing an unsaturated carboxylic acid metal salt and an organic peroxide. A hydrogenated rubber composed of a saturated nitrile-conjugated diene-based copolymer is used as a matrix. At this time, the rubber hardness of the shape-retaining rubber layer (A type in the spring hardness test of JIS K 6301) was set to 90 ° or more, and the unsaturated carboxylic acid metal salt was changed to zinc methacrylate, and the addition amount was hydrogen. 15 based on the total amount of synthetic rubber and zinc methacrylate
%, The rubber strength can be increased and excellent physical properties such as high hardness, high elastic modulus and low compression set can be obtained, and bending fatigue resistance can be secured by a small amount of short fibers mixed. In addition, heat resistance can be improved by organic peroxide vulcanization.

[Brief description of drawings]

FIG. 1 is an enlarged perspective view showing a part of a block belt according to an embodiment.

FIG. 2 is a vertical sectional view of a block belt according to an embodiment.

FIG. 3 is a vertical cross-sectional view of a block belt according to another embodiment.

FIG. 4 is a side view of a block belt according to another embodiment.

FIG. 5 is a diagram illustrating a procedure for measuring belt running life.

[Explanation of symbols]

 1 tension band 2 short fibers 3 shape retaining rubber layer 4 cores 8 blocks A block belt (high load transmission belt)

Claims (4)

[Claims] 1. A shape-retaining rubber layer mixed with short fibers,
A high-load transmission belt comprising a pair of tension bands having core wires embedded in the shape-retaining rubber layer and a large number of blocks attached to the tension bands in the longitudinal direction of the belt. The shape-retaining rubber layer of each tension band is composed of a matrix of hydrogenated rubber composed of an ethylenically unsaturated nitrile-conjugated diene copolymer to which an unsaturated carboxylic acid metal salt and an organic peroxide are added. High-load transmission belt characterized by. 2. The rubber hardness of the shape-retaining rubber layer (JIS K 6
The high load transmission belt according to claim 1, wherein the A type in the spring type hardness test of 301 is 90 ° or more. 3. The high load transmission belt according to claim 1, wherein the unsaturated carboxylic acid metal salt added to the hydrogenated rubber is zinc methacrylate. 4. The high load transmission belt according to claim 3, wherein the added amount of zinc methacrylate is 15% or more with respect to the total amount of hydrogenated rubber and zinc methacrylate.