JPH08140570A - Preparation of frozen vegetable - Google Patents

Preparation of frozen vegetable

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Publication number
JPH08140570A
JPH08140570A JP33079194A JP33079194A JPH08140570A JP H08140570 A JPH08140570 A JP H08140570A JP 33079194 A JP33079194 A JP 33079194A JP 33079194 A JP33079194 A JP 33079194A JP H08140570 A JPH08140570 A JP H08140570A
Authority
JP
Japan
Prior art keywords
frozen
vegetable
vegetables
calcium
heating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP33079194A
Other languages
Japanese (ja)
Other versions
JP2839455B2 (en
Inventor
Masabumi Suzuki
正文 鈴木
Tetsuji Tomita
哲司 富田
Tomoko Suzuki
智子 鈴木
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Showa Sangyo Co Ltd
Original Assignee
Showa Sangyo Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Showa Sangyo Co Ltd filed Critical Showa Sangyo Co Ltd
Priority to JP33079194A priority Critical patent/JP2839455B2/en
Publication of JPH08140570A publication Critical patent/JPH08140570A/en
Application granted granted Critical
Publication of JP2839455B2 publication Critical patent/JP2839455B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

PURPOSE: To prepare frozen vegetable giving a cooked food free from softening and boiling collapse after thawing and cooking and having excellent palatability. CONSTITUTION: A whole or roughly cut vegetable is subjected to the tissue strengthening treatment and frozen to prepare a frozen vegetable. This tissue strengthening treatment comprises a process containing the lst step to treat the vegetable at a high temperature and the 2nd step to heat the vegetable in a calcium-containing aqueous solution as essential steps or a process containing the above two steps and the 3rd step to treat the vegetable again at a high temperature. The vegetable is preferably potato. The calcium- containing aqueous solution is preferably an aqueous solution of calcium lactate. A whole or roughly cut vegetable can be frozen by this process without causing the browning of the vegetable, keeping good palatability and preventing the boiling collapse and softening in the thawing and cooking procedures. This process can provide a frozen vegetable for secondary processing, e.g. plain dishes such as boiled meat and potato, a frozen vegetable to be heated for a long period such as the ingredients for Japanese hotchpotch and a frozen vegetable for retort-cooking resistant to the boiling collapse and softening even under severe heating condition such as heating in a retort.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、解凍、調理した後、軟
化や煮崩れがなく、食感の優れた調理食品となる丸のま
まあるいは大きくカットした大きさの野菜類の冷凍品の
製造方法に関する。本発明の冷凍野菜は、肉ジャガなど
の惣菜用に用いる二次加工用、おでん種などの長時間加
熱用、レトルト加熱加工用に使用される。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to the production of frozen whole vegetables or large-sized cut vegetables, which are cooked foods having an excellent texture without softening or boiling after thawing and cooking. Regarding the method. The frozen vegetables of the present invention are used for secondary processing used for side dishes such as meat potatoes, for long-term heating for oden seeds, and for retort heating processing.

【0002】[0002]

【従来の技術】冷凍した野菜素材の多く、特にジャガイ
モ、ニンジンなどは、調理の際に組織が軟化してしまい
冷凍前の食感を保持することができない。また、そのた
めに解凍調理加熱時に茹で溶けや煮崩れを生じその商品
価値を著しく落とすことになる。たとえば冷凍処理しな
いジャガイモであればホクホクとした食感であったもの
が、冷凍解凍後はボソボソとした食感となり容易に煮崩
れてしまう。また、料理店やコンビニエンスストアでの
店頭で提供されるおでんなどに入れられる野菜類は、長
時間煮込むのが普通のことであり、冷凍品はもとより、
下ごしらえに手間のかかる生鮮物から調理したものでも
煮崩れ易いために十分な品質のものを提供できない。そ
のために、ある種の冷凍野菜は製造されていなかった
り、製造されていても、大きさや用途が限定されていた
り、品質面で問題のあるものが多かった。
2. Description of the Related Art Many frozen vegetable materials, particularly potatoes, carrots, etc., cannot soften their texture before being frozen because the tissues are softened during cooking. In addition, for this reason, when thawing, cooking, and heating, boiling and melting or collapse occur, resulting in a marked drop in commercial value. For example, potatoes that have not been subjected to a freezing treatment have a soft texture, but after being frozen and thawed, they have a rough texture and are easily crumbled. In addition, vegetables that can be put in oden etc. offered at restaurants and convenience stores are usually boiled for a long time, not to mention frozen products.
Even if cooked from a perishable product that takes time to prepare, it cannot be provided in sufficient quality because it is easily boiled down. Therefore, some kinds of frozen vegetables have not been manufactured, or even if they are manufactured, their size and use are limited, and there are many problems in terms of quality.

【0003】冷凍解凍後の食感の低下を防止する方法と
しては、一般に使用されている急速に凍結する方法、有
機酸塩水溶液を用いて表面処理し冷凍処理する方法(特
開平3−32337号)などがある。しかし、このよう
な方法を用いた場合、1cm角程度に小さくカットした
ものでは効果がみられるが、丸のままのジャガイモや大
きくカットした人参などの「大切り野菜」は、急速凍結
や表面処理の効果が表面組織にとどまり、内部は緩慢凍
結となり内部組織が変性してしまい解凍時の食感が低下
してしまう。また、組織が軟化してしまい解凍時の加熱
によって煮崩れ、茹で溶けが生じ商品価値が著しく低下
してしまう。
As a method for preventing the deterioration of the texture after freezing and thawing, a commonly used method is rapid freezing, or a method of surface-treating using an aqueous solution of an organic acid salt and freezing (Japanese Patent Laid-Open No. 3-32337). )and so on. However, when such a method is used, the effect can be seen with a small cut of about 1 cm square, but "round-cut vegetables" such as potatoes that are still round and carrots that are greatly cut are quickly frozen or surface-treated. The effect of is limited to the surface tissue, the inside is slowly frozen, the internal tissue is denatured, and the texture upon thawing is reduced. In addition, the tissue is softened, and it is boiled down by the heat at the time of thawing, and it is boiled and melted, so that the commercial value is remarkably reduced.

【0004】上記問題は、凍結解凍時の物理的変化に対
応できるように野菜組織を強化することで解決できると
考えられる。野菜組織を強くする方法に関しては、植物
体の骨格形成成分としてのペクチン物質とカルシウム塩
との結合により細胞壁を強固にすること(Food R
esearch 6,449,1941)、カルシウム
の添加が冷凍による軟化に対しても効果が期待されるこ
と(日本食品工業学会誌25,213,1978)が報
告されている。また、その作用が植物体の持つペクチン
エステラーゼを活性化しペクチン質の脱メチル化を促
し、遊離したカルボキシル基が共存する組織内のカルシ
ウムを含む2価カチオンと結合して硬化するためによる
ことも(Food Technology,15,16
0,1961)報告されている。また、外部からカルシ
ウムを添加することをせずとも、60℃から70℃の温
度で最大で2時間加熱することで、組織が硬化すること
も(J.AGR.FOOD CHEM.,20,2,2
66,1972)報告されている。
It is considered that the above problems can be solved by strengthening the vegetable tissue so as to cope with the physical changes during freeze-thawing. Regarding the method of strengthening the vegetable tissue, for strengthening the cell wall by binding the pectin substance as a skeleton-forming component of the plant and calcium salt (Food R
esarch 6,449,1941) and that addition of calcium is expected to have an effect on softening by freezing (Journal of the Food Industry Society of Japan 25,213,1978). Also, the action is to activate the pectinesterase possessed by the plant to promote demethylation of the pectic substance, and to bind with the divalent cation containing calcium in the tissue in which the free carboxyl group coexists and harden ( Food Technology, 15, 16
0,1961) has been reported. Further, without adding calcium from the outside, the tissue may be hardened by heating at a temperature of 60 ° C. to 70 ° C. for a maximum of 2 hours (J. AGR. FOOD CHEM., 20, 2, 2. Two
66, 1972).

【0005】これらの組織を強化する技術を利用した特
許出願としては水、希酸性水、糖液のいずれかで少なく
とも表面品温を45〜75℃、10〜180分予備加熱
することを特徴とする野菜、果実の軟化防止方法(特開
昭54−107542号)、野菜類をカルシウム水溶液
中に低温下で浸漬した後、その状態のまま該水溶液の温
度を40〜70℃の範囲に上昇させ一定時間保持するこ
とを特徴とする野菜類の軟化防止法(特開昭60−23
7957号)、野菜を煮るに先立ち、該野菜類をカルシ
ウム塩水溶液に投入して減圧処理することを特徴とする
野菜の煮崩れ防止方法(特開平3−285651号)が
ある。
A patent application utilizing the technology for strengthening these structures is characterized in that at least the surface temperature of the surface is preheated at 45 to 75 ° C. for 10 to 180 minutes with any of water, dilute acidic water and sugar solution. Method for preventing softening of vegetables and fruits (JP-A-54-107542), immersing vegetables in an aqueous calcium solution at a low temperature, and then raising the temperature of the aqueous solution in the range of 40 to 70 ° C. A method for preventing softening of vegetables, which is characterized by holding for a certain period of time (JP-A-60-23).
No. 7957), there is a vegetable collapse prevention method (Japanese Patent Laid-Open No. 3-285651) characterized in that the vegetables are added to a calcium salt aqueous solution and decompressed prior to boiling the vegetables.

【0006】しかし、これらの特許出願は冷凍野菜に関
する技術に関するものではない。これらの技術を冷凍野
菜の製造に応用したとしても、カット後の野菜は組織中
の酵素等により褐変が生じやすく、何等処理を施さずに
長時間野菜の組織強化処理を行うと、処理中に野菜表面
に褐変を生じ、特に芽や皮がわずかでものこっていたり
すると、その部分に特に強い褐変が生じてしまう。ま
た、組織の中心部まで強化処理を行うと解凍時に内部の
硬さに比べ表面部分が過度に硬くなってしまうなどの問
題が生じてしまう。特に丸のままの野菜や大きくカット
した野菜の場合にはこれらの問題が顕著に現れ、前述の
技術だけでは解凍後にも褐変を生じず、良い食感を保持
し、解凍時の調理において煮崩れが起きず軟化しない冷
凍野菜を製造することは不可能である。
However, these patent applications do not relate to the technology relating to frozen vegetables. Even if these techniques are applied to the production of frozen vegetables, the vegetables after cutting are liable to be browned by enzymes in the tissue, and if tissue strengthening treatment of vegetables is performed for a long time without any treatment, Browning occurs on the surface of the vegetables, and especially if buds and skins are slightly overgrown, particularly strong browning occurs on those areas. Further, if the strengthening treatment is performed up to the central portion of the tissue, a problem that the surface portion becomes excessively hard when compared with the internal hardness at the time of thawing occurs. Especially in the case of whole vegetables and vegetables that have been cut into large pieces, these problems become prominent, and the above-mentioned technology alone does not cause browning even after thawing, retains a good texture, and does not collapse during cooking during thawing. It is impossible to produce frozen vegetables that do not soften and do not soften.

【0007】[0007]

【発明が解決しようとする課題】本発明は、解凍、調理
した後、軟化や煮崩れがなく、食感の優れた調理食品と
なる丸のままあるいは大きくカットした大きさの野菜類
の冷凍品を製造することを目的とする。本発明は、肉ジ
ャガなどの惣菜用に用いる二次加工用冷凍野菜、おでん
種などの長時間加熱用の冷凍野菜、レトルト加熱などの
過酷な加熱条件でも煮崩れや軟化のないレトルト加熱加
工用冷凍野菜の製造を目的とする。
DISCLOSURE OF THE INVENTION The present invention is a frozen product of vegetables in the size of whole or cut into a cooked food having an excellent texture without softening or boiling down after thawing and cooking. Is intended to be manufactured. The present invention is a frozen vegetable for secondary processing used for side dishes such as meat potatoes, frozen vegetables for long-term heating such as oden seeds, and retort heating processing that does not collapse or soften even under severe heating conditions such as retort heating. Intended for the production of frozen vegetables.

【0008】[0008]

【課題を解決するための手段】本発明は、丸のままある
いは大きくカットした大きさの野菜類を、その組織の強
化処理を施こした後、冷凍処理することを特徴とする冷
凍野菜の製造方法である。
The present invention is a method for producing a frozen vegetable characterized by subjecting a vegetable having a size as a whole or a large cut to a tissue strengthening treatment and then a freezing treatment. Is the way.

【0009】上記組織の強化処理は、野菜類を高温で処
理する第一工程およびカルシウムを含む水溶液中で加熱
処理する第二工程を必須とし、必要により再度高温で処
理する第三工程を付加する工程で行われる。すなわち、
本発明は丸のままあるいは大きくカットした大きさの野
菜類を冷凍処理するに際し、野菜類を高温で処理する第
一工程およびカルシウムを含む水溶液中で加熱処理する
第二工程、必要により再度高温で処理する第三工程より
なる組織の強化処理を施すことを特徴とする冷凍野菜の
製造方法である。
The tissue strengthening treatment requires a first step of treating vegetables at a high temperature and a second step of heat treatment in an aqueous solution containing calcium, and adds a third step of treating again at a high temperature if necessary. Done in process. That is,
The present invention, when freezing a whole or large cut size vegetables, the first step of treating the vegetables at a high temperature and the second step of heat treatment in an aqueous solution containing calcium, if necessary at a high temperature again. A method for producing frozen vegetables, characterized by performing a tissue strengthening treatment comprising a third step of treatment.

【0010】本発明の対象とする野菜類は、惣菜、おで
ん種などの加熱加工食品およびレトルト加熱加工食品に
用いる野菜であれば何でもよい。ジャガイモ、人参、ご
ぼう、大根、サツマイモ、カボチャ、カリフラワー、ブ
ロッコリーが例示される。本発明において野菜類は丸の
ままあるいは大きくカットした大きさであることが好ま
しい。本発明は、丸のままや大きくカットして使用され
る野菜であって、解凍したときに生ずる食感の低下、軟
化、煮崩れなどの問題があるため、冷凍野菜の対象とな
り難かったジャガイモに特に適した方法である。
The vegetables to which the present invention is applicable may be any vegetables used for heat-processed foods such as prepared foods and oden seeds and retort heat-processed foods. Examples include potato, carrot, burdock, radish, sweet potato, pumpkin, cauliflower and broccoli. In the present invention, it is preferable that the vegetables have a size as a whole or in a large size. The present invention is a vegetable that is used as a whole or cut into large pieces, and has problems such as deterioration in texture that occurs when it is thawed, softening, and simmering. This is a particularly suitable method.

【0011】上記の野菜の種類、大きさ、以下に説明す
る野菜の組織の強化処理条件の組合せ等により多種、多
様な調理食品用の冷凍野菜を得ることが可能であり、そ
のため冷凍野菜の利用法も多岐にわたる。本発明の組織
の強化処理とは、野菜の組織を強化することができる条
件下で行われる処理である。すなわち、丸のままあるい
は大きくカットした大きさの野菜類から、解凍、調理し
た後、軟化や煮崩れがなく、食感の優れた調理食品とな
る冷凍品をつくることができる条件下で行われる処理で
ある。
It is possible to obtain a wide variety of frozen vegetables for cooked foods by combining the types and sizes of the above-mentioned vegetables and the conditions for strengthening treatment of vegetable tissues described below. There are various laws. The tissue strengthening treatment of the present invention is a treatment performed under conditions capable of strengthening the vegetable tissue. That is, it is performed under the condition that a frozen product that is a whole or a large cut size does not soften or boil down after being thawed and cooked and has a texture that is excellent in texture after being thawed and cooked. Processing.

【0012】さらに説明すると、最終の調理食品の種類
が肉ジャガなどの惣菜用に用いる二次加工用なのか、お
でん種などの長時間加熱用なのか、あるいはレトルト加
熱加工用なのかに応じて、野菜の種類、大きさ、加熱温
度、時間などの条件、第三工程を冷凍前に行うか等をど
う組み合わせるかで、野菜の組織の強化処理条件、すな
わち各工程の処理条件を調整し、解凍、調理した後の軟
化や煮崩れがなく、食感の優れた調理食品となる冷凍野
菜をつくることができる。
[0012] To further explain, depending on whether the final cooked food type is for secondary processing used for side dishes such as meat potatoes, for long-time heating for oden seeds, or for retort heating processing. , The type of vegetable, size, heating temperature, conditions such as time, how to combine the third step before freezing, etc., to adjust the vegetable tissue strengthening processing conditions, that is, the processing conditions of each step, Frozen vegetables, which are cooked foods with an excellent texture, can be produced without softening or boiling down after thawing and cooking.

【0013】上記第一工程は、野菜類を湯中または蒸気
によって表面温度が90〜100℃になるように2〜5
分間処理する工程である。この処理によって野菜表面の
褐変を起こす酵素を失活させて野菜類の褐変を防止す
る。また、表面組織をある程度軟化させてカルシウムの
浸透性を高めることができるので、第二工程により野菜
の表面のみが硬くなるのを防止することができる。さら
にまた、高温にさらすことによって野菜中心部の温度上
昇を早めて続いて行う加熱処理時間を短縮することがで
きる。この第一工程の処理を行わないで第二工程以降の
処理を行っても目的とする品質の冷凍野菜は製造するこ
とができない。
In the first step, the vegetables are heated in hot water or steam so that the surface temperature is 90 to 100 ° C.
It is a step of processing for a minute. This treatment deactivates the enzyme that causes browning of the vegetable surface and prevents the browning of vegetables. Further, since the surface texture can be softened to some extent to enhance the permeability of calcium, it is possible to prevent only the surface of the vegetables from becoming hard by the second step. Furthermore, by exposing to high temperature, the temperature rise of the central portion of the vegetables can be accelerated and the subsequent heat treatment time can be shortened. Frozen vegetables of the desired quality cannot be produced even if the treatments of the second and subsequent steps are performed without performing the treatment of the first step.

【0014】表面温度の測定方法には、微小な熱電対を
表面部分に埋め込み測定する方法、表面温度計を表面に
貼付する方法、加熱装置より野菜を取り出し直ちに赤外
線を用いた放射温度計、サーモグラフ等で測定する方
法、温度により色の変化する色素を野菜に塗布し、色の
変化で測定する方法、野菜内部の温度を測定することで
表面温度を推定する方法等がある。また、表面温度は加
熱開始後、すばやく雰囲気温度まで上昇するので、雰囲
気温度で第一工程をコントロールすることも可能であ
る。
The surface temperature can be measured by embedding a minute thermocouple in the surface, measuring the surface temperature, attaching a surface thermometer to the surface, removing the vegetables from the heating device, and immediately using infrared radiation thermometer and thermometer. There are a method of measuring with a graph and the like, a method of applying a pigment whose color changes with temperature to vegetables and measuring with a color change, and a method of estimating the surface temperature by measuring the temperature inside the vegetables. In addition, since the surface temperature rises rapidly to the ambient temperature after the heating is started, it is possible to control the first step by the ambient temperature.

【0015】第一工程は通常のブランチング操作と類似
するが、ブランチングが加熱後直ちに冷却することを特
徴とするのに対し、第一工程が加熱状態を維持する必要
がある点で相違している。また、本処理は次の第二工程
の処理の予備加熱に相当し、通常のブランチング処理よ
りも熱の加え方が少ないという点で大きく異なってい
る。通常のブランチング処理のみで製造された「大切
り」冷凍野菜は、良い食感が伴わないとともに解凍とそ
の後の調理加熱の両方に時間がかかり、生の野菜を使用
した時と比べ加工時間に長時間を要してしまう。
The first step is similar to a normal blanching operation, except that the blanching is cooled immediately after heating, while the first step is required to maintain a heated state. ing. Further, this treatment corresponds to preheating in the treatment of the next second step, and is greatly different from the normal blanching treatment in that less heat is applied. Frozen vegetables that are prepared only by normal blanching treatment do not have a good texture, and both thawing and cooking and heating take time, and the processing time is longer than when using raw vegetables. It takes a long time.

【0016】処理条件のうち、表面温度は90℃以下で
あると効果を得るのに十分でなく、褐変に関与する酵素
たとえばポリフェノールオキシダーゼなどを失活させる
に至らず褐変が生じてしまう。また、加熱時間は2分以
下であると褐変に影響する表面から数mm内側の部分に
すら熱が伝わらず組織に十分な変化がみられず褐変が生
じてしまう。また、5分以上加熱すると逆に内部まで熱
が伝わりすぎ褐変は防止できるものの組織が変化し過
ぎ、次の第二工程の組織強化を不可能にし、解凍後の加
熱で煮崩れを生じ食感が低下してまう。
Among the treatment conditions, the surface temperature of 90 ° C. or lower is not sufficient to obtain the effect, and the enzyme involved in browning, such as polyphenol oxidase, is not inactivated and browning occurs. In addition, if the heating time is 2 minutes or less, heat is not even transferred to a part within a few mm from the surface that influences browning, and sufficient change is not observed in the tissue, causing browning. On the other hand, if heated for more than 5 minutes, heat will be transferred to the inside and browning can be prevented, but the structure will change too much, making it impossible to strengthen the structure in the next second step, and heating after thawing will cause collapse of the texture. Will decrease.

【0017】本発明の第二工程は、第一工程の処理をし
た野菜を直ちに加温したカルシウム溶液中に移行し、中
心温度55℃〜75℃で10〜90分間保持することで
行う工程である。中心温度は、品温センターすなわち
(野菜の)最も温度変化の遅い部分の温度を測定した。
この処理によって植物体の持つペクチンエステラーゼを
活注化しペクチン質の脱メチル化を促し、遊離したカル
ボキシル基が共存する組織内のカルシウムと結合して野
菜類の組織を強化させることができる。この処理を行わ
ない場合、例えば、冷凍前に単に可食状態になるまで十
分加熱した後に冷凍し解凍した場合、すなわち本発明で
いう第三工程のみ行った場合には、解凍後に組織は極度
に軟化し煮崩れしやすく悪い食感の製品しか得ることは
できない。
The second step of the present invention is a step which is carried out by immediately transferring the vegetables treated in the first step into a heated calcium solution and holding the central temperature at 55 ° C to 75 ° C for 10 to 90 minutes. is there. As the central temperature, the temperature of the product temperature center, that is, the temperature of the part (of vegetables) having the slowest temperature change was measured.
By this treatment, the pectinesterase possessed by the plant is activated to promote the demethylation of the pectic substance, and the released carboxyl group can bind to calcium in the coexisting tissue to strengthen the tissue of vegetables. If this treatment is not carried out, for example, before freezing, it is simply heated sufficiently to an edible state and then frozen and thawed, that is, if only the third step in the present invention is performed, the tissue is extremely thawed. Only products that tend to soften and crumble can be obtained.

【0018】本発明の第二工程で使用するカルシウム
は、乳酸カルシウム、硫酸カルシウム、塩化カルシウ
ム、酢酸カルシウム、炭酸カルシウムなど水溶性であり
人体に無害であればいずれでも良いが、溶解性、味の点
から乳酸カルシウムが好ましい。カルシウム溶液は好ま
しくは60℃〜75℃の温度に加温したものを使用す
る。
The calcium used in the second step of the present invention may be any of calcium lactate, calcium sulfate, calcium chloride, calcium acetate, calcium carbonate and the like as long as it is water-soluble and harmless to the human body, but the solubility and taste are From the viewpoint, calcium lactate is preferable. The calcium solution used is preferably heated to a temperature of 60 ° C to 75 ° C.

【0019】第二工程におけるカルシウム濃度と処理時
間は、解凍後に必要な加熱の程度によって異なる。本発
明の好ましい実施態様は、丸のままあるいは大きくカッ
トした野菜類を第一工程で湯中または蒸気によって90
〜100℃に表面を加熱し、2〜5分間保持した後に、
第二工程でカルシウムを含む水溶液中で中心温度55℃
〜75℃で10〜90分間、第三工程で中心温度85℃
〜95℃に加熱した後に凍結し冷凍保存する、このよう
な組み合わせによる多段階加熱後冷凍を行う冷凍野菜の
製造方法である。丸のままあるいは大きくカットした野
菜であっても解凍後の食感を保持させ調理のための再加
熱時にも煮崩れ軟化を防止できる。
The calcium concentration and treatment time in the second step differ depending on the degree of heating required after thawing. In a preferred embodiment of the present invention, vegetables that have been round or cut into large pieces are heated in hot water or steam in the first step.
After heating the surface to ~ 100 ° C and holding for 2-5 minutes,
In the second step, the core temperature is 55 ° C in an aqueous solution containing calcium.
~ 75 ° C for 10 to 90 minutes, the central temperature is 85 ° C in the third step
It is a method for producing frozen vegetables in which multi-step heating and freezing are performed by such a combination, in which the material is frozen at −95 ° C. and then frozen and stored. Even if the vegetables are round or cut into large pieces, the texture after thawing can be retained and the softening by boiling can be prevented even during reheating for cooking.

【0020】本発明の目的物である冷凍野菜は、例えば
二次加工用冷凍野菜である。シチュー、カレー、調理後
すぐに供するおでん、肉ジャガなどに用いる調理用素材
すなわち、二次加工用素材の場合には、カルシウム濃度
6〜16mMで10〜30分間所定温度で保持する。二
次加工用素材の場合には、第二工程の処理を過度に行わ
ず表面を硬くしすぎないことが肝要である。すなわち、
本発明は第一工程で野菜類をまず表面温度を90〜10
0℃で2〜5分間処理した後に、第二工程で6〜16m
Mのカルシウムを含む水溶液中で中心温度55℃〜75
℃で10〜180分間、好ましくは10〜30分間処理
し、第三工程で中心部分が85℃〜95℃に到達するま
で加熱した後に冷凍処理する2次加工用冷凍野菜の製造
方法である。
The frozen vegetables which are the object of the present invention are, for example, frozen vegetables for secondary processing. In the case of a cooking material used for stews, curries, oden to be served immediately after cooking, meat potatoes, etc., that is, a secondary processing material, it is held at a predetermined temperature for 10 to 30 minutes with a calcium concentration of 6 to 16 mM. In the case of a material for secondary processing, it is important that the treatment of the second step is not performed excessively and the surface is not made too hard. That is,
In the first step of the present invention, vegetables are first subjected to a surface temperature of 90 to 10
After treatment at 0 ° C for 2-5 minutes, in the second step 6-16m
Central temperature 55 ° C to 75 in an aqueous solution containing calcium of M
It is a method for producing a frozen vegetable for secondary processing, which is a treatment at 10 ° C for 10 to 180 minutes, preferably 10 to 30 minutes, heating in the third step until the central portion reaches 85 ° C to 95 ° C, and then freezing.

【0021】本発明の目的物である冷凍野菜は、例えば
店頭販売や専門店等で長時間煮込んだ状態で提供するお
でん種用の冷凍野菜である。おでんなど長時間加熱する
料理に用いる場合にはカルシウム濃度6〜16mMで2
0〜50分間所定温度で保持する。すなわち、本発明は
第一工程で野菜類をまず90〜100℃で2〜5分間処
理した後に、第二工程で6〜16mMのカルシウムを含
む水溶液中で中心温度55〜75℃で20〜50分間処
理し、第三工程で中心温度が85〜90℃になるように
加熱した後に冷凍処理するおでんなど通常の加熱調理加
工により長時間加熱しても煮崩れ軟化しない冷凍野菜の
製造方法である。
The frozen vegetable which is the object of the present invention is a frozen vegetable for oden seeds which is provided in a state of being boiled for a long time at over-the-counter sales or specialty stores. When used for cooking such as oden for a long period of time, the calcium concentration is 6 to 16 mM.
Hold at a predetermined temperature for 0 to 50 minutes. That is, the present invention first treats vegetables in the first step at 90 to 100 ° C. for 2 to 5 minutes, and then in the second step in an aqueous solution containing 6 to 16 mM calcium at a central temperature of 55 to 75 ° C. for 20 to 50. It is a method for producing frozen vegetables that do not soften and soften even after being heated for a long time by ordinary heating and cooking processing such as oden, which is processed by heating for 3 minutes and heating in the third step so that the central temperature is 85 to 90 ° C and then frozen. .

【0022】本発明の目的物である冷凍野菜は、例えば
レトルト加熱加工用の冷凍野菜である。レトルト食品の
材料を提供するには、第二工程をカルシウム濃度13〜
50mMで30〜90分間中心温度が所定温度で保持す
る。レトルトの過酷な加熱に耐えることができるよう
に、第二工程のカルシウム濃度を高め処理時間を長くす
ることが肝要である。第三工程は省略することができ
る。この場合、本発明は第三工程を省略し、かつ、冷凍
野菜がレトルト加熱加工用の冷凍野菜の製造方法であ
る。すなわち、本発明は第一工程で野菜類をまず表面温
度が90〜100℃になるように2〜3分間処理した後
に、第二工程で13〜50mMカルシウムを含む水溶液
中で60℃から75℃で中心温度55〜75℃で30〜
90分間処理した後に冷凍処理するレトルト加熱しても
煮崩れ軟化しない冷凍野菜の製造方法である。得られた
冷凍野菜はレトルトパウチ食品の材料として最適であ
る。
The frozen vegetable which is the object of the present invention is, for example, a frozen vegetable for retort heating processing. To provide the ingredients for the retort food, the second step is a calcium concentration of 13-
The core temperature is maintained at a predetermined temperature for 30 to 90 minutes at 50 mM. It is important to increase the calcium concentration in the second step and increase the treatment time so that the retort can withstand the harsh heating. The third step can be omitted. In this case, the present invention is a method for producing frozen vegetables for retort heating processing, wherein the third step is omitted and frozen vegetables are processed. That is, according to the present invention, in the first step, vegetables are first treated at a surface temperature of 90 to 100 ° C. for 2 to 3 minutes, and then in the second step, an aqueous solution containing 13 to 50 mM calcium is used at 60 to 75 ° C. At a central temperature of 55 to 75 ° C and 30 to
This is a method for producing frozen vegetables which is not boiled down and softened even if it is heated in a retort for 90 minutes after it is frozen. The obtained frozen vegetables are optimal as a material for retort pouch foods.

【0023】これらの条件より低い濃度もしくは短い時
間では組織強化が十分ではなく用途に応じた食感が得ら
れず煮崩れなどを防止することができない。またこれよ
りも高い濃度、長い時間であると、過度に組織が硬くな
り好ましい食感、食味ではなくなる。
If the concentration is lower than these conditions or for a short time, the tissue strengthening is not sufficient, the texture corresponding to the application cannot be obtained, and it is not possible to prevent simmering. Further, if the concentration is higher than this and the time is longer, the tissue becomes excessively hard and the texture and taste are not preferable.

【0024】第三工程の処理は主として喫食前の加熱が
短時間で済み、かつ優れた食感で調理用素材として利用
できるようにするために行う。上記したごとく、レトル
ト加熱など高温高圧で長時間の殺菌を目的とした加熱な
どが予想される料理のためにはあえてこの工程を行う必
要はないが、調理素材などに用いる際には第三工程の処
理は必須になってくる。この工程を行わない場合、つま
り、カルシウムなどを用い組織強化処理のみを行った場
合即ち本発明でいう第二工程の処理まで行った場合に
は、解凍時にスジばった食感を与え、それを無くすため
には通常の調理加熱(90〜100℃で15〜30分
間)より長時間の加熱が必要になってしまう。実際の処
理条件は野菜の中心部分が90℃に達する時点で加熱を
終了すると好ましい食感が得られる。加熱が不十分であ
ると解凍後の調理に長時間を要し、かつ、すじっぽくざ
らざらした食感になってしまう。また、加熱時間が長す
ぎると解凍時に煮崩れや軟化を生じてしまう。
The treatment in the third step is mainly carried out so that the heating before eating can be completed in a short time and the material can be used as a cooking material with an excellent texture. As mentioned above, it is not necessary to perform this step for cooking where heating for the purpose of sterilization for a long time at high temperature and high pressure such as retort heating is not necessary, but when using it for cooking ingredients etc., the third step The processing of becomes necessary. When this step is not performed, that is, when only the tissue strengthening treatment using calcium or the like is performed, that is, when the treatment of the second step in the present invention is performed, a streaky texture is given at the time of thawing and it is eliminated. In order to do so, heating for a longer period of time is required than usual cooking and heating (90 to 100 ° C. for 15 to 30 minutes). As for the actual processing conditions, if the heating is terminated when the central portion of the vegetables reaches 90 ° C., a desirable texture is obtained. If the heating is not sufficient, it takes a long time to cook after thawing and the texture becomes streaky and rough. In addition, if the heating time is too long, thawing and softening will occur during thawing.

【0025】また、第三工程の処理時に処理した野菜を
通常の調理(調味と加熱)加工を行い凍結することで、
肉ジャガ、カレー、おでん、煮しめなどの調理済み冷凍
食品を製造することもできる。この場合、本発明の冷凍
野菜の製造方法は第三工程が加熱調理加工工程である。
In addition, the vegetables processed at the time of the third step are subjected to usual cooking (seasoning and heating) processing and frozen,
It is also possible to produce cooked frozen foods such as meat potatoes, curries, oden and stewed foods. In this case, the third step of the method for producing frozen vegetables of the present invention is the heating and cooking step.

【0026】凍結前の冷却方法は、真空冷却機を用いれ
ば、迅速に冷却を行うことができるが、水中で冷却、あ
るいは空気中に放置あるいは送風によって冷却すること
でも目的の品質の製品を得ることができる。凍結および
保存方法は通常のブラストフリーザーを用いて行うが、
その他の冷凍処理で行ってもかまわない。いずれにせよ
急速凍結することでよりよい品質が得られる。
As for the cooling method before freezing, if a vacuum cooler is used, the cooling can be carried out quickly, but the desired quality product can also be obtained by cooling in water, leaving it in the air or cooling it by blowing air. be able to. Freezing and storage are done using a normal blast freezer,
Other freezing treatments may be used. In any case, quick freezing gives better quality.

【0027】[0027]

【実施例】本発明を実施例によって説明する。本発明は
この実施例によって何ら限定されない。
EXAMPLES The present invention will be described with reference to examples. The invention is in no way limited by this example.

【0028】実施例1 (第一工程の加熱条件と褐変防止効果)1個あたり10
0gの生のジャガイモの皮を剥ぎ芽取りしたものを丸の
まま水道水に30分さらした後、第一工程の処理として
各表面温度になるように加熱し各時間保持した。その
後、第二工程の処理として70℃の16mMの乳酸カル
シウム溶液に入れ中心温度が55℃〜70℃になるよう
に30分間保持した。次に、3段階目の処理として中心
温度が90℃になるように、雰囲気温度95℃で約20
分間の加熱を行い、その後、−40℃で送風凍結した。
−30℃で1週間保存した後、95℃で30分間解凍
し、表1に示した結果を得た。また比較として、1段階
目を行わないもの、3段階目のみ行ったものについて同
様に処理し、結果を表1に示した。温度測定は、横河電
機(株)製(μR1000型、Kタイプ熱電対)温度記
録計を用いて行った。表面温度は野菜表面部分に熱電対
を埋め込み測定し、中心温度は品温センターすなわち野
菜の最も温度変化の遅い部分の温度を測定した。
Example 1 (heating conditions in the first step and browning prevention effect) 10 per piece
A strip of 0 g of raw potato peeled and exposed was exposed to tap water as a whole for 30 minutes, and then heated to each surface temperature as the treatment of the first step and held for each hour. Then, as a treatment of the second step, the mixture was placed in a 16 mM calcium lactate solution at 70 ° C. and held for 30 minutes so that the central temperature was 55 ° C. to 70 ° C. Next, as the third stage treatment, the center temperature is set to 90 ° C. and the ambient temperature is set to about 95 ° C. for about 20 ° C.
It was heated for 1 minute, and then blown and frozen at -40 ° C.
After storing at -30 ° C for 1 week, it was thawed at 95 ° C for 30 minutes to obtain the results shown in Table 1. In addition, as a comparison, the same treatment was carried out for those without the first step and those with only the third step, and the results are shown in Table 1. The temperature was measured using a Yokogawa Denki Co., Ltd. (μR1000 type, K type thermocouple) temperature recorder. The surface temperature was measured by embedding a thermocouple in the vegetable surface portion, and the center temperature was measured at the product temperature center, that is, the temperature of the vegetable where the temperature change was the slowest.

【0029】[0029]

【表1】 [Table 1]

【0030】実施例2 (カルシウム濃度とレトルト耐性)1個あたり100g
の生のジャガイモの皮を剥ぎ芽取りしたものを丸のまま
水道水に30分さらした後、第一工程として90℃の湯
中に投入し2分間処理した。その後、第二工程として7
0℃の各濃度の乳酸カルシウム溶液に入れ60分間処理
し冷却後−40℃で冷凍処理した。−30℃で1週間保
存した後に、おでん用だし汁200mlにジャガイモ2
個を入れ、ジャガイモの中心部が121℃の温度履歴に
換算して11分間加熱(F=11,121℃60分)
になるようにレトルト加熱したところ、表2に示した結
果を得た。
Example 2 (Calcium concentration and retort resistance) 100 g per piece
The raw potatoes obtained by peeling off the buds were exposed to tap water as they were for 30 minutes, and then placed in hot water at 90 ° C. for 2 minutes as the first step. Then, as the second step, 7
The mixture was placed in a calcium lactate solution having a concentration of 0 ° C., treated for 60 minutes, cooled, and then frozen at −40 ° C. After storing at -30 ℃ for 1 week, add 200 ml of oden soup stock to 2 potatoes.
Put the pieces and convert the temperature of the center of the potato to 121 ° C and heat for 11 minutes (F 0 = 11, 121 ° C 60 minutes)
The results shown in Table 2 were obtained by heating the retort so that

【0031】[0031]

【表2】 [Table 2]

【0032】実施例3 1個あたり100gの生のジャガイモの皮を剥ぎ芽取り
したものを丸のまま水道水に30分さらし、表3に示す
条件で処理し、−40℃で送風凍結、−30℃で30日
間保存した後、各条件で解凍したところ、表4に示す結
果を得た。
Example 3 100 g of raw potatoes, which had been peeled and sprouted, were exposed to tap water as a whole for 30 minutes, treated under the conditions shown in Table 3, frozen by blowing at -40 ° C, After storing at 30 ° C. for 30 days and thawing under each condition, the results shown in Table 4 were obtained.

【0033】[0033]

【表3】 [Table 3]

【0034】[0034]

【表4】 [Table 4]

【0035】実施例4 (第三工程の加熱条件と食感)1個あたり100gの生
のジャガイモの皮を剥いて丸のまま水道水に30分さら
した後、第一工程として表面温度が90℃になるよう
に、90℃の湯中に投入し2分間処理した。その後、第
二工程として70℃の16mM濃度の乳酸カルシウム溶
液に入れ中心部分が55℃〜70℃になるように30分
間保持し、第三工程として95〜100℃の湯中で表5
に示した各加熱時間保持し、表記の中心温度とした。次
いで冷却し、冷却後−40℃で冷凍処理した。−30℃
で1週間保存した後に、95℃30分間湯中で加熱し評
価したところ、表5に示した結果を得た。
Example 4 (Heating conditions and texture of the third step) 100 g of raw potatoes were peeled from each piece and exposed to tap water as they were for 30 minutes. The mixture was placed in hot water at 90 ° C. and treated for 2 minutes so that the temperature became 0 ° C. Then, as a second step, the mixture was placed in a 16 mM calcium lactate solution at 70 ° C. and held for 30 minutes so that the central part was at 55 ° C. to 70 ° C., and as a third step, in hot water at 95 to 100 ° C.
Each heating time shown in (4) was maintained and set as the indicated center temperature. Then, it was cooled, and after cooling, it was frozen at -40 ° C. -30 ° C
After being stored for 1 week at 95 ° C., it was heated in hot water at 95 ° C. for 30 minutes and evaluated, and the results shown in Table 5 were obtained.

【0036】[0036]

【表5】 [Table 5]

【0037】実施例5 (二次加工用処理条件で処理した冷凍ジャガイモによる
肉ジャガ調理)ジャガイモの皮を剥き芽取り4分割し、
水さらししたものを材料に用い、1段階の処理として表
面温度が90℃になるように、90℃の湯中で2分間加
熱し、2段階目の処理として、70℃の6mMの乳酸カ
ルシウム中で中心部分が55℃〜70℃になるように1
5分間保持し、3段階目の処理として中心温度が90℃
になるように、95℃で20分間加熱した。その後に冷
却し−40℃で冷凍処理を行った。−30℃で1週間保
存した。
Example 5 (Cooking Meat Potatoes with Frozen Potato Treated under Secondary Processing Conditions) Peel and peel the potatoes into four pieces,
Using the water-exposed material as a material, heat it in hot water at 90 ° C. for 2 minutes so that the surface temperature becomes 90 ° C. as a one-step treatment, and as a second step treatment in 6 mM calcium lactate at 70 ° C. 1 so that the central part is between 55 ℃ and 70 ℃
Hold for 5 minutes, center temperature is 90 ° C as the third treatment
Was heated at 95 ° C. for 20 minutes. Then, it cooled and frozen at -40 degreeC. Stored at -30 ° C for 1 week.

【0038】この冷凍ジャガイモと、玉ねぎ、牛肉を
5:3:1の割合で鍋に加えて炒めた後、醤油、みり
ん、砂糖、かつお濃縮エキスを5:2:1:0.1の割
合で加え25分煮込み肉ジャガを作成した。
This frozen potato, onion, and beef were added to a pan at a ratio of 5: 3: 1 and fried, and soy sauce, mirin, sugar, and bonito concentrated extract were mixed at a ratio of 5: 2: 1: 0.1. In addition, meat potatoes were prepared for 25 minutes.

【0039】また比較として(1)生のジャガイモを材
料としたもの、(2)1段階目のみ、(3)2段階目の
み、(4)3段階目のみの処理をした後冷凍処理したも
の、(5)1段階目と2段階目処理のみ行った後冷凍処
理したものを材料として用い同様に肉ジャガを作成し、
評価したところ、表6に示した結果を得た。
For comparison, (1) raw potatoes, (2) first stage only, (3) second stage only, (4) third stage only, and then frozen. (5) A meat jaguar was prepared in the same manner by using only the first-stage and second-stage treatments and then the frozen treatment as a material.
Upon evaluation, the results shown in Table 6 were obtained.

【0040】[0040]

【表6】 [Table 6]

【0041】さらに−20℃で3カ月冷凍保存した材料
を用いて評価を行ったところ、同様の結果を得た。ま
た、1段階目および2段階目処理を行った後に同様な調
理操作を行い肉ジャガを作成し、冷凍処理を行い冷凍保
存後湯煎で解凍したところ、生のジャガイモを用いて調
理した肉ジャガのジャガイモと遜色ない食感であった。
Further evaluation was carried out using a material which was frozen and stored at −20 ° C. for 3 months, and the same result was obtained. In addition, after performing the first and second-stage treatments, the same cooking operation was performed to prepare meat potatoes, which were frozen, thawed in hot water after frozen storage, and the meat potatoes cooked using raw potatoes were The texture was comparable to that of potatoes.

【0042】実施例6 (長時間加熱用条件で処理した冷凍ジャガイモを用いた
おでんの調理)大根、ジャガイモを水洗、皮剥き、芽取
り後、一片が50g〜100g程度にカットあるいは丸
のままで1段階目に表面温度100℃で3分間処理した
後に、2段階目に70℃の16mMの乳酸カルシウムを
含む水溶液中で中心部分が55℃〜70℃になるように
40分間保持し、3段階目で95℃で30分間加熱し
た。その後に−40℃で冷凍処理した。−30℃で1週
間冷凍保存した材料を、水、みりん、醤油、かつお濃縮
エキス、90:3:0.5:1からなるおでんだし汁中
へ凍結状態のまま他のおでんの具とともに入れ、弱く沸
騰する状態で60分間煮込んだ。その後液温を90℃に
し、さらに6時間煮込んだ。また比較として(1)1段
階目の処理のみ行ったもの、(2)2段階目の処理のみ
行ったもの、(3)3段階目の処理のみ行ったものにつ
いて同様におでんを作製し評価を行った。結果を表7に
示す。
Example 6 (Cooking of Oden Using Frozen Potatoes Treated Under Long-Term Heating Conditions) After radish and potatoes were washed with water, peeled, and sprout removed, pieces were cut to about 50 to 100 g or left as a whole. In the first step, the surface temperature was 100 ° C. for 3 minutes, and in the second step, the central portion was kept at 55 ° C. to 70 ° C. for 40 minutes in an aqueous solution containing 16 mM calcium lactate at 70 ° C. Heated visually at 95 ° C. for 30 minutes. Then, it was frozen at -40 ° C. Put the ingredients frozen at -30 ℃ for 1 week in water, mirin, soy sauce, concentrated bonito extract, 90: 3: 0.5: 1 into Odenashi soup and put it in the frozen state together with other oden ingredients. It was boiled for 60 minutes while boiling. After that, the liquid temperature was raised to 90 ° C. and the mixture was boiled for 6 hours. For comparison, oden was similarly prepared and evaluated for (1) those subjected to only the first-stage treatment, (2) those subjected to only the second-stage treatment, and (3) those subjected to only the third-stage treatment. went. The results are shown in Table 7.

【0043】[0043]

【表7】 [Table 7]

【0044】実施例7 人参を水洗後剥皮し一片が50g程度の大きさに切断
し、1段階目に表面温度が90℃になるように2分間処
理した後に、2段階目に16mMの乳酸カルシウムを含
む水溶液中で中心部分が55℃から70℃で30分間保
持し、3段階目で中心温度が95℃に到達するまで加熱
した後に−40℃で冷凍処理した。−30℃で1週間冷
凍保存した材料を、弱く沸騰する湯中で解凍し、付け合
わせ用の人参を作った。また比較として(1)1段階目
の処理のみ行ったもの、(2)2段階目の処理のみ行っ
たもの、(3)3段階目の処理のみ行ったものを作製し
評価を行った。結果を表8に示す。
Example 7 Carrots were washed with water, peeled, cut into pieces each having a size of about 50 g, treated in the first step for 2 minutes so that the surface temperature was 90 ° C., and then in the second step, 16 mM calcium lactate. The core portion was kept at 55 ° C. to 70 ° C. for 30 minutes in an aqueous solution containing, and heated in the third stage until the central temperature reached 95 ° C., and then frozen at −40 ° C. The material stored frozen at -30 ° C for 1 week was thawed in slightly boiling water to prepare carrots for garnishing. For comparison, (1) only the first-stage treatment, (2) the second-stage treatment, and (3) the third-stage treatment were prepared and evaluated. Table 8 shows the results.

【0045】[0045]

【表8】 [Table 8]

【0046】[0046]

【発明の効果】解凍、調理した後、軟化や煮崩れがな
く、食感の優れた調理食品となる冷凍野菜を製造するこ
とができる。丸のままの野菜や大きくカットした野菜の
場合に褐変を生じず、良い食感を保持し、解凍時の調理
において煮崩れが起きず軟化しない冷凍野菜を製造する
ことができる。肉ジャガなどの惣菜用に用いる二次加工
用冷凍野菜、おでん種などの長時間加熱用の冷凍野菜、
レトルト加熱などの過酷な加熱条件でも煮崩れや軟化の
ないレトルト加熱加工用冷凍野菜を提供できる。
INDUSTRIAL APPLICABILITY Frozen vegetables, which are cooked foods having an excellent texture without softening or boiling after being thawed and cooked, can be produced. It is possible to produce frozen vegetables that do not turn brown when they are whole vegetables or vegetables that are cut into large pieces, retain a good texture, and do not soften when cooked during thawing. Frozen vegetables for secondary processing used for side dishes such as meat potatoes, frozen vegetables for long-term heating such as oden seeds,
It is possible to provide frozen vegetables for retort heating processing that do not collapse or soften even under severe heating conditions such as retort heating.

【手続補正書】[Procedure amendment]

【提出日】平成7年7月10日[Submission date] July 10, 1995

【手続補正1】[Procedure Amendment 1]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0016[Correction target item name] 0016

【補正方法】変更[Correction method] Change

【補正内容】[Correction content]

【0016】処理条件のうち、表面温度は90℃未満
あると効果を得るのに十分でなく、褐変に関与する酵素
たとえばポリフェノールオキシダーゼなどを失活させる
に至らず褐変が生じてしまう。また、加熱時間は2分
であると褐変に影響する表面から数mm内側の部分に
すら熱が伝わらず組織に十分な変化がみられず褐変が生
じてしまう。また、5分以上加熱すると逆に内部まで熱
が伝わりすぎ褐変は防止できるものの組織が変化し過
ぎ、次の第二工程の組織強化を不可能にし、解凍後の加
熱で煮崩れを生じ食感が低下してまう。
If the surface temperature is lower than 90 ° C. among the treatment conditions, the effect is not sufficient, and the enzyme involved in browning, such as polyphenol oxidase, cannot be inactivated, and browning occurs. In addition, the heating time is not yet 2 minutes
When it is full , heat is not even transmitted to a part within a few mm from the surface that influences browning, and sufficient change is not seen in the tissue, causing browning. On the other hand, if heated for more than 5 minutes, heat will be transferred to the inside and browning can be prevented, but the structure will change too much, making it impossible to strengthen the structure in the next second step, and heating after thawing will cause collapse of the texture. Will decrease.

【手続補正2】[Procedure Amendment 2]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0022[Name of item to be corrected] 0022

【補正方法】変更[Correction method] Change

【補正内容】[Correction content]

【0022】本発明の目的物である冷凍野菜は、例えば
レトルト加熱加工用の冷凍野菜である。レトルト食品の
材料を提供するには、第二工程をカルシウム濃度13〜
50mMで30〜90分間中心温度が所定温度で保持す
る。レトルトの過酷な加熱に耐えることができるよう
に、第二工程のカルシウム濃度を高め処理時間を長くす
ることが肝要である。第三工程は省略することができ
る。この場合、本発明は第三工程を省略し、かつ、冷凍
野菜がレトルト加熱加工用の冷凍野菜の製造方法であ
る。すなわち、本発明は第一工程で野菜類をまず表面温
度が90〜100℃になるように2〜3分間処理した後
に、第二工程で13〜50mMカルシウムを含む水溶液
中で60℃から75℃中心温度55〜75℃で30
〜90分間処理した後に冷凍処理するレトルト加熱して
も煮崩れ軟化しない冷凍野菜の製造方法である。得られ
た冷凍野菜はレトルトパウチ食品の材料として最適であ
る。
The frozen vegetable which is the object of the present invention is, for example, a frozen vegetable for retort heating processing. To provide the ingredients for the retort food, the second step is a calcium concentration of 13-
The core temperature is maintained at a predetermined temperature for 30 to 90 minutes at 50 mM. It is important to increase the calcium concentration in the second step and increase the treatment time so that the retort can withstand the harsh heating. The third step can be omitted. In this case, the present invention is a method for producing frozen vegetables for retort heating processing, wherein the third step is omitted and frozen vegetables are processed. That is, according to the present invention, in the first step, vegetables are first treated at a surface temperature of 90 to 100 ° C. for 2 to 3 minutes, and then in the second step, an aqueous solution containing 13 to 50 mM calcium is used at 60 to 75 ° C. 30 at ( center temperature 55-75 ° C )
It is a method for producing a frozen vegetable which is not boiled down and softened even when heated in a retort which is processed by freezing for 90 minutes. The obtained frozen vegetables are optimal as a material for retort pouch foods.

Claims (5)

【特許請求の範囲】[Claims] 【請求項1】 丸のままあるいは大きくカットした大き
さの野菜類を、その組織の強化処理を施こした後、冷凍
処理することを特徴とする冷凍野菜の製造方法。
1. A method for producing frozen vegetables, which comprises subjecting vegetables having a size of a whole circle or a large cut size to a tissue strengthening treatment and then a freezing treatment.
【請求項2】 上記組織の強化処理が、野菜類を高温で
処理する第一工程およびカルシウムを含む水溶液中で加
熱処理する第二工程を必須とする工程で行われる請求項
1の冷凍野菜の製造方法。
2. The frozen vegetable according to claim 1, wherein the tissue strengthening treatment is carried out in a step in which a first step of treating vegetables at a high temperature and a second step of heat treatment in an aqueous solution containing calcium are essential. Production method.
【請求項3】 上記組織の強化処理が、少なくとも野菜
類を高温で処理する第一工程、カルシウムを含む水溶液
中で加熱処理する第二工程、および再度高温で処理する
第三工程を必須とする工程で行われる請求項1の冷凍野
菜の製造方法。
3. The tissue strengthening treatment requires at least a first step of treating vegetables at a high temperature, a second step of heat treating in an aqueous solution containing calcium, and a third step of treating again at a high temperature. The method for producing frozen vegetables according to claim 1, which is carried out in a step.
【請求項4】 野菜類がジャガイモである請求項1、2
または3の冷凍野菜の製造方法。
4. The vegetables according to claim 1, 2 or 3.
Alternatively, the method for producing frozen vegetables according to 3).
【請求項5】 カルシウムを含む水溶液が乳酸カルシウ
ムを溶解した水溶液である請求項1ないし4のいずれか
の冷凍野菜の製造方法。
5. The method for producing frozen vegetables according to claim 1, wherein the aqueous solution containing calcium is an aqueous solution in which calcium lactate is dissolved.
JP33079194A 1994-11-26 1994-11-26 Manufacturing method of frozen vegetables Expired - Fee Related JP2839455B2 (en)

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Publication number Priority date Publication date Assignee Title
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WO2003003861A1 (en) * 2001-07-03 2003-01-16 Matsushita Electric Industrial Co., Ltd. Methods of freezing and thawing food, method of freezing, thawing, and cooking food, devices for freezing and thawing food, device of freezing, thawing, and cooking food, and frozen food
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Publication number Priority date Publication date Assignee Title
US6844017B1 (en) 1999-10-12 2005-01-18 Gf Gijyutsu Kaihatsu Co. Ltd. Food processing method for edible and perishable plants
WO2001026476A1 (en) * 1999-10-12 2001-04-19 Gf Gijutsu Kaihatsu Co., Ltd. Food processing method for fresh edible plant
JP2001103907A (en) * 1999-10-12 2001-04-17 G F Gijutsu Kaihatsu:Kk Method for processing perishable edible plant into food
WO2003003861A1 (en) * 2001-07-03 2003-01-16 Matsushita Electric Industrial Co., Ltd. Methods of freezing and thawing food, method of freezing, thawing, and cooking food, devices for freezing and thawing food, device of freezing, thawing, and cooking food, and frozen food
WO2004004489A1 (en) * 2002-07-08 2004-01-15 Ajinomoto Co., Inc. Method of modifying food material
EP1407671A1 (en) * 2002-10-08 2004-04-14 Unilever Plc Freezing vegetables
WO2004107867A1 (en) * 2003-06-05 2004-12-16 Ajinomoto Co., Inc. Process for producing frozen food
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