JPH08133805A - Self-filling concrete composition - Google Patents
Self-filling concrete compositionInfo
- Publication number
- JPH08133805A JPH08133805A JP6277444A JP27744494A JPH08133805A JP H08133805 A JPH08133805 A JP H08133805A JP 6277444 A JP6277444 A JP 6277444A JP 27744494 A JP27744494 A JP 27744494A JP H08133805 A JPH08133805 A JP H08133805A
- Authority
- JP
- Japan
- Prior art keywords
- concrete composition
- self
- concrete
- filling
- reducing agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004567 concrete Substances 0.000 title claims abstract description 27
- 239000000203 mixture Substances 0.000 title claims abstract description 27
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 150000003973 alkyl amines Chemical class 0.000 claims abstract description 6
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 5
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 12
- 239000008030 superplasticizer Substances 0.000 claims description 9
- 239000011376 self-consolidating concrete Substances 0.000 claims description 7
- 229920000877 Melamine resin Polymers 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical group NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 4
- 229920001515 polyalkylene glycol Polymers 0.000 claims description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- 239000000178 monomer Substances 0.000 claims description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 2
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical group O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 claims 1
- 238000000926 separation method Methods 0.000 abstract description 12
- 238000005056 compaction Methods 0.000 abstract description 3
- 230000002401 inhibitory effect Effects 0.000 abstract description 3
- 238000003892 spreading Methods 0.000 abstract description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 8
- 239000004568 cement Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 6
- 229920003169 water-soluble polymer Polymers 0.000 description 5
- WURBVZBTWMNKQT-UHFFFAOYSA-N 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)butan-2-one Chemical compound C1=NC=NN1C(C(=O)C(C)(C)C)OC1=CC=C(Cl)C=C1 WURBVZBTWMNKQT-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- -1 1989.6 Substances 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000004088 foaming agent Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000004570 mortar (masonry) Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- QGLWBTPVKHMVHM-KTKRTIGZSA-N (z)-octadec-9-en-1-amine Chemical compound CCCCCCCC\C=C/CCCCCCCCN QGLWBTPVKHMVHM-KTKRTIGZSA-N 0.000 description 1
- 239000012028 Fenton's reagent Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- LXXANCYSUGPRMZ-UHFFFAOYSA-N docosyl(oxido)azanium Chemical compound CCCCCCCCCCCCCCCCCCCCCC[NH2+][O-] LXXANCYSUGPRMZ-UHFFFAOYSA-N 0.000 description 1
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- UYFDTXCTFHXZEL-UHFFFAOYSA-N formaldehyde;phenol;phenylsulfamic acid Chemical compound O=C.OC1=CC=CC=C1.OS(=O)(=O)NC1=CC=CC=C1 UYFDTXCTFHXZEL-UHFFFAOYSA-N 0.000 description 1
- ORCIEIBZCKPMGC-UHFFFAOYSA-N hexyl(oxido)azanium Chemical compound CCCCCC[NH2+][O-] ORCIEIBZCKPMGC-UHFFFAOYSA-N 0.000 description 1
- 239000004574 high-performance concrete Substances 0.000 description 1
- 239000011396 hydraulic cement Substances 0.000 description 1
- MGZTXXNFBIUONY-UHFFFAOYSA-N hydrogen peroxide;iron(2+);sulfuric acid Chemical compound [Fe+2].OO.OS(O)(=O)=O MGZTXXNFBIUONY-UHFFFAOYSA-N 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229920003145 methacrylic acid copolymer Polymers 0.000 description 1
- 229940117841 methacrylic acid copolymer Drugs 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910021487 silica fume Inorganic materials 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/0068—Ingredients with a function or property not provided for elsewhere in C04B2103/00
- C04B2103/0082—Segregation-preventing agents; Sedimentation-preventing agents
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/30—Water reducers, plasticisers, air-entrainers, flow improvers
- C04B2103/32—Superplasticisers
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は自己充填性コンクリート
組成物に関する。更に詳しくは、高流動性、高充填性、
高分離抵抗性を有し、打設時の締め固めを低減あるいは
不要とし、騒音に対する環境を改善する土木、建築コン
クリート製品等のコンクリート構造物に添加するコンク
リート組成物に関するものである。FIELD OF THE INVENTION This invention relates to self-compacting concrete compositions. More specifically, high fluidity, high filling property,
The present invention relates to a concrete composition which has high separation resistance, reduces or eliminates compaction during casting, and improves the environment against noise, and is added to concrete structures such as civil engineering and building concrete products.
【0002】[0002]
【従来の技術及び発明が解決しようとする課題】近年、
コンクリート業界は3K (きつい、汚い、危険) の代表
とも言われ、その中でも騒音に対する環境問題が大き
い。従って、流動性を高めて振動機を不要とする研究が
始まっている。しかしながら、単純に水や減水剤を添加
して流動性を高めるだけでは材料分離が生じ、粗骨材が
絡み合って充填性が悪くなり、均一なコンクリートが得
られないことから強度低下をきたす。この材料分離を抑
制する目的で水溶性高分子の添加や微粉末の配合が検討
されている。2. Description of the Related Art In recent years,
The concrete industry is said to be the representative of 3K (tight, dirty, dangerous), and among them, the environmental problem with noise is great. Therefore, studies have begun to improve fluidity and eliminate the need for a vibrator. However, simply adding water or a water-reducing agent to increase the fluidity causes material separation, the coarse aggregates are entangled with each other, the filling property is deteriorated, and uniform concrete cannot be obtained, resulting in a decrease in strength. For the purpose of suppressing this material separation, the addition of a water-soluble polymer and the blending of fine powder have been studied.
【0003】しかし、微粉末の添加だけでは流動性と分
離抵抗性を満足することができないことから水溶性高分
子の添加が不可欠となっている (例えば、コンクリート
工学年次論文集, 1989.6、論文No.1118"ハイパフォーマ
ンスコンクリートの開発")。しかしながら、水溶性高分
子は流動性を高める分散剤と併用添加すると、多くの場
合、減水剤と相互作用を起こして流動性の阻害をきたし
やすい。However, addition of a water-soluble polymer is indispensable because flowability and separation resistance cannot be satisfied only by adding fine powder (eg, Concrete Engineering Annual Papers, 1989.6, papers). No.1118 "Development of high performance concrete"). However, when a water-soluble polymer is added together with a dispersant which enhances fluidity, in many cases, it tends to interact with the water-reducing agent to hinder fluidity.
【0004】この阻害原因は解明されていないが、分散
剤と水溶性高分子類、それぞれの組み合わせによって阻
害性の大小がある。従って、これらの影響から目的の粘
性と流動性を確保することが極めて困難な状況となって
いる (例えば、水中コンクリート・マニュアル、昭和62
年12月10日発行、(株)山海堂、P.27, "特殊混和剤と
流動化剤との組み合わせ")。Although the cause of this inhibition has not been clarified, the inhibitory properties are different depending on the combination of the dispersant and the water-soluble polymer. Therefore, it is extremely difficult to secure the desired viscosity and fluidity from these effects (for example, underwater concrete manual, 1987).
, December 10, Sankaido, P.27, "Combination of special admixture and superplasticizer").
【0005】[0005]
【課題を解決するための手段】本発明者らは、鋭意研究
の結果、高性能減水剤とアルキルアミンオキシドとを必
須成分とすることで、コンクリート組成物は従来のよう
な流動性の阻害現象が皆無となり、高流動性と分離抵抗
性に極めて優れた効果が発現することを見出し、本発明
を完成するに至ったものである。Means for Solving the Problems As a result of earnest research, the inventors of the present invention have found that a concrete composition has a conventional fluidity-inhibiting phenomenon by using a superplasticizer and an alkylamine oxide as essential components. Therefore, the present invention has been completed, and it was found that an extremely excellent effect on high fluidity and separation resistance is exhibited, and the present invention has been completed.
【0006】即ち、本発明は、アルキル基が炭素数8〜
22のアルキルアミンオキシドと高性能減水剤とを含有す
るコンクリート組成物においてコンクリートのスランプ
フロー値(JIS-A 1101の測定による拡がり)が50cm以上
であることを特徴とする自己充填性コンクリート組成物
に関する。That is, in the present invention, the alkyl group has 8 to 8 carbon atoms.
Concerning a concrete composition containing 22 alkylamine oxides and a superplasticizer, the slump flow value of the concrete (spreading measured by JIS-A 1101) is 50 cm or more, and relates to a self-compacting concrete composition .
【0007】本発明に使用されるアルキルアミンオキシ
ドは、アルキルジメチルアミンをフェントン試薬あるい
は過酸化水素等で酸化する一般的な製造方法で得ること
ができるものである。The alkylamine oxide used in the present invention can be obtained by a general production method in which alkyldimethylamine is oxidized with Fenton's reagent or hydrogen peroxide.
【0008】また、アルキル基は炭素数8〜22程度が好
ましく、18程度が特に好ましい。8未満では増粘性が低
下傾向を示し、22を超えると水溶性が低下傾向となる。The alkyl group preferably has about 8 to 22 carbon atoms, more preferably about 18 carbon atoms. When it is less than 8, the viscosity increase tends to decrease, and when it exceeds 22, the water solubility tends to decrease.
【0009】本発明に使用する高性能減水剤は、一般に
使用されるコンクリート用混和剤であり、分散剤、流動
化剤、減水剤と呼称されるものであり、特に限定される
ものではない。The high-performance water reducing agent used in the present invention is a commonly used admixture for concrete, which is called a dispersant, a fluidizing agent, or a water reducing agent, and is not particularly limited.
【0010】本発明に好ましく使用される高性能減水剤
としては、ナフタレンスルホン塩ホルムアルデヒド縮合
物(以下、ナフタレン系と称す)、例えば、商品名マイ
テイ150(花王社製) 、メラミンスルホン酸塩ホルムアル
デヒド縮合物(以下、メラミン系と称す)、例えば、商
品名マイテイ150V-2(花王社製)が挙げられる。As the high-performance water reducing agent preferably used in the present invention, a naphthalene sulfone salt formaldehyde condensate (hereinafter referred to as naphthalene type), for example, trade name Mighty 150 (manufactured by Kao Corporation), melamine sulfonate formaldehyde condensation Examples (hereinafter referred to as melamine series), for example, trade name Mighty 150V-2 (manufactured by Kao Corporation).
【0011】更に、高性能減水剤として、フェノール・
アニリンスルホン酸ホルムアルデヒド縮合物(以下、フ
ェノール系と称す)、例えば、商品名パリックFP200 シ
リーズ(藤沢薬品社製)が好ましく使用される。Further, as a high-performance water reducing agent, phenol
Aniline sulfonic acid formaldehyde condensate (hereinafter referred to as phenol type), for example, trade name Palic FP200 series (manufactured by Fujisawa Pharmaceutical Co., Ltd.) is preferably used.
【0012】更に、高性能減水剤として、ポリアルキレ
ングリコールモノ(メタ)アクリル酸エステルと共重合
可能なモノマーとの共重合物、例えば、ポリアルキレン
グリコールモノメタクリル酸エステル・メタクリル酸共
重合物(以下、ポリカル系と称す)である商品名マイテ
イ200WHZ(花王社製)等が使用される。Further, as a high-performance water-reducing agent, a copolymer of a polyalkylene glycol mono (meth) acrylic acid ester and a copolymerizable monomer, for example, a polyalkylene glycol monomethacrylic acid ester / methacrylic acid copolymer (hereinafter , And the product name Mighty 200WHZ (manufactured by Kao Co., Ltd.), etc.
【0013】高性能減水剤とアミンオキシドの添加量
は、水硬性のセメント及び潜在水硬性組成物に対して、
アミンオキシドが0.01〜3.0 重量%、高性能減水剤が
0.1〜3.0 重量%の範囲程度が好ましい。The amount of the superplasticizer and amine oxide added is based on that of the hydraulic cement and the latent hydraulic composition.
0.01 to 3.0% by weight of amine oxide,
A range of 0.1 to 3.0% by weight is preferable.
【0014】本発明の組成物は、セメント及び水硬性組
成物を主原料とするコンクリートが対象となるが、セメ
ントペースト、モルタル等の高流動・不分離性組成物に
も使用が可能である。The composition of the present invention is intended for concrete containing cement and hydraulic composition as main raw materials, but it can also be used for a composition having high fluidity and non-separability such as cement paste and mortar.
【0015】本発明の組成物は、土木、建築、二次製品
等のセメント類の水硬性組成物に使用するもので、特に
限定されるものではない。The composition of the present invention is used for a hydraulic composition of cement such as civil engineering, construction and secondary products, and is not particularly limited.
【0016】本発明の組成物は、公知の添加剤 (材) を
併用添加することができる。例えば、AE剤、AE減水
剤、流動化剤、高性能減水剤、遅延剤、早強剤、促進
剤、起泡剤、発泡剤、保水剤、増粘剤、防水剤、消泡
剤、水溶性高分子、界面活性剤各種等やセメントペース
トモルタル、コンクリートを構成する各種セメント類、
高炉スラグ、フライアッシュ、シリカフューム等を使用
する水硬性組成物が挙げられる。Known additives (materials) can be added to the composition of the present invention in combination. For example, AE agent, AE water reducing agent, superplasticizer, high-performance water reducing agent, retarder, early strengthening agent, accelerator, foaming agent, foaming agent, water retention agent, thickener, waterproofing agent, defoaming agent, water-soluble agent. Polymers, various surfactants, cement paste mortar, various cements that make up concrete,
A hydraulic composition using blast furnace slag, fly ash, silica fume and the like can be mentioned.
【0017】[0017]
【実施例】以下、本発明を具体的に説明するが、本発明
はこれらの実施例に限定されるものではない。尚、以下
の例における「%」は、特にことわりのない限り、「重
量%」である。EXAMPLES The present invention will be specifically described below, but the present invention is not limited to these examples. In addition, "%" in the following examples is "% by weight" unless otherwise specified.
【0018】実施例及び比較例に使用したアルキルアミ
ンオキシドの記号と内容 OA:オクチルアミンオキシド LA:ラウリルアミンオキシド CA:オレイルアミンオキシド BA:ベヘニルアミンオキシド HA:ヘキシルアミンオキシド(比較)比較例に使用した水溶性高分子 MC(メチルセルローズ:CMCダイセル1170:ダイセ
ル社製)実施例及び比較例に使用した高性能減水剤の記号と内容 NS:ナフタレン系(マイテイ150 :花王社製) MS:メラミン系(マイテイ150V-2) PS:フェノール系(パリック200S:藤沢薬品社製) AC:ポリカル系(マイテイ200WHZ:花王社製)コンクリート試験による評価方法 コンクリートの配合条件を表1に示す。 Alkylamis used in Examples and Comparative Examples
Symbols and contents of oxides OA: octylamine oxide LA: laurylamine oxide CA: oleylamine oxide BA: behenylamine oxide HA: hexylamine oxide (comparative) Water-soluble polymer MC (methylcellulose: CMC Daicel 1170: Symbol and content of high-performance water reducing agent used in Examples and Comparative Examples NS: Naphthalene type (Mighty 150: made by Kao) MS: Melamine type (Mighty 150V-2) PS: Phenol type (Palic 200S: Fujisawa Pharmaceutical Co., Ltd. AC: Polycarbonate (Mighty 200WHZ: Kao Co.) Evaluation method by concrete test Mixing conditions of concrete are shown in Table 1.
【0019】[0019]
【表1】 [Table 1]
【0020】表1に示すコンクリート材料を強制二軸ミ
キサー (太平洋機工社製SD-55)で 150秒間混練りしてコ
ンクリートを製造した。流動性が55〜65cm (JIS A-1101
スランプ試験に準ずるフロー値) になるように混和剤の
添加量で調整した。性能評価は以下に示す材料分離抵抗
性と自己充填性の測定により行った。 ・材料分離抵抗性:肉眼判定 ○ − 骨材とセメントペーストの分離なし × − 骨材とセメントペーストの分離あり ・自己充填性:製造したコンクリートをφ10cmの円柱型
枠に投入してバイブレーターを使用しないで詰め、3日
間放置後、脱型してコンクリート表面の状態を肉眼で観
察した。 ○ − 5mm以上の空隙の発生が殆ど見られない。 △ − 5mm以上の空隙の発生が僅かにある。 × − 5mm以上の空隙の発生が多い。The concrete materials shown in Table 1 were kneaded with a forced twin-screw mixer (SD-55 manufactured by Taihei Koki Co., Ltd.) for 150 seconds to produce concrete. Fluidity 55-65 cm (JIS A-1101
It was adjusted by the amount of admixture added so that it would be a flow value according to the slump test). The performance evaluation was performed by measuring the material separation resistance and self-filling property shown below.・ Material separation resistance: macroscopic judgment ○ − No separation of aggregate and cement paste × − There is separation of aggregate and cement paste ・ Self-filling property: Put the manufactured concrete into a cylinder form of φ10 cm without using a vibrator After being left for 3 days, it was demolded and the state of the concrete surface was visually observed. O Almost no void of 5 mm or more was found. △ There are slight voids of 5 mm or more. × − There are many voids of 5 mm or more.
【0021】測定結果を表2に示す。Table 2 shows the measurement results.
【0022】[0022]
【表2】 [Table 2]
【0023】評価結果 表2で明らかなように、本発明の組成物は比較品に比べ
て、材料分離抵抗性が大きく、しかも自己充填性に優れ
る。これらの結果はコンクリートの施工方法が飛躍的に
改善されることを示すものであり、コンクリート構造物
の製造において騒音の解消、製造の合理化への効果が期
待される。 Evaluation Results As is clear from Table 2, the composition of the present invention has a higher resistance to material separation and a higher self-filling property than the comparative product. These results show that the concrete construction method will be dramatically improved, and it is expected to be effective in eliminating noise and rationalizing the production of concrete structures.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 FI 技術表示箇所 C04B 28/02 //(C04B 28/02 18:14 A 14:06 Z 14:02 Z 24:12 24:22) 103:32 111:62 ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification code Office reference number FI technical display location C04B 28/02 // (C04B 28/02 18:14 A 14:06 Z 14:02 Z 24: 12 24:22) 103: 32 111: 62
Claims (5)
ミンオキシドと高性能減水剤とを含有するコンクリート
組成物においてコンクリートのスランプフロー値(JIS-
A 1101の測定による拡がり)が50cm以上であることを特
徴とする自己充填性コンクリート組成物。1. A concrete composition comprising an alkylamine oxide having an alkyl group having 8 to 22 carbon atoms and a high-performance water reducing agent, has a slump flow value (JIS-
A self-compacting concrete composition, characterized in that the spread measured by A 1101) is 50 cm or more.
ホルムアルデヒド縮合物である請求項1記載の自己充填
性コンクリート組成物。2. The self-compacting concrete composition according to claim 1, wherein the superplasticizer is a naphthalene sulfonate formaldehyde condensate.
ルムアルデヒド縮合物である請求項1記載の自己充填性
コンクリート組成物。3. The self-compacting concrete composition according to claim 1, wherein the superplasticizer is a melamine sulfonate formaldehyde condensate.
ルホン酸ホルムアルデヒド縮合物である請求項1記載の
自己充填性コンクリート組成物。4. The self-compacting concrete composition according to claim 1, wherein the superplasticizer is a phenol-anilinesulfonic acid formaldehyde condensate.
ルモノ(メタ)アクリル酸エステルと共重合可能なモノ
マーとの共重合物である請求項1記載の自己充填性コン
クリート組成物。5. The self-compacting concrete composition according to claim 1, wherein the superplasticizer is a copolymer of a polyalkylene glycol mono (meth) acrylic acid ester and a copolymerizable monomer.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP27744494A JP3285457B2 (en) | 1994-11-11 | 1994-11-11 | Self-compacting concrete composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP27744494A JP3285457B2 (en) | 1994-11-11 | 1994-11-11 | Self-compacting concrete composition |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH08133805A true JPH08133805A (en) | 1996-05-28 |
JP3285457B2 JP3285457B2 (en) | 2002-05-27 |
Family
ID=17583665
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP27744494A Expired - Fee Related JP3285457B2 (en) | 1994-11-11 | 1994-11-11 | Self-compacting concrete composition |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP3285457B2 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2020095613A1 (en) | 2018-11-09 | 2020-05-14 | 花王株式会社 | Rheology modifier |
-
1994
- 1994-11-11 JP JP27744494A patent/JP3285457B2/en not_active Expired - Fee Related
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2020095613A1 (en) | 2018-11-09 | 2020-05-14 | 花王株式会社 | Rheology modifier |
Also Published As
Publication number | Publication date |
---|---|
JP3285457B2 (en) | 2002-05-27 |
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