JPH0796454B2 - Method for processing photosensitive glass and ink jet head manufactured by this method - Google Patents

Method for processing photosensitive glass and ink jet head manufactured by this method

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Publication number
JPH0796454B2
JPH0796454B2 JP23978391A JP23978391A JPH0796454B2 JP H0796454 B2 JPH0796454 B2 JP H0796454B2 JP 23978391 A JP23978391 A JP 23978391A JP 23978391 A JP23978391 A JP 23978391A JP H0796454 B2 JPH0796454 B2 JP H0796454B2
Authority
JP
Japan
Prior art keywords
photosensitive glass
glass plate
exposed
groove
jet head
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP23978391A
Other languages
Japanese (ja)
Other versions
JPH0578146A (en
Inventor
宣裕 近藤
Original Assignee
株式会社精工舎
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 株式会社精工舎 filed Critical 株式会社精工舎
Priority to JP23978391A priority Critical patent/JPH0796454B2/en
Publication of JPH0578146A publication Critical patent/JPH0578146A/en
Publication of JPH0796454B2 publication Critical patent/JPH0796454B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Surface Treatment Of Glass (AREA)
  • Glass Compositions (AREA)
  • Particle Formation And Scattering Control In Inkjet Printers (AREA)
  • Micromachines (AREA)

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、感光性ガラス板の表裏
両面に溝をエッチングにより形成する加工方法及びこの
方法によって製造したインクジェットヘッドに関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a processing method for forming grooves on both surfaces of a photosensitive glass plate by etching and an ink jet head manufactured by this method.

【0002】[0002]

【従来の技術】従来よりインクジェットヘッドにはガラ
ス基板が用いられ、このガラス基板にインク射出口,加
圧室,インク溜り,インク供給口などが連通するインク
流路となる溝がエッチングにより形成してある。この様
な溝を設けた基板に振動板を接合し、加圧室に対向する
位置の振動板の表面に圧電素子を接着してヘッドとして
いる。近来ヘッドの小型化と印字品質の向上のために、
多数のインク射出口を備え、インク射出口を複数の列に
配置するものが提案されている。複数の列のインク射出
口に至る各インク流路を、各列で同一の位置に配置する
と、加圧室もほぼ同じ位置に重なった状態になるため
に、1つのインク射出口からのインクの噴出動作が、他
のインク射出口に影響するクロストーク現象を生じやす
い。そこでこれを避けるために、インク射出口を千鳥状
に配列し、加圧室の位置もずらして形成するものが提案
されている。そこでこの様な千鳥状配列のインク射出口
を有するヘッドの従来の加工方法について、図3及び図
4を参照して説明する。
2. Description of the Related Art Conventionally, a glass substrate has been used for an ink jet head, and a groove serving as an ink flow path communicating with an ink ejection port, a pressurizing chamber, an ink reservoir, an ink supply port, etc. is formed on the glass substrate by etching. There is. A vibration plate is bonded to a substrate provided with such grooves, and a piezoelectric element is bonded to the surface of the vibration plate at a position facing the pressure chamber to form a head. For the downsizing of heads and the improvement of printing quality,
It has been proposed to provide a large number of ink ejection openings and arrange the ink ejection openings in a plurality of rows. If the ink flow paths leading to the ink ejection openings of a plurality of rows are arranged at the same position in each row, the pressurizing chambers are also overlapped at substantially the same position. The ejection operation easily causes a crosstalk phenomenon that affects other ink ejection ports. Therefore, in order to avoid this, there has been proposed a method in which the ink ejection ports are arranged in a staggered manner and the positions of the pressure chambers are also shifted. Therefore, a conventional processing method of a head having such staggered ink ejection openings will be described with reference to FIGS. 3 and 4.

【0003】図3の従来例では、中板100の表裏の両
面に、インク射出口が千鳥状配列になるようにインク流
路となる溝100a…,100b…を形成し、この溝を
覆うように中板100の両面に基板101と、基板10
2とを貼着している。
In the conventional example shown in FIG. 3, grooves 100a, 100b, which serve as ink flow paths, are formed on both the front and back surfaces of the intermediate plate 100 so that the ink ejection openings are arranged in a staggered arrangement, and the grooves are covered. The substrate 101 and the substrate 10 are provided on both sides of the intermediate plate 100.
2 and are attached.

【0004】図4の従来例では、基板201と基板20
2とのそれぞれにインク流路となる溝201a…,20
2a…を形成し、中板200の両面に、インク射出口が
千鳥状配列になるように基板201と基板202とを貼
着している。
In the conventional example of FIG. 4, a substrate 201 and a substrate 20
, 20 that serve as ink flow paths in each of the two
2a are formed, and the substrate 201 and the substrate 202 are attached to both surfaces of the intermediate plate 200 so that the ink ejection openings are arranged in a staggered arrangement.

【0005】[0005]

【発明が解決しようとする課題】上記の図3に示す従来
例では、中板100の表裏両面に溝100a,100b
を形成する際に、両溝の位置を精度良く合わせることが
極めて困難である。この相対的位置がずれると高精度の
印字が困難となる。また複雑な流路の形成を容易にする
ために、基板の素材として感光性ガラスを用いる場合に
は、流路となる部分を露光するとき、光が反対側にまで
通過してしまい、表裏に異なる流路を形成することは不
可能である。
In the conventional example shown in FIG. 3, the grooves 100a and 100b are formed on both front and back surfaces of the intermediate plate 100.
It is extremely difficult to accurately align the positions of both grooves when forming the groove. If this relative position shifts, high-precision printing becomes difficult. In addition, in order to facilitate the formation of complicated flow paths, when photosensitive glass is used as the material of the substrate, when the area that becomes the flow paths is exposed, light passes through to the opposite side and It is impossible to form different flow paths.

【0006】上記の図4に示す従来例では、基板201
と基板202とのそれぞれにインク流路となる溝201
a…,202a…を形成しなければならないので、工程
数が多くなり、また中板200に両基板201,202
を貼着する際の位置合わせが難しい。
In the conventional example shown in FIG. 4, the substrate 201 is used.
A groove 201 that serves as an ink flow path in each of the substrate and the substrate 202.
.., 202a ..., the number of steps is increased, and the intermediate plate 200 has both substrates 201, 202.
Positioning is difficult when attaching.

【0007】そこで本発明の目的は、感光性ガラス板の
表裏両面に異なるパターンの溝を容易に形成可能な加工
方法を提供し、インクジェットヘッドを高精度にしかも
安価に提供することにある。
Therefore, an object of the present invention is to provide a processing method capable of easily forming grooves having different patterns on both front and back surfaces of a photosensitive glass plate, and to provide an ink jet head with high accuracy and at low cost.

【0008】[0008]

【課題を解決するための手段】上記目的を達成するため
に、本発明の感光性ガラスの加工方法は、感光性ガラス
板の表裏両面に溝をエッチングにより形成する加工方法
であって、感光性ガラス板の端面側からその板厚を2分
するように露光して光遮断層用露光部を形成し、光遮断
層用露光部を熱処理して感光性ガラス板の板厚方向中間
部に光遮断層を形成し、その後で感光性ガラス板の表面
および裏面側から露光して溝用露光部を形成し、表裏両
面の溝用露光部を熱処理して結晶部を形成し、結晶部を
エッチングすることを特徴としている。
In order to achieve the above object, the method for processing a photosensitive glass of the present invention is a method for forming grooves on both front and back surfaces of a photosensitive glass plate by etching. The glass plate is exposed from the end face side so as to divide the plate thickness into two parts to form a light blocking layer exposure part, and the light blocking layer exposure part is heat-treated to expose light to the middle part of the photosensitive glass plate in the plate thickness direction. After forming the blocking layer, the exposed surface for the groove is formed by exposing from the front and back sides of the photosensitive glass plate, and the exposed portion for the groove on both the front and back surfaces is heat-treated to form the crystal part, and the crystal part is etched. It is characterized by doing.

【0009】また上記の加工方法によって製造したイン
クジェットヘッドは、感光性ガラス板の端面側からその
板厚を2分するように露光した光遮断層用露光部を熱処
理し結晶化してなる光遮断層と、感光性ガラス板を表面
および裏面側から露光した溝用露光部を熱処理しエッチ
ングして形成した感光性ガラス板の表裏両面のインク流
路となる溝部とを有している。
Further, the ink jet head manufactured by the above processing method has a light blocking layer obtained by heat-treating and crystallizing the exposed portion for the light blocking layer exposed from the end face side of the photosensitive glass plate so as to divide the plate thickness into two. And a groove portion which becomes an ink flow path on both front and back surfaces of the photosensitive glass plate, which is formed by heat-treating and etching an exposed portion for the groove, which is obtained by exposing the photosensitive glass plate from the front surface and the back surface side.

【0010】上記の溝部は感光性ガラス板の表裏両面側
で異なる位置に形成しても良い。
The above groove portions may be formed at different positions on both front and back surfaces of the photosensitive glass plate.

【0011】[0011]

【作用】感光性ガラス板の端面側から感光性ガラス板を
露光して、その板厚を2分するように光遮断層を設ける
ので、感光性ガラス板の表面から溝用の露光を行った場
合に、光遮断層でその光が遮断され、裏面側には露光部
を生じないので、裏面から別の溝用の露光を行うことが
できる。
The photosensitive glass plate is exposed from the end face side of the photosensitive glass plate, and the light shielding layer is provided so as to divide the thickness of the photosensitive glass plate into two parts. Therefore, the exposure for the groove is performed from the surface of the photosensitive glass plate. In this case, since the light is blocked by the light blocking layer and no exposed portion is formed on the back surface side, it is possible to perform exposure for another groove from the back surface.

【0012】[0012]

【実施例】図1を参照して本発明の加工工程を説明する
と、まずA工程において、感光性ガラス板1の端面1a
に対向して、フォトマスク2を配置する。フォトマスク
2には感光性ガラス板の板厚を2分するように所定幅の
露光パターン2aと、その両側に遮光部2b,2bとが
形成してある。紫外線をこのフォトマスク2を通過させ
て板厚方向に直交する方向から感光性ガラス板1を露光
すると、感光性ガラス板の板厚方向中間部に露光部が形
成される。
EXAMPLES The processing steps of the present invention will be described with reference to FIG. 1. First, in step A, the end surface 1a of the photosensitive glass plate 1 is processed.
The photomask 2 is arranged so as to face the. The photomask 2 is formed with an exposure pattern 2a having a predetermined width so as to divide the thickness of the photosensitive glass plate into two, and light-shielding portions 2b and 2b on both sides thereof. When the photosensitive glass plate 1 is exposed in the direction perpendicular to the plate thickness direction by passing ultraviolet rays through the photomask 2, an exposed portion is formed in the middle part of the photosensitive glass plate in the plate thickness direction.

【0013】次にB工程において、この露光部を熱処理
して、結晶部である光遮断層11を形成する。これは露
光部を結晶化すると結晶部は着色して紫外線を通さなく
なるので、これを光遮断層とし、板厚を2分するのに用
いたものである。
Next, in step B, the exposed portion is heat-treated to form the light blocking layer 11 which is a crystal portion. This is because when the exposed part is crystallized, the crystal part is colored and does not allow passage of ultraviolet rays, so this is used as a light blocking layer to divide the plate thickness into two.

【0014】その後でC工程において、感光性ガラス板
1の表面1bに対向して、フォトマスク3を配置する。
フォトマスク3には、感光性ガラス板1の表面に形成す
る溝4、この例では図2に示すインクジェットヘッド1
0のインク射出口4a,図示しない加圧室,インク溜
り,インク供給口などを連通するインク流路となるため
の溝4の露光パターン3aと、その周囲に遮光部3bと
が形成してある。このフォトマスク3の露光パターン3
aは、反転することによりインク射出口4aが反ピッチ
ずれた位置に来るように形成してあるので、裏面の露光
に使用することもできる。紫外線をこのフォトマスク3
を通過させて表面1bに直交する方向から感光性ガラス
板1を露光すると、感光性ガラス板の表面1bに溝4の
露光部が形成される。先に説明したように、光遮断層1
1が板厚を2分しているので、表面1b側からの紫外線
は感光性ガラス板1の表面側の半分の深さで止まり、裏
面側を露光することはない。そこで感光性ガラス板1を
反転させ、裏面1cを紫外線の照射側に向け、再び上記
のフォトマスク3を通過させて上記と同様に裏面1cに
溝4の露光部を形成する。この場合にも裏面1c側から
の紫外線は感光性ガラス板1の裏面側の半分の深さで止
まり、表面側を露光することはない。
After that, in step C, the photomask 3 is arranged so as to face the surface 1b of the photosensitive glass plate 1.
The photomask 3 has grooves 4 formed on the surface of the photosensitive glass plate 1, and the inkjet head 1 shown in FIG. 2 in this example.
An exposure pattern 3a of a groove 4 for forming an ink flow path communicating with the ink ejection port 4a of 0, a pressure chamber (not shown), an ink reservoir, an ink supply port, and the like, and a light shielding portion 3b are formed around the exposure pattern 3a. . Exposure pattern 3 of this photomask 3
Since a is formed so that the ink ejection port 4a is located at a position displaced from the opposite pitch by reversing, it can also be used for back surface exposure. UV this photo mask 3
When the photosensitive glass plate 1 is exposed in the direction orthogonal to the surface 1b by passing through, the exposed portion of the groove 4 is formed on the surface 1b of the photosensitive glass plate. As described above, the light blocking layer 1
Since 1 divides the plate thickness into two, ultraviolet rays from the front surface 1b side stop at a depth of half of the front surface side of the photosensitive glass plate 1, and the back surface side is not exposed. Then, the photosensitive glass plate 1 is turned over, the back surface 1c is directed to the irradiation side of ultraviolet rays, and the photomask 3 is passed again to form the exposed portion of the groove 4 on the back surface 1c in the same manner as above. Also in this case, the ultraviolet rays from the back surface 1c side stop at a depth of half of the back surface side of the photosensitive glass plate 1, and the front surface side is not exposed.

【0015】D工程において、露光部を熱処理して結晶
部12…を形成する。図1(E)はこの状態をインク射
出口が整列すべき正面側から見たものである。
In step D, the exposed portions are heat-treated to form crystal portions 12 ... FIG. 1E shows this state from the front side where the ink ejection ports should be aligned.

【0016】最後にF工程において、エッチング処理に
より結晶部12…を所望の深さまでエッチングし、感光
性ガラス板1の表面1b及び裏面1cにインク流路とな
る溝4…を形成する。
Finally, in the step F, the crystal parts 12 are etched to a desired depth by an etching process to form grooves 4 on the front surface 1b and the back surface 1c of the photosensitive glass plate 1 as ink flow paths.

【0017】このようにして加工された感光性ガラス板
をインクジェットヘッド10の流路基板として用い、図
2に示すように溝4…が形成されている表裏両面に振動
板5,5を接合し、この振動板5,5の表面であって各
溝の加圧室に対向する位置に圧電素子6…を接着するこ
とによって、インクジェットヘッド10が形成できる。
The photosensitive glass plate thus processed is used as the flow path substrate of the ink jet head 10, and the vibrating plates 5 and 5 are bonded to both front and back surfaces in which the grooves 4 are formed as shown in FIG. The ink jet head 10 can be formed by adhering the piezoelectric elements 6 on the surfaces of the vibrating plates 5 and 5 in the positions facing the pressure chambers of the grooves.

【0018】上記の加工工程では、表面側を露光した後
で裏面側を露光するように説明しているが、表裏両面に
溝部が異なる位置に形成されるような露光パターンを設
けてあるそれぞれのフォトマスクを配設し、両面の露光
を同時に行っても良い。
In the above-mentioned processing steps, the back side is exposed after the front side is exposed. However, each of the front and back surfaces is provided with an exposure pattern such that grooves are formed at different positions. A photomask may be provided and both surfaces may be exposed at the same time.

【0019】また光遮断層は板厚方向に直交するように
形成されたものに限られず、傾斜していても良く、この
光遮断層によって感光性ガラス板の板厚が2分され、そ
の両側でそれぞれ別の露光パターンによる露光が可能で
あればよい。
Further, the light blocking layer is not limited to the one formed so as to be orthogonal to the plate thickness direction, and may be inclined, and the light blocking layer divides the plate thickness of the photosensitive glass plate into two parts, and the both sides thereof. It suffices that exposure with different exposure patterns can be performed.

【0020】なお、本発明の感光性ガラスの加工方法
は、インクジェットヘッドの基板の加工に限られず、マ
イクロマシーンの極微小部品の加工その他種々の感光性
ガラスの加工に適用可能である。
The method of processing the photosensitive glass of the present invention is not limited to the processing of the substrate of the ink jet head, and can be applied to the processing of microscopic parts of micromachines and various other processing of photosensitive glass.

【0021】[0021]

【発明の効果】以上に説明したように、本発明の感光性
ガラスの加工方法では、板厚を2分するように露光し熱
処理し結晶化して光遮断層を形成するので、感光性ガラ
スの表裏両面から露光しても、この光遮断層によって遮
断されて相互に反対側を露光することがなく、両面に別
々の露光を行って非対象の溝を形成することができる。
As described above, in the method for processing the photosensitive glass of the present invention, the light-shielding layer is formed by exposing and heat-treating so as to divide the plate thickness into two, and thus forming the light-shielding layer. Even when the light is exposed from both the front and back sides, the asymmetric grooves can be formed by separately exposing the both sides without being blocked by the light blocking layer and exposing the opposite sides.

【0022】この溝は露光時に用いられるマスクによっ
てその位置が定められるので、位置精度を出すことが容
易である。また加工工程が少ないので加工が容易であ
り、低コスト化が達成できる。
Since the position of this groove is determined by the mask used during exposure, it is easy to obtain positional accuracy. Further, since the number of processing steps is small, the processing is easy and the cost can be reduced.

【0023】更にこの方法によって製造されたインクジ
ェットヘッドは、流路基板の両面にインク流路である溝
が形成してあり、かつ高精度に所望の位置にインク射出
口を整列させることができるので、インク射出口の高密
度化が可能で、ヘッドの小型化が達成でき、しかもクロ
ストークを防止でき、印字品質の向上に有効である。
Further, in the ink jet head manufactured by this method, grooves which are ink flow paths are formed on both surfaces of the flow path substrate, and the ink ejection ports can be aligned at desired positions with high accuracy. In addition, the density of the ink ejection port can be increased, the size of the head can be reduced, and crosstalk can be prevented, which is effective in improving print quality.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の加工方法の加工工程を示す説明図であ
る。
FIG. 1 is an explanatory view showing a processing step of a processing method of the present invention.

【図2】本発明のインクジェットヘッドの拡大正面図で
ある。
FIG. 2 is an enlarged front view of the inkjet head of the present invention.

【図3】従来の加工方法を説明する正面図である。FIG. 3 is a front view illustrating a conventional processing method.

【図4】従来の他の加工方法を説明する正面図である。FIG. 4 is a front view illustrating another conventional processing method.

【符号の説明】[Explanation of symbols]

1 感光性ガラス板 1a 端面 1b 表面 1c 裏面 4 溝部 10 インクジェットヘッド 11 光遮断層 12 結晶部 DESCRIPTION OF SYMBOLS 1 Photosensitive glass plate 1a End surface 1b Front surface 1c Back surface 4 Groove portion 10 Inkjet head 11 Light blocking layer 12 Crystal portion

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】 感光性ガラス板の表裏両面に溝をエッチ
ングにより形成する加工方法であって、 上記感光性ガラス板の端面側からその板厚を2分するよ
うに露光して光遮断層用露光部を形成し、 上記光遮断層用露光部を熱処理して上記感光性ガラス板
の板厚方向中間部に光遮断層を形成し、 その後で上記感光性ガラス板の表面および裏面側から露
光して溝用露光部を形成し、 上記表裏両面の溝用露光部を熱処理して結晶部を形成
し、 上記結晶部をエッチングすることを特徴とする感光性ガ
ラスの加工方法。
1. A processing method for forming a groove on both the front and back surfaces of a photosensitive glass plate by etching, which comprises exposing the photosensitive glass plate from the end face side so as to divide the plate thickness into two, and for the light blocking layer. An exposed portion is formed, and the exposed portion for the light blocking layer is heat-treated to form a light blocking layer at an intermediate portion in the plate thickness direction of the photosensitive glass plate, and then exposed from the front surface and the back surface side of the photosensitive glass plate. Then, the groove exposed portion is formed, the groove exposed portions on both front and back surfaces are heat treated to form a crystal portion, and the crystal portion is etched.
【請求項2】 感光性ガラス板の端面側からその板厚を
2分するように露光した光遮断層用露光部を熱処理し結
晶化してなる光遮断層と、 上記感光性ガラス板を表面および裏面側から露光した溝
用露光部を熱処理しエッチングして形成した上記感光性
ガラス板の表裏両面のインク流路となる溝部とを有する
ことを特徴とするインクジェットヘッド。
2. A light-shielding layer formed by heat-treating and crystallizing an exposed portion for a light-shielding layer exposed from the end face side of the photosensitive glass plate so as to divide the thickness thereof into two, and the photosensitive glass plate on the surface and An ink jet head, comprising: a groove portion which becomes an ink flow path on both front and back surfaces of the photosensitive glass plate formed by heat-treating and etching the groove exposed portion exposed from the back surface side.
【請求項3】 請求項2において、上記溝部は上記感光
性ガラス板の表裏両面側で異なる位置に形成されている
ことを特徴とするインクジェットヘッド。
3. The ink jet head according to claim 2, wherein the groove portions are formed at different positions on both front and back surfaces of the photosensitive glass plate.
JP23978391A 1991-09-19 1991-09-19 Method for processing photosensitive glass and ink jet head manufactured by this method Expired - Fee Related JPH0796454B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP23978391A JPH0796454B2 (en) 1991-09-19 1991-09-19 Method for processing photosensitive glass and ink jet head manufactured by this method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP23978391A JPH0796454B2 (en) 1991-09-19 1991-09-19 Method for processing photosensitive glass and ink jet head manufactured by this method

Publications (2)

Publication Number Publication Date
JPH0578146A JPH0578146A (en) 1993-03-30
JPH0796454B2 true JPH0796454B2 (en) 1995-10-18

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ID=17049824

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Cited By (7)

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US9067268B2 (en) 2009-08-14 2015-06-30 Saint-Gobain Abrasives, Inc. Abrasive articles including abrasive particles bonded to an elongated body
US9211634B2 (en) 2011-09-29 2015-12-15 Saint-Gobain Abrasives, Inc. Abrasive articles including abrasive particles bonded to an elongated substrate body having a barrier layer, and methods of forming thereof
US9248583B2 (en) 2010-12-30 2016-02-02 Saint-Gobain Abrasives, Inc. Abrasive article and method of forming
US9254552B2 (en) 2012-06-29 2016-02-09 Saint-Gobain Abrasives, Inc. Abrasive article and method of forming
US9278429B2 (en) 2012-06-29 2016-03-08 Saint-Gobain Abrasives, Inc. Abrasive article for abrading and sawing through workpieces and method of forming
US9375826B2 (en) 2011-09-16 2016-06-28 Saint-Gobain Abrasives, Inc. Abrasive article and method of forming
US9409243B2 (en) 2013-04-19 2016-08-09 Saint-Gobain Abrasives, Inc. Abrasive article and method of forming

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9067268B2 (en) 2009-08-14 2015-06-30 Saint-Gobain Abrasives, Inc. Abrasive articles including abrasive particles bonded to an elongated body
US9248583B2 (en) 2010-12-30 2016-02-02 Saint-Gobain Abrasives, Inc. Abrasive article and method of forming
US9375826B2 (en) 2011-09-16 2016-06-28 Saint-Gobain Abrasives, Inc. Abrasive article and method of forming
US9211634B2 (en) 2011-09-29 2015-12-15 Saint-Gobain Abrasives, Inc. Abrasive articles including abrasive particles bonded to an elongated substrate body having a barrier layer, and methods of forming thereof
US9254552B2 (en) 2012-06-29 2016-02-09 Saint-Gobain Abrasives, Inc. Abrasive article and method of forming
US9278429B2 (en) 2012-06-29 2016-03-08 Saint-Gobain Abrasives, Inc. Abrasive article for abrading and sawing through workpieces and method of forming
US9409243B2 (en) 2013-04-19 2016-08-09 Saint-Gobain Abrasives, Inc. Abrasive article and method of forming

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