JPH0794620B2 - Anti-slip coating composition - Google Patents
Anti-slip coating compositionInfo
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- JPH0794620B2 JPH0794620B2 JP20884991A JP20884991A JPH0794620B2 JP H0794620 B2 JPH0794620 B2 JP H0794620B2 JP 20884991 A JP20884991 A JP 20884991A JP 20884991 A JP20884991 A JP 20884991A JP H0794620 B2 JPH0794620 B2 JP H0794620B2
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Description
【０００１】[0001]
【産業上の利用分野】本発明は段ボ−ル等の表面に塗工
して用いられる防滑性塗料組成物に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an anti-slip coating composition which is used by coating on the surface of corrugated ball or the like.
【０００２】[0002]
【従来の技術】パレット等に積まれた段ボ−ル箱の荷崩
れを防止する方法としては、紐やバンドで縛ったり、
シュリンクフイルムやストレッチフィルムで覆ったりす
る機械的方法、上下の箱をホットメルト接着剤で点接
着する方法、箱の表面に防滑剤を塗布する方法等が知
られている。しかし、の方法は荷造り・荷解きの作業
が煩雑であり、の方法は接着剤の跡が箱の表面に残
り、美観を著しく損う不都合がある。こうした事情か
ら、現在ではの方法が最も広く採用され、なかでも段
ボ−ルシ−トを形成する前の、例えばライナ−原紙の印
刷工程で、防滑剤を塗工する、いわゆるプレプリント方
式が注目されている。2. Description of the Related Art As a method for preventing the collapse of cargo boxes stacked on a pallet or the like, tie them with strings or bands,
Known methods include a mechanical method of covering with a shrink film or a stretch film, a method of spot-bonding upper and lower boxes with a hot-melt adhesive, and a method of applying an anti-slip agent on the surfaces of the boxes. However, the method of (1) is complicated in packing and unpacking work, and the method of (1) has a disadvantage that the traces of the adhesive remain on the surface of the box, and the appearance is significantly impaired. Under these circumstances, the present method is most widely adopted, and among them, the so-called preprinting method in which the anti-slip agent is applied in the printing process of the liner base paper before forming the corrugated ball sheet, for example, attracts attention. Has been done.
【０００３】プレプリント方式に使用される従来の防滑
剤の一つとして、コロイダルシリカとアクリル共重合体
とからなる防滑性塗料組成物が、特開平１−３０８７４
８号公報に提案されている。しかし、この防滑性塗料組
成物にあっては、コロイダルシリカ粒子が、その表面を
アクリル共重合体で被覆されている関係で、ガラス転移
温度が０℃以下のアクリル共重合体を使用した場合に
は、耐ブロッキング性が必ずしも充分でない欠点があ
る。As one of the conventional anti-slip agents used in the preprint system, an anti-slip coating composition comprising colloidal silica and an acrylic copolymer is disclosed in JP-A-1-30874.
It is proposed in Japanese Patent No. However, in this anti-slip coating composition, the colloidal silica particles have a surface covered with an acrylic copolymer, and therefore, when an acrylic copolymer having a glass transition temperature of 0 ° C. or lower is used. Has the drawback that the blocking resistance is not always sufficient.
【０００４】[0004]
【発明が解決しようとする課題】本発明はガラス転移温
度が０℃以下である重合体の水分散液と、シリカ粒子と
の混合物からなる防滑性塗料組成物の防滑性能を低下さ
せることなく、耐ブロッキング性を向上させることを目
的とする。DISCLOSURE OF THE INVENTION According to the present invention, an anti-slip coating composition comprising a mixture of an aqueous dispersion of a polymer having a glass transition temperature of 0 ° C. or lower and silica particles can be used without lowering the anti-slip performance. The purpose is to improve blocking resistance.
【０００５】[0005]
【課題を解決するための手段】本発明は上記の課題を解
決するための手段として、以下の構成をとる。すなわ
ち、本発明の防滑性塗料組成物は、重合体の水分散液と
シリカ粒子との混合物からなり、シリカ粒子が固形分中
の３５〜５０重量％を占め、シリカ粒子の粒径が５〜５
０ミリミクロンの範囲にあり、かつ、重合体水分散液は
ビニルアルコキシシラン又はビニル−トリス（β−メト
キシエトキシ）シランと、これと共重合可能な他のビニ
ルモノマーとから製造され、しかもガラス転移温度が０
℃以下である共重合体を含有することを特徴とする。本
発明の組成物に於いては、シリカ粒子が共重合体粒子の
表面にに配位した状態にある。The present invention has the following constitutions as means for solving the above problems. That is, the anti-slip coating composition of the present invention comprises a mixture of an aqueous dispersion of a polymer and silica particles, the silica particles occupy 35 to 50% by weight of the solid content, and the particle size of the silica particles is 5 to 5. 5
It is in the range of 0 millimicron, and the polymer aqueous dispersion is vinylalkoxysilane or vinyltris (β-meth).
(Xyethoxy) silane and another vinyl monomer copolymerizable therewith , and having a glass transition temperature of 0.
It is characterized by containing a copolymer having a temperature of not higher than 0 ° C. In the composition of the present invention, silica particles are in a state of being coordinated with the surface of the copolymer particles.
【０００６】本発明で使用する共重合体は、ガラス転移
温度が０℃以下であって、ビニルアコキシシラン又はビ
ニル−トリス（β−メトキシエトキシ）シランと、これ
と共重合可能な他のビニルモノマーとから製造される。
ビニルアコキシシランとしては、ビニルトリエトキシシ
ラン等が使用可能であり、他のビニルモノマーとして
は、例えば、エチルアクリレート、ブチルアクリレー
ト、イソプロピルアクリレート、２−エチルヘキシルア
クリレート、ヒドロキシエチルアクリレート等のアクリ
ル酸エステルを使用することができる。本発明の共重合
体を製造するに当っては、ビニルアルコキシシラン又は
ビニル−トリス（β−メトキシエトキシ）シランを０．
５〜５重量％の範囲で、他のビニルモノマーを９５〜９
９．５重量％の範囲で使用することが好ましい。こうし
て得られる共重合体は、本発明の塗料組成物に於いて、
０．０５〜１ミクロンの粒子として存在する。尚、本発
明の塗料組成物には、所望ならば、スチレン・ブタジエ
ン共重合体、エチレン・酢酸ビニル共重合体等を、本発
明の共重合体と併用することもできる。[0006] The present invention copolymer to be used, the glass transition temperature is not more 0 ℃ less, Binirua Kokishishiran or bi
It is prepared from nyl-tris (β-methoxyethoxy) silane and another vinyl monomer copolymerizable therewith.
The vinyl Ako silane, a vinyl triethoxysilane shea <br/> run-like can be used as the other vinyl monomers, for example, ethyl acrylate, butyl acrylate, isopropyl acrylate, 2-ethylhexyl acrylate, hydroxyethyl acrylate Acrylic esters such as The hitting To prepare the copolymers of the present invention, vinylalcohol Kishishiran or
Vinyl-tris (β-methoxyethoxy) silane was added to 0.
In the range of 5 to 5% by weight , 95 to 9 other vinyl monomers
It is preferably used in the range of 9.5% by weight . The copolymer thus obtained, in the coating composition of the present invention,
Present as particles of 0.05 to 1 micron. In the coating composition of the present invention, if desired, a styrene / butadiene copolymer, an ethylene / vinyl acetate copolymer or the like may be used in combination with the copolymer of the present invention.
【０００７】本発明で使用するシリカ粒子は、その粒径
が５〜５０ミリミクロンと、共重合体粒子より小さい。
このような微細なシリカ粒子を使用することにより、本
発明では共重合体粒子がシリカと親和性の高いビニルア
ルコキシシラン又はビニル−トリス（β−メトキシエト
キシ）シラン成分を含んでいることと相俟って、液中に
分散する共重合体粒子を取囲むよう、シリカ粒子を配位
させることができ、その結果として、優れたブロッキン
グ防止性能を発揮させることができる。シリカ粒子の使
用量は、全固形分の３５〜５０重量％の範囲で選ばれ
る。シリカ粒子で共重合体粒子を取囲んでブロッキング
防止性能を発揮させるためには、全固形分中の３５重量
％以上に相当するシリカ粒子が存在することが必要であ
るが、過剰に存在すると、共重合体と紙及び共重合体同
志の接着力を弱めたり、塗膜からシリカ粒子が剥落し易
くなり、耐摩耗性が低下するので、シリカ粒子配合量の
上限は、全固形分中の５０重量％とすることが適当であ
る。The silica particles used in the present invention have a particle size of 5 to 50 mm, which is smaller than that of the copolymer particles.
By using such fine silica particles, in the present invention, the copolymer particles have a high affinity with silica such as vinylalkoxysilane or vinyltris (β-methoxyethoxide).
X) Silica particles can be coordinated so as to surround the copolymer particles dispersed in the liquid in combination with the inclusion of the silane component, and as a result, excellent blocking prevention performance is exhibited. Can be made. The amount of silica particles used is selected in the range of 35 to 50% by weight of the total solid content. In order to surround the copolymer particles with silica particles and exert the anti-blocking performance, it is necessary that silica particles corresponding to 35% by weight or more of the total solid content be present, but if they are present in excess, It weakens the adhesive strength between the copolymer and the paper and the copolymers, and silica particles are easily peeled off from the coating film.
Kuna is, since the wear resistance is lowered, the upper limit of the silica particles amount, it is appropriate to 50% by weight of the total solids.
【０００８】[0008]
【実施例】実施例１ スチレン４３重量部と、アクリル酸２−エチルヘキシル
５７重量部と、ＮＵＣシリコーンＡ−１７２（日本ユニ
カー（株）社製のビニル−トリス（β−メトキシエトキ
シ）シラン）１重量部からなる共重合成分を、４０〜８
０℃で８時間加熱重合して得た共重合体エマルジョン
（固形分５０％、粒径０．１２ミクロン、Ｔｇ＝−２０
℃）１００重量部に、シリカの水分散液（粒径２０ミリ
ミクロン、固形分３０％）１２０重量部を、緩かに加え
て充分混合し、個々の共重合体粒子の周囲にシリカ粒子
が配位した実施例１の塗料組成物を得た。Example 1 43 parts by weight of styrene, 57 parts by weight of 2-ethylhexyl acrylate , NUC Silicone A-172 (Vinyl-tris (β-methoxyethoxy) silane manufactured by Nippon Unicar Co., Ltd.) 1 40 to 8 parts by weight of the copolymerization component
Copolymer emulsion obtained by heat polymerization at 0 ° C. for 8 hours (solid content 50%, particle size 0.12 micron, Tg = −20
C.) 120 parts by weight of an aqueous dispersion of silica (particle size: 20 mm, solid content: 30%) is slowly added to 100 parts by weight of the mixture and thoroughly mixed to form silica particles around the individual copolymer particles. The coordinated coating composition of Example 1 was obtained.
【０００９】実施例２ 実施例１で得た共重合体エマルジョンと同一の共重合体
エマルジョン１００重量部に、シリカの水分散液（粒径
５０ミリミクロン、固形分５０％）１２５重量部を、緩
かに加えて充分混合し、個々の共重合体粒子の周囲にシ
リカ粒子が配位した実施例２の塗料組成物を得た。Example 2 To 100 parts by weight of the same copolymer emulsion as the copolymer emulsion obtained in Example 1, 125 parts by weight of an aqueous dispersion of silica (particle size: 50 mm, solid content: 50%) was added. The coating composition of Example 2 in which silica particles were coordinated around individual copolymer particles was obtained by slowly adding and thoroughly mixing.
【００１０】実施例３ 実施例１で得た共重合体エマルジョンと同一の共重合体
エマルジョン１００重量部に、シリカの水分散液（粒径
５ミリミクロン、固形分２０％）１３５重量部を、緩か
に加えて充分混合し、個々の共重合体粒子の周囲にシリ
カ粒子が配位した実施例３の塗料組成物を得た。Example 3 To 100 parts by weight of the same copolymer emulsion as the copolymer emulsion obtained in Example 1, 135 parts by weight of an aqueous dispersion of silica (particle size 5 mm, solid content 20%) was added. The coating composition of Example 3 in which silica particles were coordinated around individual copolymer particles was obtained by slowly adding and thoroughly mixing.
【００１１】比較例１ 実施例１で得た共重合体エマルジョンと同一の共重合体
エマルジョン１００重量部に、シリカの水分散液（粒径
６０ミリミクロン、固形分４０％）９０重量部を、緩か
に加えて充分混合し、個々の共重合体粒子の周囲にシリ
カ粒子が配位した比較例１の塗料組成物を得た。Comparative Example 1 To 100 parts by weight of the same copolymer emulsion as the copolymer emulsion obtained in Example 1, 90 parts by weight of an aqueous dispersion of silica (particle size: 60 mm, solid content: 40%) was added. The coating composition of Comparative Example 1 in which silica particles were coordinated around individual copolymer particles was obtained by slowly adding and thoroughly mixing.
【００１２】比較例２ 実施例１で得た共重合体エマルジョンと同一の共重合体
エマルジョン１００重量部に、シリカの水分散液（粒径
２０ミリミクロン、固形分５０％）７１重量部を、緩か
に加えて充分混合し、個々の共重合体粒子の周囲にシリ
カ粒子が配位した比較例１の塗料組成物を得た。Comparative Example 2 To 100 parts by weight of the same copolymer emulsion as that obtained in Example 1, 71 parts by weight of an aqueous dispersion of silica (particle size: 20 mm, solid content: 50%) was added. The coating composition of Comparative Example 1 in which silica particles were coordinated around individual copolymer particles was obtained by slowly adding and thoroughly mixing.
【００１３】実施例４ スチレン５６重量部と、アクリル酸２−エチルヘキシル
４４重量部と、ＮＵＣシリコーンＡ−１７２（日本ユニ
カー（株）社製のビニル−トリス（β−メトキシエトキ
シ）シラン）１重量部からなる共重合成分を、４０〜８
０℃で８時間加熱重合して得た共重合体エマルジョン
（固形分５０％、粒径０．１２ミクロン、Ｔｇ＝０℃）
１００重量部に、シリカの水分散液（粒径２０ミリミク
ロン、固形分３０％）１２０重量部を、緩かに加えて充
分混合し、個々の共重合体粒子の周囲にシリカ粒子が配
位した実施例４の塗料組成物を得た。[0013] Example 4 Styrene 56 parts by weight, and 2-ethylhexyl 44 parts by weight of acrylic acid, N UC Silicone A-172 (vinyl Nippon Unicar Co., Ltd. - tris (beta-methoxyethoxy) silane) 1 wt 40 to 8 parts of the copolymerization component
Copolymer emulsion obtained by heat-polymerizing at 0 ° C. for 8 hours (solid content 50%, particle size 0.12 micron, Tg = 0 ° C.)
To 100 parts by weight, 120 parts by weight of an aqueous dispersion of silica (particle size: 20 mm, solid content: 30%) is slowly added and mixed well, and the silica particles are coordinated around each copolymer particle. The coating composition of Example 4 was obtained.
【００１４】比較例３ スチレン６２重量部と、アクリル酸２−エチルヘキシル
３８重量部と、ＮＵＣシリコーンＡ−１７２（日本ユニ
カー（株）社製のビニル−トリス（β−メトキシエトキ
シ）シラン）１重量部からなる共重合成分を、４０〜８
０℃で８時間加熱重合して得た共重合体エマルジョン
（固形分５０％、粒径０．１２ミクロン、Ｔｇ＝１０
℃）１００重量部に、シリカの水分散液（粒径２０ミリ
ミクロン、固形分３０％）１２０重量部を、緩かに加え
て充分混合し、個々の共重合体粒子の周囲にシリカ粒子
が配位した比較例３の塗料組成物を得た。[0014] Comparative Example 3 Styrene 62 parts by weight, and 2-ethylhexyl 38 parts by weight of acrylic acid, N UC Silicone A-172 (vinyl Nippon Unicar Co., Ltd. - tris (beta-methoxyethoxy) silane) 1 wt 40 to 8 parts of the copolymerization component
Copolymer emulsion obtained by heat polymerization at 0 ° C. for 8 hours (solid content 50%, particle size 0.12 micron, Tg = 10
C.) 120 parts by weight of an aqueous dispersion of silica (particle size: 20 mm, solid content: 30%) is slowly added to 100 parts by weight of the mixture and thoroughly mixed to form silica particles around the individual copolymer particles. A coordinated coating composition of Comparative Example 3 was obtained.
【００１５】実施例５ スチレン４３重量部と、アクリル酸２−エチルヘキシル
５７重量部と、ＮＵＣシリコーンＡ−１７２（日本ユニ
カー（株）社製のビニル−トリス（β−メトキシエトキ
シ）シラン）０．５重量部からなる共重合成分を、４０
〜８０℃で８時間加熱重合して得た共重合体エマルジョ
ン（固形分５０％、粒径０．１２ミクロン、Ｔｇ＝−２
０℃）１００重量部に、シリカの水分散液（粒径２０ミ
リミクロン、固形分３０％）１２０重量部を、緩かに加
えて充分混合し、個々の共重合体粒子の周囲にシリカ粒
子が配位した実施例５の塗料組成物を得た。Example 5 43 parts by weight of styrene, 57 parts by weight of 2-ethylhexyl acrylate , NUC Silicone A-172 (vinyl-tris (β-methoxyethoxy) silane manufactured by Nippon Unicar Co., Ltd.) 40 parts by weight of the copolymerization component consisting of 5 parts by weight
Copolymer emulsion obtained by heat polymerization at -80 ° C for 8 hours (solid content 50%, particle size 0.12 micron, Tg = -2
120 parts by weight of an aqueous dispersion of silica (particle size: 20 mm, solid content: 30%) was slowly added to 100 parts by weight (0 ° C.) and sufficiently mixed to form silica particles around each copolymer particle. A coating composition of Example 5 coordinated with was obtained.
【００１６】実施例６ スチレン４３重量部と、アクリル酸２−エチルヘキシル
５７重量部と、ＮＵＣシリコーンＡ−１７２（日本ユニ
カー（株）社製のビニル−トリス（β−メトキシエトキ
シ）シラン）０．３重量部からなる共重合成分を、４０
〜８０℃で８時間加熱重合して得た共重合体エマルジョ
ン（固形分５０％、粒径０．１２ミクロン、Ｔｇ＝−２
０℃）１００重量部に、シリカの水分散液（粒径２０ミ
リミクロン、固形分３０％）１２０重量部を、緩かに加
えて充分混合し、個々の共重合体粒子の周囲にシリカ粒
子が配位した比較例４の塗料組成物を得た。Example 6 43 parts by weight of styrene, 57 parts by weight of 2-ethylhexyl acrylate , NUC Silicone A-172 (vinyl-tris (β-methoxyethoxy) silane manufactured by Nippon Unicar Co., Ltd.) 40 parts by weight of the copolymerization component consisting of 3 parts by weight.
Copolymer emulsion obtained by heat polymerization at -80 ° C for 8 hours (solid content 50%, particle size 0.12 micron, Tg = -2
120 parts by weight of an aqueous dispersion of silica (particle size: 20 mm, solid content: 30%) was slowly added to 100 parts by weight (0 ° C.) and sufficiently mixed to form silica particles around each copolymer particle. A coating composition of Comparative Example 4 coordinated with was obtained.
【００１７】上記の実施例及び比較例で得た各塗料組成
物を、それぞれ段ボ−ル用ラインシ−ト（本州製紙
（株）社製ＲＫ２８０）に、固形分塗布量が２ｇ／ｍ2
になるように塗布して乾燥し、テストシ−トを得た。こ
のテストシ−トを用いて次の方法により、防滑性、耐ブ
ロッキング性及び耐汚れ適性を評価した。結果を表１に
示す。Each coating composition obtained in the above Examples and Comparative Examples was applied to a line sheet for corrugated ball (RK280 manufactured by Honshu Paper Co., Ltd.) at a solid coating amount of 2 g / m 2.
To obtain a test sheet. Using this test sheet, the slip resistance, blocking resistance and stain resistance were evaluated by the following methods. The results are shown in Table 1.
【００１８】防滑性 温度及び湿度が設定条件（２０℃で６０％、０℃で６０
％）になるように設定された恒温恒湿室内で、ＪＩＳ
Ｐ８１４７の方法により滑り角度を測定した。耐ブロッキング性 シ−トを５ｃｍ角に切り、その２枚を塗布面同志が対向
するように重ね合わせこれを２ｋｇ／ｃｍ2 の圧力で２
４時間圧縮後、２枚のシ−トを手で剥がしてブロッキン
グ状態を判定した。優を◎印で、良を○印で示す。耐摩耗性 ２５℃、６０％ＲＨの条件にて、上記の防滑性評価と同
様な方法で滑り角度を１０回繰り返して測定し、１０回
目の測定値が１回目の測定値より５％以上低下しものを
×、５％未満ではあるが低下したものを△、低下しなか
ったものを○で評価した。 Anti-slip temperature and humidity are set under the set conditions (60% at 20 ° C, 60% at 0 ° C).
%) In a constant temperature and humidity room set to
The sliding angle was measured by the method of P8147. Blocking resistance sheet - off bets to 5cm square, 2 this overlapped as two thereof coated surface comrades opposed at a pressure of 2 kg / cm 2
After compression for 4 hours, the two sheets were peeled off by hand to determine the blocking state. Excellent is indicated by ◎ and good is indicated by ○. Under the conditions of abrasion resistance of 25 ° C. and 60% RH, the sliding angle was measured 10 times by the same method as in the above evaluation of the slip resistance, and the measured value at the 10th time was decreased by 5% or more from the measured value at the first time. The quality of the shimono was evaluated as ×, and the quantity of less than 5% was evaluated as Δ, and the quantity of not decreased was evaluated as ○.
【００１９】[0019]
【表１】 [Table 1]
Claims (2)
からなる防滑性塗料組成物に於いて、シリカ粒子が固形
分中の３５〜５０重量％を占め、シリカ粒子の粒径が５
〜５０ミリミクロンの範囲にあり、かつ、重合体水分散
液はビニルアルコキシシラン又はビニル−トリス（β−
メトキシエトキシ）シランと、これと共重合可能な他の
ビニルモノマーとから製造された、ガラス転移温度が０
℃以下である共重合体を含有し、その共重合体粒子の表
面にシリカ粒子が配位していることを特徴とする防滑性
塗料組成物。1. An anti-slip coating composition comprising a mixture of an aqueous polymer dispersion and silica particles, wherein the silica particles account for 35 to 50% by weight of the solid content, and the particle size of the silica particles is 5.
Is in the range of up to 50 millimicrons, and the polymer aqueous dispersion is vinylalkoxysilane or vinyltris (β-
Made from methoxyethoxy) silane and another vinyl monomer copolymerizable therewith, having a glass transition temperature of 0.
A non-slip coating composition comprising a copolymer having a temperature of not higher than 0 ° C., and silica particles being coordinated on the surface of the copolymer particles.
ン又はビニル−トリス（β−メトキシエトキシ）シラン
０．５〜５重量％と、これと共重合可能な他のビニルモ
ノマー９５〜９９．５重量％とを共重合させたものであ
ることを特徴とする請求項１記載の防滑性塗料組成物。2. The copolymer comprises 0.5 to 5% by weight of vinylalkoxysilane or vinyl-tris (β-methoxyethoxy) silane and 95 to 99.5% by weight of another vinyl monomer copolymerizable therewith. The anti-slip coating composition according to claim 1, wherein the anti-slip coating composition is a copolymer of 10% and 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20884991A JPH0794620B2 (en) | 1991-07-26 | 1991-07-26 | Anti-slip coating composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20884991A JPH0794620B2 (en) | 1991-07-26 | 1991-07-26 | Anti-slip coating composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0532916A JPH0532916A (en) | 1993-02-09 |
| JPH0794620B2 true JPH0794620B2 (en) | 1995-10-11 |
Family
ID=16563127
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP20884991A Expired - Lifetime JPH0794620B2 (en) | 1991-07-26 | 1991-07-26 | Anti-slip coating composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0794620B2 (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2724684B2 (en) * | 1994-10-19 | 1998-03-09 | 王子製紙株式会社 | Paint and anti-slip paper container for forming anti-slip layer |
| US5855973A (en) * | 1995-08-28 | 1999-01-05 | Westvaco Corporation | Heat sealed, ovenable food cartons and lids |
| FI101989B1 (en) * | 1996-11-22 | 1998-09-30 | Enso Oy | Procedures for the preparation of a liquid and gas-tight packaging board, as well as packaging and products made according to the procedures |
| JP5271666B2 (en) * | 2008-10-27 | 2013-08-21 | イサム塗料株式会社 | Rapid anti-slip construction and coating for ceramic tile floors. |
| JP7062419B2 (en) * | 2017-12-01 | 2022-05-06 | サカタインクス株式会社 | Aqueous anti-slip composition |
-
1991
- 1991-07-26 JP JP20884991A patent/JPH0794620B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0532916A (en) | 1993-02-09 |
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