JPH0789803A - Odorless ant-preventing agent - Google Patents
Odorless ant-preventing agentInfo
- Publication number
- JPH0789803A JPH0789803A JP5258961A JP25896193A JPH0789803A JP H0789803 A JPH0789803 A JP H0789803A JP 5258961 A JP5258961 A JP 5258961A JP 25896193 A JP25896193 A JP 25896193A JP H0789803 A JPH0789803 A JP H0789803A
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- JP
- Japan
- Prior art keywords
- termite
- ant
- preventing agent
- active ingredient
- solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、防蟻処理において用い
られる無臭性の防蟻剤に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an odorless termite control agent used in termite control treatment.
【０００２】[0002]
【従来の技術】白蟻等から建築物を守るための床下の防
蟻処理は不可欠である。防蟻処理は、土壌処理と木部処
理の２種類あるが、土壌処理が特に重要である。2. Description of the Related Art An under-floor ant repellency treatment is indispensable for protecting buildings from termites and the like. There are two types of ant control treatment, soil treatment and xylem treatment, but soil treatment is particularly important.
【０００３】防蟻剤は、土壌処理用乳剤と木部処理用油
剤の２種類がある。一般的な土壌処理用乳剤の組成は、
防蟻剤有効成分が約30〜60wt％、溶剤としてキシロール
が約25wt％及び灯油、軽油が約30wt％並びに界面活性剤
が約５wt％である。一般的な木部処理用油剤の組成は、
防蟻剤有効成分が約１wt％、溶剤として灯油、軽油が約
98.5wt％及び木材防腐剤が約0.5wt％である。There are two types of termite repellents: soil treatment emulsions and xylem treatment oils. The composition of a general soil treatment emulsion is
About 30 to 60 wt% of the anti-termite active ingredient, about 25 wt% of xylol as a solvent, about 30 wt% of kerosene and light oil, and about 5 wt% of surfactant. The composition of a general xylem processing oil,
Approximately 1 wt% of anti-termite active ingredient, and kerosene and light oil as solvents
98.5 wt% and wood preservative about 0.5 wt%.
【０００４】土壌処理用乳剤は、処理時に防蟻剤有効成
分の濃度が約１wt％となるように、水で20〜40倍に希釈
して、床下土壌に散布する。また、木部処理用油剤は、
そのまま木部に塗布するかまたはスプレーする。The soil treatment emulsion is diluted 20 to 40 times with water so that the concentration of the active ingredient for the termiticide is about 1 wt% at the time of treatment, and it is sprayed on the underfloor soil. Also, the xylem processing oil is
Apply as is to the wood or spray.
【０００５】国内で用いられている防蟻剤の有効成分と
しては、有機リン系が最も多く、その他、ピレスロイド
系、カーバメート系、クロロニコチニル系等がある。As the active ingredient of the termite-preventing agents used in Japan, organophosphorus compounds are the most common, and in addition, pyrethroid compounds, carbamate compounds, chloronicotinyl compounds and the like.
【０００６】土壌処理用乳剤は、原液、希釈液共に不快
臭を有し、処理時、処理後の臭気問題がある。一方、木
部処理用油剤もまた、処理時、処理後の灯油臭の問題が
ある。このため、防蟻処理により、近隣から苦情を受け
ることも多い。また、施主や近隣者がアレルギー体質の
人や神経過敏な人の場合、訴訟にまで発展することもあ
る。業者側からみても、防蟻剤の不快臭が車内に充満し
て、体が不調時には問題となることもある。このような
防蟻剤の臭気問題を解決することが強く望まれている。Emulsions for soil treatment have unpleasant odors in both undiluted solution and diluted solution, and have odor problems during and after treatment. On the other hand, an oil agent for treating wood also has a problem of kerosene odor during and after treatment. For this reason, there are many cases where complaints are received from the neighborhood due to the ant control process. In addition, when the owner or a neighbor is an allergic person or a sensitive person, a lawsuit may be developed. Even from the side of the trader, the unpleasant odor of the termite repellent may fill the inside of the vehicle, which may cause a problem when the body is in a bad condition. It is strongly desired to solve the odor problem of such an anti-termite agent.
【０００７】[0007]
【発明が解決しようとする課題】本発明の目的は、これ
らの問題を解決する無臭性の防蟻剤を提供することであ
る。SUMMARY OF THE INVENTION An object of the present invention is to provide an odorless termite control agent which solves these problems.
【０００８】[0008]
【課題を解決するための手段】本発明者等は、鋭意研究
を重ねた結果、上記の問題を解決する無臭性の防蟻剤を
得、本発明を完成するに至った。As a result of intensive studies, the inventors of the present invention have completed the present invention by obtaining an odorless termite control agent that solves the above problems.
【０００９】すなわち、本発明は、防蟻剤有効成分、溶
剤及び界面活性剤ないしは防腐剤とを含有してなる防蟻
剤において、溶剤が、一般式＜１＞（式中、Ｒ1、Ｒ
2は、水素原子または炭素数１、２のアルキル基を、Ｒ3
は、炭素数１〜３のアルキル基を示す。）で表されるア
ルキル置換ナフタレン化合物であることを特徴とする無
臭性防蟻剤である。That is, according to the present invention, in an anti-termite agent comprising an anti-termite active ingredient, a solvent and a surfactant or a preservative, the solvent is a compound represented by the general formula <1> (wherein R 1 , R
2 is a hydrogen atom or an alkyl group having 1 or 2 carbon atoms, R 3
Represents an alkyl group having 1 to 3 carbon atoms. ) An odorless termite control agent, which is an alkyl-substituted naphthalene compound represented by
【００１０】[0010]
【化１】[Chemical 1]
【００１１】本発明で用いる防蟻剤有効成分としては、
例えば、クロロピリホス、ホキシム、ピリダフェンチオ
ン、テトラクロルビンホス、フェニトロチオン、プロペ
ンタホス等の有機リン系、アレスリン、パーメスリン、
フェンバレレート、サイパメスリン等のピレスロイド
系、プロポクスル、バッサ、カルバソル等のカーバメー
ト系、イミダクロプリド等のクロロニコチニル系等があ
げられ、１種または２種以上の混合物として用いられ
る。The anti-termite active ingredient used in the present invention is
For example, chloropyrifos, phoxime, pyridafenthion, tetrachlorovinphos, fenitrothion, organophosphorus such as propentaphos, allethrin, permethrin,
Examples include pyrethroids such as fenvalerate and cypamethrin, carbamates such as propoxur, bassa and carbazol, chloronicotinyls such as imidacloprid, and the like, and one or a mixture of two or more thereof is used.
【００１２】本発明で用いる溶剤である一般式＜１＞で
表されるアルキル置換ナフタレン化合物は、Ｒ1、Ｒ2で
は、水素原子または炭素数１、２のアルキル基が好まし
く、特に炭素数１のアルキル基が好ましい。また、Ｒ3
では、炭素数１〜３のアルキル基が好ましく、特に炭素
数３のアルキル基が好ましい。In the alkyl-substituted naphthalene compound represented by the general formula <1>, which is a solvent used in the present invention, R 1 and R 2 are preferably hydrogen atoms or alkyl groups having 1 or 2 carbon atoms, and particularly 1 carbon atom. Alkyl groups of are preferred. Also, R 3
Then, an alkyl group having 1 to 3 carbon atoms is preferable, and an alkyl group having 3 carbon atoms is particularly preferable.
【００１３】本発明で用いられる溶剤である一般式＜１
＞で表されるアルキル置換ナフタレン化合物としては、
例えば、ジメチルプロピルナフタレン、モノメチルモノ
プロピルナフタレン、ジエチルプロピルナフタレン、モ
ノエチルモノプロピルナフタレン、メチルエチルプロピ
ルナフタレン、メチルジプロピルナフタレン、エチルジ
プロピルナフタレン、トリメチルナフタレン、トリエチ
ルナフタレン、トリプロピルナフタレン等があげられ、
ジメチルプロピルナフタレン及び／またはモノメチルモ
ノプロピルナフタレンが特に好ましい。また、これらの
アルキル置換ナフタレン化合物は、１種または２種以上
の混合物として用いられる。The solvent used in the present invention has the general formula <1.
The alkyl-substituted naphthalene compound represented by
For example, dimethylpropylnaphthalene, monomethylmonopropylnaphthalene, diethylpropylnaphthalene, monoethylmonopropylnaphthalene, methylethylpropylnaphthalene, methyldipropylnaphthalene, ethyldipropylnaphthalene, trimethylnaphthalene, triethylnaphthalene, tripropylnaphthalene, and the like,
Dimethylpropyl naphthalene and / or monomethyl monopropyl naphthalene are particularly preferred. Moreover, these alkyl-substituted naphthalene compounds are used alone or as a mixture of two or more kinds.
【００１４】本発明で用いる界面活性剤としては、例え
ば、高級アルコール硫酸エステル塩等の陰イオン界面活
性剤、ポリオキシエチレンアルキルエーテル等の非イオ
ン界面活性剤、アルキルアミン塩や第４級アンモニウム
塩等の陽イオン界面活性剤及びアルキルベタイン等の両
イオン界面活性剤があげられ、１種または２種以上の混
合物として用いられる。Examples of the surfactant used in the present invention include anionic surfactants such as higher alcohol sulfate ester salts, nonionic surfactants such as polyoxyethylene alkyl ethers, alkylamine salts and quaternary ammonium salts. And cationic surfactants such as alkylbetaine and amphoteric surfactants such as alkylbetaine, which may be used alone or as a mixture of two or more.
【００１５】本発明で用いる木材防腐剤としては、例え
ば、４−クロロフェニル−３−ヨードプロパギルホルマ
ール、３−ブロモ−２、３−ジヨード−２−プロペニル
エチルカルボナート等の有機ヨード系、２−（４−チア
ゾリル）ベンツイミダゾール、２−ベンツイミダゾール
カルバミン酸メチル、２−チオシアノメチルチオベンゾ
チアゾール等のベンツイミダゾール系またはベンツチア
ゾール系やトリアゾール系等があげられ、１種または２
種以上の混合物として用いられる。Examples of the wood preservative used in the present invention include 4-chlorophenyl-3-iodopropargyl formal, 3-bromo-2,3-diiodo-2-propenylethyl carbonate and other organic iodides, 2- Examples include benzimidazole-based compounds such as (4-thiazolyl) benzimidazole, methyl 2-benzimidazolecarbamate, and 2-thiocyanomethylthiobenzothiazole, and benzthiazole-based and triazole-based compounds.
Used as a mixture of two or more species.
【００１６】本発明の無臭性防蟻剤は、防蟻剤有効成
分、溶剤として一般式＜１＞で表されるアルキル置換ナ
フタレン化合物及び界面活性剤ないしは防腐剤とからな
るものであってもよいが、必要に応じてその他の成分を
含んでも良い。The odorless termiticide of the present invention may comprise an termiticide active ingredient, an alkyl-substituted naphthalene compound represented by the general formula <1> as a solvent, and a surfactant or preservative. However, other components may be included if necessary.
【００１７】その他の成分としては、例えば、ジメチル
スルホキシド、アクリル樹脂ないしはアルキド樹脂、ウ
レタン樹脂等の樹脂類、酸化防止剤、紫外線吸収剤等の
安定化剤、乳化剤、着色剤、増粘剤、染料ないしは顔料
等の添加剤及びオクタクロルジプロピルエーテル等の効
力増強剤があげられる。Other components include, for example, resins such as dimethyl sulfoxide, acrylic resin or alkyd resin, urethane resin, stabilizers such as antioxidants and ultraviolet absorbers, emulsifiers, colorants, thickeners, dyes. Or an additive such as a pigment and a potency enhancer such as octachlorodipropyl ether.
【００１８】本発明の土壌処理用乳剤は、防蟻剤有効成
分30〜60wt％、溶剤として一般式＜１＞で表されるアル
キル置換ナフタレン化合物30〜60wt％及び界面活性剤３
〜10wt％とを含有する。The emulsion for soil treatment of the present invention comprises 30 to 60 wt% of an anti-termite active ingredient, 30 to 60 wt% of an alkyl-substituted naphthalene compound represented by the general formula <1> as a solvent, and a surfactant 3
~ 10 wt%.
【００１９】また、木部処理用油剤は、防蟻剤有効成分
約１wt％、溶剤として一般式＜１＞で表されるアルキル
置換ナフタレン化合物96〜99wt％及び木材防腐剤0.5〜
２wt％とを含有する。Further, the oil agent for treating wood is about 1 wt% of an active ingredient of an anti-termite agent, 96-99 wt% of an alkyl-substituted naphthalene compound represented by the general formula <1> as a solvent, and 0.5-about a wood preservative.
And 2 wt%.
【００２０】[0020]
【実施例】以下、実施例により本発明を説明する。な
お、本発明は、これらの実施例になんら限定されない。
各実施例で用いている４−クロロフェニル−３−ヨード
プロパギルホルマールは、ナガセ化成工業(株)製（商品
名：ＩＦ−１０００）、３−ブロモ−２、３−ジヨード
−２−プロペニルエチルカルボナートは、三共(株)製
（商品名：サンプラス）である。EXAMPLES The present invention will be described below with reference to examples. The present invention is not limited to these examples.
4-Chlorophenyl-3-iodopropargyl formal used in each example is manufactured by Nagase Chemicals Industries Co., Ltd. (trade name: IF-1000), 3-bromo-2,3-diiodo-2-propenylethylcarbo. Nato is manufactured by Sankyo Co., Ltd. (trade name: Samplus).
【００２１】実施例１ 溶剤であるジメチルプロピルナフタレン54wt％中に、防
蟻剤有効成分であるクロルピリホスを40wt％、界面活性
剤ソルポール３００６Ｋ及びソルポール３００８Ｋ（東
邦化学(株)登録商標）を各々３wt％を溶解し、土壌処理
用乳剤を得た。得られた防蟻剤に対し、５人のパネラー
による臭気官能試験を行った。また、得られた防蟻剤の
４０倍希釈した液を、野外土壌に３l/m2散布して、２年
間の野外防蟻試験を行った。防蟻剤の組成を表１に、ま
た、臭気官能試験及び野外防蟻試験の結果を表４に示
す。Example 1 In 54% by weight of dimethylpropylnaphthalene as a solvent, 40% by weight of chlorpyrifos as an active ingredient of an anti-termite agent, and 3% by weight of each of surfactants Solpol 3006K and Solpol 3008K (registered trademark of Toho Kagaku Co., Ltd.). Was dissolved to obtain a soil treatment emulsion. The obtained termite control agent was subjected to an odor sensory test by 5 panelists. Further, a 40-fold diluted solution of the obtained termite control agent was sprayed on the field soil in an amount of 3 l / m 2 and a field control test for 2 years was conducted. The composition of the termite control agent is shown in Table 1, and the results of the odor sensory test and the field termite control test are shown in Table 4.
【００２２】実施例２〜７ 実施例１において、防蟻剤の組成を表１の実施例２〜７
とした以外は、実施例１と同様にして、土壌処理用乳剤
を得、実施例１と同様の試験を行った。試験結果を表４
に示す。Examples 2 to 7 In Example 1, the composition of the termite control agent is shown in Table 1 as Examples 2 to 7.
A soil treatment emulsion was obtained in the same manner as in Example 1 except that the above was used, and the same test as in Example 1 was performed. Table 4 shows the test results
Shown in.
【００２３】実施例８〜１１ 実施例１において、防蟻剤の組成を表２の実施例８〜１
１とした以外は、実施例１と同様にして、木部処理用油
剤を得た。得られた防蟻剤に対し、５人のパネラーによ
る臭気官能試験を行った。また、得られた防蟻剤を、松
杭に300ml/m2塗布して、２年間の野外防蟻試験を行っ
た。試験結果を表４に示す。Examples 8 to 11 In Example 1, the composition of the termite control agent is shown in Table 2 as Examples 8 to 1.
An oil agent for treating a wood part was obtained in the same manner as in Example 1 except that the number was 1. The obtained termite control agent was subjected to an odor sensory test by 5 panelists. Further, the obtained ant-preventive agent was applied to pine piles at 300 ml / m 2 and a field ant-proof test was conducted for 2 years. The test results are shown in Table 4.
【００２４】比較例１、２ 実施例１において、防蟻剤の組成を表３に示した比較例
１、２とした以外は、実施例１と同様にして、土壌処理
用乳剤を得、実施例１と同様の試験を行った。試験結果
を表５に示す。Comparative Examples 1 and 2 A soil treatment emulsion was obtained and carried out in the same manner as in Example 1 except that the composition of the termite control agent was changed to Comparative Examples 1 and 2 shown in Table 3. The same test as in Example 1 was performed. The test results are shown in Table 5.
【００２５】比較例３、４ 実施例１において、防蟻剤の組成を表３の比較例３、４
とした以外は、実施例１と同様にして、木部処理用油剤
を得た。得られた防蟻剤に対し、５人のパネラーによる
臭気官能試験を行った。また、得られた防蟻剤を、松杭
に300ml/m2塗布して、２年間の野外防蟻試験を行った。
試験結果を表５に示す。Comparative Examples 3 and 4 In Example 1, the composition of the termite control agent is shown in Table 3 as Comparative Examples 3 and 4.
An oil agent for treating a wood part was obtained in the same manner as in Example 1 except for the above. The obtained termite control agent was subjected to an odor sensory test by 5 panelists. Further, the obtained ant-preventive agent was applied to pine piles at 300 ml / m 2 and a field ant-proof test was conducted for 2 years.
The test results are shown in Table 5.
【００２６】比較例５ 実施例１において、溶剤としてジメチルプロピルナフタ
レンの代りに、パラフィン系炭化水素（商品名：０号ソ
ルベント、日本石油(株)製）を用いたが、防蟻剤有効成
分であるクロルピリホスが溶解せず、土壌処理用乳剤が
得られなかった。Comparative Example 5 In Example 1, paraffin hydrocarbon (trade name: No. 0 solvent, manufactured by Nippon Oil Co., Ltd.) was used as a solvent instead of dimethylpropylnaphthalene. Some chlorpyrifos did not dissolve and no soil treatment emulsion was obtained.
【００２７】比較例６ 実施例１において、溶剤としてジメチルプロピルナフタ
レンの代りに、パラフィン系炭化水素22wt％とナフテン
系炭化水素78wt％の低芳香族溶剤（商品名：ＡＦソルベ
ント、日本石油(株)製）を用いたが、防蟻剤有効成分で
あるクロルピリホスが溶解せず、土壌処理用乳剤が得ら
れなかった。Comparative Example 6 In Example 1, instead of dimethylpropylnaphthalene as a solvent, a low aromatic solvent having 22 wt% of paraffinic hydrocarbon and 78 wt% of naphthenic hydrocarbon (trade name: AF Solvent, Nippon Oil Co., Ltd.) However, the soil treatment emulsion could not be obtained because chlorpyrifos, which is an active ingredient for the termiticide, was not dissolved.
【００２８】臭気官能試験の結果、実施例１〜１１で
は、無臭であったが、比較例１、２では不快臭が、比較
例３、４では灯油臭がした。また、野外防蟻試験の結
果、実施例１〜１１及び比較例１〜４は、共に同等の防
蟻効果が確認された。As a result of the odor sensory test, Examples 1 to 11 were odorless, but Comparative Examples 1 and 2 had an unpleasant odor, and Comparative Examples 3 and 4 had a kerosene odor. Further, as a result of the outdoor termite control test, it was confirmed that Examples 1 to 11 and Comparative Examples 1 to 4 have the same termite control effect.
【００２９】[0029]
【表１】 [Table 1]
【００３０】[0030]
【表２】 [Table 2]
【００３１】[0031]
【表３】 [Table 3]
【００３２】[0032]
【表４】 [Table 4]
【００３３】[0033]
【表５】 [Table 5]
【００３４】[0034]
【発明の効果】本発明の無臭性防蟻剤により、処理時及
び処理後の臭気問題が解決できる。また、防蟻効果は、
従来の防蟻剤と同等である。The odorless termite control agent of the present invention can solve the odor problem during and after the treatment. In addition, the anti-termite effect is
It is equivalent to conventional termite control agents.
Claims (3)
いしは防腐剤とを含む防蟻剤において、溶剤が、一般式
＜１＞（式中、Ｒ1、Ｒ2は、水素原子または炭素数１、
２のアルキル基を、Ｒ3は、炭素数１〜３のアルキル基
を示す。）で表されるアルキル置換ナフタレン化合物で
あることを特徴とする無臭性防蟻剤。 【化１】 1. An anti-termite agent comprising an anti-termite active ingredient, a solvent and a surfactant or a preservative, wherein the solvent is represented by the general formula <1> (wherein R 1 and R 2 are a hydrogen atom or a carbon atom). Number one,
2 represents an alkyl group, and R 3 represents an alkyl group having 1 to 3 carbon atoms. ) An odorless termite control agent, which is an alkyl-substituted naphthalene compound represented by [Chemical 1]
ピレスロイド系防蟻剤、カーバメート系防蟻剤、クロロ
ニコチニル系防蟻剤からなる群から選ばれた少なくとも
１種以上である請求項１記載の無臭性防蟻剤。2. An anti-termite active ingredient is an organophosphorus anti-termite,
The odorless termite control agent according to claim 1, which is at least one selected from the group consisting of pyrethroid type termite control agents, carbamate type termite control agents, and chloronicotinyl type termite control agents.
キシム、ピリダフェンチオン、テトラクロルビンホス、
フェニトロチオン、プロペンタホス、アレスリン、パー
メスリン、フェンバレレート、サイパメスリン、プロポ
クスル、バッサ、カルバリル、イミダクロプリドからな
る群から選ばれた少なくとも１種以上である請求項１記
載の無臭性防蟻剤。3. An antitermite active ingredient is chlorpyrifos, phoxime, pyridafenthion, tetrachlorvinphos,
The odorless anti-termite agent according to claim 1, which is at least one selected from the group consisting of fenitrothion, propentaphos, allethrin, permethrin, fenvalerate, cypamethrin, propoxur, bassa, carbaryl, and imidacloprid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5258961A JPH0789803A (en) | 1993-09-24 | 1993-09-24 | Odorless ant-preventing agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5258961A JPH0789803A (en) | 1993-09-24 | 1993-09-24 | Odorless ant-preventing agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0789803A true JPH0789803A (en) | 1995-04-04 |
Family
ID=17327434
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5258961A Pending JPH0789803A (en) | 1993-09-24 | 1993-09-24 | Odorless ant-preventing agent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0789803A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004250437A (en) * | 2003-01-27 | 2004-09-09 | Nippon Kayaku Co Ltd | Mixed fumigant |
| US7728011B2 (en) | 2001-04-09 | 2010-06-01 | Bayer Animal Health Gmbh | Dermally applicable liquid formulations for controlling parasitic insects on animals |
-
1993
- 1993-09-24 JP JP5258961A patent/JPH0789803A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7728011B2 (en) | 2001-04-09 | 2010-06-01 | Bayer Animal Health Gmbh | Dermally applicable liquid formulations for controlling parasitic insects on animals |
| JP2004250437A (en) * | 2003-01-27 | 2004-09-09 | Nippon Kayaku Co Ltd | Mixed fumigant |
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