JPH0775535A - Method for preventing beverage from deteriorating in flavor - Google Patents

Method for preventing beverage from deteriorating in flavor

Info

Publication number
JPH0775535A
JPH0775535A JP5248797A JP24879793A JPH0775535A JP H0775535 A JPH0775535 A JP H0775535A JP 5248797 A JP5248797 A JP 5248797A JP 24879793 A JP24879793 A JP 24879793A JP H0775535 A JPH0775535 A JP H0775535A
Authority
JP
Japan
Prior art keywords
beverage
flavor
sunflower
preventing
deteriorating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP5248797A
Other languages
Japanese (ja)
Other versions
JP3276478B2 (en
Inventor
Hisashi Tanaka
久志 田中
Ken Washino
乾 鷲野
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SANEI GEN F F I Inc
San Ei Gen FFI Inc
Original Assignee
SANEI GEN F F I Inc
San Ei Gen FFI Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SANEI GEN F F I Inc, San Ei Gen FFI Inc filed Critical SANEI GEN F F I Inc
Priority to JP24879793A priority Critical patent/JP3276478B2/en
Publication of JPH0775535A publication Critical patent/JPH0775535A/en
Application granted granted Critical
Publication of JP3276478B2 publication Critical patent/JP3276478B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Abstract

PURPOSE:To obtain a beverage, capable of preventing a flavor from deteriorating due to the passage of time and having stable quality by adding an ingredient prepared from a seed of a sunflower alone or in combination with a sequestrant into a beverage. CONSTITUTION:This beverage contains an ingredient extracted from a seed of a sunflower with water or a hydrous alcohol alone or in combination with a sequestrant in a beverage such as a carbonated or fruit juice beverage. The resultant beverage is capable of preventing a flavor from deteriorating with light, heat, air, etc., during a production process, a distribution stage and preservation of the beverage and retaining the good flavor for a long period and has stable quality.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は飲料の香味劣化防止方法
に関するものであり、詳しくは飲料にヒマワリの種子か
ら水または含水アルコールで抽出される成分を単独で、
又は金属封鎖剤と併用することにより、飲料の香味劣化
を防止する方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for preventing flavor deterioration of beverages, and more specifically, to a beverage containing a component extracted from sunflower seeds with water or hydrous alcohol alone.
Alternatively, it relates to a method for preventing flavor deterioration of a beverage by using it together with a sequestering agent.

【0002】[0002]

【従来の技術】一般に飲料は製造工程中,流通段階およ
び保存中の各段階において経時的に香味が劣化してお
り、特に透明ガラスビンや透明プラスチック容器入りの
場合において劣化の度合は著しく、そのままでは本来の
香味が消失したり、香味の劣化による異味異臭が発生し
たり等の問題が生じやすい。こうした劣化を防止するた
めに、アスコルビン酸等各種の酸化防止剤の添加や低温
での流通、保存、また光や外気を極力遮断した容器を用
いる等の方法がとられているが、未だ充分な香味劣化防
止方法は確立されていないのが現状である。
2. Description of the Related Art In general, beverages have a deteriorated flavor over time during the manufacturing process, distribution stage and storage stage, and the degree of deterioration is remarkable especially in a transparent glass bottle or a transparent plastic container. Problems such as loss of original flavor and generation of off-flavours due to deterioration of flavor are likely to occur. In order to prevent such deterioration, methods such as addition of various antioxidants such as ascorbic acid, distribution at low temperature, storage, and use of a container that shields light and outside air as much as possible have been taken, but it is still insufficient. At present, the method for preventing flavor deterioration is not established.

【0003】[0003]

【発明が解決しようとする課題】一般に市販されている
飲料は製造工程中、流通段階および保存中において光、
熱、空気等による影響を受け、香味が変化し品質の低下
をまねくことがあるが、本発明はこうした飲料の香味劣
化を防止し、品質の安定した飲料を提供することを目的
とする。
Generally, commercially available beverages are exposed to light during the manufacturing process, distribution stage and storage.
Although the flavor may change due to the influence of heat, air, etc., and the quality may be deteriorated, it is an object of the present invention to prevent such flavor deterioration of the beverage and provide a beverage of stable quality.

【0004】[0004]

【課題を解決するための手段】本発明者らは飲料の香味
劣化防止について鋭意研究した結果、ヒマワリの種子か
ら水または含水アルコールで抽出される成分(特開平3
−221587、以下ヒマワリ抽出物という)が飲料の
香味劣化防止に顕著な効果のあることを見いだした。す
なわちヒマワリ抽出物を単独で、又は金属封鎖剤を併用
して飲料に適宜添加することによって、飲料の香味には
影響を及ぼさずに、良好な香味を長期間保つことができ
ることを見いだし、本発明に至ったものである。
[Means for Solving the Problems] As a result of intensive studies on prevention of flavor deterioration of beverages, the present inventors have found that the components extracted from sunflower seeds with water or hydrous alcohol (Japanese Patent Laid-Open No. Hei 3)
221587, hereinafter referred to as sunflower extract), has a remarkable effect in preventing flavor deterioration of beverages. That is, the sunflower extract alone, or by appropriately added to the beverage in combination with a sequestering agent, without affecting the flavor of the beverage, found that it is possible to maintain a good flavor for a long time, the present invention It came to.

【0005】以下に本発明を詳しく説明する。本発明で
いう飲料とは特に限定されるものではなく、例えば炭酸
飲料、果汁、果汁飲料、乳性飲料、コーヒー飲料、茶類
飲料、アルコール飲料、その他を挙げることができる。
本発明における飲料の香味劣化防止方法はヒマワリ抽出
物を単独で、又は金属封鎖剤を併用して添加すること以
外は従来からの飲料の製法を使用することができる。す
なわち飲料の原料としては砂糖、異性化糖、アスパルテ
ーム等の甘味料、クエン酸、乳酸等の酸味料、香料、乳
化剤、着色料、保存料、増粘安定剤、酸化防止剤、ビタ
ミン類等の強化剤、果汁、野菜汁、乳、乳製品、酒等の
アルコール飲料、コーヒー、茶類等の抽出液、炭酸ガ
ス、無機成分等および飲料用水であり、これらを単独も
しくは複数組み合せて使用すればよいが特にこれらに制
限されるものではなく、飲料に適した原料を適宜選択し
使用すれば良い。原料を混和、溶解、懸濁、酵素処理、
発酵等の処理をして調製し、殺菌、濾過、容器詰め等の
いくつかの工程を経て飲料として供されるものである。
こうして製造された飲料は製造工程中、流通段階および
保存中において光、熱、空気等による影響を受け徐々に
香味は変化し、製品価値が少しずつ低下していく。
The present invention will be described in detail below. The drink referred to in the present invention is not particularly limited, and examples thereof include carbonated drinks, fruit juices, fruit juice drinks, dairy drinks, coffee drinks, tea drinks, alcoholic drinks, and the like.
The method for preventing flavor deterioration of a beverage according to the present invention can use a conventional beverage production method except that the sunflower extract is added alone or in combination with a sequestering agent. That is, as raw materials for beverages, sugar, isomerized sugar, sweeteners such as aspartame, citric acid, acidulants such as lactic acid, flavors, emulsifiers, colorants, preservatives, thickening stabilizers, antioxidants, vitamins, etc. Strengthening agents, fruit juices, vegetable juices, milk, dairy products, alcoholic beverages such as liquor, coffee, extract liquids such as teas, carbon dioxide, inorganic components, etc. and drinking water, which can be used alone or in combination. However, the raw material suitable for the beverage may be appropriately selected and used. Mixing, dissolving, suspension, enzyme treatment of raw materials,
It is prepared as a result of processing such as fermentation, and is provided as a beverage after undergoing several steps such as sterilization, filtration and container filling.
The beverage produced in this manner gradually changes its flavor due to the influence of light, heat, air, etc. during the production process, distribution stage, and storage, and the product value gradually decreases.

【0006】本発明で使用されるヒマワリ抽出物はヒマ
ワリ種子を水または含水アルコールで抽出される成分で
あれば抽出物そのものであっても、除タンパクや脱色、
脱臭等の精製を行なってもよいし、酵素処理等の操作を
したり、所望により、それらの濃縮物であっても、凍結
乾燥や噴霧乾燥等を行なった粉末でもよく、どのような
剤形のものでも使用できる。本発明で使用される金属封
鎖剤としては、例えばアジピン酸、クエン酸、コハク
酸、酒石酸、フィチン酸、フマル酸、リンゴ酸、ピロリ
ン酸、ポリリン酸、メタリン酸、エチレンジアミン四酢
酸及びこれらの塩類や、アラビアガム、アルギン酸、ア
ルギン酸塩、アルギン酸プロピレングリコールエステ
ル、カードラン、カラギナン、カルボキシメチルセルロ
ース、カルボキシメチルセルロース塩、キサンタンガ
ム、キチン、キトサン、グアーガム、ジェランガム、タ
マリンドシードガム、デンプングリコール酸ナトリウ
ム、デンプンリン酸エステルナトリウム、ペクチン、ポ
リアクリル酸ナトリウム、その他をあげることができ、
これらからなる群の1種又は2種以上を使用することが
できる。
[0006] The sunflower extract used in the present invention is a component which can extract sunflower seeds with water or hydrous alcohol, even if the extract itself is deproteinized or decolorized,
Purification such as deodorization may be carried out, operations such as enzyme treatment may be performed, and if desired, concentrates thereof or powders obtained by freeze-drying or spray-drying may be used. It can also be used. Examples of the sequestering agent used in the present invention include adipic acid, citric acid, succinic acid, tartaric acid, phytic acid, fumaric acid, malic acid, pyrophosphoric acid, polyphosphoric acid, metaphosphoric acid, ethylenediaminetetraacetic acid, and salts thereof. , Gum arabic, alginic acid, alginate, propylene glycol alginate, curdlan, carrageenan, carboxymethyl cellulose, carboxymethyl cellulose salt, xanthan gum, chitin, chitosan, guar gum, gellan gum, tamarind seed gum, sodium starch glycolate, sodium starch phosphate sodium salt , Pectin, sodium polyacrylate, etc.
One or more of the group consisting of these can be used.

【0007】飲料にヒマワリ抽出物および金属封鎖剤を
添加する時期については特に限定されるものではなく、
飲料の製造工程中のどの段階で添加してもかまわない。
ヒマワリ抽出物および金属封鎖剤の添加量については添
加対象の飲料により異なるが、期待される効果や香味上
の問題から自ずと定まってくるものである。例えば60
%含水エタノールで抽出したヒマワリ抽出物の場合、無
果汁炭酸飲料に使用する際には固形分として5〜100
0ppm程度の添加が好ましい。この範囲以下の濃度の
添加では期待される効果は得られず、これ以上の濃度の
添加では添加するヒマワリ抽出物が飲料の香味に影響す
る。併せて使用される金属封鎖剤としては飲料に対して
10ppm以上添加されることが望ましい。また、これ
らと他の香味劣化防止剤を併用してもかまわない。飲料
の充填容器としては様々なものが用いられているが、光
照射の影響をうけやすいガラスびんやプラスチック製の
容器に本発明を実施した場合、著しい効果を発揮する。
以下、本発明の効果を実施例を示して更に具体的に説明
する。
The timing of adding the sunflower extract and the sequestering agent to the beverage is not particularly limited,
It may be added at any stage during the beverage manufacturing process.
The amount of sunflower extract and sequestering agent added varies depending on the beverage to which it is added, but it is naturally determined from expected effects and flavor problems. For example 60
In the case of a sunflower extract extracted with% hydrous ethanol, the solid content is 5 to 100 when used in a fruitless juice carbonated beverage.
Addition of about 0 ppm is preferable. When the concentration is lower than this range, the expected effect cannot be obtained, and when the concentration is higher than this range, the sunflower extract to be added affects the flavor of the beverage. As a sequestering agent used together, it is desirable to add 10 ppm or more to the beverage. Further, these may be used in combination with other flavor deterioration preventing agents. Various types of beverage filling containers are used, but when the present invention is applied to a glass bottle or a plastic container that is easily affected by light irradiation, a remarkable effect is exhibited.
Hereinafter, the effects of the present invention will be described more specifically with reference to examples.

【0008】[0008]

【実施例】【Example】

参考例1 機械粉砕したヒマワリ種子500gに60%(v/v)
含水エタノール3lを添加し、60℃で7時間抽出し
た。冷却濾過後、減圧下濃縮乾固した(以下、抽出物1
という)
Reference Example 1 60% (v / v) to 500 g of mechanically crushed sunflower seeds
3 l of hydrous ethanol was added, and the mixture was extracted at 60 ° C for 7 hours. After cooling and filtering, the mixture was concentrated to dryness under reduced pressure (hereinafter, extract 1
Say)

【0009】実施例1 処方1 果糖ぶどう糖液糖 130g クエン酸(結晶) 1g サイダー香料 1g 清水にて全量を200mlとしたシロップを調製し、こ
のシロップをプレーンソーダで1000mlとする処方
1の無果汁透明炭酸飲料を200ml容透明ガラスびん
に静かに移しかえ、何も添加しないもの(試験区1)
と、抽出物1を100ppmとなるように添加したもの
(試験区2)とを35℃の暗所で1ケ月間放置した後、
10名のパネラーによる官能評価を以下の5段階で行な
ったところ表1のような結果となった。 評価 5:劣化みられず(未照射品と同程度) 4:わずかに劣化している 3:劣化している 2:かなり劣化している 1:非常に劣化している(とても飲めない)
Example 1 Formulation 1 Fructose-fructose syrup 130 g Citric acid (crystal) 1 g Cider flavor 1 g A syrup was prepared with fresh water to a total volume of 200 ml, and the syrup was made to be 1000 ml with plain soda. The carbonated drink is gently transferred to a 200 ml transparent glass bottle and nothing is added (Test Zone 1)
Then, after the extract 1 and the one to which the extract 1 was added at 100 ppm (test section 2) were left in the dark at 35 ° C. for 1 month,
When the sensory evaluation by 10 panelists was conducted in the following 5 steps, the results shown in Table 1 were obtained. Evaluation 5: No deterioration observed (similar to unirradiated product) 4: Slight deterioration 3: Deteriorated 2: Significant deterioration 1: Very deteriorated (not very drinkable)

【0010】[0010]

【表1】 [Table 1]

【0011】実施例2 処方1の無果汁透明炭酸飲料を200ml容透明ガラス
びんに静かに移しかえ,何も添加しないもの(試験区
1)と、抽出物1を100ppm、フィチン酸を10p
pm含有するように添加したもの(試験区2)とを、晴
天の日に(平均気温約24℃)10時間日光照射し、5
時間目までの1時間毎及び10時間目に、10名のパネ
ラーによる官能評価を実施例1と同様に行なったところ
表2のような結果となった。官能評価の際のコメントを
集計し、まとめると試験区2は試験区1に比べて劣化臭
がなく、日光照射前のさわやかな香味が残っており、バ
ランスのとれた香味を有しているとの評価となった。
Example 2 The fruit-free juice-clear carbonated beverage of Formulation 1 was gently transferred to a 200 ml transparent glass bottle, and nothing was added (Test Group 1), 100 ppm of Extract 1 and 10 p of phytic acid.
What was added so as to contain pm (test section 2) was irradiated with sunlight for 10 hours on a sunny day (average temperature about 24 ° C.), and 5
When the sensory evaluation was conducted by 10 panelists every hour until the 10th hour and 10 hours later, the results shown in Table 2 were obtained. Comparing and summarizing the comments during the sensory evaluation, it can be said that the test plot 2 has no deteriorated odor compared to the test plot 1 and has a refreshing flavor before exposure to sunlight and has a balanced flavor. Was evaluated.

【0012】[0012]

【表2】 [Table 2]

【0013】またこの飲料の試験区1と2とについてエ
ーテルにて抽出、濃縮後、ガスクロマトグラフィー及び
質量分析器にて香気成分の挙動を調べたところ表3のよ
うになった。
After extracting and concentrating the test sections 1 and 2 of this beverage with ether, the behavior of the aroma components was examined by gas chromatography and mass spectrometry.

【0014】[0014]

【表3】 [Table 3]

【0015】上記結果から明らかなように抽出物1及び
フィチン酸を添加したものは良好な香気成分例えばリナ
ロール、ネラール、ゲラニアール等をよく残しており、
劣化により増加してくる成分例えばシス−リナロールオ
キサイド(フラノイド)、リモネン−1,2−ジオール
等の発生を抑えている。
As is apparent from the above results, the extract 1 and the one to which phytic acid was added well retained good aroma components such as linalool, neral, geranial, etc.,
It suppresses the generation of components such as cis-linalool oxide (furanoid) and limonene-1,2-diol which increase due to deterioration.

【0016】実施例3 処方2 砂糖 100g クエン酸(結晶) 2g アスコルビン酸 0.5g 濃縮1/5温州果汁 22g オレンジ香料 3.5g 清水で全量を1000mlとする。 処方2の果汁入り飲料に何も添加しないものと抽出物1
を100ppmになるように添加したものとを調製後、
200ml容ガラスびんに充填し85℃で20分間殺菌
後冷却し、晴天の日に5時間日光照射した後10名のパ
ネラーによる官能評価を実施例1と同様にして行なった
ところ表3のような結果となった。官能評価の際のコメ
ントを集計し、まとめると劣化臭がなく、日光照射前の
良好な果汁感を保っており、自然な香味を有していると
の評価となった。
Example 3 Formulation 2 Sugar 100 g Citric acid (crystal) 2 g Ascorbic acid 0.5 g Concentrated 1/5 Wenshu fruit juice 22 g Orange flavor 3.5 g A total volume of 1000 ml with fresh water. Extract 1 with nothing added to the juice-containing beverage of prescription 2
Was prepared so as to be 100 ppm,
It was filled in a 200 ml glass bottle, sterilized at 85 ° C. for 20 minutes, cooled, irradiated with sunlight for 5 hours on a sunny day, and subjected to sensory evaluation by 10 panelists in the same manner as in Example 1. It became a result. By summarizing the comments during the sensory evaluation, it was evaluated that there was no deteriorated odor, a good juice sensation before sunlight irradiation was maintained, and that it had a natural flavor.

【0017】[0017]

【発明の効果】本発明により、ヒマワリの種子から水ま
たは含水アルコールで抽出される成分を単独で、もしく
は金属封鎖剤を併用して飲料に添加することで、飲料そ
のものの香味には影響を与えずに香味の経時変化が顕著
に抑制され、品質の安定した飲料を提供することができ
るようになった。
INDUSTRIAL APPLICABILITY According to the present invention, the flavor of the beverage itself is affected by adding the components extracted from sunflower seeds with water or hydroalcohol alone or in combination with the sequestering agent to the beverage. Without changing the flavor with time, the beverage with stable quality can be provided.

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 ヒマワリの種子から水または含水アルコ
ールで抽出される成分を飲料に含有せしめることを特徴
とする香味劣化防止方法。
1. A method for preventing flavor deterioration, which comprises adding a component extracted from sunflower seeds with water or hydrous alcohol to a beverage.
【請求項2】 ヒマワリの種子から水または含水アルコ
ールで抽出される成分と併せて、金属封鎖剤を飲料に含
有せしめることを特徴とする香味劣化防止方法。
2. A method for preventing flavor deterioration, which comprises incorporating a sequestering agent into a beverage together with a component extracted from sunflower seeds with water or hydroalcoholic alcohol.
JP24879793A 1993-09-07 1993-09-07 Prevention method of flavor deterioration of beverage Expired - Fee Related JP3276478B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP24879793A JP3276478B2 (en) 1993-09-07 1993-09-07 Prevention method of flavor deterioration of beverage

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP24879793A JP3276478B2 (en) 1993-09-07 1993-09-07 Prevention method of flavor deterioration of beverage

Publications (2)

Publication Number Publication Date
JPH0775535A true JPH0775535A (en) 1995-03-20
JP3276478B2 JP3276478B2 (en) 2002-04-22

Family

ID=17183544

Family Applications (1)

Application Number Title Priority Date Filing Date
JP24879793A Expired - Fee Related JP3276478B2 (en) 1993-09-07 1993-09-07 Prevention method of flavor deterioration of beverage

Country Status (1)

Country Link
JP (1) JP3276478B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002537862A (en) * 1999-03-08 2002-11-12 ザ プロクター アンド ギャンブル カンパニー Beverage products with excellent vitamin stability

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002537862A (en) * 1999-03-08 2002-11-12 ザ プロクター アンド ギャンブル カンパニー Beverage products with excellent vitamin stability

Also Published As

Publication number Publication date
JP3276478B2 (en) 2002-04-22

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