JPH075447B2 - Skin hair treatment composition - Google Patents

Description

Description: TECHNICAL FIELD The present invention relates to a skin hair treatment composition, and more particularly, a cleansing agent and a rinse which have a good feeling during and after use and have an excellent conditioning effect. The present invention relates to a skin hair treatment composition of the type for rinsing with water for treatments, etc.

[Problems to be Solved by Prior Art and Invention]

Conventionally, the basic function of a cleansing agent for skin and hair has been to remove dirt on the surface of the body and cleanse the condition of the skin and hair. However, in recent years, along with the spread of showers, increased bathing and washing frequency, longer hair, skin care such as changes in hair style, changes in the environment surrounding hair care,
For these skin care and hair care products, not only the function of simply removing stains, but also the feel during use and after use, good feeling of finishing, mildness, conditioning effect, simplicity, etc. have been demanded. .

Among them, conditioning agents such as cationic polymers, cationic surfactants, oils, silicone derivatives, protein hydrolysates, humectants, animal and plant extracts for the purpose of adjusting the condition of the skin and hair and improving the feel. Is widely used (Cosmetic Science Guidebook, edited by Japan Cosmetic Engineers Association, published in 1979). Among them, the silicone derivative, unlike the cationic polymer and the cationic surfactant, has the characteristics that it has less oily feeling when dried and is excellent in smoothness, so that it has recently been blended in various compositions (JP-A-2004-242242). 55-108811, 55-136214, 56-1
6405, 56-22712, 56-72095, 56-92808,
56-99407, 56-110607, 56-129300, 56-1
67799, 57-56413, 57-56414, 57-58607
57, 126-409, 57-130910, 58-26811,
58-74602, 58-74798, 58-113300, 59-4621
No. 3, No. 59-110609, No. 60-116621, No. 60-120807,
60-126209, 60-126215, 61-6, 61-21002
No. 2, No. 62-77311, No. 62-84198, No. 62-286912, No.
63-22010, 63-45213, 63-156712, 63-1886
No. 17, 63-313713, 63-313714, JP 1-102016
No. 1-132509, No. 1-172313, No. 1-172314, No. 1-
233209, 1-21-2518, 1-211517, 1-211515,
1-210028, 1-2003314, 1-190619, 1-180
No. 814, No. 1-180813, etc.).

One of the main ones of such silicone derivatives is water-insoluble dimethylpolysiloxane, but it is extremely difficult to stably disperse this in a detergent composition without adversely affecting detergency and foaming. The current situation is that the cleaning agent to be used has not been obtained. In addition, dimethylpolysiloxane has a drawback that when it is rinsed with water, it causes strong squeaking and tangling of hair.

Polyether-modified silicone is also known as another silicone derivative, but the one used in the past is water-soluble and has little effect on foaming, but it is washed away with water, so skin and hair Did not remain, and the effect in the dry state was not obtained from the time of rinsing. On the other hand, for the purpose of improving the residual property, a polyether-modified silicone in which hydrophilicity is simply reduced to have self-emulsifying property is known, but like dimethylpolysiloxane, it has a strong squeaky feeling during rinsing. It had the drawback of appearing.

Amino-modified silicones or cation-modified silicones in which a cationic amino group or a quaternary ammonium group is introduced are known for the purpose of imparting the silicone derivative with residual properties on the skin and hair. However, since they are cationic, it is difficult to stably compound them in a composition based on an anionic surfactant, and there are drawbacks that they are not foamable and do not have a good feel during rinsing. .

Therefore, it improves the flexibility of the skin and hair, dryness and dryness, spreads well when used, is familiar, and cleanses the skin during rinsing.
The hair does not feel squeaky, it has a slippery, smooth feel,
There has been a demand for the development of a rinse-off type skin hair treatment composition which maintains its feeling even after continuous rinsing, has little oily feel when dried, and has excellent smoothness.

[Means for Solving the Problems]

In such an actual situation, the present inventors have conducted intensive research to solve the above problems, and as a result, if a hydroxy group-containing modified silicone derivative having specific physical properties is blended,
It has been found that a rinse-off type skin hair treatment composition which has a good feel at the time of rinsing and drying, and which is non-greasy, has a high effect of preventing dryness and dryness, can be obtained.
The present invention has been completed.

That is, the present invention is characterized by containing a modified silicone derivative which has at least one hydroxy group in the molecule, exists in a liquid state at 25 ° C., and is dispersed in an aqueous medium to exhibit birefringence. Accordingly, the present invention provides a rinse-off type skin hair treatment composition.

The modified silicone derivative used in the present invention has the above-mentioned physical properties, and its organopolysiloxane skeleton may be linear, branched or network. Further, the hydroxy group in the modified silicone derivative molecule preferably exists as a group represented by the following formula (1) or (2).

(1) R ¹ aOCbH ₂ bOcH [In the formula, R ¹ represents a divalent hydrocarbon group, a represents 0 or 1, b represents an integer of 1 to 5, and c represents an integer of 1 to 20. Examples of the divalent hydrocarbon group for R ¹ include a methylene group, an ethylene group, a propylene group, a butylene group, and —CH ₂ CH (CH ₃ ) CH ₂ —
Branched alkylene group such _{as, - (CH 2) 2 -C} 6 H 4
Examples of the alkylenearylene group such as-
Of these, an alkylene group, particularly a propylene group is preferable.

In the group represented by the formula (1), a = 1 and b is 2 or 3
It is preferable that c is an integer of 5 to 15. here,
c pieces of -CbH ₂ bo- is, b is those 2 or 3 may be bonded in a block state or random shape.

[In the formula, R ¹ has the same meaning as described above, a represents 0 or 1, and d represents an integer of 0 to 10] In the group represented by (2), a = 1 and d is 2 What is an integer of -4 is preferable.

In the organosiloxane forming the modified silicone derivative, a methyl group, an ethyl group, a propyl group, a lauryl group, an alkyl group such as a stearyl group as a functional group other than the above,
Vinyl group, alkenyl group such as allyl group, phenyl group,
An aryl group such as a naphthyl group and a cycloalkyl group such as a cyclohexyl group can be contained, but a group containing a methyl group is generally used.

Particularly preferred modified silicone derivatives include those represented by the following general formula (I), (II) or (III).

[In the formula, R ² represents a group represented by the above (1) or (2), m and n have an HLB value of 1.5 to 6.5, and a molecular weight of 2,000 to
These modified silicone derivatives can be prepared according to known methods, for example, according to the method described in JP-A-56-22712.
It is obtained by heating an organohydrogen polysiloxane and a (poly) oxyalkylene monoaryl ether in the presence of a platinum catalyst to cause a reaction.

The modified silicone derivative in the present invention exists in a liquid state at 25 ° C., but is preferably transparent or slightly cloudy, has a high fluidity, and has a viscosity of 200 to 10,000 cSt.

Further, the modified silicone derivative in the present invention is a solution dispersed in water, for example, when a 50% aqueous solution is prepared, it exhibits birefringence or flow birefringence when observed with a polarizing plate or a polarizing microscope at room temperature. .

The modified silicone derivative in the present invention forms a liquid crystal in water because it is in a liquid state at room temperature, exhibits birefringence in water, and a DSC measurement shows no melting peak of crystals. It is thought that

In the above formulas (I), (II) and (III), when n is large, hydrophilicity is high and the polymer is transparently dissolved in water, and birefringence is not observed. On the other hand, when m is too large, hydrophobicity is high. Becomes higher and the oil-like dispersion occurs in water, and birefringence is not seen. Therefore, in order for the modified silicone derivative to form a liquid crystal, a balance between the numbers of m and n, that is, a certain hydrophilic / hydrophobic balance (HLB) is required, and the HLB is 1.
Those having a ratio of 5 to 6.5 are preferable because they tend to exhibit birefringence.

HLB here is calculated by the following formula.

Commercially available products of the modified silicone derivative of the present invention are preferably KF-6005 (Shin-Etsu Chemical Co., Ltd.), SH3772C, S
H3775C (Toray Dow Corning Silicone Co., Ltd.)
Etc.

The specific modified silicone derivative of the present invention forms a liquid crystal in an aqueous medium and disperses it, and therefore has peculiar spreadability and familiarity to the liquid crystal, and moreover, since it slides while holding water,
Despite being a silicone, it does not have a squeaky feeling in water that is characteristic of dimethylpolysiloxane, and unlike general water-soluble polyether-modified silicone, it does not run into water even when rinsed with water, so it has a good feel. Is sustained.

These modified silicone derivatives are added to the composition of the present invention in an amount of 0.
It is preferable that the blending amount be from 01 to 99% by weight, particularly from 0.1 to 95% by weight.

The skin hair treatment composition of the present invention is a treatment composition of a type that is rinsed with water after being applied to the skin or hair, and specifically, to a cleaning composition and a conditioning composition such as a rinse and a treatment. Broadly divided.

When the composition of the present invention is a cleansing composition for skin / hair, a cleaning component such as an anionic surfactant, an amphoteric surfactant, a nonionic surfactant or a cationic surfactant may be further added. Be compounded.

Examples of the aonic surfactant, amphoteric surfactant, and nonionic surfactant include the following.

<Anionic surfactant> (1) Having an alkyl group having an average carbon number of 10 to 16. Straight-chain or branched-chain alkylbenzene sulfonate, (2) having a straight-chain or branched-chain alkyl or alkenyl group having an average carbon number of 10 to 20 and having an average of 0.5 to 8 mol of ethylene oxide or propylene oxide in one molecule. , Butylene oxide, an alkyl or alkenyl ether sulfate in which ethylene oxide and propylene oxide are added at a ratio of 0.1 / 9.9 to 9.9 / 0.1 or ethylene oxide and butylene oxide are added at a ratio of 0.1 / 9.9 to 9.9 / 0.1.

(3) An alkyl or alkenyl sulfate having an alkyl group or an alkenyl group having an average carbon number of 10 to 20.

(4) An olefin sulfonate having an average of 10 to 20 carbon atoms in one molecule.

(5) An alkanesulfonate having an average of 10 to 20 carbon atoms in one molecule.

(6) A saturated or unsaturated fatty acid salt having an average of 10 to 24 carbon atoms in one molecule.

(7) It has an alkyl group or an alkenyl group having an average carbon number of 10 to 20, and an average of 0.5 to 8 moles of ethylene oxide, propylene oxide, butylene oxide, ethylene oxide and propylene oxide in one molecule is 0.1 / 9.9 to.
Alkyl or alkenyl ether carboxylates in which ethylene oxide and butylene oxide are added in a ratio of 9.9 / 0.1 or in a ratio of 0.1 / 9.9 to 9.9 / 0.1.

(8) An α-sulfone fatty acid salt or ester having an alkyl group or an alkenyl group having an average of 10 to 20 carbon atoms.

(9) An N-acyl amino acid type surfactant having an acyl group having 8 to 24 carbon atoms and a free carboxylic acid residue or a sulfonic acid residue.

(10) A phosphoric acid mono- or diester type surfactant having an alkyl group or an alkenyl group having 8 to 24 carbon atoms or an ethoxylate thereof.

(11) A sulfosuccinate such as a higher alcohol having 8 to 22 carbon atoms or its ethoxylate, or a sulfosuccinate derived from a higher fatty acid amide.

(12) Higher fatty acid monoethanol amide or diethanol amide having 8 to 20 carbon atoms, or their sulfonates such as ethoxylates.

(13) Monoglyceride sulfonate having 8 to 20 carbon atoms.

(14) A salt of a condensate of a higher fatty acid having 8 to 20 carbon atoms and isethionic acid.

<Amphoteric surfactant> (15) An α-position addition type secondary amide or tertiary amide type imidazoline type amphoteric surfactant having an alkyl group, an alkenyl group or an acyl group having 8 to 24 carbon atoms.

(16) Carbobetaine-based, amidobetaine-based, sulfobetaine-based, hydroxysulfobetaine-based having an alkyl group, an alkenyl group, or an acyl group having 6 to 24 carbon atoms,
Alternatively, an amidosulfobetaine-based amphoteric surfactant.

<Nonionic Surfactant> (17) A polyoxyalkylene alkyl ether having a linear or branched alkyl or alkenyl group having an average carbon number of 10 to 24, to which ethylene oxide, propylene oxide or butylene oxide is added, or Polyoxyalkylene alkenyl ether.

(18) Ethoxylate of monoglyceride having 8 to 20 carbon atoms.

(19) Higher fatty acid sucrose ester having 8 to 20 carbon atoms.

(20) A polyglycerin fatty acid ester having an acyl group having 8 to 20 carbon atoms.

(21) Higher fatty acid monoethanol amide or diethanol amide having 8 to 20 carbon atoms or their ethoxylates.

(22) Polyoxyethylene hydrogenated castor oil.

(23) Polyoxyethyne sorbitan fatty acid ester having an acyl group having 8 to 20 carbon atoms.

(24) Polyoxyethylene sorbit fatty acid ester having an acyl group having 8 to 20 carbon atoms.

(25) An alkyl saccharide-based surfactant having a linear or branched alkyl group, alkenyl group or alkylphenyl group having 8 to 18 carbon atoms.

(26) An alkylamine oxide or an alkylamidoamine oxide having a linear or branched alkyl group having 8 to 20 carbon atoms or an alkenyl group.

As the counterion of the anionic residue of these surfactants, alkali metal ions such as sodium and potassium, alkaline earth metal ions such as calcium and magnesium,
Examples thereof include ammonium ion and alkanolamines having 1 to 3 alkanol groups having 2 or 3 carbons (for example, monoethanolamine, diethanolamine, triethanolamine, triisopropanolamine, etc.). Examples of the counter ion of the cationic residue include halogen ions such as chlorine, bromine and iodine, and methosulfate and saccharinate ions.

Among these surfactants, (2) alkyl ether sulfate, (3) alkyl sulfate, (16) saturated or unsaturated fatty acid salt, (9) acylated amino acid, (10) phosphate monoester type interface Activators, (11) sulfosuccinates, (12) amide ether sulphates, (15) secondary amide type imidazoline-based amphoteric surfactants, especially amidoamine acid-type amphoteric surfactants that are desalted to improve the solubility of the polymer. Agent (JP-A-63-128100), (16) amidobetaine or hydroxysulfobetaine, (17) polyoxyethylene alkyl ether, (21) higher fatty acid diethanolamide, (25) alkyl saccharide, or (26)
Alkyl amine oxides are preferred as the main activator.
As a preferred specific example, sodium polyoxyethylene lauryl ether sulfate (ethylene oxide average 2-3)
Mol addition), triethanolamine lauryl sulfate, coconut oil fatty acid sodium salt, coconut oil fatty acid amide ether sulfate, lauroyl-N-methyltaurine, lauroyl-N-methyl-β-alanine, polyoxyethylene lauryl disodium sulfosuccinate ( 3-7E.
O.), lauryl phosphoric acid, N-lauroyl-N'-carboxymethyl-N '-(2-hydroxyethyl) ethylenediamine triethanolamine salt, N-lauroyl-N
-(2-hydroxyethyl) -N ', N'-bis (carboxymethyl) ethylenediamine sodium salt, decyl polyglucoside, lauryl hydroxysulfobetaine, lauric acid amidopropyl dimethylaminoacetic acid betaine,
Examples thereof include polyoxyethylene (20) lauryl ether, coconut oil fatty acid diethanol amide, and lauryl amine oxide.

These surfactants are preferably incorporated in the composition in an amount of 1 to 90% by weight. In particular, it is preferable to add 30 to 90% by weight for a solid formulation, 20 to 60% by weight for a paste formulation, and 10 to 40% by weight for a liquid formulation.

These detergent compositions have a pH of 3 to 1 due to known acidic or alkaline agents used for ordinary detergent compositions.
It is preferable to adjust the pH to 0, especially pH 4 to 8.

In addition, in these detergent compositions, in addition to the above-mentioned essential components, components usually used in detergents, for example, squalene,
Lanolin, dimethylpolysiloxane, high molecular weight polysiloxane, methylphenylpolysiloxane, water-soluble polyether modified silicone, amino modified silicone, carboxy modified silicone, perfluoropolyether, JP-A-61-267505, JP-A-1-117821. Branched quaternary ammonium salts described in JP-A-58-5399.
No. 6, JP, 1-117821 JP, feel improver such as a cationic polymer, propylene glycol, glycerin, diethylene glycol monoethyl ether, moisturizers such as sorbitol, methyl cellulose, carboxyvinyl polymer, hydroxyethyl cellulose, Viscosity modifiers such as polyoxyethylene glycol distearate and ethanol, pearling agents, fragrances, dyes, UV absorbers, antioxidants, bactericides such as triclosan and trichlorocarban, anti-inflammatory agents such as potassium glycyrrhizinate and tocopherol acetate. Agents, anti-dandruff agents such as zinc pyrithione and octopirox, preservatives such as methylparaben and butylparaben, and other Encyclopedia of Shampoo Ingr
It is also possible to optionally add the components listed in edients (Micellepress, 1985) as long as the effects of the invention are not impaired.

When the composition of the present invention is a skin hair conditioning agent composition for rinsing, treatment, etc., it is preferable to add a linear or branched quaternary ammonium salt, particularly from the viewpoint of liquid crystal forming ability. It is preferable to add 0.01 to 20% by weight of a quaternary ammonium salt having a branched chain having 8 to 30 carbon atoms described in JP-A No. 61-267505 and JP-A No. 1-117821. If necessary, a higher alcohol having a linear or branched alkyl group or alkenyl group,
Lanolin or lanolin derivatives, esters, liquid paraffin, alkyl trimethylol, alkyl trimethylol amide, solid paraffin, dimethyl polysiloxane, high molecular weight polysiloxane, methylphenyl polysiloxane, water-soluble polyether modified silicone, amino modified silicone, carboxy Modified silicones, perfluoropolyethers, higher fatty acids, oils and fats such as long-chain amidoamines having alkyl or alkenyl groups, antidandruff agents, medicinal agents such as vitamins, preservatives such as parabens, water-soluble polymers, etc. Thickeners, coloring agents such as dyes and pigments, conditioning agents such as cationic polymers, pearling agents such as glycol esters, hair setting polymers such as acrylic resin liquids, propylene glycol, glycerin, diethylene glycol Ethyl ether, glucose, humectants such as sorbitol, various blended fragrance other, Encyclop
edia of Conditioning Rinse Ingredients (Micelle pr
Ingredients listed in Ess, 1987) can be appropriately mixed.

Particularly, it is preferable to add 0.01 to 20% by weight of the branched quaternary ammonium salt described in JP-A-61-267505 and JP-A-1-117821 to the composition of the present invention.

〔The invention's effect〕

The water-rinsing type skin hair treatment composition of the present invention spreads well when used, is familiar, has a smooth, smooth skin feel when rinsing, and retains that feeling even after continuous rinsing. However, it has excellent smoothness and flexibility when dried, and is not sticky, and has an excellent effect of preventing dryness and dryness.

〔Example〕

Hereinafter, the present invention will be specifically described with reference to Reference Examples and Examples, but the present invention is not limited to these Reference Examples and Examples.

Reference Example 1 For various silicone polymers shown in Table 1 below,
Samples were filled in 0 ml glass bottles and observed for appearance and flowability at 25 ° C.

Also, prepare a 50% aqueous solution or aqueous dispersion, and
The presence or absence of birefringence was observed using a polarizing plate or a polarizing microscope at (° C).

(Evaluation criteria) Appearance ○: Transparent or slightly turbid ×: Opaque Fluidity ○: Liquid flows when the glass bottle is tilted.

X: The liquid does not flow even if the glass bottle is tilted.

Birefringence ○: Birefringence is recognized.

X: No birefringence is observed.

Example 1 A detergent composition (pH = 7) having the composition shown in Table 2 below was produced, and for each of them, spreadability, familiarity, feel on hair / skin at the time of rinsing, smoothness at the time of drying, flexibility, The evaluation of stickiness, dryness and dryness was performed.

In each evaluation, 20 g (15 cm) of hair of a Japanese woman treated with a perm was applied with 1 g of the cleaning liquid, and spreads and spreads until it foams, and the feel of rinsing with running water at 40 ° C and the feel after rinsing sufficiently About the feel of hair after drying with a dryer, take 1 g of the washing liquid on the palm, add tap water appropriately and spread and familiarize until foaming, rinsing start and rinsing end and hand skin after drying Special panel 5 It was done by name.

<Evaluation Criteria> Spread / Familiarity ○: Spread / Familiarity is good.

Δ: Inadequate spread and familiarity ×: Poor spread and familiarity ○: Feeling during rinsing ○: No creaking, smooth and slippery

Δ: Slightly squeaky, smooth and non-smooth.

X: Strong squeaky, no smoothness and slippery feeling at all.

Feeling after drying ○: Good and soft, △: Slightly insufficient slip, insufficient softness ×: Poor, poor softness, dryness and dryness ○: No dryness and dryness.

Δ: Somewhat dry and dry.

X: Dryness and dryness are strongly felt.

Sticky ○: Not sticky △: Slightly sticky ×: Sticky Example 2 A hair rinse composition having the composition shown in Table 3 below was prepared, and spread, familiarity, and feel during rinsing,
The dry feel was evaluated.

For the evaluation, the same hair as in Example 1 was used. After shampooing, 2 g of a rinse agent was applied, followed by rinsing with running water at 40 ° C., towel drying, and drying with a drier. Each sensory evaluation of this hair bundle was carried out by 5 dedicated panelists based on the same evaluation criteria as in Example 1.

Preparation method of composition: After heating to 70 ° C., the components which were heated to the same temperature and dissolved, and were added and well stirred to emulsify,
The mixture was cooled to room temperature with stirring to obtain a hair rinse composition.

Example 3 A shampoo having the composition shown below was produced. It spreads well during use, has no squeaky feeling during rinsing, has a smooth and slippery feel, has a long-lasting feeling even after continuous rinsing, has excellent smoothness and flexibility after drying, and is non-greasy and dry. I didn't feel dry.

(Wt%) N-lauroyl-N'-carboxymethyl-N'-
(2-Hydroxyethyl) elenediamine TEA salt 10 Polyoxyethylene (5) disodium lauryl sulfosuccinate 5 Modified silicone derivative (compound of Table 1) 3 Coconut oil fatty acid amidopropyl betaine 2 Monodecanoic acid glyceride 1 Perfume 0.5 Dye suitable Water balance Example 4 An anti-dandruff shampoo having the composition shown below was produced.

It spreads well during use, has no squeaky feeling during rinsing, has a smooth and slippery feel, has a long-lasting feeling even after continuous rinsing, has excellent smoothness and flexibility after drying, and is non-greasy and dry. I didn't feel dry.

The antidandruff effect was also good.

(% By weight) Lauryl sulfate triethanolamine salt 10 Polyoxyethylene (2) disodium lauryl sulfosuccinate 6 Modified silicone derivative (compound of Table 1) 2 Lauryl hydroxysulfobetaine 1 Trimethylol isoheptadecane 1 Cationic polymer ( (Gaff coat 755N, made by Gaff) 0.
5 Lanolin fatty acid aminopropylethyldimethylammonium ethosulfate 0.2 Octopirox 0.5 Fragrance, dye Appropriate amount Water balance Example 5 An anti-dandruff shampoo having the composition shown below was produced. It spreads well during use, has no squeaky feeling during rinsing, has a smooth and slippery feel, has a long-lasting feeling even after continuous rinsing, has excellent smoothness and flexibility after drying, and is non-greasy and dry. I didn't feel dry.

 (Wt%) The anti-dandruff effect was also good.

3- (N-lauroylaminoethyl-N-hydroxydiethyl) amino-2-hydroxy-1-propanesulfonic acid TEA salt 12 Polyoxyethylene (3) lauryl ether sulfate sodium salt 5 Modified silicone derivative (compounds in Table 1) ) 5 Lauryl dimethyl amine oxide 2 Cationized guar gum (Diaguar C-13-S, manufactured by Celanese-Stein Hall) 0.1 Polyvinyl alcohol 0.5 Zinc pyrithione 1.0 Perfume, dye, proper amount water balance Example 6 A conditioning shampoo having the composition shown below is used. Manufactured.

It spreads well during use, has no squeaky feeling during rinsing, has a smooth and slippery feel, has a long-lasting feeling even after continuous rinsing, has excellent smoothness and flexibility after drying, and is non-greasy and dry. I didn't feel dry.

(Wt%) N-lauroyl-N'-carboxymethyl-N'-
(2-Hydroxyethyl) elenediamine TEA salt 10 Coconut oil fatty acid amide ether sulfate sodium salt (Genapol AMS-Na, manufactured by Hoechst) 5 Lauric acid monoethanolamide 2 Lauryl dimethylamino acetic acid betaine 2 Modified silicone derivative (Table 1 Compound 1) Cationized cellulose (Polymer JR400, manufactured by UCC) 0.5 2-Dodecylhexadecyltrimethylammonium chloride 0.5 Monodecanoic acid glyceride 1 Amodimethicone emulsion (SM87020, manufactured by Toray Dow Corning Silicone Co., Ltd.) 0.2 Perfume, dye suitable Water balance Example 7 A shampoo having a rinse effect having the composition shown below was produced. It spreads well during use, has no squeaky feeling during rinsing, has a smooth and slippery feel, and retains that feeling even after continuous rinsing, has excellent smoothness and flexibility after drying, is non-greasy, and has a dry feel. , I didn't feel dry.

(Wt%) N-lauroyl-N- (2-hydroxyethyl)-
N ', N'-bis (carboxymethyl) ethylenediamine
TEA salt 10 Polyoxyethylene (4) lauryl ether carboxylate sodium salt 8 Lauroyl-N-methyl-β-alanine sodium 4
Lauryl Amidopropyl Dimethylamino Acetate Betaine 2 Cationized Cellulose Derivative (QUATRISOFT POLYMER L
M-200, Amerchol) 0.5 2-decyltetradecyltrimethylammonium chloride 0.5 Modified silicone derivative (SH3775C, Toray Dow Corning Silicone) 5 Dimethylpolysiloxane (10000000cst at 25 ℃) 1 Perfume, pigment, herb extraction Liquid pH adjusting agent (pH adjusted to 6 to 7) Water amount balancing Example 8 Example 8 A face-wash foam having the composition shown below was produced. It spreads well during use, has no squeaky feeling during rinsing, has a smooth and slippery feel, has a long-lasting feeling even after continuous rinsing, has excellent smoothness and flexibility after drying, and is non-greasy and dry. I didn't feel dry.

(Wt%) alkylsaccharide _{(C 12 - (EO) 2} - (G) 2.5)
^{* 2)} 30 Disodium lauryl sulfosuccinate 30 Modified silicone derivative (Compound of Table 5 in Table 1) 10 Lauric acid 5 Ethylene glycol distearate ^{* 3)} 4 Fragrances, pigments, herbal extracts Appropriate amount water balance * 2) C ₁₂ : Lauryl group, G: glucose residue * 3) Emanone 3201M (manufactured by Kao) Example 9 A solid detergent having the composition shown below was produced. It spreads well during use, has no squeaky feeling during rinsing, has a smooth and slippery feel, and retains that feeling even after continuous rinsing, has excellent smoothness and flexibility after drying, is non-greasy, and has a dry feel. , I didn't feel dry.

(% By weight) Sodium monolauryl phosphate 60 Sodium dilauryl phosphate 20 Modified silicone derivative (compound of Table 6) 10 Polyoxyethylene (10) lauryl ether 3 Carboxymethyl chitin 0.005 Perfume 0.3 Dye minute amount Baraben 0.3 Water balance Example 10 A creamy handwash having the composition shown below was produced. It spreads well during use, has no squeaky feeling during rinsing, has a smooth and slippery feel, and retains that feeling even after continuous rinsing, has excellent smoothness and flexibility after drying, is non-greasy, and has a dry feel. , I didn't feel dry.

(Wt%) Sodium monolauryl phosphate 35 Sodium monocetyl phosphate 10 Modified silicone derivative (KF6005, Shin-Etsu Chemical Co., Ltd.)
5 Lauryl hydroxysulfobetaine 1 Lauryl amine oxide 1 Diethylene glycol monoethyl ether 2 Triclosan 0.1 Sodium chloride 5 Polyethylene glycol (molecular weight 8000) 2 Water balance Example 11 A body shampoo having the composition shown below was produced. It spreads well during use, has no squeaky feeling during rinsing, has a smooth and slippery feel, and retains that feeling even after continuous rinsing, has excellent smoothness and flexibility after drying, is non-greasy, and has a dry feel. , I didn't feel dry.

(Wt%) of monolauryl phosphate ditriethanolamine 35 alkyl saccharide ^{_{(C 12 -O- (G) 2}} ) * 4) 1
0 Lauric acid 3 Cocoyl-N-methyl-taurate 2 Cocoyl isethionate 2 Modified silicone derivative (SH3772C, manufactured by Toray Dow Corning Silicone Co., Ltd.) 4 Myristylamine oxide 1 Squalene 0.1 Perfluoropolyether (FOMBLIN HC / 25, Montefluos) 0.1) Denatured ethanol 3 Cationized silk protein hydrolyzate 0.05 Fragrance, pigment, preservative, pH adjuster Water balance * 4) C ₁₂ : Cocoyl group, G: Galactose residue Example 12 Composition shown below A face cleanser for makeup removal was manufactured. It spreads well during use, has no squeaky feeling during rinsing, has a smooth and slippery feel, and retains that feeling even after continuous rinsing, has excellent smoothness and flexibility after drying, is non-greasy, and has a dry feel. , I didn't feel dry.

(Wt%) monolauryl phosphate ditriethanolamine 10 polyoxyethylene (4) lauryl ether sulfate triethanolamine 5 cocoyl glutamate monosodium 3 coconut oil fatty acid sucrose ester (DK ester S-L18A,
Dai-ichi Kogyo Seiyaku Co., Ltd. 3 Modified silicone derivative (compound of Table 1 in Table 1) 30 Decamethylcyclopentasiloxane 20 Polyoxyethylene (20) sorbitan monolaurate 2 Perfume proper amount water balance Example 13 Manufactured hair treatments. It spreads well during use, has no squeaky feeling during rinsing, has a smooth and slippery feel, and retains that feeling even after continuous rinsing, has excellent smoothness and flexibility after drying, is non-greasy, and has a dry feel. , I didn't feel dry.

(Wt%) 2-dodecylhexadecyltrimethylammonium chloride 2 stearyltrimethylammonium chloride 5 modified silicone derivative (compound of Table 1) 5 stearyl alcohol 5 lanolin 3 liquid paraffin 3 polypeptide (collagen hydrolyzate) 5 hydroxyethylcellulose ( 1% aqueous solution viscosity 8.000
cp) 0.5 Polyoxyethylene (5) oleyl ether 0.5 Methylparaben 0.2 Perfume 0.4 Water balance Example 14 An anti-dandruff conditioner having the composition shown below was produced.
It spreads well during use, has no squeaky feeling during rinsing, has a smooth and slippery feel, and retains that feeling even after continuous rinsing, has excellent smoothness and flexibility after drying, is non-greasy, and has a dry feel. , I didn't feel dry.

The antidandruff effect was also good.

(Wt%) Dialkyldimethylammonium chloride (same as those in Examples 2 and 3) 1 Cetyltrimethylammonium chloride 1 Modified silicone derivative (KF-6005, manufactured by Shin-Etsu Chemical Co., Ltd.) 5 Cetostearyl alcohol 3 Vaseline 0.5 Sodium stearoyl lactylate 0.5 Lauryl glucoside 0.5 Zinc pyrithione 0.2 Octopirox 0.2 Hydroxypropyl methylcellulose (Metroze 60
SH-4000, manufactured by Shin-Etsu Chemical Co., Ltd. 0.5 Amodimethicone emulsion (SM-8702C, manufactured by Toray Dow Corning Silicone Co., Ltd.) 0.5 Dimethylpolysiloxane (10000000cst at 25 ° C) 0.5 Perfume, Dye Proper Water Balance Example 15 A hair hot oil treatment having the composition shown below was produced. It spreads well during use, has no squeaky feeling during rinsing, has a smooth and slippery feel, and retains that feeling even after continuous rinsing, has excellent smoothness and flexibility after drying, is non-greasy, and has a dry feel. , I didn't feel dry.

(Wt%) 2-dodecyltetradecyltrimethylammonium chloride 10 Lanolin fatty acid aminopropylethyldimethylammonium ethosulfate 2 Modified silicone derivative (SH3775C, Toray Dow Corning Silicone Co., Ltd.) 80 Jojoba oil 5 Pantothenyl alcohol 0.5 Tocopherol 0.5 Benzophenone 0.1 Fragrance 0.3 Isoprene glycol (manufactured by Kuraray Co., Ltd.) 1.6 Example 16 A body treatment having the composition shown below was produced. It spreads well during use, has no squeaky feeling during rinsing, has a smooth and slippery feel, and retains that feeling even after continuous rinsing, has excellent smoothness and flexibility after drying, is non-greasy, and has a dry feel. , I didn't feel dry.

(Wt%) 2-hexadecylphosphoric acid arginine salt 1 2-ethylhexanoic acid glyceride 20 2-ethylhexanoic acid neopentyl glycol 20 modified silicone derivative (compound of Table 1) 20 N-tris (hydroxymethyl)- Isostearic acid amide 3 Olive oil 3 Squalane 3 Sorbitol 10 Diethylene glycol monoethyl ether 10 Fragrance, pigment Appropriate amount Water balance

Claims (1)

[Claims] 1. Water containing a modified silicone derivative having at least one hydroxy group in the molecule, existing in a liquid state at 25 ° C., and exhibiting birefringence when dispersed in an aqueous medium. A rinse-off type skin hair treatment composition.