JPH0751215B2 - Method and apparatus for decomposing and removing carbon monoxide or carbon dioxide - Google Patents

Method and apparatus for decomposing and removing carbon monoxide or carbon dioxide

Info

Publication number
JPH0751215B2
JPH0751215B2 JP2128992A JP12899290A JPH0751215B2 JP H0751215 B2 JPH0751215 B2 JP H0751215B2 JP 2128992 A JP2128992 A JP 2128992A JP 12899290 A JP12899290 A JP 12899290A JP H0751215 B2 JPH0751215 B2 JP H0751215B2
Authority
JP
Japan
Prior art keywords
carbon
ions
decomposing
carbon dioxide
carbon monoxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP2128992A
Other languages
Japanese (ja)
Other versions
JPH0422416A (en
Inventor
英明 林
一敏 長井
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ebara Corp
Original Assignee
Ebara Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ebara Corp filed Critical Ebara Corp
Priority to JP2128992A priority Critical patent/JPH0751215B2/en
Publication of JPH0422416A publication Critical patent/JPH0422416A/en
Publication of JPH0751215B2 publication Critical patent/JPH0751215B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02CCAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00Capture or disposal of greenhouse gases
    • Y02C20/40Capture or disposal of greenhouse gases of CO2

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  • Treating Waste Gases (AREA)

Description

【発明の詳細な説明】Detailed Description of the Invention 【産業上の利用分野】[Industrial applications]

本発明は、一酸化炭素又は二酸化炭素分解除去方法及び
除去装置に関し、更に詳述すれば、電気力分離処理によ
る分解除去方法及び除去装置に関する。
The present invention relates to a carbon monoxide or carbon dioxide decomposing / removing method and a removing apparatus, and more specifically to a decomposing / removing method and an removing apparatus by an electric force separation process.

【従来の技術】[Prior art]

近年、地球温暖化の防止対策として、例えば二酸化炭素
(CO2)の回収処理技術の開発が急務である。 従来技術における一酸化炭素又は二酸化炭素の大規模な
除去方法並びに装置としては、例えば、湿式処理による
分離回収や固定の他に、植物,海洋などの自然環境によ
る固定等が考慮できる。
In recent years, as a preventive measure against global warming, for example, development of carbon dioxide (CO 2 ) recovery processing technology is urgently needed. As a large-scale method and apparatus for removing carbon monoxide or carbon dioxide in the prior art, for example, fixing by a natural environment such as a plant or the ocean can be considered in addition to separation and recovery by a wet treatment and fixation.

【発明が解決しようとする課題】[Problems to be Solved by the Invention]

しかしながら、上記の何れの方法でも、適用される装置
の大規模化、装置コスト及び運転コストの高騰化、周辺
近隣への環境面での影響等に対して解決すべき問題を多
く含んでいた。 本発明の目的は、上記実情に基づいてなされたものであ
り、一酸化炭素又は二酸化炭素を誘導結合ブラズマによ
り炭素原子と酸素原子に分解した後、C+,O-のイオンと
して電気的に簡単に分離,回収できる一酸化炭素又は二
酸化炭素分解除去方法を提供することにある。 又、本発明の他の目的は、分解されたC+イオンと反応す
る金属との結合物から有用物質が回収できる一酸化炭素
又は二酸化炭素分解除去方法を提供することにある。 更に、本発明の他の目的は、上記各方法が達成できる除
去装置を提供することにある。
However, any of the above methods involves many problems to be solved, such as large scale of the applied device, soaring of the device cost and operating cost, and environmental influence on the surrounding neighborhood. The object of the present invention has been made based on the above-mentioned circumstances, and after carbon monoxide or carbon dioxide is decomposed into carbon atoms and oxygen atoms by inductively coupled plasma, it is electrically simple as C + and O ions. Another object of the present invention is to provide a method for decomposing and removing carbon monoxide or carbon dioxide that can be separated and collected. Another object of the present invention is to provide a method for decomposing and removing carbon monoxide or carbon dioxide, in which a useful substance can be recovered from a combined product of a metal that reacts with decomposed C + ions. Further, another object of the present invention is to provide a removing device which can achieve each of the above methods.

【課題を解決するための手段】[Means for Solving the Problems]

本発明の上記目的は、一酸化炭素又は二酸化炭素を誘導
結合プラズマ発生用高周波コイルによりプラズマ化し、
電離した炭素イオン及び酸素イオンを直流電圧が印加さ
れた一組の電極で電界吸引し、前記酸素イオン及び前記
炭素イオンをそれぞれ分離する一酸化炭素又は二酸化炭
素分解除去方法により達成される。 又、本発明の他の目的は、一酸化炭素又は二酸化炭素を
誘導結合プラズマ発生用高周波コイルによりプラズマ化
し、電離した炭素イオン及び酸素イオンを直流電圧が印
加された一組の電極で電界吸引して酸素イオンを大気中
に放出すると共に、分離した炭素イオンを金属該炭素イ
オンと反応すると反応させることにより得られる結合物
として取り出し回収する一酸化炭素又は二酸化炭素分解
除去方法により達成される。 又、本発明の他の目的は、高周波発生用電源と接続し、
導入される一酸化炭素又は二酸化炭素をプラズマ放電に
より分解,電離する誘導結合プラズマ発生用高周波コイ
ルと、電離された酸素イオン及び炭素イオンを電界吸引
する一組の電極とを備えた放電管を、単独又は多段組み
合わせてなる一酸化炭素又は二酸化炭素分解除去装置に
より達成される。 更に、本発明の他の目的は、電離された炭素イオンと反
応する金属又は金属酸化物を充填した炭素イオン回収装
置を、上記装置の炭素イオンを吸引する電極の背面側の
放電管端部に更に追加して設置した装置により達成され
る。
The above object of the present invention is to convert carbon monoxide or carbon dioxide into plasma by a high frequency coil for inductively coupled plasma generation,
This is accomplished by a method of decomposing and removing carbon monoxide or carbon dioxide, in which the ionized carbon ions and oxygen ions are subjected to electric field attraction by a pair of electrodes to which a DC voltage is applied to separate the oxygen ions and the carbon ions. Another object of the present invention is to convert carbon monoxide or carbon dioxide into plasma by a high-frequency coil for generating inductively coupled plasma, and ionize the ionized carbon ions and oxygen ions with a set of electrodes to which a DC voltage is applied. Oxygen ion is released into the atmosphere, and the separated carbon ion is reacted with the metal carbon ion, and the carbon monoxide or carbon dioxide is decomposed and removed as a bound product obtained by reacting with the metal. Another object of the present invention is to connect to a high frequency power source,
A high-frequency coil for inductively coupled plasma generation for decomposing and ionizing introduced carbon monoxide or carbon dioxide by plasma discharge, and a discharge tube provided with a pair of electrodes for electric field attraction of ionized oxygen ions and carbon ions, This is achieved by a carbon monoxide or carbon dioxide decomposition and removal device which is used alone or in combination in multiple stages. Still another object of the present invention is to provide a carbon ion recovery device filled with a metal or a metal oxide that reacts with ionized carbon ions, at the end of the discharge tube on the back side of the electrode for attracting carbon ions of the device. This is achieved by the additionally installed device.

【作用】[Action]

一酸化炭素又は二酸化炭素を誘導結合プラズマによりプ
ラズマ化し、生じたイオンの電気的性質を利用して一酸
化炭素又は二酸化炭素の分解分離を行うことができる。
しかも、燃焼法等における過度の熱源を必要としないた
めに装置の小型化が実現できる。 なお、本明細書において述べる「一酸化炭素又は二酸化
炭素」の記載は、両者が共存する場合も含むものであ
る。
Carbon monoxide or carbon dioxide can be converted into plasma by inductively coupled plasma, and the electrical properties of the generated ions can be used to decompose and separate carbon monoxide or carbon dioxide.
Moreover, since the excessive heat source in the combustion method or the like is not required, the device can be downsized. In addition, the description of "carbon monoxide or carbon dioxide" described in the present specification includes the case where both coexist.

【実施例】【Example】

以下、本発明の一酸化炭素又は二酸化炭素分解除去方法
及び装置について図を用いて説明する。 第1図は、本発明を達成するための除去装置の構成図で
ある。 図において、この除去装置は、略T字形状をした石英製
の放電管1により構成されている。前記放電管1は分解
されるべきガス、本実施例では二酸化炭素(CO2)ガス
が導入される管路上を巻装する誘導結合プラズマ(ICP:
Inductively Coupled Plasma)発生用高周波コイル2を
配置しており、前記ICP発生用高周波コイル2は高周波
発生用電源3と接続されている。又、前記放電管1はガ
スが導入される管路に対して略直角方向に延設された管
路内に、一組の電極5,6を配置しており、前記電極5,6は
イオン分解電界用電極4と接続されて直流電圧が印加さ
れている。前記放電管1の、正電圧が印加される電極5
側の端部は排気ポンプ10と連通されており、一方、負電
圧が印加される電極6側の端部が閉鎖されている。 上記構成の装置において、分解すべきCO2ガス7を前記
放電管1の導入口1aより管内に導入して1気圧の圧力と
し、前記高周波発生用電源3より前記IPC発生用高周波
コイル2に例えば27.12MHzの高周波電力をかけると、前
記放電管1内のCO2ガス7は誘導結合プラズマとなって
C原子とO原子とに分解する。その際、分解したC原子
とO原子とを比較すると、電離電圧に関してはC原子が
11.26eVと、O原子の13.61eVよりも低いので正イオンに
なり易く、一方、電子親和力に関してはO原子が3.08eV
と、C原子の1.12eVよりも大であるので負イオンとなり
易い。従って、最適な放電条件のもとではCO2ガス7は
その殆どがC+とO-とに分解電離する。この分解電離した
イオンに対して前記電極5,6により電界をかけると、C+
イオン9とO-イオン8とはそれぞれ異符号の電極に向か
って吸引され、移動する。 なお、このときのイオンの移動度は、前記電極5,6の大
きさ、電極間距離及び印加電圧等により決まる電界強度
に左右される。因みに、本実施例では、放電管の管径t
を30mmφ、電極間距離lを50〜100mm、印加電圧を100〜
数100Vの範囲とし、且つ前記電極5,6は、図には詳細に
示していないが、管路に沿って配置される円筒形状と
し、その円筒長を10mm、肉厚を数mm厚、外径寸法をほぼ
前記管径tと等しい値として設定した。その結果、イオ
ン分離が好適に行われ、且つ常圧下で導入されるCO2
数%〜数10%のイオン化率でイオン化していることが観
察できた。 陽極5側に吸引されるO-イオン8は該電極5を通過し、
前記排気ポンプ10により排気されて大気中に放出され
る。一方、陰極6側に吸引されるC+イオン9は該電極6
を通過し、装置の器壁に衝突してそこに固定された後、
回収されて除去される。 第2図は本発明の他の実施例を実現する除去装置を示し
たもので、先の第1図に示した装置が多段連結されて構
成されている。 なお、同一箇所には同一符号を付して説明は省略する。 即ち、この除去装置は、C+イオン及びO-イオンが分解さ
れて移動する放電管1の端部に、第2及び第3の除去装
置が連結されている。この第2及び第3の除去装置は、
第1図に示したものと同一の構成からなっている。 このように構成する除去装置では、一段目で分割された
CO2ガス7は、既述の理論に基づいて第2及び第3の除
去装置により更に分解され、そのイオン化率が向上され
て、C+イオン及びO-イオンが取り除かれる。 第3図は本発明の更に他の実施例における除去装置であ
る。 この実施例において、符号1〜10の構成要素について
は、先の第1図の実施例と同一機能及び同一動作を有す
る。 この実施例における装置は、先の第1図に示した装置の
陰極6の背面側に位置する放電管端部に、炭素イオン回
収装置11が連通して配置されている。 前記炭素イオン回収装置11は、分解されたC+イオン9と
反応して該C+イオン9を固定除去できる金属または金属
酸化物が充填されて構成されている。 前記C+イオンと反応する金属としては、例えばFe,Co,N
i,Mnの少なくともいずれか一つが適用できる。 上記の如く構成した除去装置では、O-イオン8は排気ポ
ンプ10により排気されると共に、分離されたC+イオン9
が励起状態で化学的に活性であるため前記炭素イオン回
収装置11内の該炭素イオンと反応する金属と容易に結合
して固定し、除去される。
Hereinafter, the method and apparatus for decomposing and removing carbon monoxide or carbon dioxide according to the present invention will be described with reference to the drawings. FIG. 1 is a block diagram of a removing device for achieving the present invention. In the figure, this removing device is composed of a substantially T-shaped quartz discharge tube 1. The discharge tube 1 is an inductively coupled plasma (ICP :) which is wound around a pipe into which a gas to be decomposed, in this embodiment, carbon dioxide (CO 2 ) gas is introduced.
A high frequency coil 2 for generating inductively coupled plasma is arranged, and the high frequency coil 2 for generating ICP is connected to a power source 3 for high frequency generation. Further, the discharge tube 1 has a pair of electrodes 5 and 6 arranged in a conduit extending in a direction substantially perpendicular to a conduit into which gas is introduced. A DC voltage is applied by being connected to the decomposition electric field electrode 4. Electrode 5 of the discharge tube 1 to which a positive voltage is applied
The end on the side is communicated with the exhaust pump 10, while the end on the side of the electrode 6 to which a negative voltage is applied is closed. In the apparatus having the above structure, CO 2 gas 7 to be decomposed is introduced into the tube through the inlet 1a of the discharge tube 1 to a pressure of 1 atm, and the high frequency power source 3 supplies the IPC generation high frequency coil 2 to the IPC generation high frequency coil 2, for example. When high frequency power of 27.12 MHz is applied, the CO 2 gas 7 in the discharge tube 1 becomes inductively coupled plasma and decomposes into C atoms and O atoms. At that time, when comparing the decomposed C atom and O atom, the C atom is
Since it is 11.26eV, which is lower than the 13.61eV of O atom, it is easy to become a positive ion, while the electron affinity of O atom is 3.08eV.
Since it is higher than 1.12 eV of C atom, it is likely to become a negative ion. Therefore, under the optimum discharge conditions, most of the CO 2 gas 7 is decomposed and ionized into C + and O . When an electric field is applied to the decomposed and ionized ions by the electrodes 5 and 6, C +
The ions 9 and the O ions 8 are attracted and move toward the electrodes having different signs. The mobility of ions at this time depends on the electric field strength determined by the size of the electrodes 5 and 6, the distance between the electrodes, the applied voltage, and the like. Incidentally, in the present embodiment, the diameter t of the discharge tube is
30 mmφ, distance between electrodes 1 is 50-100 mm, applied voltage is 100-
Although not shown in detail in the figure, the electrodes 5 and 6 have a cylindrical shape arranged along a duct, the cylindrical length is 10 mm, the wall thickness is several mm, and the outer The diameter was set to a value substantially equal to the tube diameter t. As a result, it was observed that the ion separation was suitably performed and that CO 2 introduced under normal pressure was ionized at an ionization rate of several% to several tens%. O ions 8 attracted to the anode 5 side pass through the electrode 5,
It is exhausted by the exhaust pump 10 and released into the atmosphere. On the other hand, C + ions 9 attracted to the cathode 6 side are
After passing through and colliding with the instrument wall and being fixed there,
Recovered and removed. FIG. 2 shows a removing device for realizing another embodiment of the present invention, which is constructed by connecting the devices shown in FIG. 1 above in multiple stages. The same parts are designated by the same reference numerals and the description thereof will be omitted. That is, in this removing device, the second and third removing devices are connected to the ends of the discharge tube 1 where C + ions and O ions are decomposed and move. The second and third removing devices are
It has the same structure as that shown in FIG. In the removing device configured in this way, the first stage is divided.
The CO 2 gas 7 is further decomposed by the second and third removing devices based on the above-mentioned theory, its ionization rate is improved, and C + ions and O ions are removed. FIG. 3 shows a removing device according to still another embodiment of the present invention. In this embodiment, the components denoted by reference numerals 1 to 10 have the same function and operation as those of the embodiment shown in FIG. In the device of this embodiment, a carbon ion recovery device 11 is arranged in communication with the end of the discharge tube located on the back side of the cathode 6 of the device shown in FIG. The carbon ion recovery unit 11 is a metal or metal oxide capable of fixing remove the C + ions 9 reacts with C + ions 9 decomposed is configured filled. Examples of the metal that reacts with the C + ion include Fe, Co, N
At least one of i and Mn can be applied. In the removing apparatus configured as described above, the O ions 8 are exhausted by the exhaust pump 10 and the separated C + ions 9 are discharged.
Is chemically active in the excited state, it is easily bonded and fixed to the metal that reacts with the carbon ions in the carbon ion recovery apparatus 11, and is removed.

【発明の効果】【The invention's effect】

以上記載したとおり、本発明によれば、誘導結合プラズ
マにより分解した炭素イオン及び酸素イオンの電気的性
質の差異を利用して該炭素イオン電気的に除去している
ので、CO2ガスの分解及び炭素イオンの回収が容易にで
き、且つ酸素イオンは大気中に放出すれば、環境回復に
も効力を有する。 又、上記方法は比較的簡単な構成の装置によって達成で
きる。 更に、炭素と金属との結合物質が生成され、この結合物
質から有用炭化水素等が回収でき、温室効果防止のため
のCO2除去対策の他に、別意の有用性が得られる。 又、従来装置に見られるような燃焼装置による分解を行
わず、誘導結合プラズマによる電気力分解を行っている
ので、温度の熱源を必要としないで装置の小型化が実現
できる。
As described above, according to the present invention, since the carbon ions and oxygen ions decomposed by the inductively coupled plasma are electrically removed by utilizing the difference in the electrical properties, the decomposition of CO 2 gas and the Carbon ions can be easily recovered, and if oxygen ions are released into the atmosphere, they have an effect on environmental recovery. Further, the above method can be achieved by a device having a relatively simple structure. Further, a binding substance of carbon and a metal is generated, and useful hydrocarbons and the like can be recovered from the binding substance, and thus, other usefulness can be obtained in addition to CO 2 removal measures for preventing the greenhouse effect. Further, the decomposition by the inductively coupled plasma is carried out without performing the decomposition by the combustion device as in the conventional device, so that the device can be miniaturized without the need of the heat source for temperature.

【図面の簡単な説明】[Brief description of drawings]

第1図は本発明の一実施例を説明する一酸化炭素又は二
酸化炭素分解除去装置の構成図、第2図は他の実施例を
説明する除去装置の構成図、第3図は更に他の実施例を
説明する除去装置の構成図である。 図中符号 1……放電管、2……誘導結合プラズマ発生用高周波コ
イル、3……高周波発生用電源、4……イオン分離電界
用電源、5……電極(陽極)、6……電極(陰極)、7
……CO2ガス、8……O-イオン、9……C+イオン、10…
…排気ポンプ、11……炭素イオン回収装置
FIG. 1 is a block diagram of a carbon monoxide or carbon dioxide decomposing / removing apparatus for explaining an embodiment of the present invention, FIG. 2 is a block diagram of a removing apparatus for explaining another embodiment, and FIG. It is a block diagram of the removal apparatus explaining an Example. Reference numeral 1 ... Discharge tube, 2 ... Inductively coupled plasma generation high-frequency coil, 3 ... High-frequency generation power supply, 4 ... Ion separation electric field power supply, 5 ... Electrode (anode), 6 ... Electrode ( Cathode), 7
…… CO 2 gas, 8 …… O - ion, 9 …… C + ion, 10…
… Exhaust pump, 11 …… Carbon ion recovery device

Claims (6)

【特許請求の範囲】[Claims] 【請求項1】放電管内に導入される一酸化炭素又は二酸
化炭素を誘導結合プラズマ発生用高周波コイルが励起す
るプラズマにより分解、電離した後、電離した炭素イオ
ン及び酸素イオンを前記放電管内に配置した一組の電極
により電界吸引し、前記炭素イオン及び前記酸素イオン
をそれぞれ分離する一酸化炭素又は二酸化炭素分解除去
方法。
1. Carbon monoxide or carbon dioxide introduced into a discharge tube is decomposed and ionized by plasma excited by a high-frequency coil for generating inductively coupled plasma, and then ionized carbon ions and oxygen ions are arranged in the discharge tube. A method for decomposing and removing carbon monoxide or carbon dioxide, in which an electric field is drawn by a pair of electrodes to separate the carbon ions and the oxygen ions, respectively.
【請求項2】請求項1記載の一酸化炭素又は二酸化炭素
分解除去方法において、分解、電離した炭素イオンを励
起状態のまま該炭素イオンと反応する金属と反応させて
炭素と金属との結合物として回収することを特徴とする
一酸化炭素又は二酸化炭素分解除去方法。
2. The method for decomposing and removing carbon monoxide or carbon dioxide according to claim 1, wherein the decomposed and ionized carbon ion is reacted with a metal that reacts with the carbon ion in an excited state to form a bonded product of carbon and metal. And a method for decomposing and removing carbon monoxide or carbon dioxide.
【請求項3】前記炭素イオンと反応させる金属としてF
e,Co,Ni,Mnの少なくとも何れか一つの金属が用いられる
請求項2記載の一酸化炭素又は二酸化炭素分解除去方
法。
3. F as a metal that reacts with the carbon ions
The method for decomposing and removing carbon monoxide or carbon dioxide according to claim 2, wherein at least one metal selected from e, Co, Ni and Mn is used.
【請求項4】高周波発生用電源と接続し、プラズマ放電
して一酸化炭素又は二酸化炭素を分解、電離する誘導結
合プラズマ発生用高周波コイルと、前記電離された炭素
イオン及び酸素イオンを電界吸引する一組の電極を内蔵
する放電管を、単独又は多段組み合わせてなる一酸化炭
素又は二酸化炭素分解除去装置。
4. A high-frequency coil for generating inductively coupled plasma, which is connected to a high-frequency generating power source and decomposes and ionizes carbon monoxide or carbon dioxide by plasma discharge, and the ionized carbon ions and oxygen ions are attracted by electric field. A device for decomposing and removing carbon monoxide or carbon dioxide, which comprises single or multiple stages of a discharge tube containing a set of electrodes.
【請求項5】請求項4記載の一酸化炭素又は二酸化炭素
分解除去装置において、分解、電離した炭素イオンを吸
引する電極側の放電管端部に、前記炭素イオンと反応す
る金属が充填された炭素イオン回収装置を連通して配置
した一酸化炭素又は二酸化炭素分解除去装置。
5. The carbon monoxide or carbon dioxide decomposing / removing apparatus according to claim 4, wherein the end of the discharge tube on the electrode side that attracts the decomposed and ionized carbon ions is filled with a metal that reacts with the carbon ions. A device for decomposing and removing carbon monoxide or carbon dioxide, which is arranged in communication with a carbon ion recovery device.
【請求項6】前記炭素イオン回収装置内にFe,Co,Ni,Mn
の少なくとも何れか一つの金属が充填されている請求項
5記載の一酸化炭素又は二酸化炭素分解除去装置。
6. Fe, Co, Ni, Mn in the carbon ion recovery device
6. A carbon monoxide or carbon dioxide decomposing / removing apparatus filled with at least one metal according to claim 5.
JP2128992A 1990-05-18 1990-05-18 Method and apparatus for decomposing and removing carbon monoxide or carbon dioxide Expired - Lifetime JPH0751215B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2128992A JPH0751215B2 (en) 1990-05-18 1990-05-18 Method and apparatus for decomposing and removing carbon monoxide or carbon dioxide

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2128992A JPH0751215B2 (en) 1990-05-18 1990-05-18 Method and apparatus for decomposing and removing carbon monoxide or carbon dioxide

Publications (2)

Publication Number Publication Date
JPH0422416A JPH0422416A (en) 1992-01-27
JPH0751215B2 true JPH0751215B2 (en) 1995-06-05

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Country Link
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3708917B2 (en) * 2002-03-28 2005-10-19 ダイダン株式会社 Gas ionization separation and purification equipment
NO20024750D0 (en) * 2002-10-02 2002-10-02 Schiewe Bob Methods and equipment for ionizing gases to higher energy levels
JP2006269095A (en) * 2005-03-22 2006-10-05 Takeshi Nagasawa Plasma generation device
BRPI0700517B1 (en) * 2007-02-15 2016-02-16 Carbonobrasil Tecnologia E Serviços Ambientais Ltda Molecular degradation process of greenhouse gases and equipment of molecular degradation of greenhouse gases with retention of degraded particulate matter
WO2009073048A1 (en) * 2007-06-04 2009-06-11 New York Energy Group Apparatus and method for dissociating carbon dioxide
JP2023010045A (en) * 2021-07-08 2023-01-20 日本未来科学研究所合同会社 Carbon dioxide treatment system and carbon dioxide treatment method

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Publication number Publication date
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