JPH07507094A - Improved textile cleaning shampoo composition - Google Patents

Abstract

An improved aqueous fabric cleaning shampoo composition contains a combination of (a) about 0.5-20% by weight of a fabric cleaning polymer which is a solid at 25 C and water dispersible or water soluble upon neuturalization with an alkaline compound such as a polymer of methacrylic acid/styrene/n-butyl acrylate, (b) about 0.1-10% by weight of a specific type of wax having a melting point of at least 50 C such as pressure-emulsified polyethylene wax and (c) about 0.05-5% by weight of a silicone betaine polymer in addition to an effective amount of at least one conventional anionic, nonionic, amphoteric or zwitterionic surfactant in water at a pH of from about 7 to about 10.5. Such a fabric cleaning shampoo composition not only provides good cleaning and conditioning to fabrics, particularly synthetic fibre fabrics, such as those used in carpets as well as to upholstery and pile fabrics, but also provides soil resistance to the fabric cleaned with such a composition.

Description

[Detailed description of the invention] Improved Textile Cleaning Shampoo Composition Technology Field The present invention can be used in textiles, especially carpets, upholstery materials and pile products. Synthetic woven materials with excellent cleaning and conditioning effects as well as impart improved stain resistance to the cleaned fabric. In the improved aqueous fabric cleaning shampoo composition, at least one Common surfactants plus textile cleaning polymers and certain waxes and silicones. Textile cleaning shampoo composition containing combination with betaine polymer Regarding. Background technology Shampoo compositions for use on textiles such as carpets and upholstery materials include: It has existed for a long time. This type of product has large dimensions or is fixed to furniture. For fabrics that cannot be easily moved from their current position for leaning used. In the case of carpets and rugs, these fabrics are frequently stepped on and can quickly become dirty. There is a tendency for this to occur. Due to its size and location, such fabrics are not used very often. These fabrics often cannot be cleaned, and stain repellent treatments are not recommended for these fabrics. It is useful to do some research. Clothing products that can be washed in a washing machine are interesting. Surfactants used to wash such textiles are not easily rinsed with water. I can't do it. This is because carpets, upholstery materials, etc. are not fixed in place. This is because it is That is why carpets and upholstery have always been cleaned with the least amount of water. It can remove dirt from decorative materials and speed up the drying of cleaned textiles. This also removes as much surfactant as possible, which tends to attract dirt. There was a need to provide a fabric cleaning composition that could clean the fabric. Excess water can also It causes shrinkage and warping of the sheet, and furthermore, it promotes the growth of mold. nine Another thing that is desirable about cleaning compositions is that they do not leave stains on the cleaned fabric. Cleaners that provide preventive properties and thus extend cleaning intervals An object of the present invention is to provide a washing composition. Fabric conditioning as part of the cleaning process It is also desirable that conditioning be provided.

Anti-soiling or 5 oil repellency ) is a carpet-like fabric that is walked on after being cleaned. or furniture that may become soiled again as a result of normal use, such as being used on a daily basis. This means that there is resistance to This is useful for cleaning textiles. is one rough measure of the attractive or repellent power of a product used for this purpose. Haton Any carpet and often textile furniture upholstery materials are either manufactured or provided to the consumer. It is treated with an anti-fouling layer immediately before being used. Examples of such treatment agents are STAIN Will be used on carpets with MASTER trademark. n, E of Delaware USA, 1. Du Pont De Ne5ou TEFLON@carpet treatment from rs & Co@pany and St. Paul, Klinnesota Carpet supplied by 3M company in the United States. 5COTCHGARD [F] products used in both textile and textile upholstery materials. Ru. Although these products make these fabrics stain resistant, they can also be used to clean fabrics. Application of cleaning shampoo compositions can quickly resoil the cleaned fabric. It has been observed that this actually speeds up the rate.

Numerous attempts have already been made to provide textile cleaning shampoo compositions. ing. U.S. Patent Nos. 3,723,323 and 3, issued to Morgan et al. Each specification of No. 723358 describes anionic or nonionic surfactants as detergents. with acrylic or methacrylic acid and styrene or other unsaturated monomers. containing alkyl acrylate or methacrylate and a neutralized polymer. An aqueous fabric cleaning shampoo composition is described. This polymer is The composition is described as imparting stain resistance to fabrics cleaned.

This composition is rubbed into the fabric, left to dry and then mixed with the stain. It is removed by empty suction. This is because the composition becomes brittle when drying and stains. This is because they fall off as flakes from the fibers of the fabric. Podell U.S. Pat. No. 4,013,595 to A et al. uses a hydrocarbon propellant. teaches a non-flammable aqueous aerosol rug cleaner. This cleaner has very little Alkali metal lauryl sulfate as at least one surfactant 0.3 to 10 % lauryl alcohol in combination with at least 0. To make it exist 3% Has reduced flammability. This composition of Podella et al. Containing polymers of the type taught in the Morgan et al. .

US Pat. No. 4,304,610 to Weisensel et al. Carpet is soaked in foaming anionic surfactant using an extraction machine. A method of cleaning carpets is taught. used for this The aqueous liquid or dry powder composition reacts with the anionic surfactants in the carpet. Cationic surfactants to suppress foaming and nonionic surfactants as main cleaning agents. agents, building blocks, fillers, chelating agents and optionally optical brighteners, dyes and and fragrance.

U.S. Pat. No. 3,734,686 to Douglas and carpet cleaning shampoo compositions for pile fabrics are taught Ru.

This composition improves the abrasion resistance and static properties of cleaned carpets or pile fabrics. It is stated that it improves anti-electrostatic properties. This effect is due to oxygen-free polyurethane. It is derived from the presence of an aqueous emulsion of tyrene, and its polyethylene Particle size is 0.02 to 0.5. Those with an average molecular weight of 7,000 to 40,000 At least 30% of the dovetail particles are coated with the emulsifier composition. In the description According to Less force is required to apply the force.

No. 5,073,442 to Knowlton et al. Disclosed is a method for improving soil and stain resistance of mid and wool fabrics. It is. In that method, the fabric is treated with a solution containing the following ingredients: (1 ) Formaldehyde and bis(hydroxyphenyl)sulfone, phenylsulfone Condensation product with acid, dihydroxy(diphenyl)sulfone or benzenesulfonic acid Product: (2) Fluorine compound: and (3) Acrylic polymer or copolymer.

The composition may also be used as a modified wax composition such as a paraffin wax emulsion. containing a microcrystalline wax composition or a metallized wax emulsion. Can be done. Acrylic polymers reduce the bleaching effect of phenolic resins on textiles. It can be added to the composition to soften the fabric as well as to impart a soft feel to the fabric. Ru. Fluorine compounds improve the water and oil repellency of treated textiles, as well as reduce staining. It is stated that it improves anti-corrosion properties. Generally, Knowlton et al. Recon.

Fluorocarbons, waxes, acrylic polymers and combinations of these are water repellent Used as an oil- and stain-repellent finish, but does not spill hot or hot liquids. It teaches that there is little or no protection when This composition is usually It is mainly used as a treatment agent for a different type of cleaning work.

U.S. Pat. No. 4,784,799 to Petrof f. anionic surfactant and at least one organic zwitterionic functional Combination with silicone surfactants such as silicone sulfobetaine surfactants teaches synergistic surfactants consisting of combinations of The latter is sulfobetaine (meth siloxy units and, optionally, dimethylsiloxy units. It is a luciloxy-terminated polydiorganosiloxane. These compositions are tableware Can be used as a cleaning agent, liquid or powder cleaning agent and cleaner.

Other examples of silicone polymers containing betaine functionality include Kollmeier et al. U.S. Pat. Nos. 4,609,750 and 4,654,161, issued to Found in books. These silicone polymers are used in cosmetics, especially hair conditioning. It is described as being useful for the production of hair care cosmetics such as hair care products.

(U.S. Pat. No. 4,269,739 to Rejsner Agents are disclosed for treating and cleaning dirt and the like. this in dissolved or emulsified form, from 0.001 to 1. 2% natural or Synthetic wax or wax-like substance, 0.001 to 2.5% with lubricating effect Fluid silicone oil, 0.001 to 2.5% surface active polysiloxane copolymer body.

0.001-1.2% fluorinated organic surfactant and 0.001-2.5% % nonionic surfactant. This agent is used for records and plastic products. For example, cleaning photographic objects, optical lenses, television screens, etc. and used to provide antistatic and lubricating coatings to these articles. .

All of the above components are necessary and act synergistically. Woven such compositions There is no teaching of use in connection with cleaning.

U.S. Pat. No. 4,780,100 to Wall describes foaming surfactants. Foaming aqueous aerosol textile cream containing solvent, propellant, bilgo and water coating compositions are taught. According to the description, the bubbles penetrate into the pile of the fabric. When the solvent evaporates, a second bubble is formed that carries the dirt to the surface. The requirements for a sex agent are that it forms a foam and that it contains organosilicone. It is only possible to have. Amphoteric surfactants such as betaine can be used. this Nothing about adding polymeric additives or waxes to cleaning compositions There is no instruction.

U.S. Pat. No. 4,678,595 to Malzk et al. Carpets containing surfactants, normally solid water-soluble or water-dispersible polymers and water. A shampoo or upholstery cleaning composition is disclosed. This group The compound is applied to the carpet and, when left to dry, crumbles into non-stick crumbs. This stain-containing polymer can be removed later, as it forms an easy-to-clean film or polymer residue. The residue is removed by vacuum suction. The polymer used is butylacryl / Styrene (in some cases) / Methyl methacrylate / Methacrylic acid, acrylic It is an acid and/or itaconic acid copolymer. Optional ingredients include antistatic agents and fluorocarbons. Ombil rubber and stabilizers such as amine oxides, as well as amphoteric cycloimidines Alternatively, imidazole, fluorescent brighteners, fragrances, etc. can also be included.

U.S. Patent No. 3,335,086 to Morris -.

Dirt re-adheres to fabrics, clothing, etc. during laundry washing, dry cleaning, etc. discloses an anti-redeposition additive for preventing This additive oxymethylcellulose and a substantially linear hydrocarbon chain and hydroxyl along the chain. Synergistic combination with hydrolyzed polymers containing both syl and carboxyl groups Consists of sewage. These can be used in liquid or powder form to improve the detergent's anti-redeposition properties. Added to detergents.

No. 4,561,992 to Troger et al. Aerosol cleaning agents are taught. This cleaning agent is plasticized urea-formaldehyde resin foam particles (0,005 to 0.120 mm), Contains propellant, suspending agent, liquid, sodium aluminum silicate powder are doing. Contains silicone defoamer to facilitate removal of soap residue be able to. It is stated that no moisture retaining cationic antistatic agent is required. this The product is applied to the textile upholstery material, dried, evacuated and removed from the textile. wash The detergent is sodium aluminum silicate particles.

Furthermore, the following represents the current state of the technology. i.e. other aqueous liquids. -Pet and fabric cleaners are taught in the following patent specifications: Shea No. 3,630,919 to Fearnley et al. U.S. Patent No. 3,639,290 to Buck et al. National Patent No. 3,738,259: U.S. Patent No. 3 to ^n5tett et al. Specification No. 919101.

A surfactant-free carpet cleaning and stain prevention composition has been patented as follows: two as taught in the specification; No. 4,035,148 to Metzger et al.

A dry powder carpet cleaner is taught in the following patent specification: 5olda No. 4,659,494 to Nski et al. and U.S. Patent No. 4,659,494 to S. US Pat. No. 4,566,980.

Textile treatment compositions based on fluorine compounds are taught in the following patent specifications: No. 3,987,227 to 5chultz and Louda No. 4,043,923, issued to s.

Acrylic polymers used in carpet shampoo compositions are disclosed in the following patent specifications: Taught: U.S. Pat. No. 4,203,859 to Kirn et al.

Anti-stain and anti-redeposition polymer latte used in connection with aqueous laundering of textile products ゛x is disclosed in the following patent specification: Berrod et al. National Patent No. 4925588 specification.

Wax-containing compositions for use in connection with textile detergents are disclosed in the following patent specifications: ing: U.S. Patent No. 4,447,349 to Tai; National Patent No. 4451387 and U.S. patents granted to Wuhrwsa songs, etc. Specification No. 4599189.

"From" agreement fishing plate display One object of the invention is to clean carpets, rugs, upholstery to be cleaned on-site. Aqueous shampoo compositions for textiles of the type used for decorative materials, pile textiles, etc. The composition is particularly useful for textiles made from synthetic fibers. Useful. The composition may also be applied to fabrics that have already been pretreated with stain protection products. One composition that is particularly suitable for Significantly improved stain resistance and condensation on cleaned fabrics gives a tailored feel. Carpet cleaning polymers and waxes listed below When these ingredients are used alone, the combination of 6. The composition imparts much better properties to the composition than when cleaning and cleaning. Spray with an aerosol or non-aerosol trigger sprayer onto the fabric to be It is rubbed into the fabric, left to dry, and then the dirt is removed by suction. Ru.

This leaves the fabric conditioned and stain-resistant.

Cleaning fabrics that have been pretreated with anti-staining agents with the compositions of the invention Then, cleaning with other prior art fabric cleaning shampoo compositions Cleaned fabrics are more resistant to re-soiling than if they had been cleaned. dirt Since dirt particles are hard and have sharp edges, the presence of dirt can be detected by friction. damage the fibers. Therefore, this product reduces the amount of stains on carpet fabrics. increases the longevity of the carpet by reducing wear due to the action of dirt within its fibers. prolong life.

These and other objects and advantages of the present invention are realized in the improved carpet according to the present invention. This is achieved by a shampoo composition. The composition leaves a powdery product after application. This powder can be removed by suction after drying. Preferably about 0.5 to 20% by weight of the amount, more preferably about 0.5 to 10% by weight %, most preferably 0. 5 to 4% by weight of at least one selected from the following group: The composition comprises an effective amount of a surfactant. Anionic surfactants, nonionic surfactants, amphoteric and zwitterionic surfactants, preferably anionic surfactants, Selected from amphoteric surfactants and zwitterionic surfactants. These surfactants is suitable for shampooing carpets and can be almost removed by suction when drying. Wear. The surfactant has a pu value of about 7 to 1O85, preferably about 8.5 to 9.5. The improved composition of the present invention, which is dispersed in water with a pn number of 4, contains the following ingredients: (a) from about 0.5 to about 20% by weight of the total composition, more preferably from about 0.5 to 10%; % by weight, most preferably about 0.5 to 4% by weight, normally solid at 25° C. water-soluble or water-dispersible by neutralization with alkaline compounds. Certain textile cleaning polymers, e.g. methacrylic acid/styrene/n-butyl Acrylate polymer: (b) about 0.1% to about 10% by weight of the total composition, preferably 0.1% to about 10% by weight of the total composition; 5 to 2% by weight synthetic wax, preferably in the form of particles derived from an aqueous emulsion, Natural waxes or wax-like synthetic organic substances with a melting point of at least 50°C a wax selected from the group consisting of, preferably a pressure emulsion oxidized polyethylene Ren wax: and (c) about 0.05 to about 5% by weight of the total composition, preferably 0.25 to 0.5% by weight; % compatible silicone betaine polymers.

-non The aqueous shampoo compositions of the present invention provide the improved properties that compositions of the present invention should have. In addition to the above three ingredients, the presence of at least one surfactant and water is required. . The water is preferably deionized water or soft water with low mineral content, as described herein. The percentages shown refer to the content of non-volatile solids (active substances), unless otherwise stated. The same NVM” pace.

The surfactants used can be used in carpet shampoo compositions and are described below. It is combined with a type of carpet cleaning polymer that absorbs substantially when drying. The effective cleaning amount removed, typically 0.5 of the total shampoo composition. Up to 20% by weight of anionic surfactants, nonionic surfactants, amphoteric surfactants or is a zwitterionic surfactant. Examples of such surfactants include Morg As described in U.S. Patent Nos. 3,723,323 and 3,723,358 to an et al. has been done. Preferred are anionic surfactants, 1 amphoteric surfactants and zwitterionic surfactants. It is a surfactant. Preferably about 0.5 to 10% by weight of the total composition, more preferably or about 0.5 to 2% by weight of the total composition is constituted by such surfactant. . Using more surfactant than the minimum amount necessary to remove soil from the fabric is undesirable because surfactants left in the fabric are especially non-ionic surfactants. Sexual agents tend to attract dirt and debris to the fabric being cleaned and therefore This is because the stain prevention effect of the composition of the present invention is reduced.

Examples of suitable synthetic organic anionic surfactants are alkyl glyceryl ether sulfonas. Salts: Alkyl sulfonates: Alkyl monoglyceride sulfate or Sulfonates: Alkyl polyethoxy ether sulfonates; alkylarides lsulfonates; acyl sarcosinates; acyl esters of isothionates Le! ! 1: Alkyl esters of sulfosuccinic acid: and alkylphenol They are polyethoxysulfonates. In these compounds, the alkyl group and acyl groups, each containing 10 to 20 carbon atoms, are water-soluble salts, for example used in the form of sodium, potassium or ammonium salts. It will be done.

Specific examples of anionic organic surfactants include sodium lauryl sulfate and dodecyl. Sodium sulfate, sodium alkylolamide sulfosuccinate, N-lauroy Examples include rusarcosine sodium.

Examples of synthetic nonionic surfactants are: alkylphenol polyethylene lene oxide condensates, in which the alkyl group has 6 to 12 carbon atoms; and ethylene oxide in a ratio of 10:1 to 25:1 ethylene oxide to alkali. present in the molar ratio of propylene oxide and ethylene diamine. The condensation product of the reaction product and ethylene oxide, in this case the molecular weight of the condensate is 5,000 to 11,000; about 5 to 30 moles of ethylene oxide and about 8 with 1 mol of straight-chain or branched aliphatic alcohol having from 18 carbon atoms Condensation products nitrialkylamine oxide and trikylphosphine oxide class, in which one alkyl group has 10 to 18 carbon atoms and the other The two alkyl groups have 1 to 3 carbon atoms.

Examples of amphoteric and zwitterionic surfactants are organic alkyl betaines, alkyl These include rusulfobetaines and alkylaminocarboxylic acids, which are about 8 to Contains at least one long chain alkyl group having up to 22 carbon atoms. organic Alkyl betaines include cocoamidopropyl betaine and cocoamidoethylbetaine. Yin, Isostearamidopropyl betaine, Oleamidopropyl betaine, La Examples include uriamidobrovirpetaine and cocobetaine. zwitterionic interface One example of an active agent is coco-sultaine. Currently cocoamidopropyl Betaine is preferred.

As is known from the above-mentioned Morgan et al. patent, the fabric cleaning method of the present invention The polymer component is about 0.5 to 20% by weight of the total composition, more preferably 0.5 to 20% by weight of the total composition. lO wt% addition polymer, most preferably 0.5 to 2 wt%; Most of the polymers have at least one type of homopolymer with a glass transition temperature of 65°C. It consists of unsaturated monomers having a temperature (Tg). An example of such a monomer is methylmethane. Tacrylate (Tg is usually 105°C), ethyl methacrylate (Tg is usually 65 °C), cyclohexyl methacrylate (Tg is usually 66 °C), isobornyl methacrylate acrylate (Tg is usually 110 to 170°C) and styrene (Tg is usually 10 0°C), the addition polymer is further treated to control the hardness and viscosity of the resulting polymer. Examples of such monomers include monoethylenically unsaturated monomers of various Tg values. In addition to the above monomers, lower alkyl acrylates having 4 to 14 carbon atoms are used. Rates such as ethyl acrylate, n-propyl acrylate, n-butyl Acrylate, inbutyl acrylate hexyl acrylate, octyl acrylate ester, decyl acrylate, acrylonitrile, methacrylonitrile, α-methyl tylstyrene, alkyl methacrylates having 5 to 15 carbon atoms and For example, octyl methacrylate and l-alcohols having 2 to 30 carbon atoms. These include Ken-class. Such a 7mer is used to adjust the overall Tg of the resulting polymer. used for ? ! ! The polymer to be produced is usually so small that it is solid at room temperature. both have a Tg of 25°C, more preferably an overall Tg of at least 65°C Ru.

A small amount, generally all polymerization, of the polymer to impart water dispersibility or water solubility to the polymer. Approximately 2 to 40% of the body is a polymerizable monoethylenic compound containing free carboxyl groups. Composed of unsaturated monomers. Examples of such monomers are acrylic acid, methacrylic acid acid, itaconic acid, maleic acid, maleic anhydride, etc., and methacrylic acid is more The preferred zero polymer also has a weight average molecular weight in the range of about 2,000 to 500,000. sell. However, a weight average molecular weight in the range of about 20,000 to 400,000 is more preferred. the carboxylic acid content of the polymer to give it a water-dispersible or water-soluble polymer. Adjusted for molecular weight. Polymers of this type are known in the art and include For example, Morgan et al., U.S. Pat. No. 3,723,323 and U.S. Pat. It can be known from the specification of No. 3723358. Currently, in some cases In addition, methacrylic acid/styrene/n-butyl styrene may contain α-methylstyrene. Preferably, the polymer of tylacrylate is added as an aqueous emulsion.

org cited herein as teaching such polymers. US Pat. No. 3,723,323 and US Pat. No. 3,723,358 to an et al. As taught in the specification, this polymer is At least 10% should be present and the weight ratio of polymer to surfactant is about 0. The specific weight ratio of polymeric surfactant, which should be between 1:1 and 1:1, is selected. the type of polymer and surfactant used and the desired final composition of the shampoo composition. It should be understood that it is determined by the physical properties of

An effective amount of carboxyl groups present in the polymer, preferably about 80 to 1 stoichiometric amount. 00% neutralized to an alkaline pH value to make the polymer water-dispersible or water-soluble be done. Such neutralization can be accomplished using alkaline neutralizing agents such as triethanolamine, 2 -amino-2-methyl-1-propanol, 2-amino-2-methyl-1,3- 2 to 22 organic bases such as amino alcohols such as propanediol Organic amines having carbon atoms such as triethylamine and laurylamine, Or ammonium hydroxide, sodium hydroxide, potassium hydroxide, ammonium carbonate 6 shampoo compositions that can be carried out using inorganic bases such as The pH value is adjusted to about 7 to 10.5. More preferably a non-aerosol trigger - from about 7.5 to 8.5 for nebulizer compositions and for aerosol spray compositions. In some cases, it is adjusted to about 9.5 to 1O15.

Another component required by the present invention is from about 0.1 to about 10% by weight of the total composition. , more preferably about 0.1 to about 5% by weight, most preferably 0.5 to 2% by weight. It is a wax. This wax can be synthetic wax, natural wax or at least a wax-like synthetic organic substance having a melting point of at least 50°C, preferably at least 100°C; Selected based on quality. Examples of such waxes are carnauba wax, paraffin waxes, polyolefin waxes, modified polyethylene waxes such as oxidized polymers. Oxidized polyethylene, maleated polyethylene and Acrylated polyethylene wax, microcrystalline wax, oxidized microcrystalline wax, Mon Such as tan wax. These waxes are well known in the art; It is commercially available from various manufacturers.

Hard waxes such as pressure emulsified polyethylene waxes are currently preferred. It is. Such wax is ^1lied Chewicalg (Morri gtown, New Jersey, USA) by ACPolyethy It is sold in the market under the product name lene AC330. how much is this wax A blue fluorine containing the above carboxyl group and having a molecular weight of approximately 5000.11 degrees and 140 degrees Celsius. Kuffield viscosity is 9,000 centibois (9,000 pascal seconds), acid value is 2 5 to 34 (0.5g/xylene 10.IN alcoholic sodium hydroxide solution) liquid, phenolphthalein indicator), maximum penetration of 0.5 (100g 15 seconds 72 It is an emulsifiable oxidized high-density polyethylene with a temperature of 5°C). This wax is potassium hydroxide emulsions using a base such as chlorine, a preservative and a small amount of non-ionic surfactant. It can be done as an option. An example of a hard polyethylene wax is A11i. ACPo1yethylene AC316 from ed Chewicalg It is A. It has a Mettler dropping point of 140°C and an acid value of 15 to 18 (KOHsg /g), density at 25°C is 0°98g/cm3, temperature at 150°C. The cold viscosity is 8,500 centivoise (8,500 Pascal seconds), and the hardness at 25℃ is It is a high-density oxidized polyethylene press emulsified wax with a weight of 0.5 dw or less.

Other specific examples of waxes include: ＾11ied　Che C629 polyethylene wax from wicalg: This is AC: 330 watts. It is softer than Tsukusu, with a softening point of 104°C (ASTM E-28) and a hardness of 5. 5 (ASTM D-5), Brookfield viscosity at 140°C is 200 centipos. low molecular weight with an acid value of 16 (KOH-g/g) and an acid value of 16 (KOH-g/g) Low density oxidized polyethylene.

EPOLENE@EIO wax; This has a ring and ball softening point of 106 ℃, penetration hardness is 3.0 (100g 15 seconds/25℃, 10 minutes of 1 mm) 1), acid value is 15. Brookfield viscosity (No, 3 spindles, 30 rpm ) is 1200 centivoise (1.2 Pascals, seconds). It's a box.

EPOLENE OElf, R12, R14, EIS, R20’7 x : KotL Lava EPOLENE @ Polyethylene wax from the same series as EIO7 It's a box.

EPOLENE■ E43 wax: This is an emulsifying polypropylene wax. with an average molecular weight of 9100 (gel permeation chromatography), ring and bow The softening point is 157℃, the penetration hardness is <o, 5 (100g 15 seconds/25℃, 1mm Brookfield viscosity (N o, 3 spindles, 30 rpm+m) is 0.350 centimeter voice (0.35 pascal) (Les, seconds).

These EPOLENE @ waxes are Eastman Chemical Products Inc. (Ktngs-port.

Tennessee, USA].

An example of a montan wax ester is Hoecbs, Middlesex, UK. Hoechst Wax) fLE supplied by T Company. This is the dropping point is 79 to 85°C, and the viscosity at 100°C is 22. It is 60sPa,s. Hoe Hoecbst PED 153 Wax supplied by CHST has a dropping point It is a fairly hard oxidized polyethylene wax with a temperature of 120°C. (DGF-M-II I3(75)), Vine and other Hoecbst waxes using the composition of the invention. The food is PED 121. PED 136, PED 191. PED 261 , PED 521. It is sold under the trade name PED 522.

Another component required by the present invention is preferably about 0.05 to about 5% by weight of the total composition. preferably 0.25 to 0.5% by weight of a compatible silicone betaine polymer. . It must not be compatible with other ingredients present in the shampoo compositions of the present invention. Such polymers must be of known composition and U.S. Pat. No. 4,609,750 and U.S. Pat. No. 4,654,161 to R et al. It is written in the book. These patent specifications are intended to teach such polymers. Referenced herein. And such polymers are KollIIeisr Th.Goldschmidt of Essen, Germany, the assignee of the patents of It is commercially available under the trademarks TEGO PRENO and ABIL O. other types of siri Corn betaine and silicone sulfobetaine polymers are manufactured by Petroff as described above. No. 4,784,799, issued to Cited herein as teaching silicone sulfobetaine polymers There is.

A preferred silicone betaine polymer has the following general formula: This is the type described by Er et al.

R'(R'12 Si 0((R'h St 01x(R' R' Si O) y 5i (R'12 R' in the formula, R1 may be the same or different in the molecule, and 1 to 18 refers to an alkyl group, aryl group or polyoxyalkylene group having carbon atoms of taste, provided that at least 70% of the R groups are methyl groups, R 2 can be the same as R1, provided that at least one R2 is (I)- (CH2h 0CH2CHR' CH2R' group [wherein R3 and R4 are different from each other one means hydroxyl group and the other means -N◆R'　R'(CH21n　Coo- group (here, R6 and R6 are of the same type) or heterogeneous, each meaning an alkyl group having 1 to 4 carbon atoms. or benzyl group, preferably n=1°2 or 3)J and the following (II ) -R7C0NHRe　N”　R5R'fCH21n　Coo- group (wherein, R7 is A divalent alkylene group having 2 to 12 carbon atoms, and R8 is a divalent alkylene group having 2 to 6 carbon atoms. It means a divalent alkylene group having a carbon atom, and R5, R' g and n have the above meanings. X is a number from 0 to 200.

y is a number from 1 to 50.

Specific examples of currently preferred polymers of this type include 7h, G (11dschs+idt) It is TEGOPRENE @6950 supplied by. This is the manufacturer According to the explanation of A 30% NV14 aqueous solution of Inpolymer: fC) Ixl 3siOfstAcH301m(Si +CH31201n s i (in formula C11313.

A is a group of the following formula -((:H213QC)12CHfOHICH2N◆(CH312CI2COO -m and n are each thicker than 0 (and the sum of m+n is the viscosity of the polymer at 25°C) The speed is approximately 50 to 90 m'/sec.

Specific gravity at 25°C is approximately 1.07 to 1.09 g/c m3°8dH, temperature The Ross Miles foam height of the polymer in a 0.1% solution in water at 25°C is 80 The numerical value is such that.

Th, Goldschmidt also sells this product as ^BIL B9950 product. It is also sold under the name. According to the manufacturer's explanation, this is TEGOPRENE O. 3 of silicone betaine polymers having the same general formula and the same specific gravity as 6950. 0% NVM aqueous solution. However, a 1% solution of this polymer in water at 25°C has a temperature of 23°C. It is reported to have a surface tension of ~25 sN, m-'. Manufacturers use this polymerization Body the Co55+etics, Toiletry and Fragr Diwethi in ancea As5ocation (fCT F A-) Cone Propyl states that it was declared under the name of PG-Betaine. .

Optionally, but preferably, some compositions of the invention may be used to improve oil stain cleaning. Preferably, about 0.5 to about 15% by weight organic solvent, more preferably about 2 to 5% by weight. Contains an agent. Examples of such solvents are alcohols such as ethyl alcohol. , isopropanol, glycol ether solvents such as propylene glycol Monomethyl ether, propylene glycol n-butyl ether, dipropylene Glycol monomethyl ether, tripropylene glycol butyl ether, di Propylene glycol n-butyl ether, dipropylene glycol dimethyl ether ether, ethylene glycol monoethyl ether, ethylene glycol motupuchi ether and propylene carbonate.

In addition to the required ingredients listed above, a small amount of 2, usually less than 5% of the total composition, may be added as an optional ingredient. The following conventional additives may be included in not too great amounts.

Preservative and antibacterial agents, e.g. IRGASAN @DP-300 (substituted diphenyl) ), Ciba-Geigy Dyestuff & Chemicals Division, (Greensboro, Nortb Car shield) B Obtained from USA).

Fluorescent stimulants, such as TIN0PAL CBS-X (distyrylbife (stilbene derivative) and TlN0PAL5BM-GX (stilbene derivative), Obtained from Ciba-Geigy: Dye: Fragrance; Anti-staining agent, for example, ^LGARD@RD (nylon for anti-staining treatment) Aromatic sulfonic acid condensate used in carpets) Right and ^LGARD@NS (Aqueous solution of aromatic sulfonic acid condensate), A11i6d C61oids, (Yorkshire, UK): and ZELAN933g (Ky. 20-30% NVkl aqueous solution of ruboxylated polymer salt), E, I.

Du Font De Ne5ours & Co, (blasphemy ton, Delaware, USA): refouling inhibitors, e.g. ＾LAN＠HP22 (Non-ionic surfactant and anti-fouling agent , Tatoeba, 5OKALAN IIP22 (nonionic surfactant and 5OKAL AN @cps --- Sodium salt of modified polyacrylic acid --- and 5OKALAN ■Mixture with CP9-maleic anhydride/olein copolymer), BASF Obtained from (Ludwjgshafenn, Germany): UV absorbing compounds, such as UVINUL[F]M-40 (2-hydroxy- 4-methoxybenzophenone) and UVTNUL[F]MS-40 (2-hydro Roxy-4-methoxybenzophenone-5-sulfonic acid), BASF, Obtained from (Parsippany, New Jersey USA): Cleaner Bilgoo For example, borax; Chelating agents and other oil/soil inhibitors such as fluorinated organic compounds, such as For example, ZONYL @7950 carpet protector (improper tool medium 3 0% NV support) and TEFLON [F] MF (TLF 5180) (poly resin 72% NVM aqueous dispersion of aliphatic compounds and polyfluoroaliphatic compounds), E, 1. Du Pont De Ne5ours & Cra, (Wili*i ngton.

Obtained from Delaware, USA).

These optional additives are compatible with the shampoo compositions of the present invention. Addition of the desired properties of the shampoo composition of the present invention is not materially impaired. Can be done.

industrial uffi oily The aqueous textile shampoo compositions of the present invention are low viscosity liquids, generally having a viscosity of 2. Since it is lower than 10 centimeter voice (0,010 pascal seconds) at 5℃, spraying is not possible. The composition is suitable for dispersion at room temperature or with some heat to facilitate dispersion. It can be easily manufactured by mixing each component. After mixing The pH value of the composition is adjusted to the desired range of 7.0 to 1O15 with a suitable alkaline substance. Arrange. The wax component and the textile cleaning polymer contribute to the formed composition. They can be added as an aqueous emulsion to speed up the formulation of these materials. Similarly, if solvents are added, such as waxes or antibacterial agents, Before adding the more hydrophobic component to the aqueous component, optionally with heating, Solvents can be used to dissolve the hydrophobic components.

The textile shampoo composition according to the invention can be prepared by using a suitable packaging material such as For example, it can be used in a conventional trigger-type or pump-type spray bottle.

Alternatively, the composition may be placed in a pressurizable container and the contents may be aerated while applying pressure. One-bottle composition that can be pumped together and dispensed in spray form sprayed onto the carpet or upholstery material to be coated.

After this, use a brush or other suitable applicator as you would with a conventional shampoo composition. Rub it into the fabric with a sieve, leave it to dry, and then remove dirt and debris. Remove the dry composition by suction.

If a self-pressurized aerosol formulation is desired, one shampoo composition can be pressurized. Place the container in a metal, glass or plastic container that can be sealed with a valve, and then installing an aerosol activation button and adding propellant through that valve. Can be done. The propellant is a conventional propellant, such as dicarbonate, in an amount of about 3 to 20% of the total composition. Methyl ether or one or more atom(s) having 2 to 6 carbon atoms Lukanes such as propane, isopropane, n-butane, isobutane, isopene It can be ethane or n-hexane. Mixtures of two or more propellants may also be used. Can be used. In some cases, the propellant may be added before sealing the valve into the container. You can also do it. With an emphasis on ecology, containers can be filled with nitrogen, air or other compressible inert It can also be pressurized with a toxic gas. When the user presses the activation button, the shampoo will be activated. The product is atomized, which is then cleaned, usually in the form of a foam due to the presence of the propellant. If foam is desired when dispensed from the container, In some cases, a volatile propellant such as n-butane should be used. because, This is because such propellants quickly evaporate and form bubbles when they leave the actuation button. be.

The shampoo composition of the present invention is suitable for use in textiles such as carpets, upholstery materials and pile fabrics. Used in the same manner as other conventional shampoo compositions for cleaning objects can do. Not only does the fabric become cleaner, but it also has stain-resistant properties. You get the advantage of being in an elevated state. Therefore, this type of traditional Requires less cleaning than fabrics treated with shampoo compositions.

The following examples illustrate various aspects of the invention without departing from the scope and spirit of the invention. Zero parts and percentages are shown for purposes of illustration only, unless otherwise stated. , all by weight.

In the examples below, fabrics cleaned with various fabric cleaning shampoos ``Stain Capsule Test'' used to measure the anti-resoiling properties imparted to textiles. The experiment (Soiltng Capsule Te5t) was carried out as follows. A section of white nylon carpet that had been given a stain-resistant coating at the factory. Cut into 5 inch x 7.5 inch (63.5 cm x 19.0 cm) test pieces. Ru. This test piece is divided into 4, 5 or 6 identical pieces. should be tested Apply a shampoo composition to these sections in a flat layer and protect the hands. Rub it onto the test piece with your hand wearing medicated vinyl gloves, leaving one piece as a control. Leave this shampoo composition untreated as a blank for 24 hours at room temperature. Leave it for some time to dry. After this, the fabric is vacuum-suctioned and the shampoo set is dried. Remove build-up and debris. After drying and suctioning, run the fingers of one hand inside the fibers of the test piece. Run it to break up the fibers and make the test piece ``soft''.

After this, the specimen is placed into a drum forming a dirt capsule, the drum being lined with soot. The fibers of the specimen should therefore point inward towards the center of the drum. , powder "dirt" (previously filtered through a mesh with 1 mm openings) ) into the inside of the drum. Furthermore, this dirt capsule is activated during operation. Tetralabs with rubber feet arranged in a tetrahedral pattern to simulate a person walking on the specimen. the dirt capsule drum at a speed of approximately 40 revolutions per minute. Rotate for 5 minutes.

After 5 minutes, stop the rotation of the dirt capsule drum and remove the specimen. Shake to remove loose dirt and visually assess the amount of dirt each piece had. Ru. If you feel that dirt needs to be vacuumed out, remove it from the dirt capsule. After removal, aspirate the specimen before evaluation. Visually observe the condition of each piece. Rank them using a 10-point system. In other words, lO appears to be “completely clean” Things, and O are things that are considered "very dirty."

Implementation medical field 21 The shampoo compositions in the table below are in self-pressurizing form that can be used for daily cleaning. carpet and textile cleaning compositions, these compositions are easy to make. To be used as a product for light cleaning and air exchange effect. is what is intended. This composition is simply sprayed onto the fabric; The composition is left to dry and blotted without rubbing into the fabric. these The composition also reduces vine bacteria present in textiles such as those found in carpets. For example, disinfectant (IRG^SAN[F]DP-3 00).

Disaster relief 1 s 1 Deionized water 83.536 83.236 84.236 Sodium benzoate, Flake 1.500 1. sOo 1.500 borax lO mole o, so o　o, soo　o, so.

TlN0PAL @CBS-X O,0G2 0.0G2 0.002TIN OPAL @ SBM-GX O,002G, 002 0.002SD^-3A Ethyl alcohol (95%l 7.500 7.50G 7.500IRGAS AN　D　DP-3000, 1000, 1000, 100 Sodium Lauryl Sulfate (28%) 1.500 1.500 1.500 Sodium Lau Ril sarcosinate (30%) 0.410 0.410 0.410REWO CORO5■B 30101 0.500 0゜500 0.500 Rug Cree Ning Polymer A' 1.000 1.000 1.000AC330 Wax Emulsion (28% + 31.500 1.500 1.500TEGOPRE N[F]6950 (30% + 0.250 0.250 0.250 ZONY L[F]7950 (30%l O,5000,50G 0.500ALGLI ARD @RD O, 200---ZELAN0333 0.500 1. 000 - Fragrance o, soo o, soo o, so.

Total intermediates 100% 100% 100% WipH value (using 50% aqueous KOH) 1 10.5 10.6 10.5 Final composition: The above intermediate 85.000 + 15.000 8! 1.00 On-butane (48 p, s, i, g or 15.000 15.00G 15.000331 pa skull vapor pressure) Total composition: 100% 100% 100% The percentage after the name is active ingredient.

1. Alkenylsuccinic acid, disodium salt, Revo Chesisches Werke GsbH.

5teinau, German color obtained.

2. Methacrylic acid/styrene/n-butyl methacrylate 35155/10 Weight ratio of aqueous emulsion polymerization polymer, 25% NVM.

3.28% AC Polyethylene AC330, 7% Nonylphenol Ethoxyle (10 ethoxy group average) nonionic surfactant, 0.2% 37% formal Dehyde, consisting of 1.4% 50% aqueous potassium hydroxide solution and 63.4% water Aqueous emulsion, 35% NVM (2g/40min/145℃), p! (Ha 8.5-9.5゜ These compositions were manufactured as follows. That is, they are completed in the order listed in the table. First, prepare an intermediate composition by mixing the components with thorough stirring, and adjust its pn value to 50% water. Adjust to 1015 using an aqueous solution of potassium oxide (50% aqueous KOH).

This intermediate is placed in a conventional pressurizable aerosol container and sealed with a conventional needle sol valve. Seal. This container was filled with the stated amount of n-butane through the valve and then Attach the sol operation button or operation top cover to the valve stem. After this, the composition is It can be sprayed onto carpets and upholstery materials. Apply this to the fabric with a brush. Rub it in, leave it to dry, then blot it off. This improves dirt resistance. It has a high resistance to A clean, conditioned fabric is left behind.

Providing bean sprouts The following shampoo composition can be used as an aerosol composition for intensive cleaning. Examples of self-pressurizing carpet and fabric cleaning compositions that can be used are doing.

□　Matandanヱ Deionized water 84.296 83.99G 84.996 78.781 Bora 10 moles o, soo o, soo o, soo o, so.

Sodium benzoate, flakes 1.500 1.500 1.500 1.5 00TINOPAL @CBS-X O,0020,0020,0020,0 02TINOPAL■5BM-GX O,0020,0020,0020,00 2DowANOL■DPM' 2.000 2.000 2.000 2.50 0DOWANOL■PM22.0 [102,0002,0002,500JON CRYL ■903 (40% + 1.000 1.000 1.000 4.3 30^C330 wax emulsion (28% 1 1.500 1.50Q 1 ．． 500 1.570 Sodium lauryl sulfate (28%l 5.500 5.50G 5.500 7.310RE 0 COROS ri) B 301 0 - - - - - 0.500TEGOPREN@6950F30%l 0 ．． 250 0.250 Q, 2S0 0.255ZONYL @7950F3 0%l　O,5000,5000,500-ALGUARD @RD　O,2 00-----ZELAN @ 338 0.500 1.000 --- -Fragrance agent 0.250 0.250 G, 250 0.250 Intermediate total 10 0% 100% 100% 100% adjusted po value (using 50% aqueous KOH 1 1 0.5 10.5 10.5 10.5 Final composition: The above intermediate 92.500 92.50G 92.500 92. Eloon- Butane 7.500 7.500 7.500 7.500 Total composition 100 100% 100% 1, dipropylene glycol monomethyl ether Dow Chemical Company (Midland).

Michigan, USA).

2. Propylene glycol monomethyl ether, from Dot Chemical obtain.

3. Styrene/α-methylstyrene/acrylic acid polymer emulsion, 44%N VM (2g/40min 7145℃), the acid value of the conopolymer is 65.25℃ Kuffield viscosity is 200mPa, s, Tg is 110℃, weight average molecular weight is 2 00000 or more, pe was adjusted to 8.2 using ammonium hydroxide.

5specialty Chemicals Mijdrecht BJ, -Po Obtained from 1ylIers (Mijdrecht, Netherlands), which has S, C, Johnson & Son, Inc. (Racine, Wilico It is an affiliated company of nsin, USA).

4. Vapor pressure, 48p, s, i, g, (331 Pascal).

These compositions were manufactured as follows. That is, they are completed in the order listed in the table. First, prepare an intermediate composition by mixing the components with thorough stirring, and change the valence of 211 to 1O, Adjust to 5. This intermediate is placed in a conventional pressurizable aerosol container and – Seal with Rosol valve. Fill this container with the stated amount of n-butane through the valve. Attach a conventional aerosol actuation button or actuation top to the valve stem. Group after this The composition can be spray dispensed onto carpets and upholstery materials. Bra this Rub it into the fabric with a cloth, leave it to dry, and then blot it off. This will cause dirt A clean, conditioned fabric with improved resistance to remain.

Supporting doctor Dan Nijodan The following shampoo composition is suitable for use in a trigger sprayer as a stain remover. 1 shows a carpet and textile cleaning composition.

1 iu! Published I 8th Dan Deionized water 84.650 84.350 85.350 Citric acid, anhydrous 0. 400 0.400 0.400 Sodium carbonate o, soo o, soo o , so.

Rug cleaning polymer = A 3.0 (103,0003,000 surfactant mixed Compound A (35%)' 3.000 3.000 3.000TEGOPREN [ F] 6950 (30%l O, 2500, 2500゜250＾C330 Watsuku Sukomarujion +211% +31.500 1.500 1.500 Air freshener o , soo　o, soo　o, so.

ZONYL [F] 7950 (30%l 0.500 0.50Q O,500 ALGUARD ■RD O, 200---ZELAN [F] 338 0.50 0 1.000 - DO buy eight office lady) p threshold 3.000 3.000 3. 000 isofurohanol, anhydrous 2.00G 2.000 1000 total: io o% 100% 100% adjusted pH value (using 10% aqueous NaOH + 8.0 8 ．． 0 8.0 The percentage after the name is the active ingredient.

1. Sodium lauryl sulfate 13%, sodium alkylolamide 3 consisting of 16% rufosuccinate, 65% water and the balance surfactants and salts. 5% NVM mixture.

These compositions are prepared by mixing the ingredients in the order listed in the table with thorough stirring. A cleaning shampoo composition is prepared and mixed with a 10% aqueous sodium hydroxide solution. ("10% aqueous NaOH") using p! manufactured by adjusting to 18.0. was created. This composition is filled into a conventional trigger spray container. using this composition It can be used to clean the entire surface of the fabric, but it can also be used as a stain remover for small areas. You can also. Spray this composition onto the stained area of the carpet or upholstery material. Apply it and leave it on the stain for 2 minutes, then remove the sprayed area. Rub it with a rag or mop and leave it to dry. If desired, click The coated area may be suctioned, thereby providing improved resistance to staining. An area of clean, conditioned fabric with natural properties is left.

Plunger I12U The following shampoo composition can be used as an aerosol composition for intensive cleaning. Examples of self-pressurizing carpet and fabric cleaning compositions that can be used Ionized water -75,49378,812 borax lO mole o, soo o, So.

Sodium benzoate, flakes 1.500 1.500 Rug cleaning poly Mar A 7.735-JONCRYL[F]9G (4614,299REWO CORO5@B 3010 0.500 0.500 Sodium lauryl sulfate Feito (28%1 5.487 7.310TEGO-BETAIN[F]L 71 1.706 - DOWANOL @ DPM 2.500 2.500 DOWANOL PM 2.500 2.500 TINOPAL CBS-X O,0G2 0.002TINOPAL05BM-GX O,0020,002 ^C330 wax emulsion (28%l 1570 1.570TEGOP REN @ 6950 (30%l O, 2550, 255 fragrance 0.250 0.250 Total intermediates 100% 100% Adjusted pH value (using 10% aqueous NaOH 1 9.5 9.5 Final composition: Above intermediate 92.500 92.500 n-butane 7.500 7.500 Total composition: 100% 100% 1, :+:+7 Midobrovirhetaine 30% NVM solution, Th, Gold Obtained from Schmidt.

These compositions were obtained by sequentially combining each component in the same manner as in the above examples. Prepared by placing the composition in an aerosol container as described in Examples 4-7. It was. These compositions are intended to be used as heavy duty cleaners. has been done. i.e. sprayed onto the fabric to be cleaned and Rub into the fabric with a sponge mop for best cleaning. After this, release Allow to dry and remove from the fabric with suction.

Seedling ■1 day In this example, the performance of the compositions of Examples 11 and 12 was evaluated in the soil capsule test and in the actual walking test. was tested and compared to commercially available carpet shampoo compositions.

The results of the soil capsule test are shown in Table ■. In this table, one block is 1 Four compositions, five soil capsule carpet strips representing results for three soil capsule carpet strips. Compositions or compositions arranged from top to bottom in one block containing six compositions The order represents the order in which those compositions are arranged from left to right on the carpet strip. There is. Ratings were made visually on a scale from 0 to IO. 0 looked very dirty 10 is the score when the image is perfectly clean.

WOOIJTE @Deep C1ean’ 5 GLORY @Rug C1 eaner24 Example 11 8 Example 11 6.5 Untreated control (blank) 5 RESOLVE @Aeroso131, 5W OOLITE■Tough 5tain' 6 Untreated control 5 (WOOLIT E @5elf Cleaning' 7 P P Z' 4RESOLVE @Trigger 5prayer34 Example 12 5 Example 11 8 PPZ4 2 RESOLVE @＾eroso134 Example 11 5 Untreated control 8 GUL ORY ■ Rug C1eaner’ 31001 TR0UBLESHOOTE R57 untreated control 6PROFONDEUR61,5 Table-1 (continued) PROFONDEUR63RESOLVE @＾erosol 31PPZ4( Sample #ll 2.5 Example 11 6ppz’ (Sample #2) 2 Untreated Control 4 Untreated control 5 GLILORY@Rug C1eaner25 Example 11 6 PPZ4 4 Example 12 6 PROFONDEUR'　3 Untreated control 6 Example 11 4 1, Beckitt & Gols+an Household Prod ucts, Wayne, New Jersey, USA■■i.

2. S. Cjohnson & Son, Inc., Racine, Wi. sconsin, a product of the United States.

3. Lehn & Fink Products, Montvale, N EW Jersey, American product.

4, Henkel 5olitair, Levallois, France product.

5, PCProducts (10011Ltd, Kersal Val e, Manchester, UK product.

Q, La Johsson Francaise S, ^,, Cergy, A product of France.

Table ■ shows the results of the stain capsule test for stain prevention for Example 11 and Example 12. at least as good as five other commercially available products tested together in has been shown to be superior in many cases.

White nylon was used to test stain resistance under actual usage conditions, subject to vigorous walking. Cut out two samples of carpet with a size of 200emxlOOc, and cut each It was marked and divided into six areas. Apply and release the following products to these areas: Set it aside to dry completely. Tape each sample carpet to the hallway of the laboratory building. I stretched it out and left it for a total of four weeks to be trampled by pedestrians in the hallway. During this time The orientation of the carpet was reversed for two weeks to ensure that all areas were evenly soiled.

The results obtained after 4 weeks of heavy trampling are shown in Table II.

1100LITE @Deep C1ean’ 3 WOOLITE @＾er osol’3 Untreated control 6.5 Untreated control 5 PROFONDEIJR4PROFONDEUR3,5 Example 11 6 Example 11 6 豐00LITE 4su5elf Cleaning 5 HURRA @Alf oabras2 4RESOLVE■Aerosol 3. 5 HURRA @Especial Tap, '2.51, Reckitt-&Co 1aan, 5t-Florent-Sur-Cher, a product of France.

2. Anfort America S, A, , Martinez Ca s+pos, kladrid, products from Spain.

3. Kanfort＾-erica S,＾9 company HURRA@Espec ial Tapiceriag.

In this test, Example 11 was the best among the second samples.

The first sample, Example II, was slightly more soiled than the control; It was at least somewhat better than other compositions given.

Yujo Jose A In this example, the self-pressurizing aerosol foam compositions of Examples 1.1 and 12 were Commercially available self-pressurizing carpet shampoos of the type described in Example 13 It was evaluated in comparison with Poo composition.

To conduct this evaluation, a white cyan cloth-backed nylon carpet was It consists of mud collected outside the laboratory building, soil on the ground near the garage, and oily synthetic sludge. stained with 200 g of an oil-based soil mixture. These dirt components are thoroughly mixed The stones were then removed from this stain mixture. This soil mixture was - Spray the carpet sample evenly over the entire surface of the carpet for 5 to 1 part. Walked on it, dragged it, and trampled it. Then this carpet Shampoo composition to be shaken to shake off loose particles and tested was allowed to settle for one day before applying.

Weigh the container of each aerosol carpet shampoo composition initially and after applying each The soiled car as described above is applied in such a way that an equal amount of the shampoo composition is applied to the test area. PET samples were applied with the test composition. Follow the instructions in the instruction manual for each shunt. After shaking the poo composition well, hold it at a distance of 50 to 60 centimeters from the carpet sample. was sprayed as a foam onto the marked area of the soiled carpet sample. This bubble Easy to apply, rubbed into the carpet pile using a cleaning sponge After visually assessing the properties, the carpet was left to dry. Dryness is also important The resulting composition was removed by suction.

After this, each cleaned area of the carpet sample is compared to the cleaning performance. Conditioning was visually evaluated using a rating scale of 1 to 65. . A rating of 1 indicates very poor leaning performance or very poor condition. 5 indicates very good leaning or effective conditioning. represent.

The compositions of Examples 11 and 12 all had foam volumes and foam stability of Henkel PP. superior to the Z composition and even compared to the PROFONDEUR composition. Although it could not be said to be slightly better, it was on par. The composition of Example 11 is the most Gives a creamy lather and may be somewhat difficult to rub into the carpet pile. I found out.

on carpet samples using the tested compositions and their oil-based soil mixtures. The ranking of cleaning performance from best to worst was as follows: Example 11 (best) Example 12 PROFONDELIR )1 enkel PPZ (worst) Similarly, the evaluation ranking of the conditioning performance of each cleaning shampoo composition. was as follows: Example 11/Example 12 (best, between the two, etc.) Henkel PPZ PROFONDEUR (worst) A similar evaluation test was now carried out using a water-based soil mixture. The mixture is simply made from 200 g of soil from the ground near the garage without adding any oily dirt as described above. It had been done. Apply this water-based stain mixture to nylon carpet of the type described above. Wearing. A shampoo composition was then applied in the same manner as above. In this test, H enkel Two different samples of PPZ (PPZI and PPZ2) with mutual sex It was used for performance comparison. However, these two items were purchased from the same retailer at the same time. It is something that was given.

Henkel PPZI (best) Example 11 Example 12 Henkel PPZ2 PROFONDEUR (IN EVIL) The difference between Henkel PPZI and PPZ2 for water-based soil mixtures is explained I couldn't come.

Multiple tests using water-based soil mixtures are performed and the individual scores are combined for an overall evaluation. I got a point. The overall evaluation score for these exams is 30 points, which is the highest for ppzt. A close second place was Example 11 with 28 points. Next is Example 12 with 24 points. , followed by PPZ 2 with 19 points. PROFONDEUR is an overall evaluation score had the lowest score of 9 points. Example 11, Example 12 and PPZ 1 are carpets PPZ2 and PROFONDEtlR depending on the conditioning effect of the sample. exceeded.

夾し丞上l２λl In these examples, the types of waxes in shampoo compositions according to the invention were varied. The effect was investigated using a soil capsule test.

The basic composition was prepared with the following formulation: 76.351% deionized water: Borac. Sodium dibenzoate 10 mol 0.500% Sodium dibenzoate 1500%, REWOCOR O3■B5010 0.500%; JONCRYL■90 (45%) 4. 330%; 7.310% suprasium lauryl sulfate, DOWANOL @DPM 2.500%; DOWANOL@PM 2.500%; TlN 0PAL■CBS-X 0.002%; TlN0PAL■5BM-GXwoo, OO2%; TEGOPREN @6950 0.255%8. In, U aroma The agent t-0.250%. Mix these ingredients in the order listed, then 50 % potassium hydroxide aqueous solution p)! Base composition-base by adjusting to 9.5. It was eight minutes ago.

In Examples 15 to 23, the following amount of wax emulsion was added to 96.000 parts by weight of base A. prepared by mixing John and deionized water. That is, Example 15: AC3 30 wax emulsion (1.705 parts of 28% 1 and 2.295 parts of deionized water) .

Example 16: Hoechst Wax KLE aqueous emulsion +19. 47% + 2.822 parts and 1.178 parts deionized water.

Example 17 - Carnauba wax, Light North Country, 17% of T-3 and nonionic fatty alcohol polyglycol ether surfactant (IIULsIFAN ■ RT 359, Zsch of Lahnstein, Germany Aqueous emulsion with 3% of ISAER & Schwartz products) 2.8 22 parts and 1.178 parts deionized water.

Example 18: Carnauba wax, Light North Country, 3.4% of T-3 (melting point 82.5-85℃) and paraffin wax (lowest melting point) point 55 to 57°C) 13, 6% to klULsIFANORT 359 to 3% 2.753 parts tonneau mixture (total NVM is 19.96%) and 1.247 parts deionized water .

Example 19: AC629'7/Cux (7) 22. 9% and from BASF ( 7) LUTENSOL@0N70 (synthetic fatty alcohol with an average of 7 ethoxy groups) Aqueous emulsion (total NVM 33.2%) with 8.3% of coal) 1 , 657 parts and 2.343 parts of deionized water.

Example 20: 25.5% of Hoechst PED 153 wax and LU Aqueous emulsion with 6.4% of TENSOL@0N70 (total NVM is 33. 3%) 1.651 parts and 2.349 parts deionized water.

Example 21: 29.1% of EPOLENE OE43 and Huyu, Texas, USA - Stone's 5hell Chemica1 NEODOL@25-9 surfactant Aqueous solution with 8.7% of sex agent (CI2 C15 linear primary alcohol ethoxylate) 1.363 parts of Mulsion (40.31% total NVIi) and 2.637 parts of deionized water Department.

Example 22: EPOLENE @ 13 parts 4% of E20 and EPOLENE @ 13.4% of E20 and LLrrENSOL @ 0NTO noro, 7% (7 3 aqueous emulsion (total NVM 4133.65%) 1, 633 parts and deionized 2.367 parts of water.

Example 23: Just added 4.000 parts of deionized water to 96.000 parts of Pace A control composition.

A soil capsule test was conducted using two samples of carpet. Each sample carpet The plot was divided into six test areas. for each carpet sample. The test results are shown in Table III in a similar manner to Example 13.

Example 16 6 Example 20 6 Example 15 7 Example 15 7 Example 17 5 Example 21 Milk 5 Example 18 4.5 Example 22 5 Untreated control 3.5 Untreated control 3 Example 19 6.5 Example 23 6.5 Contains one variety of wax as above All of the compositions used were untreated control carpet samples (10 was tested for anti-resoiling performance). It was improved compared to the best version. This group adds carnauba wax. However, Example 18, which contained soft paraffin wax, had the lowest performance. vinegar All compositions had comparable performance to Control Example 23 containing anti-refouling polymer. was. Example 15 showed the best performance in this test.

Real m L21ヱ In this series of examples, one of the three necessary components of the present invention ( Textile cleaning polymers, waxes, silicone betaine polymers) compositions containing only some of the ingredients as well as compositions containing all three of the necessary ingredients. The compositions were evaluated. Examples 24 to 33 are comparative examples.

In some formulations, it is incorporated into some commercially available carpet shampoo compositions. Textile antistatic agents, namely Rewo, 5teLnau, Germany Product name REWOOLIAT CP from Chesiscbejerks GmbH A drug sold by IJ was added. In addition, REWOOAT■CPE mackerel is N -Methyl-N-(pentaethoxy)-N-cocoammonium methosulfate 1 00% NVM.

Examples 24 to 29 are according to the following formulation: For Examples 24 to 29 All intermediates contained the following components: 0.50%; Sodium breathate 1.50%; REWOCOROS B5010 0.50% : DOWANOL ■ mouth pv 2.00%: SD^-3A ethyl alcohol (9 5%) to 1.00%: and fragrance to 0.25%. In addition to these ingredients, intermediate The components listed in the table below were present in the body. Numbers are percentages.

Intermediate for the example on the right 24 λdan deionized water? 8.11 76. 75 73.48 Rug cleaning polymer A 8.22 8.04 9.51 Surfactant mixture A (35116,95-8,04 sodium lauryl sulfate Eight (28%l 8.51 -5TEINAQAT ■CPE support (100%1 0.97 0.95 --A C330 wax emulsion (28%l) -- ---3,22TEGOPREN@6950 (30%l)-----Listed on the right Intermediates for Examples Suyu Dan Deionized Water 73.57 82.46 81.37 Rug cleaning polymer A 9.28 G, 11 6.01 interface Activator Mixture A (35%) - 5,16-sodium lauryl sulfate (28 %l　8.26-6.36STEINAQAT　@CPEM(100%l　-- ---AC330 wax emulsion (28% 1 3.14 --- --T EGOPREN■6950 (30 engineering 1-o, sz 0.51 these intermediates is made by simply combining the ingredients in the following order with thorough stirring: Two bottles, borax, sodium benzoate, rug cleaning polymer A, REWOCOROS B5010, surfactant mixture A, sodium lauryl Rufeto, DOWANOL■DPM, alcohol, 5TEINA (IAT■ CPEM, AC330 wax emulsion, TEGOPREN■6950 After mixing the fragrance, the pH value of the intermediate was adjusted to 9.5 with a 10% NaOH aqueous solution. I arranged it. The final compositions of Examples 24-29 were 92.5% of the intermediates in each example. % and n-butane 7.5%.

These compositions were packaged in aerosol containers as described in Examples 1-3.

The intermediates for Examples 30-37 are mixtures of the intermediates of Examples 24-29. It was. That is, The intermediate for Example 30 is a 1:1 mixture of the intermediates for Examples 24 and 26. there were.

The intermediate for Example 31 is a l=1 mixture of the intermediates for Examples 24 and 28. there were.

The intermediate for Example 32 is a l:1fi compound of the intermediate for Examples 25 and 27. Met.

The intermediate for Example 33 is a 1:1 mixture of the intermediates for Examples 25 and 29. there were.

The intermediate for Example 34 is a l:l mixture of the intermediates for Examples 26 and 28. there were.

The intermediate for Example 35 is a l:l mixture of the intermediates for Examples 27 and 29. there were.

The intermediate for Example 36 is 1=l of the intermediate for Examples 24.26 and 28. :l mixture.

Intermediate for Example 37 is 1:l of the intermediate for Examples 25.27 and 29 :l mixture.

The final compositions of Examples 30-37 contained 92.5% of the intermediate for each example and n- It consisted of 7.5% butane. These compositions are described in Examples 4-7. packaged in an aerosol container.

To perform the soil capsule test, one nylon fabric sample is marked in five areas. It was divided into areas. In addition to Examples 24-37, this test also included the following commercially available fabrics: Also included were shampoo compositions: PROFONDELIR Henkel PPZ GLORY @Rug C1eaner Example 13 Henkel PPZ 100LITE■Tapig Moquette, fReckitt k C olwran) SAPUR, (Thos, Düsseldorf, Germany) pson Gmb)l) TIIB^, (E of Hallein, Germany) rdal　Gs+V) EXPRESS POUDRE, (La Joh (obtained from Francaise S, A.).

Each test composition was tested so that one marked area was evenly coated with foam shampoo composition within a standard period of time. The area was sprayed to cover the area. Apply the foam shampoo composition by hand. and left to dry at room temperature for approximately 26 hours. Which car – PET samples were also left uncleaned in one section as a control (blank). ), after which the dried samples were subjected to a soil drum test.

The results of this soil capsule test are shown in Table v on a scale of 1 to 5. 0 grade l is the cleanest sample section, 2 is the next cleanest, and 5 is the 5th cleanest sample section. As in Example 13, Table IV represents the dirtiest of the three compartments. The order of the compositions within is related to their position on the carpet sample.

PROFONDEUR5 Example 29 3 Example 24 2 5 APUR4 Untreated control 1 Untreated control 1 SAPUR4PROFONDEUR5 Example 27 3 Example 30 2 SAPUR4 Example 34 3 PROFONDEUR55APUR4 Untreated control'' 2 Untreated control l Example 311 3 Example 33 2 Example 32 PROFONDEUR5 Example 36 2 PROFOND EUR5PROFONDEUR5 Example 37 2 Untreated control 1 Untreated control l Example 35 3 5 APUR4 SAPUR4 Example 24 3 Henkel PPZ 2 TUB^ 2PROFONDEUR5PROFON DEUR5 untreated control l untreated control l Example 24 4 Example 24 3 WOOLITE @Tappis Moquette 3 GLORY■Ru g C1eaner Table 4-11 (continued) PROFONDEUR5 untreated control l untreated control 2 Example 30 4 SAPUR3 Example 31 5 Example 24 4 Example 32 2 EXPRESS POUDRE 1 Example 33 3 Untreated control 1 Example 34 5 Example 35 3 Example 36 4 Example 37 2 In the case of Examples 24.27 and 29, one substance of the three necessary components according to the invention Only because of this, the results were poor. In the case of Examples 30 to 35, the results were relatively good. Ta. Examples 36 and 37 were overall the best of the compositions tested.

The commercial products tested were generally not as good as other shampoo compositions tested. won.

Claims (1)

[Claims] 1. Suitable for shampooing textiles, dispersed in water with a pH value of about 7 to about 10.5. Anionic surfactants, non-ionic surfactants, which are essentially removed by suction upon drying. selected from the group consisting of surfactants, amphoteric surfactants and zwitterionic surfactants. powder containing an effective amount of at least one surfactant, which can be removed by suction upon drying; In an improved textile cleaning shampoo composition that leaves a product, a) all from about 0.5 to about 20% by weight of the composition, normally solid at 25°C and alkaline. Polymerized cleaning textiles that are water soluble or water dispersible when neutralized with compounds body, b) about 0.1 to about 10% by weight of the total composition has a melting point of at least 50°C. Selected from the group consisting of synthetic waxes, natural waxes or wax-like synthetic organic substances wax, and c) a compatible silicone betaine by weight of about 0.05 to about 5% by weight of the total composition; Union, A composition consisting of 2. Claims that the surfactant is present in an amount of about 0.5 to about 20% by weight of the total composition Item 1. Textile cleaning shampoo composition according to item 1. 3. The surfactant is present in an amount of about 0.5 to about 4% by weight, and body is present in an amount of about 0.5 to about 4% by weight and wax is present in an amount of about 0.5 to about 2% by weight. and about 0.25 to about 0.5 weight percent silicone betaine polymer. 3. A textile cleaning shampoo composition according to claim 2, wherein the shampoo composition is present in an amount of . 4. Surfactants include anionic surfactants, amphoteric surfactants, and zwitterionic surfactants. A claim selected from the group consisting of sexual agents and present in an amount of about 0.5 to about 4% by weight. Item 1. Textile cleaning shampoo composition according to item 1. 5. The textile cleaning polymer is (a) free of acrylic acid, methacrylic acid, and maleic acid. a small amount of an unsaturated alcohol selected from the group consisting of hydrate, maleic acid and itaconic acid; (b) an alkyl ataryleate having 4 to 14 carbon atoms; alkyl methacrylates having 5 to 15 carbon atoms, styrene , α-methylstyrene, acrylonitrile, methacrylonitrile and 2 to 30 the least of the bulk selected from the group consisting of 1-alkenes having 1 carbon atoms; selected from the group consisting of at least one polymer with one unsaturated organic monomer The textile cleaning shampoo composition according to claim 1, wherein the shampoo composition is 6. the wax is in the form of an aqueous emulsion of particles and at least 100°C; Pressure emulsified polyethylene, oxidized polyethylene and oxidized polypropylene with a melting point of The textile cleaning shampoo according to claim 1, wherein the shampoo is selected from the group consisting of: Composition. 7. The silicone betaine polymer has the following general formula R2(R1)2SiO((R1)2 SiO)×(R2R1SiO)ySi(R1)2R2 {wherein, Each R1 is an alkyl group having 1 to 18 carbon atoms, an aryl group, or a polyol group. means a xyalkylene group, provided that at least 70% of R1 groups are methyl groups shall be tasted; R2 is the same as R1, and at least one R2 is (I)-(C H2) 3OCH2CHR3CH2R4 group [wherein R3 and R4 are different from each other] , one means hydroxyl group and the other -N+R5R6(CH2)nCOO- group (wherein R5 and R6 are 1 to 4 carbon atoms) means an alkyl group or a benzyl group having atoms, and n=1.2 or 3)] and the following (II)-R7CONHR8N+R5R6(CH2)nC0 0-group (wherein R7 is a divalent alkylene group having 2 to 12 carbon atoms, and R8 means a divalent alkylene group having 2 to 6 carbon atoms) selected from one of the groups, x is a number from 0 to 200, y is a number from 1 to 50 1 The textile cleaning shampoo according to claim 1, which is a silicone betaine polymer. Composition. 8. The silicone betaine polymer has the following general formula (CH3)3SiO(SiACH3 O)m(Si(CH3)2O)nSi(CH3)3 [wherein, A is a group of the following formula -(CH2)3OCH2CH(OH)CH2N+(CH3)2CH2COO-m and n are each greater than O, and the sum of m+n is such that the viscosity of the polymer at 25°C is Approximately 50 to 90 m2/sec. Specific gravity at 25°C is approximately 1.07 to 1.09 g/c m3. 8dH. RossMile of the polymer in a 0.1% solution in water at a temperature of 25°C s bubble height is 80 ] The textile cleaning shampoo according to claim 7, which is a silicone betaine polymer. Composition. 9. Textile cleaning polymers include methacrylic acid, styrene, and n-butyl ataryl. and optionally further a polymer of α-methylstyrene. Textile cleaning shampoo composition. 10. Suitable for shampooing textiles, dispersed in water with a pH value of about 7 to about 10.5 Anionic surfactants, non-ionic surfactants selected from the group consisting of surfactants, amphoteric surfactants and zwitterionic surfactants. about 0.5 to 10% of at least one surfactant, which is removed by suction during drying. Improved textile cleaning shampoo compositions that leave a powder product that can be removed hand, a) from about 0.5 to about 10% by weight of the total composition, normally solid at 25°C; Fibrous cleaners that are water-soluble or water-dispersible when neutralized with a caustic compound (a) acrylic acid, methacrylic acid, maleic anhydride, from about 2 to 40% by weight of the total polymer selected from the group consisting of maleic acid and itaconic acid. % of unsaturated carboxylic acid functional monomer and (b) having from 4 to 14 carbon atoms. Alkyl acrylates, alkyl methacrylates having 5 to 15 carbon atoms salts, styrene, α-methylstyrene, acrylonitrile, methacrylonitrile and 1-alkenes having 2 to 30 carbon atoms. about 60 to 98% by weight of the total polymer of at least one unsaturated organic monomer. at least one polymer selected from the group consisting of: b) at least 100°C; selected from the group consisting of polyethylene oxide and polypropylene oxide having a melting point of the total composition selected from the group consisting of hard wax-like synthetic organic materials. about 10% wax; and c) from about 0.05 to about 5% by weight of the total composition. Compatible silicone betaine polymer R, which is a silicone betaine polymer of the following general formula: 2(R1)2SiO((R1)2SiO)X(R2R1SiO)ySi(R1) 2R2 {wherein, Each R1 is an alkyl group having 1 to 18 carbon atoms, an aryl group, or a polyol group. means a xyalkylene group, provided that at least 70% of R1 groups are methyl groups shall be tasted; R2 is the same as R1, and at least one R2 is (1)-(C H2) 3OCH2CHR3CH2R4 group [wherein R3 and R4 are different from each other] , one means hydroxyl group and the other -N+R5R6(CH2)nCOO- group (wherein R5 and R6 are 1 to 4 carbon atoms) means an alkyl group or a benzyl group having atoms, and n=1.2 or 3)] and the following (II) -R7CONHR8N+R5R6(CH2)nCO O- group [in the formula. R7 is a divalent alkylene group having 2 to 12 carbon atoms, and 1 of the group consisting of (jR8 means kylene group having 2 to 6 carbon atoms) selected from x is a number from 0 to 200, y is a number from 1 to 50 1 A composition consisting of 11. The surfactant is present in an amount of about 0.5 to about 4% by weight and has a textile cleaning weight. Coalescing is present in an amount of about 0.5 to about 4% by weight and wax is present in an amount of about 0.5 to about 2% by weight. % and the silicone petaine polymer is present in an amount of about 0.25% to about 0.5% by weight 11. The fabric cleaning shampoo composition of claim 10, wherein the shampoo composition is present in an amount of %. 12. Surfactants include anionic surfactants, amphoteric surfactants and zwitterionic surfactants. The textile cleaning shampoo according to claim 11, wherein the cleaning agent is selected from the group consisting of activators. Pooh composition. 13. The wax is in the form of an aqueous emulsion of particles and has at least 100 The textile cream according to claim 12, which is a pressurized emulsified oxidized polyethylene having a melting point of shampoo composition. 14. Textile cleaning polymers include methacrylic acid, styrene and n-butyl atari Claim 1 which is a polymer of ester and optionally further α-methylstyrene. 3. The textile cleaning shampoo composition according to 3. 15. The amount of silicone betaine combined has the following general formula (CH3)3SiO(SiACH 3O)m(Si(CH3)2O)nSi(CH3)3 [wherein, A is a group of the following formula (CH2)3OCH2CH(OH)CH2N+(CH3)2CH2COOm and n are each greater than O and the sum of m+n is such that the viscosity of the polymer at 25°C is about 5 0 to 90m2/sec. ．． The specific amount at 25°C is about 1.07 to 1.09 g/cm 3.8dH. ROssmi of the polymer in a 0.1% solution in water at a temperature of 25°C lle foam height is 80 ] The textile cleaning shampoo according to claim 15, which is a combination of silicone betaine and - composition.