JPH07494A - Deodorant - Google Patents

Abstract

PURPOSE:To enable the sustaining of deodorizing effect exceeding 90 days with the prevention of the drying of a water absorbing resin by a method wherein a capillary absorbent is mounted vertically at the center of a hydrate resin container and water of a deodorizing fragrant liquid is inserted into a separate container fitted into a lower part of the container to keep contact with a water supply resin on the top surface through the capillary absorbent while a lower liquid is brought into contact with the upper water absorbing resin to replenish water thereto. CONSTITUTION:A water tank holding water is inserted into an internal lower stage of an outer box body 1 for advertisement and a converging fiber 3, ceramic porous matter or resin porous body 3 as capillary absorbent is inserted into the center thereof and the porous body 3 is stuck out of the tip A of the absorbent to insert a container holding a gelled deodorant or a porous sponge molded body 4 into an upper stage. The absorbent 3 of a water tank at the center lower part of the container is kept in contact with an upper absorbent 6. The vapor of the deodorant is emanated an diffused to contact with air so that malodor is absorbed to be adsorbed and embedded. Water is moved upward with the absorbent 3 and distributed to raise from the water tank by the amount of water of the gelled resin evaporated. Thus, a gelled absobent 10 is supplied with water through absorption medeum 3.

Description

Detailed Description of the Invention

In the present invention, a conventionally known hygroscopic deodorant is mainly composed of an absorbent resin, and the water content is evaporated to change the absorbent resin from a powder to a hydrogel, and then to a lump dry powder. The disadvantage that the deodorant effect is lost due to such evaporation is that the deodorant on the gel is equipped with a separately prepared aquarium container containing water and a capillary absorber or porous body is placed on top of this. After fitting, the capillary absorber or porous body is used to replenish the water in the water tank to the gel deodorant, and the gel deodorant is replenished with water. The development of deodorant characterized by maintaining the deodorant effect by replenishing the moisture of the above, and further, the deodorant in which the advertising text of each company, the picture book, and the ultraviolet rays were applied to this outer casing. Is the content of the development. Most conventional gel deodorants are 80cc-3
Put perfume and deodorant absorbent resin in a 00cc container and add water afterwards to make a gel, and remove the moisture and gel of the gel deodorant from the porous surface or open surface of this container. Many products tried to eliminate odors by releasing odorants and fragrances, and gelatin, agar, and seaweed were separately used as gelling agents. However, in this container, the water vaporization of the gelled product was extremely rapid and the gelled product was dried in about 20 to 40 days, and the deodorizing effect was decreased in proportion to the drying. The reason for this is that the water vapor that evaporates from the top surface of the gelled substance creates convection in the room, so the more the water vapor, the greater its deodorizing effect, and the less the amount of evaporation with water vapor, the less the deodorizing effect. . Therefore, in order to enhance the evaporation and enhance the deodorizing effect, the shorter the usage time of the deodorant is, the higher the effectiveness is, and the life is shortened for practical use. Further, there is a problem in that the deodorant is replaced with a short-lived one and the cost and cost are high. Moreover, since many of these deodorants are all non-productive, there is a possibility that the consumer side has a limited range and period of use due to an increase in cost, especially for commercial use, for example,
It was inconvenient to handle in freezer warehouses, dining rooms, banquet halls, theaters, and public toilets because of the high cost. Recently, a germicidal lamp using an ultraviolet lamp and a deodorizer using a sterilization method that generates ozone gas have been used. However, the constant use of ultraviolet rays adversely affects the human body along with the use of ozone gas. While limiting the amount by indirect irradiation and indirect absorption to the human body by the combined use of deodorant,
It is more novel to make the deodorant effect less harmful to the human body, and to reduce the radiation of the radiation substance to maintain the bactericidal property. Is adapted to this. Therefore, the present invention, by separately providing this gelled product, and by increasing the sustainability by replenishing water, improve the economic efficiency and enhance the performance of the deodorant,
In addition, the selection of the deodorant component was changed by improving the deodorant in the water liquid, and it was equipped with an advertising purpose to enhance the advertising effect and alleviate the harmful effects of the UV and ozone gas generators that have been conventionally used, and have an immediate effect. The effect of sustaining the property is provided, and it is particularly useful for removing harmful gases by removing marine product processing, livestock product processing, frozen warehouses, manure sludge, industrial waste, etc.
It is an industrially useful invention because it is useful for the continuous release of the bactericide in the medical field. In order to distinguish between this water tank container and the gel deodorant container, you can freely choose in the sled selection,
A method of stacking two containers, a combination of a porous container and a water tank, etc., absorption by focusing fibers of a capillary absorber, and combination with a gel deodorant by porous ceramics, plastics, sintered porous bodies, etc. Is free. Also, a method of dipping the sealed bag-shaped deodorant gelated product in a porous plastic bag into a water tank container to evaporate water from the porous surface of the porous bag surface is also included in this structure. Also, a method of constantly replenishing water or deodorant liquid with a gelled substance or a porous body as an evaporation surface to bring it into contact with air to exert a deodorizing effect by evaporating water is also included in this deodorizer. Therefore, replenishment of water in the aquarium will maintain deodorization forever, and for amine-based malodors, a deodorant that absorbs this will also be used for organic malodorous substances such as butyric acid and Yoshigusa slope. As for the deodorant that absorbs this, it also has the effect of selectively distinguishing the deodorant that absorbs sulfide, such as mercaptan, and deodorizing it. Because it is made by the combination of, it is possible to selectively absorb it according to the bad odor. The following is a description of the embodiment of the present invention with reference to the drawings.
It is as follows.

FIG. 1 shows a water tank (2) containing water inserted into the lower stage of an outer housing (1) for advertisement, and a focusing fiber (3) of a capillary absorber or ceramic porous or plastics in the center thereof. The container (5) containing the gel deodorant or the porous sponge molded body (4) on the upper surface is inserted into the porous body (3) and protruded from the tip (A) of the absorbent body of the porous body, and the container (5) is placed on the upper stage. Then, the absorber (3) of the water tank tank in the lower center of the container (5) and the absorber (6) of the upper part are brought into contact with each other. This, hanging equipment (7)
When the suspension is stopped and left still with the deodorant vapor from the porous surface (8) fitted to the upper part of the outer casing (1) and the porous surface (8) of the lid plate (9) to the upper part. It diffuses and diffuses, and when it comes into contact with the air, it exerts a deodorizing effect, absorbs a bad odor, and embeds and absorbs it. Then, the water content of the gelled product (10) gradually diffuses to the outside and then is dried, and if it changes to a solid condensate, the deodorizing effect disappears. However, the water tank (2) installed in the lower stage is the absorber (3). ) To move water to the upper part, and the lower middle absorbent body (3) is brought into contact with the lower absorbent body (3) by the lower middle absorbent body (6) of the upper gelled material container (5) to bring the lower aqueous solution into the upper absorbent body (6). Only the water content of the gelled resin that has been absorbed and evaporated is distributed from the water tank and raised to supply the gelled material and water to moisten the rapid dry state of the gelled product, so the lower water tank (2) The water liquid is replenished to the gelled absorbent body (10) in the upper stage through the absorbent body (6) through the absorption medium (3) until the water solution (B) in (1) is exhausted. Then, the gelled substance of the absorbent body (10) repeatedly evaporates on the upper surface, and water is replenished from the lower portion. Therefore, if the lower water is always replenished from the replenishment pipe (11) on the upper portion of the water tank, it will evaporate forever. Not only continues, but also when the water supply is switched to the deodorant solution, the deodorant solution rises and wets the gelled substance (10) with the deodorant solution, so the activity of deodorant is always increased. . That

2 is a front view of a side view of FIG.

FIG. 4 shows.

FIG. 3 shows the upper evaporator (4 ′) containing the gelled product.
It is a side view which shows (4 ").

Fig. 4 is a side view showing a water tank (2 ') (2 ") installed in the lower part. It is assumed that the deodorant liquids (B') and (B") are different from each other in the water liquid in this tank. The mixture is a mixture, and its formulation example is as follows.

[Example 1] Sulfide absorption medium Water 97.8% Glyoxal 10% Perfume 1% Surfactant 1% Bamboo oil or soybean oil 0.1% Others 0.1%

[Example 2] Organic acid absorbent Water 92.8% Glyoxal 1% Triethanolamine 10% Surfactant 1% Perfume 0.1% Plant dry matter 0.1% Alcohol 5%

Example 3 Amine Absorbent Water 93.0% Copper Chloride or Iron Chloride 1% Humic Acid or Yeast 3% Others 9.4% Perfume 1% Plant Dry Distillate 0.1% Surfactant 1% Peroxide 0.1. 5% When a plurality of water tanks (2 ') (2 ") containing this compounded liquid are evaporated according to the malodorous gas, they can be adsorbed and removed freely. Degradation products such as nucleic acids, hormones, and enzymatic odors such as trypsin and pepsin cannot be deodorized unless separate deodorants are added, and CLO2, BrO2, JO2, monochloroacetic acid, boric acid, iron chloride, Copper chloride, silver chloride, etc. are used, and the addition of Glycol moderates the evaporation rate.

[Fig. 2] On the surface of the outer casing (-1) shown in Fig. 2, advertisements such as Suntory are printed, and when the printed label is pasted on with pressure-sensitive adhesive, it is displayed on each surface in addition to its medicinal effect. It can also be used as a promotional material, and when it is also used for public toilets, conference rooms, outside the station room, and for cold storage, it can be sold as a novel. next,

FIG. 5 shows a bag (13) in which a gelled product (10) is placed in a porous vinyl film bag (13) in a lower water tank container (1).
4) The upper part of 4) is fitted with packing (15), and the water tank container (1
4) The gelled porous bag (13) is brought into contact with the upper part of the inside.
That is, a part of the gelled porous bag (13) is immersed. At this time, the water evaporates on the perforated bag surface on the liquid (B), and the replenishment of the evaporated water is absorbed by the deodorized liquid (B) immersed in the lower part, so the lower water tank The deodorizing effect lasts until the water solution inside is exhausted, and the deodorizing and evaporation continue by supplementing the water solution.

FIG. 6 is a deodorized gelled product container (15) (15 ′) (1) fitted to the side surface of a float (19) (19 ′) (19 ″).
Small tube (16) (16 ') (16 ") in the lower center of 5")
Are connected, and after the gelling resin is introduced, the deodorant liquid is introduced and the perforated plug is fitted, and the capillary fiber bundle (18) (18 ') (1
8 ") is fitted as an inner core in an extended state, and the deodorant gelated material container (15) (15 ') (1
5 ") on top of heat-sealed plastic film (1
7) is fused and the container (15) (15 ') (15 ")
When used, the film (17) is peeled off to expose the gelled resin and form an evaporation surface. Several kinds of these deodorant containers (15) (15 ') (15 ") are combined and floated on the water liquid (B) in the water tank (20), and the capillary fiber bundles (18) (18') are added to the water liquid (B). ) (18 ") soak
When the capillary fiber bundles (18), (18 '), (18 ") are used to absorb the capillaries, a gelling resin (2) containing a different type of deodorant is used.
2) (22 ') (22 ") is constantly wet and continues to evaporate from the deodorant liquid containers (15) (15') (15"). The water (B) in the aquarium container (20) may be ordinary water. C
It may be one containing LO2BrO2JO2, a fragrance, or alcohol, or an aqueous solution containing a surfactant. In this container (15) (15 ') (15 "), different kinds of deodorants are introduced in the form of powder in advance, and it is made to gel by adding water. The gelling container (15) (15 ') (1
5 ") on the side of the foamed resin float (19) (19 ')
(19 ") is fitted. This type of deodorizer

FIG. 7 is shown as a side view. This deodorizer effectively acts on a plurality of different types of malodors. For example, (2
2) is a sulfide deodorizing liquid powder, (22) is a powder for absorbing ammonia and amines, and (22 ″ 9 is a powder for organic acid nicotine tar).

[Fig. 5] The structure of the evaporation surface control inside the porous bag of Fig. 5 is such that the evaporation amount is limited by mixing the expanded polystyrene powder (13a) in the upper part or the lower part, and when it is inserted in the lower part, a water liquid is used. (B) The degree of levitating the surface changes. This porous plastic film is made by mixing vinyl chloride and vinyl acetate copolymer resin, polyacrylonitrile resin, polyethylene, polypropylene, polyethylene vinyl acetate mixed resin with urea ester, boric acid ester, oxybenzoic acid ester and glycol. The diazo foaming agent as a foaming agent and mineral powder are mixed and stretched into a film to be used as a porous material, which is treated with acidic water or boiling water to be made porous. And this

The deodorant pre-inserted in the deodorant container (15) (15 ') (15 ") of Fig. 6 is a mixture of powdered water-absorbent resin, microencapsulated fragrance, surfactant and peroxide. It is sealed as a powder (B ') and gels when used by adding water, so that a durable deodorant can be obtained, and the porous body (D) can be removed by inserting it. The compound does not leak even if it is reversed.This powder deodorant has the following composition.

Example 4 Water 300 parts Water-absorbent resin, polyvinyl acrylate copolymerization 10 parts Surfactant capsule powder 0.1 parts Microcapsule fragrance 1.2 parts Peroxide microcapsules 2 parts Beans, bamboo dry oil microcapsules 1 part Pigment 0-0.1 part This powder blend

[Fig. 3] Put into a container (4) (4 ') of Fig. 3 and seal it, and put a capillary absorber (6) tube into the central protruding port (6') (6 ") of the lower part of the container (4) (4 '). It is fitted and the bottom surface of the absorber is pressure-bonded with films (6a) and (6a ') to seal it, and when used, it is peeled off to take out the adsorbent (6) and projecting port (6').
Water is added from (6 ") to swell and gel.
The adsorbent (6) is fitted into the projecting ports (6 ′) (6 ″), and the absorbent (6) comes into contact with the capillary fiber bundle (3) in the upper center of the lower water tank (2), Liquid (B) is an upper gelled product (1
It is designed so as to come into capillary contact with 0). For the structure of the capillary absorber,

8 (a), (6b), and (6c) in FIG.

FIG. 2 is a capillary absorbent fiber (3) extended in the aquarium (2)
Installed

Figure 9: Felt and capillary absorbent fibers (3) on top as shown
An extension of is also used.

FIG. 10 shows a short absorbent fiber bundle (6) at the center of the bottom, which separates from the capillary absorbent fiber (3) of the water tank to raise the water liquid by contact.

[Figure 8]

[Figure 9]

FIG. 10 shows a side view of the deodorant containers (5a) (5b) (5c). However, to increase the amount of water,

As shown in the side view of FIG. 11, the inverted U-shaped capillary absorber (3b) is deeply inserted into the gel deodorant, and the water tank (2
d) is installed in parallel, and the other end of the deeply-immersed inverted U-shaped capillary absorber (3b) is held to make the gelled substance (10d) absorb the aqueous liquid (B) by the capillary absorption action. The migration speed of this water liquid varies depending on the size, but in the case of a glass fiber bundle of 5 mesh diameter or a cotton fiber bundle, 300 g of water is replenished to 300 g of gelled product in 30 days in an inverted U shape, and the gelled product is always supplied. It keeps wet condition.

In the case of the one shown in FIG. 8, 100 g of the water liquid is absorbed and increased in 30 days,

FIG. 9 shows that 120g

In FIG. 10, 80 g of water liquid rises. Also used in either structure. If the amount of water in this aquarium is constantly reduced, it can be used for 6 months by replenishing it, and if a radiation mineral is put in the water in advance, the water will be 6 to 4 molecules of condensed water. Increased, less bacterial generation, and the addition of bactericides has a similar effect. When this gelled substance is substituted with felt, glass fiber, polyurethane, or foamed resin molded body, if it is absorbed by a capillary as a liquid dissolved with the deodorant of the lower aqueous liquid, evaporation and deodorization can be performed by this method as well.

FIG. 12 is a side view of the UV lamp (1E), which is attached to the cover (2E) for fixing the UV lamp (IE), and an air suction groove (3E) is formed in the lower part of the cover. , Deodorized air (K) irradiated with ultraviolet rays is covered (2
E) As it is discharged from the air outlet groove (4E) joined to the upper part, the water tank plate (5E) containing the deodorant liquid is screwed on the front surface and the surface that covers the ultraviolet rays, and the gelled product is erased on the upper part. Capillary absorbers (6a) (6b) by joining the odor device (6E)
(6c) is brought into contact with each other to absorb capillaries and to serve as a light shield for ultraviolet rays. As described above, the combination of the ultraviolet ray and the deodorant exerts an effect that the deodorizing action of the malodorous gas is immediately effective. For replenishing the water liquid, the rubber pipe (8E) is replenished with the pump by the pipe (7E) provided on the side surface. The ozone generator also has a structure similar to this device and is used together with the deodorizer. However, in addition to ozone air gas, a method of absorbing 5% to 10% of ozone water in the water tank and absorbing it with a capillary tube can also be used. I can. This porous polyolefin-based resin film bag may be a non-woven cloth bag such as Tipac or a filter cloth type in which plant fibers are mixed with synthetic resin or synthetic fibers. This tipak is highly absorbent and is used for deodorization in factories and warehouses. In addition, since the ozone gas generated by the ozone gas generator using 10% dissolved in water has little effect on the human body, when the ozone water is evaporated and absorbed, the bad smell of the toilet is reduced. In any case, the gelling deodorant using the absorption resin is more advantageous in terms of endurance because the evaporation is suppressed to one-third or less as compared with the one directly evaporated from the liquid through the capillary absorbent fiber. Malodorous gas is rarely adsorbed on the gel. Further, in the case of direct evaporation of this liquid, when a sponge resin block such as polyurethane is used as a gelled product instead of the absorbent resin, the gelled product is more durable because it is higher than the evaporation of the gelled deodorant. Further, as the position of the water tank and the structure of the capillary absorbing fiber, any of plant fiber, synthetic fiber, glass fiber, metal fiber and the like are used, but ceramic porous rod and porous glass rod are also used. This deodorizer is also used for adjusting the humidity of air and deodorizing it, and for cleaning the interior of pachinko parlors. General gel deodorant is effective for 1 to 2 months at a time, whereas gel deodorant with water tank deodorizes for 6 months while using it for a long time, convenient for nursing homes, It can also be used for the continuous deodorizing action of chlorine dioxide in addition to hydrogen peroxide and perchloric acid water of the deodorant liquid. In a car toilet,

[FIG. 5] The deodorant of the porous plastic film bag of FIG. 5 which is fitted in the form of a bag on the upper surface of the water tank is strong against vibration because it has no water leakage.

FIG. 2 is convenient because it can be hung and fixed by the handle of the outer casing as shown in FIG. In particular, the deodorant of the deodorizer of the present invention has many deodorizing effects due to the adsorption of water molecule groups due to the evaporation of water, in addition to the effect of the deodorant. The formation of tetramolecular water suppresses the growth of bacteria, so that mineral substances such as monazite, garnet, and marble are mixed in the aquarium. Unlike ordinary activated carbon or enzymatic gelation products, there is no malodorization of the gelation product itself, which occurs due to self-absorption of the malodor. As described above, according to the present invention, the gelled deodorant has a capacity of 300 cc and is put in a plastics container to generate steam from the upper part. However, to improve this, a separate water tank was set up. Capillary absorber is used to replenish the amount of vaporized water vapor, and multiple absorbers are selected according to the type of malodorous gas. By using them together, the deodorizing effect is further enhanced. Its endurance is 6 months or more in a row. It becomes possible to raise it to. In addition, in order to improve the convenience, a float is fitted on the side of the deodorizer and floats on the liquid surface to automatically absorb the liquid by the capillary.

[FIG. 7] When performing the method of FIG. 7, deodorization is performed by a selective method for deodorizing any gas, which is convenient in handling. In particular, since the powder deodorant is used by microencapsulation, the weight is reduced and the storability is high. In addition, the deodorization of fisheries processing plants and the absence of freezer and freezer in livestock processing plants are maintained due to the sustainability of the combined use of water tanks. It is an industrially useful invention because it is deodorized, deodorized in cafeterias, conference rooms, and in toilets, and is also used for large-scale business.

[Brief description of drawings]

[Figure 1] Front view of the deodorant unit with water tank

[Figure 2] Side view

[Fig. 3] Side view of a container containing a deodorant

FIG. 4 is a side view of the lower water tank container.

FIG. 5 is a side view of a deodorizer in which a porous plastic bag is immersed in a water tank.

FIG. 6 is a side view of a container containing a deodorant powder in which a capillary absorber is suspended.

[Fig. 7] Side view of a deodorant device containing different kinds of deodorant powder in an aquarium.

FIG. 8 is a side view in which the capillary absorber is deeply inserted in the center of the deodorant gelation product.

FIG. 9 is a side view of a deodorant device in which a gelled deodorant and a water solution are connected by a capillary absorber and floated on the water surface.

FIG. 10 is a side view showing a capillary absorber having only a bottom surface of a deodorant gelled product.

FIG. 11 is a side view of a deodorant device using an inverted U-shaped capillary absorber.

FIG. 12 is a side view of a deodorant device in which ultraviolet rays and ozone gas are used in combination.

Claims (1)

[Claims] As described later, make a water tank container containing water in the top or bottom of the plastic, glass, or ceramic container, and fit the bundle of the capillary absorber or the ceramic or plastic porous body on top of Liquid or its water vapor is sent to the gel deodorant medium, the evaporation of the water content of the gelling deodorant is replenished to the adsorption capillary medium to prevent it from drying, and the convection of air is caused by the water content of the evaporated gel substance. Cause the deodorant effect. A persistent deodorant characterized by printing advertising posters and plastic models on the surface.