JPH0747530B2 - Hair cosmetics - Google Patents
Hair cosmeticsInfo
- Publication number
- JPH0747530B2 JPH0747530B2 JP61253580A JP25358086A JPH0747530B2 JP H0747530 B2 JPH0747530 B2 JP H0747530B2 JP 61253580 A JP61253580 A JP 61253580A JP 25358086 A JP25358086 A JP 25358086A JP H0747530 B2 JPH0747530 B2 JP H0747530B2
- Authority
- JP
- Japan
- Prior art keywords
- hair
- perfluoropolyether
- oil
- present
- cosmetic composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/69—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing fluorine
- A61K8/70—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing fluorine containing perfluoro groups, e.g. perfluoroethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/007—Preparations for dry skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、パーフルオロポリエーテルを含む頭髪化粧料
に関する。本発明による頭髪化粧料は、粘度変化および
硬度変化が少なく、しかも酸化劣化を受けず、毛髪に対
してはつやや仕上がり効果を付与するものである。TECHNICAL FIELD The present invention relates to hair cosmetics containing perfluoropolyether. The hair cosmetic composition according to the present invention has a small change in viscosity and a small change in hardness, is not subject to oxidative deterioration, and imparts a glossy finishing effect to hair.
頭髪化粧料としての最も重要な目的の一つは、頭髪に水
分を保持させ、湿潤性、はり及び柔軟性等を与えること
である。しかも、使用性面では伸びが良く、頭髪への適
用が容易であることが要求される。更に、最近になっ
て、頭髪に対する「いたわり」の関心が強くなり、湿潤
性、はり及び柔軟性を与える主要成分である水を頭髪に
長時間保持させることが強く要望されている。One of the most important purposes as a hair cosmetic composition is to make the hair retain moisture, and to impart wettability, elasticity and flexibility. Moreover, in terms of usability, it is required to have good elongation and easy application to hair. Further, recently, there has been a strong interest in "care" for hair, and it has been strongly demanded that water, which is a main component that imparts wettability, elasticity and softness, to be held in hair for a long time.
従来、これらの要望に答えるために、鉱物油や植物油等
の中で閉塞性の高い油分（例えば流動パラフィン、スク
ワラン、ワセリン、水添植物油脂）を配合し、ころ油分
の作用によって毛髪上での水分の揮散を防ぐことが試み
られていた。しかしながら、これらの油分は、経時で酸
化されて劣化し、しかもそれに伴って頭髪化粧料の粘度
及び硬度が低下し、使用感及び安全性等の点で問題があ
り、充分満足すべき製品が得られなかった。Conventionally, in order to meet these demands, a highly occlusive oil component (for example, liquid paraffin, squalane, petrolatum, hydrogenated vegetable fats and oils) has been blended among mineral oils and vegetable oils, and the action of the roller oil component on the hair Attempts have been made to prevent the evaporation of water. However, these oils are oxidized and deteriorated with the passage of time, and the viscosity and hardness of the hair cosmetics are reduced accordingly, and there are problems in terms of usability and safety, and a sufficiently satisfactory product is obtained. I couldn't do it.
また、頭髪化粧料の種類によっては、密閉度の低い容器
に収納することがあり、必然的に水分が揮発するという
欠点があった。In addition, depending on the type of hair cosmetic composition, it may be stored in a container having a low degree of airtightness, and there is a drawback that water is inevitably volatilized.
以上のように、頭髪化粧料には水分を配合保持し、揮散
を極力おさえる等の重要な課題があり、これらの課題を
解決する上で調製の困難性や製品の安定性に問題があっ
た。As described above, hair cosmetics have important problems such as mixing and holding water and suppressing volatilization as much as possible, and there are problems in preparation difficulty and product stability in solving these problems. .
本発明の目的は、伸びが良く、保湿効果が良好で、閉塞
性の高い保水効果をもつ頭髪化粧料であって、酸化劣化
が少なく、粘度および硬度の経時変化が少なく、しかも
安全性等の点で問題のない頭髪化粧料を提供することに
ある。The object of the present invention is a hair cosmetic having good elongation, good moisturizing effect, and high water-retaining effect with high occlusive property, which is less susceptible to oxidative deterioration, has less change in viscosity and hardness over time, and is safe and the like. The point is to provide a hair cosmetic that does not have any problems.
前記の目的は、式 ＦC3F6OｎC2F5 （Ｉ） （式中、ｎは４〜500である） で表されるパーフルオロポリエーテル0.01〜95重量％を
含む頭髪化粧料によって達成することができる。The foregoing objects, (wherein, n is a 4 to 500) wherein FC 3 F 6 O n C 2 F 5 (I) by hair cosmetic comprising a perfluoropolyether 0.01 to 95 wt%, represented by Can be achieved.
本発明による頭髪化粧料は、パーフルオロポリエーテル
を配合することにより、毛髪に、つや、湿潤性および柔
軟性を与え、しかも頭髪化粧料のタイプによっては、著
しく水分の揮散を防止することができ、更に酸化劣化が
少なく、粘度および硬度の経時変化が少なく、安全性等
の点で問題のないものである。By incorporating perfluoropolyether, the hair cosmetic composition according to the present invention can impart gloss, wettability and flexibility to hair, and can significantly prevent evaporation of water depending on the type of hair cosmetic composition. Furthermore, there is little oxidative deterioration, there is little change in viscosity and hardness over time, and there is no problem in terms of safety and the like.
すなわち、本発明による頭髪化粧料は、不飽和油、エス
テル油、アルデヒド等の油分を配合した従来の頭髪化粧
料と比較して、著しく優れた保水効果および使用感を有
し、水分の揮散防止効果を有し、酸化劣化が少なく、粘
度および硬度の経時変化が少なく、しかも安全性等の点
で問題のない頭髪化粧料である。That is, the hair cosmetic composition according to the present invention has a remarkably excellent water-retaining effect and a feeling of use as compared with a conventional hair cosmetic composition containing an oil component such as an unsaturated oil, an ester oil or an aldehyde, and prevents evaporation of water. It is a cosmetic for hair that has effects, has little oxidative deterioration, has little change in viscosity and hardness over time, and has no problem in terms of safety and the like.
以下、本発明の構成について説明する。The configuration of the present invention will be described below.
本発明で使用するパーフルオロポリエーテルは式、 （式中、ｎは４〜500好ましくは４〜300である）で表さ
れる油状の化合物である。本発明の頭髪化粧料において
は、式（Ｉ）のパーフルオロポリエーテルを単独でまた
は任意に組合せて配合することができる。The perfluoropolyether used in the present invention has the formula: (In the formula, n is 4 to 500, preferably 4 to 300) and is an oily compound. In the hair cosmetic composition of the present invention, the perfluoropolyether of formula (I) may be blended alone or in any combination.
式（Ｉ）の化合物の分子量は約800（ｎ＝４の場合）〜
約83,000（ｎ＝500の場合）の範囲に亘るが、本発明に
おいては平均分子量約800〜約50000特には約1,000〜約1
0,000のパーフルオロポリエーテル混合物を使用するの
が好ましい。The molecular weight of the compound of formula (I) is about 800 (when n = 4)
In the present invention, the average molecular weight is about 800 to about 50,000, and particularly about 1,000 to about 1 although it ranges from about 83,000 (when n = 500).
Preference is given to using 0,000 perfluoropolyether mixtures.
式（Ｉ）のパーフルオロポリエーテルの調製は、例え
ば、2,2,3,3−テトラフルオロオキセタンを弗素イオン
触媒で開環重合してオリゴマーを生成し、このオリゴマ
ーを弗素ガスで直接に弗素化してパーフルオロ体に変換
した後、末端を安定することにより、パーフルオロトリ
メチレンオキサイドの繰返し単位を有するポリエーテル
を生成することによって実施することができる。The preparation of the perfluoropolyether of the formula (I) is carried out, for example, by ring-opening polymerization of 2,2,3,3-tetrafluorooxetane with a fluorine ion catalyst to form an oligomer, and the oligomer is directly converted into fluorine gas with fluorine gas. It can be carried out by forming a polyether having a repeating unit of perfluorotrimethylene oxide by stabilizing the terminal after conversion into a perfluoro form.
本発明においては市販のパーフルオロポリエーテルを使
用することができる。市販品としては、ダイキン工業製
のデムナムＳ−20,S−65,S−100およびＳ−200（各々、
商品名）の４種のオイルがある。デムナムＳ−20は重量
平均分子量2500および動粘度（20℃）42±5cstのエーテ
ル油であり、デムナムＳ−65は重量平均分子量4500およ
び動粘度（20℃）150±15cstのエーテル油であり、デム
ナムＳ−100は重量平均分子量5600および動粘度（20
℃）250±25cstのエーテル油であり、そしてデムナムＳ
−200は重量平均分子量8400および動粘度（20℃）500±
50cstのエーテル油である。In the present invention, commercially available perfluoropolyether can be used. As commercially available products, Daikin Industries' Demnum S-20, S-65, S-100 and S-200 (respectively,
There are four kinds of oil (commercial name). Demnum S-20 is an ether oil having a weight average molecular weight of 2500 and a kinematic viscosity (20 ° C) of 42 ± 5 cst, and Demnum S-65 is an ether oil having a weight average molecular weight of 4500 and a kinematic viscosity (20 ° C) of 150 ± 15 cst, Demnum S-100 has a weight average molecular weight of 5600 and a kinematic viscosity (20
℃) 250 ± 25 cst ether oil, and Demnum S
-200 is weight average molecular weight 8400 and kinematic viscosity (20 ℃) 500 ±
It is 50 cst ether oil.
更に上記のパーフルオロポリエーテルの低分子量体（パ
ーフルオロトリメチレンオキサイドの７〜８量体で、動
粘度（20℃）約10cst）を配合すると、さっぱりした使
用感をもつ頭髪化粧料を得ることができる。Furthermore, when a low molecular weight perfluoropolyether (a perfluorotrimethylene oxide 7 to 8 mer and a kinematic viscosity (20 ° C.) of about 10 cst) is blended, a hair cosmetic having a refreshing feeling of use can be obtained. You can
本発明の頭髪化粧料においては、式（Ｉ）のパーフルオ
ロポリエーテルを、頭髪化粧料全重量中の0.01〜95重量
％の量で配合するが、伸びの良い頭髪化粧料を得るため
には、0.5〜95重量％程度の量で配合するのが好まし
い。In the hair cosmetic composition of the present invention, the perfluoropolyether of the formula (I) is blended in an amount of 0.01 to 95% by weight based on the total weight of the hair cosmetic composition. , 0.5 to 95% by weight is preferable.
本発明の頭髪化粧料には、上記のパーフルオロポリエー
テルに加えて、必要により、頭髪化粧料の種類に応じ
て、油分、水、界面活性剤、保湿剤、低級アルコール、
増粘剤、香料、酸化防止剤、キレート剤、色素、防腐防
黴剤等の通常頭髪化粧料に用いられる成分を配合するこ
とができる。In addition to the above-mentioned perfluoropolyether, the hair cosmetic composition of the present invention may optionally contain oil, water, a surfactant, a moisturizing agent, a lower alcohol, depending on the type of hair cosmetic composition.
Ingredients usually used in hair cosmetics such as thickeners, fragrances, antioxidants, chelating agents, dyes, antiseptic and antifungal agents can be added.
本発明の頭髪化粧料の剤型としては、溶液系、可溶化
系、乳化系、粉末分散系、水−油二層系、水−油−粉末
三層系等の任意の剤型をとることができる。As the dosage form of the hair cosmetic composition of the present invention, any dosage form such as a solution system, a solubilization system, an emulsification system, a powder dispersion system, a water-oil two-layer system, and a water-oil-powder three-layer system can be adopted. You can
また、本発明の頭髪化粧料の具体例としてはヘアトニッ
ク、ヘアクリーム、シャンプー、ヘアリンスなどをあげ
ることができる。Specific examples of the hair cosmetic composition of the present invention include hair tonics, hair creams, shampoos, and hair rinses.
次に実施例および比較例をあげて、本発明を具体的に説
明する。本発明はこれにより限定されるものではない。
配合量は、特に断らない限り、重量％である。Next, the present invention will be specifically described with reference to Examples and Comparative Examples. The present invention is not limited to this.
The blending amount is% by weight unless otherwise specified.
また、以下の実施例で使用したパーフルオロポリエーテ
ルは次のとおりである。The perfluoropolyether used in the following examples is as follows.
（ｉ）パーフルオロポリエーテルA:重量平均分子量＝4,
500および動粘度（20℃）＝150±15cstのパーフルオロ
ポリエーテル油：デムナムＳ−65（ダイキン工業）。(I) Perfluoropolyether A: weight average molecular weight = 4,
Perfluoropolyether oil with 500 and kinematic viscosity (20 ° C) = 150 ± 15 cst: Demnum S-65 (Daikin Industries).
（ii）パーフルオロポリエーテルB:重量平均分子量＝8,
400および動粘度（20℃）＝500±50cstのパーフルオロ
ポリエーテル油：デムナムＳ−200（ダイキン工業）。(Ii) Perfluoropolyether B: weight average molecular weight = 8,
Perfluoropolyether oil with 400 and kinematic viscosity (20 ° C) = 500 ± 50 cst: Demnum S-200 (Daikin Industries).
（iii）パーフルオロポリエーテルC:重量平均分子量＝
5,600および動粘度（20℃）＝250±25cstのパーフルオ
ロポリエーテル油：デムナムＳ−100（ダイキン工
業）。(Iii) Perfluoropolyether C: weight average molecular weight =
5,600 and kinematic viscosity (20 ° C.) = 250 ± 25 cst perfluoropolyether oil: Demnum S-100 (Daikin Industries).
（iv）パーフルオロポリエーテルD:動粘度（20℃）＝約
10cstでＦC3F6O）７〜８C2F5のパーフルオロポリエ
ーテル油（ダイキン工業）。(Iv) Perfluoropolyether D: Kinematic viscosity (20 ° C) = approx.
FC 3 F 6 O) 7~8 perfluoropolyether oil of C 2 F 5 with 10 cst (Daikin Industries).
（ｖ）パーフルオロポリエーテルE:重量平均分子量＝2,
500および動粘度（20℃）＝42±5cstのパーフルオロポ
リエーテル油：デムナムＳ−20（ダイキン工業）。(V) Perfluoropolyether E: weight average molecular weight = 2,
Perfluoropolyether oil with 500 and kinematic viscosity (20 ° C) = 42 ± 5 cst: Demnum S-20 (Daikin Industries).
実施例1:ヘアリンス （重量％） （１）塩化アルキルトリメチル アンモニウム ３ （２）セチルアルコール ２ （３）パーフルオロポリエーテルＥ ２ （４）防腐剤 0.1 （５）グリセリン ５ （６）香料 0.3 （７）色素 適量 （８）トリオレイン酸ポリオキシエチレン ソルビタン （エチレンオキシド10モル付加） ２ （９）精製水 全体を100％にする量 成分（１）〜（９）を80℃にて混合溶解し、室温まで放
冷してヘアリンスを得た。Example 1: Hair rinse (% by weight) (1) Alkyltrimethylammonium chloride 3 (2) Cetyl alcohol 2 (3) Perfluoropolyether E 2 (4) Preservative 0.1 (5) Glycerin 5 (6) Perfume 0.3 (7) ) Dye Appropriate amount (8) Polyoxyethylene sorbitan trioleate (10 mol of ethylene oxide added) 2 (9) Purified water Amount to make the total 100% Components (1) to (9) are mixed and dissolved at 80 ° C. and room temperature It was left to cool to obtain hair rinse.
比較例１ 実施例１において成分（３）パーフルオロエーテルＥの
代りに流動パラフィンを配合したこと以外は実施例１と
同様にして、比較用のヘアリンスを得た。Comparative Example 1 A hair rinse for comparison was obtained in the same manner as in Example 1 except that liquid paraffin was blended in place of the component (3) perfluoroether E in Example 1.
実施例１および比較例１の各ヘアリンスについて20〜30
歳の女性パネル20名による実使用テストを行い、毛髪の
つやおよびくし通りについて評価した。20 to 30 for each hair rinse of Example 1 and Comparative Example 1
A 20-year-old female panel was used in a field test to assess hair gloss and combing.
その結果、実施例１のヘアリンスの方が良好とした者が
19名で、比較例１のヘアリンスの方が良好とした者が１
名であった。すなわち本発明によるヘアリンスの方が優
れていることが確認された。As a result, those who found that the hair rinse of Example 1 was better
19 out of 19 people found that the hair rinse of Comparative Example 1 was better.
It was a name. That is, it was confirmed that the hair rinse according to the present invention was superior.
実施例2:ヘアクリームオイル （重量％） （１）精製水 全体を100％にする量 （２）1,3−ブチレングリコール 10 （３）アロエ抽出液 ２ （４）パーフルオロポリエーテルＥ ６ （５）ステアリルアルコール ４ （６）トリオレイン酸ポリオキシエチ レンソルビタン （エチレンオキシド20モル付加） ２ （７）モノステアリン酸グリセライド 2.5 （８）パラオキシ安息香酸メチル 0.3 （９）ワセリン ２ （10）オリーブ油 ４ 成分（１）〜（３）を70℃で混合した。これに、成分
（４）〜（10）を70℃で混合溶解した部分を加えて乳化
し、冷却して目的のヘアクリームオイルを得た。Example 2: Hair cream oil (% by weight) (1) Purified water Amount that makes 100% of the whole (2) 1,3-butylene glycol 10 (3) Aloe extract 2 (4) Perfluoropolyether E 6 ( 5) Stearyl alcohol 4 (6) Polyoxyethylene sorbitan trioleate (addition of 20 mol of ethylene oxide) 2 (7) Glyceride monostearate 2.5 (8) Methyl paraoxybenzoate 0.3 (9) Vaseline 2 (10) Olive oil 4 Component (1) )-(3) were mixed at 70 ° C. A portion obtained by mixing and dissolving components (4) to (10) at 70 ° C. was added to this and emulsified, followed by cooling to obtain a target hair cream oil.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 東塚 崇志 大阪府三島郡島本町若山台１丁目５番９− 401 (56)参考文献 特開 昭61−234928（ＪＰ，Ａ) ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Takashi Higashizuka 1-5-9-Wakayamadai, Wakayamadai, Shimamoto-cho, Mishima-gun, Osaka (56) References JP-A-61-234928 (JP, A)
Claims (1)
含む頭髪化粧料。1. A formula FC 3 F 6 O n C 2 F 5 (I) ( wherein, n is a 4 to 500) hair cosmetic comprising a perfluoropolyether 0.01 to 95 wt%, represented by.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61253580A JPH0747530B2 (en) | 1986-10-27 | 1986-10-27 | Hair cosmetics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61253580A JPH0747530B2 (en) | 1986-10-27 | 1986-10-27 | Hair cosmetics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63107911A JPS63107911A (en) | 1988-05-12 |
| JPH0747530B2 true JPH0747530B2 (en) | 1995-05-24 |
Family
ID=17253350
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61253580A Expired - Lifetime JPH0747530B2 (en) | 1986-10-27 | 1986-10-27 | Hair cosmetics |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0747530B2 (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1227206B (en) * | 1988-09-23 | 1991-03-27 | Ausimont Spa | PROCEDURE FOR THE PREPARATION OF DETERGENT EMULSIONS FOR COSMETICS COSMETIC PRODUCTS OBTAINED. |
| CA2050212C (en) * | 1990-09-03 | 1997-09-30 | Andrew M. Murray | Hair treatment composition |
| GB9109693D0 (en) * | 1991-05-03 | 1991-06-26 | Unilever Plc | Hair treatment composition |
| GB9204509D0 (en) * | 1992-03-02 | 1992-04-15 | Unilever Plc | Hair care composition |
| JPH1029920A (en) * | 1996-07-12 | 1998-02-03 | Pola Chem Ind Inc | Protectant against irritation and composition for external use for skin comprising the same |
| JPH1030044A (en) * | 1996-07-15 | 1998-02-03 | Pola Chem Ind Inc | Emulsion composition containing perfluoro-polyether |
| JP4049414B2 (en) * | 1997-06-26 | 2008-02-20 | ポーラ化成工業株式会社 | Emulsified composition |
| JP4819377B2 (en) * | 2005-03-10 | 2011-11-24 | 中野製薬株式会社 | Three-component hair cosmetic and hair treatment method |
| JP5663753B2 (en) * | 2010-09-08 | 2015-02-04 | 株式会社サイエンスリン | Hair treatment composition |
| JPWO2020021798A1 (en) * | 2018-07-27 | 2021-04-01 | 株式会社Moresco | Hair protectant, hair treatment agent and hair treatment method |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1183530B (en) * | 1985-03-29 | 1987-10-22 | Monteluos S P A | COMPOSITIONS FOR COSMETICS INCLUDING PERFLUOROPOLYETERS |
-
1986
- 1986-10-27 JP JP61253580A patent/JPH0747530B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPS63107911A (en) | 1988-05-12 |
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