JPH07331185A - Two-pack acrylic reactive adhesive composition - Google Patents
Two-pack acrylic reactive adhesive compositionInfo
- Publication number
- JPH07331185A JPH07331185A JP14577394A JP14577394A JPH07331185A JP H07331185 A JPH07331185 A JP H07331185A JP 14577394 A JP14577394 A JP 14577394A JP 14577394 A JP14577394 A JP 14577394A JP H07331185 A JPH07331185 A JP H07331185A
- Authority
- JP
- Japan
- Prior art keywords
- agent
- weight
- parts
- pack
- acrylic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、二液性アクリル反応型
接着剤組成物に関するものである。FIELD OF THE INVENTION The present invention relates to a two-component acrylic reactive adhesive composition.
【０００２】[0002]
【従来の技術】二液性アクリル反応型接着剤の反応（硬
化）機構としては、有機過酸化物、例えば過安息香酸、
過酢酸などを分解してラジカルを発生させ、アクリルモ
ノマーを重合させて硬化させるのが一般的であるが、こ
の硬化を促進させるために様々の硬化促進剤が使用され
ている。一例を示せば、レドックス触媒系、アミンーア
ルデヒド縮合物系、Ｎ−Ｎ′ージメチルアニリンなどの
アニリン系、ナフテン酸コバルト等の金属石鹸、ジメチ
ルトルイジン等のトルイジン系、チオウレア等のウレア
系、メルカプトベンゾイミダゾール等のチオアミド系、
鉄ーポリアミン錯体系、フタロシアニン鉄等のフタロシ
アニン化合物などの促進剤があげられる。2. Description of the Related Art As a reaction (curing) mechanism of a two-component acrylic reactive adhesive, an organic peroxide such as perbenzoic acid,
It is general to decompose peracetic acid or the like to generate radicals and polymerize the acrylic monomer to cure it, and various curing accelerators are used to accelerate the curing. As an example, redox catalyst system, amine-aldehyde condensate system, aniline system such as NN′-dimethylaniline, metal soap such as cobalt naphthenate, toluidine system such as dimethyltoluidine, urea system such as thiourea, and mercapto. Thioamides such as benzimidazole,
Examples include accelerators such as iron-polyamine complex-based compounds and phthalocyanine compounds such as phthalocyanine iron.
【０００３】[0003]
【発明が解決しようとする課題】しかし、これらの従来
の硬化促進剤では、近年、要求が高まる硬化時間の短縮
化に対して未だ充分に満足することができないため、接
着剤の反応性を一層向上せしめて硬化時間の短縮化の努
力が要望されている。本発明は二液性アクリル反応型接
着剤の強度、貯蔵安定性等の各種性能を損なうことな
く、反応性を大幅に改善して硬化時間の短縮化を可能と
する二液性アクリル反応型接着剤組成物を提供すること
を目的とするものである。However, these conventional curing accelerators have not been able to sufficiently satisfy the shortening of the curing time, which has been recently required in recent years, so that the reactivity of the adhesive is further improved. Efforts to improve and shorten the curing time are desired. INDUSTRIAL APPLICABILITY The present invention is a two-component acrylic reaction type adhesive capable of significantly improving the reactivity and shortening the curing time without impairing various performances such as strength and storage stability of the two-component acrylic reaction type adhesive. It is intended to provide an agent composition.
【０００４】[0004]
【課題を解決するための手段】本発明の二液性アクリル
反応型接着剤組成物は、かかる目的を達成するものであ
って、Ａ剤 アクリルモノマー、メタクリルモノマーの１種以上 オリゴマー、重合体の１種以上 有機過酸化物 およびＢ剤 アクリルモノマー、メタクリルモノマーの１種以上 オリゴマー、重合体の１種以上 硬化促進剤 からなる二液性接着剤において、Ａ剤、Ｂ剤の少なくと
も一方に硬化促進助剤としてｔ−ブチルフェノール樹脂
２をＡ剤、Ｂ剤の総量に対して０．１〜１０重量％加え
たことを特徴とするものである。The two-component acrylic reaction type adhesive composition of the present invention achieves the above object, and is composed of one or more oligomers of A-component acrylic monomers and methacrylic monomers, and polymers. One or more kinds of organic peroxides and B agents One or more kinds of acrylic monomers and methacrylic monomers, one or more kinds of oligomers and polymers In a two-component adhesive consisting of a hardening accelerator, hardening acceleration is applied to at least one of agents A and B T-butylphenol resin 2 is added as an auxiliary agent in an amount of 0.1 to 10% by weight with respect to the total amount of agents A and B.
【０００５】以下、本発明の構成を具体的に説明する。
本発明の接着剤組成物は、ともにアクリルモノマー、メ
タクリルモノマーの１種以上とオリゴマー、重合体の１
種以上とを含有する二液（Ａ剤、Ｂ剤）からなるもので
あり、Ａ剤には、さらに有機過酸化物を含有しており、
Ｂ剤には硬化促進剤を含有していて、さらに、少なくと
も一方の液には硬化促進助剤を含有している。The structure of the present invention will be specifically described below.
The adhesive composition of the present invention contains at least one type of acrylic monomer or methacrylic monomer and one type of oligomer or polymer.
It is composed of two liquids (agent A and agent B) containing at least one species, and agent A further contains an organic peroxide,
The agent B contains a curing accelerator, and at least one of the solutions contains a curing accelerator.
【０００６】Ａ剤とＢ剤に含有させるアクリルモノマ
ー、メタクリルモノマーとしては、アクリル酸、メタク
リル酸、２ーヒドロキシエチルメタクリレート等のヒド
ロキシアルキルメタクリレート、エチレングリコールジ
メタクリレート等のモノ〜ポリエチレングリコールジメ
タクリレート、トリメチロールプロパントリアクリレー
ト、グリシジルメタクリレート、メチルメタクリレート
等のＣ1 〜Ｃ18のアルキルメタクリレート、アクリロニ
トリル・ブタジエン共重合体等のアクリル系共重合体等
をあげることができる。Acrylic monomers and methacrylic monomers contained in agents A and B include acrylic acid, methacrylic acid, hydroxyalkyl methacrylates such as 2-hydroxyethyl methacrylate, mono-polyethylene glycol dimethacrylates such as ethylene glycol dimethacrylate, and trimethacrylate. Examples thereof include C 1 to C 18 alkyl methacrylates such as methylolpropane triacrylate, glycidyl methacrylate and methyl methacrylate, and acrylic copolymers such as acrylonitrile-butadiene copolymer.
【０００７】また、Ａ剤とＢ剤に含有させるオリゴマー
としては、ウレタンアクリレート、エポキシアクリレー
ト、ポリエステルアクリレート等があげられる。重合体
としては、ポリメタクリル酸エステル、ポリアクリル酸
エステル、ポリスチレン、ＡＢＳ樹脂、ポリビニルクロ
リド、各種合成ゴム、ポリエステル樹脂等または共重合
体があげられる。Examples of the oligomers contained in the agents A and B include urethane acrylate, epoxy acrylate, polyester acrylate and the like. Examples of the polymer include polymethacrylic acid ester, polyacrylic acid ester, polystyrene, ABS resin, polyvinyl chloride, various synthetic rubbers, polyester resin and the like, or copolymers.
【０００８】Ａ剤に含有させる過酸化物は重合開始剤で
あり、該物質としては過酸化ベンゾイル、メチルエチル
ケトンパーオキサイド、シクロヘキサノンパーオキサイ
ド、クメンハイドロパーオキサイド、ｔーブチルハイド
ロパーオキサイド、ジーｔーブチルハイドロパーオキサ
イド、ジクミルパーオキサイド、テトラメチルハイドロ
パーオキサイドなどがあげられる。The peroxide contained in the agent A is a polymerization initiator, and examples of the substance include benzoyl peroxide, methyl ethyl ketone peroxide, cyclohexanone peroxide, cumene hydroperoxide, t-butyl hydroperoxide and di-t-butyl. Examples thereof include hydroperoxide, dicumyl peroxide, tetramethyl hydroperoxide and the like.
【０００９】Ｂ剤に含有させる硬化促進剤は、重合・硬
化を促進するものであって、レドックス触媒系、金属石
鹸、鉄フタロシアニン等のフタロシアニン化合物、鉄ー
ポリアミン錯体等があげられ、特にフタロシアニン化合
物が好適である。The curing accelerator contained in the agent B accelerates polymerization and curing, and includes redox catalyst systems, metal soaps, phthalocyanine compounds such as iron phthalocyanine, iron-polyamine complexes, and the like. It is suitable.
【００１０】Ａ剤とＢ剤の少なくとも一方に含有させる
ｔーブチルフェノール樹脂は前述の硬化促進剤と併用す
ることにより重合・硬化をさらに促進するものである。
この硬化促進助剤は、全接着剤に対する配合比率で０．
１〜１０重量％、好ましくは０．５〜５重量％であっ
て、０．１重量％未満の場合には促進硬化はほとんど認
められず、１０重量％を超える場合には硬化時間は早く
ならないばかりでなく、引っ張りせん断強度が低くな
る。The t-butylphenol resin contained in at least one of the agent A and the agent B is used in combination with the aforementioned curing accelerator to further accelerate the polymerization and curing.
This curing accelerating aid has a compounding ratio of 0.
1 to 10% by weight, preferably 0.5 to 5% by weight. When the amount is less than 0.1% by weight, accelerated curing is hardly observed, and when the amount exceeds 10% by weight, the curing time is not shortened. Not only that, but the tensile shear strength is low.
【００１１】なお、本発明の接着剤には、必要に応じて
他の添加剤も添加することも可能である。本発明のＡ剤
とＢ剤は、二液を混合してから接着個所に塗布して使用
してもよいが、必ずしもこれに限らず、接着個所にそれ
ぞれ塗布した後、接合しても良好な接着が可能である。If desired, other additives can be added to the adhesive of the present invention. The agents A and B of the present invention may be used by mixing the two liquids and then applying them to the adhering points, but the invention is not limited to this, and they may be applied to the adhering points and then joined together. Can be bonded.
【００１２】[0012]
【作用】本発明の二液性アクリル反応型接着剤組成物
は、ともにアクリルモノマー、メタクリルモノマーの１
種以上とオリゴマー、重合体の１種以上とを含有する二
液（Ａ剤、Ｂ剤）からなるものであり、Ａ剤には、さら
に有機過酸化物を含有しており、Ｂ剤には硬化促進剤を
含有しているので、接着強度が大きく、酸を使用しなく
ても硬化するため、金属に対しての腐食がなく、貯蔵安
定性が良く、常温で貯蔵できるなどの利点を有するほ
か、さらに、Ａ剤、Ｂ剤の少なくとも一方の液には硬化
促進助剤としてｔ−ブチルフェノール樹脂０．１〜１０
重量％を含有しているので、反応性が大幅に改善され、
硬化・重合時間が大幅に短縮されることとなる。The two-component acrylic reactive adhesive composition of the present invention is composed of an acrylic monomer and a methacrylic monomer.
It is composed of two liquids (agent A and agent B) containing one or more species and one or more oligomers and polymers. The agent A further contains an organic peroxide, and the agent B is Since it contains a curing accelerator, it has high adhesive strength and cures without the use of acid, so it has the advantages that it does not corrode metals, has good storage stability, and can be stored at room temperature. In addition, a t-butylphenol resin of 0.1 to 10 is used as a curing accelerator in at least one of the liquids A and B.
Since it contains wt%, the reactivity is greatly improved,
The curing / polymerization time will be greatly shortened.
【００１３】[0013]
【実施例】次に、本発明を実施例によってさらに詳細に
説明する。EXAMPLES Next, the present invention will be described in more detail by way of examples.
【００１４】実施例１ メチルメタクリレート２００重量部、２ーヒドロキシエ
チルメタクリレート６００重量部、ｔーブチルフェノー
ル樹脂１０重量部、アクリロニトリル・ブタジエン共重
合体１５０重量部、クメンハイドロパーオキサイド５０
重量部の配合組成を攪拌機付き溶解缶で均一溶液となる
まで攪拌混合してＡ剤を作成し、メチルメタクリレート
２４０重量部、２ーヒドロキシエチルメタクリレート６
００重量部、アクリロニトリル・ブタジエン共重合体１
５０重量部、鉄フタロシアニン１０重量部の配合組成に
よりＡ剤と同様にしてＢ剤を作成した。得られたＡ剤と
Ｂ剤とを用いて接着試験を行った。接着試験としては、
硬化時間および引っ張りせん断強度を下記の方法によっ
て測定した。Example 1 200 parts by weight of methyl methacrylate, 600 parts by weight of 2-hydroxyethyl methacrylate, 10 parts by weight of t-butylphenol resin, 150 parts by weight of acrylonitrile-butadiene copolymer, 50 parts of cumene hydroperoxide.
Part A is prepared by stirring and mixing parts by weight of the blended composition in a dissolution can equipped with a stirrer until a uniform solution is obtained, and 240 parts by weight of methyl methacrylate and 2-hydroxyethyl methacrylate 6 are added.
00 parts by weight, acrylonitrile-butadiene copolymer 1
Agent B was prepared in the same manner as agent A with a compounding composition of 50 parts by weight and 10 parts by weight of iron phthalocyanine. An adhesion test was performed using the obtained agents A and B. As an adhesion test,
Curing time and tensile shear strength were measured by the following methods.
【００１５】接着試験 (1) 硬化時間 表面をトリクロルエチレンで脱脂した厚さ1.6 mm、幅25
mm、長さ100 mmの冷間圧延鋼板を用意した。この鋼板に
前記Ａ液およびＢ液を等量ずつそれぞれ別々に塗布し、
次いでこれらを接合し（接合長さ25mm) 、接合部が手で
引き剥がせなくなるまでの時間を測定し、硬化時間とし
た。 (2) 引っ張りせん断強度 前記と同様の鋼板を同様に接合し（接合長さ12.5mm）、
室温で3 日放置した後、テンシロン引っ張り試験機（オ
リエンテック社製) を用いて引っ張り速度5 mm/minで引
っ張りせん断強度を測定した。得られた結果は表１に示
したように、引っ張り強度が優れているとともに、硬化
時間が非常に短いものであった。Adhesion test (1) Curing time The surface was degreased with trichlorethylene, thickness 1.6 mm, width 25
A cold rolled steel plate having a length of 100 mm and a length of 100 mm was prepared. Liquid A and liquid B are separately applied to this steel plate in equal amounts, respectively,
Then, these were bonded (bonding length 25 mm), and the time until the bonded portion could not be peeled off by hand was measured and set as the curing time. (2) Tensile shear strength Steel sheets similar to the above were joined in the same manner (joint length 12.5 mm),
After standing at room temperature for 3 days, the tensile shear strength was measured at a tensile speed of 5 mm / min using a Tensilon tensile tester (manufactured by Orientec Co., Ltd.). The results obtained were, as shown in Table 1, excellent tensile strength and a very short curing time.
【００１６】[0016]
【表１】 [Table 1]
【００１７】比較例１ ｔーブチルフェノール樹脂を用いない以外は実施例１と
同様のＡ剤と、実施例１と同様のＢ剤を作成した。得ら
れたＡ剤とＢ剤とを用いて接着試験を行った結果は表１
に示したように、引っ張り強度は優れているが、硬化時
間が著しく長いものであった。Comparative Example 1 Agent A similar to Example 1 and agent B similar to Example 1 were prepared except that t-butylphenol resin was not used. The results of the adhesion test using the obtained agents A and B are shown in Table 1.
As shown in, the tensile strength was excellent, but the curing time was extremely long.
【００１８】実施例２ メチルメタクリレート２００重量部、２ーヒドロキシエ
チルメタクリレート６００重量部、ｔーブチルフェノー
ル樹脂３重量部、アクリロニトリル・ブタジエン共重合
体１５０重量部、クメンハイドロパーオキサイド６０重
量部の配合組成によりＡ剤を作成し、メチルメタクリレ
ート２４０重量部、２ーヒドロキシエチルメタクリレー
ト６００重量部、アクリロニトリル・ブタジエン共重合
体１５０重量部、鉄フタロシアニン１０重量部の配合組
成によりＢ剤を作成した。得られたＡ剤とＢ剤とを用い
て接着試験を行った結果は表１に示したように、引っ張
り強度が優れているとともに、硬化時間が非常に短いも
のであった。Example 2 200 parts by weight of methyl methacrylate, 600 parts by weight of 2-hydroxyethyl methacrylate, 3 parts by weight of t-butylphenol resin, 150 parts by weight of acrylonitrile / butadiene copolymer, and 60 parts by weight of cumene hydroperoxide were used. The agent A was prepared, and the agent B was prepared by the compounding composition of 240 parts by weight of methyl methacrylate, 600 parts by weight of 2-hydroxyethyl methacrylate, 150 parts by weight of acrylonitrile / butadiene copolymer, and 10 parts by weight of iron phthalocyanine. As shown in Table 1, the results of the adhesion test using the obtained agents A and B were that the tensile strength was excellent and the curing time was very short.
【００１９】実施例３ ｔーブチルフェノール樹脂３重量部を１０重量部とする
以外は実施例２と同様のＡ剤と、実施例２と同様のＢ剤
を作成した。得られたＡ剤とＢ剤とを用いて接着試験を
行った結果は表１に示したように、引っ張り強度が優れ
ているとともに、硬化時間が非常に短いものであった。Example 3 Agent A similar to Example 2 and agent B similar to Example 2 were prepared except that 3 parts by weight of t-butylphenol resin was changed to 10 parts by weight. As shown in Table 1, the results of the adhesion test using the obtained agents A and B were that the tensile strength was excellent and the curing time was very short.
【００２０】実施例４ ｔーブチルフェノール樹脂３重量部を１００重量部とす
る以外は実施例２と同様のＡ剤と、実施例２と同様のＢ
剤を作成した。得られたＡ剤とＢ剤とを用いて接着試験
を行った結果は表１に示したように、引っ張り強度が優
れているとともに、硬化時間が非常に短いものであっ
た。Example 4 Agent A as in Example 2 and B as in Example 2 except that 3 parts by weight of t-butylphenol resin was 100 parts by weight.
The agent was created. As shown in Table 1, the results of the adhesion test using the obtained agents A and B were that the tensile strength was excellent and the curing time was very short.
【００２１】実施例５ ｔーブチルフェノール樹脂３重量部を２００重量部とす
る以外は実施例２と同様のＡ剤と、実施例２と同様のＢ
剤を作成した。得られたＡ剤とＢ剤とを用いて接着試験
を行った結果は表１に示したように、引っ張り強度が優
れているとともに、硬化時間が非常に短いものであっ
た。Example 5 Agent A as in Example 2 and B as in Example 2 except that 200 parts by weight of 3 parts by weight of t-butylphenol resin was used.
The agent was created. As shown in Table 1, the results of the adhesion test using the obtained agents A and B were that the tensile strength was excellent and the curing time was very short.
【００２２】比較例２ ｔーブチルフェノール樹脂３重量部を０．１重量部とす
る以外は実施例２と同様のＡ剤と、実施例２と同様のＢ
剤を作成した。得られたＡ剤とＢ剤とを用いて接着試験
を行った結果は表１に示したように、引っ張り強度は優
れているが、硬化時間が著しく長いものであった。Comparative Example 2 Agent A similar to Example 2 and B similar to Example 2 except that 3 parts by weight of t-butylphenol resin was changed to 0.1 parts by weight.
The agent was created. As shown in Table 1, the results of the adhesion test using the obtained agents A and B showed that the tensile strength was excellent, but the curing time was extremely long.
【００２３】比較例３ ｔーブチルフェノール樹脂３重量部を３００重量部とす
る以外は実施例２と同様のＡ剤と、実施例２と同様のＢ
剤を作成した。得られたＡ剤とＢ剤とを用いて接着試験
を行った結果は表１に示したように、引っ張り強度が劣
るものであった。Comparative Example 3 A agent similar to Example 2 and B similar to Example 2 except that 3 parts by weight of t-butylphenol resin was changed to 300 parts by weight.
The agent was created. As shown in Table 1, the results of an adhesion test using the obtained agents A and B were inferior in tensile strength.
【００２４】[0024]
【発明の効果】以上の説明から明らかなように、本発明
によれば、引っ張り強度等の接着剤としての性能を損な
うことなく、硬化時間の大幅な短縮を可能にするもので
ある。また、二液の混合を必要とせず、酸を使わなくて
も硬化するので、金属に対する腐食も無く、貯蔵安定性
が良く、毒性が無く、価格も安価であるという経済性、
作業性その他にも大きな利点を有するものである。As is clear from the above description, according to the present invention, the curing time can be greatly shortened without impairing the performance as an adhesive such as the tensile strength. In addition, since it does not require the mixing of two liquids and cures without the use of acid, there is no corrosion to metals, storage stability is good, there is no toxicity, and the cost is low.
It has great advantages in workability and the like.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 布上 秀二 神奈川県愛甲郡愛川町中津4085 ダイアボ ンド工業株式会社厚木工場内 (72)発明者 佐佐木 新吾 神奈川県愛甲郡愛川町中津4085 ダイアボ ンド工業株式会社厚木工場内 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Shuji Nunoue 4085 Nakatsu, Aikawa-cho, Aiko-gun, Kanagawa Daibon Industry Co., Ltd. Atsugi Plant (72) Inventor Shingo Sasaki 4085, Nakatsu, Aikawa-cho, Kanagawa Prefecture Diamond Bond Industry Atsugi Factory Co., Ltd.
Claims (1)
なくとも一方に硬化促進助剤としてｔ−ブチルフェノー
ル樹脂をＡ剤、Ｂ剤の総量に対して０．１〜１０重量％
加えたことを特徴とする二液性アクリル反応型接着剤組
成物。1. An agent A, one or more kinds of acrylic monomers and methacrylic monomers, one or more kinds of oligomers and polymers, organic peroxide and an agent B, one or more kinds of acrylic monomers and methacrylic monomers, and one or more kinds of oligomers and polymers. In a two-component reactive adhesive composed of an agent, a t-butylphenol resin as a curing accelerator in at least one of the agents A and B is used in an amount of 0.1 to 10% by weight based on the total amount of the agents A and B.
A two-component acrylic reactive adhesive composition characterized by being added.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14577394A JPH07331185A (en) | 1994-06-06 | 1994-06-06 | Two-pack acrylic reactive adhesive composition |
| TW83109037A TW259811B (en) | 1994-06-06 | 1994-09-30 | Two-liquid acrylic reactive type adhesive composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14577394A JPH07331185A (en) | 1994-06-06 | 1994-06-06 | Two-pack acrylic reactive adhesive composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH07331185A true JPH07331185A (en) | 1995-12-19 |
Family
ID=15392838
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14577394A Pending JPH07331185A (en) | 1994-06-06 | 1994-06-06 | Two-pack acrylic reactive adhesive composition |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JPH07331185A (en) |
| TW (1) | TW259811B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005010095A1 (en) * | 2003-07-29 | 2005-02-03 | Mitsubishi Rayon Co., Ltd. | Two-pack type acrylic sol composition |
| JP2007169352A (en) * | 2005-12-20 | 2007-07-05 | Denki Kagaku Kogyo Kk | Adhesive composition, adhesive, bonding method and furniture |
| JP5427026B2 (en) * | 2007-03-02 | 2014-02-26 | 電気化学工業株式会社 | Bonding method and joined body |
| DE102013222278A1 (en) * | 2013-11-01 | 2015-05-07 | Tesa Se | Reactive 2-component adhesive system |
-
1994
- 1994-06-06 JP JP14577394A patent/JPH07331185A/en active Pending
- 1994-09-30 TW TW83109037A patent/TW259811B/en active
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005010095A1 (en) * | 2003-07-29 | 2005-02-03 | Mitsubishi Rayon Co., Ltd. | Two-pack type acrylic sol composition |
| JP4951239B2 (en) * | 2003-07-29 | 2012-06-13 | 三菱レイヨン株式会社 | Two-component plastisol composition and method of use thereof |
| JP2007169352A (en) * | 2005-12-20 | 2007-07-05 | Denki Kagaku Kogyo Kk | Adhesive composition, adhesive, bonding method and furniture |
| JP4627258B2 (en) * | 2005-12-20 | 2011-02-09 | 電気化学工業株式会社 | Adhesive composition, adhesive, adhesion method and furniture |
| JP5427026B2 (en) * | 2007-03-02 | 2014-02-26 | 電気化学工業株式会社 | Bonding method and joined body |
| DE102013222278A1 (en) * | 2013-11-01 | 2015-05-07 | Tesa Se | Reactive 2-component adhesive system |
| JP2016539218A (en) * | 2013-11-01 | 2016-12-15 | テーザ・ソシエタス・ヨーロピア | Two-component reactive adhesive system |
Also Published As
| Publication number | Publication date |
|---|---|
| TW259811B (en) | 1995-10-11 |
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