JPH07291703A - Backfillgrouting material - Google Patents

Abstract

PURPOSE:To obtain a backfillgrouting material for freezing by using a liquid (A) having a specified amt. of clay mineral, a specified mixing ratio of cement and fly ash, and specified density of a curing agent powder and a liquid (B) containing a specified amt. of sodium silicate to produce the backfill grouting material. CONSTITUTION:A cement slurry liquid (A) is prepared by mixing cement such as a high-early-strength Portland cement and fly ash or fly ash partly substituted with slag by 2/8 to 7/3wt. ratio, and further mixing clay mineral such as bentonite by 20-150kg per 1m<3> of the grouting material and a proper amt. of water so as to obtain 35-70wt.% density of a curing agent powder based on the grouting material. Then a liquid (B) comprising sodium silicate soln. is mixed to the liquid (A) in such a manner that the amt.of whole sodium silicate to the cement of the liquid (A) becomes 5-80wt.%. The obtd. backfillgrouting material is grouted into the ground. Even when the backfillgrouting material is grouted in an atmosphere of <=0 deg.C, it causes no freeze collapse but smoothly develops high strength after the temp. reaches normal temp.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a backfill injection material used when excavating a tunnel or the like by a shield method,
Particularly, it relates to a backfill injection material for the freezing method.

[0002]

2. Description of the Related Art In various tunnel constructions using the shield construction method, a backfill material must be injected in order to fill the gap between the excavated ground and the outer diameter of the lining. Conventionally, bean gravel, concrete, cement mortar, cement air mortar, cement milk, etc. have been used as this backfill material, but recently, for reasons such as improving the initial strength, cement slurry liquid and sodium silicate have recently been used. A two-liquid mixed type backfill material in which a solution is mixed and backfilled immediately before injection is often used.

On the other hand, in recent tunnel excavation work using the shield construction method, there are many cases where excavation is performed in soft ground. In such cases, the soil is often solidified by the chemical injection method, but it is necessary for the chemical injection method to have a gap in the ground. Therefore, chemical solution injection work is impossible. Therefore, the freezing method is becoming popular, in which the entire ground is frozen to strengthen the ground and then excavation work for the tunnel is performed.

This freezing method freezes the water contained in the soft soil with water retention to solidify the soil,
It is a construction method in which the work is performed after preventing the spring water, and after the work is completed, the freezing is released and the original ground is restored.

As a freezing method, conventionally, a method of driving a freezing pipe into the ground and circulating a freezing liquid such as ammonia or freon in the freezing pipe has been used, but recently, liquid nitrogen is directly poured into the freezing pipe. A method and a method of pouring liquid nitrogen directly into the ground to freeze the ground by the latent heat of vaporization have also been developed.

[0006]

However, in the tunnel excavation work by various freezing methods, when the conventional backfill material is injected at a temperature of 0 ° C. or lower, the injected backfill material freezes, so that strength develops after melting. There is a problem of freezing and disintegrating.

Therefore, the temperature of the ground after the freeze is released is 0 due to natural temperature rise or forced heating (electrical heating) of the segment.
The backfilling injection work had to be stopped until it reached above ℃.

As described above, in the conventional backfill material, not only the injection work is significantly restricted, but also the ground subsidence occurs due to the loosening and collapse of the ground until the backfill injection is performed at a temperature of 0 ° C. or higher. However, it was difficult to function as the original backfill material.

Therefore, it is an object of the present invention to provide a novel backfilling material which can be backfilled by a conventional method even in an atmosphere where the temperature of the ground or segment after freezing is 0 ° C. or lower. is there.

[0010]

Under these circumstances, the inventors of the present invention have conducted extensive studies and as a result, as a result, a cement slurry liquid (hereinafter referred to as "A") containing a hardening material having a specific composition.
Liquid) and an aqueous solution containing a specific amount of sodium silicate (hereinafter referred to as “B liquid”), a two-liquid mixed backfill injection material causes freezing disintegration even when injected in an atmosphere of 0 ° C. or lower. However, the present invention has been completed, and the present invention was completed, and it was found that the strength is satisfactorily expressed after reaching the normal temperature and the function as a backfill material can be sufficiently fulfilled.

That is, the present invention is a backfill injection material comprising liquid A prepared by kneading cement, fly ash, clay mineral and water, and liquid B which is an aqueous solution of sodium silicate,
Clay minerals content in the liquid A to injecting material 1 m ³ twenty to fifteen
0 kg, the weight mixing ratio of cement and fly ash is cement: fly ash = 2: 8-7: 3, the concentration of the hardener powder is 35-70 wt% with respect to the injected material, and the content of sodium silicate in solution B is The backfill injection material is characterized in that it is 5 to 80% by weight based on cement.

The term "hardening material" as used herein means cement,
It refers to fly ash and clay minerals, and part of the fly ash can be replaced with slag. Examples of cement include various Portland cements such as ordinary Portland cement and early strength Portland cement.
Early strength Portland cement is particularly preferred.

Examples of the clay mineral to be mixed in the liquid A include bentonite and acid clay, and bentonite is particularly preferable. The content of clay minerals for injecting material 1 m ³
It is necessary to be 20 to 150 kg, preferably 40 to 80 kg. If the content is less than 20 kg, the material separation of the injected material becomes significantly large, causing freeze-disintegration, and if it exceeds 150 kg, the fluidity of the liquid A decreases, which is not preferable.

Next, the weight mixing ratio of cement and fly ash in the hardener mixed in the liquid A must be cement: fly ash = 2: 8 to 7: 3, but 3: 7 to 5: 5 is preferable. If the cement content is less than 20% by weight, the gelation rate will be significantly slowed down, and 70% by weight
If it exceeds, the fluidity and the pot life characteristics deteriorate, so both are not preferable.

Further, the concentration of the hardener powder blended in the liquid A must be 35 to 70% by weight, preferably 40 to 55% by weight, based on the injected material. If the concentration of the hardener powder is less than 35% by weight, freeze-disintegration occurs, and if it exceeds 70% by weight, the concentration of the solid powder becomes too high and the fluidity decreases, which is not preferable.

Further, the concentration of sodium silicate in the liquid B must be 5 to 80% by weight, preferably 10 to 60% by weight, based on the cement of the liquid A. If the concentration of sodium silicate is less than 5% by weight, gelation does not occur, and if it exceeds 80% by weight, freezing and expansion occur.

In addition to the above-mentioned essential components, the backfill injection material of the present invention contains various addition aids such as gluconic acid-based auxiliaries and antifreeze agents, depending on the purpose, as long as the effects of the present invention are not impaired. Can be mixed.

[0018]

The backfill injection material of the present invention shows good strength without freezing and disintegration when it is cooled to 0 ° C. or below and frozen at the time of injection, but is then heated to room temperature.

Here, the reason why the injection material of the present invention does not freeze and disintegrate, which is found from various experimental results, will be described.

The injection material of the present invention is prepared by mixing the slurry liquid (liquid A) of the cement-based hardening agent and the sodium silicate solution (liquid B) immediately before the injection and mixing. A gelation reaction occurs immediately after injection, and fine silica gel is uniformly dispersed in the injection material. The injectable material of the present invention, which has completed the gelation reaction, is frozen and then expanded in volume when cooled to 0 ° C or lower. When the frozen injectable material of the present invention is released from freezing, the volume contracts and almost restores the original volume. Then, the cement-based hardening material causes a hydration reaction without causing freeze-disintegration, and the strength of the injection material increases.

Therefore, the present inventors consider that the injectable material of the present invention does not freeze-disintegrate because it uniformly contracts in volume upon thawing after freezing. The reason why the volume shrinks uniformly is considered as follows.

The injection material of the present invention generates fine silica gel after injection, and the silica gel is uniformly distributed in the injection material. Therefore, the hardener powder, the water content, and the excess aqueous solution of sodium silicate that did not contribute to the gelation reaction are contained in fine silica gel when viewed microscopically. When the injection material freezes, the water content and the sodium silicate aqueous solution contained in the silica gel freeze and the volume expands. When it is thawed after freezing, the ice contained in the silica gel is thawed and its volume is also contracted. At this time, the silica gel also moves to the position before freezing according to the volume variation of the water content and the sodium silicate aqueous solution. Due to this phenomenon, it is considered that the present injection material does not change structurally and componentally before and after freezing, and thus it is possible to prevent freezing disintegration.

On the contrary, it is considered that freeze disintegration occurs when there is not enough silica gel to move with the expansion and contraction of water or the like. Therefore, in the formulation of the backfill injection material, what is important in order to prevent freezing disintegration is

1) When the amount of the clay mineral in the injected material is too small, the material separation is extremely high, the silica gel generated by the gelation reaction is not uniformly dispersed, and freezing disintegration occurs. That is, in order to prevent freezing disintegration, it is preferable to add more clay mineral. However, if it is too large, the fluidity is lowered, which is not preferable.

2) When the concentration of the hardener powder in the injected material is lowered, the amount of water increases and the amount of expansion increases, while the amount of silica gel generated in the gelation reaction decreases. Therefore, due to lack of sufficient amount of silica gel, freeze-thaw occurs. That is, in order to prevent freezing disintegration, it is preferable that the concentration of the hardener powder in the injected material is higher. However, if it is too high, the fluidity is lowered, which is not preferable.

3) When the concentration of sodium silicate in the injected material is increased, the amount of extra sodium silicate aqueous solution that did not contribute to the gelation reaction increases, so that the amount of expansion becomes larger and freeze collapse occurs. That is, the concentration of sodium silicate in the injected material is preferably lower in order to prevent freezing disintegration. However, if it is too low, gelation does not occur.

The mixing ratio of cement and fly ash in the hardened material is such that if the cement content is too small, the gelation time will be significantly delayed. It is not preferable because the working time characteristics deteriorate.

[0028]

The present invention will be described in more detail with reference to examples, but the present invention is not limited thereto.

A two-liquid mixed type backfill material injection material shown in Table 1 was prepared, and the liquids A and B were mixed to have a diameter of 5 cm and a height of 10 cm.
The specimen was molded and then left in a freezer at -10 ° C for 48 hours to freeze the specimen. Then, the frozen specimens were taken out from the freezer and cured in water at 20 ° C. for 7 days, and the uniaxial compressive strength of each cured specimen was measured. Further, the mortar flow value of the injection material shown in Table 1 for the solution A and the gelation time of the mixed solution of the solutions A and B were measured. The measurement results are shown in Table 2.

[0030]

[Table 1]

[0031]

[Table 2]

* 1: S: cement F: fly ash * 2: Fly ash includes slag.

According to the results of Test Nos. 1, 2 and 3, favorable results were obtained under the condition of Test No. 1 in which the amount of bentonite used in 1 m ^{3 of} the injected material was 78 kg. But,
The specimen under the condition of Test No. 2 where the amount of bentonite used was 10 kg had several cracks and the amount of bentonite used was
The specimen under the condition of the test number 3 of 200 kg had a high viscosity and it was difficult to mix the liquid A and the liquid B.

According to the results of Test Nos. 4, 5 and 6, the weight mixing ratio of the hardeners was cement: fly ash = 5 :.
Under the condition of Test No. 5, which is 5, good results are obtained. However, gelation did not occur under the condition of Test No. 4 in which cement: fly ash = 1: 9. Further, under the condition of Test No. 6 where Cement: Fly ash = 8: 2, the viscosity was high, so the experiment was stopped.

According to the results of Test Nos. 7, 8 and 9, good results were obtained under the condition of Test No. 8 in which the hardener powder concentration was 52.9% by weight. However, the test piece under the condition of the test number 7 in which the hardening material powder concentration is 32.8% by weight has almost no strength and has many cracks on the surface, and the hardening material powder concentration is 74.4% by weight in the test number 9 Since the viscosity was high under the condition of, the experiment was stopped.

According to the results of Test Nos. 10, 11 and 12, the amount of sodium silicate in the injected material was 50.5% by weight based on the cement.
Good results were obtained under the condition of test number 11, which is However, under the condition of test number 10 which is 2.6% by weight,
The specimen that did not gel and was 83.9% by weight under the condition of Test No. 12 had some strength, but had several large cracks on its surface.

Test No. 13 is an example in which ordinary Portland cement is used, Test No. 14 is an example in which the fly ash of the hardening material is partially replaced by slag, and Test No. 15 is an example in which it is combined with a commercially available antifreezing agent. However, good results were obtained in all cases.

[0038]

INDUSTRIAL APPLICABILITY The backfilling injection material of the present invention is backfilled by a conventional method in a tunnel excavation work by a freezing method in an atmosphere where the temperature of the ground or segment after freezing is 0 ° C. or lower. However, it does not freeze and disintegrate, and after reaching normal temperature, it develops strength satisfactorily and can sufficiently fulfill the function as a backfill material.

─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. ⁶ Identification number Office reference number FI technical display location C04B 18:14 Z 24:06) Z (72) Inventor Satoru Matsui 2-chome Daisaku, Sakura City, Chiba Prefecture No. 2 Stock Company Onoda Development Laboratory

Claims (3)

[Claims] 1. A liquid A prepared by kneading cement, fly ash, clay minerals and water, and B which is an aqueous sodium silicate solution.
A back-filling injection material consisting of liquid, in which the content of clay mineral in liquid A is 20 to 150 kg per 1 m ^{3 of} injection material, and the weight mixing ratio of cement and fly ash is cement: fly ash = 2: 8 to 7: 3. A backfill injection material, characterized in that the hardener powder concentration is 35 to 70% by weight with respect to the injection material, and the content of sodium silicate in solution B is 5 to 80% by weight with respect to the cement. 2. The backfill injection material according to claim 1, wherein fly ash, which is a hardening material, is partially replaced by slag. 3. The backfill injection material according to claim 1, which is for a freezing method.