JPH07285527A - Heat resistant and pressure resistant self-standing container - Google Patents
Heat resistant and pressure resistant self-standing containerInfo
- Publication number
- JPH07285527A JPH07285527A JP22497194A JP22497194A JPH07285527A JP H07285527 A JPH07285527 A JP H07285527A JP 22497194 A JP22497194 A JP 22497194A JP 22497194 A JP22497194 A JP 22497194A JP H07285527 A JPH07285527 A JP H07285527A
- Authority
- JP
- Japan
- Prior art keywords
- container
- heat
- self
- crystallized
- mouth
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D1/00—Containers having bodies formed in one piece, e.g. by casting metallic material, by moulding plastics, by blowing vitreous material, by throwing ceramic material, by moulding pulped fibrous material, by deep-drawing operations performed on sheet material
- B65D1/02—Bottles or similar containers with necks or like restricted apertures, designed for pouring contents
- B65D1/0223—Bottles or similar containers with necks or like restricted apertures, designed for pouring contents characterised by shape
- B65D1/0261—Bottom construction
- B65D1/0284—Bottom construction having a discontinuous contact surface, e.g. discrete feet
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D1/00—Containers having bodies formed in one piece, e.g. by casting metallic material, by moulding plastics, by blowing vitreous material, by throwing ceramic material, by moulding pulped fibrous material, by deep-drawing operations performed on sheet material
- B65D1/02—Bottles or similar containers with necks or like restricted apertures, designed for pouring contents
- B65D1/0207—Bottles or similar containers with necks or like restricted apertures, designed for pouring contents characterised by material, e.g. composition, physical features
Landscapes
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Mechanical Engineering (AREA)
- Containers Having Bodies Formed In One Piece (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は、例えば炭酸飲料や清涼
飲料水などを充填するのに好適な二軸延伸ブロ−成形さ
れた飽和ポリエステル製の自立容器に関し、さらに詳細
には、内容物の加熱殺菌時の耐熱及び耐圧性に優れた自
立容器に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a self-standing container made of biaxially stretched blow-molded saturated polyester, which is suitable for filling carbonated drinks, soft drinks and the like. The present invention relates to a self-supporting container having excellent heat resistance and pressure resistance during heat sterilization.
【0002】[0002]
【従来の技術】従来、耐熱、耐圧性容器としては、容器
本体の耐内圧性を高めるため底部を半球殻状に膨出成形
し、これに有底筒状に成形されたベ−スカップを装着し
て、容器に自立機能を付与したものが主流であった。し
かしながら、ベ−スカップの使用は、別途ベ−スカップ
を成形し装着固定を行わなければならないこと、容器の
重量が大きくなり、形状も大型化すること、加熱殺菌工
程で温水が容器底部に十分に達しないため内容物の加熱
殺菌をスム−ズに行うことができないこと、また、この
とき、ベ−スカップ内に水が溜まり、速やかに排水され
にくいこと、など様々な問題があった。2. Description of the Related Art Conventionally, as a heat-resistant and pressure-resistant container, in order to improve the internal pressure resistance of the container body, the bottom portion is bulged to form a hemispherical shell, and a base cup molded into a bottomed cylinder is attached to this. Then, the mainstream is a container with a self-supporting function. However, the use of the base cup requires that the base cup be separately molded and mounted and fixed, the weight of the container becomes large and the shape also becomes large, and hot water is sufficiently supplied to the bottom of the container during the heat sterilization process. There were various problems such that the heat sterilization of the contents could not be smoothly carried out because it did not reach, and that at this time, water was accumulated in the base cup and it was difficult to drain it quickly.
【0003】さらに、省資源や環境問題の観点から使用
済みの空容器を有効再利用することが望まれているが、
ベ−スカップを装着した容器では通常、容器本体とベ−
スカップや接着剤の材料が異なるため、再利用する場合
にはこれらを分離しなければならず、プロセス的にコス
ト高となるという問題も抱えている。Further, it is desired to effectively reuse a used empty container from the viewpoint of resource saving and environmental problems.
In a container equipped with a base cup, the container body and base are usually used.
Since the materials of the scup and the adhesive are different, they must be separated when they are reused, and there is a problem that the process cost becomes high.
【0004】このような問題から、ベ−スカップを必要
としない耐熱、耐圧性容器が望まれていた。ベ−スカッ
プを必要としない耐圧性容器としては、いくつかの提案
がなされており、一般的には底部中心部の周りに複数の
脚部を放射状に膨出し、これらの脚部の間に谷線部を形
成した構造か、あるいはシャンペンタイプの構造かのい
ずれかであり、例えば、特公昭48−5708号公報、
特公昭59−40693号公報、特公昭61−9170
号公報、特開昭63−202424号公報、及び特開平
3−43342号公報に記載されている。Due to these problems, a heat-resistant and pressure-resistant container that does not require a base cup has been desired. Several proposals have been made for pressure-resistant containers that do not require a base cup, and generally, a plurality of legs are radially bulged around the center of the bottom, and valleys are formed between these legs. It has either a structure in which a line portion is formed or a champagne type structure, and is disclosed in, for example, Japanese Patent Publication No. 48-5708.
Japanese Patent Publication No. 59-40693, Japanese Patent Publication No. 6-9170
JP-A-63-202424 and JP-A-3-43342.
【0005】[0005]
【発明が解決しようとする課題】しかしながら、これら
各公報に記載された容器は、耐圧性容器としては満足す
る性能を得ることができるものの、加熱殺菌工程を行う
耐熱、耐圧性容器として使用した場合には十分な性能を
得ることができない。すなわち、前記各公報に記載され
た容器は、底部中心部および該中心部周辺に未延伸領域
あるいは低延伸領域が存在しているため、加熱殺菌時に
内容物の温度が50℃〜70℃程度に上昇すると、内圧
が増大すること、また容器材料自体もクリ−プ変形を起
こしやすくなることにより、底部中心部および該中心部
周辺の低延伸領域がクリ−プ変形を起こして突出し、容
器は自立安定性を失うことになる。However, although the container described in each of these publications can achieve satisfactory performance as a pressure resistant container, when used as a heat resistant and pressure resistant container for performing a heat sterilization step. Can't get enough performance. That is, in the containers described in the above publications, since the unstretched region or the low-stretched region exists in the center of the bottom and the periphery of the center, the temperature of the contents becomes about 50 ° C to 70 ° C during heat sterilization. When it rises, the internal pressure increases, and the container material itself also easily undergoes creep deformation, so that the center part of the bottom part and the low-stretching region around the center part undergoes creep deformation to project, and the container stands by itself. You will lose stability.
【0006】この問題を解決する方法として、例えば、
特開平5−85535号公報に記載された容器を使用す
ることが考えられる。この容器は、底部中心部を結晶化
し、中心部周辺を十分に延伸した容器であるため、加熱
殺菌時に内圧が増大した場合の底部−プ変形をある程度
抑制することができる。しかしながら、この容器の場合
においても、脚部と脚部との間に形成された谷線部を十
分に延伸することは困難で該部分に低延伸領域が残るた
め、加熱殺菌時に該部分がクリ−プ変形を起こし底部が
突出して自立安定性を失うか、または、自立安定性は保
持されても、入り味線が大幅に降下し、実用性を失うと
いう問題が生じる。As a method for solving this problem, for example,
It is conceivable to use the container described in JP-A-5-85535. Since this container is a container in which the central portion of the bottom portion is crystallized and the periphery of the central portion is sufficiently stretched, it is possible to suppress the deformation of the bottom portion to some extent when the internal pressure increases during heat sterilization. However, even in the case of this container, it is difficult to sufficiently stretch the valley line portion formed between the leg portions and a low stretched region remains in the portion, so that the portion is not cleared during heat sterilization. -There is a problem in that the bottom portion is projected to lose the self-sustaining stability due to the deformation of the base, or the self-sustaining stability is maintained, but the flavor line is greatly lowered to lose the practicality.
【0007】本発明の研究者等は鋭意研究の結果、底部
中心部の周りに複数の脚部を放射状に膨出し、これらの
脚部と脚部との間に谷線部を形成した底部構造の場合、
内圧による応力が特に底部中心部の周辺部と谷線部に集
中することを見い出し、さらに実際の加熱殺菌時の底部
突出においては、谷線部のうち中心部に近い部分のクリ
−プ変形が特に大きいことを発見した。As a result of earnest research by the researchers of the present invention, a bottom structure in which a plurality of legs are radially bulged around the center of the bottom and a valley line portion is formed between the legs. in the case of,
It was found that the stress due to the internal pressure was concentrated especially on the peripheral part of the center of the bottom part and the valley line part.Furthermore, in the bottom protrusion during actual heat sterilization, creep deformation of the part of the valley line part close to the center part was observed. I found it to be particularly large.
【0008】本発明はこのような問題点を解決したもの
であり、加熱殺菌時に内圧の増大によりクリ−プ変形を
起こしやすい、主に底部中心部の周辺部及び谷線部の中
心部に近い部分を結晶化することにより、加熱殺菌時に
底部が突出して自立安定性を失うことがなく、さらには
耐薬品性にも優れた、耐熱、耐圧性自立容器を提供する
ものである。The present invention solves such a problem, and is apt to cause creep deformation due to an increase in internal pressure during heat sterilization, mainly near the periphery of the bottom center and the center of the valley line. It is intended to provide a heat-resistant and pressure-resistant self-supporting container which does not lose its self-sustaining stability due to its bottom portion protruding during heat sterilization by crystallizing a part and which is also excellent in chemical resistance.
【0009】[0009]
【課題を解決するための手段】すなわち、本発明の第1
の発明は、口頸部、肩部、胴部及び底部からなる二軸延
伸ブロー成形された飽和ポリエステル樹脂製中空容器に
おいて、前記底部は、底部中心部の周りに複数の脚部を
放射状に膨出し、これらの脚部と脚部との間に谷線部を
形成した自立可能な構造を有し、下記の(A)〜(E)
から選ばれた少なくとも一つの部分が結晶化されてお
り、かつ、前記口頸部の内周径が外周径に対して60%
〜90%であり、前記口頸部はネジ部を有し、少なくと
もこのネジ部が熱処理により残留内部応力・歪を緩和さ
れており、前記口頸部と前記肩部とをつなぐ首部の未延
伸部分が結晶化されていることを特徴とする耐熱及び耐
圧性自立容器である。 (A)底部中心部 (B)底部中心部の周辺部 (C)谷線部の底部中心部に近い部分 (D)脚部の底部中心部の周辺部の縁より接地部にいた
る部分 (E)前記(C)と前記(D)の間の部分 第2の発明は、前記胴部が、二軸延伸ブロ−成形時に5
0℃〜140℃に加熱された金型内に保持されることに
より、熱固定を施されている第1の発明の耐熱及び耐圧
性自立容器である。That is, the first aspect of the present invention
The invention, in a biaxially stretched blow molded saturated polyester resin hollow container consisting of a mouth, a shoulder, a body and a bottom, wherein the bottom is a plurality of legs radially expanded around the center of the bottom. It has a self-supporting structure in which a valley line portion is formed between these leg portions and the following (A) to (E)
At least one portion selected from the above is crystallized, and the inner diameter of the mouth / neck portion is 60% of the outer diameter.
% To 90%, the mouth / neck portion has a threaded portion, and at least this threaded portion has a residual internal stress / strain relaxed by heat treatment, and the neck portion that connects the mouth / neck portion and the shoulder portion is not stretched. A heat-resistant and pressure-resistant freestanding container characterized in that a part thereof is crystallized. (A) Center part of bottom part (B) Peripheral part of center part of bottom part (C) Part close to center part of bottom part of valley line part (D) Part of peripheral part of center part of bottom part of leg to ground part (E ) Portion between (C) and (D) In a second aspect of the invention, the body portion is 5 at the time of biaxial stretching blow molding.
The heat-resistant and pressure-resistant freestanding container of the first invention is heat-fixed by being held in a mold heated to 0 ° C to 140 ° C.
【0010】以下、本発明を詳細に説明する。本発明の
中空容器に用いられる飽和ポリエステル樹脂は、主たる
繰り返し単位がエチレンテレフタレートである熱可塑性
ポリエステル樹脂が好ましく、該熱可塑性ポリエステル
樹脂とは、ポリエチレンテレフタレートのホモポリマー
を主たる成分とするものである。The present invention will be described in detail below. The saturated polyester resin used in the hollow container of the present invention is preferably a thermoplastic polyester resin whose main repeating unit is ethylene terephthalate, and the thermoplastic polyester resin is a homopolymer of polyethylene terephthalate as a main component.
【0011】この熱可塑性ポリエステル樹脂としては、
テレフタル酸成分の一部を例えば、イソフタル酸、ナフ
タリンジカルボン酸、ジフェニルジカルボン酸、ジフェ
ノキシエタンジカルボン酸、ジフェニルエーテルジカル
ボン酸、ジフェニルスルホンジカルボン酸等の芳香族ジ
カルボン酸;ヘキサヒドロテレフタル酸、ヘキサヒドロ
イソフタル酸等の脂環族ジカルボン酸;アジピン酸、セ
バチン酸、アゼライン酸等の脂肪族ジカルボン酸;P−
β−ヒドロキシエトキシ安息香酸、ε−オキシカプロン
酸等のオキシ酸等の他の二官能性カルボン酸の1種以上
を置換して共重合したものが使用できる。As this thermoplastic polyester resin,
Some of the terephthalic acid components are aromatic dicarboxylic acids such as isophthalic acid, naphthalene dicarboxylic acid, diphenyl dicarboxylic acid, diphenoxyethane dicarboxylic acid, diphenyl ether dicarboxylic acid, diphenyl sulfone dicarboxylic acid; hexahydroterephthalic acid, hexahydroisophthalic acid Alicyclic dicarboxylic acids such as; adipic acid, sebacic acid, azelaic acid and other aliphatic dicarboxylic acids; P-
A copolymer obtained by substituting at least one other difunctional carboxylic acid such as oxyacid such as β-hydroxyethoxybenzoic acid and ε-oxycaproic acid can be used.
【0012】また、熱可塑性ポリエステル樹脂は、エチ
レングリコール成分の一部を例えば、トリメチレングリ
コール、テトラメチレングリコール、ヘキサメチレング
リコール、デカメチレングリコール、ネオペンチレング
リコール、ジエチレングリコール、1,1−シクロヘキ
サンジメチロール、1,4−シクロヘキサンジメチロー
ル、2,2(4’−β−ヒドロキシエトキシフェニル)
スルホン酸等の他のグリコール及びこれらの機能的誘導
体の多官能化合物の1種以上で置換して共重合した共重
合体でもよい。In the thermoplastic polyester resin, a part of the ethylene glycol component is, for example, trimethylene glycol, tetramethylene glycol, hexamethylene glycol, decamethylene glycol, neopentylene glycol, diethylene glycol, 1,1-cyclohexanedimethylol. , 1,4-cyclohexanedimethylol, 2,2 (4'-β-hydroxyethoxyphenyl)
It may be a copolymer obtained by substituting one or more polyfunctional compounds of other glycols such as sulfonic acid and functional derivatives thereof for copolymerization.
【0013】また、本発明の容器に使用する熱可塑性ポ
リエステル樹脂は、固有粘度が0.7〜0.9が好まし
く、特に好ましくは0.75〜0.85である。The intrinsic viscosity of the thermoplastic polyester resin used in the container of the present invention is preferably 0.7 to 0.9, and particularly preferably 0.75 to 0.85.
【0014】更に、本発明に使用する熱可塑性ポリエス
テル樹脂には、着色剤、熱劣化防止剤、酸化防止剤、紫
外線吸収剤、帯電防止剤、抗菌剤、滑剤等の添加剤を適
宜用いることができる。Further, for the thermoplastic polyester resin used in the present invention, additives such as a colorant, a heat deterioration preventing agent, an antioxidant, an ultraviolet absorber, an antistatic agent, an antibacterial agent and a lubricant may be appropriately used. it can.
【0015】本発明において、容器底部を部分的に結晶
化させる方法としては、赤外線ヒ−タ−、熱風、赤外線
ランプ、石英管ヒーター、高周波加熱装置などの熱源を
用い、この熱源と容器底部との間にスリットを有する遮
蔽板を設置して、この遮蔽板に設けられたスリットを通
して容器底部の所望の部分を加熱することによって熱結
晶化する方法がある。この遮蔽板の片面の表面形状は容
器底部とほぼ同様な凹部形状を有し、容器底部と遮蔽板
が嵌合するものが好ましい。熱源の熱は、遮蔽板のスリ
ットを通って容器底部に達し、熱により底部の所望の部
分が結晶化される。又、遮蔽板は、冷却水又は温水を通
すことにより、表面温度を容器材料のTg以下の温度に
一定に保ち、容器底部と接触する部分がTgを越えて高
温に加熱されることを防ぐことが好ましい。In the present invention, as a method of partially crystallizing the bottom of the container, a heat source such as an infrared heater, hot air, an infrared lamp, a quartz tube heater, or a high frequency heating device is used. There is a method in which a shield plate having a slit is installed between the two, and a desired portion of the bottom of the container is heated through a slit provided in the shield plate to perform thermal crystallization. It is preferable that the surface shape of one surface of the shielding plate has a concave shape substantially similar to that of the container bottom portion, and the container bottom portion and the shielding plate are fitted to each other. The heat of the heat source reaches the bottom of the container through the slit of the shielding plate, and the heat crystallizes a desired portion of the bottom. In addition, the shielding plate keeps the surface temperature constant at a temperature not higher than the Tg of the container material by passing cooling water or hot water, and prevents the portion in contact with the bottom of the container from being heated to a high temperature exceeding Tg. Is preferred.
【0016】本発明において、容器底部の(A)〜
(E)の部分は、容器底部の低延伸部分である。(A)
底部中心部とは、例えば、図24の3で示される部分で
あり、(B)底部中心部の周辺部は図24の4で示され
る部分であり、(C)谷線部の底部中心部に近い部分と
は、谷線部の内中心部に近い部分で、谷線部全体の5%
〜85%、特に好ましくは10%〜50%を言い、例え
ば、図24の6Aで示される部分である。(D)脚部の
底部中心部の周辺部の縁より接地部にいたる部分とは、
脚部の内、脚部の底部中心部の周辺部の縁より接地部に
いたる部分をいい、例えば、図24の7で示される部分
である。(E)前記(C)と前記(D)の間の部分と
は、例えば、図24の20で示される部分である。In the present invention, (A) to the bottom of the container
The portion (E) is a low stretched portion at the bottom of the container. (A)
The bottom center portion is, for example, a portion indicated by 3 in FIG. 24, (B) the peripheral portion of the bottom center portion is a portion indicated by 4 in FIG. 24, and (C) the bottom center portion of the valley line portion. The part near to is the part near the inner center of the valley line part, which is 5% of the whole valley line part.
.About.85%, particularly preferably 10% to 50%, for example, the portion indicated by 6A in FIG. (D) From the edge of the peripheral part of the bottom center of the leg to the ground contact part,
Of the legs, the part from the edge of the peripheral part of the center of the bottom of the legs to the ground contact part, for example, the part indicated by 7 in FIG. (E) The portion between (C) and (D) is, for example, the portion indicated by 20 in FIG.
【0017】本発明においては、(A)〜(E)の中か
ら選ばれた少なくとも1つの部分が結晶化されており、
好ましい構成は、(B)及び(C)を含む組み合わせで
あり、特に好ましい構成は、下記の(イ)〜(ホ)の組
み合わせである。容器底部の結晶化により、加熱殺菌時
の容器底部のクリープ変形を抑制することができる。 (イ)(A)、(B)及び(C)の組み合わせ (ロ)(A)、(B)、(C)及び(D)の組み合わせ (ハ)(A)、(B)、(C)、(D)及び(E)の組
み合わせ (ニ)(B)、(C)及び(D)の組み合わせ (ホ)(B)、(C)、(D)及び(E)の組み合わせIn the present invention, at least one portion selected from (A) to (E) is crystallized,
A preferred configuration is a combination including (B) and (C), and a particularly preferred configuration is a combination of (a) to (e) below. By crystallizing the bottom of the container, creep deformation of the bottom of the container during heat sterilization can be suppressed. (B) Combination of (A), (B) and (C) (b) Combination of (A), (B), (C) and (D) (C) (A), (B), (C) , Combination of (D) and (E) (d) combination of (B), (C) and (D) (e) combination of (B), (C), (D) and (E)
【0018】本発明の容器底部の結晶化された部分は、
ポリエチレンテレフタレ−トの密度が、1.350g/cm3〜1.
390g/cm3の範囲で不透明な状態であり、特に好ましい密
度は、1.355g/cm3〜1.385g/cm3である。結晶化された部
分の密度が1.350g/cm3未満であると、容器の加熱殺菌時
に、内圧により底部がクリ−プ変形して突出し易くな
り、自立安定性を失い商品価値を失うことがある。ま
た、1.390g/cm3を越えると結晶化部分の衝撃強度が低下
し、容器に落下衝撃を与えたときに底部が破壊すること
がある。The crystallized portion of the bottom of the container of the present invention is
The density of polyethylene terephthalate is 1.350 g / cm 3 to 1.
It is in an opaque state in the range of 390 g / cm 3 , and a particularly preferable density is 1.355 g / cm 3 to 1.385 g / cm 3 . If the density of the crystallized part is less than 1.350 g / cm 3 , the bottom part of the container may creep and deform due to internal pressure during heat sterilization of the container, and the product may lose its self-standing stability and lose its commercial value. . Further, if it exceeds 1.390 g / cm 3 , the impact strength of the crystallized portion is lowered, and the bottom portion may be broken when the container is given a drop impact.
【0019】また、本発明において結晶化される容器底
部は、クレ−ズの発生し易い部分の一つである。クレ−
ズは充填工場のコンベア−ラインにおける潤滑剤などに
よってさらに促進され、ストレスクラックを引き起こす
が、該部分を結晶化することにより材料の耐薬品性も向
上させることができるため、ストレスクラックの発生を
抑制することができる。The bottom of the container to be crystallized in the present invention is one of the parts where craze is likely to occur. Cray
Is further promoted by a lubricant or the like in the conveyor line of the filling factory and causes stress cracks, but the chemical resistance of the material can also be improved by crystallizing the part, so the occurrence of stress cracks is suppressed. can do.
【0020】本発明の容器の口頸部は、70℃〜130
℃に加熱して材料の残留内部応力・歪を緩和した後、歪
が再発生しないように徐冷する。これにより加熱殺菌時
に起こる口頸部の熱収縮が少なく、十分な耐熱性を有す
る自立容器が得られる。また、ネジ部は白化結晶化され
ないため、材料の残留内部応力・歪の緩和時に急激な収
縮が起こらず寸法精度にも優れている。The mouth and neck of the container of the present invention has a temperature of 70 ° C to 130 ° C.
After heating to ℃ to relax the residual internal stress and strain of the material, it is gradually cooled so that strain does not re-occur. As a result, a heat-shrinkage of the mouth and neck that occurs during heat sterilization is small, and a self-supporting container having sufficient heat resistance can be obtained. Further, since the screw portion is not whitened and crystallized, it does not cause a rapid shrinkage when relaxing the residual internal stress and strain of the material, and is excellent in dimensional accuracy.
【0021】本発明における容器口頸部は、内周径が外
周径に対して60%〜90%であり、特に好ましくは、
74%〜77%である。これにより、加熱殺菌時にキャ
ップの締め付け力による変形を防止し、良好な性能が得
られる。60%未満では口部の肉厚が厚過ぎて外観上好
ましくない上、内容物充填時にノズルが円滑に挿入され
ないという問題が生ずる。また、90%を越えると口部
の肉厚が薄すぎて強度が低下し、キャップの締め付け力
等により変形を招く恐れがある。The container neck in the present invention has an inner diameter of 60% to 90% of the outer diameter, and particularly preferably,
74% to 77%. This prevents deformation due to the tightening force of the cap during heat sterilization, and good performance can be obtained. If it is less than 60%, the thickness of the mouth is too thick, which is not preferable in appearance, and there is a problem that the nozzle cannot be smoothly inserted when filling the contents. On the other hand, if it exceeds 90%, the thickness of the mouth portion becomes too thin and the strength decreases, which may cause deformation due to the tightening force of the cap or the like.
【0022】本発明において、容器口頸部と肩部とをつ
なぐ首部の未延伸部分は、結晶化されており、前記部分
は、例えば、図1のネックサポートリング下部14で示
される斜線の部分を言う。ネックサポートリング下部を
結晶化することにより、加熱殺菌時の該部分のクリ−プ
変形を抑制することができる。該部分を結晶化しない場
合、加熱殺菌時に該部分がクリ−プ変形を起こし、容器
の全高、容量が著しく増大し、容器は実用性を失う。In the present invention, the unstretched portion of the neck portion connecting the neck and shoulder portion of the container is crystallized, and the portion is, for example, the hatched portion shown by the lower portion 14 of the neck support ring in FIG. Say By crystallizing the lower part of the neck support ring, it is possible to suppress creep deformation of the portion during heat sterilization. If the portion is not crystallized, the portion undergoes creep deformation during heat sterilization, the overall height and volume of the container are significantly increased, and the container loses practicality.
【0023】本発明における飽和ポリエステル樹脂製容
器の胴部は、二軸延伸ブロ−成形時に50℃〜140℃
に加熱された金型内に保持され、熱固定を施されてい
る。熱固定を施すことにより材料の結晶化度を高めるこ
とができ、容器の加熱殺菌時に内容物の温度が50℃〜
70℃に上昇した時に、容器の熱変形及びクリ−プ変形
を抑制することができる。熱固定温度が高いほど容器の
耐熱、耐圧性は良好となるが、それに連れて容器を金型
より取り出す際の冷却工程に要する時間が長くなり、全
体としての成形サイクルが長くなるため、両者のバラン
スから金型の温度は60℃〜95℃がより好ましい。The body of the saturated polyester resin container of the present invention has a body temperature of 50 ° C. to 140 ° C. during biaxial stretching blow molding.
It is held in a mold that has been heated to and is heat-fixed. By heat-setting, the crystallinity of the material can be increased, and the temperature of the contents during the heat sterilization of the container is 50 ° C to
When the temperature rises to 70 ° C., thermal deformation and creep deformation of the container can be suppressed. The higher the heat setting temperature, the better the heat resistance and pressure resistance of the container, but the longer the time required for the cooling step when the container is taken out of the mold, the longer the overall molding cycle. From the balance, the mold temperature is more preferably 60 ° C to 95 ° C.
【0024】[0024]
【実施例】以下、実施例により本発明を詳細に説明す
る。The present invention will be described in detail below with reference to examples.
【0025】実施例1 ポリエチレンテレフタレート(IV=0.85)を射出
成形して得たプリフォーム11(図19に示す)のネッ
クサポ−トリング13の下約6mmのネックサポ−トリン
グ下部14を、赤外線ヒ−タ−により局部的に加熱して
結晶化させ、さらに、口頸部のネジ部12を100℃で
20分加熱した後、徐冷して残留内部応力・歪を緩和し
た。このプリフォ−ムの口頸部の内周径15は、外周径
16に対して76%となるようにした(図20に示
す)。このプリフォ−ムの口頸部及びネックサポ−トリ
ング下部を除く部分を再加熱した後、ブロー金型内に配
置して、ストレッチロッドにより軸方向に延伸しながら
エアーブローにより周方向に延伸して、二軸延伸ブロー
成形を行った。 この時、金型の胴部を90℃に加熱し
た状態で、5秒間熱固定を行い、続いてブロ−金型内に
常温のエア−を循環させて成形体を冷却した後に取り出
して、容器を得た。この容器は、図2及び図3に示すよ
うに、5個の脚部5が底部中心部3の周りに放射状に等
間隔に膨出すると共に、該脚部5の間に谷線部6を形成
した自立型の底部構造を有している。EXAMPLE 1 About 6 mm below the neck support ring 13 of a preform 11 (shown in FIG. 19) obtained by injection-molding polyethylene terephthalate (IV = 0.85), a lower part 14 of the neck support ring was fitted with an infrared heater. It was locally heated with a taper to be crystallized, and the screw portion 12 of the mouth and neck was heated at 100 ° C. for 20 minutes and then gradually cooled to relieve residual internal stress and strain. The inner diameter 15 of the mouth and neck of this preform was set to be 76% of the outer diameter 16 (shown in FIG. 20). After reheating the part of the preform except the mouth and neck and the lower part of the neck support ring, it is placed in a blow mold and stretched in the circumferential direction by air blow while stretching in the axial direction by a stretch rod, Biaxial stretch blow molding was performed. At this time, while the body of the mold was heated to 90 ° C., heat fixing was performed for 5 seconds, and then air at room temperature was circulated in the blow mold to cool the molded body and then taken out to obtain a container. Got In this container, as shown in FIGS. 2 and 3, five legs 5 are radially bulged around the bottom central portion 3 at equal intervals, and valley lines 6 are provided between the legs 5. It has a self-supporting bottom structure formed.
【0026】次に、この容器を図4及び図5に示すよう
な遮蔽板8aの上に設置し、遮蔽板8aの下方から赤外
線ヒ−タ−により容器の底部を加熱したところ、底部中
心部3、底部中心部の周辺部4及び谷線部の底部中心部
に近い部分6Aが結晶化された容器底部2a(図6に示
す)を有する自立容器を得た。自立容器の底部の結晶化
された部分を切り取って、密度勾配管法により密度を測
定したところ、1.365g/cm3であった。この容器の全高は
305mm、入り味線容量は1.5リットルであり、容
器口頸部の内周径は外周径に対して76%であった。図
1に自立容器の正面図を示す。Next, this container was placed on a shield plate 8a as shown in FIGS. 4 and 5, and the bottom of the container was heated from below the shield plate 8a by an infrared heater. 3, a self-standing container having a container bottom 2a (shown in FIG. 6) in which the peripheral portion 4 of the bottom center portion and the portion 6A near the bottom center portion of the valley line portion were crystallized were obtained. The crystallized portion at the bottom of the self-supporting container was cut off, and the density was measured by the density gradient tube method. As a result, it was 1.365 g / cm 3 . The total height of this container was 305 mm, the volume of the contained taste line was 1.5 liters, and the inner diameter of the neck of the container was 76% of the outer diameter. FIG. 1 shows a front view of the self-supporting container.
【0027】上記において、遮蔽板8aの表面形状は容
器の底面とほぼ同様な表面形状を有し、図4、5に示す
ようなスリット9aを有する。赤外線ヒ−タ−の輻射熱
は、このスリットを通って容器底部に達し、熱により所
望の部分を結晶化させることができる。遮蔽板には冷却
水又は温水を通すことにより、遮蔽板の表面温度を一定
に保ち、容器底部と接触する部分が、材料のTgを越え
る高温度になるのを防ぐことができる。In the above, the surface shape of the shielding plate 8a is substantially the same as the bottom surface of the container, and has the slit 9a as shown in FIGS. The radiant heat of the infrared heater reaches the bottom of the container through this slit, and the desired part can be crystallized by the heat. By passing cooling water or hot water through the shield plate, the surface temperature of the shield plate can be kept constant, and the portion in contact with the bottom of the container can be prevented from reaching a high temperature exceeding the Tg of the material.
【0028】実施例2 実施例1と同様にして図7、8に示すような遮蔽板8b
を使用し、容器の底部を加熱し、底部中心部の周辺部4
および谷線部の底部中心部に近い部分6Aが結晶化され
た容器底部2bを得た(図9に示す)。自立容器の底部
の結晶化された部分を切り取って、密度を測定したとこ
ろ、1.363g/cm3であった。この容器の全高は305m
m、入り味線容量は1.5リットルであり、容器口頸部
の内周径は外周径に対して75%であった。Embodiment 2 Similar to Embodiment 1, a shielding plate 8b as shown in FIGS.
The bottom of the container is heated using the
A container bottom 2b was obtained in which the portion 6A near the center of the bottom of the valley line portion was crystallized (shown in FIG. 9). The crystallized portion at the bottom of the self-supporting container was cut off and the density was measured and found to be 1.363 g / cm 3 . The total height of this container is 305m
m, the taste line capacity was 1.5 liters, and the inner diameter of the neck of the container was 75% of the outer diameter.
【0029】実施例3 実施例1と同様にして図10、11に示すような遮蔽板
8cを使用し、容器の底部を加熱し、底部中心部3およ
び谷線部の底部中心部に近い部分6Aが結晶化された容
器底部2cを得た(図12に示す)。自立容器の底部の
結晶化された部分を切り取って、密度を測定したとこ
ろ、1.365g/cm3であった。この容器の全高は305m
m、入り味線容量は1.5リットルであり、容器口頸部
の内周径は外周径に対して76%であった。Example 3 Similar to Example 1, a shielding plate 8c as shown in FIGS. 10 and 11 was used to heat the bottom of the container and to close the center 3 of the bottom and the center of the bottom of the valley portion. A container bottom 2c in which 6A was crystallized was obtained (shown in FIG. 12). The crystallized portion at the bottom of the self-supporting container was cut off, and the density was measured and found to be 1.365 g / cm 3. The total height of this container is 305m
m, the taste line capacity was 1.5 liters, and the inner diameter of the neck of the container was 76% of the outer diameter.
【0030】実施例4 実施例1と同様にして図13及び図14に示すような遮
蔽板8dを使用し、容器の底部を加熱し、底部中心部
3、および底部中心部の周辺部4、および谷線部の底部
中心部に近い部分6A、および脚部の底部中心部の周辺
部の縁より接地部にいたる部分7、および谷線部の底部
中心部に近い部分と脚部の底部中心部の周辺部の縁より
接地部にいたる部分の間の部分20が結晶化された容器
底部2dを得た(図15に示す)。自立容器の底部の結
晶化された部分を切り取って、密度を測定したところ、
1.366g/cm3であった。この容器の全高は305mm、入
り味線容量は1.5リットルであり、容器口頸部の内周
径は外周径に対して76%であった。Example 4 In the same manner as in Example 1, a shielding plate 8d as shown in FIGS. 13 and 14 was used to heat the bottom portion of the container, and the bottom center portion 3 and the bottom center peripheral portion 4 were used. And a portion 6A near the bottom center of the valley line portion, a portion 7 from the peripheral edge of the bottom center portion of the leg to the ground contact portion, and a portion near the bottom center portion of the valley line portion and the bottom center of the leg portion. A container bottom 2d was obtained in which the portion 20 between the edge of the peripheral portion and the portion reaching the grounding portion was crystallized (shown in FIG. 15). When the crystallized part of the bottom of the self-supporting container was cut out and the density was measured,
It was 1.366 g / cm 3 . The total height of this container was 305 mm, the volume of the contained taste line was 1.5 liters, and the inner diameter of the neck of the container was 76% of the outer diameter.
【0031】実施例5 実施例1と同様にして図16、17に示すような遮蔽板
8eを使用し、自立容器の底部を加熱し、谷線部の底部
中心部に近い部分6Aが結晶化された容器底部2eを得
た(図18に示す)。この時、底部の加熱時間を1.5
倍とした。自立容器の底部の結晶化された部分を切り取
って、密度を測定したところ、1.375g/cm3であった。こ
の容器の全高は305mm、入り味線容量は1.5リッ
トルであり、容器口頸部の内周径は外周径に対して76
%であった。Example 5 In the same manner as in Example 1, the shielding plate 8e as shown in FIGS. 16 and 17 was used to heat the bottom of the self-supporting container, and the portion 6A near the center of the bottom of the valley line portion was crystallized. The container bottom 2e thus obtained was obtained (shown in FIG. 18). At this time, the heating time of the bottom is 1.5
Doubled The crystallized portion at the bottom of the self-supporting container was cut off, and the density was measured and found to be 1.375 g / cm 3 . The total height of this container is 305 mm, the volume of the taste line is 1.5 liters, and the inner diameter of the neck of the container is 76 relative to the outer diameter.
%Met.
【0032】比較例1 実施例1において、容器底部の加熱、熱結晶化を行なわ
ない以外は同様に行なった。得られた中空容器は、底部
が全く結晶化していなかった。Comparative Example 1 The same procedure as in Example 1 was carried out except that the heating and thermal crystallization of the bottom of the container were not performed. The bottom of the obtained hollow container was not crystallized at all.
【0033】比較例2 実施例1において、プリフォ−ム11の口頸部のネジ部
12の加熱、徐冷処理を行わず、内部残留応力・歪を緩
和しなかった以外は同様に行なった。Comparative Example 2 The same procedure as in Example 1 was carried out, except that the screw portion 12 at the mouth and neck of the preform 11 was not heated and gradually cooled, and the internal residual stress and strain were not relaxed.
【0034】比較例3 実施例1において、プリフォ−ム11のネックサポ−ト
リング13の下約6mmのネックサポ−トリング下部14
を結晶化させなかった以外は同様に行なった。COMPARATIVE EXAMPLE 3 In Example 1, the neck support ring lower portion 14 of about 6 mm below the neck support ring 13 of the preform 11 is used.
Was performed in the same manner except that was not crystallized.
【0035】評価方法及び結果 (1)自立安定性 底部の中心部が脚部の接地面より下に突出していないも
のを○、突出しているものを×とした。 (2)入り味線降下量 評価前後の、中空容器の口頸部の先端から内容物の液面
までの高さの差を求めた。降下量が20mm以下を良好
とする。 (3)口頸部内周径変形量 評価前後の、キャップをはずした状態での口頸部内周径
を測定し差を求めた。 (4)全高変形量 評価前後の、容器全体の高さを測定し差を求めた。Evaluation Method and Results (1) Self-Stability Stability: The one in which the central portion of the bottom portion did not project below the grounding surface of the leg portion was marked with ◯, and the one with protruding portion was marked in x. (2) Amount of drop in taste line before and after the evaluation The difference in height from the tip of the mouth and neck of the hollow container to the liquid level of the contents was determined. A fall amount of 20 mm or less is considered good. (3) Amount of Deformation of Inner Diameter of Mouth and Neck Before and after the evaluation, the inner circumference of the mouth and neck with the cap removed was measured to obtain the difference. (4) Total deformation amount Before and after the evaluation, the height of the entire container was measured to obtain the difference.
【0036】実施例1〜5および比較例1〜3で得られ
る容器を、各12本ずつ作成し、5℃において、2.5
ガスボリュームの炭酸水を入味線43mmまで充填して、
キャッピングした後、70℃の温水シャワーを30分間
かけ、その後、20℃の水で10分間シャワ−をかけ冷
却を行い、自立容器の評価を行った。自立安定性(底部
突出)の評価結果及び入り味線降下量の測定結果(12
本の平均値)を表1に示す。さらに、キャップを開栓
し、充填前に対する口頸部内周径の変形量、同じく容器
の全高変形量を測定した結果(12本の平均値)を表1
に示す。12 containers were prepared for each of the containers obtained in Examples 1-5 and Comparative Examples 1-3.
Fill the gas volume of carbonated water to the line of 43mm,
After capping, a hot water shower at 70 ° C. was applied for 30 minutes, and then showering was performed with water at 20 ° C. for 10 minutes to perform cooling, and the self-standing container was evaluated. Evaluation results of self-sustaining stability (bottom protrusion) and measurement results of entering taste line drop amount (12
Table 1 shows the average value of the book. Further, the results (average value of 12 bottles) obtained by opening the cap and measuring the deformation amount of the inner circumference of the mouth and neck portion before filling and also the total height deformation amount of the container are shown in Table 1.
Shown in.
【0037】[0037]
【表1】 (注1)自立安定性不良のため測定できず。[Table 1] (Note 1) Measurement cannot be performed due to poor self-standing stability.
【0038】上記の試験結果において、実施例1〜5お
よび比較例1〜3の結果から、本発明の容器は、加熱殺
菌時のクリ−プ変形による底部突出を抑制して入り味線
の降下を防ぎ、自立安定性を保持することに優れている
ことが理解される。なお、本発明における容器底部の構
造は、本実施例の構造に限定されるものではなく、本実
施例と類似の他の構造においても同様に適用できる。実
施例1と形状の異なる自立容器の例として、図21、図
22及び図23に示される容器がある。From the results of the above test, from the results of Examples 1 to 5 and Comparative Examples 1 to 3, the container of the present invention suppresses the bottom protrusion due to creep deformation during heat sterilization and lowers the taste line. It is understood that it is excellent in preventing self-reliance and maintaining self-sustaining stability. The structure of the bottom of the container in the present invention is not limited to the structure of this embodiment, and can be similarly applied to other structures similar to this embodiment. As an example of a self-supporting container having a shape different from that of the first embodiment, there is a container shown in FIGS. 21, 22 and 23.
【0039】[0039]
【発明の効果】以上の通り、本発明の自立容器は、加熱
殺菌時の底部突出を抑制して自立安定性を保持し、耐薬
品性にも優れ、かつ、口頸部の耐熱性及び寸法精度に優
れ、首部のクリ−プ変形を防ぎ、胴部の耐熱、耐圧性に
も優れた、耐熱、及び耐圧性自立容器を提供することが
できる。また、本発明による容器はベースカップを必要
としないため、加熱殺菌処理時の熱水が容器底部に十分
に達し、内容物の加熱殺菌をスムーズに行うことがで
き、さらには、使用済み容器の再利用も容易となる。As described above, the self-supporting container of the present invention suppresses the bottom protrusion during heat sterilization to maintain self-supporting stability, has excellent chemical resistance, and has heat and dimension of the mouth and neck. It is possible to provide a heat-resistant and pressure-resistant self-supporting container that is excellent in accuracy, prevents creep deformation of the neck portion, and has excellent heat resistance and pressure resistance of the body portion. Further, since the container according to the present invention does not require a base cup, hot water at the time of heat sterilization reaches the bottom of the container sufficiently, and heat sterilization of the contents can be smoothly performed. Reuse becomes easy.
【図1】本発明の自立容器の正面図である。FIG. 1 is a front view of a self-supporting container of the present invention.
【図2】本発明の自立容器の底部の結晶化を行う前の底
面図である。FIG. 2 is a bottom view before crystallization of the bottom of the self-supporting container of the present invention.
【図3】本発明の自立容器の底部の断面図である。FIG. 3 is a cross-sectional view of the bottom of the self-supporting container of the present invention.
【図4】実施例1で使用する遮蔽板の平面図である。FIG. 4 is a plan view of a shielding plate used in Example 1.
【図5】実施例1で使用する遮蔽板の図4におけるA
A’断面図である。5 is a view of the shielding plate used in Example 1 as shown in FIG.
It is an A'sectional view.
【図6】実施例1の自立容器の底面図である。FIG. 6 is a bottom view of the self-supporting container of Example 1.
【図7】実施例2で使用する遮蔽板の平面図である。FIG. 7 is a plan view of a shielding plate used in Example 2.
【図8】実施例2で使用する遮蔽板の図7におけるB
B’断面図である。8 is a B of FIG. 7 of the shielding plate used in Example 2. FIG.
It is a B'sectional view.
【図9】実施例2の自立容器の底面図である。FIG. 9 is a bottom view of the self-supporting container according to the second embodiment.
【図10】実施例3で使用する遮蔽板の平面図である。FIG. 10 is a plan view of a shielding plate used in Example 3.
【図11】実施例3で使用する遮蔽板の図10における
CC’断面図である。11 is a cross-sectional view of the shielding plate used in Example 3 taken along the line CC ′ in FIG.
【図12】実施例3の自立容器の底面図である。FIG. 12 is a bottom view of the self-supporting container of Example 3.
【図13】実施例4で使用する遮蔽板の平面図である。13 is a plan view of a shielding plate used in Example 4. FIG.
【図14】実施例4で使用する遮蔽板の図13における
DD’断面図である。FIG. 14 is a DD ′ cross-sectional view of the shielding plate used in Example 4 in FIG. 13.
【図15】実施例4の自立容器の底面図である。FIG. 15 is a bottom view of the self-supporting container of Example 4.
【図16】実施例5で使用する遮蔽板の平面図である。16 is a plan view of a shield plate used in Example 5. FIG.
【図17】実施例5で使用する遮蔽板の図16における
EE’断面図である。FIG. 17 is a sectional view of the shielding plate used in Example 5 taken along the line EE ′ in FIG.
【図18】実施例5の自立容器の底面図である。FIG. 18 is a bottom view of the self-supporting container of Example 5.
【図19】本発明の自立容器の製造に用いるプリフォ−
ムの正面図であるFIG. 19 is a preform used for manufacturing the self-supporting container of the present invention.
FIG.
【図20】本発明の自立容器の製造に用いるプリフォ−
ムの口頸部の断面図である。FIG. 20 is a preform used for manufacturing the self-supporting container of the present invention.
It is a sectional view of the mouth and neck of the mouse.
【図21】形状の異なる自立容器の正面図である。FIG. 21 is a front view of free-standing containers having different shapes.
【図22】図21に示す自立容器の底部の結晶化を行う
前の底面図である。22 is a bottom view before crystallization of the bottom portion of the self-supporting container shown in FIG. 21. FIG.
【図23】図21に示す自立容器の底部の断面図であ
る。23 is a cross-sectional view of the bottom of the self-supporting container shown in FIG.
【図24】本発明の容器底部の各部分を示す図である。FIG. 24 is a view showing each part of the container bottom of the present invention.
【図25】図24に示す容器底部の断面図である。25 is a cross-sectional view of the container bottom shown in FIG. 24.
1 自立容器 2 底部 2a、2b、2c、2d、2e 部分的に結晶化された
容器底部 3 (A)底部中心部 4 (B)底部中心部の周辺部 5 脚部 6A (C)谷線部の中心部に近い部分 6 谷線部 7 (D)底部中心部の周辺部の縁より接地部にいたる
部分 8a、8b、8c、8d、8e 遮蔽板 9a、9b、9c、9d、9e スリット 10 冷却水又は温水配管 11 プリフォ−ム 12 ネジ部 13 ネックサポ−トリング 14 ネックサポ−トリング下部 15 口頸部内周径 16 口頸部外周径 17 口頸部 18 肩部 19 胴部 20 (E)谷線部の底部中心部に近い部分と脚部の前
記周辺部の縁より接地部にいたる部分の間の部分DESCRIPTION OF SYMBOLS 1 Freestanding container 2 Bottom part 2a, 2b, 2c, 2d, 2e Partially crystallized container bottom part 3 (A) Bottom center part 4 (B) Bottom center part peripheral part 5 Leg part 6A (C) Valley line part Near the center of the bottom 6 Valley line 7 (D) Bottom part 8a, 8b, 8c, 8d, 8e from the peripheral edge of the center to the ground 8a, 9b, 9c, 9d, 9e Slit 10 Cooling water or hot water piping 11 Preform 12 Screw part 13 Neck support ring 14 Neck support ring lower part 15 Neck inner diameter 16 Mouth neck outer diameter 17 Mouth neck 18 Shoulder 19 Body 20 (E) Valley line The part between the part near the center of the bottom of the part and the part from the edge of the peripheral part of the leg to the ground contact part
Claims (2)
軸延伸ブロー成形された飽和ポリエステル樹脂製中空容
器において、前記底部は、底部中心部の周りに複数の脚
部を放射状に膨出し、これらの脚部と脚部との間に谷線
部を形成した自立可能な構造を有し、下記の(A)〜
(E)から選ばれた少なくとも一つの部分が結晶化され
ており、かつ、前記口頸部の内周径が外周径に対して6
0%〜90%であり、前記口頸部はネジ部を有し、少な
くともこのネジ部が熱処理により残留内部応力・歪を緩
和されており、前記口頸部と前記肩部とをつなぐ首部の
未延伸部分が結晶化されていることを特徴とする耐熱及
び耐圧性自立容器。 (A)底部中心部 (B)底部中心部の周辺部 (C)谷線部の底部中心部に近い部分 (D)脚部の底部中心部の周辺部の縁より接地部にいた
る部分 (E)前記(C)と前記(D)の間の部分1. A biaxially stretch blow-molded hollow container made of saturated polyester resin comprising a mouth, a neck, a shoulder, a body and a bottom, wherein the bottom has a plurality of legs radially around a center of the bottom. It has a structure in which it bulges out and forms a valley line portion between these leg portions so that it can stand on its own.
At least one portion selected from (E) is crystallized, and the inner diameter of the mouth / neck portion is 6 with respect to the outer diameter.
0% to 90%, the mouth / neck portion has a threaded portion, and at least this threaded portion is relieved of residual internal stress / strain by heat treatment, and the neck portion connecting the mouth / neck portion and the shoulder portion is A heat-resistant and pressure-resistant freestanding container characterized in that the unstretched portion is crystallized. (A) Center part of bottom part (B) Peripheral part of center part of bottom part (C) Part close to center part of bottom part of valley line part (D) Part of peripheral part of center part of bottom part of leg to ground part (E ) Portion between (C) and (D)
0℃〜140℃に加熱された金型内に保持されることに
より、熱固定を施されている請求項1記載の耐熱及び耐
圧性自立容器。2. The body part is formed by a biaxial stretching blow molding process.
The heat-resistant and pressure-resistant freestanding container according to claim 1, which is heat-fixed by being held in a mold heated to 0 ° C to 140 ° C.
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP22497194A JPH07285527A (en) | 1994-02-28 | 1994-09-20 | Heat resistant and pressure resistant self-standing container |
EP94120407A EP0669255B1 (en) | 1994-02-23 | 1994-12-22 | Heat and pressure resistant container |
DE69417389T DE69417389T2 (en) | 1994-02-23 | 1994-12-22 | Heat and pressure resistant container |
TW83112327A TW287134B (en) | 1994-02-23 | 1994-12-29 | |
KR1019940040220A KR950024946A (en) | 1994-02-23 | 1994-12-30 | Freestanding containers |
CN94120795A CN1043747C (en) | 1994-02-23 | 1994-12-31 | Self stand container |
US08/857,587 US5858300A (en) | 1994-02-23 | 1997-05-16 | Self-sustaining container |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3025294 | 1994-02-28 | ||
JP6-30252 | 1994-02-28 | ||
JP22497194A JPH07285527A (en) | 1994-02-28 | 1994-09-20 | Heat resistant and pressure resistant self-standing container |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH07285527A true JPH07285527A (en) | 1995-10-31 |
Family
ID=26368574
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP22497194A Pending JPH07285527A (en) | 1994-02-23 | 1994-09-20 | Heat resistant and pressure resistant self-standing container |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH07285527A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH10305824A (en) * | 1995-10-31 | 1998-11-17 | Yoshino Kogyosho Co Ltd | Heat-resistant and pressure-resistant self-supporting type hollow container made of synthetic resin |
JP2006103735A (en) * | 2004-10-04 | 2006-04-20 | Toyo Seikan Kaisha Ltd | Synthetic resin-made container |
WO2012029665A1 (en) * | 2010-09-01 | 2012-03-08 | 大日本印刷株式会社 | Plastic bottle |
JP2012051623A (en) * | 2010-09-01 | 2012-03-15 | Dainippon Printing Co Ltd | Plastic bottle |
JP2012140156A (en) * | 2010-12-28 | 2012-07-26 | Dainippon Printing Co Ltd | Plastic bottle |
JP2012140154A (en) * | 2010-12-28 | 2012-07-26 | Dainippon Printing Co Ltd | Plastic bottle |
-
1994
- 1994-09-20 JP JP22497194A patent/JPH07285527A/en active Pending
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH10305824A (en) * | 1995-10-31 | 1998-11-17 | Yoshino Kogyosho Co Ltd | Heat-resistant and pressure-resistant self-supporting type hollow container made of synthetic resin |
JP2006103735A (en) * | 2004-10-04 | 2006-04-20 | Toyo Seikan Kaisha Ltd | Synthetic resin-made container |
WO2012029665A1 (en) * | 2010-09-01 | 2012-03-08 | 大日本印刷株式会社 | Plastic bottle |
JP2012051623A (en) * | 2010-09-01 | 2012-03-15 | Dainippon Printing Co Ltd | Plastic bottle |
CN103118950A (en) * | 2010-09-01 | 2013-05-22 | 大日本印刷株式会社 | Plastic bottle |
JP2012140156A (en) * | 2010-12-28 | 2012-07-26 | Dainippon Printing Co Ltd | Plastic bottle |
JP2012140154A (en) * | 2010-12-28 | 2012-07-26 | Dainippon Printing Co Ltd | Plastic bottle |
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