JPH07265906A - Working method for mirror finished material having fine hole and rolling roll therefor - Google Patents

Working method for mirror finished material having fine hole and rolling roll therefor

Info

Publication number
JPH07265906A
JPH07265906A JP6180694A JP6180694A JPH07265906A JP H07265906 A JPH07265906 A JP H07265906A JP 6180694 A JP6180694 A JP 6180694A JP 6180694 A JP6180694 A JP 6180694A JP H07265906 A JPH07265906 A JP H07265906A
Authority
JP
Japan
Prior art keywords
rolling roll
mirror
holes
fine
processing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP6180694A
Other languages
Japanese (ja)
Other versions
JP3384507B2 (en
Inventor
Hiroshi Ike
浩 池
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
RIKEN Institute of Physical and Chemical Research
Original Assignee
RIKEN Institute of Physical and Chemical Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by RIKEN Institute of Physical and Chemical Research filed Critical RIKEN Institute of Physical and Chemical Research
Priority to JP06180694A priority Critical patent/JP3384507B2/en
Publication of JPH07265906A publication Critical patent/JPH07265906A/en
Application granted granted Critical
Publication of JP3384507B2 publication Critical patent/JP3384507B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Metal Rolling (AREA)
  • Reduction Rolling/Reduction Stand/Operation Of Reduction Machine (AREA)
  • Welding Or Cutting Using Electron Beams (AREA)

Abstract

PURPOSE:To provide a working method for a mirror finished surface good at lubricity in press working, not impairing the excellent property as mirror finished surface (brightness, image clarity), having apparent mirror finished surface but fine hole therein and to provide a rolling roll used therefor. CONSTITUTION:Many fine recessed holes 2 apart each other in an interval are formed on the surface of a sintered hard alloy tool 1, by coining of the tool, a projecting part 4 corresponding to the recessed part 2 is transferred on the outer surface of a rolling roll 3, by the rolling roll, a mirror finished material 5 is rolled so as to form many fine recessed parts on the surface. The recessed hole 2 in the sintered hard alloy tool 1 is formed by ion beam machining, a diameter of which is about <=50mum.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、微細穴を有する鏡面材
の加工法とこれに用いる圧延ロールに係わり、更に詳し
くは、プレス加工における潤滑性が良く、かつ見掛け上
は鏡面であるが規則正しい微細な凹孔を有する鏡面材の
加工方法とこの加工に用いる圧延ロールに関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for processing a mirror-finished material having fine holes and a rolling roll used for the same. More specifically, it has good lubricity in press working and has a regular but apparently mirror surface. The present invention relates to a method for processing a mirror surface material having fine concave holes and a rolling roll used for this processing.

【0002】[0002]

【従来の技術】自動車ボディの外板や家庭電気製品の外
装板などの成形加工に用いられる薄板材(例えば鋼板)
では、特に塗装面の乱反射が少なく光沢性に優れている
こと、および写像の歪みが少なく写像性に優れているこ
とが重要であり、これらの光沢性と写像性をあわせて一
般に鮮映性と称している。
2. Description of the Related Art Thin plate materials (for example, steel plates) used for forming outer plates of automobile bodies and exterior plates of household electric appliances.
In particular, it is important that the diffused reflection on the painted surface is small and the gloss is excellent, and the distortion of the image is small and the image clarity is excellent. I am calling it.

【0003】従来、プレス成形時における耐焼付性等を
向上させるため、ショットブラスト法や放電加工法によ
りダル仕上げされた圧延ロールを用いて鋼板表面に粗面
を形成することが一般的に行われている。しかし、かか
る粗面化処理により鋼板表面は不規則な山と谷で構成さ
れた粗面を呈し、この表面に塗装をおこなっても山と谷
の間に塗膜が形成されるにすぎず水平な塗膜は少なく、
結果として粗面化処理により鮮映性が悪化してしまう問
題点があった。
Conventionally, in order to improve seizure resistance and the like during press forming, a rough surface is generally formed on the surface of a steel sheet by using a rolling roll dull-finished by a shot blast method or an electric discharge machining method. ing. However, the roughening treatment causes the steel plate surface to have a rough surface composed of irregular peaks and valleys, and even if painting is performed on this surface, a coating film is only formed between the peaks and valleys and the surface is horizontal. Few coatings,
As a result, there is a problem that the sharpness deteriorates the image clarity.

【0004】かかる問題点を解決するために、レーザー
ビームをチョッパーでパルスビームに変換し、これをレ
ンズを通して回転している圧延ロールの表面に集光し、
ロールの集光部を瞬間的に加熱溶融させて溶融金属のプ
ールを形成し、レーザービームの斜め横から吹き付ける
アシストガスの圧力によって溶融プールを凹状に形成し
て冷却する加工手段が提案され一部で実施されている
(例えば、特開昭62−168602号、特開昭62−
224405号)。
In order to solve such a problem, a laser beam is converted into a pulse beam by a chopper, which is focused through a lens on the surface of a rotating rolling roll,
A processing means has been proposed in which the condensing part of the roll is instantaneously heated and melted to form a pool of molten metal, and the molten pool is formed into a concave shape by the pressure of the assist gas blown obliquely from the side of the laser beam and cooled. (For example, JP-A-62-168602 and JP-A-62-168602).
No. 224405).

【0005】[0005]

【発明が解決しようとする課題】しかし、特開昭62−
168602号、特開昭62−224405号の手段で
は、圧延時に有効に作用する突起の形状を十分に制御で
きず、この圧延ロールで表面が鏡面の素材(以下、鏡面
材)を圧延加工すると、潤滑に有効に作用する凹孔が効
率よく形成されない問題点があった。このため、かかる
鏡面材(製品)をプレス加工する際に、鏡面材表面に潤
滑油を保持することが困難であり、プレス加工における
潤滑性が悪い問題点があった。
However, Japanese Patent Laid-Open No. 62-62
No. 168602 and JP-A No. 62-224405 cannot sufficiently control the shape of the protrusion that effectively acts during rolling, and when a material having a mirror surface on this rolling roll (hereinafter, mirror surface material) is rolled, There is a problem that the concave holes that effectively act on lubrication are not efficiently formed. Therefore, it is difficult to retain the lubricating oil on the surface of the mirror surface material when the mirror surface material (product) is pressed, and there is a problem of poor lubricity in the press processing.

【0006】本発明はかかる問題点を解決するために創
案されたものである。すなわち、本発明の目的は、プレ
ス加工における潤滑性が良く、かつ鏡面としての優れた
特性(光沢、鮮映性)を損なうことなく、見掛け上は鏡
面であるが規則正しい微細穴を有する鏡面材の加工法と
これに用いる圧延ロールを提供することにある。
The present invention was devised to solve such problems. That is, an object of the present invention is to provide a mirror-finished material having good lubricity in press working and excellent mirror-finishing characteristics (gloss, sharpness) without apparently being a mirror surface but having regular fine holes. It is to provide a processing method and a rolling roll used for the processing method.

【0007】[0007]

【課題を解決するための手段】本発明によれば、超硬合
金工具の表面に互いに間隔を隔てた多数の微細な凹孔を
形成し、該工具の圧印により圧延ロールの外表面に前記
凹孔に対応した凸部を形成し、該圧延ロールにより鏡面
材を圧延加工して該表面に多数の微細な凹孔を形成す
る、ことを特徴とする微細穴を有する鏡面材の加工法が
提供される。本発明の好ましい実施例によれば、前記超
硬合金工具の凹孔形成はイオンビーム加工による。
According to the present invention, a large number of minute recessed holes spaced apart from each other are formed on the surface of a cemented carbide tool, and the recesses are formed on the outer surface of the rolling roll by the coining of the tool. A method for processing a mirror-finished material having fine holes, characterized in that a convex portion corresponding to a hole is formed, and the mirror-finished material is rolled by the rolling roll to form a large number of fine recessed holes on the surface. To be done. According to a preferred embodiment of the present invention, the formation of the concave hole in the cemented carbide tool is performed by ion beam machining.

【0008】また、本発明によれば、互いに間隔を隔て
た多数の微細な凸部を外表面に有する、ことを特徴とす
る微細穴を有する鏡面材加工用圧延ロールが提供され
る。本発明の好ましい実施例によれば、前記圧延ロール
の凸部は、互いに間隔を隔てた多数の微細な凹孔を有す
る超硬合金工具の圧印により形成され、前記凹孔はイオ
ンビーム加工により形成され、直径は約50μm以下で
ある。
Further, according to the present invention, there is provided a rolling roll for processing a mirror-finished material having fine holes, characterized in that it has a large number of fine convex portions spaced apart from each other on its outer surface. According to a preferred embodiment of the present invention, the projections of the rolling roll are formed by coining a cemented carbide tool having a large number of minute recesses spaced apart from each other, and the recesses are formed by ion beam processing. And the diameter is about 50 μm or less.

【0009】[0009]

【作用】上記本発明の方法及び装置によれば、圧延ロー
ルの外表面に互いに間隔を隔てた多数の微細な凸部が形
成されるので、この圧延ロールにより表面が鏡面の素材
(鏡面材)を圧延加工することにより、鏡面材の表面に
多数の微細な凹孔を形成することができる。従って、か
かる鏡面材(製品)をプレス加工する際に、鏡面材表面
の凹孔に潤滑油を保持することができ、プレス加工にお
ける潤滑性を高めることができる。
According to the above-described method and apparatus of the present invention, a large number of minute convex portions spaced apart from each other are formed on the outer surface of the rolling roll, so that the rolling roll has a mirror-finished surface (mirror surface material). A large number of fine recessed holes can be formed on the surface of the mirror surface material by rolling. Therefore, when the mirror surface material (product) is pressed, the lubricating oil can be retained in the concave hole on the surface of the mirror surface material, and the lubricity in the press processing can be improved.

【0010】また、本発明の好ましい実施例によれば、
イオンビーム加工により超硬合金工具に凹孔を形成し、
これを圧印により圧延ロールへ転写し、この圧延ロール
により圧延加工することにより、広い面積の鏡面材に微
細な凹孔(例えば直径、約50μm以下、中心間距離、
約150μm以下)を効率よく形成することができる。
According to a preferred embodiment of the present invention,
By forming a concave hole in the cemented carbide tool by ion beam processing,
This is transferred to a rolling roll by coining, and by rolling with this rolling roll, fine concave holes (for example, diameter, about 50 μm or less, center distance,
(About 150 μm or less) can be efficiently formed.

【0011】[0011]

【実施例】以下、本発明の好ましい実施例を図面を参照
して説明する。図1は、本発明の微細穴を有する鏡面材
の加工法を模式的に示す図である。図1において、本発
明の方法は、超硬合金工具1の表面に互いに間隔を隔て
た多数の微細な凹孔2を形成する第1ステップ10と、
工具1の圧印により圧延ロール3の外表面に凹孔2に対
応した凸部4を形成する第2ステップ12と、圧延ロー
ル3により鏡面材5を圧延加工してその表面に多数の微
細な凹孔6を形成する第3ステップ14とからなる。図
1の第1ステップ10において、超硬合金工具1の微細
な凹孔2は、イオンビーム加工により形成される。すな
わち、図1において、真空チャンバー内に超硬合金工具
1を保持し、マスク7の微細穴を通してイオンビーム8
を照射する。かかるイオンビーム加工により、イオンビ
ーム8の照射位置を原子・分子のオーダで除去加工(イ
オンスパッタ除去加工)することができ、照射位置が発
熱することなく多数の微細な凹孔2を形成することがで
きる。なお、本発明の第1ステップ12は、イオンビー
ム加工に限定されるものではなく、電子ビーム加工、レ
ーザエッチング等であってもよい。また、超硬合金工具
1には、工具鋼のような高硬度の材料(例えばWC−C
o)を用い、表面は予め鏡面加工し、かつ十分な硬化処
理を行っておくのがよい。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT A preferred embodiment of the present invention will be described below with reference to the drawings. FIG. 1 is a diagram schematically showing a method of processing a mirror-finished material having fine holes according to the present invention. Referring to FIG. 1, the method of the present invention comprises a first step 10 of forming a large number of minute recessed holes 2 spaced from each other on the surface of a cemented carbide tool 1.
The second step 12 of forming the convex portion 4 corresponding to the concave hole 2 on the outer surface of the rolling roll 3 by the imprinting of the tool 1, and the mirror surface material 5 is rolled by the rolling roll 3 to form a large number of fine concaves on the surface. And a third step 14 of forming the holes 6. In the first step 10 of FIG. 1, the fine recessed holes 2 of the cemented carbide tool 1 are formed by ion beam processing. That is, in FIG. 1, the cemented carbide tool 1 is held in a vacuum chamber, and the ion beam 8 is passed through the fine holes of the mask 7.
Irradiate. By such ion beam processing, the irradiation position of the ion beam 8 can be removed (atomic sputter removal processing) on the order of atoms and molecules, and a large number of minute concave holes 2 can be formed without heat generation at the irradiation position. You can The first step 12 of the present invention is not limited to ion beam processing, but may be electron beam processing, laser etching, or the like. Further, the cemented carbide tool 1 has a high hardness material such as tool steel (for example, WC-C).
It is preferable that the surface is mirror-finished in advance and the surface is subjected to sufficient curing treatment.

【0012】次いで、図1の第2ステップ12におい
て、工具1に圧延ロール3を押付けながら回転させて、
圧印により圧延ロール3の外表面に凹孔2に対応した凸
部4を形成し、更に、第3ステップ14において、圧延
ロール3により鏡面材5を圧延加工する。
Next, in the second step 12 of FIG. 1, the rolling roll 3 is rotated while being pressed against the tool 1,
A convex portion 4 corresponding to the concave hole 2 is formed on the outer surface of the rolling roll 3 by coining, and further, in a third step 14, the mirror surface material 5 is rolled by the rolling roll 3.

【0013】図2は、図1のA部を拡大して示す模式図
である。本発明の方法に用いる圧延ロール3は、図2に
示すように外表面に互いに間隔を隔てた多数の微細な凸
部4を有する。この圧延ロール3の凸部4は、互いに間
隔を隔てた多数の微細な凹孔2を有する超硬合金工具1
の圧印により形成され、超硬合金工具1の凹孔2はイオ
ンビーム加工により形成され、直径は約50μm以下で
あり中心間距離は約150μm以下であるのが好まし
く、最大直径が約30μmであり中心間距離が約130
μmであることが更に好ましい。なお、図2のように、
鏡面材5の両面に凹孔6を圧延加工してもよく、或いは
片面のみに加工してもよい。また、本発明における微細
穴(凹孔)は、図2の凹孔6のように、底のある凹み
(窪み)であってもよく、或いは貫通穴であってもよ
い。
FIG. 2 is a schematic view showing an enlarged part A of FIG. The rolling roll 3 used in the method of the present invention has a large number of fine convex portions 4 spaced from each other on the outer surface as shown in FIG. The convex portion 4 of the rolling roll 3 has a plurality of minute concave holes 2 spaced apart from each other, and thus the cemented carbide tool 1
It is preferable that the concave hole 2 of the cemented carbide tool 1 is formed by ion beam processing, the diameter is about 50 μm or less, the center-to-center distance is about 150 μm or less, and the maximum diameter is about 30 μm. Distance between centers is about 130
More preferably, it is μm. In addition, as shown in FIG.
The concave holes 6 may be rolled on both surfaces of the mirror-finished material 5, or may be processed on only one surface. Further, the fine holes (recessed holes) in the present invention may be recesses (recesses) having a bottom like the recessed holes 6 in FIG. 2 or may be through holes.

【0014】上記本発明の方法及び装置によれば、圧延
ロール3の外表面に互いに間隔を隔てた多数の微細な凸
部4が形成されるので、この圧延ロール3により表面が
鏡面の素材(鏡面材5)を圧延加工することにより、鏡
面材5の表面に多数の微細な凹孔6を形成することがで
きる。従って、かかる鏡面材5(製品)をプレス加工す
る際に、鏡面材表面の凹孔6に潤滑油を保持することが
でき、鏡面材のプレス加工における潤滑性を高めること
ができる。
According to the method and apparatus of the present invention described above, since a large number of minute convex portions 4 spaced from each other are formed on the outer surface of the rolling roll 3, the rolling roll 3 has a mirror-finished surface ( By rolling the mirror-finished material 5), a large number of fine recessed holes 6 can be formed on the surface of the mirror-finished material 5. Therefore, when the mirror surface material 5 (product) is pressed, the lubricating oil can be retained in the concave holes 6 on the surface of the mirror surface material, and the lubricity in the press processing of the mirror surface material can be improved.

【0015】また、本発明の好ましい実施例によれば、
イオンビーム加工により超硬合金工具に凹孔2を形成
し、これを圧印により圧延ロール3へ転写し、この圧延
ロール3により圧延加工することにより、広い面積の鏡
面材に微細な凹孔6(例えば直径、約50μm以下、中
心間距離、約150μm以下)を効率よく形成すること
ができる。
According to a preferred embodiment of the present invention,
A concave hole 2 is formed in a cemented carbide tool by ion beam processing, transferred to a rolling roll 3 by coining, and rolled by this rolling roll 3 to form a fine concave hole 6 ( For example, a diameter of about 50 μm or less and a center-to-center distance of about 150 μm or less) can be efficiently formed.

【0016】図3は、本発明の方法により製作した鏡面
を有する超硬合金工具1の表面拡大図である。この図に
おいて、(A)(B)は、同一の超硬合金工具の表面で
あり、(A)は200倍、(B)は100倍の場合を示
している。また図中短い横線(黒線)は100μmの長
さを示す。工具の材料には超硬材であるWC−Coを用
い、適当なマスクを用いてイオンビーム加工により凹孔
を形成した。この図から明らかなように、凹孔の最大直
径は約30μmであり、かつその中心間距離は約130
μmであった。また、この図からは明らかでないが、こ
の超硬合金工具を拡大せずに目視した場合には、凹孔の
まったくない鏡面と区別することができず、見掛け上は
鏡面であるが規則正しい微細な凹凸を有している。
FIG. 3 is an enlarged surface view of the cemented carbide tool 1 having a mirror surface manufactured by the method of the present invention. In this figure, (A) and (B) are the surfaces of the same cemented carbide tool, (A) shows a case of 200 times, and (B) shows a case of 100 times. The short horizontal line (black line) in the figure indicates a length of 100 μm. WC-Co, which is a superhard material, was used as the material of the tool, and a concave hole was formed by ion beam processing using a suitable mask. As is clear from this figure, the maximum diameter of the concave holes is about 30 μm, and the center-to-center distance is about 130 μm.
was μm. Further, although it is not clear from this figure, when this cemented carbide tool was visually inspected without enlarging it, it could not be distinguished from a mirror surface with no recessed holes, and it was apparently a mirror surface, but with regular fine particles. It has irregularities.

【0017】なお、本発明は上述した実施例に限定され
ず、本発明の要旨を逸脱しない範囲で種々変更できるこ
とは勿論である。
The present invention is not limited to the above-mentioned embodiments, and it goes without saying that various modifications can be made without departing from the gist of the present invention.

【0018】[0018]

【発明の効果】上述したように、本発明の微細穴を有す
る鏡面材の加工法とこれに用いる圧延ロールは、プレス
加工における潤滑性が良く、かつ鏡面としての優れた特
性(光沢、鮮映性)を損なうことなく、見掛け上は鏡面
であるが規則正しい微細穴を有する鏡面材を加工するこ
とができる、等の優れた効果を有する。
As described above, the method for processing a mirror surface material having fine holes of the present invention and the rolling roll used therefor have good lubricity in press working and excellent characteristics as a mirror surface (gloss, sharpness). It has an excellent effect that a mirror surface material having an apparently mirror surface but having regular fine holes can be processed without deteriorating the property).

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の微細穴を有する鏡面材の加工法を模式
的に示す図である。
FIG. 1 is a diagram schematically showing a processing method of a mirror surface material having microscopic holes according to the present invention.

【図2】図1のA部を拡大して示す模式図である。FIG. 2 is a schematic view showing an enlarged part A of FIG.

【図3】本発明の方法により製作した超硬合金工具の表
面拡大図である。
FIG. 3 is a surface enlarged view of a cemented carbide tool manufactured by the method of the present invention.

【符号の説明】[Explanation of symbols]

1 超硬合金工具 2 工具の凹孔 3 圧延ロール 4 凸部 5 鏡面材(製品) 6 鏡面材の凹孔 7 マスク 8 イオンビーム 10 第1ステップ 12 第2ステップ 14 第3ステップ 1 Cemented Carbide Tool 2 Tool Cavity 3 Rolling Roll 4 Convex 5 Mirror Surface Material (Product) 6 Mirror Surface Cavity Hole 7 Mask 8 Ion Beam 10 First Step 12 Second Step 14 Third Step

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 超硬合金工具の表面に互いに間隔を隔て
た多数の微細な凹孔を形成し、該工具の圧印により圧延
ロールの外表面に前記凹孔に対応した凸部を形成し、該
圧延ロールにより鏡面材を圧延加工して該表面に多数の
微細な凹孔を形成する、ことを特徴とする微細穴を有す
る鏡面材の加工法。
1. A plurality of minute concave holes spaced apart from each other are formed on the surface of a cemented carbide tool, and convex portions corresponding to the concave holes are formed on the outer surface of a rolling roll by coining the tool. A method for processing a mirror-finished material having fine holes, characterized in that the mirror-finished material is rolled by the rolling roll to form a large number of fine recessed holes on the surface.
【請求項2】 前記超硬合金工具の凹孔の形成はイオン
ビーム加工による、ことを特徴とする請求項1に記載の
微細穴を有する鏡面材の加工法。
2. The method for processing a mirror-finished material having fine holes according to claim 1, wherein the concave holes of the cemented carbide tool are formed by ion beam processing.
【請求項3】 互いに間隔を隔てた多数の微細な凸部を
外表面に有する、ことを特徴とする微細穴を有する鏡面
材加工用圧延ロール。
3. A roll for processing a mirror-finished material having fine holes, characterized in that it has a large number of fine projections spaced apart from each other on its outer surface.
【請求項4】 前記圧延ロールの凸部は、互いに間隔を
隔てた多数の微細な凹孔を有する超硬合金工具の圧印に
より形成され、前記凹孔はイオンビーム加工により形成
され、直径は約50μm以下である、ことを特徴とする
請求項3に記載の微細穴を有する鏡面材加工用圧延ロー
ル。
4. The convex portion of the rolling roll is formed by coining a cemented carbide tool having a large number of minute concave holes spaced apart from each other, the concave holes being formed by ion beam processing, and having a diameter of about It is 50 micrometers or less, The rolling roll for mirror surface material processing which has the fine hole of Claim 3 characterized by the above-mentioned.
JP06180694A 1994-03-31 1994-03-31 Processing method of mirror material with micro holes Expired - Fee Related JP3384507B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP06180694A JP3384507B2 (en) 1994-03-31 1994-03-31 Processing method of mirror material with micro holes

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP06180694A JP3384507B2 (en) 1994-03-31 1994-03-31 Processing method of mirror material with micro holes

Publications (2)

Publication Number Publication Date
JPH07265906A true JPH07265906A (en) 1995-10-17
JP3384507B2 JP3384507B2 (en) 2003-03-10

Family

ID=13181710

Family Applications (1)

Application Number Title Priority Date Filing Date
JP06180694A Expired - Fee Related JP3384507B2 (en) 1994-03-31 1994-03-31 Processing method of mirror material with micro holes

Country Status (1)

Country Link
JP (1) JP3384507B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000044510A1 (en) * 1999-01-27 2000-08-03 Pechiney Rolled Products, Llc Mechanically textured aluminum alloy sheet

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6153316A (en) * 1998-07-17 2000-11-28 Pechiney Rolled Products Llc Mechanically textured aluminum alloy sheet
WO2000044510A1 (en) * 1999-01-27 2000-08-03 Pechiney Rolled Products, Llc Mechanically textured aluminum alloy sheet

Also Published As

Publication number Publication date
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