JPH07265704A - Production of steam reforming catalyst of methanol - Google Patents

Abstract

PURPOSE:To obtain a steam reforming catalyst of methanol having high activity and excellent durability. CONSTITUTION:A process preparing a molten bath of an Al alloy compsn. wherein Cu content is 5-20atom% and the content of at least one kind of an alloying element AE selected from rare earth elements, Fe, Mn, Pd, Co, V, Ag and Pt is 4-18atom%, a process applying quenching coagulation treatment to the molten bath to obtain a catalyst material and a process applying Al elution treatment to the catalyst material to obtain a powdery catalyst 1 wherein the surface layer 3 on a catalyst nucleus 2 is a mixed layer wherein numberless Cu ultrafine particles and numberless AE ultrafine particles 5 are mutually mixed and dispersed uniformly are used. The Cu ultrafine particles 4 have high activity and the growth of the particles 4 due to high temp. sintering can be obstructed by the AE ultrafine particles 5.

Description

Detailed Description of the Invention

[0001]

TECHNICAL FIELD The present invention relates to a method for producing a catalyst for steam reforming of methanol.

[0002]

2. Description of the Related Art Conventionally, as a method for producing this type of catalyst,
Known methods include a kneading method, a coprecipitation method, a Cu plating method, and a Cu spraying method, but these methods have limitations on the minimum particle size of the catalyst. Therefore, in order to obtain a highly active catalyst that cannot be obtained by the kneading method or the like, Al-C containing 10 atomic% of Cu is used.
a step of preparing a molten alloy having a u alloy composition, a step of subjecting the molten alloy to a rapid solidification treatment to obtain a catalyst material, and
After elution treatment, the surface layer of the catalyst material was
And a step of forming a mixed layer of ultrafine particles and innumerable Cu ₂ O ultrafine particles have been developed.

[0003]

However, since the catalyst according to the conventional method has undergone the rapid solidification treatment, it initially has a relatively large specific surface area and exhibits excellent initial activity in a temperature environment of, for example, about 300 ° C. However, there is a problem in that, if the ultrafine particles are kept for a long time in the temperature environment, a sintering phenomenon occurs between the ultrafine particles and the ultrafine particles become coarse, so that the activity is remarkably reduced.

In view of the above, the present invention has a large specific surface area by changing the Al alloy composition, and therefore has high activity, and also has excellent durability which can maintain the high activity for a long period of time. It is an object of the present invention to provide the above-mentioned manufacturing method capable of obtaining the above.

[0005]

According to the present invention, when a catalyst for steam reforming of methanol is produced, a Cu content of 5 is used.
Atomic% ≤ Cu ≤ 20 atomic%, and rare earth element, F
The content of at least one alloying element AE selected from e, Mn, Pd, Co, V, Ag and Pt is 4 atomic%.
A step of preparing a molten metal having an Al-based alloy composition of ≦ AE ≦ 18 atomic%; a step of subjecting the molten metal to a rapid solidification treatment to obtain a catalyst material;
And a step of obtaining a catalyst in which the surface layer is a mixed layer in which a myriad of Cu-based ultrafine particles and a myriad of alloying element AE-based ultrafine particles are uniformly mixed and dispersed with each other.

[0006]

The catalyst obtained by the above-mentioned means has a large specific surface area and therefore is highly active, because the surface layer thereof has numerous Cu-based ultrafine particles having catalytic ability.

Further, in a high temperature environment, the sintering of Cu-based ultrafine particles is prevented by the alloying element AE-based ultrafine particles, so that the high activity of the catalyst is maintained for a long period of time, and therefore the catalyst has excellent durability. Have.

If the Cu content and the alloying element AE content deviate from the above ranges, a catalyst having the above characteristics cannot be obtained.

[0009]

[Example] Steam reforming of methanol was conducted in the presence of a catalyst.
Based on a chemical reaction of CH ₃ OH + H ₂ O → CO ₂ + 3H ₂ . In this case, the ratio of H ₂ O and CH ₃ OH H ₂ O / CH
₃ OH is set to 0-3.

In the production of the steam reforming catalyst,
The content of Cu is 5 atomic% ≦ Cu ≦ 20 atomic%, and the content of at least one alloying element AE selected from rare earth elements, Fe, Mn, Pd, Co, V, Ag and Pt is 4 atomic%. % AE ≤ 18 atomic%, a step of preparing a molten metal having an Al-based alloy composition, a step of subjecting the molten metal to a rapid solidification treatment to obtain a catalyst material, and a step of subjecting the catalyst material to an aluminum elution treatment to form a surface layer A step of obtaining a catalyst which is a mixed layer in which a myriad of Cu-based ultrafine particles and a myriad of alloying element AE-based ultrafine particles are uniformly mixed and dispersed with each other. When two or more kinds of alloying elements AE are selected, the total amount of the alloying elements AE is the above content.

As the rapid solidification treatment, a single roll method is applied, and the condition is that the diameter of the cooling roll made of Cu is 200 to 200 mm.
300 mm, chill roll speed 2000-4000 rpm
, Quartz nozzle ejection diameter 0.5 mm or less, or 0.5 mm or less vertically, 500 mm horizontally in case of slit shape
Hereafter, the molten metal jet pressure is 0.3 to 1 kgf / cm ² and the chamber internal pressure is 100 to 300 Torr. The catalyst material obtained by applying this single roll method has a ribbon shape.

The metallic structure of the ribbon-shaped catalyst material is, for example,
Al supersaturated solid solution single phase structure, quasicrystalline single phase structure, fine Al
Mixed phase structure of crystalline phase and quasi crystalline phase, mixed phase structure of fine Al crystalline phase and fine Al-based intermetallic compound phase, amorphous single phase structure,
It is a kind selected from a mixed phase structure of an amorphous phase and a fine Al crystal phase, and a mixed phase structure of an amorphous phase, a fine Al crystal phase and a fine Al-based intermetallic compound phase.

The Al elution treatment is carried out by immersing the ribbon-shaped catalyst material in an aqueous solution containing either acid or alkali. As an alkaline aqueous solution, for example, NaOH
When using, the concentration of NaOH is 20-30% by weight
The liquid temperature is 50 to 80 ° C, and the immersion time is 1 to
Each is set for 30 minutes. In this case, the amount of Na is A
It is set to Na: Al = 5: 1 to 50: 1 for 1 volume, which is, for example, 100 ml of 20 to 30% by weight NaO.
This means that about 1 g of the ribbon-shaped catalyst material having the above composition is added to the H aqueous solution.

By this Al elution treatment, the ribbon-shaped catalyst material is usually decomposed into powder, and therefore the catalyst is in powder form, and the surface layer thereof is Cu-based ultrafine particles and alloy element AE.
It becomes a mixed layer of ultrafine particles. This powdery catalyst is washed with ion-exchanged water until Na ions are no longer detected in the filtrate, and then dried. The A
l In the elution process, by adjusting the immersion time,
It is possible for the catalyst to be ribbon-shaped or flaky.

The Cu-based ultrafine particles and the alloying element AE-based ultrafine particles have different shapes depending on the composition.
It has a needle-like shape, a flaky shape, or a spherical shape, and the length of the longest part thereof is about 200 nm or less. In this case, when the metal structure of the catalyst material is an amorphous single-phase structure, the Cu-based and alloying element AE-based ultrafine particles are the finest. Therefore, in order to enhance the activity of the catalyst, the metal structure of the catalyst material is not It is desirable to form a crystalline single-phase structure.

The Cu-based ultrafine particles include, for example, Cu ultrafine particles composed of simple Cu and C composed of Cu ₂ O which is an oxide.
u ₂ O ultrafine particles are included, and these are present alone or in a mixture. In addition, for the alloy element AE-based ultrafine particles,
For example, it includes AE ultrafine particles composed of a simple alloy element AE and AE oxide ultrafine particles which is an oxide of the alloy element AE,
These exist alone or in a mixture. NaO
When an H aqueous solution is used, the alloy element AE-based ultrafine particles may take the form of a hydroxide.

In FIG. 1, a powdery catalyst 1 is composed of a catalyst main body 2 having an Al alloy composition and a surface layer 3, and the surface layer 3 is
It becomes a mixed layer in which innumerable Cu-based ultrafine particles 4 and innumerable alloy element AE-based ultrafine particles 5 are uniformly mixed. Therefore, in the powdery catalyst 1, the surface layer 3 has innumerable C
Since it has the u-based ultrafine particles 4, it has a large specific surface area and is therefore highly active.

Further, in a high temperature environment, the sintering between the Cu-based ultrafine particles 4 is hindered by the alloying element AE-based ultrafine particles 5, so that the high activity of the powdery catalyst 1 is maintained for a long time, and thus the catalyst is 1 has excellent durability.

Example 1 (a) Production of Catalyst Various molten metals having an Al-based alloy composition containing Cu, La, and one selected from Fe, Co, V, Mn, Pd, Ag, or Pt are prepared. Then, each melt was subjected to a rapid solidification treatment applying a single roll method to prepare various ribbon-shaped catalyst materials.

The conditions of the single roll method are as follows: cooling roll diameter 200 mm, cooling roll rotation speed 4000 rpm, quartz nozzle spout size diameter 0.3 mm, molten metal spout pressure.
The pressure is 4 kgf / cm ² , and the chamber internal pressure is 100 Torr.

Next, 0.5 g of ribbon-shaped catalyst material was added.
Al elution treatment was carried out by immersing in 50 ml of 20 wt% NaOH aqueous solution for 30 minutes at 60 ° C., whereby various powdery catalyst examples 1 to 7 were obtained.

For comparison, a melt having an Al-based alloy composition represented by Al ₉₀ Cu ₁₀ (numerical value is atomic%, which is the same in each chemical formula described later) is used, and a single roll method is conducted under the same conditions as described above. Then, Al elution treatment was performed to obtain a powdery catalyst of Comparative Example A.

Tables 1 and 2 show the compositions of the melts for the catalyst examples 1 to 7 and comparative example A, the metal structure of the catalyst material, the Cu system,
The type and specific surface area of the alloy element AE-based ultrafine particles are shown.

[0024]

[Table 1]

[0025]

[Table 2] From Tables 1 and 2, it can be seen that Examples 1 to 7 of the catalyst have a specific surface area equal to or larger than that of Comparative Example A.

FIG. 2 is a photomicrograph showing the metallographic structure of the surface of Example 4 of the catalyst. As shown in FIG. 2, innumerable ultrafine particles having a longest length of about 200 nm or less are dispersed on the main body of the catalyst. it is obvious. (B) Temperature and Activity of Catalyst 0.1 g of the catalyst of Example 1 was weighed and placed in a constant pressure fixed bed flow reactor to form a catalyst layer. Then, using the temperature of the catalyst layer as the activity evaluation temperature, 125, 149, 19
3,240,286,334,383,432,482
The temperature is set to 0 ° C., and H ₂ O: CH ₃ OH =
A 1: 1 mixed solution was circulated to perform steam reforming of methanol.

The activity of Example 1 of the catalyst was evaluated by analyzing the generated gas with a gas chromatograph and evaluating the hydrogen gas generation rate. Hydrogen gas generation rate is the amount of hydrogen gas generated in 1 minute by 1 kg of catalyst, therefore, liter / kg · min
Is represented by Similar tests were performed on Catalyst Examples 2-4 and Comparative Example A.

FIG. 3 shows the test results. Point (1) in the figure
-(4) and (A) are catalyst examples 1-4 and comparative example A
Respectively correspond to. As is clear from FIG. 3, at the activity evaluation temperature of 300 to 400 ° C., the catalyst examples 1 and 2 have higher activity than the comparative example A, which means that when hydrogen gas is used as the fuel for the intermediate temperature fuel cell. Optimal. The catalysts of Examples 3 and 4 exhibit an activity substantially equal to that of Comparative Example A at the activity evaluation temperature. (C) Durability of catalyst 0.1 g of Catalyst Example 1 was weighed and placed in the constant pressure fixed bed flow reactor to form a catalyst layer. And
The temperature of the catalyst layer is set to 300 ° C., which is the activity evaluation temperature, and a mixed solution of H ₂ O: CH ₃ OH = 1: 1 is circulated in the catalyst layer to perform steam reforming of methanol. The initial activity of 1 (the generation rate of hydrogen gas at the activity evaluation temperature of 300 ° C. in FIG. 3), the activity after 24 hours and the activity after 48 hours were examined. Further, the same test was performed for catalyst examples 2 to 5 and comparative example A.

Table 3 shows the test results.

[0030]

[Table 3] As is clear from Table 3, Examples 1 to 5 of the catalysts have high initial activity, and the activity thereof does not change substantially even after 48 hours, so that they have high activity and excellent durability. I understand. Comparative Example A has a high initial activity, but its activity drops significantly over time and is therefore extremely poor in durability.

Example 2 (a) Manufacture of Catalyst Various melts having an Al-based alloy composition containing Cu and La were prepared,
Next, various ribbon-shaped catalyst materials were produced by subjecting each molten metal to a rapid solidification treatment applying a single roll method.

The condition of the single roll method is the same as in Example 1 except that the diameter of the cooling roll is 200 mm and the number of rotations of the cooling roll is 4
000 rpm, size of jet nozzle of quartz nozzle, diameter 0.3 mm,
Molten metal jet pressure 0.4 kgf / cm ² , chamber pressure 10
It is 0 Torr.

Then, as in Example 1, 0.5 g of ribbon-shaped catalyst material was added at 60 ° C. to 50 ml of 20 wt% NaOH.
It was immersed in an aqueous solution for 30 minutes to perform Al elution treatment, and thereby Examples 1 to 5 of various powdery catalysts were obtained.

Table 4 shows the composition of the molten metal for the catalyst examples 1 to 5 and the comparative example A, the metal structure of the catalyst material, the Cu system,
The type and specific surface area of the alloy element AE-based ultrafine particles are shown.

[0035]

[Table 4] From Table 4, it can be seen that Examples 1 to 5 of the catalyst have a specific surface area larger than that of Comparative Example A. (B) Temperature and Activity of Catalyst As in Example 1, 0.1 g of the catalyst of Example 1 was weighed and placed in a constant pressure fixed bed flow reactor to form a catalyst layer. Then, using the temperature of the catalyst layer as the activity evaluation temperature, 12
5, 149, 193, 240, 286, 334, 38
Set the temperature to 3,432,482 ° C and add H to the catalyst layer.
A mixed solution of ₂ O: CH ₃ OH = 1: 1 was circulated to perform steam reforming of methanol.

The activity of the catalyst of Example 1 was evaluated in the same manner as in Example 1 by analyzing the generated gas with a gas chromatograph and measuring the hydrogen gas generation rate (liter / kg · min). Similar tests were also conducted on catalyst examples 2, 4 and 5.

FIG. 4 shows the test results. In the figure, points (1), (2), (4), (5) and (A) correspond to catalyst examples 1, 2, 4, 5 and comparative example A, respectively. As is clear from FIG. 4, activity evaluation temperatures of 300 to 4
At 00 ° C., catalyst examples 1, 2, 4, 5 are more active than comparative example A, which is optimal when hydrogen gas is used as the fuel for the medium temperature fuel cell as in example 1. . (C) Durability of catalyst As in Example 1, 0.1 g of the catalyst of Example 4 was weighed and placed in the constant pressure fixed bed flow reactor to form a catalyst layer. Then, the temperature of the catalyst layer is 3 which is the activity evaluation temperature.
The catalyst layer was set to 00 ° C. and H ₂ O: CH ₃ O was added to the catalyst layer.
The initial activity of the catalyst of Example 4 (hydrogen gas generation rate at an activity evaluation temperature of 300 ° C. in FIG. 4) and the activity after 24 hours were passed by performing steam reforming of methanol by circulating a mixed solution of H = 1: 1. And when the activity after 48 hours was examined,
The results shown in Table 5 were obtained.

[0038]

[Table 5] As is clear from Table 5, Example 4 of the catalyst has a high initial activity, and its activity does not change substantially even after 48 hours, so that it has a high activity and an excellent durability. .

Example 3 (a) Production of catalyst Cu and Fe, Co, V, Mn, Pd, Pt or Y
Various melts having an Al-based alloy composition containing one kind selected from (rare earth elements) were prepared, and then each melt was subjected to a rapid solidification treatment by applying a single roll method to prepare various ribbon-shaped catalyst materials.

As in Example 1, the condition of the single roll method is that the diameter of the cooling roll is 200 mm and the number of rotations of the cooling roll is 4
000 rpm, size of jet nozzle of quartz nozzle, diameter 0.3 mm,
Molten metal jet pressure 0.4kgf / cm ² , chamber pressure 1
00 Torr.

Then, as in Example 1, 0.5 g of ribbon-shaped catalyst material was added at 60 ° C. to 50 ml of 20 wt% NaOH.
It was dipped in an aqueous solution for 30 minutes and subjected to Al elution treatment, thereby obtaining Examples 1 to 7 of various powdery catalysts.

Table 6 shows the compositions of the melts for the catalyst examples 1 to 7 and the comparative example A, the metal structure of the catalyst material, the Cu system,
The type and specific surface area of the alloy element AE-based ultrafine particles are shown.

[0043]

[Table 6] From Table 6 it can be seen that catalyst examples 1-5 have a specific surface area greater than comparative example A. Catalysts 6 and 7 have smaller specific surface areas than Comparative Example A. (B) Temperature and Activity of Catalyst As in Example 1, 0.1 g of the catalyst of Example 1 was weighed and placed in a constant pressure fixed bed flow reactor to form a catalyst layer. Then, using the temperature of the catalyst layer as the activity evaluation temperature, 12
5, 149, 193, 240, 286, 334, 38
Set the temperature to 3,432,482 ° C and add H to the catalyst layer.
A mixed solution of ₂ O: CH ₃ OH = 1: 1 was circulated to perform steam reforming of methanol.

The activity of the catalyst of Example 1 was evaluated in the same manner as in Example 1 by analyzing the generated gas with a gas chromatograph and measuring the hydrogen gas generation rate (liter / kg · min). Also, the same test was performed on Examples 2 to 5 of the catalyst.

FIG. 5 shows the test results. Point (1) in the figure
-(5) and (A) correspond to Examples 1-5 of the catalyst and Comparative Example A, respectively. As is clear from FIG. 5, at the activity evaluation temperature of 300 to 400 ° C.
Nos. 2 and 5 have higher activities than Comparative Example A, which is optimal when hydrogen gas is used as the fuel for the intermediate temperature fuel cell, as in Example 1. The catalysts of Examples 3 and 4 exhibit an activity substantially equal to that of Comparative Example A at the activity evaluation temperature. (C) Durability of catalyst In the same manner as in Example 1, 0.1 g of the catalyst of Example 1 was weighed and placed in the constant pressure fixed bed flow reactor to form a catalyst layer. Then, the temperature of the catalyst layer is 30 which is the activity evaluation temperature.
The catalyst layer was set to 0 ° C. and H ₂ O: CH ₃ OH was added to the catalyst layer.
= 1: 1 mixed solution was passed through to perform steam reforming of methanol, and the initial activity of the catalyst of Example 1 (hydrogen gas generation rate at an activity evaluation temperature of 300 ° C. in FIG. 5), activity after 24 hours, and The activity was examined after 48 hours. Also, the same test was performed on Examples 2 to 5 of the catalyst.

Table 7 shows the test results.

[0047]

[Table 7] As is clear from Table 7, Examples 1 to 5 of the catalysts have high initial activity, and their activity does not change substantially even after 48 hours, so that they have high activity and excellent durability. I understand.

Example 4 (a) Production of Catalyst A molten metal having an Al-based alloy composition containing Cu, La and Fe was prepared, and then the molten metal was subjected to rapid solidification treatment by applying a single roll method to form a ribbon A crystalline catalyst material was prepared.

The condition of the single roll method is the same as in Example 1 except that the diameter of the cooling roll is 200 mm and the number of rotations of the cooling roll is 4
000 rpm, size of jet nozzle of quartz nozzle, diameter 0.3 mm,
Molten metal jet pressure 0.4kgf / cm ² , chamber pressure 1
00 Torr.

Then, as in Example 1, 0.5 g of the ribbon-shaped amorphous catalyst material was added at 60 ° C. to 50 ml of 20 wt% N.
Immerse in an aOH aqueous solution for 30 minutes to perform Al elution treatment,
This obtained Example 1 of a powdery catalyst.

For comparison, the ribbon-shaped amorphous catalyst material was heat-treated in vacuum at 450 ° C. for 24 hours to prepare a ribbon-shaped crystalline catalyst material, and then the crystalline catalyst material was made of Al similar to the above. Comparative example B of powdered catalyst after elution treatment
I got

Further, the molten metal having the Al-based alloy composition is gradually cooled to prepare an ingot, and then the ingot is subjected to a pulverization treatment to prepare a powdery catalyst material having a particle size of 50 μm or less, and then the powdery catalyst material. Al elution treatment similar to the above was performed to obtain a powdery catalyst comparative example C.

Table 8 shows the composition of the molten metal for the catalyst of Example 1, Comparative Examples B and C, the metal structure of the catalyst material, and Cu.
The type and specific surface area of AE type ultrafine particles of alloy type and alloying elements are shown.

[0054]

[Table 8] It can be seen from Table 8 that catalyst example 1 has a specific surface area equal to or greater than that of comparative examples B and C. (B) Temperature and Activity of Catalyst As in Example 1, 0.1 g of the catalyst of Example 1 was weighed and placed in a constant pressure fixed bed flow reactor to form a catalyst layer. Then, using the temperature of the catalyst layer as the activity evaluation temperature, 12
5, 149, 193, 240, 286, 334, 38
Set the temperature to 3,432,482 ° C and add H to the catalyst layer.
A mixed solution of ₂ O: CH ₃ OH = 1: 1 was circulated to perform steam reforming of methanol.

The activity of the catalyst of Example 1 was evaluated in the same manner as in Example 1 by analyzing the generated gas with a gas chromatograph and evaluating the hydrogen gas generation rate (liter / kg · min). Further, the same test was performed on Comparative Examples B and C.

FIG. 6 shows the test results. In the figure, points (1), (B) and (C) correspond to Example 1 of the catalyst, Comparative Example B and Comparative Example C, respectively. As is clear from FIG. 5, in the temperature range where the activity evaluation temperature is higher than 150 ° C., it is understood that the catalyst example 1 has higher activity than the comparative examples B and C. This is because the metal structure of the catalyst material in Example 1 of the catalyst is an amorphous single-phase structure, and therefore, the Cu ₂ O ultrafine particles and the La (OH) ₃ ultrafine particles are extremely miniaturized. (C) Durability of catalyst In the same manner as in Example 1, 0.1 g of the catalyst of Example 1 was weighed and placed in the constant pressure fixed bed flow reactor to form a catalyst layer. Then, the temperature of the catalyst layer is 3 which is the activity evaluation temperature.
The catalyst layer was set to 00 ° C. and H ₂ O: CH ₃ O was added to the catalyst layer.
The initial activity of Example 1 of the catalyst (hydrogen gas generation rate at an activity evaluation temperature of 300 ° C. in FIG. 6), the activity after 24 hours have passed, by carrying out steam reforming of methanol by circulating a mixed solution of H = 1: 1. The activity was examined after 48 hours. Further, the same test was performed on Comparative Examples B and C.

Table 9 shows the test results.

[0058]

[Table 9] As is clear from Table 9, Example 1 of the catalyst has a high initial activity, and its activity does not change substantially even after 48 hours, so that it is highly active and has excellent durability. . Comparative Examples B and C have low initial activity, and their activity extremely decreases with time, and therefore, both activity and durability are extremely low.

[0059]

According to the present invention, by adopting the means specified above, it is possible to obtain a catalyst for steam reforming of methanol which is highly active and has excellent durability.

[Brief description of drawings]

FIG. 1 is a schematic sectional view of a main part of a powdery catalyst.

FIG. 2 is a micrograph showing the metal structure of the catalyst surface.

FIG. 3 is a graph of a first example showing the relationship between the activity evaluation temperature and the hydrogen gas generation rate.

FIG. 4 is a graph of a second example showing the relationship between the activity evaluation temperature and the hydrogen gas generation rate.

FIG. 5 is a graph of a third example showing the relationship between the activity evaluation temperature and the hydrogen gas generation rate.

FIG. 6 is a graph of a fourth example showing the relationship between the activity evaluation temperature and the hydrogen gas generation rate.

[Explanation of symbols]

 DESCRIPTION OF SYMBOLS 1 catalyst 2 catalyst main body 3 surface layer 4 Cu-based ultrafine particles 5 alloying element AE-based ultrafine particles

 ─────────────────────────────────────────────────── ─── Continuation of the front page (71) Applicant 000000240 Chichibu Onoda Co., Ltd. 2-14-1, Nishishimbashi, Minato-ku, Tokyo (71) Applicant 000005326 Honda Motor Co., Ltd. 1-1-1, Minami-Aoyama, Minato-ku, Tokyo No. (72) Inventor Katsutoshi Nozaki 1-4-1 Chuo, Wako-shi, Saitama, Ltd., Honda R & D Co., Ltd. (72) Inventor Ken Masumoto 3-8-22, Uesugi, Aoba-ku, Sendai City, Miyagi Prefecture (72) Inventor Akihisa Inoue Kawauchi Mubanen, Aoba-ku, Sendai-shi, Miyagi Kawauchi Housing 11-806 (72) Inventor Hideo Fukui 3-15-15 Wakabayashi, Wakabayashi-ku, Sendai-shi, Miyagi Inventor Masami Uzawa 189, Honsanrizuka, Narita-shi, Chiba -3-B-201

Claims (3)

[Claims] 1. The content of Cu is 5 atomic% ≦ Cu ≦ 20 atomic%, and rare earth elements, Fe, Mn, Pd, and C are used.
The content of at least one alloying element AE selected from o, V, Ag and Pt is 4 atom% ≦ AE ≦ 18 atom%
A step of preparing a molten metal having an Al-based alloy composition, a step of subjecting the molten metal to a rapid solidification treatment to obtain a catalyst material, and a step of subjecting the catalytic material to an aluminum elution treatment to form a Cu layer having an infinite number of surface layers.
A method for producing a catalyst for steam reforming of methanol, which comprises: a step of obtaining a catalyst, which is a mixed layer in which ultrafine particles of a system and numerous ultrafine particles of an alloying element AE are uniformly mixed and dispersed with each other. . 2. The method for producing a steam reforming catalyst for methanol according to claim 1, wherein the Al elution treatment is performed by immersing the catalyst material in an aqueous solution containing one of acid and alkali. 3. The method for producing a catalyst for steam reforming of methanol according to claim 1, wherein the metal structure of the catalyst material is an amorphous single phase structure.