JPH0726051B2 - Liquid painting material - Google Patents
Liquid painting materialInfo
- Publication number
- JPH0726051B2 JPH0726051B2 JP62019475A JP1947587A JPH0726051B2 JP H0726051 B2 JPH0726051 B2 JP H0726051B2 JP 62019475 A JP62019475 A JP 62019475A JP 1947587 A JP1947587 A JP 1947587A JP H0726051 B2 JPH0726051 B2 JP H0726051B2
- Authority
- JP
- Japan
- Prior art keywords
- parts
- water
- liquid
- painting material
- calcium carbonate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Description
【発明の詳細な説明】 （産業上の利用分野） 本発明は水性版画インキ，水彩絵具といった液状画材に
関するものであり，更に詳細には，版画，絵画といった
作品とした場合に優れた発色を有し，耐摩耗性に優れた
液状画材に関するものである。DETAILED DESCRIPTION OF THE INVENTION (Industrial field of application) The present invention relates to a liquid painting material such as a water-based printing ink or watercolor paint. More specifically, it has excellent coloring when it is used as a print or painting. However, the present invention relates to a liquid painting material having excellent wear resistance.
（従来の技術） 従来の水性版画インキ，水彩絵具といった液状画材は，
顔料，水溶性樹脂，水等の外に，流動性，着色力，隠蔽
性，光沢等の調整のために体質顔料としてアルミナホワ
イト，硫酸バリウム，シリカ等を用いている。(Prior Art) Conventional water-based printing inks, liquid paints such as watercolors,
In addition to pigments, water-soluble resins, water, etc., alumina white, barium sulfate, silica, etc. are used as extender pigments in order to adjust fluidity, coloring power, hiding power, gloss and the like.
（発明が解決しようとする問題点） しかしながら，上記従来の液状画材を用いている体質顔
料は，該液状画材を用いた絵画，版画等の作品におい
て，発色を低下させたり，塗膜の耐摩耗性を低下させて
しまうという欠点を有していた。(Problems to be solved by the invention) However, the extender pigment using the above-mentioned conventional liquid-state painting material reduces the color development and wear resistance of the coating film in works such as paintings and prints using the liquid-state painting material. It has a drawback that it deteriorates the property.
（問題点を解決するための手段 そこで本発明者等は，発色の低下が少なく，かつ，塗膜
の耐摩性の低下が少ない体質顔料を種々検討した結果本
発明を完成したものであり，即ち本発明は，顔料と，体
質顔料と，水溶性樹脂と，水とより少なくともなる液状
画材において，該体質顔料がアビエチン酸変性炭酸カル
シウムを少なくとも含んでいることを特徴とする液状画
材を要旨とするものである。(Means for Solving the Problems) Therefore, the inventors of the present invention have completed the present invention as a result of various studies on extender pigments in which the reduction in color development is small and the abrasion resistance of the coating film is small. The gist of the present invention is a liquid painting material comprising at least a pigment, an extender pigment, a water-soluble resin, and water, wherein the extension pigment contains at least abietic acid-modified calcium carbonate. It is a thing.
以下本発明を詳細に説明する。The present invention will be described in detail below.
顔料は着色材として使用するものであり，従来水彩絵
具，水性版画インキに用いられているカーボンブラッ
ク，酸化チタン，ベンガラ，黄土，ハンザエローG,同10
G,バーントシェンナー，レーキレッド，カーミン3B,同6
B,群青，フタロシアニンブルー，フタロシアニングリー
ン等の有機及び無機顔料を単独若しくは複数混合して使
用でき，その使用量は液状画材全量に対して５〜35重量
％が好ましい。水溶性樹脂は，定着剤及び展色剤として
用いるものであり，にかわ，アラビアガム，デキストリ
ン，ポリビニルアルコール等の水溶性樹脂の外，ポリ
（メタ）アクリル酸，スチレン−アクリル酸共重合体，
スチレン−マレイン酸共重合体，ポリマレイン酸，ポリ
フマル酸，ロジン変形マレイン酸樹脂のアンモニウム，
アミン及びアルカリ金属塩等の電離型水溶性樹脂や，該
電離型水溶性樹脂のフリー酸とアルカノ−ルアミン類と
の併用により水可溶とした樹脂等を使用でき，その使用
量は液状画材全量に対して５〜20重量％が好ましい。The pigment is used as a coloring material. Carbon black, titanium oxide, red iron oxide, ocher, Hansa Yellow G, 10 used in conventional watercolors and water-based printing inks.
G, Burnt Schenner, Rake Red, Carmin 3B, 6
Organic and inorganic pigments such as B, ultramarine blue, phthalocyanine blue and phthalocyanine green can be used alone or in combination, and the amount thereof is preferably 5 to 35% by weight based on the total amount of the liquid painting material. The water-soluble resin is used as a fixing agent and a color-developing agent. In addition to water-soluble resins such as glue, gum arabic, dextrin, and polyvinyl alcohol, poly (meth) acrylic acid, styrene-acrylic acid copolymer,
Styrene-maleic acid copolymer, polymaleic acid, polyfumaric acid, ammonium rosin modified maleic acid resin,
Ionizable water-soluble resins such as amines and alkali metal salts, and water-soluble resins that can be used by combining the free acid of the ionizable water-soluble resin with alkanol amines can be used. 5 to 20% by weight is preferable.
本発明の骨子であるアビエチン酸変性炭酸カルシウムは
発色の低下及び塗膜の耐摩耗性の低下を防止する為に体
質顔料の一部あるいは全部として用いるものであり，炭
酸カルシウムの表面に，該炭酸カルシウムの２〜３重量
％のアビエチン酸をドライブレンド等の処理方法により
コーティングしたものを用い，その使用量は液状画材全
量に対し１〜35重量％が好ましい。The abietic acid-modified calcium carbonate, which is the essence of the present invention, is used as part or all of the extender pigment in order to prevent the deterioration of color development and the abrasion resistance of the coating film. Abietic acid of 2 to 3% by weight of calcium is coated by a treatment method such as dry blending, and the amount used is preferably 1 to 35% by weight based on the total amount of the liquid painting material.
尚，上記成分以外に必要に応じて，グリコール類，エチ
レングリコール等の高沸点水溶性有機溶剤や，界面活性
剤，防腐・防カビ剤，防錆剤等の添加剤を適宜用いても
よい。In addition to the above components, high boiling water-soluble organic solvents such as glycols and ethylene glycol, and additives such as surfactants, antiseptic / antifungal agents, and rust preventives may be appropriately used, if necessary.
又，本発明の液状画材は上記成分を三本ロールミルや横
型ボールミル等の分散機にて混合分散することにより容
易に得ることができる。The liquid paint of the present invention can be easily obtained by mixing and dispersing the above components with a disperser such as a three-roll mill or a horizontal ball mill.
（作用） 本発明の液状画材が何故優れた発色を有し，耐摩耗性に
優れているのかについては以下の様に推察される。(Function) The reason why the liquid painting material of the present invention has excellent color development and excellent abrasion resistance is presumed as follows.
本発明に使用するアビエチン酸変性炭酸カルシウムはア
ビエチン酸が炭酸カルシウムの表面を被っているので，
従来の未処理の体質顔料に比べ表面における乱反射が少
なくなるので発色の低下が少なくなり，又，表面がアビ
エチン酸で被われているが故に摩擦抵抗が少なくなり耐
摩耗性に優れると推察される。In the abietic acid-modified calcium carbonate used in the present invention, since abietic acid covers the surface of calcium carbonate,
It is presumed that the diffuse reflection on the surface is less than that of conventional untreated extender pigments, and thus the decrease in color development is less, and because the surface is covered with abietic acid, the friction resistance is less and the abrasion resistance is excellent. ..
（実施例） 以下本発明を実施例により更に詳細に説明するが，実施
例，比較例中単に「部」とあるものは特にことわらない
限り「重量部」を示すものとする。(Examples) Hereinafter, the present invention will be described in more detail with reference to Examples. In Examples and Comparative Examples, "parts" simply means "parts by weight" unless otherwise specified.
実施例1.（水性版画インキ） カーボンブラック 10部 アビエチン酸変性炭酸カルシウム 15部 ロジン変性マレイン酸樹脂 15部 ジメチルエタノールアミン ５部 グリセリン ７部 トリエチレングリコール 28部 エチルアルコール ５部 水 15部 上記各成分をラボミキサーに入れ,1時間プレミキシング
した後，三本ロールミルにて２回通しを行ない，黒色の
水性版画インキを得た。Example 1 (Aqueous printing ink) Carbon black 10 parts Abietic acid-modified calcium carbonate 15 parts Rosin-modified maleic acid resin 15 parts Dimethylethanolamine 5 parts Glycerin 7 parts Triethylene glycol 28 parts Ethyl alcohol 5 parts Water 15 parts Each of the above components Was put in a lab mixer, premixed for 1 hour, and then passed through a three-roll mill twice to obtain a black aqueous print ink.
比較例1. 実施例１のアビエチン酸変性炭酸カルシウム15部を炭酸
カルシウム15部にかえた以外は実施例１と同様になして
黒色の版画インキを得た。Comparative Example 1. A black print ink was obtained in the same manner as in Example 1 except that 15 parts of the abietic acid-modified calcium carbonate of Example 1 was replaced with 15 parts of calcium carbonate.
実施例2.（水彩絵具） 不溶性アゾ顔料（C.I.No.12485） 10部 アビエチン酸変性炭酸カルシウム 20部 硫酸バリウム 20部 酸化ケイ素 ３部 グリセリン ８部 アラビアガム 10部 焙焼デキストリン 10部 水 19部 上記各成分をラボミキサーに入れ,15分間撹拌した後，
三本ロールミルにて２回通しを行ない，赤色の水彩絵具
を得た。Example 2 (Watercolor paint) Insoluble azo pigment (CI No. 12485) 10 parts Abietic acid-modified calcium carbonate 20 parts Barium sulfate 20 parts Silicon oxide 3 parts Glycerin 8 parts Arabic gum 10 parts Roasted dextrin 10 parts Water 19 parts above Put the ingredients in the lab mixer, stir for 15 minutes,
It was passed through a three-roll mill twice to obtain red watercolor paint.
比較例2. 実施例２のアビエチン酸変性炭酸カルシウム20部を炭酸
カルシウム20部にかえた以外は実施例２と同様になして
赤色の水彩絵具を得た。Comparative Example 2. A red watercolor paint was obtained in the same manner as in Example 2, except that 20 parts of calcium carbonate modified with abietic acid of Example 2 was replaced with 20 parts of calcium carbonate.
（発明の効果） 上記実施例1,2及び比較例1,2について試験を行なった結
果を表に示す。(Effects of the Invention) The results of the tests conducted on the above Examples 1 and 2 and Comparative Examples 1 and 2 are shown in the table.
発色…各液状画材をJISP3201上質紙Ａにアプリケータ
ーにて0.76mm厚に均一に塗布し乾燥したものを試験片と
して色差計（スガ試験機（株）製）にて彩度及び刺激値
（Ｙ値）を測定した。 Color development: Each liquid material was applied uniformly to JISP3201 woodfree paper A with an applicator to a thickness of 0.76 mm and dried, and used as test pieces with a color difference meter (manufactured by Suga Test Instruments Co., Ltd.) for saturation and stimulation values (Y value). ) Was measured.
彩度：数値の大きい程発色が優れている 刺激値（Ｙ値）：数値が低い程黒色度が高い 耐摩耗性 上記発色の試験に用いた試験片に,JISP3201筆記用紙Ａ
をのせ,500g荷重を加え左右に10回移動し，上にのせた
該筆記用紙を目視観察する。Saturation: The higher the value, the better the color development. Stimulus value (Y value): The lower the value, the higher the blackness. Abrasion resistance. The test piece used for the above-mentioned color development test was JIS P3201 Writing Paper A.
Put a load of 500 g on it and move it to the left and right 10 times, and visually observe the writing paper placed on it.
○：色がまったくつかない ×：色が少し移る 以上詳細に説明した様に，本発明に係る液状画材は，水
性版画インキ，水彩絵具として用いた場合，優れた発色
を有し耐摩耗性に優れた版画，絵画が得られる優れたも
のである。◯: No color is attached ×: Color is slightly transferred As described above in detail, the liquid drawing material according to the present invention has excellent color development and abrasion resistance when used as a water-based printing ink or watercolor paint. It's an excellent print and painting.
Claims (1)
より少なくともなる液状画材において，該体質顔料がア
ビエチン酸変性炭酸カルシウムを少なくとも含んでいる
ことを特徴とする液状画材。1. A liquid painting material comprising at least a pigment, an extender pigment, a water-soluble resin, and water, wherein the extender pigment contains at least abietic acid-modified calcium carbonate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62019475A JPH0726051B2 (en) | 1987-01-29 | 1987-01-29 | Liquid painting material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62019475A JPH0726051B2 (en) | 1987-01-29 | 1987-01-29 | Liquid painting material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63186781A JPS63186781A (en) | 1988-08-02 |
| JPH0726051B2 true JPH0726051B2 (en) | 1995-03-22 |
Family
ID=12000355
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62019475A Expired - Lifetime JPH0726051B2 (en) | 1987-01-29 | 1987-01-29 | Liquid painting material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0726051B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10633259B2 (en) * | 2016-01-14 | 2020-04-28 | Omya International Ag | Wet surface treatment of surface-modified calcium carbonate |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2015089930A (en) * | 2013-11-07 | 2015-05-11 | 株式会社サクラクレパス | Finger pigment |
| JP6219333B2 (en) | 2015-03-31 | 2017-10-25 | 富士フイルム株式会社 | Pigment dispersion and method for producing the same |
-
1987
- 1987-01-29 JP JP62019475A patent/JPH0726051B2/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10633259B2 (en) * | 2016-01-14 | 2020-04-28 | Omya International Ag | Wet surface treatment of surface-modified calcium carbonate |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS63186781A (en) | 1988-08-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |