JPH07237286A - Decorative sheet and its production - Google Patents

Decorative sheet and its production

Info

Publication number
JPH07237286A
JPH07237286A JP2945594A JP2945594A JPH07237286A JP H07237286 A JPH07237286 A JP H07237286A JP 2945594 A JP2945594 A JP 2945594A JP 2945594 A JP2945594 A JP 2945594A JP H07237286 A JPH07237286 A JP H07237286A
Authority
JP
Japan
Prior art keywords
decorative sheet
ink
resin
electron beam
liquid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2945594A
Other languages
Japanese (ja)
Inventor
Ryotaro Sato
亮太郎 佐藤
Eiji Hinishi
英二 日西
Katsunori Nishijima
克典 西島
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toppan Inc
Original Assignee
Toppan Printing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toppan Printing Co Ltd filed Critical Toppan Printing Co Ltd
Priority to JP2945594A priority Critical patent/JPH07237286A/en
Publication of JPH07237286A publication Critical patent/JPH07237286A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To obtain a decorative sheet having resistance to solvent, resistance to chemicals, rub resistance, and wear resistance while stably repelling a resin to be repelled by liquid repellent ink and imparting a three-dimensional feeling harmonious with a picture pattern and its production method. CONSTITUTION:A decorative sheet is formed by providing a printing layer 6 of ink made of an electron beam- or ultraviolet radiation-curing resin having a liquid repellency and a resin layer 7 repelled by the printing layer on a decorative sheet substrate. In the production method of the decorative sheet, ink made of an electron beam- or ultraviolet radiation-curing resin having a liquid repellency is printed on the decorative sheet substrate, the ink is cured by an electron beam- or ultraviolet radiation, and the resin 7 to be repelled is applied all over the surface.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は家具、器物の表面や、建
築物の内装材の表面等に使用する化粧シート及びその製
造方法に関し、特に撥液性インキを使用し、絵柄に同調
した凹凸を有する立体感のある化粧シートに関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a decorative sheet for use on the surface of furniture, articles and interior materials of buildings, and a method for producing the same, and more particularly, it uses a liquid-repellent ink and has unevenness in synchronization with the design. And a decorative sheet having a three-dimensional effect.

【0002】[0002]

【従来の技術】従来、前記のような目的に用いられる化
粧シートは、図1に示すように、基材1に必要に応じて
べたインキ層2、絵柄インキ層3を印刷した後、油性ま
たは水性の撥液性インキ4を印刷し、この上全面に前記
撥液性インキにはじかれる樹脂5を塗布し、撥液性イン
キの部分をはじかせて、硬化させたものであった。
2. Description of the Related Art Conventionally, as shown in FIG. 1, a decorative sheet used for the above-mentioned purpose has an oily property after a solid ink layer 2 and a pattern ink layer 3 are printed on a substrate 1 as necessary. The water-repellent ink 4 was printed, and the resin 5 that was repelled by the liquid-repellent ink was applied to the entire surface of the ink, and the liquid-repellent ink portion was repelled and cured.

【0003】ここで撥液性インキにはじかれる樹脂は、
立体感を設けるという効果以外に、化粧シート基材に通
常あるベたインキや絵柄インキがもっていない耐溶剤
性、耐薬品性、ラビング性、耐摩耗性等の物性を補うと
いう効果も、あわせ持つものである。
Here, the resin that is repelled by the liquid repellent ink is
In addition to the effect of providing a three-dimensional effect, it also has the effect of supplementing physical properties such as solvent resistance, chemical resistance, rubbing resistance, and abrasion resistance, which are not normally found in solid ink and pattern ink on decorative sheet base materials. It is a thing.

【0004】しかし、この化粧シート基材に撥液性イン
キを印刷する方法では、撥液性インキがはじかれる樹脂
をはじいてしまうため、撥液性インキが真下の化粧シー
ト基材、あるいは必要に応じて設けられる絵柄インキ
層、べたインキ層の物性を補わなくてはならない。しか
し、従来の撥液性インキは真下の層を補うほどの物性は
持ちあわせてはおらず、このためはじかれる樹脂をはじ
いた撥液性インキの部分は、耐溶剤性、耐薬品性、ラビ
ング性、耐摩耗性等の物性に劣っているという問題があ
った。
However, in the method of printing the liquid-repellent ink on the decorative sheet base material, the liquid-repellent ink repels the resin that is repelled. The physical properties of the corresponding pattern ink layer and solid ink layer must be supplemented. However, the conventional liquid-repellent ink does not have enough physical properties to supplement the layer directly below, and therefore the part of the liquid-repellent ink that is repelled by the repelled resin has solvent resistance, chemical resistance, and rubbing resistance. However, there is a problem that the physical properties such as abrasion resistance are inferior.

【0005】さらに、この化粧シート基材に撥液性イン
キを印刷する方法は、撥液性インキを印刷した後、はじ
き性を持たせるために、撥液性インキの焼き付け工程を
必要とする。焼き付け工程には赤外線、温風等を用いる
のが一般的だが、これらの装置では、中央部と両サイド
といった具合に部分的な温度のばらつきが起こり易く、
このため撥液性インキの部分的な焼き付け不足を生じ、
はじき不良を起こすという問題があった。
Further, the method of printing the liquid-repellent ink on the decorative sheet substrate requires a step of printing the liquid-repellent ink after printing the liquid-repellent ink in order to impart repellency. It is common to use infrared rays, warm air, etc. in the baking process, but in these devices, partial temperature variations such as the central part and both sides easily occur,
For this reason, partial printing of the liquid-repellent ink is insufficient,
There was a problem of causing repellency.

【0006】[0006]

【発明が解決しようとする課題】本発明はこのような問
題点を解決するためになされたものであり、その課題と
するところは、撥液性インキにはじかれる樹脂を安定し
てはじかせ、絵柄に同調した立体感を持たせながら、耐
溶剤性、耐薬品性、ラビング性、耐摩耗性に優れた化粧
シートの製造方法を提供することにある。
SUMMARY OF THE INVENTION The present invention has been made to solve the above problems, and its object is to stably repel a resin repelled by a liquid-repellent ink, An object of the present invention is to provide a method for producing a decorative sheet having excellent solvent resistance, chemical resistance, rubbing resistance, and abrasion resistance while giving a three-dimensional effect that is in tune with a design.

【0007】[0007]

【課題を解決するための手段】本発明は、この課題を解
決するため、化粧シート基材の上に、撥液性を有する電
子線又は紫外線硬化型樹脂からなるインキによる印刷層
と、これにはじかれた樹脂層とを有することを特徴とす
る化粧シートを提供するものであり、その製造方法とし
て、化粧シート基材の上に、撥液性を有する電子線又は
紫外線硬化型樹脂からなるインキにより印刷し、これを
電子線又は紫外線にて硬化し、その後この上全面にわた
って前記撥液性を有する電子線又は紫外線硬化型樹脂か
らなるインキにはじかれる樹脂を塗布してなることを特
徴とするものである。
In order to solve this problem, the present invention provides a printed layer of an ink made of a liquid-repellent electron beam or an ultraviolet curable resin on a decorative sheet substrate, and The present invention provides a decorative sheet having a repelled resin layer, and as a method for producing the decorative sheet, an ink made of an electron beam or ultraviolet curable resin having liquid repellency on a decorative sheet base material. Is printed, and is cured with an electron beam or an ultraviolet ray, and then a resin that is repelled by an ink made of the electron beam or ultraviolet ray curable resin having the liquid repellency is applied over the entire surface. It is a thing.

【0008】以下、本発明を図2に基づき詳細に説明す
る。本発明に係る化粧シート基材に使用するベース基材
1としては、紙、各種フィルム、不織布等が使用できる
が、本発明の方法に最も適した物は紙で、特に紙が良
い。
The present invention will be described in detail below with reference to FIG. As the base material 1 used for the decorative sheet base material according to the present invention, paper, various films, non-woven fabrics and the like can be used, but paper is most suitable for the method of the present invention, and paper is particularly preferable.

【0009】また、本発明における化粧シート基材とし
ては、ベース基材に任意にべたインキ層2か又は絵柄イ
ンキ層3を設けたものが好適に使用される。これらのイ
ンキには油性インキ、水性インキ、紫外線硬化型インキ
等が使用可能で、これらの層を設ける方法としては、グ
ラビア印刷法、グラビアオフセット印刷法、スクリーン
印刷法、フレキソ印刷法等、任意である。
As the decorative sheet base material in the present invention, a base material optionally provided with a solid ink layer 2 or a pattern ink layer 3 is preferably used. Oil-based inks, water-based inks, UV-curable inks, etc. can be used for these inks, and as a method for providing these layers, a gravure printing method, a gravure offset printing method, a screen printing method, a flexo printing method, etc. can be arbitrarily used. is there.

【0010】本発明における撥液性を有する電子線又は
紫外線硬化型樹脂6としては、透明なものか、必要に応
じて顔料、染料による着色が可能である。
The liquid-repellent electron beam or ultraviolet ray curable resin 6 in the present invention may be transparent or colored with a pigment or a dye if necessary.

【0011】これらを印刷する方法としては、グラビ
ア、グラビアオフセット等従来の方法を任意に使用でき
る。
As a method for printing these, any conventional method such as gravure or gravure offset can be used.

【0012】本発明における撥液性を有する電子線又は
紫外線硬化型樹脂にはじかれる樹脂7としては、電子線
硬化型樹脂、紫外線硬化型樹脂、ウレタン系樹脂、アミ
ノアルキッド系樹脂等が使用できる。塗布方法として
は、ロールコーター、グラビアコーター、リバースコー
ター、ナイフコーター、コンマコーター等がある。塗布
量は7〜50g/m2 が好適である。
As the resin 7 which is repelled by the electron beam or ultraviolet ray curable resin having liquid repellency in the present invention, electron beam curable resin, ultraviolet ray curable resin, urethane resin, aminoalkyd resin or the like can be used. Examples of the coating method include a roll coater, a gravure coater, a reverse coater, a knife coater, a comma coater and the like. The coating amount is preferably 7 to 50 g / m 2 .

【0013】[0013]

【作用】以上に示したように、本発明の化粧シートの製
造方法によって、撥液性インキの代わりに撥液性を有す
る電子線又は紫外線硬化型樹脂を用いることで、はじか
れる樹脂のはじかれた部分においても、硬化した撥液性
を有する電子線又は紫外線硬化型樹脂インキにより耐溶
剤性、耐薬品性、ラビング性、耐摩耗性等に優れた化粧
シートを得ることができる。
As described above, according to the method for producing a decorative sheet of the present invention, by using a liquid repellent electron beam or ultraviolet curable resin instead of the liquid repellent ink, the repelled resin is repelled. Even in the exposed portion, a cured liquid-repellent electron beam or ultraviolet ray curable resin ink can provide a decorative sheet excellent in solvent resistance, chemical resistance, rubbing property, abrasion resistance and the like.

【0014】また、これらの撥液性を有する電子線又は
紫外線硬化型樹脂の硬化方法を、電子線硬化、または紫
外線硬化とすることで、熱硬化装置のような部分的な焼
き付け不足を解消させ、樹脂を安定して硬化させること
で、はじき不良のない優れた化粧シートを得ることがで
きる。
Further, by using electron beam curing or ultraviolet curing as the curing method for the electron beam or ultraviolet curable resin having the liquid repellency, it is possible to eliminate partial insufficient baking such as in a thermosetting device. By stably curing the resin, it is possible to obtain an excellent decorative sheet without repellency defects.

【0015】[0015]

【実施例】【Example】

<実施例1>ベース基材として坪量30g/m2 の薄葉
紙を用い、これに油性のベたインキ、木目絵柄インキを
印刷して化粧シート基材とし、この木目絵柄の導管部に
顔料を含む下記<配合1>による撥液性を有する紫外線
線硬化型樹脂インキをグラビアにて印刷を施した。この
印刷物を高圧水銀80W/cm×3のランプを用い、ラ
ンプ下10cm、照射速度20m/minで紫外線を照
射して硬化させた。
<Example 1> A thin paper having a basis weight of 30 g / m 2 was used as a base material, and an oily solid ink and a wood grain pattern ink were printed on the base material to make a decorative sheet substrate, and a pigment was added to a conduit portion of the wood grain pattern. A UV ray curable resin ink having liquid repellency according to the following <Formulation 1> was printed by gravure. This printed matter was cured by irradiating it with ultraviolet rays using a high pressure mercury 80 W / cm × 3 lamp at 10 cm under the lamp and at an irradiation speed of 20 m / min.

【0016】 <配合1> エポキシアクリレート(ダイセルUCB(株)製「EB810」) 60重量部 モノマー(TMPTA) 30重量部 カーボン顔料 5重量部 シリコンオイル 5重量部 開始剤(メルク社製「ダロキュアー1173」) 3重量部<Formulation 1> Epoxy acrylate (“EB810” manufactured by Daicel UCB Ltd.) 60 parts by weight Monomer (TMPTA) 30 parts by weight Carbon pigment 5 parts by weight Silicon oil 5 parts by weight Initiator (“Darocur 1173” manufactured by Merck) ) 3 parts by weight

【0017】この化粧シートの撥液性を有する紫外線線
硬化型樹脂インキにはじかれる樹脂としては下記<配合
2>による紫外線硬化型樹脂を用い、ロールコーターに
て10g/m2 塗工し、高圧水銀120W/cm×4の
ランプを用い、ランプ下10cm、照射速度30m/m
inで紫外線を照射して硬化させた。こうして得られた
化粧シートは、導管部の紫外線硬化型樹脂がはじかれ、
絵柄に同調した立体感が得られた。この化粧シートは耐
溶剤性、耐薬品性、ラビング性、耐摩耗性等に優れたも
のであった。
As the resin repelled by the liquid repellent ultraviolet ray curable resin ink of the decorative sheet, an ultraviolet curable resin according to the following <Formulation 2> is used, which is coated with a roll coater at 10 g / m 2 and is subjected to high pressure. Using a lamp of 120 W / cm x 4 mercury, 10 cm below the lamp, irradiation speed 30 m / m
It was irradiated with ultraviolet rays and cured. The decorative sheet thus obtained is repelled by the ultraviolet curable resin in the conduit portion,
A three-dimensional effect that matches the design was obtained. This decorative sheet was excellent in solvent resistance, chemical resistance, rubbing property, abrasion resistance and the like.

【0018】 <配合2> ポリエステルアルリレート (東亞合成化学工業(株)製「M−8030」) 70重量部 モノマー(TMPTA) 30重量部 シリコンオイル 5重量部 開始剤(メルク社製「ダロキュアー1173」) 5重量部<Compound 2> Polyester acrylate (“M-8030” manufactured by Toagosei Co., Ltd.) 70 parts by weight Monomer (TMPTA) 30 parts by weight Silicone oil 5 parts by weight Initiator (“Darocurure 1173” manufactured by Merck) ) 5 parts by weight

【0019】<実施例2>ベース基材として坪量50g
/m2 の紙間強化紙を用い、これに水性のベたインキ、
木目絵柄インキを印刷して化粧シート基材とし、この木
目絵柄の導管部に顔料を含む下記<配合3>による撥液
性を有する電子線線硬化型樹脂をグラビアにて印刷を施
した。この印刷物に200Kv、2Mradの電子線を
照射して硬化させた。
<Example 2> 50 g of basis weight as a base material
/ M 2 inter-paper reinforced paper is used.
A wood grain picture ink was printed to make a decorative sheet substrate, and an electron beam curable resin having a liquid repellency according to the following <formulation 3> containing a pigment was gravure printed on the conduit portion of the wood grain picture. The printed matter was irradiated with an electron beam of 200 Kv and 2 Mrad to be cured.

【0020】 <配合3> ポリエステルアクリレート (東亞合成化学工業(株)製「M−8030」) 60重量部 ポリエステルアクリレート(ダイセルUCB(株)製「EB80」)20重量部 モノマー(TMPTA) 10重量部 カーボン顔料 5重量部 シリコンオイル 5重量部<Formulation 3> Polyester acrylate (“M-8030” manufactured by Toagosei Chemical Industry Co., Ltd.) 60 parts by weight Polyester acrylate (“EB80” manufactured by Daicel UCB Co., Ltd.) 20 parts by weight Monomer (TMPTA) 10 parts by weight Carbon pigment 5 parts by weight Silicon oil 5 parts by weight

【0021】この化粧シートの撥液性を有する電子線線
硬化型樹脂インキにはじかれる樹脂としては下記<配合
4>からなる電子線硬化型樹脂を用い、コンマコーター
にて15g/m2 塗工し、200Kv、3Mradの電
子線を照射して硬化させた。こうして得られた化粧シー
トは、導管部の電子線硬化型樹脂がはじかれ、絵柄に同
調した立体感が得られた。この化粧シートは耐溶剤性、
耐薬品性、ラビング性、耐摩耗性に優れたものであっ
た。
As the resin repelled by the liquid-repellent electron beam curable resin ink of this decorative sheet, an electron beam curable resin consisting of the following <formulation 4> was used and coated with a comma coater at 15 g / m 2 Then, it was cured by irradiating it with an electron beam of 200 Kv and 3 Mrad. In the decorative sheet thus obtained, the electron beam curable resin in the conduit portion was repelled, and a three-dimensional effect in tune with the design was obtained. This decorative sheet is solvent resistant,
It was excellent in chemical resistance, rubbing resistance, and abrasion resistance.

【0022】 <配合4> ポリエステルアクリレート (ダイセルUCB(株)製「EB1016」) 80重量部 モノマー(TPGDA) 20重量部 シリコンオイル 5重量部<Formulation 4> Polyester acrylate (“EB1016” manufactured by Daicel UCB Ltd.) 80 parts by weight Monomer (TPGDA) 20 parts by weight Silicone oil 5 parts by weight

【0023】[0023]

【発明の効果】本発明の化粧シートの製造方法によっ
て、撥液性インキに撥液性を有する電子線硬化型樹脂、
または紫外線硬化型樹脂を用いることで、はじかれる樹
脂のはじかれた部分においても、耐溶剤性、耐薬品性、
ラビング性、耐摩耗性等に優れた化粧シートを得ること
ができる。また、これらの樹脂の硬化方法を、電子線硬
化、または紫外線硬化とすることで、熱硬化装置のよう
な部分的な焼き付け不足を解消させ、樹脂を安定して硬
化させることで、はじき不良のない優れた化粧シートを
得ることができる。
According to the method for producing a decorative sheet of the present invention, an electron beam curable resin having liquid repellency in a liquid repellent ink,
Or by using an ultraviolet curable resin, even in the repelled portion of the repelled resin, solvent resistance, chemical resistance,
It is possible to obtain a decorative sheet having excellent rubbing properties and abrasion resistance. Further, the curing method of these resins is electron beam curing or ultraviolet curing, thereby eliminating partial baking shortage such as in a thermal curing device, and by curing the resin in a stable manner, repelling failure is prevented. It is possible to obtain an excellent decorative sheet that does not have.

【0024】[0024]

【図面の簡単な説明】[Brief description of drawings]

【図1】従来の撥液性を有するインキによる化粧シート
の断面の構造の一例を示す説明図である。
FIG. 1 is an explanatory diagram showing an example of a structure of a cross section of a conventional decorative sheet made of a liquid-repellent ink.

【図2】本発明による化粧シートの断面の構造の一例を
示す説明図である。
FIG. 2 is an explanatory view showing an example of a cross-sectional structure of a decorative sheet according to the present invention.

【符号の説明】[Explanation of symbols]

1…ベース基材 2…べたインキ層 3…絵柄インキ層 4…撥液性インキ 5…撥液性インキにはじかれる樹脂 6…撥液性を有する電子線又は紫外線硬化型樹脂インキ 7…撥液性を有する電子線又は紫外線硬化型樹脂インキ
にはじかれる樹脂
DESCRIPTION OF SYMBOLS 1 ... Base substrate 2 ... Solid ink layer 3 ... Design ink layer 4 ... Liquid repellent ink 5 ... Resin repelled by liquid repellent ink 6 ... Electron beam or ultraviolet curable resin ink 7 having liquid repellent 7 ... Liquid repellent Resin repelled by electron beam or UV curable resin ink

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】化粧シート基材の上に、撥液性を有する電
子線又は紫外線硬化型樹脂からなるインキによる印刷層
と、これにはじかれた樹脂層とを有することを特徴とす
る化粧シート。
1. A decorative sheet comprising a decorative sheet substrate, a printed layer of ink made of a liquid-repellent electron beam or ultraviolet curable resin, and a resin layer repelled by the printed layer. .
【請求項2】化粧シート基材の上に、撥液性を有する電
子線又は紫外線硬化型樹脂からなるインキにより印刷
し、これを電子線又は紫外線にて硬化し、その後この上
全面にわたって前記撥液性を有する電子線又は紫外線硬
化型樹脂からなるインキにはじかれる樹脂を塗布してな
ることを特徴とする請求項1記載の化粧シートの製造方
法。
2. A decorative sheet base material is printed with an ink made of an electron beam or ultraviolet ray curable resin having liquid repellency, cured by an electron beam or ultraviolet rays, and then the repellent agent is applied over the entire surface. 2. The method for producing a decorative sheet according to claim 1, wherein a resin that is repelled by ink that is a liquid electron beam or ultraviolet curable resin is applied.
JP2945594A 1994-02-28 1994-02-28 Decorative sheet and its production Pending JPH07237286A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2945594A JPH07237286A (en) 1994-02-28 1994-02-28 Decorative sheet and its production

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2945594A JPH07237286A (en) 1994-02-28 1994-02-28 Decorative sheet and its production

Publications (1)

Publication Number Publication Date
JPH07237286A true JPH07237286A (en) 1995-09-12

Family

ID=12276588

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2945594A Pending JPH07237286A (en) 1994-02-28 1994-02-28 Decorative sheet and its production

Country Status (1)

Country Link
JP (1) JPH07237286A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006281632A (en) * 2005-03-31 2006-10-19 Dainippon Printing Co Ltd Shaping sheet
JP2009172943A (en) * 2008-01-28 2009-08-06 Toppan Printing Co Ltd Printed matter and its manufacturing method

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006281632A (en) * 2005-03-31 2006-10-19 Dainippon Printing Co Ltd Shaping sheet
JP4679207B2 (en) * 2005-03-31 2011-04-27 大日本印刷株式会社 Molding sheet
JP2009172943A (en) * 2008-01-28 2009-08-06 Toppan Printing Co Ltd Printed matter and its manufacturing method

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