JPH07206544A - Method for extrusion molding of lightweight inorganic building material - Google Patents
Method for extrusion molding of lightweight inorganic building materialInfo
- Publication number
- JPH07206544A JPH07206544A JP1886394A JP1886394A JPH07206544A JP H07206544 A JPH07206544 A JP H07206544A JP 1886394 A JP1886394 A JP 1886394A JP 1886394 A JP1886394 A JP 1886394A JP H07206544 A JPH07206544 A JP H07206544A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- extrusion
- inorganic building
- lightweight
- cement
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00034—Physico-chemical characteristics of the mixtures
- C04B2111/00129—Extrudable mixtures
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Panels For Use In Building Construction (AREA)
- Porous Artificial Stone Or Porous Ceramic Products (AREA)
- Press-Shaping Or Shaping Using Conveyers (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】この発明は、軽量無機質建材の押
出成形方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an extrusion molding method for lightweight inorganic building materials.
【0002】[0002]
【従来の技術】従来、繊維補強セメント製とされた無機
質建材が非常に広く使用されている。これら無機質建材
の製造方法としてセメント、シリカ質原料、骨材及び補
強繊維からなるセメント配合物を適量の水で混練し、こ
れを成形ダイから押出成形する押出成形法が知られてい
る。ところで、この無機質建材の押出成形法の場合、一
定以上の押出圧力が成形材料に加えられるので製品が高
密度、高硬度となり勝ちであり、製品強度向上の点では
好都合なものの、製品が重く釘打や鋸切断の加工性が悪
いといった問題があった。従って、このような問題を解
消するため押出成形配合材料にパーライトなどの無機発
泡軽量骨材や発泡スチレンビーズなどの有機発泡軽量骨
材を添加し製品組織を多孔化して比重の低下及び加工性
を向上することなどが行われている。2. Description of the Related Art Conventionally, inorganic building materials made of fiber reinforced cement have been very widely used. As a method for producing these inorganic building materials, an extrusion molding method is known in which a cement mixture composed of cement, a silica raw material, an aggregate and a reinforcing fiber is kneaded with an appropriate amount of water, and this is extruded from a molding die. By the way, in the case of the extrusion molding method of this inorganic building material, since the extrusion pressure above a certain level is applied to the molding material, the product tends to have high density and high hardness, which is convenient in terms of improving the product strength, but the product is heavy and nailed. There was a problem that the workability of punching and saw cutting was poor. Therefore, in order to solve such a problem, an inorganic foamed lightweight aggregate such as pearlite or an organic foamed lightweight aggregate such as expanded styrene beads is added to the extrusion compounding material to make the product structure porous to reduce the specific gravity and processability. Improvements are being made.
【0003】[0003]
【従来技術の問題点】しかしながら、上記軽量化技術の
内、前者の無機発泡軽量骨材を添加する方法の場合は押
出機内で無機発泡軽量骨材が粉砕されることが多く、こ
のため添加に見合った軽量化が達成され難いといった問
題があり、また後者の有機発泡軽量骨材を添加する方法
の場合、圧縮されて成形ダイを通過した後、材料に含ま
れる有機発泡軽量骨材がスプリングバック現象により復
元膨張し、このため製品表面に細かい凹凸ができ製品表
面が平滑にならなくなるといった問題があった。もっと
も、このような問題は有機発泡軽量骨材を非常に細かい
微粉末となるまで粉砕すれば解消できるのであるが、有
機発泡軽量骨材に加えられる微粉砕時の衝撃あるいは摩
擦による熱で有機発泡軽量骨材が容積を減少させる現象
を生じ、この結果嵩比重が大きくなり、上記スプリング
バックなどの現象は解消できても十分な軽量化が達成で
きなくなるといった問題があった。However, in the case of the former method of adding the inorganic foam lightweight aggregate among the above-mentioned weight-reducing techniques, the inorganic foam lightweight aggregate is often crushed in the extruder, and therefore, the addition is not recommended. There is a problem that it is difficult to achieve a suitable weight reduction, and in the latter method of adding organic foam lightweight aggregate, after being compressed and passing through the molding die, the organic foam lightweight aggregate contained in the material is springback. Due to the phenomenon, the product expands and restores, which causes fine irregularities on the product surface, resulting in a problem that the product surface is not smooth. However, such problems can be solved by crushing the organic foamed lightweight aggregate until it becomes a very fine powder, but the organic foamed by the heat due to the impact or friction during the pulverization applied to the organic foamed lightweight aggregate. There is a problem in that the lightweight aggregate causes a phenomenon of reducing the volume, and as a result, the bulk specific gravity is increased, and even if the phenomenon such as the springback described above can be eliminated, sufficient weight reduction cannot be achieved.
【0004】[0004]
【発明が解決しようとする課題】この発明は上記問題点
に鑑み、無機質建材の押出成形法において、製品の軽量
化を効率良く達成することのできる軽量無機質建材の押
出成形方法を得ることを目的としてなされたものであ
る。SUMMARY OF THE INVENTION In view of the above problems, an object of the present invention is to provide an extrusion molding method for an inorganic building material, which is an extrusion molding method for a lightweight inorganic building material, which can efficiently reduce the weight of a product. It was made as.
【0005】[0005]
【課題を解決するための手段】即ち、この発明の軽量無
機質建材の押出成形方法は、セメント、シリカ質原料、
骨材及び補強繊維からなるセメント配合物 100重量%に
対し、外割重量比で押出助剤 0.5〜0.8 重量%、軽量骨
材10〜20重量%及び水55〜60重量%を添加してなる軽量
無機質建材の押出配合材料に対し、発泡スチロール粉砕
物であって、粉砕時の熱で減容していないものあるいは
減容したものを除去したもので、嵩比重が0.02以下、粒
度が 1.2mm以下の発泡スチロール粉砕物を上記セメント
配合物 100重量%に対し外割重量比で0.5 〜1.2 重量%
添加し、該混練物を所定形状に押出成形し、次いで前記
発泡スチロール粉砕物の溶融温度以上の温度でオートク
レーブ養生することを特徴とするものである。That is, the method for extrusion molding a lightweight inorganic building material of the present invention is to provide a cement, a siliceous raw material,
0.5 to 0.8% by weight of extrusion aid, 10 to 20% by weight of lightweight aggregate and 55 to 60% by weight of water are added to 100% by weight of cement mixture consisting of aggregate and reinforcing fiber in an external weight ratio. Extruded and compounded materials for lightweight inorganic building materials, extruded styrofoam that has not been reduced in volume or reduced in volume due to heat during pulverization, and has a bulk specific gravity of 0.02 or less and a particle size of 1.2 mm or less. 0.5 to 1.2% by weight of the crushed styrene foam of
It is characterized in that it is added, the kneaded product is extruded into a predetermined shape, and then the autoclave is cured at a temperature equal to or higher than the melting temperature of the styrofoam crushed product.
【0006】[0006]
【作用】この発明において使用される軽量無機質建材の
押出配合材料は、セメント、シリカ質原料、骨材及び補
強繊維からなるセメント配合物 100重量%に対し、外割
重量比で押出助剤 0.5〜0.8 重量%、軽量骨材10〜20重
量%及び水55〜60重量%を添加してなる配合で、従来と
同様であり、この点には特に記する点はない。The extruding compounding material of the lightweight inorganic building material used in the present invention is an extruding aid of 0.5 to 100% by weight with respect to 100% by weight of the cement compounding mixture consisting of cement, siliceous raw material, aggregate and reinforcing fiber. It is a composition obtained by adding 0.8% by weight, 10 to 20% by weight of lightweight aggregate, and 55 to 60% by weight of water, which is the same as the conventional one, and there is no particular point on this point.
【0007】本願発明において、上記配合に対し発泡ス
チロール粉砕物であって、粉砕時の熱で減容していない
ものあるいは減容したものを除去したもので、嵩比重が
0.02以下、粒度が 1.2mm以下の発泡スチロール粉砕物を
上記セメント配合物 100重量%に対し外割重量比で0.5
〜1.2 重量%添加する。この発泡スチロール樹脂を添加
する理由は、押出成形品の軽量化を達成するためであ
る。そしてこの発泡スチロール樹脂は、粉砕時の熱で減
容していないものあるいは減容したものを除去したもの
で、嵩比重が0.02以下、粒度が 1.2mm以下のものが使用
される。この理由は、粉砕時の熱で減容したものは、嵩
比重が0.02より大きく従って添加しても軽量化が十分に
達成されなくなるからである。また粒度を 1.2mm以下と
するのは、押出成形後のスプリングバック現象を防止す
るためで 1.2mmより大きいとスプリングバック現象によ
る表面平滑性等が得られなくなる。In the present invention, a styrofoam crushed product with respect to the above composition, which has not been reduced in volume by heat during pulverization or has been reduced in volume, has a bulk specific gravity of
A styrene foam crushed product with a particle size of 0.02 or less and a particle size of 1.2 mm or less is 0.5% by weight based on 100% by weight of the above cement mixture.
Add ~ 1.2% by weight. The reason for adding this styrofoam resin is to achieve weight reduction of the extrusion molded product. This styrofoam resin is obtained by removing one that has not been reduced in volume by heat during pulverization or one whose volume has been reduced. It has a bulk specific gravity of 0.02 or less and a particle size of 1.2 mm or less. The reason for this is that the volume reduced by the heat during pulverization has a bulk specific gravity of more than 0.02, and therefore even if added, the weight reduction cannot be sufficiently achieved. The particle size is 1.2 mm or less in order to prevent the springback phenomenon after extrusion molding. If it is larger than 1.2 mm, the surface smoothness due to the springback phenomenon cannot be obtained.
【0008】この発泡スチロール樹脂粉砕物の添加量を
セメント配合物 100重量%に対し外割重量比で0.5 〜1.
2 重量%添加するのは、0.5 重量%より少ないと軽量化
が十分に達成されず、1.2 重量%より多くすると、軽量
化の点では好都合であるが、発泡スチロール樹脂粉砕物
の添加相対容積が大きくなり、セメントマトリックスの
結合強度が弱くなると同時に押出成形体全体のスプリン
グバック現象による製品の歪み等が生じるからである。[0008] The addition amount of this styrofoam crushed resin is 0.5-1.
If 2% by weight is added, less than 0.5% by weight will not achieve sufficient weight reduction, and if it is more than 1.2% by weight, it will be convenient in terms of weight reduction, but the relative volume of addition of ground polystyrene foam resin will be large. This is because the bond strength of the cement matrix is weakened, and at the same time, the product is distorted due to the springback phenomenon of the entire extrusion molded body.
【0009】なお上記において、発泡スチロールを粉砕
する時に、粉砕時の熱で減容させない手段は、粉砕機の
歯の隙間、回転数、粗粉砕の粒度等の条件によるが、共
通する効果的な手段としては、内部に冷却ジャケットを
備えた粉砕歯が使用される。In the above, when crushing Styrofoam, the means for not reducing the volume by the heat during crushing depends on the conditions such as the tooth gap of the crusher, the number of revolutions, and the particle size of the coarse crushing, but common effective means. For this, crushing teeth with a cooling jacket inside are used.
【0010】[0010]
【実施例】次にこの発明の実施例を説明する。Embodiments of the present invention will be described below.
【0011】まず、発泡スチロール樹脂を、歯内部に冷
却ジャケットを備えた粉砕機を使用し、粉砕時の温度上
昇を防止しつつ粉砕し嵩比重が0.02以下、粒度が 1.2mm
以下の発泡スチロール粉砕物を得た。 (実施例1)セメント42重量%、珪砂40重量%、骨材13
重量%、パルプ繊維 5重量%の合計100重量%に対し、
押出助剤としてメチルセルロースを外割で0.7 重量%、
無機軽量骨材としてパーライトを外割で15重量%及び水
を外割で55〜60重量%添加して得た配合を基本配合と
し、このセメント配合物 100重量%に対し、上記嵩比重
が0.02以下、粒度が 1.2mm以下の発泡スチロール粉砕物
を上記セメント配合物 100重量%に対し外割重量比で0.
5 重量%添加し、該混練物を厚さ2cm 、幅20cmの断面形
状で押出成形し、長さ50cmの板状試験片を得た。First, a styrofoam resin is crushed by using a crusher equipped with a cooling jacket inside the teeth to prevent a temperature rise during crushing, and a bulk specific gravity of 0.02 or less and a particle size of 1.2 mm.
The following styrofoam pulverized product was obtained. (Example 1) Cement 42% by weight, silica sand 40% by weight, aggregate 13
Wt%, pulp fiber 5 wt% total 100 wt%,
0.7% by weight of methyl cellulose as an extrusion aid,
As the inorganic lightweight aggregate, the basic composition is a composition obtained by adding 15% by weight of perlite to the outer part and 55 to 60% by weight of water to the outer part. Below, a styrene foam pulverized product with a particle size of 1.2 mm or less is 0.
5% by weight was added, and the kneaded product was extrusion-molded into a cross-sectional shape having a thickness of 2 cm and a width of 20 cm to obtain a plate-shaped test piece having a length of 50 cm.
【0012】(実施例2)実施例1における発泡スチロ
ール樹脂微粉砕物の添加量を、セメント配合物 100重量
%に対し1.0 重量%とした他は実施例1と同様にして板
状試験片を得た。(Example 2) A plate-shaped test piece was obtained in the same manner as in Example 1 except that the amount of the finely ground polystyrene foam resin added in Example 1 was 1.0% by weight relative to 100% by weight of the cement mixture. It was
【0013】(実施例2)実施例1における発泡スチロ
ール樹脂微粉砕物の添加量を、セメント配合物 100重量
%に対し1.2 重量%とした他は実施例1と同様にして板
状試験片を得た。(Example 2) A plate-like test piece was obtained in the same manner as in Example 1 except that the amount of the finely ground polystyrene foam resin added in Example 1 was 1.2% by weight relative to 100% by weight of the cement mixture. It was
【0014】(比較例1)粉砕時に熱により減容し、嵩
比重が0.05以下、粒度が 1.2mm以下の発泡スチロール粉
砕物を使用した他は実施例2と同様にして実施例2と同
形の板状試験片を得た。(Comparative Example 1) A plate having the same shape as that of Example 2 except that a styrofoam crushed product having a volume specific gravity of 0.05 or less and a particle size of 1.2 mm or less was used to reduce the volume by heat during crushing. A test piece was obtained.
【0015】(比較例2)粉砕時に熱により減容し、嵩
比重が0.05以下、粒度が 1.2mm以下の発泡スチロール粉
砕物を使用し、かつその添加量を2.0 重量%とした他は
実施例2と同様にして実施例2と同形の板状試験片を得
た。(Comparative Example 2) Example 2 was repeated except that a styrene foam pulverized product having a volume specific gravity of 0.05 or less and a particle size of 1.2 mm or less was used by reducing the volume by heat during pulverization and the addition amount thereof was 2.0% by weight. A plate-shaped test piece having the same shape as in Example 2 was obtained in the same manner as in.
【0016】(比較例3)粉砕時に熱により減容してい
ないが、平均粒子径が2mm 、嵩比重が0.02の発泡スチロ
ール粉砕物を1.0 重量%添加した他は実施例2と同様に
して実施例2と同形の板状試験片を得た。(Comparative Example 3) The same procedure as in Example 2 was carried out except that 1.0% by weight of a styrene foam pulverized product having an average particle size of 2 mm and a bulk specific gravity of 0.02 was added, although the volume was not reduced by heat during pulverization. A plate-shaped test piece having the same shape as 2 was obtained.
【0017】上記実施例1〜3及び比較例1〜3を6時
間室温で自然養生後、180 ℃×12時間の条件でオートク
レーブ養生を行い硬化させた。得た試験片について、曲
げ強度、比重、釘打試験、及び表面状態の観察試験を行
ったところ、表1のような結果となった。The above Examples 1 to 3 and Comparative Examples 1 to 3 were naturally cured at room temperature for 6 hours, and then autoclaved at 180 ° C. for 12 hours to be cured. The obtained test piece was subjected to bending strength, specific gravity, nailing test, and surface state observation test, and the results shown in Table 1 were obtained.
【0018】なお、表1において「曲げ強度」はJIS
4号曲げ試験に準拠したものであり単位はkg/cm2であ
る。また「釘打性」は、試験板の隅20mm×20mmの位置に
釘を打ち込み割れ欠けを生じないものの数を被試験体数
の数に対して表示したものである。また「表面状態」は
スプリングバックによる凹凸状態の発生の有無を見たも
のであり、○は表面平滑で良好、△は僅かな凹凸が見ら
れるが一応平滑状態を保もの、×は凹凸が明瞭に見られ
るものを示す。In Table 1, "bending strength" means JIS.
It is based on the No. 4 bending test, and the unit is kg / cm 2 . The "nailability" is the number of nails that are driven into the corners of the test plate 20 mm x 20 mm and which does not cause cracks and chips, relative to the number of test objects. "Surface condition" refers to the presence or absence of unevenness due to springback. ○ indicates that the surface is smooth and good, △ indicates slight unevenness but a smooth surface is maintained, and × indicates unevenness. Shows what is seen in.
【0019】表1から明らかなように、この発明で得た
試験片はいずれも比重が1.015 〜1.011 の範囲内に納ま
り軽量化が達成されると共に、曲げ強度も十分な強度と
することが判明した。なお、比較例1は強度的には優れ
るが釘打性が全く不可、比較例2は強度、比重、表面状
態の点で不可、比較例3は比重の点では優れるが、表面
状態が全く不可であった。As is apparent from Table 1, all the test pieces obtained by the present invention have a specific gravity within the range of 1.015 to 1.011 to achieve weight reduction and have sufficient bending strength. did. It should be noted that Comparative Example 1 is excellent in strength but is not capable of nailing at all, Comparative Example 2 is unacceptable in terms of strength, specific gravity and surface condition, and Comparative Example 3 is excellent in terms of specific gravity but not in surface condition at all. Met.
【0020】[0020]
【表1】 [Table 1]
【0021】[0021]
【発明の効果】この発明は以上説明したように、従来の
軽量無機質建材の押出成形配合において、軽量化のため
の添加材として、粉砕時の熱で減容していないものある
いは減容したものを除去した発泡スチロール粉砕物を使
用するので、少ない添加量で十分な軽量化が図れると共
にスプリングバックによる表面不良も十分に解消できる
といった効果を有する。As described above, according to the present invention, in the conventional extrusion molding compounding of a lightweight inorganic building material, as an additive material for reducing the weight, one which has not been reduced in volume by heat during pulverization or one whose volume has been reduced Since the styrofoam pulverized product from which is removed is used, it is possible to achieve a sufficient weight reduction with a small amount of addition and to sufficiently eliminate surface defects due to springback.
フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 FI 技術表示箇所 //(C04B 28/02 16:08 14:06 Z 14:02 Z 16:02 Z 14:18 24:38) B 103:60 111:40 Continuation of the front page (51) Int.Cl. 6 Identification code Office reference number FI technical display area // (C04B 28/02 16:08 14:06 Z 14:02 Z 16:02 Z 14:18 24:38 ) B 103: 60 111: 40
Claims (1)
繊維からなるセメント配合物 100重量%に対し、外割重
量比で押出助剤 0.5〜0.8 重量%、軽量骨材10〜20重量
%及び水55〜60重量%を添加してなる軽量無機質建材の
押出配合材料に対し、発泡スチロール粉砕物であって、
粉砕時の熱で減容していないものあるいは減容したもの
を除去したもので、嵩比重が0.02以下、粒度が 1.2mm以
下の発泡スチロール粉砕物を上記セメント配合物 100重
量%に対し外割重量比で0.5 〜1.2 重量%添加し、該混
練物を所定形状に押出成形し、次いで前記発泡スチロー
ル粉砕物の溶融温度以上の温度でオートクレーブ養生す
ることを特徴とする軽量無機質建材の押出成形方法。1. An extrusion aid of 0.5 to 0.8% by weight and a lightweight aggregate of 10 to 20% by weight based on 100% by weight of a cement mixture consisting of cement, a siliceous raw material, an aggregate and a reinforcing fiber. For extruded compounding materials of lightweight inorganic building materials made by adding 55 to 60% by weight of water, it is a styrene foam pulverized product,
Those that have not been or have been reduced in volume by the heat of crushing, and have a bulk specific gravity of 0.02 or less and a particle size of 1.2 mm or less are crushed styrofoam, and the outer weight is based on 100% by weight of the above cement mixture. A method for extrusion-molding a lightweight inorganic building material, comprising adding 0.5 to 1.2% by weight of the mixture, extruding the kneaded product into a predetermined shape, and then curing the autoclave at a temperature equal to or higher than the melting temperature of the styrofoam crushed product.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1886394A JPH07206544A (en) | 1994-01-18 | 1994-01-18 | Method for extrusion molding of lightweight inorganic building material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1886394A JPH07206544A (en) | 1994-01-18 | 1994-01-18 | Method for extrusion molding of lightweight inorganic building material |
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Publication Number | Publication Date |
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JPH07206544A true JPH07206544A (en) | 1995-08-08 |
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JP1886394A Pending JPH07206544A (en) | 1994-01-18 | 1994-01-18 | Method for extrusion molding of lightweight inorganic building material |
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JP (1) | JPH07206544A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112919927A (en) * | 2021-03-25 | 2021-06-08 | 华南理工大学 | Porous light cement-based heat insulation material and preparation method thereof |
-
1994
- 1994-01-18 JP JP1886394A patent/JPH07206544A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112919927A (en) * | 2021-03-25 | 2021-06-08 | 华南理工大学 | Porous light cement-based heat insulation material and preparation method thereof |
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