JPH07199540A - Organic and inorganic composite powder for dry transfer and its production - Google Patents
Organic and inorganic composite powder for dry transfer and its productionInfo
- Publication number
- JPH07199540A JPH07199540A JP5355244A JP35524493A JPH07199540A JP H07199540 A JPH07199540 A JP H07199540A JP 5355244 A JP5355244 A JP 5355244A JP 35524493 A JP35524493 A JP 35524493A JP H07199540 A JPH07199540 A JP H07199540A
- Authority
- JP
- Japan
- Prior art keywords
- composite powder
- transfer paper
- inorg
- organic
- dry
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- Developing Agents For Electrophotography (AREA)
- Decoration By Transfer Pictures (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、乾式印刷用の有機・無
機複合粉体およびその製造方法ならびに有機・無機複合
紛体を用いた転写紙に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an organic / inorganic composite powder for dry printing, a method for producing the same, and a transfer paper using the organic / inorganic composite powder.
【０００２】[0002]
【従来技術】従来、転写紙を作成するにあたっては、た
とえば陶磁器用転写紙あるいは耐熱ガラス用転写紙は、
スクリーン印刷による方法が一般的に使用されている。
すなわち、ステンレススチールあるいはプラスチックな
どの細線からなる織物に感光性高分子を塗布し、絵柄に
応じた光で露光し、露光した部分を溶解ないし残留させ
て織目を露出させて版を形成し、しかる後、陶磁器顔料
・ガラス成分および有機ビヒクルからなるペーストを、
ステンレススチール織物の織目を通して水可溶性高分子
を塗布した紙に印刷して形成するというものである。2. Description of the Related Art Conventionally, when making transfer paper, for example, transfer paper for ceramics or transfer paper for heat-resistant glass is
The screen printing method is generally used.
That is, a photosensitive polymer is applied to a woven fabric made of fine wire such as stainless steel or plastic, and exposed to light according to the pattern, and the exposed portion is dissolved or left to expose the texture to form a plate, Then, paste containing ceramic pigment, glass component and organic vehicle,
It is formed by printing on a paper coated with a water-soluble polymer through the texture of a stainless steel fabric.
【０００３】[0003]
【解決しようとする課題】しかしながら前記スクリーン
印刷方法によると、感光性高分子の塗布、露光に多大の
時間と労力が必要とされる。また、印刷に際しては有機
溶剤を使用するため、作業環境を悪化させるなどの問題
点を有している。However, according to the screen printing method, much time and labor are required for coating and exposing the photosensitive polymer. In addition, since an organic solvent is used for printing, there is a problem that the working environment is deteriorated.
【０００４】そこで、スクリーン印刷方法にかわるもの
として、特開平２−７７７５６号公報において、着色に
は有機顔料やガーボンを使用し、乾式印刷により通常の
紙に印刷する方法が開示されている。しかしこの方法で
陶磁器用転写紙あるいは耐熱ガラス用転写紙を作成する
と、有機顔料やガーボンは本体の焼成時に飛散してしま
い、本体に着色することができない。よって、この方法
は、陶磁器や耐熱ガラス用の転写紙作成には適していな
い。Therefore, as an alternative to the screen printing method, Japanese Patent Application Laid-Open No. 2-77756 discloses a method in which an organic pigment or garbon is used for coloring and printing is performed on ordinary paper by dry printing. However, when a transfer paper for ceramics or a transfer paper for heat-resistant glass is produced by this method, the organic pigment or garbon is scattered during firing of the main body, and the main body cannot be colored. Therefore, this method is not suitable for making transfer paper for ceramics and heat-resistant glass.
【０００５】また、特開平４−１３５７９８号公報にお
いては、陶磁器用転写紙の作成に乾式印刷の可能性が示
唆されている。しかし、ここで開示されている転写紙
は、顔料と無機結合層とを別に形成する方式であるた
め、転写紙作成には、従来のスクリーン印刷法と同様に
多くの時間や労力を要することになる。さらに、陶磁器
用の着色剤としてどのような顔料が使用し得るかなんら
開示されていない。本発明者は、かかる従来の問題点に
鑑み、電気的方式による乾式印刷に使用できる有機・無
機複合紛体を提供し、さらにこれら有機・無機複合紛体
を電気的に乾式印刷した転写紙を提供しようとするもの
である。Further, Japanese Patent Laid-Open No. 4-135798 suggests the possibility of dry printing for producing transfer paper for ceramics. However, since the transfer paper disclosed herein is a method of separately forming a pigment and an inorganic binding layer, it requires a lot of time and labor to create the transfer paper as in the conventional screen printing method. Become. Moreover, there is no disclosure of what pigments can be used as colorants for ceramics. In view of such conventional problems, the present inventor will provide an organic / inorganic composite powder that can be used for dry printing by an electrical method, and further provide a transfer paper in which the organic / inorganic composite powder is electrically dry printed. It is what
【０００６】[0006]
【課題の解決手段】本発明は、ビニル重合体１０〜５０
ｗｔ％と、無機顔料およびガラス成分９０〜５０ｗｔ％
とからなる粉体であって、その平均直径が１〜２０μｍ
である乾式印刷用有機・無機複合粉体と、これを電気的
に乾式印刷した転写紙にある。The present invention is directed to vinyl polymers 10-50.
wt% and inorganic pigment and glass component 90 to 50 wt%
Powder having an average diameter of 1 to 20 μm
The organic-inorganic composite powder for dry printing and the transfer paper on which this is electrically dry printed.
【０００７】上記乾式印刷用有機・無機複合紛体は、ビ
ニル重合体と無機顔料およびガラス成分混合し、ついで
湿式粉砕して製造する。さらに上記複合粉体を、電気的
に乾式印刷して転写紙とする。こうして得られた転写紙
を、陶磁器あるいは耐熱ガラス等に貼り、ついで焼成す
ることによって、転写紙に描かれた絵柄等は陶磁器ある
いは耐熱ガラス等に転写される。The above-mentioned organic / inorganic composite powder for dry printing is produced by mixing a vinyl polymer, an inorganic pigment and a glass component and then wet pulverizing them. Further, the composite powder is electrically dry printed to obtain a transfer paper. The transfer paper thus obtained is attached to a ceramic or a heat-resistant glass or the like, and then fired to transfer the design or the like drawn on the transfer paper to the ceramic or a heat-resistant glass or the like.
【０００８】ビニル重合体は１０〜５０ｗｔ％であると
こが好ましい。ビニル重合体は、陶磁器あるいは耐熱ガ
ラス等に絵柄等を焼き付ける際に飛散するため、５０ｗ
ｔ％より多いと上記焼成時に絵柄等にクラックが生ずる
恐れがある。また、１０ｗｔ％より少ないと転写紙への
絵柄の付着が悪くなる恐れがある。本発明で使用するビ
ニル重合体は、スチレンないしメタクリル酸低級アルキ
ルエステルの単独ないし共重合体とからなることが好ま
しい。これらの重合体は、陶磁器あるいは耐熱ガラス等
に絵柄等を焼き付ける工程で炭素を残留させることが少
ないため、上記焼成を円滑に行うことができる。共重合
に使用するビニル単量体は、メタクリル酸、アクリル
酸、マレイン酸ないしマレイン酸無水物、アクリル酸低
級アルキルエステル、アクリル酸アミドなどをあげるこ
とができる。The vinyl polymer is preferably 10 to 50 wt%. 50w because vinyl polymer scatters when baking patterns on ceramics or heat-resistant glass.
If it is more than t%, cracks may occur in the pattern or the like during the above firing. On the other hand, if it is less than 10 wt%, the adhesion of the design to the transfer paper may be deteriorated. The vinyl polymer used in the present invention preferably comprises a homopolymer or copolymer of styrene or methacrylic acid lower alkyl ester. Since these polymers rarely leave carbon in the step of baking a design or the like on a ceramic or a heat-resistant glass, the above-mentioned firing can be carried out smoothly. Examples of the vinyl monomer used for copolymerization include methacrylic acid, acrylic acid, maleic acid or maleic anhydride, acrylic acid lower alkyl ester, and acrylic acid amide.
【０００９】無機顔料およびガラス成分は９０〜５０ｗ
ｔ％であることが好ましい。９０ｗｔ％より多い場合に
は、転写紙への絵柄等の付着が悪くなる恐れがある。ま
た、５０ｗｔ％より少ない場合には、陶磁器あるいは耐
熱ガラス等に絵柄等を焼き付ける際にクラックが発生す
る恐れがある。90 to 50 w of the inorganic pigment and the glass component
It is preferably t%. If it is more than 90 wt%, the adhesion of the design or the like to the transfer paper may be deteriorated. On the other hand, if it is less than 50 wt%, cracks may occur when baking a design or the like on a ceramic or a heat-resistant glass.
【００１０】さらに、無機顔料とガラス成分との比率
は、１：９〜９：１が好ましい。ガラス成分が少ない
と、陶磁器あるいは耐熱ガラス等に絵柄等を焼き付ける
際に、絵柄等の接合が不充分な恐れがある。また、ガラ
ス成分が多いと絵柄等の発色が悪い恐れがある。Further, the ratio of the inorganic pigment to the glass component is preferably 1: 9 to 9: 1. If the glass component is small, the pattern or the like may be insufficiently bonded when the pattern or the like is baked on a ceramic or a heat-resistant glass. In addition, if the glass component is large, coloring such as a pattern may be bad.
【００１１】無機顔料は、鉄、コバルト、ニッケル、
銅、セレン、チタン、モリブデン、クロム、マンガンな
どの酸化物および金、ロジウムなど貴金属コロイド、セ
レン・ガドミウムなどをあげることができる。Inorganic pigments include iron, cobalt, nickel,
Examples thereof include oxides of copper, selenium, titanium, molybdenum, chromium, manganese, and the like, precious metal colloids such as gold and rhodium, and selenium-cadmium.
【００１２】ガラス成分は、無機顔料を陶磁器本体に固
着させるために使用されるものであり、珪素、アルミニ
ウム、カルシウム、マグネシウム、ほう素、アルカリ金
属、鉛、亜鉛、ジルコニウムなどの酸化物が用いられ
る。The glass component is used to fix the inorganic pigment to the ceramic body, and oxides such as silicon, aluminum, calcium, magnesium, boron, alkali metals, lead, zinc and zirconium are used. .
【００１３】有機・無機複合粉体の平均粒径は１〜２０
μｍであることが好ましい。１μｍより小さいと粉砕が
困難となる恐れがある。２０μｍより大きいと絵柄等の
鮮明さが劣る恐れがある。The average particle size of the organic / inorganic composite powder is 1 to 20.
It is preferably μm. If it is smaller than 1 μm, crushing may be difficult. If it is larger than 20 μm, the sharpness of the design may be deteriorated.
【００１４】さらに粉砕の容易さと絵柄等の鮮明さとを
配慮すれば、有機・無機複合紛体の平均粒径は、３〜１
５μｍであることが好ましい。Further, considering the ease of crushing and the sharpness of the design, the average particle size of the organic-inorganic composite powder is 3 to 1
It is preferably 5 μm.
【００１５】有機・無機複合粉体は、平均粒径０．５〜
１０μｍのガラス粉体および無機顔料粉体と、ビニル重
合体とを、加熱ニーダで混合あるいは有機溶剤の存在下
３本ロールで混合し、次に粗粉砕し、さらにボールミル
などで所望の粒度になるまで湿式粉砕をおこない、次に
分級して複合粉体とする製造方法によって得る。The organic-inorganic composite powder has an average particle size of 0.5 to
10 μm glass powder and inorganic pigment powder and vinyl polymer are mixed by a heating kneader or by three rolls in the presence of an organic solvent, then coarsely pulverized, and then a ball mill or the like to obtain a desired particle size. It is obtained by a manufacturing method in which wet pulverization is performed up to and then classification is performed to obtain a composite powder.
【００１６】転写紙は、紙による場合には、紙の表面に
ポリビニルアルコール、でんぷん、デキストリンなどの
水可溶性高分子を塗布する。この塗布面に、上記複合粉
体を絵柄に応じて乾式印刷する。次にメタクリル酸アル
キル系樹脂を全面に塗布して転写紙を製造する。When the transfer paper is paper, a water-soluble polymer such as polyvinyl alcohol, starch or dextrin is applied to the surface of the paper. The composite powder is dry-printed on the coated surface according to the pattern. Then, an alkyl methacrylate resin is applied to the entire surface to manufacture a transfer paper.
【００１６】転写紙は、水可溶性フィルムによる場合に
は、ポリビニルアルコールフィルムなどを用いる。この
フィルム上に、上記複合粉体を絵柄に応じて乾式印刷す
る。次にメタクリル酸アルキル系樹脂を全面に塗布して
転写紙を製造する。When the transfer paper is a water-soluble film, a polyvinyl alcohol film or the like is used. The composite powder is dry-printed on the film according to the design. Then, an alkyl methacrylate resin is applied to the entire surface to manufacture a transfer paper.
【００１７】[0017]
【作用】本発明方法の転写紙は、乾式法で製造されるた
め、溶剤の使用量を減少させることが可能であり、環境
を悪化させない。また、従来法と異なって、ガラス成分
と無機顔料を併用して粉体を形成するため、転写紙製造
に際して無機結合層を必須としない。さらに、乾式方法
のため、コンピュータ等に接続し、コンピュータ等の画
像を直接印刷することが可能であり、卓上で転写紙を制
作できる。このため、制作に要する時間を大幅に短縮す
ることが可能となる。また、絵柄等を画像データとして
送信できるため、遠隔地から送信し転写紙を作成するこ
とも可能となる。このように、本発明の複合紛体および
複合紛体による転写紙によれば、陶磁器、耐熱ガラスの
みならず、広く一般ガラス、ほうろう等への応用が可能
である。Since the transfer paper of the method of the present invention is manufactured by the dry method, the amount of the solvent used can be reduced and the environment is not deteriorated. Further, unlike the conventional method, since the powder is formed by using the glass component and the inorganic pigment together, the inorganic binding layer is not essential in the production of the transfer paper. Further, since it is a dry method, it is possible to connect to a computer or the like and directly print an image on the computer or the like, and transfer paper can be produced on a desk. Therefore, it is possible to greatly reduce the time required for production. Further, since the pattern and the like can be transmitted as image data, it is also possible to transmit the image from a remote place and create a transfer sheet. As described above, the composite powder of the present invention and the transfer paper of the composite powder can be applied not only to ceramics and heat-resistant glass but also to general glass, enamel and the like.
【００１８】[0018]
実施例１ 酸化鉛、酸化珪素、酸化アルミニウム、酸化アルカリ金
属、酸化アルカリ土類金属を構成要素とする平均粒径３
μｍのガラスフリット７０部（重量部、以下同じ）と、
酸化コバルトを主成分とする青色顔料３０部、酸価５の
ポリスチレン樹脂の３０％トルエン溶液７０部を混合
し、さらに３本ロールで混合した。この混合物をエタノ
ール中に投入してトルエンを溶出し、風乾させた。次
に、粗粉砕した後、水を使用してボールミルで粉砕し、
さらに乾燥させて平均粒径１３μｍ複合粉体を得た。こ
の複合粉体を乾式電子複写器を用い、デキストリンを塗
布した紙に印刷した。次にメタクリル酸系樹脂を印刷面
に塗布し、転写紙を得た。この転写紙を、常法により陶
磁器に転写し、およそ８００℃度で焼成した。このよう
にして得られた絵柄は、陶磁器に密着し、クラックやち
ぢれがなく、光沢のよい、美麗な絵柄が形成できた。Example 1 Average particle diameter 3 containing lead oxide, silicon oxide, aluminum oxide, alkali metal oxide, and alkaline earth metal oxide as constituent elements
70 parts of glass frit of μm (weight part, the same hereinafter),
30 parts of a blue pigment containing cobalt oxide as a main component and 70 parts of a 30% toluene solution of a polystyrene resin having an acid value of 5 were mixed and further mixed with a three-roll mill. This mixture was put into ethanol to elute toluene, and then air-dried. Next, after roughly crushing, crushing with a ball mill using water,
Further, it was dried to obtain a composite powder having an average particle size of 13 μm. The composite powder was printed on dextrin-coated paper using a dry electronic copying machine. Next, a methacrylic acid resin was applied to the printed surface to obtain a transfer paper. This transfer paper was transferred to a ceramic ware by a conventional method and fired at about 800 ° C. The pattern thus obtained was in close contact with the ceramics, was free from cracks and cracks, and had a beautiful glossy pattern.
【００１９】実施例２ 顔料として、実施例１の酸化コバルトの代わりにカドミ
ウム・セレン系顔料を用いた。また、ポリスチレン溶液
７０部の代わりにポリスチレンン溶液１２０部を用い
た。その他は実施例１と同様とした。これらを混合し、
さらにボールミルで混合した。以下実施例１と同様に操
作して、平均粒度１０μｍの複合粉体を得た。この複合
紛体を、実施例１と同様の方法で転写紙を作成した。こ
の転写紙を常法で陶磁器に転写した。その結果、陶磁器
に対する密着性に優れ、クラックやちぢれがなく、光沢
のよい美麗な絵柄が形成できた。Example 2 As a pigment, a cadmium-selenium type pigment was used in place of the cobalt oxide of Example 1. Further, 120 parts of polystyrene solution was used instead of 70 parts of polystyrene solution. Others were the same as in Example 1. Mix these,
Furthermore, it mixed with the ball mill. Thereafter, the same operation as in Example 1 was carried out to obtain a composite powder having an average particle size of 10 μm. A transfer paper was prepared from this composite powder in the same manner as in Example 1. This transfer paper was transferred to a ceramic by a conventional method. As a result, it was possible to form a beautiful design with excellent adhesion to ceramics, no cracks or cracks, and good gloss.
【００２０】実施例３ 実施例１の酸価５のポリスチレン樹脂のトルエン３０％
溶液７０部の代わりに、酸価３のポリメタクリル酸低級
アルキルエステル３０％溶液７０部を用いた。その他の
構成は実施例１と同様とした。これらを混合し、この混
合物を、水とエタノールが１：１の溶液に投入し、トル
エンを溶出後、風乾した。以後の操作は実施例１と同様
とし、平均粒度１０μｍの複合粉末を得た。この複合紛
体を、実施例１と同様の方法で転写紙を作成した。この
転写紙を常法で陶磁器に転写した。その結果、陶磁器に
対する密着性に優れ、クラツクやちぢれがなく、光沢の
よい美麗な絵柄が形成できた。Example 3 Toluene 30% of polystyrene resin with acid value 5 of Example 1
Instead of 70 parts of the solution, 70 parts of a 30% solution of polymethacrylic acid lower alkyl ester having an acid value of 3 was used. The other configurations were the same as in Example 1. These were mixed, and this mixture was poured into a solution of water and ethanol at a ratio of 1: 1 to elute toluene and then air-dried. Subsequent operations were the same as in Example 1 to obtain a composite powder having an average particle size of 10 μm. A transfer paper was prepared from this composite powder in the same manner as in Example 1. This transfer paper was transferred to a ceramic by a conventional method. As a result, it was possible to form a beautiful design with excellent adhesion to ceramics, no cracks and scratches, and good gloss.
【００２１】[0021]
【効果】本発明は、従来のスクリーン印刷方法に代わっ
て乾式方法で行うものであり、製版作業が大幅に短縮で
き、溶剤の使用量が少ないため、印刷工程の作業環境の
改善に有益で、耐熱ガラス製品やほうろう製品にも応用
可能であり、その工業的意義は大きい。[Effect] The present invention is performed by a dry method instead of the conventional screen printing method, which can significantly shorten the plate making work and uses a small amount of solvent, which is useful for improving the working environment of the printing process. It can be applied to heat-resistant glass products and enamel products, and its industrial significance is great.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 ＦＩ 技術表示箇所 Ｂ４４Ｃ 1/17 Ｄ 7361−3Ｋ Ｇ０３Ｇ 9/09 9/08 // Ｇ０３Ｇ 7/00 １０１ Ｚ Ｇ０３Ｇ 9/08 ３６１ ３６８ ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification code Internal reference number FI technical display location B44C 1/17 D 7361-3K G03G 9/09 9/08 // G03G 7/00 101 Z G03G 9 / 08 361 368
Claims (3)
顔料およびガラス成分９０〜５０ｗｔ％とからなる紛体
であって、その平均直径が１〜２０μｍであることを特
徴とする乾式印刷用有機・無機複合粉体。1. An organic material for dry printing, which is a powder comprising 10 to 50 wt% of a vinyl polymer, 90 to 50 wt% of an inorganic pigment and a glass component, and having an average diameter of 1 to 20 μm. Inorganic composite powder.
分とを混合し、ついで湿式粉砕することを特徴とする乾
式印刷用有機・無機複合紛体の製造方法。2. A method for producing an organic-inorganic composite powder for dry printing, which comprises mixing a vinyl polymer, an inorganic pigment and a glass component and then wet-milling them.
刷したことを特徴とする転写紙。3. A transfer paper, wherein the composite powder of claim 1 is electrically dry printed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5355244A JPH07199540A (en) | 1993-12-28 | 1993-12-28 | Organic and inorganic composite powder for dry transfer and its production |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5355244A JPH07199540A (en) | 1993-12-28 | 1993-12-28 | Organic and inorganic composite powder for dry transfer and its production |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH07199540A true JPH07199540A (en) | 1995-08-04 |
Family
ID=18442811
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5355244A Pending JPH07199540A (en) | 1993-12-28 | 1993-12-28 | Organic and inorganic composite powder for dry transfer and its production |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH07199540A (en) |
Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5212571B1 (en) * | 1967-06-02 | 1977-04-08 | ||
| JPS5289112A (en) * | 1976-01-22 | 1977-07-26 | Matsushita Electric Ind Co Ltd | Method of painting ceramics |
| JPS5684383A (en) * | 1979-12-13 | 1981-07-09 | Nissha Printing | Method of painting ceramic product |
| JPS5782083A (en) * | 1980-11-10 | 1982-05-22 | Hiroshi Goto | Ornamenting method for ceramic product |
| JPS6280668A (en) * | 1985-10-04 | 1987-04-14 | Matsushita Electric Ind Co Ltd | Developer for electrophotography |
| JPS6450060A (en) * | 1987-08-21 | 1989-02-27 | Seitetsu Kagaku Co Ltd | Production of electrostatic charge image developing toner |
| JPS6458582A (en) * | 1987-08-31 | 1989-03-06 | Kazuyoshi Kaigawa | Ceramic-decorating toner, production of transfer paper for ceramics by using of said toner and pattern printing method for ceramics by using of said toner |
| JPH0343289A (en) * | 1989-07-12 | 1991-02-25 | Katsushi Ishihama | Transfer paper and transfer |
| JPH03155567A (en) * | 1989-08-11 | 1991-07-03 | Bando Chem Ind Ltd | Production of toner for developing electrostatic latent image and production of dye and pigment dispersion used therefor |
| JPH04135798A (en) * | 1990-09-27 | 1992-05-11 | Mino Nendo Kk | Ceramic transfer sheet and manufacture of ceramics using the same sheet |
| JPH04195153A (en) * | 1990-11-28 | 1992-07-15 | Kao Corp | Production of electrostatic charge image developing toner |
| JPH05139020A (en) * | 1991-11-15 | 1993-06-08 | Noritake Co Ltd | Transfer paper and manufacture thereof |
-
1993
- 1993-12-28 JP JP5355244A patent/JPH07199540A/en active Pending
Patent Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5212571B1 (en) * | 1967-06-02 | 1977-04-08 | ||
| JPS5289112A (en) * | 1976-01-22 | 1977-07-26 | Matsushita Electric Ind Co Ltd | Method of painting ceramics |
| JPS5684383A (en) * | 1979-12-13 | 1981-07-09 | Nissha Printing | Method of painting ceramic product |
| JPS5782083A (en) * | 1980-11-10 | 1982-05-22 | Hiroshi Goto | Ornamenting method for ceramic product |
| JPS6280668A (en) * | 1985-10-04 | 1987-04-14 | Matsushita Electric Ind Co Ltd | Developer for electrophotography |
| JPS6450060A (en) * | 1987-08-21 | 1989-02-27 | Seitetsu Kagaku Co Ltd | Production of electrostatic charge image developing toner |
| JPS6458582A (en) * | 1987-08-31 | 1989-03-06 | Kazuyoshi Kaigawa | Ceramic-decorating toner, production of transfer paper for ceramics by using of said toner and pattern printing method for ceramics by using of said toner |
| JPH0343289A (en) * | 1989-07-12 | 1991-02-25 | Katsushi Ishihama | Transfer paper and transfer |
| JPH03155567A (en) * | 1989-08-11 | 1991-07-03 | Bando Chem Ind Ltd | Production of toner for developing electrostatic latent image and production of dye and pigment dispersion used therefor |
| JPH04135798A (en) * | 1990-09-27 | 1992-05-11 | Mino Nendo Kk | Ceramic transfer sheet and manufacture of ceramics using the same sheet |
| JPH04195153A (en) * | 1990-11-28 | 1992-07-15 | Kao Corp | Production of electrostatic charge image developing toner |
| JPH05139020A (en) * | 1991-11-15 | 1993-06-08 | Noritake Co Ltd | Transfer paper and manufacture thereof |
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